WO2009043496A3 - Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung - Google Patents
Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung Download PDFInfo
- Publication number
- WO2009043496A3 WO2009043496A3 PCT/EP2008/007954 EP2008007954W WO2009043496A3 WO 2009043496 A3 WO2009043496 A3 WO 2009043496A3 EP 2008007954 W EP2008007954 W EP 2008007954W WO 2009043496 A3 WO2009043496 A3 WO 2009043496A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- producing
- same
- hydrogenation
- dehydrogenation reactions
- resistant catalyst
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000006356 dehydrogenation reaction Methods 0.000 title 1
- 238000005245 sintering Methods 0.000 title 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000002828 nitro derivatives Chemical class 0.000 abstract 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/056—Submicron particles having a size above 100 nm up to 300 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/16—Metallic particles coated with a non-metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/677,157 US20100204518A1 (en) | 2007-10-04 | 2008-09-09 | Sintering resistant catalyst for use in hydrogenation and dehydrogenation reactions and methods for producing the same |
JP2010527353A JP5415425B2 (ja) | 2007-10-04 | 2008-09-20 | 水素化および脱水素化反応において使用する焼結耐性触媒ならびにその製造方法 |
CN200880110149A CN101815575A (zh) | 2007-10-04 | 2008-09-20 | 用于氢化和脱氢反应的烧结稳定的催化剂及其制备方法 |
EP08802454A EP2200739A2 (de) | 2007-10-04 | 2008-09-20 | Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung |
BRPI0817590-0A BRPI0817590A2 (pt) | 2007-10-04 | 2008-09-20 | Catalisador estável à sinterização para hidrogenação e desidrogenação e processo para a sua produção |
RU2010116815/04A RU2480278C2 (ru) | 2007-10-04 | 2008-09-20 | Не подверженный спеканию катализатор гидрирования и дегидрирования и способ его получения |
US13/625,972 US20130035511A1 (en) | 2007-10-04 | 2012-09-25 | Process for hydrogenating organic compounds with hydrogen in the gas phase in the presence of a catalyst |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007047434.4 | 2007-10-04 | ||
DE102007047434A DE102007047434A1 (de) | 2007-10-04 | 2007-10-04 | Sinterstabiler Katalysator für die Hydrierung und Dehydrierungen und Verfahren zu dessen Herstellung |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/625,972 Division US20130035511A1 (en) | 2007-10-04 | 2012-09-25 | Process for hydrogenating organic compounds with hydrogen in the gas phase in the presence of a catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009043496A2 WO2009043496A2 (de) | 2009-04-09 |
WO2009043496A3 true WO2009043496A3 (de) | 2009-06-18 |
Family
ID=40386027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/007954 WO2009043496A2 (de) | 2007-10-04 | 2008-09-20 | Sinterstabiler katalysator für die hydrierung und dehydrierungen und verfahren zu dessen herstellung |
Country Status (8)
Country | Link |
---|---|
US (2) | US20100204518A1 (de) |
EP (1) | EP2200739A2 (de) |
JP (1) | JP5415425B2 (de) |
CN (1) | CN101815575A (de) |
BR (1) | BRPI0817590A2 (de) |
DE (1) | DE102007047434A1 (de) |
RU (1) | RU2480278C2 (de) |
WO (1) | WO2009043496A2 (de) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008060259A1 (de) | 2008-12-03 | 2010-06-10 | Bayer Technology Services Gmbh | Katalysator für Oxidationsreaktionen in Gegenwart von Chlorwasserstoff und/oder Chlor und Verfahren zu dessen Herstellung, sowie dessen Verwendung |
