WO2006080054A1 - Gas calorie variation suppressing device, fuel gas supply facility, gas turbine facility, and boiler facility - Google Patents
Gas calorie variation suppressing device, fuel gas supply facility, gas turbine facility, and boiler facility Download PDFInfo
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- WO2006080054A1 WO2006080054A1 PCT/JP2005/000977 JP2005000977W WO2006080054A1 WO 2006080054 A1 WO2006080054 A1 WO 2006080054A1 JP 2005000977 W JP2005000977 W JP 2005000977W WO 2006080054 A1 WO2006080054 A1 WO 2006080054A1
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- gas
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- inlet
- outlet
- fuel
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K5/00—Feeding or distributing other fuel to combustion apparatus
- F23K5/002—Gaseous fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
- F02C3/22—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C7/00—Features, components parts, details or accessories, not provided for in, or of interest apart form groups F02C1/00 - F02C6/00; Air intakes for jet-propulsion plants
- F02C7/22—Fuel supply systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C9/00—Controlling gas-turbine plants; Controlling fuel supply in air- breathing jet-propulsion plants
- F02C9/26—Control of fuel supply
- F02C9/40—Control of fuel supply specially adapted to the use of a special fuel or a plurality of fuels
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K5/00—Feeding or distributing other fuel to combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K5/00—Feeding or distributing other fuel to combustion apparatus
- F23K5/02—Liquid fuel
- F23K5/14—Details thereof
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N2221/00—Pretreatment or prehandling
- F23N2221/10—Analysing fuel properties, e.g. density, calorific
Definitions
- Gas calorie fluctuation suppression device fuel gas supply equipment, gas turbine equipment and boiler equipment
- the present invention relates to a gas calorie fluctuation suppressing device, a fuel gas supply facility, a gas turbine facility, and a boiler facility. More specifically, when the calorific value (also referred to as calorie) of the gas used as the fuel for the combustion facility fluctuates, such as low calorie gas, this gas calorie fluctuation suppressing device can suppress this calorific value fluctuation, and this gas calorie fluctuation suppressing device. And a gas turbine facility and a boiler facility as a combustion facility equipped with a fuel gas supply facility.
- BFG Blast Furnace Gas
- C0 carbon dioxide
- CH3 methane
- BFG contains 2-10 g / Nm 3 of dust. After removing this to about 0. Olg / Nm 3 with a dust remover, the fuel gas with a calorific value of about 800 kcal / Nm 3 It is used in hot air ovens, coke ovens, heating furnaces, boilers, etc.
- gas turbines have also been able to burn low calorie gas due to improvements in technology, and there are an increasing number of cases where BFG is used as gas turbine fuel to generate electricity.
- low calorie gas is defined as a gas whose calorific value is about 12 MJ / Nm 3 or less.
- the low calorie gas is not limited to blast furnace gas (BFG) but includes various types of gas such as converter gas (LDG) and mixed gas thereof.
- N 2 nitrogen gas
- N 2 nitrogen gas
- Patent Document 1 JP 2002-155762 A
- Patent Document 2 Japanese Patent Laid-Open No. 9-317499
- the present invention has been made to solve such a problem, and by suppressing the calorie fluctuation of the fuel gas such as low calorie gas supplied as fuel to the combustion facility, the fuel gas can be reduced by the diluted gas. It is easy and effective to increase heat not only by heat but also by heat-increased gas (medium calorie and high calorie gas mixed to increase the caloric value of fuel gas, hereinafter also called medium / high calorie gas).
- a gas calorie fluctuation suppressing device that can eliminate the need for heat reduction using a dilution gas or heat increasing gas
- a fuel gas supply facility equipped with the gas calorie fluctuation suppressing device and a fuel gas supply facility The purpose is to provide gas turbine equipment and boiler equipment.
- the gas calorie fluctuation suppressing device of the present invention includes:
- a gas mixing device for mixing fuel gas disposed in a fuel gas supply passage for supplying gas to the combustion facility as fuel;
- the gas mixing device is formed separately from a gas passage component having a plurality of gas passages, an inlet member for allowing fuel gas to flow into the gas passage component from the fuel gas supply passage, and the inlet member. Further, the gas passage component member force is provided with an outlet member for allowing the fuel gas to flow out into the fuel gas supply passage, and the gas continuously flowing in from the inlet member further includes a plurality of gas passage component members. After passing through the gas passages with a time difference, the gas passages join together and can flow out from the outlet member.
- Fuel gas which is supplied every moment through the fuel gas supply passage, flows into the gas passage constituent member, and is mixed with time difference when it comes out from each of the plurality of gas passages and merges. Therefore, even when the caloric value of the fuel gas is fluctuating, the time difference mixing reduces the width of the caloric fluctuation, and the caloric fluctuation speed is reduced. As a result, it becomes easy and effective to adjust the calorie fluctuation of the fuel gas within the allowable fluctuation range of the gas characteristics of the combustion facility by using the dilution gas or the heat increasing gas. Also, depending on the average caloric value of the fuel gas, it is possible to make it unnecessary to reduce or increase heat. Note that the time difference mixing means that the gas flowing into the gas passage constituting member continuously with a time delay is mixed with the gas that has already flowed and stayed.
- connection to the inlet member is not limited to the upstream side of the fuel gas supply passage
- connection to the outlet member is not limited to the downstream side of the fuel gas supply passage.
- the gas passage constituting member comprises a first container in which a plurality of gas chambers constituting the gas passage are formed,
- the inlet member is branched and connected from the fuel gas supply passage to the gas inlet of each gas chamber, the outlet member is integrated from the gas outlet of each gas chamber and connected to the fuel gas supply passage, and the inlet member is branched.
- a gas flow rate adjusting device capable of changing the gas flow rate can be provided in each of the portions.
- the gas passes through each of the plurality of gas chambers with a time difference, so that the time difference may be mixed when the gases merge later. It becomes possible.
- the gas passage constituting member comprises a first container in which a plurality of gas chambers constituting the gas passage are formed,
- the inlet member is branched and connected from the fuel gas supply passage to the gas inlet of each gas chamber, the outlet member is integrated from the gas outlet of each gas chamber and connected to the fuel gas supply passage, and the plurality of gases It is also possible to configure the chambers to have different volumes.
- the gas passes through the plurality of gas chambers with a time difference, so that the time difference mixing is performed when the gas that has passed through the gas chambers later merges. It becomes possible.
- the gas passage constituting member includes a plurality of second containers constituting the gas passage, and a gas inlet and a gas outlet are formed in each second container,
- the inlet member is branched and connected from the fuel gas supply passage to the gas inlet of each second container.
- the outlet member is integrated from the gas outlet of each second container and connected to the fuel gas supply passage, and a gas flow rate adjusting device capable of changing the gas flow rate is provided at each branched portion of the inlet member. Can do.
- the gas passage constituting member includes a plurality of second containers constituting the gas passage, and each of the second containers has a gas inlet and a gas outlet,
- the inlet member is branched and connected from the fuel gas supply passage to the gas inlet of each second container, and the outlet member is integrated from the gas outlet of each second container and connected to the fuel gas supply passage.
- the two containers can be configured to have different volumes.
- the plurality of second containers described above may be bound together or may be in an independently separated state.
- the gas passage constituting member comprises a third container force including a perforated plate in which a plurality of through holes constituting the gas passage are formed,
- the inlet member and the outlet member are disposed in a third container
- the perforated plate can be arranged so as to cut the interior of the third container into a space on the inlet member side and a space on the outlet member side.
- the structure of the third container is not limited.
- it may be a fixed-shaped container whose volume does not change, or may be a variable-volume tank used as a device (gas holder) for monitoring the gas supply-demand balance in a conventional gas turbine facility or the like.
- the internal volume variable tank is a tank with a lid member that is airtightly mounted that can move up and down according to the tank internal pressure, and the balance member can be maximized by positively moving the lid member up and down with a drive unit.
- a plurality of the perforated plates may be arranged at intervals.
- the through hole is formed in a range excluding a portion of the porous plate that intersects with a gas flow path central axis of the inlet member toward the inside of the third container and the vicinity thereof. ,. This is because the residence time of the gas flowing into the third container can be extended.
- the gas outlet force is preferably formed at a position deviating from an extension line of the central axis of the gas inlet. . This is because the residence time of the gas flowing into the first container or the second container can be extended.
- the gas inlet is configured to change the inflow angle of the fuel gas into the gas passage of the gas passage constituent member. It is preferable to install a gas inflow device. This is because the gas inflow direction can be adjusted so that the time difference mixing of the gas is effectively performed inside the first container or the second container.
- the inflow angle of the fuel gas into the third container can be changed to one of the inlet member and the vicinity of the inlet member in the third container. It is preferable to install a gas inflow device configured as described above. This is because the gas inflow direction can be adjusted so that the time difference mixing of the gas is effectively performed inside the third container.
- the gas calorie fluctuation suppressing device including the gas inflow device has at least one louver that is swingably mounted so that the tilt angle can be changed from the outside. It can consist of variable louvers.
