WO2006028144A1 - ポリプロピレン樹脂組成物及びその製造方法 - Google Patents
ポリプロピレン樹脂組成物及びその製造方法 Download PDFInfo
- Publication number
- WO2006028144A1 WO2006028144A1 PCT/JP2005/016438 JP2005016438W WO2006028144A1 WO 2006028144 A1 WO2006028144 A1 WO 2006028144A1 JP 2005016438 W JP2005016438 W JP 2005016438W WO 2006028144 A1 WO2006028144 A1 WO 2006028144A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- talc
- polypropylene resin
- compression
- resin composition
- weight
- Prior art date
Links
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 77
- -1 Polypropylene Polymers 0.000 title claims abstract description 76
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 59
- 239000011342 resin composition Substances 0.000 title claims abstract description 52
- 230000008569 process Effects 0.000 title abstract description 9
- 229910052623 talc Inorganic materials 0.000 claims abstract description 146
- 239000000454 talc Substances 0.000 claims abstract description 144
- 238000007906 compression Methods 0.000 claims abstract description 72
- 230000006835 compression Effects 0.000 claims abstract description 72
- 230000005484 gravity Effects 0.000 claims abstract description 44
- 238000004898 kneading Methods 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 31
- 229920005989 resin Polymers 0.000 claims abstract description 31
- 239000002245 particle Substances 0.000 claims abstract description 27
- 238000007872 degassing Methods 0.000 claims abstract description 25
- 238000001125 extrusion Methods 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
- 239000005977 Ethylene Substances 0.000 claims description 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 16
- 230000000704 physical effect Effects 0.000 claims description 15
- 238000007873 sieving Methods 0.000 claims description 15
- 229920001384 propylene homopolymer Polymers 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 229920001400 block copolymer Polymers 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 abstract description 8
- 239000011256 inorganic filler Substances 0.000 abstract description 8
- 229910003475 inorganic filler Inorganic materials 0.000 abstract description 8
- 238000013329 compounding Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 230000002411 adverse Effects 0.000 abstract description 4
- 241000519995 Stachys sylvatica Species 0.000 description 23
- 238000011156 evaluation Methods 0.000 description 12
- 238000000465 moulding Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 6
- 238000005469 granulation Methods 0.000 description 6
- 230000003179 granulation Effects 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- OJJLEPPNZOMRPF-UHFFFAOYSA-J dimagnesium;tetrachloride Chemical compound Cl[Mg]Cl.Cl[Mg]Cl OJJLEPPNZOMRPF-UHFFFAOYSA-J 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 229940114940 disilver oxide Drugs 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- CENHPXAQKISCGD-UHFFFAOYSA-N trioxathietane 4,4-dioxide Chemical compound O=S1(=O)OOO1 CENHPXAQKISCGD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0013—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor using fillers dispersed in the moulding material, e.g. metal particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
- B29L2031/3008—Instrument panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3044—Bumpers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Definitions
- the present invention relates to a polypropylene resin composition containing talc and a method for producing the same, and more particularly to a polypropylene resin composition containing talc having excellent mechanical properties and a method for producing the same economically. It is.
- Patent Document 1 discloses a degassed compressed talc having a compression ratio of more than 3.0, and an effect that the dispersion state of talc is improved by using it and melt kneading with propylene resin.
- the kneader used in the examples (CIM-90 manufactured by Nippon Steel Works) has a screw diameter of about 90 mm, and is used in a recent enlargement facility (for example, Patent Document 2). In this case, the screw diameter of 320 mm is used), and it has not been verified whether the talc is dispersed in the desired state.
- Patent Document 1 Japanese Patent Laid-Open No. 4-306261
- Patent Document 2 JP 2002-302554 A (Claim 1, Claim 6)
- the present invention is derived from kneading a large amount of resin in a short time when actually manufactured with a twin-screw kneader of a scale used in a commercial production plant.
- a new problem is that inorganic fillers are poorly dispersed (white spots are generated) even if the compounding is not a problem in relatively small-scale kneaders such as CIM-90.
- degassing compression talc produced by a conventionally known method is free from clumps due to compression unevenness generated during degassing compression. Based on talc dispersion failure while being inline compounded by using specific degassed compression talc that has the feature that it has a high compression ratio and few compressed masses that are hard to collapse The inventors have found that a talc-containing polypropylene resin composition having no white spots can be obtained, and completed the present invention.