DE102009056700A1 (de) | 2009-12-02 | 2011-06-16 | Bayer Technology Services Gmbh | Katalysator bestehend aus Silikathüllen und darin befindlichen, räumlich orientierten Nanopartikeln einer Rutheniumverbindung |
CN101972651B (zh) * | 2010-10-20 | 2012-06-13 | 中南民族大学 | 一种金属钯纳米材料催化剂及其制备和应用 |
JP6158166B2 (ja) * | 2011-04-11 | 2017-07-05 | カウンシル オブ サイエンティフィック アンド インダストリアル リサーチ | 金属クラスターおよびナノ粒子が封入された安定酸化物 |
CN103480369B (zh) * | 2012-06-13 | 2015-05-20 | 中国石油天然气股份有限公司 | 一种铂纳米复合催化剂及其制备和应用 |
CN103990453A (zh) * | 2014-05-30 | 2014-08-20 | 南京工业大学 | 一种催化加氢用催化剂制备方法 |
US9433932B2 (en) | 2014-08-29 | 2016-09-06 | National Cheng Kung University | Hydrogenation catalyst and method of manufacturing the same |
US9855547B2 (en) | 2015-10-05 | 2018-01-02 | GM Global Technology Operations LLC | Low-temperature oxidation catalysts |
US10046310B2 (en) | 2015-10-05 | 2018-08-14 | GM Global Technology Operations LLC | Catalytic converters with age-suppressing catalysts |
US9827562B2 (en) | 2015-10-05 | 2017-11-28 | GM Global Technology Operations LLC | Catalytic converters with age-suppressing catalysts |
US10422036B2 (en) | 2015-10-23 | 2019-09-24 | GM Global Technology Operations LLC | Suppressing aging of platinum group metal particles in a catalytic converter |
US9901907B1 (en) | 2016-08-31 | 2018-02-27 | GM Global Technology Operations LLC | Catalytic converters with age-suppressing catalysts |
US10159960B2 (en) | 2016-10-25 | 2018-12-25 | GM Global Technology Operations LLC | Catalysts with atomically dispersed platinum group metal complexes |
US10035133B2 (en) | 2016-10-25 | 2018-07-31 | GM Global Technology Operations LLC | Catalysts with atomically dispersed platinum group metal complexes and a barrier disposed between the complexes |
CN109833879B (zh) * | 2017-11-24 | 2021-08-06 | 中国石油化工股份有限公司 | 一种渣油加氢催化剂及其制备方法 |
CN110252272B (zh) * | 2019-06-17 | 2022-04-22 | 万华化学集团股份有限公司 | 一种连续大规模制备烯烃环氧化催化剂的方法及装置 |
CN112958080B (zh) * | 2021-02-05 | 2022-10-11 | 浙江工业大学上虞研究院有限公司 | 一种介孔型钯催化剂的制备方法 |
CN112958081B (zh) * | 2021-02-05 | 2022-10-14 | 浙江工业大学上虞研究院有限公司 | 一种中空型复合钯催化剂的制备方法 |
CN112934220B (zh) * | 2021-02-05 | 2022-10-04 | 浙江工业大学上虞研究院有限公司 | 一种中空型钯催化剂微球的制备方法 |
CN116351441B (zh) * | 2023-03-21 | 2024-07-02 | 北京化工大学 | 具有协同位点负载型选择性加氢催化剂及其制备方法和应用 |
CN116060137B (zh) * | 2022-11-23 | 2023-10-27 | 中国农业大学 | 用于液体有机储氢材料加氢与脱氢的纳米金属催化剂及其制备方法和应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007063615A1 (ja) * | 2005-11-30 | 2007-06-07 | Juridical Foundation Osaka Industrial Promotion Organization | 中空層多孔質カプセルに包接された触媒及びその製造方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4111719A1 (de) * | 1991-04-10 | 1992-10-15 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung hochaktiver, dotierter metall-traegerkatalysatoren |
DE4319909C2 (de) * | 1993-06-16 | 1996-11-07 | Solvay Deutschland | Palladium, Platin, Nickel, Kobalt und/oder Kupfer umfassender Aerogel-Trägerkatalysator, Verfahren zu seiner Herstellung und Verwendung eines Palladium-Aerogel-Trägerkatalysators |
JPH09225305A (ja) * | 1996-02-27 | 1997-09-02 | Chunkuo Suuyuu Kofun Yugenkoshi | 卵殻状金属触媒の製造方法 |
DE19753464A1 (de) * | 1997-12-02 | 1999-06-10 | Basf Ag | Palladium-Cluster und ihre Verwendung als Katalysatoren |
JP3867232B2 (ja) * | 2004-03-25 | 2007-01-10 | 株式会社 東北テクノアーチ | 触媒ナノ粒子 |
JP5260278B2 (ja) * | 2005-05-09 | 2013-08-14 | ビーエーエスエフ コーポレーション | 不飽和トリグリセリドの水素化方法 |
JP2007029778A (ja) * | 2005-07-22 | 2007-02-08 | Nissan Motor Co Ltd | 排ガス浄化触媒及びその製造方法 |
RU2299190C1 (ru) * | 2005-11-09 | 2007-05-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ окислительного дегидрирования легких парафинов |