- a plurality of the inlet members are provided, and an inlet member for allowing the fuel gas to flow into the third container can be selected and switched among the inlet members.
- a plurality of the outlet members are provided, and an outlet member that allows the fuel gas to flow out of the third container can be selected and switched in synchronization with the switching of the inlet member. Can be configured.
- the gas calorie fluctuation suppressing device including the third container, a plurality of inlet members are formed.
- a flow rate adjusting device at each inlet member, and to configure it so that the flow rate of the gas flowing through each inlet member can be changed.
- the powerful configuration for example, it is possible to promote the time difference mixing of the gas in the third container S by periodically switching the gas inlet through which the gas flows.
- an inert gas supply passage for allowing an inert gas to flow into the gas passage constituent member is connected to the gas passage constituent member or the inlet member. This is because the fuel gas and the inert gas are preliminarily mixed with each other in the gas passage constituent member.
- waste nitrogen discharged from at least one of an oxygen production plant and a nitrogen production plant is preferable to use waste nitrogen discharged from at least one of an oxygen production plant and a nitrogen production plant as the inert gas. This is because it is easy and inexpensive to procure inert gas.
- the oxygen production plant and nitrogen production plant those installed in processes such as the blast furnace method and the direct reduced iron method can be applied.
- a stirring device for stirring gas may be installed in the gas mixing device.
- a fan or the like can be adopted as the stirring device.
- An inlet gas calorific value measuring device for measuring the gas calorie value of the fuel gas is installed in one of the fuel gas supply passage and the inlet member connected to the inlet member, and the outlet member is installed in the outlet member.
- An outlet gas calorific value measuring device for measuring the gas calorie value of the fuel gas can be installed in one of the connected fuel gas supply passage and the outlet member.
- the gas calorie fluctuation of the gas flowing into the gas passage constituent member is reduced.
- a control device that controls the amount of gas flowing into the gas passage component based on the comparison result and the calorie fluctuation of the discharged gas. Can be set.
- the calorie fluctuation of the inflow gas to the gas path constituent member and the calorie fluctuation of the exhaust gas from the gas path constituent member It is possible to arrange a control device that controls the change of the gas inflow direction into the gas passage constituting member based on the comparison result.
- the fuel gas supply facility of the present invention comprises: A fuel gas supply passage for supplying gas as fuel to the combustion facility, and a gas calorie fluctuation suppressing device for suppressing fluctuations in the calorific value of the fuel gas supplied through the fuel gas supply passage,
- This gas calorie fluctuation suppressing device is composed of any one of the gas calorie fluctuation suppressing devices described above.
- An outlet passage connected between the outlet member of the gas mixing device and the fuel gas supply passage, and connected between an inlet member of the gas mixing device and the upstream side of the connection point of the outlet passage in the fuel gas supply passage. And an upstream inlet passage.
- this gas calorie fluctuation suppressing device instead of the upstream side inlet passage or together with the upstream side inlet passage, it is downstream from the connection point between the inlet member of the gas mixing device and the outlet passage in the fuel gas supply passage. And a downstream inlet passage connected to the gas inlet side, and a gas pumping device installed in the downstream inlet passage for pumping the fuel gas toward the gas mixing device.
- An outlet passage connected between the outlet member of the gas mixing device and the fuel gas supply passage, and connected between an inlet member of the gas mixing device and the upstream side of the connection point of the outlet passage in the fuel gas supply passage.
- a return passage connected between the downstream side of the connection point of the outlet passage in the fuel gas supply passage and the upstream side of the connection point of the upstream inlet passage in the fuel gas supply passage; and installed in the return passage;
- a gas pressure feeding device that pressure-feeds the fuel gas toward the upstream side fuel gas supply passage may be further provided.
- the gas mixing device has two inlet members;
- a downstream fuel gas supply passage is connected to the outlet member of the gas mixing device, an upstream fuel gas supply passage is connected to one inlet member of the gas mixing device, and the other inlet member of the gas mixing device
- a return passage connected between the fuel gas supply passage and the downstream fuel gas supply passage;
- a gas pressure feeding device that is installed in the return passage and pumps the fuel gas toward the gas mixing device can be further provided.
- the fuel gas supply passage on the downstream side is connected to the outlet member of the gas mixing device, the fuel gas supply passage on the upstream side is connected to the inlet member of the gas mixing device, and the fuel gas supply on the upstream side of the gas mixing device is supplied
- a return passage connected between the passage and the fuel gas supply passage downstream of the gas mixing device;
- a gas pumping device installed in the return passage and pumping the fuel gas from the downstream side to the upstream side of the fuel gas supply passage may be further provided.
- the gas turbine equipment of the present invention comprises:
- the fuel gas supply facility is composed of one of the best fuel gas supply facilities mentioned above.
- the boiler equipment of the present invention comprises:
- the fuel gas supply facility is configured as any one of the above-mentioned fuel gas supply facilities.
- the calorie of the low calorie gas supplied by time difference mixing. Variation can be suppressed (mitigated). That is, not only to reduce the amplitude of fluctuation, but also as if it were a low-pass filter, a short cycle or medium Since the fluctuations in the period can be eliminated and only the long-period fluctuations can remain, heat reduction by the dilution gas and heat increase by the heat-increasing gas can be effectively and easily performed. In addition, there is a case where heat reduction by dilution gas and heat increase by heating gas are not necessary.
- FIG. 1 is a piping diagram showing an outline of a gas turbine power generation facility including a low calorie gas supply facility which is an embodiment of the fuel gas supply facility of the present invention.
- FIG. 2 is a graph showing an example of a state in which the calorie change of the gas is suppressed by passing the low calorie gas through the gas mixing device.
- FIG. 3 is a piping diagram showing another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 4 (a) is a longitudinal section taken along a plane along the central axis of the apparatus, showing still another example of the gas mixing apparatus that can be installed in the gas turbine power generation facility of FIG. Fig. 4 (b) is a sectional view taken along line IV-IV in Fig. 4 (a).
- FIG. 5 (a) is a longitudinal section taken along a plane along the central axis of the apparatus, showing still another example of the gas mixing apparatus that can be installed in the gas turbine power generation facility of FIG. Fig. 5 (b) is a cross-sectional view taken along line V-V in Fig. 5 (a).
- FIG. 6 is a longitudinal sectional view showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 7 is a longitudinal sectional view showing still another example of the gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 8 (a) is a front view showing another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG. 1, and FIG. 8 (b) is a front view of FIG. 8 (a).
- FIG. 8 is a sectional view taken along line VIII-VIII.
- FIG. 9 is a partially cutaway perspective view showing still another example of the gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 10 is a longitudinal section taken along a plane along the central axis of the gas mixing apparatus of FIG.
- FIG. 11 is a graph showing an example of a result of simulation of time-difference mixing of gases in the gas mixing apparatus.
- FIG. 12 is a graph showing another example of the result of the simulation of the time difference mixing of the gas in the gas mixing apparatus.
- FIG. 13 (a) is a longitudinal section taken along a plane along the central axis of the apparatus, showing still another example of a gas mixing apparatus that can be installed in the gas turbine power generation facility of FIG. Fig. 13 (b) is a cross-sectional view taken along the line ⁇ _ ⁇ of Fig. 13 (a).
- FIG. 14 is a longitudinal sectional view showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG. 1.
- FIG. 15 is a longitudinal sectional view showing still another example of the gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 16 is a longitudinal sectional view showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG. 1.
- FIG. 17 is a partially cutaway perspective view showing an example of a gas inflow device used in the gas mixing device of FIG.
- FIG. 18 is a cross-sectional view showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG. 1.
- FIG. 19 is a longitudinal sectional view showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG. 1.
- FIG. 20 is a piping diagram showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 21 is a piping diagram showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- FIG. 22 is a piping diagram showing another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG.
- Fig. 23 is a piping diagram showing another example of a gas mixing device that can be installed in the gas turbine power generation facility of Fig. 1.
- FIG. 24 is a piping diagram showing still another example of a gas mixing device that can be installed in the gas turbine power generation facility of FIG. 1.
- FIG. 25 shows a boiler including a low-calorie gas supply facility according to another embodiment of the present invention. It is a piping diagram which shows the outline of an installation.
- Fig. 1 shows a low calorie gas supply facility 1 which is an embodiment of the fuel gas supply facility of the present invention for supplying low calorie gas as a fuel gas to a gas turbine as a combustion facility, and the low calorie gas supply facility 1 It is a piping diagram showing the outline of the included gas turbine equipment.
- a gas turbine power generation facility is exemplified as a gas turbine facility.
- the calorific value is Low calorie gas, defined as a gas of about 12 MJ / Nm 3 or less, often changes its calorie characteristics.
- the low-calorie gas supply facility 1 as the fuel gas supply facility is a fuel gas supply that supplies by-product gas (hereinafter referred to as low-calorie gas) generated directly in the reduced iron facility S to the gas turbine 2 as fuel.
- a low calorie gas supply pipe 3 as a passage and a dilution gas supply pipe 4 for supplying a dilution gas to the low calorie gas supply pipe 3 to reduce the heat of the low calorie gas are provided.