- Deaerated compression talc force 2 The polypropylene resin composition according to 1 above, wherein the proportion of the component having a particle diameter of greater than 2.8 mm is 0.3% by weight or less.
- polypropylene resin is a propylene′ethylene block copolymer or propylene homopolymer having an ethylene content of 25% by weight or less and an MFR of 3 to 300 gZlO.
- Polypropylene resin composition according to 1.
- A Force specific gravity 0.3 to 1.0, compressibility 3 obtained by degassing and compressing talc with an average particle size of 0.1 to 12 / ⁇ ⁇ and bulk specific gravity of 0.1 to 0.5
- B A method for producing a polypropylene resin composition containing polypropylene resin, wherein the polypropylene resin and the degassing agent are placed in an extruder disposed downstream of the polymerization reactor for producing the polypropylene resin.
- a method for producing a polypropylene resin composition comprising supplying gas-compressed talc and melt-kneading.
- degassing and compressing talc having an average particle size of 0.1 to 12 / ⁇ ⁇ and a force specific gravity of 0.1 to 0.5, a force specific gravity of 0.3 to 1.0, and a compression ratio of 3.1 to 7.
- Degassed and compressed talc 0.
- Degassed and compressed talc containing less than 15% by weight of components of 1,000 m or more when sieved by the low tap method. The invention's effect
- FIG. 1 is a diagram for explaining an example of a talc degassing compression apparatus.
- the present invention is a talc-containing polypropylene resin composition containing (A) degassed compressed talc and (B) polypropylene resin.
- A degassed compressed talc
- B polypropylene resin
- the degassed and compressed talc used in the present invention is obtained by degassing and compressing talc having an average particle size of 0.1 to 12 m and a force specific gravity of 0.1 to 0.5, and a specific gravity of 0.3 to 1 is obtained.
- Compressed talc with a compression ratio of 3.1 to 7.0, and 1,000 or more components, when sifted by the low-tap method, are less than 15% by weight.
- the component of m or more is preferably 20% by weight or less, and if necessary, the proportion of the component having a particle size of more than 2.8 mm is 0.3% by weight or less.
- the average particle size of the talc before being deaerated and compressed for use in the present invention is 0.1 to 12 / ⁇ ⁇ , preferably 0.1 to 10 ⁇ m, and more preferably 2 to 8 ⁇ m.
- the average particle diameter exceeds the above-mentioned regulation, the flexural modulus of the product obtained by molding a polypropylene resin composition obtained by melting and kneading these talc with a small increase in mechanical strength due to talc decreases. There is an inconvenience.
- the average particle size is a value obtained from a particle size value of a cumulative amount of 50% by weight obtained by reading a particle size cumulative distribution curve force measured by a laser method measuring instrument (for example, LA900 manufactured by Horiba, Ltd.).
- the specific gravity of the talc before deaeration and compression used in the present invention is 0.1 to 0.5, preferably 0.1 to 0.35, and particularly preferably 0 to 0. 12-0. 25. Further, the specific gravity of the talc after deaeration and compression used in the present invention is 0.3 to 1.0, preferably 0.4 to 0.9, and particularly preferably 0.45 or more. The range does not exceed 0.6. When the strength specific gravity exceeds this range, a lump based on uneven compression tends to occur, which is not preferable. Conversely, force specific gravity is If it is less than this range, the amount of air brought into the twin-screw kneader at the time of melt-kneading increases, and this adversely affects the productivity.
- the force specific gravity is a value measured based on JIS K-6720.
- the compression ratio of the degassed and compressed talc used in the present invention is 3.1 to 7.0, preferably 3.1 to 6.5, and particularly preferably 3.2 to 5.5. It is. If the compression rate is outside the lower limit of the above specified range, the amount of air brought into the twin-screw kneader during melt kneading increases, which is not preferable because of inconvenience in productivity such as a feed net. On the other hand, if the above specified upper limit is not reached, there will be inconvenience that lumps based on uneven compression occur and white spots based on talc aggregation immediately occur in the molded product.
