WO2009043957A1 - Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas - Google Patents
Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas Download PDFInfo
- Publication number
- WO2009043957A1 WO2009043957A1 PCT/ES2008/070179 ES2008070179W WO2009043957A1 WO 2009043957 A1 WO2009043957 A1 WO 2009043957A1 ES 2008070179 W ES2008070179 W ES 2008070179W WO 2009043957 A1 WO2009043957 A1 WO 2009043957A1
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- Prior art keywords
- film
- additive
- ppm
- less
- polar
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- 239000000654 additive Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 25
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 230000003287 optical effect Effects 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims description 18
- 239000003831 antifriction material Substances 0.000 claims description 17
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 15
- 239000002981 blocking agent Substances 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 150000002193 fatty amides Chemical class 0.000 claims description 4
- 229940037312 stearamide Drugs 0.000 claims description 3
- OXDXXMDEEFOVHR-CLFAGFIQSA-N (z)-n-[2-[[(z)-octadec-9-enoyl]amino]ethyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCNC(=O)CCCCCCC\C=C/CCCCCCCC OXDXXMDEEFOVHR-CLFAGFIQSA-N 0.000 claims description 2
- 125000003749 fatty amide group Chemical group 0.000 claims 1
- 239000012748 slip agent Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 23
- 239000011347 resin Substances 0.000 abstract description 23
- 239000000463 material Substances 0.000 abstract description 17
- 229920005672 polyolefin resin Polymers 0.000 abstract description 9
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- -1 polyethylene Polymers 0.000 description 14
- 239000010410 layer Substances 0.000 description 12
- 229920001971 elastomer Polymers 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 229920000034 Plastomer Polymers 0.000 description 8
- 239000000806 elastomer Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 5
- 229920002367 Polyisobutene Polymers 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 239000004611 light stabiliser Substances 0.000 description 4
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 4
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 4
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 2
- 229920001973 fluoroelastomer Polymers 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 239000004811 fluoropolymer Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 description 1
- FUSNPOOETKRESL-ZPHPHTNESA-N (z)-n-octadecyldocos-13-enamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCC\C=C/CCCCCCCC FUSNPOOETKRESL-ZPHPHTNESA-N 0.000 description 1
- 229910018089 Al Ka Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 229920000697 Lastol Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- XSMJZKTTXZAXHD-UHFFFAOYSA-N ethene;2-methylprop-2-enoic acid Chemical group C=C.CC(=C)C(O)=O XSMJZKTTXZAXHD-UHFFFAOYSA-N 0.000 description 1
- DERLTVRRWCJVCP-UHFFFAOYSA-N ethene;ethyl acetate Chemical compound C=C.CCOC(C)=O DERLTVRRWCJVCP-UHFFFAOYSA-N 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000011005 laboratory method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- VMRGZRVLZQSNHC-ZCXUNETKSA-N n-[(z)-octadec-9-enyl]hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(=O)NCCCCCCCC\C=C/CCCCCCCC VMRGZRVLZQSNHC-ZCXUNETKSA-N 0.000 description 1
- 150000002894 organic compounds Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
Definitions
- the present invention refers to a method for reducing the amount of polar additives necessary for use in polyolefin resin materials.
- the method includes
- the additives are used with polyolefin materials to confer various properties to the resin, in order to make it more suitable for its intended use.
- plasticizers e.g., hindered phenolics (e.g., Irganox TM 1010 manufactured by Ciba Specialty Ch.)
- Adhesion additives e.g., polyisobutylene (PIB)
- stabilizers of heat e.g, phosphites (eg, Irgafos TM 168)
- pigments eg, benzophenon Cyasorb TM UV 531 manufactured by Cytec Industries and obstructed amine light stabilizer Tinuvin TM 622 manufactured by Ciba Specialty Ch.
- Technological auxiliaries eg, polyethylene glycols, fluoropolymers, fluoroelastomers, waxes
- flame retardants eg, flame retardant based on Amgard TM CPC 102 phosphoric acid
- Booster TM manufactured by DuPont Booster TM manufactured by DuPont
- fogging agents eg, Atmer TM 100 sorbitan ester manufactured by Uniqema
- mo impact drivers eg, Paxon TM Pax Plus rubber modified film resin manufactured by Allied Corp.
- antistatic agents eg, Armostat tertiary ethoxylated amine manufactured by Akzo Chemicals, Inc.
- one or more of said objectives can be extended by adding at least one component with the formula Ri (OCH 2 CH 2 ) ⁇ OH to the polyolefin resin, where Ri is a linear or branched alkyl chain of 20 to 60 atoms of carbon, and x is between 2 and 100.