- the reason why the diluted gas is supplied to the low calorie gas is to prevent the calorie value of the low calorie gas from fluctuating and exceeding the allowable calorie range inherent to the gas turbine.
- the dilution gas supply pipe 4 is provided with a flow meter 18 and a flow rate adjustment valve (hereinafter referred to as a flow control valve) 19 for adjusting the flow rate of the dilution gas.
- a flow control valve for adjusting the flow rate of the dilution gas.
- the dilution gas inert gas, air, steam, exhaust gas discharged from combustion facilities, etc. can be employed.
- Force S that nitrogen gas (N 2) can be preferably used as an inert gas S, of course, not limited to N, and may be CO, helium (He), etc.
- the downstream part of the mixer 6 of the low-calorie gas supply pipe 3 may be sent to the gas turbine 2 in a state where the low-calorie gas is mixed with the dilution gas, so this range of pipe is called the mixed gas supply pipe 14 .
- the low calorie gas supply facility 1 is provided with a control device 5 for controlling its operation.
- a dust collector 7 for removing dust from the low calorie gas directly sent from the reduced iron facility S and a mixture of the low calorie gas are used.
- a gas mixing device 10 is installed.
- the gas mixing device 10 includes a gas passage component member 23 having a plurality of gas passages, an inlet member 11 for connecting the upstream low calorie gas supply pipe 3 to the gas passage member 23, and a gas separate from the inlet member 11.
- An outlet member 12 for connecting the low-calorie gas supply pipe 3 on the downstream side to the passage constituting member 23 is provided.
- the gas mixing device 10 has a relatively large capacity, and the low caloric gas flowing in while changing the calorie from time to time is mixed in the gas mixing device 10 with a time difference. That is, at the same time The low calorie gas that has flowed into the gas mixing device 10 is distributed from a portion that flows out of the outlet member 12 relatively early to a portion that stays in the gas mixing device 10 from late. On the other hand, since new gas continuously flows from the inlet member 11, the gas that has flowed in the past and the gas that has flowed in are continuously mixed. Here, this is called time difference mixing. As will be described later, the gas mixing device functions as a gas calorie fluctuation suppressing device by exhibiting this time difference mixing.
- calorific value detection devices 8 and 9 for detecting the calorific value of the low calorie gas are installed, and the gas flow rate is set on the downstream side of the gas mixing device 10.
- a flow meter 13 for measurement is installed.
- the installation location of the calorific value detection devices 8 and 9 is not limited to the low calorie gas supply pipe 3, but can be installed on the inlet member 11 and outlet member 12 of the gas mixing device 10 if possible.
- the flow meter 13 is installed in a portion between the gas mixing device 10 and the mixer 6 in the low calorie gas supply pipe 3, but the position is not limited to this. For example, it may be installed in the mixed gas supply pipe 14 downstream from the mixer 6 or may be installed in the fuel pipe 17 connected to the combustor 20 of the gas turbine 2 described later.
- the calorific value detection devices 8 and 9 a so-called calorimeter that directly measures the calorific value of gas, a device that measures the content (concentration) of combustible components, and the like are used. If importance is attached to the detection speed, it is now preferable to use a combustible gas concentration detector. Furthermore, depending on the type of combustible component contained in the low calorie gas applied, and depending on the combustible component in which the main concentration fluctuation occurs (for example, carbon monoxide in the byproduct gas in the direct reduced iron method), You may use the density
- a calorimeter 15 is installed in the mixed gas supply pipe 14. This is because the calorimeter 9 and the flow meter 13 on the outlet side of the gas mixing device 10 are monitored and the calorimeter 15 of the mixed gas supply pipe 14 is monitored to determine the appropriateness of the final caloric value of the mixed gas. It is. Furthermore, when using a gas containing a relatively large amount of oxygen, such as air or exhaust gas from combustion equipment, as the dilution gas, the mixed gas supply pipe 14 or 14 is used to control the oxygen concentration of the mixed gas. It is desirable to install an oxygen concentration meter (not shown) in the dilution gas supply pipe 4. A fuel gas compressor 16 of the gas turbine 2 is installed on the downstream side of the calorimeter 15.
- a flow control valve 21 for adjusting the turbine output is installed in the fuel pipe 17 connected from the fuel gas compressor 16 to the combustor 20 of the gas turbine 2.
- a generator 22 is connected to the gas turbine 2.
- the gas turbine 2 may be provided with an exhaust heat recovery boiler power generation facility that generates power using the exhaust gas.
- the gas mixing device 10 includes the inlet member 11 and the outlet member 12 to which the low calorie gas supply pipe 3 is connected. Therefore, the low caloric gas sent flows through the inlet member 11 and into the gas passage constituting member 23.
- the gas passage component 23 has a large volume, for example, a low calorie gas supply pipe 3 having a diameter of about 23 m and a normal volume of about 20000 20000 Om 3 is installed. The low calorific gas that is sent while the calorie fluctuates from time to time is mixed in a time difference in the gas mixing device.
- FIG. 2 when the volume of 2 00000M 3 below the gas passage forming member 23 having a gas mixing device 10 in Figure 1, supply of low-calorie gas force S flow rate 500,000 nm 3 / hr varying calorific value
- the simulation results for the state of suppression (relaxation) of calorie fluctuation are shown.
- the horizontal axis represents time (minutes), and the vertical axis represents the gas calorie value (kcal / Nm 3 ), which is the calorific value of low calorie gas.
- the curve indicated by the broken line in the figure indicates the calorie fluctuation (original fluctuation) of the low calorie gas sent to the gas mixing device 10. This is a sample that was actually measured.
- the curve shown by the solid line shows the calorie fluctuation (after-suppression fluctuation) of the low calorie gas exiting from the gas mixing device 10 after sufficient time difference mixing.
- the calorific value of the low calorific gas before entering the gas mixing device 10 fluctuates to about 1530 kcal / Nm 3 force about 2360 kca 1 / Nm. In other words, it has a fluctuation range of about ⁇ 21% of the average value (1945 kcal / Nm 3 ).
- the calorie fluctuation of the low calorie gas coming out of the gas mixing device 10 it is 1780 kcal / Nm 3 force, etc., up to 1960 kcal / Nm 3 and the fluctuation range is flat.
- the average value (1870kcal / Nm 3 ) is suppressed to about ⁇ 5%.
- fluctuations in the short period and medium period are removed, and fluctuations in a relatively long period remain. This effect tends to become more pronounced as the volume of the gas mixing device is increased with respect to the low calorie gas supply flow rate. If the period of the original fluctuation is short and the fluctuation width is small, the economic power will be effective even if the volume of the gas mixing device is reduced.
- the gas mixing device that can realize the time difference mixing of the low calorie gas
- the calorie fluctuation of the low calorie gas is greatly suppressed.
- the control of mixing the dilution gas downstream is very easy.
- the calorie fluctuation range of the fuel gas of gas turbine 2 is set to ⁇ 10% of the standard calorie value (average value)
- the average value of the fluctuating calorie is calculated downstream of the gas mixing device.
- the air supply operation it is no longer necessary to consider the power calorie fluctuation of low calorie gas.
- the gas mixing device 10 has a predetermined volume, the low-calorie gas time difference mixing described above can be performed. However, the low-calorie gas time difference mixing is more sufficiently performed in the gas mixing device.
- the gas mixing device is configured so that a part of the low calorific gas flowing into the tank stays in the tank for as long as possible and is mixed sufficiently in the tank, so that more effective time difference mixing is performed.
- a gas mixing device is a gas mixing device in which the gas that has flowed into it passes through the gas passages formed there over different times, and the gas that has passed through each gas passage is mixed. The time difference mixing is configured to be achieved. This configuration will be described with reference to FIG. 4 and FIG.
- the gas mixing device 10 shown in FIG. 4 employs a tank 25 in which a gas chamber 24 serving as a plurality of gas passages is formed as a gas passage constituent member 23.
- a plurality of cylindrical partition walls 26 having upper ends opened on the floor surface in the cylindrical tank 23 are arranged concentrically at intervals, and the tank peripheral wall and the cylindrical partition wall 26 are connected to each other.
- the space between each other and the space between the cylindrical partition walls 26 constitute a gas passage 24, respectively.
- the height of the upper end of the cylindrical partition wall 26 is lower than the height of the ceiling of the tank 25, and each gas chamber (gas passage) 24 is formed by the space between the ceiling of the tank 25 and the upper end of each cylindrical partition wall 26. It is communicated.
- Gas inlet holes 27 are formed at positions corresponding to the gas chambers 24 at the bottom of the tank 25, and one gas connected to the low-calorie gas supply pipe 3 on the downstream side is formed on the ceiling of the tank 25.
- An outlet hole 28 is formed.
- the inlet member 11 adjusts the amount of inflow gas installed in the pipe 29 branched from the low-calorie gas supply pipe 3 on the upstream side and connected to each of the inlet holes 27 and the pipe 29.