- the compression ratio is a value obtained by dividing the force specific gravity before deaeration compression by the force specific gravity after deaeration compression.
- the component of 1,000 / zm or more when sieved by the low-tap method of degassed and compressed talc used in the present invention is 15% by weight or less, preferably 13% by weight or less, more preferably 10% by weight or less.
- the component strength of 500 m or more is 5% by weight or less, preferably 40% by weight or less, more preferably 35% by weight or less.
- the amount of propylene resin composition extruded per hour when the component of 1,000 m or more exceeds 15% by weight when sieving by the low tap method is preferred. It is not preferable to form pellets when granulated with a large kneader that exceeds 1, OOOkg / hr because white spots are formed.
- the low-tap method is a low-tap type sieve shaker with a diameter of 200 mm ⁇ , a depth of 45 mm, and a mesh of 30 mesh (500 m sieve) and a 16 mesh of the same diameter (1000 m sieve).
- This is a method in which 100g of talc is placed on the top mesh and placed on the top mesh and shaken for 3 minutes under the conditions of a sieve width of 25mm, a shaking speed of 290rpm, and a hammer hitting speed of 156rpm.
- the value obtained by the intensive method has significance as a measure of the amount of large talc mass causing the white spot of the molded product and the dispersibility of the talc mass during kneading.
- the degassed and compressed talc used in the present invention has a high compressibility, and the amount of coarse powder of 1,000 ⁇ m or more measured by the above-mentioned low tap method is 15% by weight or less. Force Specify the amount of ingredients according to the ⁇ improved sieving method '' with improved measurement accuracy as required. Can do.
- the component of 500 m or more by the improved sieving method of degassed and compressed talc used in the present invention is preferably 20% by weight or less, more preferably 10% by weight or less, and further preferably 5% by weight or less. . If these amounts are not within the above range, white spots are generated when melt kneading with a large kneader. In order to reduce lumps based on these compression irregularities, it is important to highly control the conditions for degassing and compressing talc.
- the improved sieving method is the condition that the diameter is 150mm ⁇ , the screen width is 20cm, and the number of shaking is 60 times Z. This is a method for measuring components of 500 m or more when shaken for 3 minutes while preventing clogging.
- the improved sieving method has a characteristic that the sieve amplitude is larger than that of the low-tap method, but the number of shakes is small. Therefore, the impact energy when the lumps collide with each other or when the lumps collide with the sieve wall is large.For example, when the wetness of the powder is high, the strength of the lumps is high. When the amount of powder increases apparently, it has the significance of preventing the accuracy of the test value from being reduced.
- the value obtained by the intensive method has significance as a measure of the amount of large talc mass that causes white spots of the molded product and the dispersibility of the talc mass during kneading.
- the proportion of the component (A) having a degassing compression talc force particle size greater than 2.8 mm is 0.3% by weight or less, preferably 0.1% by weight or less. Viewpoint power to prevent generation is preferable.
- Degassed and compressed talc with a particle size of more than 2.8mm and a proportion of 0.1% by weight or less can be obtained by removing the coarse powder (2.8mm or more) after degassing and compression once. it can.
- Examples of the method for removing the coarse powder include a method using a relatively coarse mesh and applying a sieve that does not significantly impair the compression structure.
- the size of the sieve mesh at this time is ⁇ , specifically ⁇ , 6.5 (mesh 2.8 mm) to 26 mesh (mesh 600 m), preferably ⁇ 7.5 (sieve 2. 36 mm) It is in the range of ⁇ 22 mesh (sieve 710 m), more preferably 8.6 (mesh 2. Omm;) to 18.5 mesh (mesh 850 m). Larger eyes than this range impair the processing productivity of the tar, and conversely, if the eyes are smaller and the eyes are larger, the white spot prevention effect is inferior. It is not preferable.
- the degassed compressed talc used in the present invention satisfies the above-mentioned regulations, and is characterized in that, unlike the conventional talc, it is compacted relatively uniformly for a high compression rate. Therefore, since there is no strong compression history received locally, the presence of ⁇ core '' is very small when melt-kneaded so that it is easily dispersible and uniformly dispersed, and there are white spots on the appearance surface of the molded product No power The number is extremely small.
