WO2007146863A1 - Led device with re-emitting semiconductor construction and reflector - Google Patents
Led device with re-emitting semiconductor construction and reflector Download PDFInfo
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- WO2007146863A1 WO2007146863A1 PCT/US2007/070853 US2007070853W WO2007146863A1 WO 2007146863 A1 WO2007146863 A1 WO 2007146863A1 US 2007070853 W US2007070853 W US 2007070853W WO 2007146863 A1 WO2007146863 A1 WO 2007146863A1
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- Prior art keywords
- reflector
- emitting semiconductor
- light
- semiconductor construction
- led
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Classifications
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/08—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a plurality of light emitting regions, e.g. laterally discontinuous light emitting layer or photoluminescent region integrated within the semiconductor body
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/44—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the coatings, e.g. passivation layer or anti-reflective coating
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
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- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/481—Disposition
- H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
- H01L2224/48247—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
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- H01L2924/13055—Insulated gate bipolar transistor [IGBT]
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- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
Definitions
- the present invention relates to light sources. More particularly, the present invention relates to light sources in which light emitted from a light emitting diode (LED) impinges upon and excites a re-emitting semiconductor construction to down-convert a portion of the emitted light to longer wavelengths.
- LED light emitting diode
- LEDs Light emitting diodes
- Conventional LED's contain a single pn junction.
- the pn junction may include an intermediate undoped region; this type of pn junction may also be called a pin junction.
- conventional LED's pass an electrical current much more readily in one direction, i.e., in the direction where electrons are moving from the n-region to the p-region. When a current passes in the "forward" direction through the LED, electrons from the n-region recombine with holes from the p-region, generating photons of light.
- the light emitted by a conventional LED is monochromatic in appearance; that is, it is generated in a single narrow band of wavelengths.
- the wavelength of the emitted light corresponds to the energy associated with electron-hole pair recombination. In the simplest case, that energy is approximately the band gap energy of the semiconductor in which the recombination occurs.
- LED's may additionally contain one or more quantum wells at the pn junction which capture high concentrations of both electrons and holes, thereby enhancing light-producing recombination.
- Several investigators have attempted to produce an LED device which emits white light, or light which appears white to the 3 -color perception of the human eye.
- Some investigators report the purported design or manufacture of LED' s having multiple quantum wells within the pn junction, where the multiple quantum wells are intended to emit light at different wavelengths.
- the following references may be relevant to such a technology: U.S. Pat. No. 5,851,905; U.S. Pat. No. 6,303,404; U.S. Pat. No. 6,504,171; U.S. Pat. No. 6,734,467; Damilano et al, Monolithic White Light Emitting
- the present disclosure provides a device comprising: a) an LED capable of emitting light at a first wavelength; b) a re-emitting semiconductor construction which comprises a potential well not located within a pn junction; and c) a reflector positioned to reflect light emitted from the LED onto the re-emitting semiconductor construction.
- the re-emitting semiconductor construction may additionally comprise an absorbing layer closely adjacent or immediately adjacent to a potential well. Potential wells may be quantum wells.
- the re-emitting semiconductor construction is capable of emitting light at a second wavelength and the reflector reflects light at said first wavelength and transmits light at said second wavelength.
- the reflector may be a multilayer reflector, a non-planar flexible multilayer reflector, or a reflective polarizer layer.
- the present disclosure provides a device comprising: a) an LED capable of emitting light at a first wavelength; b) a re-emitting semiconductor construction capable of emitting light at a second wavelength which comprises at least one potential well not located within a pn junction; and c) a reflector which transmits light at said first wavelength and reflects at least a portion of light at said second wavelength.
- the re-emitting semiconductor construction may additionally comprise an absorbing layer closely adjacent or immediately adjacent to a potential well. Potential wells may be quantum wells.
- the reflector may be positioned between the LED and the re-emitting semiconductor construction.
- the reflector may be a multilayer reflector or a non-planar flexible multilayer reflector.
- the present disclosure provides a device comprising: a) a semiconductor unit comprising: i) a first potential well located within a pn junction which comprises a LED capable of emitting light at a first wavelength, and ii) a second potential well not located within a pn junction which comprises a re-emitting semiconductor construction; and b) a reflector positioned to reflect light emitted from the LED onto the re-emitting semiconductor construction.
- the re-emitting semiconductor construction may additionally comprise an absorbing layer closely adjacent or immediately adjacent to a potential well.
- Potential wells may be quantum wells.
- the re-emitting semiconductor construction is capable of emitting light at a second wavelength and the reflector reflects light at said first wavelength and transmits light at said second wavelength.
- the reflector may be a multilayer reflector, a non-planar flexible multilayer reflector, or a reflective polarizer layer.
- the present invention provides a graphic display device comprising the LED device according to the present invention. In another aspect, the present invention provides an illumination device comprising the LED device according to the present invention.
- immediately adjacent means next in sequence without intervening layers
- closely adjacent means next in sequence with one or a few intervening layers
- surrounding means both before and after in sequence
- “potential well” means a layer of semiconductor in a semiconductor device which has a lower conduction band energy than surrounding layers or a higher valence band energy than surrounding layers, or both; "quantum well” means a potential well which is sufficiently thin that quantization effects raise the electron-hole pair transition energy in the well, typically having a thickness of 100 nm or less;
- Transition energy means electron-hole recombination energy
- lattice-matched means, with reference to two crystalline materials, such as an epitaxial film on a substrate, that each material taken in isolation has a lattice constant, and that these lattice constants are substantially equal, typically not more than 0.2% different from each other, more typically not more than 0.1% different from each other, and most typically not more than 0.01% different from each other;
- “pseudomorphic” means, with reference to a first crystalline layer of given thickness and a second crystalline layer, such as an epitaxial film and a substrate, that each layer taken in isolation has a lattice constant, and that these lattice constants are sufficiently similar so that the first layer, in the given thickness, can adopt the lattice spacing of the second layer in the plane of the layer substantially without misfit defects.
- Fig. 1 is a flat-band diagram of conduction and valence bands of semiconductors in a construction according to one embodiment of the present invention. Layer thickness is not represented to scale.
- Fig. 2 is a graph indicating lattice constant and band gap energy for a variety of II- VI binary compounds and alloys thereof.
- Fig. 3 is a graph representing the spectrum of light that emits from a device according to one embodiment of the present invention.
- Fig. 4 is a flat-band diagram of conduction and valence bands of semiconductors in a construction according to one embodiment of the present invention. Layer thickness is not represented to scale.
- Fig. 5 is a schematic sectional view of a device according to the present disclosure.
- Fig. 6 is a sectional view of a re-emitting semiconductor construction and reflector assembly used in the device of Fig. 4;
- FIGs. 7-9 are schematic sectional views of alternative a devices according to the present disclosure
- Fig. 10 depicts a portion of still another device according to the present disclosure
- Fig. 11 is a schematic sectional view of still another device according to the present disclosure.
- Fig. 12 is a schematic side view of another device that utilizes front surface illumination, as does the embodiment of Fig. 10;
- Fig. 13 is a schematic side view of a device that makes use of an arrangement of nonimaging concentrators;
- Fig. 14 is a close-up view of a portion of Fig. 12; and Figs. 15-19 are schematic sectional views of other embodiments of the present disclosure.
- the present invention provides a device comprising: an LED; a re-emitting semiconductor construction and a reflector positioned to reflect light emitted from the LED onto the re-emitting semiconductor construction.
- the LED is capable of emitting light at a first wavelength and the a re-emitting semiconductor construction is capable of absorbing light at that first wavelength and re-emitting light at a second wavelength.