- the flow control valve 30 is provided. It can be said that the outlet member 12 includes the outlet hole 28 and a portion of the tank 25 above the upper end of each cylindrical partition wall 26. That is, the outlet member 12 is a portion of the tank that defines the space between the ceiling of the tank 25 and the upper end of each cylindrical partition wall 26 including the outlet hole 28.
- the gas that passes through the gas passages 24 merges at the outlet member 12 and is mixed there.
- the gas passage component 23 in FIG. 4 has four gas passages 24a, 24b, 24c, and 24d. However, the number is not limited, and two or more gas passages may be used. From the standpoint of realizing a long time gap, the better.
- connection of the inlet member 11 to each gas passage 24 is not limited to the bottom of the tank 25 as in this embodiment, but the length of the gas passage 24 extending from the inlet member 11 to the outlet member 12 is longer. Therefore, when the upper end of the gas passage 24 is opened and communicated with the outlet member 12, the inlet member 11 should be connected to the bottom of the tank 25 as shown in the figure.
- the volumes of all the gas chambers 24 are substantially the same.
- the flow rate of the gas flowing into each gas chamber 24 is made different by adjusting the opening degree of the flow control valve 30.
- the time until the gas that has flowed into each gas chamber 24 at the same time reaches the outlet member 12 is gas. It will vary depending on chambers 24a, 24b, 24c and 24d. As a result, the gas that has flowed out of each gas chamber and merged is mixed by time difference, and calorie fluctuation is suppressed. This will be explained below.
- V the total gas flow rate through the inlet member 11, and the ratio of the gas flow rates flowing into the first to nth gas passages having the same volume W is 1: 2: 3: ⁇
- ⁇ 2 ⁇ is the nth gas after 1 / n X t
- the gas that has flowed into all the gas passages at the same time flows out from each gas passage after a different time, and merges and is mixed at the outlet member 12.
- the gas flowing into the gas mixing device 10 is effectively time-diffused and the calorie fluctuation of the gas is suppressed.
- a mixer or a stirring device may be installed at the outlet member 12 (for example, a portion of the tank 25 above the gas passage 24).
- a fan or the like can be used as the stirring device. It is preferable to install an electric motor or the like for driving a fan or the like outside the tank or gas passage.
- the flow rate of gas flowing into each gas passage is an integer ratio, but the present invention is not limited to this configuration, and an arbitrary flow rate ratio can be selected. Moreover, you may make the gas of the same flow flow in some some gas passages as needed.
- the plurality of gas passages have the same volume, and the flow rates of the gas flowing into the gas passages are different.
- the volume of the plurality of gas passages is as follows.
- the inflow gas flow rate may be the same.
- the gas mixing device 31 shown in FIG. 5 has a gas passage constituting member 33 in which a plurality of gas chambers 32a, 32b, 32c, 32d having different volumes are formed.
- This gas passage constituting member 33 is similar to the gas passage constituting member 10 of FIG. 4 in that a tank 25 in which a plurality of cylindrical partition walls 26 whose upper ends are opened on the floor surface are arranged concentrically at intervals. The circumference of the tank 25 The space between the wall and the cylindrical partition wall 26 and the space between the cylindrical partition walls 26 constitute a gas passage 32, respectively.
- the inside of the innermost cylindrical partition wall 26a is a part of the path through which the merged gas flows out.
- the upper end of the all-cylindrical partition wall 26 is located at a position spaced downward from the ceiling of the tank 25.
- the inlet member 11 has a pipe 29 branched from the low-calorie gas supply pipe 3 on the upstream side and connected to each of the inlet holes 27 of the tank 25.
- the flow control valve 30 is not provided. Les. Then, almost the same flow rate of gas flows into all the gas passages (gas chambers) 32.
- the outlet hole 28 of the tank 25 is formed at the center of the bottom of the tank 25 at a position corresponding to the inner side of the innermost cylindrical partition wall 26a.
- the space inside the innermost cylindrical partition wall 26a constitutes a part of the outlet member 12.
- the gas flowing into each gas chamber 32a, 32b, 32c, 32d passes through the space above all the gas chambers 32 in the tank 25 and the inside of the innermost cylindrical partition wall 26a, and the downstream side from the outlet hole 28. It flows into the calorie gas supply pipe 3. Therefore, it can be said that the outlet member 12 is composed of the portion of the tank 25 above each gas chamber 32, the inner side of the innermost cylindrical partition wall 26a, and the outlet hole 28.
- the outlet member 12 includes a tank portion including the outlet hole 28 that divides a space between the ceiling of the tank 25 and the upper end of each cylindrical partition wall 26, and the innermost cylindrical partition wall 26a.
- the gas that passes through the gas passages 32 merges at the outlet member 12 and is mixed there.
- a mixer or a stirring device is installed at the outlet member 12 (for example, the portion above the gas chamber 24 in the tank 25 or the inside of the innermost cylindrical partition wall 26a). Also good.
- the gas flowing out of the gas mixing device is time-mixed to suppress fluctuations in force. This will be described below.
- the gas that has flowed into all the gas passages at the same time that is, the gas having substantially the same caloric value, flows out from each gas passage after a different time, and merges and mixes at the outlet member 12.
- the gas flowing into the gas mixing device 31 is effectively time-diffused and the calorie fluctuation of the gas is suppressed.
- the volume ratio of the gas passages is an integer ratio, but the present invention is not limited to this configuration, and an arbitrary volume ratio can be selected. If necessary, some gas passages have the same volume.
- the gas passage constituent member, the inlet member, and the outlet member are not limited to the configurations shown in Figs. 4 and 5, and various suitable configurations can be adopted.
- the gas passage constituting member 36 in the gas mixing device 35 shown in FIG. 6 is divided into a plurality of gas passages (gas chambers) by dividing the inside of the tank 25 by a plurality of horizontal partition walls 37 spaced vertically. 38) is formed. Horizontal partition walls 37 are arranged at equal intervals, and all gas chambers 38 have substantially the same volume.
- Each gas chamber 38 has an inlet hole 27 at one end and an outlet hole 28 at the other end. The inlet hole 27 and the outlet hole 28 are not opposed to each other, and the outlet hole 28 is formed at a position away from the central axis of the inlet hole 27.
- the formation of the outlet hole 28 at a position deviating from the central axis of the inlet hole 27 is not limited to the gas passage component member 36 of FIG. It can be applied to tanks.
- the gas chamber 38 is not limited to a forceful structure defined by the horizontal partition walls 37.
- the gas chamber 38 may be partitioned by a partition wall extending in the vertical direction, vertically, horizontally, and horizontally. It may be partitioned into a shape. Moreover, you may divide radially like the cross section of a citrus fruit.
- the inlet member 11 is the same as that shown in Fig. 4, and is divided from the low-calorie gas supply pipe 3 on the upstream side and connected to each of the plurality of inlet holes 27, and the pipe 29 Is equipped with a flow control valve 30 installed in The flow rate of the gas flowing into each gas chamber 38 is made different by adjusting the opening degree of the flow control valve 30.
- the outlet member 12 is connected to the plurality of outlet holes 28, and is composed of a pipe 39 that is integrated and connected to the low-calorie gas supply pipe 3 on the downstream side. The gas flowing out of the gas chamber 38 with a time difference starts to mix in the integrated piping section 39.
- a mixer or stirrer may be installed at the outlet member 12 (eg, an integrated piping section) to facilitate gas mixing. Also in this gas path constituting member 36, as described for the gas mixing device 10 in FIG. 4, the inflowing gas is effectively time-diffused and the calorie fluctuation of the gas is suppressed.
- the gas flow rate flowing into each gas chamber is made substantially the same, and the volume of the gas chamber is set to be the same. They may be different from each other. In this case, it is not particularly necessary to install a flow control valve on the inlet member. Even in the case of the gas mixing device 35, as in the case of the gas mixing device 31 shown in FIG. 5, the inflowing gas is effectively time-diffused and the calorie fluctuation of the gas is suppressed.
- the shape of the tank 25 described above is not limited, and various shapes such as a polygonal cylindrical shape and a spherical shape can be adopted in addition to the cylindrical shape.
- the gas passage constituent members are not limited to the gas passage constituent members 23 and 33 in which a plurality of gas chambers are formed in one tank as shown in FIGS. It may be composed of a container.
- FIG. 7 shows a gas mixing device 40 having a gas passage constituting member 42 composed of a plurality of independent containers 41 as described above.
- Each container 41 constitutes a gas chamber (gas passage), and all have substantially the same volume.
- An inlet hole 27 is formed at the lower end (which may be the upper end or the side surface) of each container 41, and a gas outlet hole 28 is formed at the upper end (which may be the lower end or the side surface).
- the inlet member 11 is the same as that shown in Figs. 4 and 6, and a pipe 29 branched from the low-calorie gas supply pipe 3 on the upstream side and connected to each of the plurality of inlet holes 27, and this arrangement A flow control valve 30 is installed in each branched part of the pipe 29.
- the flow rate of the gas flowing into each gas chamber 41 is made different by adjusting the opening of the flow control valve.
- the outlet member 12 is the same as that shown in FIG. 6, and is connected to and integrated with the plurality of outlet holes 28.
