WO2007049439A1 - Refrigerator - Google Patents

Refrigerator Download PDF

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Publication number
WO2007049439A1
WO2007049439A1 PCT/JP2006/319861 JP2006319861W WO2007049439A1 WO 2007049439 A1 WO2007049439 A1 WO 2007049439A1 JP 2006319861 W JP2006319861 W JP 2006319861W WO 2007049439 A1 WO2007049439 A1 WO 2007049439A1
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WO
WIPO (PCT)
Prior art keywords
sheet
decorative
transparent
layer
refrigerator
Prior art date
Application number
PCT/JP2006/319861
Other languages
French (fr)
Japanese (ja)
Inventor
Tooru Kubota
Masami Endo
Shigeo Tada
Original Assignee
Kabushiki Kaisha Toshiba
Toshiba Consumer Marketing Corporation
Toshiba Ha Products Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kabushiki Kaisha Toshiba, Toshiba Consumer Marketing Corporation, Toshiba Ha Products Co., Ltd. filed Critical Kabushiki Kaisha Toshiba
Publication of WO2007049439A1 publication Critical patent/WO2007049439A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/02Doors; Covers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2400/00General features of, or devices for refrigerators, cold rooms, ice-boxes, or for cooling or freezing apparatus not covered by any other subclass
    • F25D2400/18Aesthetic features

Definitions

  • the present invention relates to a refrigerator, and more particularly to a refrigerator having an improved design configuration such as a door that forms a main body outline.
  • Patent Document 1 Japanese Patent Laid-Open No. 2004-232887
  • Patent Document 2 JP 2004-278891 A
  • the present invention has been made in consideration of the above points, and various patterns, characters, and patterns can be decorated on an outer forming member such as a door, and a high-quality design structure is easy.
  • the purpose is to provide a refrigerator that can be obtained in the same way.
  • a refrigerator according to the present invention forms a box-shaped outer plate by thermoforming a laminated sheet obtained by bonding a decorative sheet to one surface of a transparent sheet made of thermoplastic resin.
  • the outer shell is formed by foaming and filling a hard heat insulating material made of polyurethane on the decorative sheet side of the outer plate.
  • patterns and characters can be freely applied to the outer shell surface via a transparent resin, so that the width of the design norelation can be greatly widened to easily obtain a high-quality refrigerator. be able to.
  • the refrigerator (1) whose front view is shown in Fig. 1, is divided into a number of storage rooms, such as a refrigerated room, a vegetable room, a freezer room and an ice making room, and the opening of each room is opened and closed.
  • a free-range open-type refrigerator compartment door (2) a drawer-type ice making door (3), a vegetable compartment door (4), and a freezer compartment door (5).
  • FIG. 2 is a cross-sectional view taken along line A—A of the refrigerator compartment door (2), one of which is a box-shaped outer plate (6) that forms the outer shell of the door, and a seal
  • the inner plate (7) on which the gasket mounting portion (8) is formed is joined, and the space on the inner surface thereof is filled with the foam insulation (9) and integrated together.
  • the outer plate (6) is provided with an outer surface sheet (10) having a transparent physical strength on the outer surface, and decorative printing printed on the film sheet (12) located in the lower layer portion.
  • the layer (11) is integrally formed so that it can be seen.
  • the outer sheet (10) is formed of a transparent acrylic resin sheet having a thickness of 1 to 3 mm
  • the film sheet (12) is It is made of a 200 ⁇ m thick polypropylene resin film, and its surface is decorated with decorative prints (11) such as patterns, patterns, or letters, and is bonded to the outer sheet (10) via a binder (13). And integrated.
  • An opaque layer (14) is provided on the film sheet (12) side of the decorative printed layer (11), and a foam insulation (9) is provided on the lower surface of the film sheet (12).
  • a binder layer (15) is provided, and the outer plate (6) is formed by vacuum forming a sheet that is formed by integrating these layers! /
  • the outer sheet (10) is acrylic resin in the above description, but is not limited to this, and any thermoplastic resin having transparency may be used.
  • polycarbonate (PC) resin, polystyrene (PS) resin, polypropylene (PP) resin may be AS resin, ABS resin, etc.
  • PC polycarbonate
  • PS polystyrene
  • PP polypropylene
  • PLA polylactic acid
  • PLA polylactic acid
  • the transparency is further improved, and the PLA resin, which is generally thermally deformed at about 60 ° C, also has a high heat resistance temperature, The effect of increasing the rigidity and facilitating vacuum forming is obtained.
  • the use of PLA resin can suppress the production amount of carbon dioxide in the natural world, so that a product with less environmental pollution can be provided.
  • the outer surface sheet (10) may be configured by using a sheet in which a transparent acrylic resin is provided on the front side and a transparent ABS resin is provided on the back side, and these are bonded together.
  • a transparent acrylic resin is provided on the front side
  • a transparent ABS resin is provided on the back side
  • This binder (13) is a known adhesive which is transparent and is applied by screen printing. It is a thermoplastic urethane resin, a vinyl acetate resin, a salt vinyl bisvinyl acetate copolymer, a thermoplastic resin. As long as it has a function of melting the heat-resistant polyester resin, polyamide resin, ionomer resin, chlorinated polyolefin, etc., and bonding the resin sheets together.
  • the coating method of the noinder (13) is carried out by generating ink containing the above-mentioned resin and using a printing method such as screen printing or gravure printing or a coating method such as a roll coater. May be.
  • the binder (13) may be a heat-curing type resin.
  • the ability to apply a two-component curing type binder by printing has the advantage of being easy to apply and dissolve in the solvent due to its low molecular weight, and then heat drying to cure the binder resin. By doing so, the melting point of the binder itself is increased, and the binder layer is not remelted by heat during vacuum forming or foaming of the urethane foam heat insulating material, thereby eliminating the problem of peeling. .