- the a re-emitting semiconductor construction comprises a potential well not located within a pn junction.
- the potential wells of the re-emitting semiconductor construction are typically but not necessarily quantum wells.
- the device comprises a reflector which transmits light at the first wavelength and reflects at least a portion of light at the second wavelength.
- This reflector may be positioned between the LED and the re-emitting semiconductor construction.
- the LED emits photons in response to an electric current and the re-emitting semiconductor construction emits photons in response to the absorption of a portion of the photons emitted from the LED.
- the re-emitting semiconductor construction additionally comprises an absorbing layer closely or immediately adjacent to the potential well. Absorbing layers typically have a band gap energy which is less than or equal to the energy of photons emitted by the LED and greater than the transition energy of the potential wells of the re-emitting semiconductor construction. In typical operation the absorbing layers assist absorption of photons emitted from the LED.
- the re-emitting semiconductor construction additionally comprises at least one second potential well not located within a pn junction having a second transition energy not equal to the transition energy of the first potential well.
- the LED is a UV LED.
- the re-emitting semiconductor construction comprises at least one first potential well not located within a pn junction having a first transition energy corresponding to blue- wavelength light, at least one second potential well not located within a pn junction having a second transition energy corresponding to green- wavelength light, and at least one third potential well not located within a pn junction having a third transition energy corresponding to red-wavelength light.
- the LED is a visible light LED, typically a green, blue or violet LED, more typically a green or blue LED, and most typically a blue LED.
- the re-emitting semiconductor construction comprises at least one first potential well not located within a pn junction having a first transition energy corresponding to yellow- or green-wavelength light, more typically green-wavelength light, and at least one second potential well not located within a pn junction having a second transition energy corresponding to orange- or red- wavelength light, more typically red- wavelength light.
- the re-emitting semiconductor construction may comprise additional potential wells and additional absorbing layers.
- any suitable LED may be used in the practice of the present invention.
- Elements of the device according to the present invention may be composed of any suitable semiconductors, including Group IV elements such as Si or Ge (other than in light-emitting layers), III-V compounds such as InAs, AlAs, GaAs, InP, AlP, GaP, InSb, AlSb, GaSb, and alloys thereof, II-VI compounds such as ZnSe, CdSe, BeSe, MgSe, ZnTe, CdTe, BeTe, MgTe, ZnS, CdS, BeS, MgS and alloys thereof, or alloys of any of the above.
- Group IV elements such as Si or Ge (other than in light-emitting layers)
- III-V compounds such as InAs, AlAs, GaAs, InP, AlP, GaP, InSb, AlSb, GaSb, and alloys thereof
- II-VI compounds such as ZnSe, CdSe
- the semiconductors may be n-doped or p-doped by any suitable method or by inclusion of any suitable dopant.
- the LED is a III-V semiconductor device and the re-emitting semiconductor construction is a II-VI semiconductor device.
- the compositions of the various layers of a component of the device are selected in light of the following considerations.
- Each layer typically will be pseudomorphic to the substrate at the thickness given for that layer or lattice matched to the substrate. Alternately, each layer may be pseudomorphic or lattice matched to immediately adjacent layers.
- Potential well layer materials and thicknesses are typically chosen so as to provide a desired transition energy, which will correspond to the wavelength of light to be emitted from the quantum well. For example, the points labeled 460 nm, 540 nm and 630 nm in Fig.
- each quantum well layer represents Cd(Mg)ZnSe alloys having lattice constants close to that for an InP substrate (5.8687 Angstroms or 0.58687 nm) and band gap energies corresponding to wavelengths of 460nm (blue), 540nm (green) and 630nm (red).
- the potential well may be regarded as a quantum well.
- the thickness of each quantum well layer will determine the amount of quantization energy in the quantum well, which is added to the bulk band gap energy to determine the transition energy in the quantum well.
- the wavelength associated with each quantum well can be tuned by adjustment of the quantum well layer thickness.
- thicknesses for quantum well layers are between 1 nm and 100 nm, more typically between 2 nm and 35 nm.
- the quantization energy translates into a reduction in wavelength of 20 to 50 nm relative to that expected on the basis of the band gap energy alone.
- Strain in the emitting layer may also change the transition energy for potential wells and quantum wells, including the strain resulting from the imperfect match of lattice constants between pseudomorphic layers.
- any suitable emission wavelengths may be chosen, including those in the infrared, visible, and ultraviolet bands.
- the emission wavelengths are chosen so that the combined output of light emitted by the device creates the appearance of any color that can be generated by the combination of two, three or more monochromatic light sources, including white or near-white colors, pastel colors, magenta, cyan, and the like.
- the device according to the present invention emits light at an invisible infrared or ultraviolet wavelength and at a visible wavelength as an indication that the device is in operation.
- the LED emits photons of the shortest wavelength, so that photons emitted from the LED have sufficient energy to drive the potential wells in the re-emitting semiconductor construction.
- the LED is a III-V semiconductor device, such as a blue-emitting GaN-based LED, and re-emitting semiconductor construction is a II-VI semiconductor device.
- Fig. 1 is a band diagram representing conduction and valence bands of semiconductors in a re-emitting semiconductor construction according to one embodiment of the present invention. Layer thickness is not represented to scale. Table I indicates the composition of layers 1-9 in this embodiment and the band gap energy (E 2 ) for that composition. This construction may be grown on an InP substrate.
- Layer 3 represents a single potential well which is a red-emitting quantum well having a thickness of about 10 nm.
- Layer 7 represents a single potential well which is a green-emitting quantum well having a thickness of about 10 nm.
- Layers 2, 4, 6 and 8 represent absorbing layers, each having a thickness of about 1000 nm.
- Layers 1, 5 and 9 represent support layers. Support layers are typically chosen so as to be substantially transparent to light emitted from quantum wells 3 and 7 and from short- wavelength LED 20. Alternately, the device may comprise multiple red- or green-emitting potential wells or quantum wells separated by absorbing layers and/or support layers.
- Fig. 1 operates according to the following principles: Blue wavelength photons emitted by the LED and reflected upon the re-emitting semiconductor construction may be absorbed and re-emitted from the green-emitting quantum well 7 as green- wavelength photons or from the red-emitting quantum well 3 as red- wavelength photons. The absorption of a short- wavelength photon generates an electron-hole pair which may then recombine in the quantum wells, with the emission of a photon.
- the polychromatic combination of blue-, green- and red- wavelength light emitted from the device may appear white or near- white in color.
- the intensity of blue-, green- and red-wavelength light emitted from the device may be balanced in any suitable manner, including manipulation of the number of quantum wells of each type, the use of filters or reflective layers, and manipulation of the thickness and composition of absorbing layers.
- Fig. 3 represents a spectrum of light that emits from one embodiment of the device according to the present invention.
- absorbing layers 2, 4, 5 and 8 may be adapted to absorb photons emitted from the LED by selecting a band gap energy for the absorbing layers that is intermediate between the energy of photons emitted from the LED and the transition energies of quantum wells 3 and 7. Electron-hole pairs generated by absorption of photons in the absorbing layers 2, 4, 6 and 8 are typically captured by the quantum wells 3 and 7 before recombining with concomitant emission of a photon.
- Absorbing layers may optionally have a gradient in composition over all or a portion of their thickness, so as to funnel or direct electrons and/or holes toward potential wells.
- the LED and the re-emitting semiconductor construction are provided in a single semiconductor unit.