- the pipe 39 is connected to the low-calorie gas supply pipe 3 on the downstream side. The gas flowing out of the gas chamber 41 with a time difference starts to mix in the integrated piping section 39.
- a mixer or stirrer may be installed at the outlet member 12 (eg, an integrated piping section) to facilitate gas mixing. Also in this gas mixing device 40, as described for the gas mixing device 10 in FIG. 4, the inflowing gas is effectively time-diffused and the calorie fluctuation of the gas is suppressed. In addition, since each gas passage is constituted by a single container force, the installation work of the partition wall for partitioning the gas chamber can be omitted, so that the manufacture becomes easy.
- the gas flow rates flowing into the containers are made substantially the same, and the volumes of the containers are mutually interchanged. It may be different. In this case, it is not particularly necessary to install a flow control valve on the inlet member. Even with such a gas mixing device, as described with respect to the gas mixing device 31 of FIG. 5, the time difference mixing of the flowing gas is performed, and the calorie fluctuation of the gas is suppressed.
- the shape of the container 41 is not limited, and various shapes such as a cylindrical shape, a polygonal cylindrical shape, and a spherical shape can be adopted. Since each gas passage is composed of one independent container, the volume of the container can be easily made different.
- Each container can be formed of, for example, metal pipes having different diameters or metal pipes having different lengths.
- the gas mixing device 43 shown in FIG. 8 is configured such that the gas passage constituting member 44 integrally binds the containers 41 shown in FIG. Except that the plurality of containers 41 are compactly bundled, the configuration is almost the same as that of the gas mixing device 40 shown in FIG. 7, so that the same members as those in FIG. Omitted. This gas mixing device 43 can save installation space.
- a gas mixing device 45 shown in FIG. 9 and FIG. 10 has a tank 46 provided with a perforated plate 47 having a large number of through holes 47a.
- FIG. 9 is a partially cutaway perspective view of the gas mixing device 45
- FIG. 10 is a longitudinal sectional view.
- An inlet hole 27 and an outlet hole 28 are formed in the peripheral wall of the tank 46, the upstream low calorie gas supply pipe 3 is connected to the inlet hole 27, and the downstream low calorie gas supply pipe 3 is connected to the outlet hole 28.
- the perforated plate 47 has a vertical direction so that the space inside the tank 46 is divided into a space on the inlet hole 27 side and a space on the outlet hole 28 side. It is arranged in the direction.
- the inlet hole 27, the outlet hole 28, and the force S tank 46 are formed so as to face each other, and the perforated plate 47 is orthogonal to a virtual straight line connecting the inlet hole 27 and the outlet hole 28.
- Force arranged vertically It is not limited to such a configuration.
- the inlet hole 27 and the portion of the tank 46 that connects the low calorie gas supply pipe 3 to the inlet hole 27 constitute an inlet member.
- the portion of the tank 46 that connects the low calorie gas supply pipe 3 to the hole 28 constitutes the outlet member.
- an imaginary straight line L (hereinafter referred to as the center of the inlet hole 27) connected to the inlet hole 27 of the low calorie gas supply pipe 3 from the center of the inlet hole 27 and extending in the direction of the central axis of the portion.
- a non-porous region 48 (indicated by a two-dot chain line in the figure). This non-porous region 48 is formed in order to prevent a part of the gas flowing in from the inlet hole 27 from reaching the outlet hole 28 in a very short time and allow the gas to stay in the tank 46 as long as possible. ing.
- the non-porous region 48 may be a range that is more than the force that is almost the same as the shape of the inlet hole 27 and the outlet hole 28 as an example.
- the tank 46 and the perforated plate 47 constitute a gas passage constituting member. That is, a large number of through holes 47a of the multi-hole plate 47 each constitute a gas passage.
- a large number of through holes 47a of the multi-hole plate 47 each constitute a gas passage.
- the gas is mixed with time difference in the space on the inlet hole side from the porous plate 47, and further mixed with time difference in the space on the outlet hole side after passing through the through hole 47a of the porous plate. Is made. Therefore, suppression of gas calorie fluctuation is effectively achieved.
- the perforated plate 47 may be installed inside the gas chambers 24, 32, 38 and the container 41 in the gas passage constituting members 23, 33, 36, 42, 44 shown in FIG. 4 and FIG. Les. By doing so, it is possible to mix the gases in each gas passage.
- FIG. 11 and FIG. 12 show the simulation of the time difference mixing of the gas in the gas mixing apparatus. The results are shown as a curve representing the relationship between the gas residence time and the cumulative gas flow rate. Both figures are based on a model that uses a tank as a gas passage component. The horizontal axis indicates the gas residence time (minutes) in the tank, and the vertical axis indicates the percentage of the gas that remains. The curve in the graph of Fig. 11 shows the state where the gas is completely mixed. That is, the gas flows into the inlet force tank, and at the same time, it is mixed with the gas that has been in the tank until then. These figures show the simulation results under the condition that the volume of the tank is 40000 m 3 and the flow rate of the inflowing gas is 280000 Nm 3 / hr.
- this graph indicates the ratio of the gas flowing out from the outlet at a predetermined time indicated on the horizontal axis, that is, the ratio to the gas volume of the entire tank.
- the number 1.0 on the vertical axis represents the gas volume of the entire tank.
- the value on the horizontal axis in Fig. 11 flows out from the outlet in 100 minutes (indicated by the symbol HI) of 500 minutes to 600 minutes (this indicates the elapsed time since entering the tank, ie, the residence time).
- the time difference mixing is ideal when the gas is mixed in the same ratio regardless of the elapsed time from the inflow, that is, the line shown in the graph is a straight line. However, this does not exist in reality. It is reasonable to consider the state where complete mixing is performed as shown in Fig. 11 as the state where the best time difference mixing is performed.
- Fig. 12 shows a simulation of time difference mixing of a gas modeled on the curve showing the state of complete mixing in Fig. 11 and the gas mixing device 45 incorporating the porous plate 47 shown in Figs. 9 and 10.
- a curve showing the result of the race is shown. Contrast with the above-mentioned completely mixed state In this way, the time-difference mixing of gases with the same conditions such as gas flow rate and tank volume is simulated.
- the complete mixing state described above is indicated by a solid line, and the case of using a gas mixing device 45 incorporating a porous plate is indicated by a broken line.
- a close curve is drawn even if it does not match the complete mixing state. In other words, it can be said that good time difference mixing is performed.
- the gas calorie fluctuation is also effectively suppressed in the gas mixing device 45.
- the gas mixing device 49 shown in Fig. 13 is a tank 46 in which two (or three or more) perforated plates 47 are arranged substantially in parallel with a space therebetween. is there. Therefore, three spaces partitioned by the perforated plate 47 are formed inside the tank 46. Compared with the gas mixing device 45 in FIG. 9, in this gas mixing device 49, further time-difference mixing is performed by the space between the two perforated plates 47, so that the calorie fluctuation of the gas can be more effectively suppressed. it can .
- the non-porous region 28 may be formed in the perforated plate on the outlet hole 28 side.
- FIG. 14 shows another gas mixing device 50.
- a tank 51 used as a gas holder in a conventional gas turbine facility is modified to be used as a gas calorie fluctuation suppressing device. That is, the inlet 27 and the outlet 28 are separately formed in the gas holder, and the upstream side low calorie gas supply pipe 3 and the downstream side low calorie gas supply pipe 3 are connected to the gas holder, respectively.
- the perforated plate 47 is installed in the same manner as the gas mixing device 45 in FIG.
- the gas holder is a device for monitoring the gas amount balance.
- the gas balance monitor and balance are intended to balance the amount of low calorie gas sent from the upstream side with the amount of gas consumed by the gas turbine.
- the gas balance monitor and balance are intended to balance the amount of low calorie gas sent from the upstream side with the amount of gas consumed by the gas turbine.
- the gas amount balance monitoring apparatus includes the tank 51, and a lid member 52 that is airtightly closed at the upper end opening of the tank 51 by a seal member 52a and the like and is arranged to be movable up and down in the tank. And an adjustment weight 52b connected to the lid member 52.
- the seal member 52 a is disposed in the gap between the lid member 52 and the inner peripheral surface of the tank 51. Weight of the lid member 52 and above The tank moves up and down by the balance between the total weight of the weight 52b and the push-down force due to the atmospheric pressure and the push-up force caused by the internal pressure of the tank 51. Therefore, the lid member 52 moves up and down in accordance with a change in the balance between the supply amount and consumption amount of low calorie gas. While monitoring the vertical movement of the lid member 52, measures such as outgassing of the system and reduction of the turbine load are taken.
- This gas holder is also used as a gas mixing device 50 for time difference mixing of low calorie gas.
- the height of the perforated plate 47 is made low so as not to interfere with the lid member 52 that moves up and down. Therefore, the force generated in the space 51a between the upper end of the multi-hole plate 47 and the lid member 52 when the lid member 52 is raised.