  • the design can be applied to landscape photos and paintings with only wood, stone, and tile, or gravure printing such as geometric patterns, screen printing, offset printing, and inkjet printing. Also, application by a roll coater is possible.
  • the opaque layer (14) is provided so that the foamed heat insulating material (9) below the decorative printed layer (11) is not visible from the surface side, and the upper decorative layer (11) In order to improve the color development and color reproducibility, it is usually a white and opaque printed layer.
  • the film sheet (12) is not limited to polypropylene (PP) as described above as long as it has flexibility to be freely deformed by vacuum forming, and is a resin such as PET or PC. It may be. In this example, a force of about 0.5 to 2 mm thick using a film sheet having a thickness of about 200 m may be used. Even in this case, decorative printing (11 ) Is applied to the outer sheet (10) and vacuum formed.
  • PP polypropylene
  • PC polypropylene
  • a polyolefin resin such as PP having a very low water permeability is interposed between the layer of the hard urethane foam heat insulating material (9) and the transparent outer sheet (10). Water or detergent entering from the outside through the outer sheet (10) is blocked by the film sheet (12). Therefore, it is possible to suppress deterioration and cracking caused by intruding into the heat insulating material (9) and hydrolyzing the urethane foam, and it is possible to prevent a decrease in heat insulating performance.
  • the film sheet (12) a polyolefin resin, it is possible to reduce the solvent cracks on the transparent outer sheet (10) due to the organic gas generated from the inside of the polyurethane foam. Can be improved.
  • the binder layer (15) provided between the film sheet (12) and the urethane foam heat insulating material (9) is made of thermoplastic urethane resin, vinyl acetate resin, salt, as with the above-mentioned noinder (13).
  • This binder layer (15) can be used for foam insulation (9) Is firmly adhered to the film sheet (12), so that the shape of the structure can be maintained as a heat insulating box, for example, a heat insulating door (2), and a large rigidity can be maintained.
  • the binder layer (15) in this example is roughened by a surface treatment with a flame applied to the surface of the film sheet (12), or is opaque on the side of the foam insulation (9) as described later. It can be made unnecessary by adopting a structure in which the adhesion with the urethane foam is improved by arranging the layer (14).
  • the manufacturing process which does not need to be dried can be simplified.
  • the opaque layer (14) may be formed not only by printing but also by roller coating, and may be applied to the foam insulation (9 ') side surface of the film sheet ().
  • the film sheet (12 ') is generally a polypropylene film that is difficult to adhere to the hard urethane foam that is a heat insulating material, the adhesiveness to the urethane foam is determined by the resin component contained in the opaque layer.
  • a single layer of binder (15 mm) is formed between the foam insulation (9 mm) and the heat insulation material (9 ′). ), There is no need to provide this, so that the cost can be reduced.
  • a layer (14) of white opaque ink is provided on the upper surface of a film sheet (12) made of PP resin. As described above, this may be screen printing or roller coating.
  • decorative printing (11) is performed on the upper surface of the opaque layer (14) by gravure printing or the like. It is also possible to print multiple times to achieve multiple colors.
  • a transparent binder (13) is applied to the surface of the decorative print layer.
  • the surface is temporarily covered with a protective film (16) to prevent dust adhesion and scratches until the next process, and then (e) as urethane foam when the door is formed.
  • a decorative sheet (17) is formed by laminating a binder layer (15) having basically the same specifications as the binder (13).
  • the protective film (16) of the binder (13) in the decorative sheet (17) is removed, and an outer sheet made of acrylic resin on the upper surface thereof (10) is thermocompression-bonded by a press machine (19) having a heating device (18). Pressing pressure at this time is about lOkgZcm 2, the temperature is brought into close contact is set to 0.99 ° C, pressing time 30 sec. As a result, the binder (13) is melted, and the decorative sheet (17) and the outer sheet (10) are adhered in a sealed state to form the laminated sheet (20) shown in (g).
  • the laminated sheet (20) softened by preheating is placed in a mold (21) schematically shown in (h), and the vacuum pump (22) is used as shown in (i).
  • the vacuum pump (22) is used as shown in (i).
  • the laminated sheet (20) is vacuum formed into a predetermined shape to obtain the outer plate (6) of the refrigerator door (2).
  • the method of forming the laminated sheet (20) into the outer plate (6) is not limited to the above-described vacuum forming method, and may be performed by pressure forming or press forming, which is a method for forming a sheet-shaped object. It can be obtained in the same way.
  • the outer plate (6) formed in a predetermined shape as described above is coupled to the inner plate (7) forming the inner surface side of the refrigerator compartment as shown in FIG.
  • the binder layer (15) on the inner plate (7) and outer plate (6) by injecting a raw solution of rigid urethane foam heat insulating material (9) into the interior space and foaming it, filling and solidifying it, Alternatively, it constitutes a heat insulating door (2) having a heat insulating material layer (9) firmly bonded to an opaque printed layer (14 ").
  • the force described as an example of the refrigerator compartment door of the refrigerator is not limited to this, and can be applied to other doors such as a vegetable room and an ice making room. It can be applied to the table plate and the outer plate at the top of the main body to improve the design effect and form a high-quality outer surface.
  • the present invention can be used for a refrigerator having an improved design structure of the outer shell such as a door.
  • FIG. 1 is an external front view of a refrigerator showing an embodiment of the present invention.
  • FIG. 2 is a cross-sectional view taken along line AA of the refrigerator compartment door of FIG.
  • FIG. 3 is a cross-sectional view showing a laminated state of the door outer plates in FIG.
  • FIG. 4 is a cross-sectional view of another embodiment of the door skin shown in FIG.
