WO2006001418A1 - 燃料電池用燃料貯留体 - Google Patents
燃料電池用燃料貯留体 Download PDFInfo
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- WO2006001418A1 WO2006001418A1 PCT/JP2005/011732 JP2005011732W WO2006001418A1 WO 2006001418 A1 WO2006001418 A1 WO 2006001418A1 JP 2005011732 W JP2005011732 W JP 2005011732W WO 2006001418 A1 WO2006001418 A1 WO 2006001418A1
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- Prior art keywords
- fuel
- liquid
- fuel cell
- liquid fuel
- reservoir
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
- H01M8/04208—Cartridges, cryogenic media or cryogenic reservoirs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a fuel reservoir for a fuel cell, and more particularly, a fuel reservoir suitable for a small fuel cell used as a power source for portable electronic devices such as a mobile phone, a notebook personal computer, and a PDA. About the body.
- a fuel cell includes a fuel cell in which an air electrode layer, an electrolyte layer, and a fuel electrode layer are stacked, a fuel supply unit for supplying fuel as a reducing agent to the fuel electrode layer, and an air electrode A battery that has an air supply part for supplying air as an oxidant to the layer, and causes an electrochemical reaction in the fuel cell by the fuel and oxygen in the air to obtain electric power outside.
- liquid fuel cells described in each of these patent documents supply the liquid fuel from the fuel tank to the fuel electrode by capillary force, and therefore do not require a pump for pumping the liquid fuel. There is.
- the applicant of the present application has a unit cell formed by constructing an electrolyte layer on the outer surface of a fuel electrode body made of a microcarbon porous body, and constructing an air electrode layer on the outer surface of the electrolyte layer.
- a plurality of fuel cells connected to each other, each unit cell being connected to a fuel supply body having a permeation structure connected to a fuel storage body such as a force cartridge structure body for storing liquid fuel.
- a direct methanol fuel cell to be supplied is filed (see, for example, Patent Document 9).
- Patent Document 1 JP-A-5-258760 (Claims, Examples, etc.)
- Patent Document 2 JP-A-5-307970 (Claims, Examples, etc.)
- Patent Document 3 Japanese Patent Application Laid-Open No. 59-66066 (Claims, Examples, etc.)
- Patent Document 4 JP-A-6-188008 (Claims, Examples, etc.)
- Patent Document 5 Japanese Unexamined Patent Publication No. 2003-229158 (Claims, Examples, etc.)
- Patent Document 6 Japanese Patent Laid-Open No. 2003-299946 (Claims, Examples, etc.)
- Patent Document 7 Japanese Patent Laid-Open No. 2003-340273 (Claims, Examples, etc.)
- Patent Document 8 Japanese Patent Laid-Open No. 2001-102069 (Claims, Examples, etc.)
- Patent Document 9 Japanese Unexamined Patent Application Publication No. 2004-63200 (Claims, Examples, etc.)
- the present invention has been made in view of the problems and current situation of the above-described conventional fuel cell fuel reservoir, and has been made to solve this problem. Even when the fuel reservoir is heated to a high temperature state, It can prevent boiling of liquid fuel, generation of bubbles, blowing out of fuel, etc., and also stably supply liquid fuel directly to the fuel cell body, and there is no loss of liquid fuel even when stored at high temperature And it aims at providing the fuel storage body for fuel cells which can achieve size reduction of a fuel cell.
- a fuel reservoir that can be connected to a fuel cell main body is a fuel that contains liquid fuel.
- the storage container, the fuel outflow portion, and a follower having specific physical properties at the rear end portion of the liquid fuel, and the fuel storage container further having a specific structure can be used to store the fuel for the target fuel cell.
- the body was successfully obtained and the present invention was completed.
- the present invention resides in the following (1) to (7).
- a fuel reservoir that can be connected to a fuel cell main body, and the fuel reservoir is disposed at a fuel storage container that stores liquid fuel, a fuel outflow portion, and a rear end portion of the liquid fuel.
- a fuel storage chamber in which the inside of the fuel container is at least sealed by the follower, and the follower in a state of being isolated and sealed from the outside air.
- a fuel reservoir for a fuel cell comprising a pressurizing chamber in which means for pressing the body is enclosed.
- the volatile liquid sealed in the pressurizing chamber is filled with an amount capable of obtaining a saturated vapor pressure at least the sum of the volume of the pressurizing chamber and the volume of the fuel storage chamber.
- Fuel cell fuel reservoir
- the fuel cell main body is constructed by constructing an electrolyte layer on the outer surface portion of the fuel electrode body, and connecting a plurality of unit cells formed by constructing an air electrode layer on the outer surface portion of the electrolyte layer.
- the fuel reservoir for a fuel cell according to any one of (1) to (6), wherein a fuel supply body connected to the fuel reservoir is connected to the cell to supply liquid fuel.