- This space 51a can also be considered as one of the plurality of gas passages. Also in this gas mixing device 50, good time difference mixing is performed by the same operation as described for the gas mixing device 45 in FIG. 9, and the fluctuation of the gas calorie is suppressed.
- FIG. 15 shows a tank 46 as a gas passage constituting member incorporating a porous plate 47, which is the same as the gas mixing device 45 of FIGS. 9 and 10.
- a tank 46 as a gas passage constituting member incorporating a porous plate 47, which is the same as the gas mixing device 45 of FIGS. 9 and 10.
- an inclined pipe 53 inclined continuously from the horizontal to the low calorie gas supply pipe 3 is interposed between the inlet hole 27 of the tank 46 and the low calorie gas supply pipe 3.
- the inclination angle ⁇ from the horizon is not limited. In this way, the gas inflow direction into the tank 46 is deviated from the position of the outlet hole 28.
- this inclined pipe 53 attachable to and detachable from the low calorie gas supply pipe 3 and the tank 46, it can be replaced with an inclined pipe having a different inclination angle.
- the use of the inclined pipe 53 does not form a non-porous region 48.
- a perforated plate through holes 47a are uniformly formed on the entire surface
- the direction of gas flow into the tank 46 is used as an outlet.
- the position force of the hole 28 is preferable because it can be kept away.
- the inclined tube 53 is not installed only in the gas mixing device incorporating the perforated plate 47.
- the outlet hole 28 may be removed from the extended line of the central axis of the inlet hole 27 of the gas passage by connecting to the pipe 29 constituting the inlet member shown in FIG. 4 and FIG.
- the direction of the inclined pipe 53 and the inclination angle from the central axis of the inlet hole should be selected in accordance with the gas passage.
- FIG. 16 shows a gas mixing device 50 using the same conventional gas holder as that shown in FIG. 14, but between the inlet hole 27 of the tank 51 and the low calorie gas supply pipe 3, gas A gas inflow device 54 for changing the inflow direction is provided.
- the gas mixing device 50 originally has the function of mixing the gas that has flowed into the inside thereof with time difference, but the gas inflow device 54 can change the mode of gas flow according to the vertical movement of the lid member 52 of the tank 51. The uniform mixing effect can be further improved.
- the gas inflow device 54 includes a housing 55 disposed between the tank inlet hole 27 and the low calorie gas supply pipe 3, and the housing 55. And a plurality of variable louvers 56 accommodated in the interior of the interior of the interior of the housing at intervals.
- Each variable louver 56 is arranged substantially horizontally, and its rotating shaft 56 a protrudes outside the housing 55.
- the protruding portion of the rotating shaft 56a can be rotated by known means such as an electric motor, a hydraulic motor, a pneumatic cylinder, a hydraulic cylinder, and the louver 56 can be swung in the vertical direction.
- the louver 56 is swung in the vertical direction, the gas inflow direction can be changed accordingly.
- the number of louvers to be installed is not limited and may be one or more.
- an inclination direction indicator 56b is installed on the rotation shaft 56a protruding to the outside of the housing 55, and the inclination direction of the louver 56 from the outside of the gas inflow device 54.
- the gas inflow direction can be displayed.
- the inclination direction of the louver 56 may be detected by a detector (not shown), and the detection signal may be transmitted to the control device 5 and displayed on a remote display device (not shown) based on the detected signal.
- a see-through window may be formed in the housing 55 so that the inclination direction of the louver 56 can be confirmed from the outside.
- a position signal of the lid member 52 is input to the control device 5, and the position signal is It is possible to select the optimal gas inflow direction. For example, in order to tilt the gas inflow direction further upward when the lid member 52 is raised, the louver 56 may be swung upward so that the elevation angle from the horizontal is increased. When the lid member 52 is lowered, the louver 56 may be swung so that the elevation angle from the horizontal direction becomes small in order to incline the gas inflow direction downward from the current direction.
- the low calorie gas supply pipe 3 on the upstream side and the downstream side of the gas mixing device Each has an inlet calorimeter 8 and an outlet calorimeter 9 (see Figure 1). Since the calorimeters 8 and 9 continuously measure the gas calorie value, the calorie fluctuation in the low calorie gas supply pipe 3 on the upstream side and the downstream side can be detected. Since the control device 5 receives a signal indicating the gas calorie fluctuation on each of the upstream side and the downstream side, the controller 5 can detect the degree of the effect of suppressing the calorie fluctuation by the gas mixing device by comparing them.
- control device 5 calculates the deviation between the set value of the calorie fluctuation suppression level and the detected value, and the gas inflow device 54 so as to support this deviation (so that the uniform time difference mixing effect is maximized).
- the gas inflow angle (inclination angle of louver 56) is controlled.
- This gas inflow device 54 is not limited to the internal volume fluctuation type gas mixing device 50, but also applies to fixed volume type gas mixing devices 10, 31, 36, 40, 43, 45, 49 where the ceiling does not move up and down. can do. Then, the force S can be measured by continuously measuring the calorie value by the force bolometers 8 and 9 while changing the inclination angle of the louver 56 by the control device 5 and monitoring the calorie fluctuation suppressing effect. Then, it is possible to know the optimum inclination angle of the louver 56 for time difference mixing.
- the gas inflow device 54 in FIG. 16 is not limited to a power-powered configuration in which a variable louver 56 is accommodated inside a housing 55 installed outside the tank.
- a variable louver 56 may be installed in a position close to the inlet in the tank so that it can be swung from outside the tank without providing a housing.
- Two inlet holes 27 and two outlet holes 28 may be provided on the peripheral wall (may be the bottom of the tank) of the tank 51 shown in FIG. That's it.
- a pipe 57 having a branch pipe 57a branched from the low calorie gas supply pipe 3 toward each inlet hole 27, and the above branch pipe 57a The flow control valve (or stop valve) 59 installed in is installed.
- a pipe 58 having a branch pipe 58 a integrally connected to the low calorie gas supply pipe 3 from each outlet hole 27, and the above branch A flow control valve 59 installed in the pipe 58a is provided. Only one outlet hole 28 may be formed, and only a plurality of inlet holes 27 may be formed. [0115] With the control device 5, the inlet-side flow control valve 59 is appropriately selected to open and close, or the flow rate is adjusted to change the gas inflow position into the tank 51, or the gas flow at the gas inflow position. The amount can be varied. In this way, the control device 5 performs control so as to optimize the mode of gas flow in the tank 51.
- This optimal mode is based on a data set created based on a lot of operating data, and applies the data set that is most suitable for similar operating conditions (gas calorie, gas flow rate, gas composition, residence time in tank, etc.) be able to.
- the control device 5 calculates the deviation between the set value of the calorie fluctuation suppression level and the actually measured fluctuation suppression level based on the detection values of both calorimeters 8 and 9, so that this deviation can be applied (uniform Adjust the flow rate and change the gas flow position so that the time difference mixing effect is maximized.
- a gas mixing device 60 shown in FIG. 19 includes a tank 46 in which a perforated plate 47 is built, similar to the gas mixing device 45 of FIG. However, as an inlet member for connecting the inlet hole 27 and the low calorie gas supply pipe 3, a pipe 62 to which an inert gas supply pipe 61 is connected is disposed.
- the inert gas supply pipe 61 is for introducing an inert gas for reducing the temperature of the low calorie gas into the tank 46.
- An inert gas supply pipe 61 is inserted and connected to the inside of the pipe 62, and its tip is opened so that the inert gas is mixed into the flow of low calorie gas. Therefore, this pipe 62 is configured as a double pipe.
- the flow rate of the inert gas is preferably lower than that of the low calorie gas from the viewpoint of improving the mixing property.
- a dilution gas supply pipe 4 for supplying a dilution gas such as an inert gas is disposed downstream of the gas mixing device 10.
- a dilution gas such as an inert gas
- the purpose is to reduce the caloric value by gas.
- the dilution gas necessary for lowering the average calorie value is introduced into the gas mixing device 10 in advance, the calorie control performed using the dilution gas supply pipe 4 can be simplified. It is advantageous because it becomes unnecessary.
- the supply of the inert gas into the tank 46 is not limited to the configuration shown in FIG.
- the inert gas supply pipe 61 may be directly connected to the tank 46 independently of the low calorie gas supply pipe 3.
- the installation target of the inert gas supply pipe 61 is not limited to the gas mixing device (see FIG. 9 and FIG. 13-19) with the porous plate 47 built-in.
- the present invention can also be applied to the gas mixing device shown in Fig. 4 and Fig. 8.
- the inert gas introduced into the gas mixing apparatus described above includes waste nitrogen emitted from oxygen production plants used in the blast furnace method and direct reduced iron methods such as the FIN EX method and the COREX method, and It is preferable to recover and use waste nitrogen containing a small amount of oxygen discharged from a nitrogen production plant attached to the oxygen production plant. This is because the operation cost is extremely low because a large amount of discarded nitrogen is recovered and used.
- oxygen is used as the reducing agent, so it is essential to install an oxygen production plant that produces large amounts of oxygen.
- Oxygen is also used in the blast furnace method, so an oxygen production plant will be used even if there is a difference in scale.