  • FIG. 5 is a cross-sectional view of still another embodiment of the door skin shown in FIG.
  • FIG. 6 is a process diagram showing a manufacturing process of the door outer plate shown in FIG. 2.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Refrigerator Housings (AREA)
  • Laminated Bodies (AREA)

Abstract

A refrigerator in which a shell-forming member such as a door can be decorated with various patterns, characters, or designs and to which a fashionable design constitution can be easily imparted. It is characterized by having a main-body shell formed by thermally molding a layered sheet (20) comprising a transparent sheet (10) made of a thermoplastic resin and a decorative sheet (17) bonded to one side thereof to form a box-form outer plate (6) and filling a space on the decorative-sheet side of the outer plate by packing a rigid heat insulator (9) made of a polyurethane into the space and foaming it.

Description

明 細 書  Specification
冷蔵庫  Refrigerator
技術分野  Technical field
[0001] 本発明は、冷蔵庫に係り、特に本体外郭を形成する扉などの意匠構成を向上させ た冷蔵庫に関する。  TECHNICAL FIELD [0001] The present invention relates to a refrigerator, and more particularly to a refrigerator having an improved design configuration such as a door that forms a main body outline.
背景技術  Background art
[0002] 一般に、家庭用冷蔵庫の開口部を開閉自在に閉塞する扉は、冷蔵庫表面に設け るものであり意匠的に重要な部品であることから、外観デザインを考慮した美麗なも のであることが条件となる。そして近年では、アクリル榭脂などの透明樹脂からなる射 出成形体の内側に凹凸成形や塗装による意匠模様を施し、これにキャップや内板を 組み込み、断熱材を充填して形成した冷蔵庫扉が商品化されている (例えば、特許 文献 1参照)。また、透明榭脂製のパネルで外表面を覆われる鋼板製の外箱と前記 パネルとの間に色彩、模様の榭脂フィルムを配置する構成が提案されている (特許文 献 2参照)。  [0002] In general, a door that opens and closes an opening of a household refrigerator is provided on the surface of the refrigerator and is an important part of the design. Therefore, the door is beautiful considering the external design. Is a condition. In recent years, there has been a refrigerator door formed by embossing a design pattern by concavo-convex molding or painting on the inside of a projection molded body made of a transparent resin such as acrylic resin, and incorporating a cap or inner plate into it and filling it with a heat insulating material. Commercialized (see, for example, Patent Document 1). In addition, a configuration has been proposed in which a colored or patterned resin film is disposed between a steel sheet outer box whose outer surface is covered with a transparent resin panel and the panel (see Patent Document 2).
特許文献 1:特開 2004— 232887号公報  Patent Document 1: Japanese Patent Laid-Open No. 2004-232887
特許文献 2 :特開 2004— 278891号公報  Patent Document 2: JP 2004-278891 A
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0003] し力しながら、上記による透明アクリル榭脂などの射出成形体の内側に凹凸成形の ほか塗装などによって着色する構成では、微細な模様とすることはできないことから 意匠の自由度は少なぐまた、多色模様とするためには、マスキングを施すなどの煩 雑さの面力 実質的に実施は困難であり、従来方法では充分な高級感を持った意匠 構成を得ることはできなカゝつた。 [0003] However, in the configuration in which the inside of the injection-molded product such as transparent acrylic resin is colored by concavo-convex molding or by painting or the like, a fine pattern cannot be formed, so the degree of freedom of design is small. In addition, in order to obtain a multicolor pattern, it is practically difficult to carry out masking and other complexities, and it is impossible to obtain a design structure with a sufficiently high-class feeling with the conventional method. Katsutsu.
[0004] 本発明は上記の点を考慮してなされたもので、扉などの外郭形成部材に様々なパ ターンや文字、模様を加飾することができ、高級感を持った意匠構成が容易に得ら れる冷蔵庫を提供することを目的とする。 [0004] The present invention has been made in consideration of the above points, and various patterns, characters, and patterns can be decorated on an outer forming member such as a door, and a high-quality design structure is easy. The purpose is to provide a refrigerator that can be obtained in the same way.
課題を解決するための手段 [0005] 上記課題を解決するため本発明による冷蔵庫は、熱可塑性榭脂からなる透明シー トの一面に加飾シートを接着した積層シートを加熱成形して箱状の外板を形成し、前 記外板の加飾シート側にポリウレタンからなる硬質断熱材を発泡充填して本体外郭 を形成したことを特徴とするものである。 Means for solving the problem [0005] In order to solve the above problems, a refrigerator according to the present invention forms a box-shaped outer plate by thermoforming a laminated sheet obtained by bonding a decorative sheet to one surface of a transparent sheet made of thermoplastic resin. The outer shell is formed by foaming and filling a hard heat insulating material made of polyurethane on the decorative sheet side of the outer plate.
発明の効果  The invention's effect
[0006] 本発明によれば、外郭表面に透明榭脂を介して模様や文字を自由に施すことがで きるので、意匠ノリエーシヨンの幅を格段に広げて高級感を持った冷蔵庫を容易に 得ることができる。  [0006] According to the present invention, patterns and characters can be freely applied to the outer shell surface via a transparent resin, so that the width of the design norelation can be greatly widened to easily obtain a high-quality refrigerator. be able to.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0007] 以下、図面に基づき本発明の 1実施形態について説明する。図 1にその外観正面 図を示す冷蔵庫(1)は、断熱された貯蔵庫内を冷蔵室や野菜室、冷凍室や製氷室 など多数の貯蔵室に区分し、それぞれの室の開口部には開閉自在に枢支した観音 開き方式の冷蔵室扉 (2)や引出し式の製氷室扉 (3)や野菜室扉 (4)、冷凍室扉 (5) などを設けている。 Hereinafter, an embodiment of the present invention will be described with reference to the drawings. The refrigerator (1), whose front view is shown in Fig. 1, is divided into a number of storage rooms, such as a refrigerated room, a vegetable room, a freezer room and an ice making room, and the opening of each room is opened and closed. There are a free-range open-type refrigerator compartment door (2), a drawer-type ice making door (3), a vegetable compartment door (4), and a freezer compartment door (5).