- the present invention even when the fuel reservoir is heated to a high temperature state, it is possible to prevent the liquid fuel from boiling, the generation of bubbles, the blowing of fuel, and the like, and directly to the fuel cell main body.
- a fuel cell fuel storage body that can stably supply liquid fuel, lose force, lose liquid fuel even when stored at high temperatures, and reduce the size of the fuel cell.
- FIG. 1 (a) is a schematic perspective view showing a fuel reservoir for a fuel cell according to a first embodiment of the present invention, and (b) is a partial sectional view showing an essential part of a pressurizing chamber.
- FIG. 2 (a) to (h) show a valve body structure of a fuel outflow valve provided in the fuel outflow portion of the first embodiment of the present invention
- (a) is a perspective view of the valve body
- (b) ) Is a plan view of the valve body
- (c) is a longitudinal section view of the valve body
- (d) is a plan view of the adapter
- (e) is a longitudinal section view of the adapter
- (f) is a state in which the valve body is loaded on the adapter.
- G is a longitudinal section with the valve element loaded on the adapter.
- (H) is a partial longitudinal sectional view showing a valve body structure of a fuel outflow valve provided in the fuel outflow portion.
- FIG. 3 is a schematic cross-sectional view showing an example of a state in which the fuel cell fuel reservoir of FIG. 1 is connected to a fuel cell body and used as a fuel cell.
- FIG. 4 (a) and 4 (b) are a perspective view and a longitudinal sectional view for explaining the fuel battery cell 20.
- FIG. 4 (a) and 4 (b) are a perspective view and a longitudinal sectional view for explaining the fuel battery cell 20.
- FIG. 5 is a schematic perspective view showing a fuel reservoir for a fuel cell according to a second embodiment of the present invention.
- FIG. 6 (a) to (c) show a fuel cell fuel reservoir according to a third embodiment of the present invention.
- (A) is a schematic partial cross-sectional view shown in a vertical cross-sectional view.
- (c) is a perspective view.
- FIG. 7 is a partial schematic cross-sectional view showing how the fuel cell fuel reservoir according to the third embodiment of the present invention is used.
- FIG. 8 is a schematic cross-sectional view showing a form before use of the fuel cell fuel reservoir of FIG. Explanation of symbols
- FIG. 1 and 2 show a basic form (first embodiment) of a fuel cell fuel reservoir A showing a basic embodiment of the present invention.
- a fuel reservoir A for a fuel cell is a fuel reservoir that can be connected to a fuel cell main body, a tube-type fuel storage container 10 that stores liquid fuel F, and a fuel flow
- the outlet 11 and the trailing end 12 of the liquid fuel F are provided with a follower 12 that seals the liquid fuel F and moves as the liquid fuel F is consumed.
- 12 is provided with a fuel storage chamber 13 sealed at least by 12 and a pressurization chamber 14 in which means for pressing the follower 12 in a state of being isolated and sealed from the outside air is enclosed.
- the tube-type fuel storage container 10 has storage stability, durability, and gas impermeability (gas impermeability to oxygen gas, nitrogen gas, etc.) with respect to the liquid fuel to be stored. It is preferable that it is composed of light-transmitting materials so that the remaining amount of fuel can be seen.
- the fuel container 10 for example, when light transmittance is not required, power such as metal, stainless steel, synthetic resin, glass, etc., the visibility of the remaining amount of liquid fuel described above
- polypropylene, polybutyl alcohol, ethylene butyl alcohol copolymer resin, polyacryl-tolyl having the above characteristics.
- a multilayer structure as long as at least one layer is made of a resin having the above-mentioned performance (gas permeability), the remaining layers can be used with ordinary resins without any problem in practical use.
- a multi-layered tube can be manufactured by extrusion molding, injection molding, coextrusion molding, or the like.
- the fuel outflow portion 11 includes a valve body 11a serving as a fuel outflow valve that seals communication between the inside and the outside of the cylindrical fuel storage container 10.
- the valve body 1 la is accommodated in the fuel outflow part 11 directly or via a valve body adapter.
- the valve body 11a has the same configuration as a member used in a writing instrument or the like, and is directly stored in the fuel storage container 10 due to atmospheric pressure, temperature change, etc., as shown in FIGS. 2 (a) to (c). This prevents foreign substances such as air entering the liquid fuel F from the vicinity of the fuel supply pipe described later.
- the valve body 11a is a linear slit that allows the liquid storage container 12 and the inside to communicate with each other by inserting a liquid fuel supply member and supplies the liquid fuel F inside the fuel storage container 10 to the outside.
- the valve body 1 la is compressed in the radial direction by the valve body outer edge 1 lc when the valve body 11a is stored in the fuel outflow portion 11 or the valve body adapter.