- This semiconductor unit typically contains a first potential well located within a pn junction and a second potential well not located within a pn junction.
- the potential wells are typically quantum wells.
- the unit is capable of emitting light at two wavelengths, one corresponding to the transition energy of the first potential well and a second corresponding to the transition energy of the second potential well.
- the first potential well emits photons in response to an electric current passing through the pn junction and the second potential well emits photons in response to the absorption of a portion of the photons emitted from the first potential well.
- the semiconductor unit may additionally comprise one or more absorbing layers surrounding or closely or immediately adjacent to the second potential well.
- Absorbing layers typically have a band gap energy which is less than or equal to the transition energy of the first potential well and greater than that of the second potential well. In typical operation the absorbing layers assist absorption of photons emitted from the first potential well.
- the semiconductor unit may comprise additional potential wells, located within the pn junction or located not within the pn junction, and additional absorbing layers.
- Fig. 4 is a band diagram representing conduction and valence bands of semiconductors in such a semiconductor unit according to one embodiment of the present invention. Layer thickness is not represented to scale. Table II indicates the composition of layers 1-14 in this embodiment and the band gap energy (E 2 ) for that composition.
- Layers 10, 11, 12, 13 and 14 represent a pn junction, or, more specifically, a pin junction, since intermediate undoped ("intrinsic" doping) layers 11, 12 and 13 are interposed between n-doped layer 10 and p-doped layer 14.
- Layer 12 represents a single potential well within the pn junction which is a quantum well having a thickness of about 10 nm. Alternately, the device may comprise multiple potential or quantum wells within the pn junction.
- Layers 4 and 8 represent second and third potential wells not within a pn junction, each being a quantum well having a thickness of about 10 nm. Alternately, the device may comprise additional potential or quantum wells not within the pn junction.
- the device may comprise a single potential or quantum well not within the pn junction.
- Layers 3, 5, 7 and 9 represent absorbing layers, each having a thickness of about 1000 nm.
- Electrical contacts, not shown, provide a path for supply of electrical current to the pn junction. Electrical contacts conduct electricity and typically are composed of conductive metal. The positive electrical contact is electrically connected, either directly or indirectly through intermediate structures, to layer 14. The negative electrical contact is electrically connected, either directly or indirectly through intermediate structures, to one or more of layers 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10.
- this embodiment of the present invention operates according to the following principles: When an electrical current passes from layer 14 to layer 10, blue-wavelength photons are emitted from quantum well (12) in the pn junction. Photons traveling in the direction of layer 14 may leave the device. Photons traveling in the opposite direction may be absorbed and re- emitted from the second quantum well (8) as green- wavelength photons or from the third quantum well (4) as red- wavelength photons. The absorption of a blue -wavelength photon generates an electron-hole pair which may then recombine in the second or third quantum wells, with the emission of a photon. Green- or red- wavelength photons traveling in the direction of layer 14 may leave the device.
- the polychromatic combination of blue-, green- and red- wavelength light emitted from the device may appear white or near- white in color.
- the intensity of blue-, green- and red- wavelength light emitted from the device may be balanced in any suitable manner, including manipulation of the number of potential wells of each type and the use of filters or reflective layers.
- Fig. 3 represents a spectrum of light that emits from one embodiment of the device according to the present invention.
- absorbing layers 3, 5, 7 and 9 may be especially suitable to absorb photons emitted from the first quantum well (12), since they have a band gap energy that is intermediate between the transition energy of the first quantum well (12) and those of the second and third quantum wells (8 and 4). Electron-hole pairs generated by absorption of photons in the absorbing layers 3, 5, 7 and 9 are typically captured by the second or third quantum wells 8 and 4 before recombining with concomitant emission of a photon.
- Absorbing layers may optionally be doped, typically like to surrounding layers, which in this embodiment would be n-doping. Absorbing layers may optionally have a gradient in composition over all or a portion of their thickness, so as to funnel or direct electrons and/or holes toward potential wells.
- the layers of the re-emitting semiconductor construction may be partially transparent to the light emitted from the LED.
- the layers of re-emitting semiconductor construction may block a greater portion or substantially or completely all of the light emitted from the LED, so that a greater portion or substantially or completely all of the light emitted from the device is light re-emitted from the re-emitting semiconductor construction.
- re-emitting semiconductor construction 10 may include red-, green- and blue- emitting quantum wells.
- the device according to the present invention may comprise additional layers of conducting, semiconducting or non-conducting materials.
- Electrical contact layers may be added to provide a path for supply of electrical current to the LED.
- Light filtering layers may be added to alter or correct the balance of light wavelengths in the light emitted by the adapted LED.
- the device according to the present invention generates white or near- white light by emitting light at four principal wavelengths in the blue, green, yellow and red bands. In one embodiment, the device according to the present invention generates white or near- white light by emitting light at two principal wavelengths in the blue and yellow bands.
- the device according to the present invention may comprise additional semiconductor elements comprising active or passive components such as resistors, diodes, zener diodes, capacitors, transistors, bipolar transistors, FET transistors, MOSFET transistors, insulated gate bipolar transistors, phototransistors, photodetectors, SCR' s, thyristors, triacs, voltage regulators, and other circuit elements.
- the device according to the present invention may comprise an integrated circuit.
- the device according to the present invention may comprise a display panel or an illumination panel.
- the LED and the re-emitting semiconductor construction which make up the device according to the present invention may be manufactured by any suitable method, which may include molecular beam epitaxy (MBE), chemical vapor deposition, liquid phase epitaxy and vapor phase epitaxy.
- the elements of the device according to the present invention may include a substrate. Any suitable substrate may be used in the practice of the present invention. Typical substrate materials include Si, Ge, GaAs, InP, sapphire, SiC and ZnSe. The substrate may be n-doped, p-doped, or semi-insulating, which may be achieved by any suitable method or by inclusion of any suitable dopant. Alternately, the elements of the device according to the present invention may be without a substrate.
- elements of the device according to the present invention may be formed on a substrate and then separated from the substrate.
- the elements of the device according to the present invention may be joined together by any suitable method, including the use of adhesive or welding materials, pressure, heat or combinations thereof.
- the bond created is transparent. Bonding methods may include interfacial or edge bonding.
- refractive index matching layers or interstitial spaces may be included. Any suitable reflector may be used in the device of the present invention.
- a multilayer reflector is used, which may be a non-planar flexible multilayer reflector.
- Multilayer reflectors include polymeric multilayer optical films, i.e., films having tens, hundreds, or thousands of alternating layers of at least a first and second polymer material, whose thicknesses and refractive indices are selected to achieve a desired reflectivity in a desired portion of the spectrum, such as a reflection band limited to UV wavelengths or a reflection band limited to visible wavelengths. See, for example, U.S. Patent 5,882,774 (Jonza et al.).
- the polymeric multilayer optical films can be processed so that adjacent layer pairs have matching or near-matching, or deliberately mismatched refractive indices associated with a z-axis normal to the film such that the reflectivity of each interface between adjacent layers, for p-polarized light, decreases slowly with angle of incidence, is substantially independent of angle of incidence, or increases with angle of incidence away from the normal.
- such polymeric multilayer optical films can maintain high reflectivity levels for p-polarized light even at highly oblique incidence angles, reducing the amount of p-polarized light transmitted by the reflective films compared to conventional inorganic isotropic stack reflectors.
- the polymer materials and processing conditions are selected so that, for each pair of adjacent optical layers, the difference in refractive index along the z-axis (parallel to the thickness of the film) is no more than a fraction of the refractive index difference along the x- or y- (in-plane) axes, the fraction being 0.5, 0.25, or even 0.1.