[0008] 図 2は、その中のひとつである冷蔵室扉(2)の A— A線に沿った横断面図であり、 扉の外郭を形成する箱状の外板 (6)と、シールガスケットの装着部(8)を形成した内 板 (7)とを結合し、それらの内面の空間部に発泡断熱材 (9)を充填して一体ィ匕したも のである。  [0008] Fig. 2 is a cross-sectional view taken along line A—A of the refrigerator compartment door (2), one of which is a box-shaped outer plate (6) that forms the outer shell of the door, and a seal The inner plate (7) on which the gasket mounting portion (8) is formed is joined, and the space on the inner surface thereof is filled with the foam insulation (9) and integrated together.
[0009] しかして、前記外板 (6)は、その外表面に透明体力もなる外面シート(10)を配して おり、下層部に位置するフィルムシート(12)に印刷された加飾印刷層(11)が視認で きるように一体に形成されて 、る。  [0009] Therefore, the outer plate (6) is provided with an outer surface sheet (10) having a transparent physical strength on the outer surface, and decorative printing printed on the film sheet (12) located in the lower layer portion. The layer (11) is integrally formed so that it can be seen.
[0010] 図 3に外板 (6)部分の詳細断面を示すように、前記外面シート(10)は、 l〜3mm厚 の透明アクリル榭脂シートで形成されており、フィルムシート(12)は 200 μ m厚のポリ プロピレン榭脂フィルムで形成され、その表面に絵柄や模様、あるいは文字などの加 飾印刷(11)を施し、これをバインダー(13)を介して外面シート(10)に接着して一体 化している。  [0010] As shown in FIG. 3 which shows a detailed cross section of the outer plate (6), the outer sheet (10) is formed of a transparent acrylic resin sheet having a thickness of 1 to 3 mm, and the film sheet (12) is It is made of a 200 μm thick polypropylene resin film, and its surface is decorated with decorative prints (11) such as patterns, patterns, or letters, and is bonded to the outer sheet (10) via a binder (13). And integrated.
[0011] 前記加飾印刷された層 (11)のフィルムシート(12)側には、不透明層(14)を設けて おり、さらに、フィルムシート(12)の下面には発泡断熱材(9)との密着性を大きくする ためにバインダー層(15)を設け、これらを一体化して積層体としたシートを真空成形 することで外板 (6)を形成して!/、る。 [0011] An opaque layer (14) is provided on the film sheet (12) side of the decorative printed layer (11), and a foam insulation (9) is provided on the lower surface of the film sheet (12). Increase adhesion with For this purpose, a binder layer (15) is provided, and the outer plate (6) is formed by vacuum forming a sheet that is formed by integrating these layers! /
[0012] 外面シート(10)は、前記説明においては、アクリル榭脂としたが、これに限らず透明 性を有する熱可塑性榭脂であればよぐ例えば、ポリカーボネート (PC)榭脂、ポリス チレン (PS)榭脂、ポリプロピレン (PP)榭脂ゃ AS榭脂、 ABS榭脂などでもよい。この 他、ポリ乳酸 (PLA)ベースの榭脂を用いることも可能であり、特に、 PLA榭脂とアタリ ル榭脂とを混合 (ァロイ)した榭脂シートを用いてもょ 、。  [0012] The outer sheet (10) is acrylic resin in the above description, but is not limited to this, and any thermoplastic resin having transparency may be used. For example, polycarbonate (PC) resin, polystyrene (PS) resin, polypropylene (PP) resin may be AS resin, ABS resin, etc. In addition, it is also possible to use polylactic acid (PLA) -based resin, and in particular, use a resin sheet in which PLA resin and talyl resin are mixed (alloyed).
[0013] このように、アクリルとのァロイ榭脂を用いることで、より透明度が向上し、また、一般 的に 60°C程度で熱変形する PLA榭脂でも耐熱温度が高くなり、加熱時の剛性が増 大して真空成形し易くなる効果が得られる。そしてまた、 PLA榭脂を用いることで、自 然界における炭酸ガスの生成量を抑制することができるため、環境汚染の少ない製 品を提供することができる。  [0013] Thus, by using an alloy resin with acrylic, the transparency is further improved, and the PLA resin, which is generally thermally deformed at about 60 ° C, also has a high heat resistance temperature, The effect of increasing the rigidity and facilitating vacuum forming is obtained. In addition, the use of PLA resin can suppress the production amount of carbon dioxide in the natural world, so that a product with less environmental pollution can be provided.
[0014] また、外面シート (10)については、上記の他、表面側に透明アクリル榭脂、裏面側 に透明 ABS榭脂を設けてこれらを張り合わせたシートを用いてもよぐこのように構成 することで、耐衝撃性にやや劣るアクリル榭脂シートと、表面性がやや劣り、屈折率の 関係から高級感にやや欠ける ABS榭脂シートのそれぞれの欠点を補い、双方の長 所を併せ持つシートを得ることができる。また、シート表面にハードコート処理を施せ ば、傷つきを抑制することができ、高級感を長期に亙って保持することができる。さら に裏面のフィルムシート(12)側にあら力じめシボカ卩ェのような凹凸成形による装飾処 理を施しておけば加飾による意匠効果を一層向上させることができる。  [0014] In addition to the above, the outer surface sheet (10) may be configured by using a sheet in which a transparent acrylic resin is provided on the front side and a transparent ABS resin is provided on the back side, and these are bonded together. This makes it possible to compensate for the disadvantages of the acrylic resin sheet, which is slightly inferior in impact resistance, and the ABS resin sheet, which is slightly inferior in surface quality and somewhat lacking in high-class feeling due to the refractive index. Can be obtained. Further, if the hard coat treatment is applied to the sheet surface, scratching can be suppressed and a high-class feeling can be maintained for a long time. Furthermore, if the surface of the film sheet (12) on the back side is reinforced and decorated by uneven molding such as shibokae, the design effect by decoration can be further improved.