- one aspect of the present invention is the use of a compound with the formula Ri (OCH 2 CH 2 ) X OH as co-additive for polar additives in a polyolefin resin, where Ri is a linear or branched alkyl chain of 20 to 60 carbon atoms, and x is between 2 and 100.
- the co-additives of the present invention have a greater capacity to remain attached to the polyolefin resin. This phenomenon is considered to be, in part, the result of the resistance to movement given the relatively high molecular weight of the materials and, in part, of the increase in Van der Waals forces resulting from the relatively long non-polar tail. Likewise, it is considered that the OH groups at the end of these glues can be used as hydrogen bonds to fix polar additives, such as fatty amides, such as erucamide, which is commonly used as an antifriction agent in polyolefins.
- polar additives such as fatty amides, such as erucamide
- polar additives in particular those that function as surface modification, such as antifriction agents, are obtained with less material when the additive is on the surface, the ideal position for it to be effective. Likewise, the effects are maintained over a longer period of time, since the additive adheres to the resin to a greater degree than other commonly used additives. Likewise, it is important that the co-additives do not adversely affect the performance of the products manufactured with the resins that include the co-additive. For example, it is desirable that the sealability of the films made of resin incorporating the co-additives does not deteriorate substantially.
- the present invention refers to the use as a co-additive for use with any polar additive, the co-additive being a compound with the formula Ri (OCH 2 CH 2 ) x OH, where Ri is a linear alkyl chain or branched from 20 to 100 carbon atoms, preferably from 20 to 60 carbon atoms, and x is between 2 and 100.
- Ri is a linear alkyl chain or branched from 20 to 100 carbon atoms, preferably from 20 to 60 carbon atoms, and x is between 2 and 100.
- Ri is an alkyl linear chain with an average value of 30 carbon atoms, and x present an average value of approximately 5.
- Ri is a branched chain, or that Ri has 20 to 60 carbon atoms. It is preferred that the total average molecular weight for the co-additive be at least 400 g / mol, more preferably at least about 450 g / mol and less than about 2000 g / mol, more preferably less than about 1500 g / mol. It is also preferred that the ethylene oxide content comprises 20 to 80% by weight of the co-additive, more preferably less than or equal to about 50% by weight. Said compounds are described more widely for use as hydrophilic agents for the improvement of wettability in WO02 / 42530, which is incorporated herein by reference in its entirety.
- An example of such a compound is commercially available as a transport polypropylene concentrate from Ciba Specialty Chemicals, Inc. under the trade name Irgasurf TM HL 560.
- Other examples are commercially available through Baker Petrolite, under the trade name ethoxylates UNITHOX.
- the co-additive of the present invention will preferably be added to the resin in an amount of approximately 200 ppm, alternatively 500 ppm, or 1000 ppm to approximately 3000 ppm, alternatively 2500 ppm, or 2000 ppm, depending on the total resin or of the resin mixture.
- the fibers as is well known in the sector, it is generally preferable to use lower amounts of additives within the aforementioned range of variation (for example, from about 200 ppm to about 1000 ppm) to avoid problems in fiber spinning.
- These materials can be used with any polyolefin resin, or with a polyolefin resin that contains a mixture. Polyolefin materials Recommended are plastomers and / or elastomers.
- polyethylene elastomers and plastomers examples include polyethylene elastomers and plastomers, polypropylene plastomers, block oleophinic copolymers (also called multi-block statistical olefin copolymers), linear low density polyethylene, very high-density polyethylene Low density, low density and high pressure polyethylene, and high density polyethylene.
- polyethylene-based elastomers and plastomers there can be mentioned homogeneously branched linear ethylene polymers such as those of U.S. Patent No. 3,645,992, and substantially linear ethylene polymers such as those described in U.S. Patent 5,272,236, in U.S.
- Patent 5,278,272 in U.S. Patent 5,582,923 and in U.S. Patent 5,733,155, and / or mixtures thereof (such as those disclosed in U.S. Patents 3,914,342 or 5,854,045). These references are incorporated in their entirety to this document by reference.
- high pressure ethylene copolymers such as the ethylene vinyl acetate interpolymer, the ethylene acrylic acid interpolymer, the ethylene ethyl acetate interpolymer, the ethylene methacrylic acid interpolymer, the ionomer of methacrylic acid ethylene, cte.
- Substantially linear ethylene polymers are preferable.