RU2289565C1 (ru) * | 2005-11-09 | 2006-12-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ селективного гидрирования ацетиленовых углеводородов в газовых смесях, богатых олефинами |
KR100745744B1 (ko) * | 2005-11-11 | 2007-08-02 | 삼성전기주식회사 | 나노 입자 코팅 방법 |
DE102006007619A1 (de) * | 2006-02-18 | 2007-08-23 | Bayer Materialscience Ag | Verfahren zur Herstellung von Anilin |
FR2898519B1 (fr) * | 2006-03-20 | 2009-01-09 | Commissariat Energie Atomique | Nanoparticules notamment a structure coeur coquilles, enrobees |
-
2007
- 2007-10-04 DE DE102007047434A patent/DE102007047434A1/de not_active Withdrawn
-
2008
- 2008-09-09 US US12/677,157 patent/US20100204518A1/en not_active Abandoned
- 2008-09-20 CN CN200880110149A patent/CN101815575A/zh active Pending
- 2008-09-20 BR BRPI0817590-0A patent/BRPI0817590A2/pt not_active Application Discontinuation
- 2008-09-20 RU RU2010116815/04A patent/RU2480278C2/ru not_active IP Right Cessation
- 2008-09-20 EP EP08802454A patent/EP2200739A2/de not_active Ceased
- 2008-09-20 WO PCT/EP2008/007954 patent/WO2009043496A2/de active Application Filing
- 2008-09-20 JP JP2010527353A patent/JP5415425B2/ja not_active Expired - Fee Related
-
2012
- 2012-09-25 US US13/625,972 patent/US20130035511A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007063615A1 (ja) * | 2005-11-30 | 2007-06-07 | Juridical Foundation Osaka Industrial Promotion Organization | 中空層多孔質カプセルに包接された触媒及びその製造方法 |
Non-Patent Citations (6)
Title |
---|
ARNAL P M ET AL: "High-Temperature-Stable Catalysts by Hollow Sphere Encapsulation", ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, WILEY VCH VERLAG, WEINHEIM, vol. 118, no. 48, 16 November 2006 (2006-11-16), pages 8404 - 8407, XP002500592, ISSN: 1433-7851 * |
CARUSO F: "NANOENGINEERING OF PARTICLE SURFACES", ADVANCED MATERIALS, WILEY VCH, WEINHEIM, DE, vol. 13, no. 1, 5 January 2001 (2001-01-05), pages 11 - 22, XP001001060, ISSN: 0935-9648 * |
LI K T ET AL: "Palladium core-porous silica shell-nanoparticles for catalyzing the hydrogenation of 4-carboxybenzaldehyde", CATALYSIS COMMUNICATIONS, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 9, no. 13, 20 July 2008 (2008-07-20), pages 2257 - 2260, XP022824418, ISSN: 1566-7367, [retrieved on 20080521] * |
SANG HOON JOO, JEONG YOUNG PARK, CHIA-KUANG TSUNG, YUSUKE YAMADA, PEIDONG YANG, GABOR A. SOMORJAI: "Thermally stable Pt/mesoporous silica core?shell nanocatalysts for high-temperature reactions", NATURE MATERIALS, vol. 8, 23 November 2008 (2008-11-23), pages 126 - 131, XP002518588 * |
SONG J R ET AL: "Preparation and characterization of novel Pd/SiO2 and Ca-Pd/SiO2 egg-shell catalysts with porous hollow silica", APPLIED SURFACE SCIENCE, ELSEVIER, AMSTERDAM, NL, vol. 253, no. 5, 30 December 2006 (2006-12-30), pages 2678 - 2684, XP024892327, ISSN: 0169-4332, [retrieved on 20061230] * |
ZHONG C-J ET AL: "CORE-SHELL ASSEMBLED NANOPARTICLES AS CATALYSTS", ADVANCED MATERIALS, WILEY VCH, WEINHEIM, DE, vol. 13, no. 19, 2 October 2001 (2001-10-02), pages 1507 - 1511, XP001129515, ISSN: 0935-9648 * |
Also Published As
Publication number | Publication date |
---|---|
JP2010540232A (ja) | 2010-12-24 |
WO2009043496A2 (de) | 2009-04-09 |
CN101815575A (zh) | 2010-08-25 |
JP5415425B2 (ja) | 2014-02-12 |
RU2480278C2 (ru) | 2013-04-27 |
EP2200739A2 (de) | 2010-06-30 |
US20100204518A1 (en) | 2010-08-12 |
RU2010116815A (ru) | 2011-11-10 |
US20130035511A1 (en) | 2013-02-07 |
BRPI0817590A2 (pt) | 2015-03-31 |
DE102007047434A1 (de) | 2009-04-09 |
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