- the refractive index difference along the z-axis can be opposite in sign to the in-plane refractive index differences.
- polymeric multilayer optical films also makes available a variety of new embodiments and methods of construction due to the flexibility and formability of such films, whether or not they also have the refractive index relationships referred to above.
- polymeric multilayer optical film can be permanently deformed by embossing, thermo forming, or other known means to have a 3 -dimensional shape such as a portion of a paraboloid, a sphere, or an ellipsoid. See generally published application US 2002/0154406 (Merrill et al). See also U.S. Patent 5,540,978 (Schrenk) for additional polymeric multilayer film embodiments.
- polymeric multilayer optical films can be made in high volume roll form, and can also be laminated to other films and coated, and can be die cut or otherwise subdivided into small pieces for easy incorporation into an optical system as further explained below. Suitable methods of subdividing polymeric multilayer optical film are disclosed in pending U.S. Application Serial No. 10/268,118, filed October 10, 2002.
- the multilayer optical film preferably comprises alternating polymer layers composed of materials that resist degradation when exposed to UV light.
- a particularly preferred polymer pair is polyethylene terephthalate (PET)/co-polymethylmethacrylate (co-PMMA).
- PET polyethylene terephthalate
- co-PMMA co-polymethylmethacrylate
- the UV stability of polymeric reflectors can also be increased by the incorporation of non-UV absorbing light stabilizers such as hindered amine light stabilizers (HALS).
- HALS hindered amine light stabilizers
- the polymeric multilayer optical film can also include transparent metal or metal oxide layers. See e.g. PCT Publication WO 97/01778
- inorganic materials can be isotropic, or can be made to exhibit form birefringence as described in PCT Publication WO 01/75490 (Weber) and thus have the beneficial refractive index relationships that yield enhanced p-polarization reflectivity as described above.
- PCT Publication WO 01/75490 Weber
- the multilayer optical film it is most convenient and cost effective for the multilayer optical film to be substantially completely polymeric, free of inorganic materials.
- Figs. 5 and 6 depict one embodiment wherein re-emitting semiconductor construction 22 is may be combined with one or both of long-pass (LP) reflector 24 and short-pass (SP) reflector 26 (both are shown) to form a combined reflector-re-emitter construction 16.
- LP mirrors or filters based on scattering processes can achieve relatively constant performance as a function of incidence angle.
- LP and SP mirrors constructed from an inorganic dielectric material stack can have good spectral selectivity over a narrow range of incidence angles.
- the device 10 additionally includes LED 12 on mount 14 and may include capsule 18 with convex surface 20. Where the LED and re-emitting semiconductor construction comprise a single semiconductor unit, only long-pass (LP) reflector 24 may be needed.
- Figs. 7-9 depict alternative constructions of device 40, 50, 60 utilizing a concave- shaped multilayer optical film LP reflector 46, 56.
- Spacing LP reflector 46, 56 away from the re-emitting semiconductor construction 42, 52 and curving it to present a concave surface to the re-emitting semiconductor construction 42, 52 and LED 12 helps reduce the range of incidence angles of excitation light impinging on the LP reflector 46, 56, thereby reducing the leakage of LED light through the LP reflector 46, 56 caused by its blue-shift effect.
- the multilayer optical film is permanently deformed by embossing or other suitable process into a concave surface of suitable shape before immersion in transparent medium 18.
- the multilayer optical films, whether LP or SP, are specular reflectors within their respective reflection bands. Diffuse reflection from a multilayer optical film is typically negligible.
- device 40 includes a relatively small area re-emitting semiconductor construction layer 42 disposed on an optional SP reflector 44 composed of a polymeric multilayer optical film.
- LP reflector 46 has been embossed to acquire a concave shape and positioned next to the other components (42, 44) of the re-emitting semiconductor construction-reflector assembly.
- LED 12 and heat sink 14 are arranged to direct excitation light emitted by the LED toward the central portion of re-emitting semiconductor construction layer 42.
- the excitation light has its highest fluence at or near the center of re-emitting semiconductor construction layer 42.
- Excitation light not absorbed in its initial traversal of re-emitting semiconductor construction layer 42 passes through a region 48 between LP reflector 46 and re-emitting semiconductor construction layer 42 before being reflected by LP reflector 46 back towards the re-emitting semiconductor construction layer.
- the region 48 can be composed of transparent potting material 18, or alternatively of another polymeric material, or air (or other gas), or glass.
- LP reflector 46 is preferably shaped to maximize the amount of excitation light reflected back to the re- emitting semiconductor construction.
- Fig. 8 shows a device 50 similar to device 40, except that the size of the re- emitting semiconductor construction layer 52, SP reflector 54, and LP reflector 56 are increased.
- region 58 can be composed of potting material 18 or another polymeric material, or air (or other gas), or glass.
- Device 60 shown in Fig. 9, is similar to device 50, except the LP reflector 66 now forms an outer surface of the light source. Region 68 can be filled with potting material 18 or other transparent medium.
- the re-emitting semiconductor construction layers of Figs. 7-9 can be continuous, or patterned to limit the re-emitting semiconductor construction to where it is most effective.
- the device in the embodiments of Figs. 5 and 7-9 and other embodiments where the re-emitting semiconductor construction-reflector assembly is disposed above and spaced apart from the LED, the device can be manufactured in two halves: one containing the LED with heat sink, and the other containing the re-emitting semiconductor construction layer and multilayer reflector(s). The two halves can be made separately, and then be joined or otherwise secured together. This construction technique can help simplify manufacturing and increase overall yields.
- Fig. 10 demonstrates a concept that can be applied beneficially to the other embodiments herein: providing an air gap between the LED and the re-emitting semiconductor construction layer, and/or providing an air gap proximate to one or more elements of the re-emitting semiconductor construction-reflector assembly. Only some elements of a device are shown in the figure for simplicity of description.
- An air gap 70 is shown between LED 12 and re-emitting semiconductor construction layer 72, adjacent multilayer optical film SP reflector 74. The air gap has a minimal detrimental effect on excitation light from the LED reaching the re-emitting semiconductor construction layer because of the relatively small angles involved.
- the air gap enables total internal reflection (TIR) of light traveling at high incidence angles, such as light traveling in the SP reflector 74, the re-emitting semiconductor construction layer 72, and the LP reflector.
- TIR total internal reflection
- the efficiency of the SP reflector 74 is enhanced by allowing TIR at the lower surface of reflector 74.
- SP reflector 74 can be eliminated and the air gap can be formed directly under re-emitting semiconductor construction layer 72.
- An air gap can also be formed at the upper side of re-emitting semiconductor construction layer 72, or adjacent to the LP reflector at its upper or lower surface.
- One approach for providing the air gap involves the use of known microstructured films. Such films have a substantially flat surface opposed to a microstructured surface.
- the microstructured surface can be characterized by a single set of linear v-shaped grooves or prisms, multiple intersecting sets of v-shaped grooves that define arrays of tiny pyramids, one or more sets of narrow ridges, and so forth.
- a single set of linear v-shaped grooves or prisms multiple intersecting sets of v-shaped grooves that define arrays of tiny pyramids, one or more sets of narrow ridges, and so forth.
- the re-emitting semiconductor construction converts light of one wavelength (the excitation wavelength) to other wavelengths (the emitted wavelengths)
- heat may be produced.
- the presence of an air gap near the re-emitting semiconductor construction may significantly reduce heat transmission from the re-emitting semiconductor construction to surrounding materials.