- Substantially linear ethylene polymers are commercially available through Dow Chemical Company, under the trade name AFFINITY TM
- propylene-based elastomers and plastomers mention may be made of the propylene-based plastomers and elastomers described in WO03 / 040442, and in US patent application 60/709688 filed on August 19, 2005 (both of which are incorporated herein in their entirety document by reference - some of these materials are commercially available through The Dow Chemical Company under the trade name of VERSI FY TM), and the propylene-based plastomers and elastomers marketed by ExxonMobil Chemical under the trade name of VISTAMAXX TM.
- Segmented ethylene block alpha-olefin copolymers include those described, for example, in WO 2005/090427, WO 2005/090425 and WO 2005/090426, all of which are incorporated herein by reference in their entirety. Some of these resins are commercially available through The Dow Chemical Company under the trade name of INFUSE TM.
- Preferred polymers for use in the present invention are those containing a polymeric structure containing a minimum of 50% carbon atoms, 65% of carbon atoms being more recommended, and being more 75% carbon atoms recommended.
- the polymers that benefit most from using the present invention are those with a relatively low surface energy.
- the surface energy can be measured using various conventional techniques, and they are known by specialists in this discipline, such as the measurement of the contact angle of the water (ASTM D 2578) or the direct measurement using a stylus measuring in dynes (ASTM D 2578) , such as the ACCUDYNE TEST TM markers sold by Diversified Enterprises, Claremont, NH.
- a base resin having a density (determined according to ASTM D-792) of 0.87 g / cm 3 , 0.90 g / cm 3 , 0.91 g / cm 3 or 0.92 g / cm 3 at about 0.96 g / cm 3 , 0.95 g / cm 3 or 0.94 g / cm 3 .
- a base resin having a melt index (determined according to ASTM D-1238, Condition 190 C / 2.16 kilogram (kg)) of 0.5 g / 10 min, preferably 1, 0 g / 10 min, more preferably 2 g / 10 min at about 20 g / 10 min, preferably 18 g / 10 min, more preferably 15 g / 10 min.
- the polar additive of the present invention can be any additive commonly used with polyolefin resins.
- Functional additives include plasticizers, antioxidants (e.g., hindered phenolics (e.g., Irganox TM 1010 manufactured by Ciba Specialty Ch.)), Heat stabilizers (e.g., phosphites (e.g.
- adhesion additives eg, polyisobutylene (PIB)
- pigments eg, benzophenon Cyasorb TM UV 531 manufactured by Cytec Industries and obstructed amine light stabilizer Tinuvin TM 622 manufactured by Ciba Specialty Ch.
- PIB polyisobutylene
- Technical complements eg, polyethylene glycols, fluoropolymers, fluoroelastomers, waxes
- flame retardants eg, flame retardant based on Amgard TM CPC 102 phosphorus base manufactured by Albright and Wilson Americas
- lubricants e.g., waxes, stearates, mineral oils
- anti-friction agents e.g., erucamide, oleamide
- bonding agents e.g., peroxides, (e.g.
- Booster TM manufactured by DuPont Booster TM manufactured by DuPont
- fogging agents eg, Atmer TM 100 sorbitan ester manufactured by Uniqe ma
- impact modifiers eg, Paxon TM Pax Plus rubber modified film resin manufactured by Allied Corp.
- antistatic agents eg, Armostat tertiary ethoxylated amine 4.10 manufactured by Akzo Chemicals, Inc.
- antifriction agents are often polar and, therefore, are effectively adapted to the present invention.
- the antifriction agent is an organic compound (including metal salts thereof) with a wax or chain type hydrocarbon component, and is semi-compatible with the polyolefin.
- the antifriction agents may be amides of a mono or dicarboxylic fatty acid having a number of carbon atoms between 8 and 30, and in particular having between 12 and 24 carbon atoms that may be saturated or unsaturated with ethylene, with ammonia or mono or diamines having between 2 and 10 carbon atoms, such as primary alkylamines or primary alkyne diamines.
- anti-friction agents examples include oleamide, behenamide, stearamide, erucamide and diamine N, N'-alkyl bis stearamide, bis oleamide or bis erucamide, oleyl palmitamide, stearyl erucamide, ethylene bis bis steamide and ethylene bis oleamide.
- the antifriction agent can be a hydrocarbon wax. Because the co-additives of the present invention allow the use of less polar additive without a proportional loss of efficiency, additives can be added in amounts lower than those observed in general. For erucamide in films, fibers or manufactured articles, it can be added effectively in a range of 250 ppm to 2% by weight. For numerous applications, it will be preferable that the co-additive is added in an amount of 1500 ppm or less, for example 1000 ppm or less, 750 ppm or less, 500 ppm or less or even less than 200 ppm.