- a compressive force acts on the communication portion 11c.
- the communication portion 11c is elliptical as shown in FIG. 2 (b), and becomes a communication portion in the minor axis direction Y.
- a slit l ib is provided to compress the outer edge portion 11c in the major axis direction X, and a compressive force acts in the direction in which the slit l ib is closed.
- the communication portion 1 lb is formed by a straight slit
- the liquid fuel supply member is inserted to connect the fuel storage container 10 to the inside, and the liquid fuel F inside the fuel storage container 10 is exchanged.
- the structure is not particularly limited as long as the structure can be supplied to the outside, and a plurality of cross-shaped and radial slits, a structure in which a plurality of slits are formed so that each slit intersects at the same location, a circular hole shape, a rectangular hole shape, etc. There may be.
- the linear slit is desirable.
- the shape of the outer edge portion 11c is not particularly limited, and it can be formed in a circular shape in addition to an elliptical shape as in the above embodiment.
- a convex tapered surface (protrusion) l id is formed toward the inside of the fuel storage container 10 so that the liquid fuel supply member can be inserted smoothly when inserted. It is preferable to do.
- the fuel outflow portion 11 is provided with an adapter l ie as shown in FIGS. 2 (d) and 2 (e).
- the adapter l ie is formed in a cylindrical shape and has a stopper portion 1 If, 1 on its inner peripheral surface. It consists of a main body l lg on which If is formed and a fixing member l lh formed in a cylindrical shape, and the valve body 1 la having the above configuration is sandwiched between the stopper 1 If and the fixing member 1 lh. It will be.
- valve body 11a and the adapter l ie there is an elliptical slit valve and a circular adapter, and conversely, a circular slit valve and an elliptical valve. In this case, it is necessary to make the slit direction of the slit valve the long diameter of the adapter.
- valve body 11a prevents the intrusion of foreign substances such as air even when it is suspended (not used). This is to prevent accidents such as fuel leakage and jetting due to an increase in pressure in the liquid fuel container 10 due to intrusion of air or the like.
- valve body l la and the adapter l ie prevent liquid fuel leakage more effectively.
- the above structure, etc. is made of a material having low gas permeability to the liquid fuel F, and also has a material force with a compression set of 20% or less as defined in JIS K 6262-1997. preferable.
- valve bodies lla and adapter integrated lie has storage stability, durability, gas impermeability, and elasticity that can adhere to the fuel supply pipe with respect to the liquid fuel F to be stored.
- polybutyl alcohol ethylene vinyl alcohol copolymer resin, polyacryl-tolyl, nylon, cellophane, polyethylene terephthalate, polycarbonate, polystyrene, polyvinyl chloride, polysalt vinylidene, Synthetic resins such as polyvinyl chloride, natural rubber, isoprene rubber, butadiene rubber, acrylonitrile butadiene rubber, 1,2-polybutadiene rubber, styrene butadiene rubber, chloroprene rubber, nitrino rubber, butyl rubber, ethylene-propylene rubber, chlorosulfonated Polyethylene rubber, acrylic rubber, epichlorohydrin Rubber, polysulfide rubber, silicone rubber, fluorine rubber, rubber such as Uretango
- liquid fuel F to be used a methanol liquid that has the power of methanol and water can be cited, but the compound power supplied as fuel in the fuel electrode body described later can efficiently obtain hydrogen ions (H +) and electrons (e_).
- the liquid fuel is not particularly limited as long as it can be used. Power depending on the structure of the fuel electrode body, for example, dimethyl ether (DME), ethanol solution, formic acid, hydrazine, ammonia solution, ethylene glycol, sucrose aqueous solution, hydrogenation Liquid fuels such as sodium boron can also be used.
- DME dimethyl ether
- ethanol solution formic acid, hydrazine, ammonia solution, ethylene glycol, sucrose aqueous solution
- hydrogenation Liquid fuels such as sodium boron
- the liquid fuel can be used at various concentrations depending on the structure and characteristics of the fuel cell. For example, a liquid fuel having a concentration of 1 to 100% can be used.
- the follower 12 is in contact with the rear end surface of the liquid fuel F stored in the fuel storage container 10, seals the liquid fuel F, and moves as the fuel is consumed. This prevents the liquid fuel in the tank 10 from leaking and evaporating, and also prevents air from entering the liquid fuel.
- the follower 12 is required not to dissolve or diffuse in the liquid fuel F.
- liquid fuel in the fuel storage container 10 serving as a fuel storage tank leaks and evaporates, so that it cannot function as a fuel storage tank. It is conceivable that the substances constituting the follower 12 enter the fuel electrode of the fuel cell body and adversely affect the reaction. Considering these conditions, preferable characteristics and the like of the follower 12 used in the present invention are selected.
- the follower 12 that can be used is not particularly limited as long as it has the above-mentioned characteristics.