[0015] 前記外面シート(10)の下層に位置するフィルムシート(12)の表面には、外面シート  [0015] On the surface of the film sheet (12) positioned below the outer sheet (10), there is an outer sheet.
(10)とフィルムシート(12)とを接着するノ インダー (13)の層を設けて!/、る。このバイン ダー(13)は透明性を有しスクリーン印刷によって塗布される公知の接着剤であり、熱 可塑性ウレタン榭脂ゃ酢酸ビニル榭脂、塩ィ匕ビ二ルー酢酸ビニル共重合体、熱可塑 性ポリエステル榭脂、ポリアミド榭脂、アイオノマー榭脂、塩素化ポリオレフインなどの 加熱によって融解し、榭脂シート同士を接着させる機能を有していればよいものであ る。なお、ノインダー(13)の塗布方式は、前記榭脂を含むインクを生成して、スクリー ン印刷やグラビア印刷などの印刷方法やロールコーターなどの塗装方法でおこなつ てもよい。 Provide a layer of nodder (13) to bond (10) and film sheet (12)! / This binder (13) is a known adhesive which is transparent and is applied by screen printing. It is a thermoplastic urethane resin, a vinyl acetate resin, a salt vinyl bisvinyl acetate copolymer, a thermoplastic resin. As long as it has a function of melting the heat-resistant polyester resin, polyamide resin, ionomer resin, chlorinated polyolefin, etc., and bonding the resin sheets together. In addition, the coating method of the noinder (13) is carried out by generating ink containing the above-mentioned resin and using a printing method such as screen printing or gravure printing or a coating method such as a roll coater. May be.
[0016] また、このバインダー (13)は、加熱硬化型の榭脂を用いてもよい。この場合、 2液硬 化型のバインダーを印刷によって塗布するものである力 低分子量であることから溶 剤に溶けやすぐ塗布しやすい長所があり、その後、加熱乾燥させてバインダーの榭 脂を硬化させることで、バインダー自体の融点が高くなり、真空成形時やウレタンフォ ーム断熱材の発泡時の熱によってもバインダー層が再融解することがないので、剥 がれる問題をなくすることができる。  [0016] Further, the binder (13) may be a heat-curing type resin. In this case, the ability to apply a two-component curing type binder by printing has the advantage of being easy to apply and dissolve in the solvent due to its low molecular weight, and then heat drying to cure the binder resin. By doing so, the melting point of the binder itself is increased, and the binder layer is not remelted by heat during vacuum forming or foaming of the urethane foam heat insulating material, thereby eliminating the problem of peeling. .
[0017] 前記バインダー(13)の下層に施されている加飾印刷(11)は、前述のように、フィル ムシート(12)の表面に絵柄や模様、文字など印刷して装飾効果を高めるものであり、 絵柄は木目調や石目調、タイル調だけでなぐ風景写真や絵画、あるいは幾何学模 様などのグラビア印刷やスクリーン印刷、オフセット印刷やインクジェット印刷などあら ゆる印刷技術によるものが適用でき、また、ロールコーターによる塗布も可能である。  [0017] The decorative printing (11) applied to the lower layer of the binder (13), as described above, prints patterns, patterns, characters, etc. on the surface of the film sheet (12) to enhance the decorative effect. The design can be applied to landscape photos and paintings with only wood, stone, and tile, or gravure printing such as geometric patterns, screen printing, offset printing, and inkjet printing. Also, application by a roll coater is possible.
[0018] 不透明層(14)は、前記加飾印刷層(11)の下層の発泡断熱材(9)を表面側から見 えなくするために設けられており、上層の加飾層(11)の発色と色再現性を良好にす るために通常白色で不透明な印刷層としている。  [0018] The opaque layer (14) is provided so that the foamed heat insulating material (9) below the decorative printed layer (11) is not visible from the surface side, and the upper decorative layer (11) In order to improve the color development and color reproducibility, it is usually a white and opaque printed layer.
[0019] フィルムシート(12)は、真空成形によって自由に変形する柔軟性を有しておればよ ぐ前記説明のようにポリプロピレン (PP)に限るものではなぐ PETや PCなどの榭脂 であってもよいものである。また実施例では、 200 m厚程度のフィルムシートを用い た力 0. 5〜2mm厚程度の榭脂シートであってもよぐこの場合についても、榭脂シ ート上に加飾印刷(11)を施して外面シート(10)に接着し、これを真空成形するように する。  [0019] The film sheet (12) is not limited to polypropylene (PP) as described above as long as it has flexibility to be freely deformed by vacuum forming, and is a resin such as PET or PC. It may be. In this example, a force of about 0.5 to 2 mm thick using a film sheet having a thickness of about 200 m may be used. Even in this case, decorative printing (11 ) Is applied to the outer sheet (10) and vacuum formed.
[0020] なお、上記のように、フィルムシート(12)に PP榭脂を用いた場合には、 PPが他の榭 脂と比較して安価であるとともに、製造時における炭酸ガスの発生量が少ないことか ら、環境に対する負荷が小さぐまた有害な触媒を使用していないことから、より環境 保護に適した構成となる。  [0020] As described above, when PP resin is used for the film sheet (12), PP is less expensive than other resins, and the amount of carbon dioxide generated during production is low. Since the amount is small, the load on the environment is small and no harmful catalyst is used, so the configuration is more suitable for environmental protection.