- the additive (s) and the co-additive of the present invention can be added using any method known in this discipline, such as by concentrating and mixing the combined products.
- Polypropylene can be used effectively as a polymer transport agent to form a concentrate for the co-additive.
- non-polar additives can be added to the polyolefin materials, depending on the intended use.
- additional anti-blocking agents for example, silicon anti-blocking agents such as silicon dioxide. This may be particularly desirable for use in films.
- an additive package suitable for use in the manufacture of polyolefin films may include silicon dioxide, erucamide and Irgasurf TM HL 560.
- the additive and co-additive containing resins, object of the present invention can be used in any application in which polyolefins are currently used.
- the invention may have a special utility in fibers and in films.
- films containing at least approximately 300 ppm of anti-blocking agent can be obtained and, nevertheless, are characterized with a brightness (determined at 45 ° using ASTM D2457-90) greater than about 50, together with a total optical clarity (determined using Ia ISO 14782 standard, with a film thickness of 50 microns) less than approximately 14%.
- the films manufactured using the present invention can be manufactured according to the standardized processes of the sector. Accordingly, they can be used for example with mono or coextruded films that can optionally be subjected to a corona treatment.
- each example contains a unique combination of additives, which is shown in Table 1.
- comparative example 1 contained 750 ppm of erucamide, 0 ppm of Irgasurf TM and 2500 ppm of silica.
- the silica used in these examples was a flux type of calcined diatomaceous earth, with a particle size distribution of 90% less than 20.2 ⁇ m and less than 10% less than 2.3 ⁇ m.
- Film specimens were removed from the roll based on the elapsed time, as indicated in the tables.
- the integrity of the specimens was optimized using thorough laboratory techniques, such as the use of gloves to cut the films of the roll, and minimizing contact with the test surface.
- the exact geometry of the specimens remained uniform, since all samples were reduced from a larger sample using a die cutter.
- the coefficient of friction (COF) was measured in static mode and in dynamic mode, using a universal meter (Instron 5564) according to the test method of ASTM 1894-06. Experiments were performed on the film by displacing it on an aluminum surface, as well as a film-against-film test. In general, a dynamic film COF against film less than or equal to about 0.3, preferably less than or equal to 0.2, is desirable.
- the method of the present invention produces particularly improved performance in reducing COF at higher temperatures, such as temperatures above 4O 0 C or 5O 0 C.
- Table 2 shows the COF data generated while the film is in contact with itself when moving (that is, the inner layer of the film bubble is in contact with the outer layer of the bubble).
- Table 3 shows the COF data generated while the outer layer of the film bubble moves on a metal surface.
- Example 2 The Irgasurf film at 2500 ppm (Example 2) obtained the lowest dynamic COF for both film-film and film-metal.
- Table 4 shows the COF data of these films generated while the film is in contact with itself when it moves (that is, the inner layer of the film bubble is in contact with the outer layer of the bubble).
- Table 5 shows the COF data generated while the outer layer of the bubble of the film moves on a metal surface.
- This second set of films was also tested according to the same test method of ASTM 1894-06 using a slip / friction coefficient monitor purchased from Testing Machines, Inc. (TMI).
- Table 6 shows the COF data generated while the film is in contact with itself when it moves (that is, the inner layer of the film bubble is in contact with the outer layer of the bubble).
- Table 7 shows the COF data generated while the outer layer of the film bubble was displaced on a metal surface.
- the base resin for Examples 11 and 13 was a copolymer of ethylene 1-octene with a density of 0.919 and a melt index (2.16 Kg 190 0 C) of 1.05 g / 10 min.
- the base resin for Examples 12 and 14 was a copolymer of ethylene 1-octene with a density of 0.921 with the same melt index (1.05 g1 10 min).
- the compositions tested are presented in Table 8.
- the films were produced in the Covex monolayer line (45 mm 25D).
- the COF in the Instron equipment was measured again following ISO 8295: 1995.
- Table 9 shows the COF data generated while the film is in contact with itself when moving (that is, the inner layer of the film bubble is in contact with the outer layer of the bubble).
- Table 10 shows the COF data generated while the outer layer of the film bubble moves on a metal surface.
- Example 13 the sample with Irgasurf at 1000 ppm and only 350 ppm of erucamide (ie, Example 13) presented a COF higher than that of comparative example 12, demonstrating the effect that the density of the base resin has on the COF. Note the comparison of Examples 13 and 14 that with Irgasurf, even the film with half the erucamide level continued to offer COF values below 0.2 for the film-film COF.
