WO2008000700A2 - Graphitfreier hochtemperatur-schmierstoff - Google Patents
Graphitfreier hochtemperatur-schmierstoff Download PDFInfo
- Publication number
- WO2008000700A2 WO2008000700A2 PCT/EP2007/056260 EP2007056260W WO2008000700A2 WO 2008000700 A2 WO2008000700 A2 WO 2008000700A2 EP 2007056260 W EP2007056260 W EP 2007056260W WO 2008000700 A2 WO2008000700 A2 WO 2008000700A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mixture
- fatty acid
- temperature lubricant
- lubricant according
- pyrophosphate
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
- C10M2201/0853—Phosphorus oxides, acids or salts used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/055—Particles related characteristics
- C10N2020/06—Particles of special shape or size
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/08—Solids
Definitions
- the present invention relates to a high-temperature lubricant for the hot processing of metals.
- graphite Many lubricants for hot deformation of metals contain graphite because of its good lubricating properties.
- graphite has significant disadvantages, such. Example, the inclusion of graphite carbon in the machined metal surface, whereby the composition and the properties of the metal surface can be changed.
- graphite is undesirable for occupational hygiene reasons, because the graphite powder is easily atomized into the ambient atmosphere and represents a health hazard to nearby people by inhalation of graphite powder.
- the object of the present invention was to provide a high-temperature lubricant with good flow and flow behavior for scale dissolution on heated metal surfaces, applied in powder form allows good coverage of the metal surface and even after prolonged storage under production conditions still good trickle and Has flow properties without strong clumping and avoids the use of graphite.
- a high-temperature lubricant for the hot processing of metals consisting of a mixture of pulverulent materials, the mixture containing at least the following constituents:
- the mixture according to the invention with the components (a), (b), (c) and (d) is particularly suitable as a lubricant for the hot processing of metals. It is understood that the lubricant according to the invention may contain further constituents, as long as they do not significantly adversely affect the desired advantageous properties.
- Secondary and / or tertiary calcium phosphate compounds have surprisingly proven to be particularly suitable flow aids in a high-temperature lubricant of the type according to the invention for the hot processing of metals.
- Monocalcium phosphate is unsuitable because it leads to clumping when humid.
- the calcium phosphate compound of the high-temperature lubricant according to the invention is under Hxdroxylapatit [Ca 5 (PO 4) OH S] and tricalcium phosphate [Ca 3 (PO 4) 2] is selected, wherein Hxdroxylapatit is particularly preferred.
- the mixture of the high-temperature lubricant according to the invention also contains a fatty acid or a fatty acid salt in combination with the other constituents. It has surprisingly been found that by using a fatty acid or a fatty acid salt, the agglomeration of the fine powder can be significantly reduced and the storage stability can be improved. Without the applicant thereby being bound to a theory, it becomes assumed that the fatty acid or fatty acid salt attaches to the grains of one or more other components of the mixture and thus prevents or reduces clumping of the grains, prevents moisture from the grains and thereby the storage stability and the flow behavior of the lubricant improved.
- the fatty acid or the fatty acid salt is selected from saturated and unsaturated fatty acids having 6 to 26 carbon atoms or their salts. Particular preference is given to the fatty acid or the fatty acid salt among caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, margaric acid, stearic acid, arachic acid, behenic acid, lignoceric acid, cerotic acid, palmitoleic acid, oleic acid, elaidic acid, vaccenic acid, icosenoic acid, erucic acid, nervonic acid, Linoleic acid, linolenic acid, arachidonic acid, timnodonic acid, clupanodonic acid or salts thereof.
- the fatty acid or the fatty acid salt is stearic acid or its salt, in particular magnesium stearate.
- the fatty acid or the fatty acid salt is present at a temperature> 30 0 C as a solid.
- the high-temperature lubricant according to the invention contains as further constituent boric acid, a boric acid salt (borate) and / or a mineral containing boric acid (borate).
- boric acid H 3 BO 3
- borax Na 2 B 4 O 5 (OH) 4 SH 2 O or Na 2 B 4 O 7 I OH 2 O
- further sodium borates such as Na 2 B 4 O 7 OH 2 O, Na 2 B 4 O 7 (anhydrous), sodium metaborate [NaBO 2 4H 2 O] and boric anhydride [B 2 O 3 ].
- boric acid a boric acid salt (borate) and / or a mineral containing a boric acid (borate) improves the uniform distribution of the lubricant on the metal surface and reduces scale formation. At high metalworking temperatures, the high temperature lubricant forms a melt.