- the production method of talc with few lumps based on compression unevenness used in the present invention is not particularly limited as long as it does not depart from the gist of the present invention. For example, the following steps (a) and (b) are continuously performed. ! ⁇ can be manufactured.
- a known apparatus and method can be used. For example, as a degassing volume reduction machine, it can be degassed in advance before being compressed by a roller with a Kurimoto Sae Talipack or a Hosokawa Micron dense pack. Following this deaeration process, a compression operation is performed as shown below.
- a known device can be used, and examples thereof include a roller (a roller compactor manufactured by Kurimoto Tsue Co., Ltd.).
- Fig. 1 As a continuous device of the above (a) and (b) for reducing the lump based on the compression unevenness used in the present invention, for example, Fig. 1 as disclosed in JP-A-10-100144 is disclosed.
- the apparatus shown in Fig. 1 can be used.
- talc stored in the hopper 15 is taken into the vacuum deaeration device 1 from the supply port 5, and is discharged by 6 screws through the screw while being deaerated by the vacuum pump 12.
- the degassed talc is dropped into the feeder 2 from the discharge port 6, pushed downward by a screw, supplied to the compression deaerator 3 having a pair of cylindrical rolls 23, and further between the rolls 23. It is discharged downward while being compressed and deaerated.
- the clearance size is adjusted between 0.8 and 2. Omm. This is achieved by this fact.
- the distance between the rolls is small, a large pressure is generated in the talc compressed between the rolls. As a result, a lump that is difficult to collapse even during melt kneading is generated.
- the width is too large, the talc cannot be compressed and a slip-through occurs, which is not preferable.
- the steps (a) and (b) may be performed simultaneously.
- the (A) degassed compressed talc defined in the present invention is a variety of organic titanate coupling agents, organic silane coupling agents, fatty acids for the purpose of improving adhesion or dispersibility with a polymer.
- organic titanate coupling agents organic silane coupling agents
- fatty acids for the purpose of improving adhesion or dispersibility with a polymer.
- a surface treated with a fatty acid metal salt, a fatty acid ester or the like may be used.
- Component (B) polypropylene resin
- the (B) polypropylene resin composition constituting the talc-containing polypropylene resin composition of the present invention is not particularly limited, but a propylene ethylene glycol copolymer or propylene homopolymer having an ethylene content of 25% by weight or less is preferred. . Propylene 'ethylene block copolymer has poor rigidity when the ethylene content exceeds 25% by weight.
- the form of the polypropylene rosin is not particularly limited, but it is preferably a powder form in order to produce the blend and melt-kneading process from the polypropylene polymerization process.
- the component (B) polypropylene resin used in the talc-containing polypropylene resin composition of the present invention is not particularly limited, but the melt flow rate (MFR: 230 ° C, 2.16 kg load) is 3 to 300 gZlO, Preferably 8 to 250 gZlO, particularly preferably 10 to 200 gZlO, most preferably 20 to LOOgZlO is used. If the MFR of the polypropylene resin component is less than the above range, the fluidity is insufficient, and a molding machine with a large clamping force is required when molding a thin molded product, or the molding temperature is increased. As the need arises, it adversely affects productivity.
- MFR melt flow rate
- the MFR of the polypropylene resin component exceeds the above range, properties such as impact resistance are poor.
- the MFR of the above polypropylene resin component was adjusted at the time of polymerization, or adjusted by adding an organic peroxide such as disilver oxide or dialkyl peroxide after the exit of the polymerization reactor and before melt kneading. It may be.
- MFR is a value measured according to JIS K-7210-1995.
- Polypropylene resin (B) power A propylene / ethylene block copolymer or propylene homopolymer having an ethylene content of 25% by weight or less and an MFR of 3 to 300 gZlO is preferable.
- the propylene / ethylene block copolymer is a block copolymer comprising a propylene homopolymer portion and a propylene / ethylene random copolymer partial force, wherein the propylene homopolymer portion has an MFR of the propylene homopolymer portion. Is preferably from 5 to 1, OOOgZlO, more preferably from 10 to 800 g / 10 minutes, and particularly preferably from 30 to 500 g / 10 minutes.
- the isotactic pentad fraction of the propylene homopolymer portion is preferably 0.98 or more, more preferably 0.985 or more.
