WO2008084167A3 - Procede et appareil de separation d'un melange gazeux par distillation cryogenique - Google Patents

Procede et appareil de separation d'un melange gazeux par distillation cryogenique Download PDF

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Publication number
WO2008084167A3
WO2008084167A3 PCT/FR2007/052552 FR2007052552W WO2008084167A3 WO 2008084167 A3 WO2008084167 A3 WO 2008084167A3 FR 2007052552 W FR2007052552 W FR 2007052552W WO 2008084167 A3 WO2008084167 A3 WO 2008084167A3
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WIPO (PCT)
Prior art keywords
gas mixture
capacity
separating
cryogenic distillation
liquid
Prior art date
Application number
PCT/FR2007/052552
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English (en)
Other versions
WO2008084167A2 (fr
Inventor
Bihan Herve Le
Jean-Marc Peyron
Original Assignee
Air Liquide
Bihan Herve Le
Jean-Marc Peyron
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide, Bihan Herve Le, Jean-Marc Peyron filed Critical Air Liquide
Priority to EP07871966.3A priority Critical patent/EP2104825B1/fr
Priority to US12/520,112 priority patent/US8713964B2/en
Priority to CN2007800474576A priority patent/CN101595356B/zh
Publication of WO2008084167A2 publication Critical patent/WO2008084167A2/fr
Publication of WO2008084167A3 publication Critical patent/WO2008084167A3/fr
Priority to US14/200,049 priority patent/US9546815B2/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812Different modes, i.e. "runs" of operation
    • F25J3/04836Variable air feed, i.e. "load" or product demand during specified periods, e.g. during periods with high respectively low power costs
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
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    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
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    • F25J3/0409Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
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    • F25J3/04181Regenerating the adsorbents
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    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04642Recovering noble gases from air
    • F25J3/04648Recovering noble gases from air argon
    • F25J3/04654Producing crude argon in a crude argon column
    • F25J3/04666Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system
    • F25J3/04672Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04642Recovering noble gases from air
    • F25J3/04648Recovering noble gases from air argon
    • F25J3/04654Producing crude argon in a crude argon column
    • F25J3/04666Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system
    • F25J3/04672Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser
    • F25J3/04678Producing crude argon in a crude argon column as a parallel working rectification column of the low pressure column in a dual pressure main column system having a top condenser cooled by oxygen enriched liquid from high pressure column bottoms
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04775Air purification and pre-cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812Different modes, i.e. "runs" of operation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763Start-up or control of the process; Details of the apparatus used
    • F25J3/04769Operation, control and regulation of the process; Instrumentation within the process
    • F25J3/04812Different modes, i.e. "runs" of operation
    • F25J3/0483Rapid load change of the air fractionation unit
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/60Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • F25J2205/66Regenerating the adsorption vessel, e.g. kind of reactivation gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/60Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • F25J2205/66Regenerating the adsorption vessel, e.g. kind of reactivation gas
    • F25J2205/72Pressurising or depressurising the adsorption vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00Processes or apparatus involving steps for recycling of process streams
    • F25J2245/40Processes or apparatus involving steps for recycling of process streams the recycled stream being air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/30External or auxiliary boiler-condenser in general, e.g. without a specified fluid or one fluid is not a primary air component or an intermediate fluid
    • F25J2250/40One fluid being air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00Control of the process or apparatus
    • F25J2280/02Control in general, load changes, different modes ("runs"), measurements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/62Details of storing a fluid in a tank

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

Un appareil de distillation cryogénique d un mélange gazeux (1) comprend un appareil d'épuration (A) pour épurer le mélange gazeux dans un système à plusieurs bouteilles d'adsorbant, un système de colonnes (MP,LP,AR), une capacité (15), des moyens pour envoyer un liquide cryogénique (19,V19,29,V29) à la capacité, des moyens pour envoyer du liquide vaporisé (2,V2) de la capacité à une colonne (MP) du système, un vaporiseur (R2) dans la capacité pour vaporiser le liquide contenu, des moyens pour envoyer un gaz calorigène (4) au vaporiseur et des moyens pour soutirer du liquide (3) de la capacité.
PCT/FR2007/052552 2006-12-22 2007-12-18 Procede et appareil de separation d'un melange gazeux par distillation cryogenique WO2008084167A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP07871966.3A EP2104825B1 (fr) 2006-12-22 2007-12-18 Procede et appareil de separation d'un melange gazeux par distillation cryogenique
US12/520,112 US8713964B2 (en) 2006-12-22 2007-12-18 Method and device for separating a gas mixture by cryogenic distillation
CN2007800474576A CN101595356B (zh) 2006-12-22 2007-12-18 通过低温蒸馏分离气体混合物的方法和装置
US14/200,049 US9546815B2 (en) 2006-12-22 2014-03-07 Method and device for separating a gas mixture by cryogenic distillation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0655924A FR2910604B1 (fr) 2006-12-22 2006-12-22 Procede et appareil de separation d'un melange gazeux par distillation cryogenique
FR0655924 2006-12-22

Related Child Applications (2)