- Oxygen production plants produce oxygen by separating nitrogen from air, but the exhaust gas after separating oxygen is usually released to the atmosphere as waste nitrogen.
- there is also a lot of power to produce high-purity nitrogen by adding a nitrogen production plant to the oxygen production plant. Even in this case, nitrogen containing a small amount of oxygen is released to the atmosphere as waste nitrogen.
- Such waste nitrogen is about 95-98% by volume of nitrogen gas and 2-5 of oxygen.
- highly purified nitrogen may be used.
- FIG. 20 to FIG. 24 exemplify various piping modes when the above-described gas mixing device is connected to the low calorie gas supply pipe 3 in the low calorie gas supply facility 1.
- the piping is not limited to the range shown in these drawings.
- FIG. 20 shows a gas mixing device 50 installed in parallel to the low calorie gas supply pipe 3, that is, a bypass pipe attached to the low calorie gas supply pipe 3.
- a gas mixing device 50 is shown.
- This gas mixing device 50 is also used as a gas calorie fluctuation suppressing device by slightly changing the structure of a gas holder installed in an existing low calorie gas supply facility. Therefore, the internal volume variation type gas mixing apparatus 50 shown in FIGS. 14 and 16 can be suitably arranged as shown in FIG. In this case, since the outlet hole 28 is formed substantially at the center of the bottom of the tank 51, the porous plate inside the tank 51 is disposed at a position slightly closer to the inlet hole 27 than the central axis of the tank 51.
- the gas holder installed in the conventional low calorie gas supply facility has one communication pipe for the low calorie gas supply pipe 3 (corresponding to the outlet pipe indicated by reference numeral 63 in FIG. 20). Only connected by. This single communication pipe doubles as an entrance. Since the gas holder only needs to balance the supply and demand of gas in the low calorie gas supply pipe, it is sufficient to communicate with the low calorie gas supply pipe with a single communication pipe.
- the above-mentioned communication pipe 63 as an outlet pipe is connected to the outlet member 12 of the tank 51, and in addition to this outlet pipe 63, the low-calorie gas supply pipe 3 is newly connected to the upstream side.
- the inlet pipe 64 is connected to the inlet member 11 of the tank 51.
- the upstream side inlet pipe 6 4 and the outlet pipe 63 constitute the bypass pipe.
- the upstream side inlet pipe 64 is connected to the upstream side from the connection with the outlet pipe 63 of the low calorie gas supply pipe 3.
- the upstream side inlet pipe 64 is provided with a fan 65 as a gas pressure feeding device for feeding low calorie gas into the tank 51. Therefore, a part of the low calorie gas supplied is upstream inlet piping.
- the low calorie gas flows into the tank 51 through 64, and the low calorie gas is mixed with time in the tank 51, and the same amount of gas returns from the tank 51 to the low calorie gas supply pipe 3 through the outlet pipe 63. Since the upstream side inlet pipe 64 is connected to the upstream side of the low calorie gas supply pipe 3 from the outlet pipe 63, the fan 65 can be omitted by piping design taking pressure loss into consideration. The same applies to the upstream side inlet pipe 64 shown in FIGS.
- FIG. 21 shows a gas mixing device 66 using another gas amount balance monitoring device that can be used as a calorie fluctuation suppressing means.
- This gas mixing device 66 has a more economical configuration as a gas quantity balance monitoring device, and an inlet member 11 and an outlet member 12 are respectively connected by an upstream side inlet pipe 64 and an outlet pipe (communication pipe) 63. It has an airtight tank 67 connected to the low calorie gas supply pipe 3.
- the tank 67 contains a porous plate (not shown), and a pressure detection device 68 is installed to constantly monitor the internal pressure of the tank 67. When the detected pressure reaches the upper limit, the control device 5 issues a command to increase the gas consumption in the facility, and balances the gas supply and demand.
- This gas mixing device 66 also suppresses the calorie fluctuation of a part of the low calorie gas supplied to the gas turbine through the low calorie gas supply pipe 3.
- FIG. 22 also shows a gas mixing device 50 installed in parallel to the low calorie gas supply pipe 3.
- an inlet pipe 69 and an outlet pipe 63 are connected between the inlet member 11 and outlet member 12 of the tank 51 and the low calorie gas supply pipe 3, respectively.
- the inlet pipe 69 is connected to the downstream side of the connection portion between the low calorie gas supply pipe 3 and the outlet pipe 63. Therefore, this inlet pipe 69 is referred to as a downstream inlet pipe 69.
- the downstream inlet pipe 69 is provided with a fan 65 for sending low calorie gas to the tank 51.
- the low calorie gas is It is sent into the tank 51 through the pipe 69, mixed with a time difference, and flows out from the outlet member 12 to the outlet pipe 63.
- a part of the low calorie gas in which calorie fluctuation is suppressed circulates, so that effective time difference mixing is performed.
- the downstream inlet pipe 69 The longer the length, the longer the time difference mixing in the tank 51 is realized.
- FIG. 23 also shows a gas mixing device 50 installed in parallel to the low calorie gas supply pipe 3.
- an outlet pipe 63 and an upstream inlet pipe 64 having a fan 65 are connected between the tank 51 and the low calorie gas supply pipe 3 as shown in the figure. That is, the upstream side inlet pipe 64 is connected to the inlet member 11 of the tank 51, and the outlet pipe 63 is connected to the outlet member 12.
- a further inlet member 70 is formed in the tank 51, and a downstream inlet pipe 69 is connected to the inlet member 70.
- the downstream inlet pipe 69 is connected to the downstream side from the connection with the outlet pipe 63 in the low calorie gas supply pipe 3.
- the downstream inlet pipe 69 is provided with a fan 65 for sending low calorie gas to the tank 51.
- the positions of the upstream inlet pipe 64 and the downstream inlet pipe 69 connected to the tank 51 are close to each other.
- a part of the low calorie gas is pumped into the tank 51 from the upstream side of the low calorie gas supply pipe 3 through the upstream side inlet pipe 64, and at the same time downstream from the downstream side of the low calorie gas supply pipe 3 A part of the low calorie gas is pumped through the inlet pipe 69, mixed with time, and flows out from the outlet member 12 to the outlet pipe 63. That is, since a part of the low calorie gas in which the calorie fluctuation is suppressed circulates, the time difference mixing for a long time is realized in the tank 51.
- the downstream inlet pipe 69 is connected to the inlet member 70 of the tank 51 from the downstream side of the low calorie gas supply pipe 3.
- a return pipe connected to the upstream side of the connection with the upstream side inlet pipe 64 of the calorie gas supply pipe 3 may be connected.
- the piping configuration for connecting the gas mixing device to the low calorie gas supply facility 1 shown in Fig. 20 to Fig. 23 is the force suitable for the gas mixing devices 50 and 66 using the conventional gas holders. It is also possible to apply to the gas mixing apparatus.
- the tank 46 of the gas mixing device 45 shown in FIG. 24 has one outlet member 12 and two types of inlet members 11 and 70.
- One inlet member 11 is connected to the upstream low calorie gas supply pipe 3
- the outlet member 12 is connected to the downstream low calorie gas supply pipe 3
- the other A return pipe 71 connected to the downstream-side low calorie gas supply pipe 3 is connected to the inlet member 70.
- the two inlet members 12, 70 are formed close to each other.
- the return pipe 71 is provided with a fan 65 for sending low calorie gas into the tank 46.
- the return pipe 71 is connected to the inlet member 70 of the tank 46 from the downstream side of the low calorie gas supply pipe 3, but may be connected to the upstream side of the tank 46 in the low calorie gas supply pipe 3 from the downstream side.
- the mode of the piping connecting the gas mixing device to the low calorie gas supply facility 1 shown in Fig. 24 is a force suitable for the gas mixing device 45 shown in Figs. 9 and 10 and the other gases described above. It is also possible to apply to a mixing device.
- FIG. 25 shows the boiler equipment.
- the boiler equipment is provided with a boiler 73 and a low calorie gas supply equipment 72 for supplying the boiler 73 with low calorie gas as fuel.
- the boiler 73 is used for generating steam by burning gas with a burner and using it for power generation, or for supplying steam used for other purposes.
- This low calorie gas supply facility 72 has removed the equipment installed in the low calorie gas supply piping 3 and the mixed gas supply piping 14 on the downstream side of the gas mixing device 10 from the low calorie gas supply facility 1 shown in FIG. Is. That is, the low calorie gas supply facility 72 shown in FIG. 25 includes a low calorie gas supply pipe 74 that supplies the low calorie gas generated in the direct reduced iron facility S to the boiler 73 as fuel.
- the low-calorie gas supply pipe 74 includes a dust collector 7 for removing dust from the low-calorie gas sent directly from the reduced iron facility S, a gas mixer 10 for primary storage of the low-calorie gas, and a gas mixer 10 On the upstream side and downstream side, calorific value detection devices 8 and 9 for detecting the calorific value of low caloric gas, and a flow meter 75 for measuring the supply amount of low caloric gas are installed.