- the isotactic pentad fraction (P) is preferably 0.98 or more, more preferably 0.985 or more.
- the flexural modulus may be insufficient.
- the isotactic pentad fraction (P) is the isotactic fraction of pentad units in the polypropylene molecular chain measured using 13 C-NMR.
- the polypropylene resin used in the present invention can be obtained by using various known catalysts. Specifically, a known Ziegler-Natta catalyst or a metalocene catalyst can be used. As the Ziegler-Natta catalyst, a highly stereoregular catalyst is used. As an example of producing a Ziegler-Natta catalyst, tetrasalt ⁇ titanium is reduced with an organoaluminum compound, and further treated with various electron donors and electron acceptors.
- a method of combining the titanium trichloride composition thus obtained with an organoaluminum compound and an aromatic carboxylic acid ester See 100806, JP-A-56-120712, JP-A-58-104907;), and supported catalysts in which magnesium tetrachloride is contacted with titanium tetrachloride and various electron donors. And the like (see JP-A-57-63310, JP-A-63-43915, JP-A-63-83116) and the like.
- a production process such as a gas phase fluidized bed, a solution method, a slurry method, etc. is applied and polymerization is carried out using propylene and, if necessary, ethylene.
- the blending ratio of the above component (A) degassed compression torque and component (B) propylene resin is the sum of component (A) and component (B).
- the component (B) is preferably 50 to 99% by weight, more preferably 60 to 95% by weight, and particularly preferably 70 to 90% by weight based on the amount.
- the blending amount is less than the above, the amount of talc increases and the specific gravity becomes heavy, which is not preferable. Conversely, when it exceeds the above range, the impact resistance is poor.
- talc-containing polypropylene resin composition of the present invention in addition to the essential components (A) and (B), other additional components (optional components) are included within a range that does not significantly impair the effects of the present invention. Can be added.
- Such additive components include ethylene-propylene copolymer elastomers such as ethylene propylene copolymer, ethylene butene copolymer, ethylene otaten copolymer, styrene elastomers such as SEBS and SEPS, Neutralization represented by phenolic and phosphorus antioxidants, hindered amines, benzophenones, benzotriazoles, weathering deterioration inhibitors, nucleating agents such as organoaluminum compounds and organophosphorus compounds, and metal salts of stearic acid Agents, dispersants, colored substances such as quinacridone, perylene, phthalocyanine, titanium oxide, carbon black, fibrous potassium titanate, fibrous magnesium oxysulfate, fibrous aluminum borate, calcium carbonate whiskers, carbon fiber Examples include materials such as glass fibers.
- ethylene-propylene copolymer elastomers such as ethylene propylene copolymer, ethylene butene copolymer,
- the method for producing a polypropylene resin composition of the present invention comprises the step of introducing the polypropylene resin and the degassing into an extruder disposed downstream of the polymerization reactor for producing the polypropylene resin.
- Supply gas compression talc and melt knead are supplied to the polypropylene resin.
- the talc-containing polypropylene resin composition of the present invention is produced by melt-kneading with a large kneader having a large extrusion amount. At that time, in order to enjoy the cost merit of in-line compound, it is preferable that it is transferred from the polymerization process as follows, and premixing, melt-kneading and granulation processes are performed consistently.
- polypropylene resin manufactured in a polypropylene polymerization plant is transferred to a kneading and granulating facility through a transport pipeline.
- the transferred polypropylene resin ((
- Component B) is premixed with the above-described degassed compressed talc (component (A)) and, if necessary, the additional component (component (C)).
- component (A) degassed compressed talc
- component (C) additional component
- it does not specifically limit as a premixer A notch type Henschel mixer, a tumbler mixer, a continuous type powder mixer etc. can be illustrated.
- the extrusion amount of the resin composition is ⁇ , the lower limit value Si, OOOkg / hr, preferably ⁇ 2, OOOkg / hr, more preferably ⁇ 3, OOOkg Zhr.
- the upper limit is not particularly limited, but considering the scale of facilities that have been used so far, it is preferably 20,000 kg / hr, more preferably 10, OOOkgZhr.
- the kneader is not particularly limited, and examples thereof include a single-screw kneader, a twin-screw kneader, or a tandem kneader in which two and a single shaft (uniaxial) are combined.