- the high-temperature lubricant according to the invention contains as further constituent condensed alkali metal phosphates, preferably condensed sodium or potassium phosphates or mixtures thereof, more preferably polyphosphates and / or pyrophosphates and / or metaphosphates or mixtures thereof.
- the constituents of the mixture have an average particle size of ⁇ 150 ⁇ m. Preference is given to an average particle size of the constituents of the mixture of ⁇ 100 ⁇ m, more preferably of ⁇ 50 ⁇ m. Due to the small mean particle sizes of the constituents of the mixture according to the invention, the flow and flow behavior of the high-temperature lubricant according to the invention compared to known lubricants is significantly improved, facilitates the spraying on surfaces as a powder and ensures better and more uniform layer formation or occupancy on the metal surface. At the same time, the combination of the constituents of the mixture according to the invention prevents or reduces clumping which has regularly occurred in the case of lubricants according to the prior art with small grain sizes and has led to considerable disadvantages.
- the constituents of the mixture of the high-temperature lubricant according to the invention have an average particle size of> 3 ⁇ m, preferably ⁇ 10 ⁇ m, particularly preferably> 15 ⁇ m. It has been found that too small average grain sizes can only be produced very costly and under relatively high costs and, on the other hand, they also increase the tendency to clumping again. An average grain size in the range of 20 to 50 microns has therefore proved to be optimal.
- the secondary or tertiary calcium phosphate compound (a) is in an amount of 0.1 to 15% by weight, preferably 0.5 to 10% by weight, more preferably 1 to 5 Wt .-% in the mixture.
- the fatty acid or fatty acid salt (b) is present in an amount of from 0.1 to 15% by weight, preferably from 1 to 10% by weight, more preferably from 3 to 7 Wt .-% in the mixture.
- boric acid, boric acid salt (borate) and / or a mineral (c) containing boric acid (c) are present in an amount of from 5 to 30% by weight, preferably from 10 to 25% by weight. %, more preferably from 15 to 20 wt .-% in the mixture.
- the high-temperature lubricant according to the invention is polyphosphate and / or pyrophosphate and / or metaphosphate (d) in an amount of 60 to 95 wt .-%, preferably from 70 to 85 wt .-%, particularly preferably from 75 to 80 wt .-% in the mixture.
- the average particle size of the mixture or constituents of the mixture of the high-temperature lubricant according to the invention is determined by means of a Cilas Model 715/920 laser granulometer from Cilas. Inc. Approximately 80 mg of sample is suspended in 2-propanol and the measurement is made one minute after preparation of the suspension according to the manufacturer's instructions.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007800240323A CN101479369B (zh) | 2006-06-28 | 2007-06-22 | 无石墨的高温润滑剂 |
SI200731628T SI2032679T1 (sl) | 2006-06-28 | 2007-06-22 | Visokotemperaturno mazivo brez grafita |
PL07765571T PL2032679T3 (pl) | 2006-06-28 | 2007-06-22 | Smar wysokotemperaturowy bez grafitu |
EP07765571.0A EP2032679B1 (de) | 2006-06-28 | 2007-06-22 | Graphitfreier hochtemperatur-schmierstoff |
ES07765571.0T ES2532847T3 (es) | 2006-06-28 | 2007-06-22 | Lubricante de altas temperaturas libre de grafito |
US12/308,440 US8940672B2 (en) | 2006-06-28 | 2007-06-22 | Graphite-free high-temperature lubricant |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006030113.7 | 2006-06-28 | ||
DE102006030113A DE102006030113B4 (de) | 2006-06-28 | 2006-06-28 | Graphitfreier Hochtemperatur-Schmierstoff |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008000700A2 true WO2008000700A2 (de) | 2008-01-03 |