- the reduced heat transfer can be compensated for in other ways, such as by providing a layer of glass or transparent ceramic near the re- emitting semiconductor construction layer that can remove heat laterally.
- Still another approach of improving the efficiency of devices according to the present disclosure is to configure the LED, re-emitting semiconductor construction layer, and LP reflector such that at least some of the excitation light from the LED is reflected by the LP reflector directly onto the top (viewing) surface of the re-emitting semiconductor construction layer, rather than directing all of the excitation light onto the bottom surface of the re-emitting semiconductor construction layer.
- Fig. 11 shows such a device 80.
- the heat sink 14' has been modified from above embodiments so that the LED 12 and the re- emitting semiconductor construction layer 82 can be mounted generally co-planar.
- An SP reflector 84 is shown underneath the re-emitting semiconductor construction layer, but in many cases will not be required.
- LP reflector 86 which has been embossed in the form of a concave ellipsoid or similar shape, directs UV excitation light directly from the LED onto the upper surface of re-emitting semiconductor construction layer 82, which surface faces the front of device 80.
- the LED and re-emitting semiconductor construction layer are preferably disposed at the foci of the ellipsoid.
- the visible light emitted by the re-emitting semiconductor construction layer is transmitted by LP reflector 86 and collected by the rounded front end of the device body to form the desired pattern or visible (preferably white) light.
- Directing excitation light directly at the front surface of the re-emitting semiconductor construction layer has a number of benefits.
- the brightest portion of the re-emitting semiconductor construction layer where the excitation light is the strongest — now is exposed at the front of the device rather than being obscured through the thickness of the re-emitting semiconductor construction layer.
- the re-emitting semiconductor construction layer can be made substantially thicker so that it absorbs substantially all of the UV excitation light, without concern for the thickness/brightness tradeoff referred to above.
- the re-emitting semiconductor construction can be mounted on a broadband metal mirror, including silver or enhanced aluminum. Fig.
- LED 12 shows schematically another embodiment where the LED light impinges on the front surface of the re-emitting semiconductor construction layer, but wherein some of the LED light also impinges on the back surface.
- some light emitted by LED 12 impinges on the back surface of re-emitting semiconductor construction layer 92, but some LED light also reflects off of the concave-shaped LP reflector 96 to strike the front surface of re-emitting semiconductor construction layer 92 without traversing through the re-emitting semiconductor construction.
- Visible light emitted by re-emitting semiconductor construction layer 92 then passes through the LP reflector 96 towards the viewer or object to be illuminated.
- the LED, re-emitting semiconductor construction layer, and LP reflector can all be immersed or attached to a transparent potting medium as shown in previous embodiments.
- Fig. 13 shows schematically another embodiment, wherein combinations of nonimaging concentrators are arranged to enhance the operation of the multilayer optical films.
- concentrator elements 100a, 100b, 100c are provided as shown between the LED 12, SP reflector 104, re-emitting semiconductor construction layer 102, and LP reflector 106.
- the concentrator elements have the effect of reducing the angular spread of light impinging on the multilayer reflectors, thus reducing the blue-shift of the reflection band discussed above in connection with Figs. 7-9.
- the concentrator elements may be in the form of simple conical sections with flat sidewalls, or the sidewalls can take on a more complex curved shape as is known to enhance collimation or focusing action depending on the direction of travel of the light.
- Concentrator element 100a collects a wide angular range of light emitted by the LED, which range is reduced by the time such light has traveled to the large end of concentrator element 100a, where SP reflector 104 is mounted.
- the SP reflector transmits the UV excitation light to concentrator element 100b, which concentrates such light onto re-emitting semiconductor construction layer 102 (while increasing the angular spread of the light).
- Wide angular range visible light emitted downwardly by re-emitting semiconductor construction layer 102 is converted by concentrator element 100b to a more narrow angular range at SP reflector 104, where it is reflected back up towards the re-emitting semiconductor construction layer 102.
- excitation light that leaks through re-emitting semiconductor construction layer 102 and visible light emitted upwardly by re-emitting semiconductor construction layer 102 initially has a wide angular spread, but is converted by concentrator element 100c to a smaller angular spread so that LP reflector 106 will better transmit the visible light emitted by the re-emitting semiconductor construction and reflect the excitation light back towards the re-emitting semiconductor construction layer.
- the small end of concentrator element 100a can have a cavity so as to capture at least some light emitted by the sides of the LED, as shown in Fig. 14.
- the interference reflector described herein includes reflectors that are formed of organic, inorganic or a combination of organic and inorganic materials.
- the interference reflector can be a multilayer interference reflector.
- the interference reflector can be a flexible interference reflector.
- a flexible interference reflector can be formed from polymeric, non-polymeric materials, or polymeric and non-polymeric materials. Exemplary films including a polymeric and non-polymeric material are disclosed in U.S. Patent Nos. 6,010,751 and 6,172,810 and EP 733,919A2, all incorporated by reference herein.
- the interference reflector described herein can be formed from flexible, plastic, or deformable materials and can itself be flexible, plastic or deformable.
- interference reflectors can be deflectable or curved to a radius usable with conventional LEDs, i.e., from 0.5 to 5 mm. These flexible interference reflectors can be deflected or curved and still retain its pre-de flection optical properties.
- Known self-assembled periodic structures such as cholesteric reflecting polarizers and certain block copolymers, are considered to be multilayer interference reflectors for purposes of this application.
- Cholesteric mirrors can be made using a combination of left and right handed chiral pitch elements.
- a long-pass filter that partially transmits all wavelengths of blue light can be used in combination with a thin yellow re-emitting semiconductor construction layer in order to direct some blue light from the LED back onto the re-emitting semiconductor construction layer after the first pass through the re- emitting semiconductor construction.
- a function of the multilayer optical film can be to block transmission of UV light so as to prevent degradation of subsequent elements inside or outside the LED package, including prevention of human eye damage.
- a UV absorber on the side of the UV reflector furthest away from the LED. This UV absorber can be in, on, or adjacent to the multilayer optical film.
- interference filters Although a variety of methods are known in the art for producing interference filters, an all polymer construction can offer several manufacturing and cost benefits. If high temperature polymers with high optical transmission and large index differentials are utilized in the of an interference filter, then an environmentally stable filter that is both thin and very flexible can be manufactured to meet the optical needs of short-pass (SP) and (LP) filters.
- SP short-pass
- LP long-pass
- coextruded multilayer interference filters as taught in US 6,531,230 (Weber et al.) can provide precise wavelength selection as well as large area, cost effective manufacturing.
- the use of polymer pairs having high index differentials allows the construction of very thin, highly reflective mirrors that are freestanding, i.e. have no substrate but are still easily processed.
- An all polymeric filter can be thermoformed into various 3D shapes such as e.g. hemispherical domes (as described below). However, care must be taken to control the thinning to the correct amount over the entire surface of the dome to create the desired angular performance. Filters having a simple two dimensional curvature are easier to create than 3D, compound shaped filters. In particular, any thin and flexible filter can be bent into a 2D shaped such as e.g. a part of a cylinder, in this case an all polymeric filter is not needed.
- Multilayer inorganic filters on thin polymeric substrates can be shaped in this manner, as well as can inorganic multilayers on glass substrates that are less than 200 microns in thickness.
- the latter may have to be heated to temperatures near the glass transition point to obtain a permanent shape with low stress.
- Optimum bandedges for long and short pass filters will depend on the emission spectra of both the LED and the re-emitting semiconductor construction in the system the filters are designed to operate in.