- the method of melt kneading with a single screw extruder is preferred after the twin screw melt kneading preferred with a tandem kneader.
- the talc-containing polypropylene resin composition of the present invention is reinforced with talc, it has an excellent balance between rigidity and impact resistance, and is a material having high dimensional properties. Although it can be processed, it is particularly preferable to use it for injection molded products such as automobile interior parts, especially door trims, pillar trims, console boxes, various types of nodding materials and the like.
- Example [0030] The ability to specifically describe the present invention in the following examples The present invention is not limited thereto.
- the measuring method used for an Example and a comparative example is as follows.
- Talc average particle size measured using a laser particle size distribution analyzer (LA920 manufactured by Horiba, Ltd.).
- the weight of the coarse particles that did not pass through the mesh was determined, and the weight of the component more than 1,000 ⁇ m from the 16 mesh sieve residue, the 16 mesh sieve residue and the 30 mesh sieve residue.
- the weight of components over 500 m was calculated from the total, and the ratio was calculated.
- Molding conditions Molding temperature: 220 ° C, mold temperature; 40 ° C, injection pressure: 100 MPa, holding pressure: 40 MPa, injection filling time: 7 seconds, holding pressure time: 8 seconds, cooling time: 20 seconds, screw rotation speed: 1 50 rpm, screw back pressure: none
- Fine talc with an average particle size of 5.O ⁇ m and a force specific gravity of 0.12 (manufactured by Hayashi Kosei Co., Ltd .: MW50 00S) (hereinafter referred to as raw material 1) was used using a Kurimoto Seiko Talipack. After the primary deaeration to a force specific gravity of around 0.35, the secondary compression is continued with a roller compactor made by Kurimoto Seiko (roller 1. lmm, roller rotation speed 10rpm, push screw 17rpm). Degassed compressed talc (talc 1) was produced.
- this talc 1 The properties of this talc 1 were a force specific gravity of 0.58, an amount of 1,000 ⁇ mJ3 ⁇ 4 upper component by the low tap method was 5.5% by weight, and an amount of component above 500 m was 35.9% by weight. It was. In addition, the amount of components over 500 m by the improved sieving method was 3.4% by weight, which was extremely small in mass.
- PP- l: MFR 30gZlO content, rubber content 13 wt 0/0, E Ji Ren in the rubber Content: 50% by weight: Nippon Polypro Co., Ltd .: BC03EQ
- tetrakis [methylene-3- (3 ', 5, -di-t-butyl) per 100 parts by weight of polypropylene resin 4, monohydroxyphenol) propionate] methane (113 ⁇ 4 ⁇ 0 1010 manufactured by Ciba Specialty Chemicals Co., Ltd.) 0.05 parts by weight, 0.4 parts by weight of canolesium stearate, and a biaxial continuous powder mixer ( Screw diameter 330mm, L
- Example 1 For the talc used in Example 1, the same roll interval and the same roll speed as in Example 1 were adopted for the production conditions of Example 1, and only the rotational speed of the push screw was changed and adjusted, and the degassing compression talc (talc 1 2 , And talc 3). Using the obtained talc, the composition shown in Table 2 was blended by the same method as in Example 1, melt-kneaded and granulated, and the white point of the test sample was evaluated. Table 1 shows the physical properties of talc and Table 2 shows the evaluation results of the greave composition.
- the raw material talc used in Example 1 was first degassed using a Kurimoto Seiko Taripack until the Kashimoto Specific Gravity 0.3 before and afterwards.
- Degassing compression talc (talc-5) was produced by secondary compression at a distance of 0.5 mm, a roller rotation speed of 20 rpm, and an indentation screw speed of 16 rpm.
- This talc-5 is characterized by a bulk specific gravity of 0.58, a sieved component by the low tap method, 22% by weight of components over 1,000 m, and 53% by weight of components over 500 m. It was.
- the amount of components over 500 m by the improved sieving method was 31.8% by weight, and there were many lumps.
- composition of talc-5 produced above is shown in Table 2, and tetrakis [methylene-3- (3 ', 5, -di-tert-butyl-4, hydroxyphenol) propionate] methane (manufactured by Ciba Specialty Chemicals) IRGANOX1010)
- IRGANOX101010 tetrakis [methylene-3- (3 ', 5, -di-tert-butyl-4
- Table 2 shows the evaluation results of the greave composition.
