WO2009038369A3 - Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same - Google Patents

Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same Download PDF

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Publication number
WO2009038369A3
WO2009038369A3 PCT/KR2008/005525 KR2008005525W WO2009038369A3 WO 2009038369 A3 WO2009038369 A3 WO 2009038369A3 KR 2008005525 W KR2008005525 W KR 2008005525W WO 2009038369 A3 WO2009038369 A3 WO 2009038369A3
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WO
WIPO (PCT)
Prior art keywords
organic
layer
metal oxide
photovoltaic cell
junction
Prior art date
Application number
PCT/KR2008/005525
Other languages
French (fr)
Other versions
WO2009038369A2 (en
Inventor
Kwang-Hee Lee
Sung-Heum Park
Hee-Joo Kim
Original Assignee
Kwangju Inst Sci & Tech
Kwang-Hee Lee
Sung-Heum Park
Hee-Joo Kim
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kwangju Inst Sci & Tech, Kwang-Hee Lee, Sung-Heum Park, Hee-Joo Kim filed Critical Kwangju Inst Sci & Tech
Priority to JP2010525759A priority Critical patent/JP5149389B2/en
Priority to EP08832235.9A priority patent/EP2191523A4/en
Priority to US12/678,372 priority patent/US20100193034A1/en
Priority to CN200880107678A priority patent/CN101803054A/en
Publication of WO2009038369A2 publication Critical patent/WO2009038369A2/en
Publication of WO2009038369A3 publication Critical patent/WO2009038369A3/en
Priority to US14/539,169 priority patent/US20150072465A1/en

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    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
    • H01L31/072—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/20—Organic diodes
    • H10K10/29—Diodes comprising organic-inorganic heterojunctions
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/80—Constructional details
    • H10K10/82—Electrodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
    • H10K30/151—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2 the wide bandgap semiconductor comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/40—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising a p-i-n structure, e.g. having a perovskite absorber between p-type and n-type charge transport layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10—Deposition of organic active material
    • H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
    • H10K71/15—Deposition of organic active material using liquid deposition, e.g. spin coating characterised by the solvent used
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/30—Doping active layers, e.g. electron transporting layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/60—Forming conductive regions or layers, e.g. electrodes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90—Applications
    • C08G2261/91—Photovoltaic applications
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80—Constructional details
    • H10K30/81—Electrodes
    • H10K30/82—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10—Deposition of organic active material
    • H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H10K85/1135—Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

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  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Materials Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

Provided are an organic-inorganic hybrid junction device in which organic and inorganic materials are connected by junction, and a depletion layer is formed at a junction interface, and an organic photovoltaic cell using the same. A basic metal oxide solution is applied to a top surface of a P-doped organic layer. The basic metal oxide solution has N-type characteristics. An oxidation-reduction reaction occurs in response to the application of the basic metal oxide solution at a junction interface of the organic layer, and the metal oxide layer is simultaneously gelated. A free charge is removed from a surface region of the P-doped organic layer by the oxidation-reduction reaction at the interface, which is converted into a depletion region. According to the introduction of the depletion region, P-N junction occurs, and thus the device has a diode characteristic in an electrical aspect. Also, an organic photovoltaic cell including the organic layer, the depletion layer and the metal oxide layer is fabricated.
PCT/KR2008/005525 2007-09-18 2008-09-18 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same WO2009038369A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2010525759A JP5149389B2 (en) 2007-09-18 2008-09-18 Organic-inorganic hybrid junction device using oxidation-reduction reaction and organic solar cell using the same
EP08832235.9A EP2191523A4 (en) 2007-09-18 2008-09-18 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same
US12/678,372 US20100193034A1 (en) 2007-09-18 2008-09-18 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same
CN200880107678A CN101803054A (en) 2007-09-18 2008-09-18 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same
US14/539,169 US20150072465A1 (en) 2007-09-18 2014-11-12 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2007-0094992 2007-09-18
KR20070094992 2007-09-18

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/678,372 A-371-Of-International US20100193034A1 (en) 2007-09-18 2008-09-18 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same
US14/539,169 Division US20150072465A1 (en) 2007-09-18 2014-11-12 Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same

Publications (2)

Publication Number Publication Date
WO2009038369A2 WO2009038369A2 (en) 2009-03-26
WO2009038369A3 true WO2009038369A3 (en) 2009-05-14

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Country Status (6)

Country Link
US (2) US20100193034A1 (en)
EP (1) EP2191523A4 (en)
JP (1) JP5149389B2 (en)
KR (1) KR100972735B1 (en)
CN (1) CN101803054A (en)
WO (1) WO2009038369A2 (en)

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Publication number Priority date Publication date Assignee Title
SM200900070B (en) * 2009-08-07 2012-03-05 Antonio Maroscia Multilayer photovoltaic composition and construction method
KR101415822B1 (en) * 2010-06-29 2014-07-09 코오롱인더스트리 주식회사 Polymer solar cell and method for manufacturing the same
US8735718B2 (en) 2010-09-13 2014-05-27 University Of Central Florida Electrode structure, method and applications
KR101130516B1 (en) * 2010-11-08 2012-03-28 단국대학교 산학협력단 High efficient organic solar cell and method for preparing the same
KR101651688B1 (en) * 2010-12-03 2016-08-26 서울시립대학교 산학협력단 Solar cell and method of the manufacturing of the same
KR101651689B1 (en) * 2010-12-24 2016-08-26 서울시립대학교 산학협력단 Organic-inorganic hybrid solar cell and method of the manufacturing of the same
KR101756991B1 (en) * 2011-01-10 2017-07-12 서울시립대학교 산학협력단 Conductive paper, solar cell using the conductive paper and method of the manufacturing of the same
KR101880153B1 (en) 2012-04-05 2018-07-20 삼성전자주식회사 Hybrid metal oxide and method of forming the same and solar cell including the same
KR101483959B1 (en) * 2013-07-01 2015-01-20 광주과학기술원 Organic electronic device and manufacturing method thereof
CN103346260B (en) * 2013-07-24 2016-03-02 苏州大学 Hybrid inorganic-organic solar cell of organic film passivation and preparation method thereof
CN104701455A (en) * 2013-12-06 2015-06-10 中国科学院苏州纳米技术与纳米仿生研究所 Hybrid membrane production method
KR101772437B1 (en) 2014-12-03 2017-08-30 경희대학교 산학협력단 Light-emitting Device fabricated utilizing charge generation layer formed by solution process and fabrication method thereof

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Also Published As

Publication number Publication date
KR20090029675A (en) 2009-03-23
KR100972735B1 (en) 2010-07-27
EP2191523A2 (en) 2010-06-02
US20100193034A1 (en) 2010-08-05
CN101803054A (en) 2010-08-11
JP5149389B2 (en) 2013-02-20
JP2010539726A (en) 2010-12-16
WO2009038369A2 (en) 2009-03-26
EP2191523A4 (en) 2017-07-26
US20150072465A1 (en) 2015-03-12

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