- substantially all of the LED emission passes through the filter to excite the re-emitting semiconductor construction, and substantially all of the emissions of the re-emitting semiconductor construction are reflected by the filter so they do not enter the LED or its base structure where they could be absorbed.
- the short pass defining bandedge is placed in a region between the average emission wavelength of the LED and the average emission wavelength of the re-emitting semiconductor construction.
- the filter is placed between the LED and the re-emitting semiconductor construction. If however, the filter is planar, the emissions from a typical LED will strike the filter at a variety of angles, and at some angle of incidence be reflected by the filter and fail to reach the re-emitting semiconductor construction. Unless the filter is curved to maintain a nearly constant angle of incidence, one may desire to place the design bandedge at a wavelength larger than the midpoint of the re-emitting semiconductor construction and LED emission curves to optimize the overall system performance. In particular, very little of the emission of the re-emitting semiconductor construction is directed to the filter near zero degrees angle of incidence because the included solid angle is very small.
- long pass reflective filters are placed opposite the re-emitting semiconductor construction layer from the LED in order to recycle the LED excitation light back to the re-emitting semiconductor construction in order to improve system efficiency.
- a long pass filter may be omitted if the LED emissions are in the visible spectrum and large amounts are needed to balance the re-emitting semiconductor construction color output.
- a long pass filter that partially transmits the shortwave light such as e.g. blue light, can be used to optimize the angular performance of a blue-LED/yellow-re-emitting semiconductor construction system via the spectral angle shift that would pass more blue light at higher angles than at normal incidence.
- the LP filter is curved, in order to maintain a nearly constant angle of incidence of the LED emitted light on the filter.
- the re-emitting semiconductor construction and the LED both face one side of the LP filter.
- the LP filter will not reflect the shortwave light.
- the long wave bandedge of the LP filter can be placed at as long a wavelength as possible while blocking as little of the emission of the re-emitting semiconductor construction as possible. Again, the bandedge placement can be changed to optimize the overall system efficiency.
- adjacent is defined herein to denote a relative positioning of two articles that are near one another. Adjacent items can be touching, or spaced away from each other with one or more materials disposed between the adjacent items.
- LED excitation light can be any light that an LED source can emit.
- LED excitation light can be UV, or blue light. Blue light also includes violet and indigo light.
- LEDs include spontaneous emission devices as well as devices using stimulated or super radiant emission including laser diodes and vertical cavity surface emitting laser diodes.
- Layers of re-emitting semiconductor construction described herein can be a continuous or discontinuous layer.
- the layers of re-emitting semiconductor construction material can be a uniform or non-uniform pattern.
- the layer of re-emitting semiconductor construction material can be plurality of regions having a small area.
- the plurality of regions can each be formed from a re-emitting semiconductor construction which emits visible light at one or more different wavelengths such as, for example, a region emitting red, a region emitting blue, and a region emitting green.
- the regions emitting visible light at a plurality of wavelengths can be arranged and configured in any uniform or non-uniform manner as desired.
- the layer of re-emitting semiconductor construction material can be a plurality of regions with a non-uniform density gradient along a surface or an area. The regions can have any regular or irregular shape.
- Structured re-emitting semiconductor construction layers can be configured in several ways to provide benefits in performance, as described below.
- light from shorter wavelength re-emitting semiconductor constructions can be re-absorbed by other re-emitting semiconductor constructions.
- Patterns comprising isolated lines or isolated regions of each re-emitting semiconductor construction type reduce the amount of re-absorption. This would be particularly effective in cavity type constructions where unabsorbed pump light is reflected back to the re-emitting semiconductor construction pattern.
- a first optical component comprising a re-emitting semiconductor construction/reflector assembly can be later attached to an LED base; a heat sink can optionally include a transparent heat sink to which the re-emitting semiconductor construction layer and interference filter may be attached.
- the transparent heat sink can be a layer of sapphire disposed between the re-emitting semiconductor construction layer/interference filter and the LED base.
- Most glasses have a higher thermal conductivity than polymers and can be useful in this function as well. Many other crystalline material's thermal conductivities are higher than most glasses and can be used here also.
- the sapphire layer can be contacted at the edges by a metal heat sink.
- the lifetime of an SP or LP filter is preferably greater than or equal to the lifetime of the LED in the same system.
- the degradation of a polymeric interference filter can be due to overheating which can cause material creep which changes the layer thickness values and therefore the wavelengths that the filter reflects. In the worst case, overheating can cause the polymer materials to melt, resulting in rapid flow of material and change in wavelength selection as well as inducing non-uniformities in the filter.
- Degradation of polymer materials can also be induced by short wavelength (actinic) radiation such as blue, violet or UV radiation, depending on the polymer material.
- actinic radiation such as blue, violet or UV radiation
- the rate of degradation is dependent both on the actinic light flux and on the temperature of the polymer. Both the temperature and the flux will in general, decrease with increasing distance from the LED.
- Placement of the polymer filter on a transparent heat sink as described above can also improve the lifetime of the filter.
- the flux of actinic radiation decreases as the square of the distance from the LED.
- the system of LED, re-emitting semiconductor construction, and multilayer optical film can be designed with light flux and temperature control taken into consideration.
- a reflective polarizer can be disposed adjacent the multilayer reflector and/or adjacent the re-emitting semiconductor construction material.
- the reflective polarizer allows light of a preferred polarization to be emitted, while reflecting the other polarization.
- the re-emitting semiconductor construction layer and other film components known in the art can depolarize the polarized light reflected by reflective polarizer, and either by the reflection of the re-emitting semiconductor construction layer, or re-emitting semiconductor construction layer in combination with the multilayer reflector, light can be recycled and increase the polarized light brightness of the solid state light device (LED).
- Suitable reflective polarizers include, for example, cholesteric reflective polarizers, cholesteric reflective polarizers with a 1 A wave retarder, DBEF reflective polarizer available from 3M Company or DRPF reflective polarizer also available from 3M
- the reflective polarizer preferably polarizes light over a substantial range of wavelengths and angles emitted by the re-emitting semiconductor construction, and in the case where the LED emits blue light, may reflect the LED emission wavelength range as well.
- Suitable multilayer reflector films are birefringent multilayer optical films in which the refractive indices in the thickness direction of two adjacent layers are substantially matched and have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal.
- multilayer films having high reflectivity for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers
- These polymeric multilayer reflectors include alternating layers of a first and second thermoplastic polymer.
- the alternating layers defining a local coordinate system with mutually orthogonal x- and y-axes extending parallel to the layers and with a z-axis orthogonal to the x- and y-axes, and wherein at least some of the layers are birefringent.
- the absolute value of the difference in indices of refraction between the first and second layers is ⁇ x, ⁇ y, and ⁇ z respectively, for light polarized along first, second, and third mutually orthogonal axes.
- the third axis is orthogonal to the plane of the film where ⁇ x is greater than about 0.05, and where ⁇ z is less than about 0.05.
- Fig 15 is a schematic sectional view of another embodiment of the present disclosure, device 210.
- a non-planar multilayer reflector 224 is shown adjacent a of re- emitting semiconductor construction 222, however the non-planar multilayer reflector 224 need only be positioned such that light can travel between the re-emitting semiconductor construction 222 and the multilayer reflector 224.
- the non-planar multilayer reflector 224 reflects LED excitation light excitation light such as, for example UV, or blue light and transmits visible light.
- This non-planar multilayer reflector 224 can be referred to as a long-pass (LP) reflector, as described above.
- the above arrangement can be disposed within an optically transparent material 220.