[0021] また、水分透過性のきわめて低い PPのようなポリオレフイン系榭脂が、硬質ウレタン フォーム断熱材(9)の層と透明の外面シート(10)との間に介在していることから、外 面シート(10)を介して外部から侵入する水や洗剤がフィルムシート (12)で阻止される ため、断熱材(9)内に侵入してウレタンフォームを加水分解させることによる劣化や亀 裂の発生を抑制することができ、断熱性能の低下を防ぐことができる。 [0021] In addition, a polyolefin resin such as PP having a very low water permeability is interposed between the layer of the hard urethane foam heat insulating material (9) and the transparent outer sheet (10). Water or detergent entering from the outside through the outer sheet (10) is blocked by the film sheet (12). Therefore, it is possible to suppress deterioration and cracking caused by intruding into the heat insulating material (9) and hydrolyzing the urethane foam, and it is possible to prevent a decrease in heat insulating performance.
[0022] さらに、フィルムシート(12)をポリオレフイン系榭脂にすることで、ポリウレタンの発泡 体内部から発生する有機ガスによる前記透明の外面シート(10)へのソルベントクラッ クを低減でき、品質信頼性を向上させることができる。  [0022] Further, by making the film sheet (12) a polyolefin resin, it is possible to reduce the solvent cracks on the transparent outer sheet (10) due to the organic gas generated from the inside of the polyurethane foam. Can be improved.
[0023] フィルムシート(12)とウレタンフォーム断熱材(9)との間に設けたバインダー層(15) は、前述のノインダー(13)と同様、熱可塑性ウレタン榭脂ゃ酢酸ビニル榭脂、塩ィ匕 ビュル 酢酸ビュル共重合体、熱可塑性ポリエステル榭脂、ポリアミド榭脂、アイオノ マー榭脂、塩素化ポリオレフインなどの樹脂で形成すればよぐこのバインダー層(15 )によって、発泡断熱材(9)がフィルムシート(12)に強固に接着することから、断熱箱 、例えば、断熱扉(2)として構造体の形状が保持されるとともに、大きな剛性強度を 保有することができるものである。  [0023] The binder layer (15) provided between the film sheet (12) and the urethane foam heat insulating material (9) is made of thermoplastic urethane resin, vinyl acetate resin, salt, as with the above-mentioned noinder (13). Büll Bule Acetic acid bule copolymer, Thermoplastic polyester resin, Polyamide resin, Ionomer resin, Chlorinated polyolefin, etc. This binder layer (15) can be used for foam insulation (9) Is firmly adhered to the film sheet (12), so that the shape of the structure can be maintained as a heat insulating box, for example, a heat insulating door (2), and a large rigidity can be maintained.
[0024] また、この実施例におけるバインダー層(15)は、フィルムシート(12)面に施した火 炎による表面処理で粗表面化したり、後述するように、発泡断熱材 (9)側に不透明層 (14)を配置させることによるウレタンフォームとの密着性を向上させた構成を採用す ることで不要とすることができる。  In addition, the binder layer (15) in this example is roughened by a surface treatment with a flame applied to the surface of the film sheet (12), or is opaque on the side of the foam insulation (9) as described later. It can be made unnecessary by adopting a structure in which the adhesion with the urethane foam is improved by arranging the layer (14).
[0025] 上記実施例においては、加飾印刷(11)を施す箇所を、フィルムシート(12)の表面 に配置した力 図 4に示すように、フィルムシート )を透明体としてその下層に配 置するようにしてもよぐ下層に配置した場合は、前記ノ インダー( )はフィルムシ ート )の上層に位置することから、バインダー )を印刷する前に加飾印刷( 11' )の層を乾燥処理する必要がなぐ製造工程を簡素化することができる。  [0025] In the above embodiment, the force for placing the decorative print (11) on the surface of the film sheet (12), as shown in Fig. 4, the film sheet) is placed in the lower layer as a transparent body. If it is placed in the lower layer, the noinder () is located in the upper layer of the film sheet). The manufacturing process which does not need to be dried can be simplified.
[0026] なお、不透明層(14)は、印刷のみでなくローラーコートで形成してもよいものであり 、また、前記フィルムシート( )の発泡断熱材(9' )側の面に施してもよ!、。このよ うに設けることで、フィルムシート(12' )が一般に断熱材である硬質ウレタンフォーム と接着しにくいポリプロピレンフィルムであっても、不透明層 )に含まれる榭脂成 分によってウレタンフォームとの密着性が向上し、より強固に断熱材(9' )と接着させ ることができるものであり、この場合、図 5に示すように、発泡断熱材(9〃 )との間にバ インダ一層(15)を設ける必要がないため、コスト的に低減できる効果を奏する。 [0027] 以下、図 6により、前記 1実施例の冷蔵庫扉(2)における外板 (6)の 1製造工程に ついて詳細に説明する。まず、(a)に示すように、 PP榭脂からなるフィルムシート(12) の上面に白色の不透明インクの層(14)を設ける。これは前述のように、スクリーン印 刷でもローラーコートでもよい。次に、(b)で、前記不透明層(14)の上面にグラビア印 刷などで加飾印刷(11)を施す。また、多色にするために複数回印刷をおこなうように してちよい。 [0026] The opaque layer (14) may be formed not only by printing but also by roller coating, and may be applied to the foam insulation (9 ') side surface of the film sheet (). Yeah! In this way, even if the film sheet (12 ') is generally a polypropylene film that is difficult to adhere to the hard urethane foam that is a heat insulating material, the adhesiveness to the urethane foam is determined by the resin component contained in the opaque layer. In this case, as shown in FIG. 5, a single layer of binder (15 mm) is formed between the foam insulation (9 mm) and the heat insulation material (9 ′). ), There is no need to provide this, so that the cost can be reduced. Hereinafter, with reference to FIG. 6, one manufacturing process of the outer plate (6) in the refrigerator door (2) of the first embodiment will be described in detail. First, as shown in (a), a layer (14) of white opaque ink is provided on the upper surface of a film sheet (12) made of PP resin. As described above, this may be screen printing or roller coating. Next, in (b), decorative printing (11) is performed on the upper surface of the opaque layer (14) by gravure printing or the like. It is also possible to print multiple times to achieve multiple colors.