WO2008000700A3 WO2008000700A3 (de) | 2008-02-28 |
Family
ID=38722664
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/056260 WO2008000700A2 (de) | 2006-06-28 | 2007-06-22 | Graphitfreier hochtemperatur-schmierstoff |
Country Status (10)
Country | Link |
---|---|
US (1) | US8940672B2 (de) |
EP (2) | EP2878661A1 (de) |
CN (1) | CN101479369B (de) |
AR (1) | AR061694A1 (de) |
DE (1) | DE102006030113B4 (de) |
ES (1) | ES2532847T3 (de) |
PL (1) | PL2032679T3 (de) |
RU (1) | RU2458111C2 (de) |
SI (1) | SI2032679T1 (de) |
WO (1) | WO2008000700A2 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014146927A1 (de) * | 2013-03-21 | 2014-09-25 | Chemische Fabrik Budenheim Kg | Zusammensetzung für den schutz vor zunder und als schmiermittel für die heissverarbeitung von metallen |
WO2018172627A1 (fr) | 2017-03-23 | 2018-09-27 | Air Liquide France Industrie | Dispositif d'injection d'un fluide cryogénique par le bas d'un mélangeur |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102559337A (zh) * | 2010-12-28 | 2012-07-11 | 张红芬 | 一种高温芯棒用润滑剂及其制备方法 |
RU2536820C1 (ru) * | 2013-09-10 | 2014-12-27 | Открытое акционерное общество "Российский научно-исследовательский институт трубной промышленности" (ОАО "РосНИТИ") | Продукт для горячей обработки металлов давлением |
US20170174614A1 (en) | 2015-12-22 | 2017-06-22 | Zogenix International Limited | Metabolism resistant fenfluramine analogs and methods of using the same |
ES2861774T3 (es) | 2015-12-22 | 2021-10-06 | Zogenix International Ltd | Composiciones de fenfluramina y procedimientos para prepararlas |
KR20190040237A (ko) | 2016-08-24 | 2019-04-17 | 조게닉스 인터내셔널 리미티드 | 5-ht2b 작용물질의 형성을 억제하기 위한 제제 및 그것의 사용 방법 |
CN106544149B (zh) * | 2016-11-08 | 2019-10-18 | 北京科技大学 | 一种基于石墨烯强化的液-固混合润滑剂及其制备方法 |
US10682317B2 (en) | 2017-09-26 | 2020-06-16 | Zogenix International Limited | Ketogenic diet compatible fenfluramine formulation |
EP3790537A1 (de) | 2018-05-11 | 2021-03-17 | Zogenix International Limited | Zusammensetzungen und verfahren zur behandlung von plötzlichem tod infolge eines krampfanfalls |
EP3806835A1 (de) | 2018-06-14 | 2021-04-21 | Zogenix International Limited | Zusammensetzungen und verfahren zur behandlung von atemdepression mit fenfluramin |
JP2023517381A (ja) * | 2020-03-16 | 2023-04-25 | ケミスケ ファブリック ブデンヘイム ケージー | 金属の熱間加工における潤滑および/またはスケール除去用組成物 |
US11612574B2 (en) | 2020-07-17 | 2023-03-28 | Zogenix International Limited | Method of treating patients infected with severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) |
CN111909762B (zh) * | 2020-08-18 | 2022-06-28 | 烟台开发区阳光工贸有限责任公司 | 一种水溶性钢管热轧用耐高温润滑剂 |
Citations (1)
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DD292678A5 (de) | 1988-12-30 | 1991-08-08 | Zi Fuer Festkoerperphysik Und Werkstofforschung,De | Ueberzug zur verminderung der reibung |
Family Cites Families (17)
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DE850051C (de) * | 1940-09-24 | 1952-09-22 | Steinkohlenbergwerk Rheinpreus | Verfahren zur Herstellung hochdruckbestaendiger konsistenter Schmierfette |
SU454246A1 (ru) | 1973-04-09 | 1974-12-25 | Ленинградский механический институт | Смазка дл гор чей обработки металлов |
SU505674A1 (ru) | 1974-02-08 | 1976-03-05 | Предприятие П/Я В-8739 | Смазка дл гор чей обработки внутренней поверхности труб |
JPS548261A (en) | 1977-06-22 | 1979-01-22 | Kao Corp | Dry type lubricant for expansion line |
WO1982002058A1 (en) | 1980-12-11 | 1982-06-24 | Cattell Harold G | Hot metal forging and stamping lubricant composition |
CH670106A5 (de) | 1984-07-23 | 1989-05-12 | Lonza Ag | |
JPS6474295A (en) * | 1987-08-21 | 1989-03-20 | Akad Wissenschaften Ddr | Lubricant and its use |
EP0334977B1 (de) * | 1988-03-28 | 1993-03-10 | ECOFORM Umformtechnik GmbH | Schmiermittel für die Umformung metallischer Werkstoffe |