- the non-planar multilayer reflector 224 can be positioned to receive light from an LED 212, as discussed herein.
- the non-planar multilayer reflector 224 can be any useable thickness.
- the non-planar polymeric multilayer reflector 224 can be 5 to 200 micrometers thick or 10 to 100 micrometers thick.
- the non-planar multilayer reflector 224 can optionally be substantially free of inorganic materials.
- the non-planar multilayer reflector 224 can be formed of a material that resists degradation when exposed to UV, blue or violet light such, as discussed herein.
- the multilayer reflectors discussed herein can be stable under high intensity illumination for extended periods of time.
- High intensity illumination can be generally defined as a flux level from 1 to 100 Watt/cm 2 .
- Operating temperatures at the interference reflectors can be 100° C or less, or 65° or less.
- Suitable illustrative polymeric materials can include UV resistant material formed from, for example, acrylic material, PET material, PMMA material, polystyrene material, polycarbonate material, THV material available from 3M (St. Paul, MN), and combinations thereof. These materials and PEN material can be used for blue excitation light.
- the non-planar multilayer reflector 224 can have a non-uniform thickness or thickness gradient along its length, width, or both.
- the non-planar multilayer reflector 224 can have a first thickness at an inner region 223 of the non-planar multilayer reflector 224 and a second thickness at an outer region 225 of the non-planar multilayer reflector 224.
- the difference in thickness across the surface of the reflector is associated with a corresponding difference or shift in spectral reflectance, with the thinner areas being blue- shifted relative to the thicker areas.
- thickness gradients can be created. For example, thickness gradients can be formed by thermoforming, embossing, laser embossing, or extrusion, to list a few.
- the inner region 223 thickness can be greater than the outer region 225 thickness.
- Increasing the inner region 223 thickness can reduce an undesirable effect know as the "halo effect".
- the "halo effect” is a problem known in industry where the balance of blue excitation light and yellow converted light changes as a function of viewing angle of the LED.
- the inner region 223 thickness can be greater than the outer region 225 thickness so as to reduce on-axis blue transmission.
- the outer region 325 thickness can be greater than the inner region 323 thickness.
- the above arrangement can be disposed within an optically transparent material 320.
- the non-planar multilayer reflector can be positioned in any usable configuration with the LED, as described herein.
- the non-planar multilayer reflector is positioned between the re-emitting semiconductor construction and the LED (see e.g., Fig. 17).
- the re-emitting semiconductor construction is positioned between the non-planar multilayer reflector and the LED (see e.g., Figs. 15, 16).
- the non-planar multilayer reflector 224/324 can be configured to reflect UV or blue light and transmit at least a portion of the visible light spectrum such as green, yellow, or red light. In another illustrative embodiment, the non-planar multilayer reflector 224/324 can be configured to reflect UV, blue or green light and transmit at least a portion of the visible light spectrum such as yellow or red light.
- the re-emitting semiconductor construction 222/322 is capable of emitting visible light when illuminated with excitation light emitted from an LED 212/312.
- the re- emitting semiconductor construction material can be any useable thickness.
- Fig. 17 is a schematic sectional view of another embodiment of the present device 410.
- a non-planar multilayer reflector 426 is shown adjacent a re-emitting semiconductor construction 422, however the non-planar multilayer reflector 426 need only be positioned such that light can travel between the re-emitting semiconductor construction 422 and the non-planar multilayer reflector 426.
- the non-planar multilayer reflector 426 reflects visible light and transmits LED excitation light such as, for example UV, or blue light.
- This non-planar multilayer reflector 426 can be referred to as a short-pass (SP) reflector, as described above.
- SP short-pass
- the non-planar multilayer reflector 426 may include the same materials and be formed in a similar manner as the non-planar multilayer reflector 424 described above.
- the re-emitting semiconductor construction layer 422 is also described above.
- the non-planar multilayer reflector 426 can be positioned in any usable configuration with the LED 412 as described herein. In an illustrative embodiment shown as Fig. 17, the non-planar multilayer reflector 426 is positioned between the re-emitting semiconductor construction 422 and the LED 412. In another illustrative embodiment, the re-emitting semiconductor construction 422 is positioned between the non-planar multilayer reflector 426 and the LED 412.
- non-planar multilayer reflector 426 is a hemispherical concave shape facing toward the LED 412. Such a design allows light emitted by the LED 412 to strike the non-planar multilayer reflector 426 at a normal or a near normal incidence angle.
- the non-planar geometry of the multilayer reflector 426 allows substantially all short wave light to pass through the non-planar multilayer reflector 426 no matter what side or direction it emanates from the LED 412.
- Fig. 18 is a schematic sectional view of another embodiment of the present device 510.
- a first non-planar multilayer reflector 524 is shown spaced away from a re-emitting semiconductor construction 522, however the first non-planar multilayer reflector 524 need only be positioned such that light can travel between the re-emitting semiconductor construction 522 and the first non-planar multilayer reflector 524.
- the first non-planar multilayer reflector 524 reflects LED excitation light such as, for example UV, or blue light and transmits visible light.
- This first non-planar multilayer reflector 524 can be referred to as a long-pass (LP) reflector, as described above.
- LP long-pass
- a second non-planar multilayer reflector 526 is shown adjacent a re-emitting semiconductor construction material 22, however the second non-planar multilayer reflector 526 need only be positioned such that light can travel between the re-emitting semiconductor construction material 522 and the second non-planar multilayer reflector 526.
- the second non-planar multilayer reflector 526 reflects visible light and transmits LED excitation light such as, for example UV, or blue light.
- This second non-planar multilayer reflector 526 can be referred to as a short-pass (SP) reflector, as described above.
- SP short-pass
- a re-emitting semiconductor construction 522 is shown disposed between the first non-planar polymeric multilayer reflector 524 and the second non-planar polymeric multilayer reflector 526.
- the re-emitting semiconductor construction 522 is described above.
- Fig.19 is a schematic sectional view of another embodiment of the present device 610.
- a first non-planar multilayer reflector 624 is shown adjacent a re-emitting semiconductor construction material 622, however the first non-planar multilayer reflector 624 need only be positioned such that light can travel between the re-emitting semiconductor construction material 622 and the first non-planar multilayer reflector 624.
- the first non-planar multilayer reflector 624 reflects LED excitation light excitation light such as, for example UV, or blue light and transmits visible light.
- This first non-planar multilayer reflector 624 can be referred to as a long-pass (LP) reflector, as described above.
- the above arrangement can be disposed within an optically transparent material 620.
- a second non-planar multilayer reflector 626 is shown adjacent a re-emitting semiconductor construction material 622, however the second non-planar multilayer reflector 626 need only be positioned such that light can travel between the re-emitting semiconductor construction material 622 and the second non-planar multilayer reflector 626.
- the second non-planar multilayer reflector 626 reflects visible light and transmits LED excitation light such as, for example UV, or blue light.
- This second non-planar multilayer reflector 626 can be referred to as a short-pass (SP) reflector, as described above.
- SP short-pass
- a re-emitting semiconductor construction layer 622 is shown disposed between the first non-planar multilayer reflector 624 and the second non-planar multilayer reflector 626.
- the re-emitting semiconductor construction 622 is described above.
- the device according to the present invention may be a component or the critical component of a graphic display device such as a large- or small-screen video monitor, computer monitor or display, television, telephone device or telephone device display, personal digital assistant or personal digital assistant display, pager or pager display, calculator or calculator display, game or game display, toy or toy display, large or small appliance or large or small appliance display, automotive dashboard or automotive dashboard display, automotive interior or automotive interior display, marine dashboard or marine dashboard display, marine interior or marine interior display, aeronautic dashboard or aeronautic dashboard display, aeronautic interior or aeronautic interior display, traffic control device or traffic control device display, advertising display, advertising sign, or the like.