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US12/520,112 A-371-Of-International US8713964B2 (en) 2006-12-22 2007-12-18 Method and device for separating a gas mixture by cryogenic distillation
US14/200,049 Division US9546815B2 (en) 2006-12-22 2014-03-07 Method and device for separating a gas mixture by cryogenic distillation

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WO2008084167A2 WO2008084167A2 (fr) 2008-07-17
WO2008084167A3 true WO2008084167A3 (fr) 2009-05-22

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US (2) US8713964B2 (fr)
EP (1) EP2104825B1 (fr)
CN (1) CN101595356B (fr)
FR (1) FR2910604B1 (fr)
WO (1) WO2008084167A2 (fr)

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Publication number Priority date Publication date Assignee Title
DE102009003350C5 (de) * 2009-01-14 2017-02-09 Reicat Gmbh Verfahren und Vorrichtung zur Abtrennung von Argon aus einem Gasgemisch
FR2973486B1 (fr) * 2011-03-31 2013-05-03 Air Liquide Procede de separation d'air par distillation cryogenique
US11097221B2 (en) 2018-10-05 2021-08-24 8 Rivers Capital, Llc Direct gas capture systems and methods of use thereof
US11285437B2 (en) 2019-05-03 2022-03-29 8 Rivers Capital, Llc Systems and methods for carbon capture
EP4022223A1 (fr) 2019-08-26 2022-07-06 8 Rivers Capital, LLC Réglage de flamme dans un procédé de combustion oxycombustible

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US5406800A (en) * 1994-05-27 1995-04-18 Praxair Technology, Inc. Cryogenic rectification system capacity control method
US6073463A (en) * 1998-10-09 2000-06-13 Air Products And Chemicals, Inc. Operation of a cryogenic air separation unit which intermittently uses air feed as the repressurization gas for a two bed PSA system
US6351968B1 (en) * 1998-01-30 2002-03-05 Linde Aktiengesellschaft Method and device for evaporating liquid oxygen
US20020108377A1 (en) * 2000-12-29 2002-08-15 Alain Guillard Process for supplying air to at least one gas turbine unit and at least one air distillation unit, an installation for practicing the same
FR2849172A1 (fr) * 2002-12-19 2004-06-25 Air Liquide Procede de distillation d'air ameliore, et installation de mise en oeuvre de ce procede
FR2896860A1 (fr) * 2006-01-31 2007-08-03 Air Liquide Procede de separation d'air par distillation cryogenique et installation correspondante

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US5218825A (en) * 1991-11-15 1993-06-15 Air Products And Chemicals, Inc. Coproduction of a normal purity and ultra high purity volatile component from a multi-component stream
FR2704632B1 (fr) * 1993-04-29 1995-06-23 Air Liquide Procede et installation pour la separation de l'air.
FR2723184B1 (fr) * 1994-07-29 1996-09-06 Grenier Maurice Procede et installation de production d'oxygene gazeux sous pression a debit variable
US6357259B1 (en) * 2000-09-29 2002-03-19 The Boc Group, Inc. Air separation method to produce gaseous product
US6351971B1 (en) * 2000-12-29 2002-03-05 Praxair Technology, Inc. System and method for producing high purity argon
US6499312B1 (en) * 2001-12-04 2002-12-31 Praxair Technology, Inc. Cryogenic rectification system for producing high purity nitrogen
CN2606739Y (zh) * 2003-03-14 2004-03-17 大连理工大学 吸附精馏提纯二氧化碳装置

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Publication number Priority date Publication date Assignee Title
US5406800A (en) * 1994-05-27 1995-04-18 Praxair Technology, Inc. Cryogenic rectification system capacity control method
US6351968B1 (en) * 1998-01-30 2002-03-05 Linde Aktiengesellschaft Method and device for evaporating liquid oxygen
US6073463A (en) * 1998-10-09 2000-06-13 Air Products And Chemicals, Inc. Operation of a cryogenic air separation unit which intermittently uses air feed as the repressurization gas for a two bed PSA system
US20020108377A1 (en) * 2000-12-29 2002-08-15 Alain Guillard Process for supplying air to at least one gas turbine unit and at least one air distillation unit, an installation for practicing the same
FR2849172A1 (fr) * 2002-12-19 2004-06-25 Air Liquide Procede de distillation d'air ameliore, et installation de mise en oeuvre de ce procede
FR2896860A1 (fr) * 2006-01-31 2007-08-03 Air Liquide Procede de separation d'air par distillation cryogenique et installation correspondante

Also Published As

Publication number Publication date
CN101595356A (zh) 2009-12-02
US20100011811A1 (en) 2010-01-21
WO2008084167A2 (fr) 2008-07-17
EP2104825A2 (fr) 2009-09-30
US8713964B2 (en) 2014-05-06
CN101595356B (zh) 2012-11-28
FR2910604B1 (fr) 2012-10-26
EP2104825B1 (fr) 2018-08-15
FR2910604A1 (fr) 2008-06-27
US20140202208A1 (en) 2014-07-24
US9546815B2 (en) 2017-01-17

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