- Talc-5 is a large kneading machine such as CIM-320 that is installed in a power plant. A white spot occurred.
- Example 1 For the production conditions of talc used in Example 1, the same roll interval and the same roll rotation speed as in Example 1 were adopted, and only the rotation speed of the push screw was changed and adjusted. ) was manufactured. Using the obtained talc, the composition shown in Table 2 was blended by the same method as in Example 1, melt-kneaded and granulated, and the white spot of the test sample was evaluated. Table 1 shows the physical properties of talc and Table 2 shows the evaluation results of the resin composition.
- fine talc made by Nippon Talc Co., Ltd .: product name Microace ⁇ —2 with an average particle size of 7.8 / ⁇ ⁇ and a force specific gravity of 0.15 is used.
- the deaeration compression talc (talc 4) was manufactured by adjusting only the rotation speed of the pushing screw and degassing and compressing.
- the property of this talc 4 is that the bulk specific gravity is 0.56, the amount of components over 1,000 m by the low tap method is 4.3% by weight, and the amount of components over 500 m is 30.5% by weight. It was.
- the amount of components over 500 m by the improved sieving method was 3.5% by weight and very little lump.
- Example 1 using coarse talc (manufactured by Nippon Talc Co., Ltd .: product name MS) having an average particle size of 13 / ⁇ ⁇ and a force specific gravity of 0.40 instead of the raw material 1 using Taripack manufactured by Kurimoto Seiko Co., Ltd.
- the degassing compression talc (talc 7) was manufactured by using the same roll interval and the same rotation speed as the above, and adjusting only the rotation speed of the pushing screw. Properties of the talc one 7, the force of gravity 0.6, the amount of 1, 000 m or more components by ro-tap method 4. The amount of 1 weight 0/0, 500 m or more components met 26 by weight% It was. Also.
- the amount of components over 500 m by the improved sieving method was 1.3% by weight, which was extremely small in mass. Further, blending, kneading and granulation were conducted in the same manner as in Example 1 with the formulation shown in Table 2, and the white point was evaluated. Table 1 shows the physical properties of talc, and Table 2 shows the evaluation results of the greave composition. When this talc was used, bending rigidity was low.
- talc 10 Commercially available compression talc manufactured by Hayashi Kasei Co., Ltd .: MW5000SMA (Talc 10), blended as shown in Table 2, blended by the same method as in Example 1, melt-kneaded and granulated, test sample The white spot of was evaluated.
- Table 1 shows the physical properties of talc
- Table 2 shows the evaluation results of the greave composition.
- Degassed compressed talc (talc 1-8) was produced by sieving the compressed talc in the same manner as in Example 1 with a 16-mesh sieve.
- This talc-1 has a strength specific gravity of 0.51, and although the specific gravity of the talc is slightly reduced by sieving, it maintains the bulk specific gravity, which is much different from the initial, and is 1,000 m by the low tap method.
- the amount of the above components 0 weight 0/0, 500 / the amount of ingredient above zm has had an excellent 28% by weight.
- the content of 500 ⁇ m or more by the improved sieving method was 0% by weight, and it was extremely small in mass.
- the blend shown in Table 2 was blended, kneaded and granulated in the same manner as in Example 1, and the white point was evaluated.
- Table 1 shows the physical properties of talc
- Table 2 shows the evaluation results of the resin composition.
- the talc-containing polypropylene resin composition of the present invention is a high-performance material that does not suffer from the problem of poor dispersion of inorganic fillers (white spots), injection molded products such as automobile interior parts, particularly door trims, It can be used for pillar trims, console boxes, various swaging materials, etc.