US5000862A (en) * | 1989-03-31 | 1991-03-19 | Amoco Corporation | Process for protecting bearings in steel mills and other metal processing mills |
RU2017799C1 (ru) * | 1990-03-30 | 1994-08-15 | Анисимова Иза Васильевна | Смазка для горячей обработки металлов давлением |
JP3294679B2 (ja) * | 1993-08-06 | 2002-06-24 | 神鋼特殊鋼管株式会社 | 難加工性金属材料の塑性加工用潤滑剤 |
ATE243247T1 (de) * | 1996-09-17 | 2003-07-15 | Chem Fab Budenheim Kg | Graphitfreier dornstangenschmierstoff |
JP2000202508A (ja) * | 1998-11-09 | 2000-07-25 | Nippon Steel Corp | 固形潤滑剤を用いた冷間圧延方法 |
RU2148616C1 (ru) * | 1999-04-12 | 2000-05-10 | Открытое акционерное общество "Производственное объединение "Волжский трубный завод" | Смазка для горячей обработки металлов давлением |
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DE602005017420D1 (de) * | 2004-11-22 | 2009-12-10 | Sumitomo Metal Ind | Pulverschmiermittelzusammensetzung für das warmumformen und verfahren zur herstellung eines nahtlosen rohrs |
RU2296636C1 (ru) | 2005-08-03 | 2007-04-10 | Открытое акционерное общество "Российский научно-исследовательский институт трубной промышленности" (ОАО "РосНИТИ") | Способ продольной прокатки труб |
-
2006
- 2006-06-28 DE DE102006030113A patent/DE102006030113B4/de not_active Expired - Fee Related
-
2007
- 2007-06-22 CN CN2007800240323A patent/CN101479369B/zh not_active Expired - Fee Related
- 2007-06-22 US US12/308,440 patent/US8940672B2/en not_active Expired - Fee Related
- 2007-06-22 ES ES07765571.0T patent/ES2532847T3/es active Active
- 2007-06-22 WO PCT/EP2007/056260 patent/WO2008000700A2/de active Application Filing
- 2007-06-22 EP EP14198677.8A patent/EP2878661A1/de not_active Withdrawn
- 2007-06-22 EP EP07765571.0A patent/EP2032679B1/de not_active Not-in-force
- 2007-06-22 RU RU2009102453/04A patent/RU2458111C2/ru not_active IP Right Cessation
- 2007-06-22 SI SI200731628T patent/SI2032679T1/sl unknown
- 2007-06-22 PL PL07765571T patent/PL2032679T3/pl unknown
- 2007-06-25 AR ARP070102795A patent/AR061694A1/es active IP Right Grant
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DD292678A5 (de) | 1988-12-30 | 1991-08-08 | Zi Fuer Festkoerperphysik Und Werkstofforschung,De | Ueberzug zur verminderung der reibung |
Non-Patent Citations (1)
Title |
---|
See also references of EP2032679A2 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014146927A1 (de) * | 2013-03-21 | 2014-09-25 | Chemische Fabrik Budenheim Kg | Zusammensetzung für den schutz vor zunder und als schmiermittel für die heissverarbeitung von metallen |
JP2016519701A (ja) * | 2013-03-21 | 2016-07-07 | ケミスケ ファブリック ブデンヘイム ケージー | 金属熱間加工のスケール保護用および潤滑剤としての組成物 |
EA030719B1 (ru) * | 2013-03-21 | 2018-09-28 | Хемише Фабрик Буденхайм Кг | Состав для защиты от окалины и в качестве смазки при горячей обработке металлов |
US10995297B2 (en) | 2013-03-21 | 2021-05-04 | Chemische Fabrik Budenheim Kg | Composition for protection from scale and as lubricant for hot processing metals |
WO2018172627A1 (fr) | 2017-03-23 | 2018-09-27 | Air Liquide France Industrie | Dispositif d'injection d'un fluide cryogénique par le bas d'un mélangeur |
Also Published As
Publication number | Publication date |
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EP2032679A2 (de) | 2009-03-11 |
ES2532847T3 (es) | 2015-04-01 |
EP2032679B1 (de) | 2015-01-07 |
RU2009102453A (ru) | 2010-08-10 |
SI2032679T1 (sl) | 2015-04-30 |
US8940672B2 (en) | 2015-01-27 |
EP2878661A1 (de) | 2015-06-03 |
CN101479369B (zh) | 2013-05-01 |
RU2458111C2 (ru) | 2012-08-10 |
AR061694A1 (es) | 2008-09-17 |
CN101479369A (zh) | 2009-07-08 |
DE102006030113B4 (de) | 2009-02-12 |
US20100298181A1 (en) | 2010-11-25 |
DE102006030113A1 (de) | 2008-01-03 |
PL2032679T3 (pl) | 2015-06-30 |
WO2008000700A3 (de) | 2008-02-28 |
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