- a graphic display device such as a large- or small-screen video monitor, computer monitor or display, television, telephone device or telephone device display, personal digital assistant or personal digital assistant display, pager or pager display, calculator or calculator display, game or game display, toy or toy display, large or small appliance or large or small appliance display, automotive dashboard or automotive dashboard display, automotive interior or automotive interior display,
- the device according to the present invention may be a component or the critical component of a liquid crystal display (LCD), or like display, as a backlight to that display.
- the semiconductor device according to the present invention is specially adapted for use a backlight for a liquid crystal display by matching the colors emitted by the semiconductor device according to the present invention to the color filters of the LCD display.
- the device according to the present invention may be a component or the critical component of an illumination device such as a free-standing or built-in lighting fixture or lamp, landscape or architectural illumination fixture, hand-held or vehicle-mounted lamp, automotive headlight or taillight, automotive interior illumination fixture, automotive or non-automotive signaling device, road illumination device, traffic control signaling device, marine lamp or signaling device or interior illumination fixture, aeronautic lamp or signaling device or interior illumination fixture, large or small appliance or large or small appliance lamp, or the like; or any device or component used as a source of infrared, visible, or ultraviolet radiation.
- an illumination device such as a free-standing or built-in lighting fixture or lamp, landscape or architectural illumination fixture, hand-held or vehicle-mounted lamp, automotive headlight or taillight, automotive interior illumination fixture, automotive or non-automotive signaling device, road illumination device, traffic control signaling device, marine lamp or signaling device or interior illumination fixture, aeronautic lamp or signaling device or interior illumination fixture, large or small appliance or large or small appliance lamp, or the like; or
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Led Devices (AREA)
- Led Device Packages (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07798368.2A EP2033237A4 (en) | 2006-06-12 | 2007-06-11 | LED DEVICE WITH RE-TRANSMIT SEMICONDUCTOR CONSTRUCTION AND REFLECTOR |
JP2009515585A JP2009540617A (ja) | 2006-06-12 | 2007-06-11 | 再発光半導体構造体及び反射体を有するled装置 |
CN2007800219318A CN101467273B (zh) | 2006-06-12 | 2007-06-11 | 具有再发光半导体构造和反射器的led装置 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US80453806P | 2006-06-12 | 2006-06-12 | |
US60/804,538 | 2006-06-12 |
Publications (1)
Publication Number | Publication Date |
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WO2007146863A1 true WO2007146863A1 (en) | 2007-12-21 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/070853 WO2007146863A1 (en) | 2006-06-12 | 2007-06-11 | Led device with re-emitting semiconductor construction and reflector |
Country Status (6)
Country | Link |
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EP (1) | EP2033237A4 (ko) |
JP (1) | JP2009540617A (ko) |
KR (1) | KR20090018627A (ko) |
CN (1) | CN101467273B (ko) |
TW (1) | TW200810156A (ko) |
WO (1) | WO2007146863A1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008012316A1 (de) * | 2007-09-28 | 2009-04-02 | Osram Opto Semiconductors Gmbh | Halbleiterlichtquelle mit einer Primärstrahlungsquelle und einem Lumineszenzkonversionselement |
Families Citing this family (6)
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KR101701137B1 (ko) | 2009-04-30 | 2017-02-01 | 젤티크 애스세틱스, 인코포레이티드. | 피하 지질 과다 세포로부터 열을 제거하는 디바이스, 시스템 및 방법 |
DE102013212372A1 (de) * | 2013-06-27 | 2014-12-31 | Robert Bosch Gmbh | Optische Baueinheit |
CN105865668B (zh) * | 2015-01-20 | 2019-12-10 | 北京纳米能源与***研究所 | 压力传感成像阵列、设备及其制作方法 |
JP7242886B2 (ja) * | 2019-10-02 | 2023-03-20 | 富士フイルム株式会社 | バックライトおよび液晶表示装置 |
JP2024044397A (ja) * | 2022-09-21 | 2024-04-02 | 株式会社トプコン | 植物センサ |
JP2024044396A (ja) * | 2022-09-21 | 2024-04-02 | 株式会社トプコン | 植物センサ |
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US20040075102A1 (en) * | 2002-10-21 | 2004-04-22 | Nai-Chuan Chen | AlGaInP light emitting diode |
WO2004068552A2 (en) * | 2003-01-27 | 2004-08-12 | 3M Innovative Properties Company | Phosphor based light sources having a non-planar long pass reflector |
US7045375B1 (en) * | 2005-01-14 | 2006-05-16 | Au Optronics Corporation | White light emitting device and method of making same |
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JP3559446B2 (ja) * | 1998-03-23 | 2004-09-02 | 株式会社東芝 | 半導体発光素子および半導体発光装置 |
JP3358556B2 (ja) * | 1998-09-09 | 2002-12-24 | 日本電気株式会社 | 半導体装置及びその製造方法 |
US7136408B2 (en) * | 2004-06-14 | 2006-11-14 | Coherent, Inc. | InGaN diode-laser pumped II-VI semiconductor lasers |
US7223998B2 (en) * | 2004-09-10 | 2007-05-29 | The Regents Of The University Of California | White, single or multi-color light emitting diodes by recycling guided modes |
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2007
- 2007-06-11 CN CN2007800219318A patent/CN101467273B/zh not_active Expired - Fee Related
- 2007-06-11 TW TW096121063A patent/TW200810156A/zh unknown
- 2007-06-11 EP EP07798368.2A patent/EP2033237A4/en not_active Withdrawn
- 2007-06-11 JP JP2009515585A patent/JP2009540617A/ja active Pending
- 2007-06-11 KR KR1020087030065A patent/KR20090018627A/ko not_active Application Discontinuation
- 2007-06-11 WO PCT/US2007/070853 patent/WO2007146863A1/en active Application Filing
Patent Citations (3)
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US20040075102A1 (en) * | 2002-10-21 | 2004-04-22 | Nai-Chuan Chen | AlGaInP light emitting diode |
WO2004068552A2 (en) * | 2003-01-27 | 2004-08-12 | 3M Innovative Properties Company | Phosphor based light sources having a non-planar long pass reflector |
US7045375B1 (en) * | 2005-01-14 | 2006-05-16 | Au Optronics Corporation | White light emitting device and method of making same |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008012316A1 (de) * | 2007-09-28 | 2009-04-02 | Osram Opto Semiconductors Gmbh | Halbleiterlichtquelle mit einer Primärstrahlungsquelle und einem Lumineszenzkonversionselement |
US8564185B2 (en) | 2007-09-28 | 2013-10-22 | Osram Opto Semiconductors Gmbh | Semiconductor light source having a primary radiation source and a luminescence conversion element |
DE102008012316B4 (de) | 2007-09-28 | 2023-02-02 | OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung | Halbleiterlichtquelle mit einer Primärstrahlungsquelle und einem Lumineszenzkonversionselement |
Also Published As
Publication number | Publication date |
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EP2033237A1 (en) | 2009-03-11 |
EP2033237A4 (en) | 2013-10-02 |
CN101467273B (zh) | 2012-05-09 |
KR20090018627A (ko) | 2009-02-20 |
CN101467273A (zh) | 2009-06-24 |
TW200810156A (en) | 2008-02-16 |
JP2009540617A (ja) | 2009-11-19 |
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