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Abstract
Description
Claims
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US11/574,926 US20070260004A1 (en) | 2004-09-08 | 2005-09-07 | Polypropylene Resin Composition And Process For Producing The Same |
EP05782261.1A EP1788024B1 (en) | 2004-09-08 | 2005-09-07 | Process for producing polypropylene resin composition |
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US (1) | US20070260004A1 (ja) |
EP (1) | EP1788024B1 (ja) |
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EP2813334A4 (en) * | 2012-02-07 | 2015-07-22 | Mitsubishi Rayon Co | METHOD FOR MANUFACTURING RESIN MIXTURE |
CN102817601B (zh) * | 2012-08-31 | 2015-04-08 | 中国石油天然气股份有限公司 | 应用交联剂进行聚合物驱油田在线调剖的方法及装置 |
EP2945986A4 (en) | 2013-01-17 | 2016-08-31 | Imerys Talc America Inc | VENTILATED TALCUM AND RELATED METHODS |
CN104354321A (zh) * | 2014-11-11 | 2015-02-18 | 成都利君科技有限责任公司 | 一种压球机 |
CN114736456B (zh) * | 2022-03-24 | 2023-09-26 | 金发科技股份有限公司 | 一种聚丙烯组合物及其制备方法和应用 |
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JPH03135431A (ja) * | 1989-10-20 | 1991-06-10 | Kurimoto Ltd | 微粉の造粒方法およびその装置 |
JPH04306261A (ja) * | 1991-04-04 | 1992-10-29 | Mitsui Petrochem Ind Ltd | タルク入りポリプロピレン樹脂組成物の製造方法 |
JPH10100144A (ja) * | 1996-09-30 | 1998-04-21 | Kurimoto Ltd | 無機質充填材入り樹脂組成物の製造方法 |
JP2002079515A (ja) * | 2000-09-07 | 2002-03-19 | Calp Corp | 熱可塑性樹脂組成物及びゴム組成物の製造方法 |
JP2002302554A (ja) * | 2001-04-04 | 2002-10-18 | Tamio Serita | 無機フィラー配合ポリオレフィン樹脂組成物の製造方法及び製造装置 |
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WO1994020575A1 (en) * | 1993-03-01 | 1994-09-15 | Nippon Zeon Co., Ltd. | Resin composition and molding produced therefrom |
JP3347958B2 (ja) * | 1996-11-26 | 2002-11-20 | 日本ポリケム株式会社 | プロピレン系樹脂組成物 |
WO2002020233A1 (fr) | 2000-09-07 | 2002-03-14 | Calp Corporation | Procede de production d'une composition de resine thermoplastique et composition de resine thermoplastique ainsi obtenue |
US6469088B1 (en) | 2000-11-02 | 2002-10-22 | Equistar Chemicals, Lp | Polyolefin insulation compositions having improved oxidative stability |
CN1329110C (zh) | 2001-09-26 | 2007-08-01 | 伊内奥斯美国公司 | 一体化的化工工艺控制 |
JP3882909B2 (ja) * | 2002-06-20 | 2007-02-21 | カルプ工業株式会社 | 異形押出用熱可塑性樹脂組成物 |
-
2005
- 2005-09-07 WO PCT/JP2005/016438 patent/WO2006028144A1/ja active Application Filing
- 2005-09-07 EP EP05782261.1A patent/EP1788024B1/en not_active Revoked
- 2005-09-07 CN CN200580030171.8A patent/CN100582154C/zh active Active
- 2005-09-07 US US11/574,926 patent/US20070260004A1/en not_active Abandoned
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JPH03135431A (ja) * | 1989-10-20 | 1991-06-10 | Kurimoto Ltd | 微粉の造粒方法およびその装置 |
JPH04306261A (ja) * | 1991-04-04 | 1992-10-29 | Mitsui Petrochem Ind Ltd | タルク入りポリプロピレン樹脂組成物の製造方法 |
JPH10100144A (ja) * | 1996-09-30 | 1998-04-21 | Kurimoto Ltd | 無機質充填材入り樹脂組成物の製造方法 |
JP2002079515A (ja) * | 2000-09-07 | 2002-03-19 | Calp Corp | 熱可塑性樹脂組成物及びゴム組成物の製造方法 |
JP2002302554A (ja) * | 2001-04-04 | 2002-10-18 | Tamio Serita | 無機フィラー配合ポリオレフィン樹脂組成物の製造方法及び製造装置 |
Non-Patent Citations (1)
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EP1788024A4 (en) | 2011-05-04 |
EP1788024B1 (en) | 2015-06-10 |
US20070260004A1 (en) | 2007-11-08 |
CN101014662A (zh) | 2007-08-08 |
CN100582154C (zh) | 2010-01-20 |
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