- Example 14 had a higher brightness and a total optical clarity lower than that of Example 12, despite similar erucamide and slightly higher levels of CaCO 3 .
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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CN200880118747XA CN101883813A (zh) | 2007-10-02 | 2008-10-01 | 减少聚烯烃中必需使用的极性添加剂的方法 |
US12/680,970 US20120046401A1 (en) | 2007-10-02 | 2008-10-01 | Method for the reduction of polar additives required for use in polyolefins |
JP2010527476A JP5366956B2 (ja) | 2007-10-02 | 2008-10-01 | ポリオレフィンにおける使用のために要求される極性添加物の削減方法 |
EP08835316A EP2233520A1 (en) | 2007-10-02 | 2008-10-01 | Methods for reducing the polar additives necessary for use in polyolefins |
MX2010003688A MX2010003688A (es) | 2007-10-02 | 2008-10-01 | Metodo para la reduccion de aditivos polares necesarios para uso en poliolefinas. |
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ESPCT/ES2007/070165 | 2007-10-02 | ||
PCT/ES2007/070165 WO2009043946A1 (es) | 2007-10-02 | 2007-10-02 | Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas |
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PCT/ES2007/070165 WO2009043946A1 (es) | 2007-10-02 | 2007-10-02 | Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas |
PCT/ES2008/070179 WO2009043957A1 (es) | 2007-10-02 | 2008-10-01 | Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas |
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US (1) | US20120046401A1 (es) |
EP (1) | EP2233520A1 (es) |
JP (1) | JP5366956B2 (es) |
CN (1) | CN101883813A (es) |
AR (1) | AR068654A1 (es) |
MX (1) | MX2010003688A (es) |
RU (1) | RU2010117361A (es) |
TR (1) | TR201002739T2 (es) |
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WO2010145995A1 (en) * | 2009-06-15 | 2010-12-23 | Basf Se | Permanent antistatic additive composition |
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EP2512805B1 (en) | 2009-12-18 | 2018-02-21 | Dow Global Technologies LLC | Films and articles prepared from the same |
EP2471856A1 (en) * | 2010-12-30 | 2012-07-04 | Dow Global Technologies LLC | Polyolefin compositions |
CN103421235B (zh) * | 2013-07-30 | 2016-06-01 | 金发科技股份有限公司 | 一种聚丙烯组合物及其制备方法 |
US10251770B2 (en) | 2014-01-03 | 2019-04-09 | Hollister Incorporated | Lubricated valve for ostomy pouch |
JP2018529006A (ja) * | 2015-09-18 | 2018-10-04 | ダウ グローバル テクノロジーズ エルエルシー | 温室フィルムに使用される高性能滴下防止剤 |
EP3911705A4 (en) * | 2019-01-15 | 2022-09-14 | Avient Corporation | SLUBABLE THERMOPLASTIC COMPOUNDS AND THERMOPLASTIC ARTICLES MADE THEREOF |
CN115678155B (zh) * | 2022-12-13 | 2024-04-23 | 宁波致微新材料科技有限公司 | 一种聚烯烃弹性体微孔发泡材料及其制备方法 |
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- 2008-10-01 RU RU2010117361/05A patent/RU2010117361A/ru not_active Application Discontinuation
- 2008-10-01 US US12/680,970 patent/US20120046401A1/en not_active Abandoned
- 2008-10-01 JP JP2010527476A patent/JP5366956B2/ja not_active Expired - Fee Related
- 2008-10-01 TR TR2010/02739T patent/TR201002739T2/xx unknown
- 2008-10-01 MX MX2010003688A patent/MX2010003688A/es unknown
- 2008-10-01 TW TW097137712A patent/TW200922985A/zh unknown
- 2008-10-01 AR ARP080104297A patent/AR068654A1/es not_active Application Discontinuation
- 2008-10-01 WO PCT/ES2008/070179 patent/WO2009043957A1/es active Application Filing
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Also Published As
Publication number | Publication date |
---|---|
JP5366956B2 (ja) | 2013-12-11 |
TW200922985A (en) | 2009-06-01 |
JP2010540743A (ja) | 2010-12-24 |
US20120046401A1 (en) | 2012-02-23 |
MX2010003688A (es) | 2010-06-17 |
EP2233520A1 (en) | 2010-09-29 |
AR068654A1 (es) | 2009-11-25 |
TR201002739T2 (tr) | 2012-02-21 |
RU2010117361A (ru) | 2011-11-10 |
WO2009043946A1 (es) | 2009-04-09 |
CN101883813A (zh) | 2010-11-10 |
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