- the gas mixing device installed in the low calorie gas supply facility 72 for the boiler not only the gas mixing device 10 shown in Fig. 4 but also all the gas mixing devices described above can be applied.
- the This low calorie gas supply facility 72 has no dilution gas supply facility. This is because it is desirable for boilers to suppress calorie fluctuation itself by a gas mixing device in order to obtain a stable output.
- the calorific value that is raised by the calorie fluctuation of low calorie gas mentioned above causes a big problem. It is not a thing.
- Fig. 25 only the boiler 73 is installed as a combustion facility to which low calorie gas is supplied by the low calorie gas supply facility 72. However, it is not limited to a powerful configuration. Along with the boiler 73, another combustion facility may be installed along with the gas turbine 2 (Fig. 1). For example, when the gas turbine 2 and the boiler 73 shown in FIG. 1 are installed, the portion between the calorimeter 9 and the flow meter 13 in the low calorie gas supply pipe 3 in FIG. 1 is downstream of the calorimeter 9 in FIG. The low calorie gas supply pipe 74 from the side to the boiler 73 may be connected so as to be branched.
- the gas turbine and the boiler are exemplified as the combustion equipment.
- the combustion equipment in the present invention is not limited to the gas turbine and the boiler.
- the gas calorie fluctuation suppressing device and the low calorie gas supply facility described here can also be applied to other combustion facilities such as a heating furnace and an incinerator.
- the fuel gas supply facility of the present invention includes not only the dilution gas supply facility. Instead of this, a heating gas supply facility may be provided together with the dilution gas supply facility.
- the fuel gas supply facility described here is characterized by including the gas calorie fluctuation suppressing device (gas mixing device) exemplified with the above-described embodiment.
- the heat-increasing gas supply facility is a medium-high fuel gas that prevents the calorific value of the fuel gas from decreasing in order to adjust it within the allowable fluctuation range of the gas characteristics of the combustion equipment such as a gas turbine boiler. It is a facility that mixes caloric gas. Examples of medium-high calorie gas include natural gas and coke oven gas (COG).
- the force exemplified as a by-product gas generated by the direct reduction iron-making method as the low calorie gas to be used is not limited to this.
- Low calorie gas includes blast furnace gas (BFG), converter gas (LDG), coal bed gas (Coal mine gas, expressed as CMG), by-product gas generated by smelting reduction ironmaking, GTL (Gas-to-Liquid) Tail gas generated in the process, oil sand force, by-product gas generated during the oil refining process, gas generated by incineration of dust using plasma, and general waste containing garbage are stored
- BFG blast furnace gas
- LDG converter gas
- CMG coal bed gas
- GTL Gas-to-Liquid Tail gas generated in the process
- oil sand force by-product gas generated during the oil refining process
- gas generated by incineration of dust using plasma and general waste containing garbage are stored
- methane gas Lithane gas
- low-calorie gas such as by-product gas generated by chemical reaction of other similar raw materials
- the calorie fluctuation of low calorie gas can be suppressed.
- Heat reduction by heat reduction or heat-increasing gas is effective and easy. In some cases, heat reduction by dilution gas or heat increase by heat-increasing gas is not necessary. It is also acceptable to construct a device that suppresses fluctuations in gas calories by using existing gas holders.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2005/000977 WO2006080054A1 (en) | 2005-01-26 | 2005-01-26 | Gas calorie variation suppressing device, fuel gas supply facility, gas turbine facility, and boiler facility |
JP2007500367A JP4481330B2 (en) | 2005-01-26 | 2005-01-26 | Gas calorie fluctuation suppression device, fuel gas supply equipment, gas turbine equipment and boiler equipment |
KR1020077014967A KR100875498B1 (en) | 2005-01-26 | 2005-01-26 | Gas calorie fluctuation suppressor, fuel gas supply equipment, gas turbine equipment and boiler equipment |
BRPI0520608-1A BRPI0520608A2 (en) | 2005-01-26 | 2005-01-26 | gas calorie fluctuation suppression device, fuel gas supply system, gas turbine system and boiler system |
CNB2005800470631A CN100549391C (en) | 2005-01-26 | 2005-01-26 | Heat release in gas region variation suppressing, fuel gas supply equipment, gas-turbine plant and boiler equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2005/000977 WO2006080054A1 (en) | 2005-01-26 | 2005-01-26 | Gas calorie variation suppressing device, fuel gas supply facility, gas turbine facility, and boiler facility |
Publications (1)
Publication Number | Publication Date |
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WO2006080054A1 true WO2006080054A1 (en) | 2006-08-03 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/000977 WO2006080054A1 (en) | 2005-01-26 | 2005-01-26 | Gas calorie variation suppressing device, fuel gas supply facility, gas turbine facility, and boiler facility |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP4481330B2 (en) |
KR (1) | KR100875498B1 (en) |
CN (1) | CN100549391C (en) |
BR (1) | BRPI0520608A2 (en) |
WO (1) | WO2006080054A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009108913A (en) * | 2007-10-30 | 2009-05-21 | Tokyo Gas Co Ltd | Liquefied fuel gas supply apparatus |
JP2010281319A (en) * | 2009-06-02 | 2010-12-16 | General Electric Co <Ge> | System and method for controlling calorie content of fuel |
JP2013053525A (en) * | 2011-08-31 | 2013-03-21 | Mitsubishi Heavy Ind Ltd | Fuel mixing tank and gas turbine power generation system including the same |
JP2013119818A (en) * | 2011-12-08 | 2013-06-17 | Mitsubishi Heavy Ind Ltd | Gas turbine facility |
EP3571443B1 (en) | 2018-10-05 | 2020-12-02 | Sensirion AG | Device for regulating a mixing ratio of a gas mixture |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112240234B (en) * | 2020-10-21 | 2021-08-31 | 安徽天沃重工机械有限公司 | Diesel engine with exhaust purification effect for agricultural machinery |
Citations (3)
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JPH09317499A (en) * | 1996-05-28 | 1997-12-09 | Kawasaki Steel Corp | Control method for blast furnace gas monofuel combustion gas turbine |
JP2003293860A (en) * | 2002-04-05 | 2003-10-15 | Takuma Co Ltd | Methane fermentation treatment system and methane fermentation treatment method |
JP2004225117A (en) * | 2003-01-23 | 2004-08-12 | Jfe Steel Kk | Method for utilizing by-produced gas in iron works |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH10266899A (en) * | 1997-03-26 | 1998-10-06 | Tokyo Gas Co Ltd | Pressure fluctuation absorber and fluid consumption device |
BRPI0419147B1 (en) * | 2004-12-27 | 2015-12-01 | Kawasaki Heavy Ind Ltd | gas calorie fluctuation suppression device, fuel gas supply system, gas turbine system and boiler system |
-
2005
- 2005-01-26 CN CNB2005800470631A patent/CN100549391C/en not_active Expired - Fee Related
- 2005-01-26 JP JP2007500367A patent/JP4481330B2/en active Active
- 2005-01-26 WO PCT/JP2005/000977 patent/WO2006080054A1/en not_active Application Discontinuation
- 2005-01-26 KR KR1020077014967A patent/KR100875498B1/en active IP Right Grant
- 2005-01-26 BR BRPI0520608-1A patent/BRPI0520608A2/en active Search and Examination
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09317499A (en) * | 1996-05-28 | 1997-12-09 | Kawasaki Steel Corp | Control method for blast furnace gas monofuel combustion gas turbine |
JP2003293860A (en) * | 2002-04-05 | 2003-10-15 | Takuma Co Ltd | Methane fermentation treatment system and methane fermentation treatment method |
JP2004225117A (en) * | 2003-01-23 | 2004-08-12 | Jfe Steel Kk | Method for utilizing by-produced gas in iron works |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009108913A (en) * | 2007-10-30 | 2009-05-21 | Tokyo Gas Co Ltd | Liquefied fuel gas supply apparatus |
JP2010281319A (en) * | 2009-06-02 | 2010-12-16 | General Electric Co <Ge> | System and method for controlling calorie content of fuel |
JP2013053525A (en) * | 2011-08-31 | 2013-03-21 | Mitsubishi Heavy Ind Ltd | Fuel mixing tank and gas turbine power generation system including the same |
JP2013119818A (en) * | 2011-12-08 | 2013-06-17 | Mitsubishi Heavy Ind Ltd | Gas turbine facility |
EP3571443B1 (en) | 2018-10-05 | 2020-12-02 | Sensirion AG | Device for regulating a mixing ratio of a gas mixture |
EP3760926A1 (en) * | 2018-10-05 | 2021-01-06 | Sensirion AG | Device for regulating a mixing ratio of a gas mixture |
Also Published As
Publication number | Publication date |
---|---|
JP4481330B2 (en) | 2010-06-16 |
JPWO2006080054A1 (en) | 2008-06-19 |
CN100549391C (en) | 2009-10-14 |
KR20070086819A (en) | 2007-08-27 |
BRPI0520608A2 (en) | 2009-09-29 |
CN101107434A (en) | 2008-01-16 |
KR100875498B1 (en) | 2008-12-22 |
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