[0028] 次いで、(c)で、加飾印刷層の表面に透明のバインダー(13)を塗布する。このとき( d)として、次工程までの間の埃の付着や傷付きを防ぐために、一時的に表面を保護 フィルム(16)で覆うようにし、次に (e)として、扉形成時にウレタンフォーム断熱材(9) と接触する面に、前記バインダー (13)と基本的に同仕様のバインダー層(15)を配設 して積層された加飾シート(17)を形成する。  [0028] Next, in (c), a transparent binder (13) is applied to the surface of the decorative print layer. At this time, as (d), the surface is temporarily covered with a protective film (16) to prevent dust adhesion and scratches until the next process, and then (e) as urethane foam when the door is formed. On the surface in contact with the heat insulating material (9), a decorative sheet (17) is formed by laminating a binder layer (15) having basically the same specifications as the binder (13).
[0029] 次ステップにおいては、(f)に示すように、この加飾シート(17)における前記バイン ダー(13)の保護フィルム(16)を除去し、その上面にアクリル榭脂からなる外面シート( 10)を加熱装置(18)を有するプレス機(19)によって加熱圧着する。このときのプレス 圧力は約 lOkgZcm2であり、密着させる温度は 150°C、加圧時間は 30秒間に設定 する。これにより、バインダー (13)が融解し、加飾シート (17)と外面シート(10)とが密 着状態に接着され、 (g)に示す積層シート (20)が形成される。 In the next step, as shown in (f), the protective film (16) of the binder (13) in the decorative sheet (17) is removed, and an outer sheet made of acrylic resin on the upper surface thereof (10) is thermocompression-bonded by a press machine (19) having a heating device (18). Pressing pressure at this time is about lOkgZcm 2, the temperature is brought into close contact is set to 0.99 ° C, pressing time 30 sec. As a result, the binder (13) is melted, and the decorative sheet (17) and the outer sheet (10) are adhered in a sealed state to form the laminated sheet (20) shown in (g).
[0030] 次に、予備加熱して軟化させた前記積層シート (20)を、 (h)に概略的に示す成形 型 (21)に設置し、(i)のように真空ポンプ (22)で型内の空気を吸引することで積層シ ート (20)を所定形状に真空成形し、冷蔵庫扉 (2)の外板 (6)を得るものである。  [0030] Next, the laminated sheet (20) softened by preheating is placed in a mold (21) schematically shown in (h), and the vacuum pump (22) is used as shown in (i). By sucking the air in the mold, the laminated sheet (20) is vacuum formed into a predetermined shape to obtain the outer plate (6) of the refrigerator door (2).
[0031] なお、積層シート (20)を外板 (6)に成形する方法は、前記真空成形法に限るもので はなぐシート状の被成形体の成形方法である圧空成形やプレス成形によっても同 様に得ることができる。  [0031] The method of forming the laminated sheet (20) into the outer plate (6) is not limited to the above-described vacuum forming method, and may be performed by pressure forming or press forming, which is a method for forming a sheet-shaped object. It can be obtained in the same way.
[0032] 上記により所定形状に形成された外板 (6)は、前述の図 2に示すように、冷蔵室の 内面側を形成する内板(7)と結合し、図示しない発泡成形型内に設置してその内部 空間に硬質ウレタンフォーム断熱材 (9)の原液を注入して発泡させ、充填固化するこ とで内板(7)や外板 (6)の前記バインダー層(15)、あるいは不透明印刷層(14" )と 強固に接着した断熱材層 (9)を有する断熱扉(2)を構成するものである。 [0033] なお、上記実施例においては、冷蔵庫の冷蔵室扉を例として説明した力 これに限 ることなく野菜室や製氷室など他の扉に適用できることは言うまでもなぐさらに、扉に 限らず、本体上部のテーブル板や外側板に適用して意匠効果を向上し高級感を持 つた外郭面を形成することも可能である。 [0032] The outer plate (6) formed in a predetermined shape as described above is coupled to the inner plate (7) forming the inner surface side of the refrigerator compartment as shown in FIG. The binder layer (15) on the inner plate (7) and outer plate (6), by injecting a raw solution of rigid urethane foam heat insulating material (9) into the interior space and foaming it, filling and solidifying it, Alternatively, it constitutes a heat insulating door (2) having a heat insulating material layer (9) firmly bonded to an opaque printed layer (14 "). [0033] It should be noted that in the above embodiment, the force described as an example of the refrigerator compartment door of the refrigerator is not limited to this, and can be applied to other doors such as a vegetable room and an ice making room. It can be applied to the table plate and the outer plate at the top of the main body to improve the design effect and form a high-quality outer surface.
産業上の利用可能性  Industrial applicability
[0034] 本発明は、扉など本体外郭の意匠構成を向上させた冷蔵庫に利用することができ る。 [0034] The present invention can be used for a refrigerator having an improved design structure of the outer shell such as a door.
図面の簡単な説明  Brief Description of Drawings
[0035] [図 1]本発明の 1実施形態を示す冷蔵庫の外観正面図である。 FIG. 1 is an external front view of a refrigerator showing an embodiment of the present invention.
[図 2]図 1の冷蔵室扉の A— A線に沿う断面図である。  FIG. 2 is a cross-sectional view taken along line AA of the refrigerator compartment door of FIG.
[図 3]図 2における扉外板の積層状態を示すの断面図である。  FIG. 3 is a cross-sectional view showing a laminated state of the door outer plates in FIG.
[図 4]図 3に示す扉外板の他の実施例の断面図である。  FIG. 4 is a cross-sectional view of another embodiment of the door skin shown in FIG.
[図 5]図 3に示す扉外板のさらに他の実施例の断面図である。  FIG. 5 is a cross-sectional view of still another embodiment of the door skin shown in FIG.
[図 6]図 2に示す扉外板の製造過程を示す工程図である。  FIG. 6 is a process diagram showing a manufacturing process of the door outer plate shown in FIG. 2.
符号の説明  Explanation of symbols
[0036] 1 冷蔵庫本体 2 冷蔵室扉 6 扉外板  [0036] 1 Refrigerator body 2 Refrigeration room door 6 Door skin
7 内板 9 断熱材 10 外面シート  7 Inner plate 9 Thermal insulation 10 Outer sheet
11 加飾印刷層 12 フィルムシート 13 ノインダー  11 Decorative printing layer 12 Film sheet 13 Noinder
14 不透明層 15 バインダー層 16 保護フィルム  14 Opaque layer 15 Binder layer 16 Protective film
17 加飾シート 19 プレス機 20 積層シート  17 Decorative sheet 19 Press machine 20 Laminated sheet
21 成形型 22 真空ポンプ  21 Mold 22 Vacuum pump

Claims

請求の範囲 The scope of the claims
[1] 熱可塑性榭脂からなる透明シートの一面に加飾シートを接着した積層シートを加熱 成形して箱状の外板を形成し、前記外板の加飾シート側にポリウレタンからなる硬質 断熱材を発泡充填して本体外郭を形成したことを特徴とする冷蔵庫。  [1] A laminated sheet in which a decorative sheet is bonded to one side of a transparent sheet made of thermoplastic resin is formed by heating to form a box-shaped outer plate, and a hard insulating material made of polyurethane on the decorative sheet side of the outer plate. A refrigerator characterized by forming a main body shell by foam filling.
[2] 透明シートと加飾シートとを加熱接着して形成した積層シートを真空あるいは圧空 成形、若しくはプレス成形により箱状に形成したことを特徴とする請求項 1記載の冷 蔵 。  [2] The refrigeration according to claim 1, wherein the laminated sheet formed by heating and bonding the transparent sheet and the decorative sheet is formed into a box shape by vacuum or pressure forming or press forming.
[3] フィルムシートに模様や色彩を印刷あるいは塗装した加飾シートの印刷あるいは塗 装を施した層の発泡断熱材側に透光性の低い印刷層を設けたことを特徴とする請求 項 1記載の冷蔵庫。  [3] The printed sheet having a low translucency is provided on the foam insulation side of the layer on which the decorative sheet is printed or coated with a pattern or color on the film sheet. The refrigerator described.
[4] 透明シートに加熱接着させた加飾された熱可塑性榭脂シートをポリオレフイン系榭 脂で形成したことを特徴とする請求項 1記載の冷蔵庫。  [4] The refrigerator according to claim 1, wherein the decorated thermoplastic resin sheet heat-bonded to the transparent sheet is formed of a polyolefin resin.
[5] 加飾シートと透明シートとを接着するバインダー層は加熱硬化型榭脂からなることを 特徴とする請求項 1記載の冷蔵庫。  [5] The refrigerator according to claim 1, wherein the binder layer for bonding the decorative sheet and the transparent sheet is made of a thermosetting resin.
[6] フィルムシートの上面に不透明層を設け、この不透明層の上面に加飾印刷を施し、 次いで前記加飾印刷層の表面に透明のノ インダーを塗布するとともに前記フィルム シートの下面側にバインダー層を設けて加飾シートを形成し、この加飾シートにおけ る前記透明バインダーの上面に透明の外面シートを圧着して積層シートを形成し、こ の積層シートを成形型に設置して所定形状に成形することで外板を得るとともに、こ の外板を室内側を形成する内板と結合し、その内部空間に硬質ウレタンフォーム断 熱材発泡充填させることで断熱体を形成したことを特徴とする冷蔵庫。  [6] An opaque layer is provided on the upper surface of the film sheet, decorative printing is performed on the upper surface of the opaque layer, a transparent binder is then applied to the surface of the decorative printing layer, and a binder is provided on the lower surface side of the film sheet. A decorative sheet is formed by providing a layer, and a laminated sheet is formed by press-bonding a transparent outer sheet to the upper surface of the transparent binder in the decorated sheet. The outer plate is obtained by molding into a shape, and the outer plate is combined with the inner plate forming the indoor side, and the heat insulation foam is filled by filling the inner space with hard urethane foam thermal insulation foam. Features a refrigerator.
PCT/JP2006/319861 2005-10-25 2006-10-04 Refrigerator WO2007049439A1 (en)

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JP2016090193A (en) * 2014-11-10 2016-05-23 パナソニックIpマネジメント株式会社 Home electric appliance and decoration exterior plate used for the same
JP2016211787A (en) * 2015-05-11 2016-12-15 パナソニックIpマネジメント株式会社 Household electric appliance and decorative sheath material used for the same
JP2019090565A (en) * 2017-11-14 2019-06-13 有限会社河村 Method for pasting decorative sheet for consumer electronics

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