- petroleums such as mineral oil, polydaricol, polyester, polybutene, and silicone oil, aliphatic metal sarcophagus
- examples thereof include those obtained by adding a solvent or the like to modified clay, silica gel, carbon black, natural or synthetic rubber, and various synthetic polymers.
- the surface free energy is lower than that of the liquid fuel F.
- the fuel container 10 and the follower 12 It is possible to increase the possibility of preventing liquid fuel from entering the gaps and leaking outside. In view of these conditions, the material, surface state, etc. of the follower 12 can be appropriately selected.
- the inside of the fuel storage container 10 includes a fuel storage chamber 13 in which the liquid fuel F at least sealed by the follower 12 is stored.
- the structure has a pressurizing chamber 14 in which means for pressing the follower 12 that is isolated and sealed from the outside air is enclosed.
- the pressurizing chamber 14 is provided on the rear end side of the fuel storage container 10 and is formed by the upper surface of the follower 12 and a sealing body 15 having a sealing valve.
- the space is the pressurizing chamber.
- the pressurizing chamber 14 contains a means for pressing the follower. As the means for pressing, a volatile liquid G having a higher vapor pressure than the liquid fuel F sealed in the fuel storage chamber 13 is sealed.
- the aqueous methanol solution is the liquid fuel F as an example
- the liquid fuel of the present invention is not limited to this.
- the volatile liquid G enclosed in the pressurizing chamber 14, for example, Liquid fuel F can be pressurized through the follower 12 by evaporation of the solvent vapor.
- the air By simply enclosing air in the pressurizing chamber 14, the air expands as the temperature rises, and the force of pressurizing the liquid fuel F through the follower 12 alone is less effective for pressurization.
- the initial pressure in the pressurizing chamber is lOlkPa
- the pressure will only be 122kPa (l. 2 times).
- the vapor pressure of methanol which is a liquid fuel, changes from 12 kPa to 181 kPa (10 times or more).
- the pressurizing chamber 14 in order to prevent boiling of the liquid fuel, the pressurizing chamber 14 needs to be pressurized to a pressure higher than the vapor pressure of the liquid fuel, so that the vapor pressure is higher than the vapor pressure of the liquid fuel. It is necessary to enclose a liquid of composition.
- vapor pressure in the present invention refers to the physical vapor pressure itself when compared at the same temperature.
- volatile liquid defined in the present invention refers to a solvent that is a liquid at least at room temperature and normal pressure, and has a vapor pressure of 20 ° C. or less ⁇ OlkPa.
- a liquid with a high vapor pressure means, for example, when a 50 wt% methanol aqueous solution is used, a higher concentration of methanol can be said to be a liquid with a higher vapor pressure.
- the vapor pressure of 100% methanol is shown in Table 1 below.
- the vapor pressure of the mixed solvent of methanol and water (methanol aqueous solution) is shown in Table 2 below.
- a liquid having a high vapor pressure and a composition means, for example, when a 50 wt% aqueous methanol solution is used, as shown in Table 2 above, methanol having a higher concentration than this is used. Is a liquid with higher vapor pressure. It can also be seen that in the mixed solvent of methanol and water (methanol aqueous solution), the higher the methanol concentration, the higher the vapor pressure at each temperature.
- the vapor pressure of the volatile liquid G needs to be larger (or closer) than the vapor pressure of the liquid fuel F, a liquid having a higher vapor pressure than the vapor pressure at a certain methanol concentration, The liquid must have a composition having a vapor pressure.
- the volatile liquid G to be used is preferably a liquid having a composition in which the vapor pressure at 20 ° C. is 4 to: LOOkPa, more preferably 10 to 50 kPa.
- Liquids with a vapor pressure of less than 4kPa at 20 ° C will not be pressurized enough to pressurize the fuel, while liquids with a pressure exceeding lOOkPa will be difficult to handle such as filling because they are gases at room temperature.
- Table 3 shows an example of a volatile liquid having a composition of a vapor pressure of 20 ° C to 100 kPa that can be used in the present invention, but the present invention is not limited thereto.
- the volatile liquid G sealed in the pressurizing chamber 14 is sealed in such an amount that the saturated vapor pressure can be obtained by adding at least the volume of the pressurizing chamber 14 and the volume of the fuel storage chamber 13. .
- the required amounts of volatile liquid are XX Dg and XX D X Eml.
- the amount of volatile liquid G required is relatively small. For example, 60wt for a fuel reservoir (tank) with a pressurized chamber volume of 20ml and liquid fuel capacity of 100ml. / c ⁇ Methanol aqueous solution filled with liquid fuel and 100wt% methanol is used to give heat resistance at 100 ° C. When 100wt% methanol is used, the amount of 100wt% methanol filled in the pressure chamber 14 is 0.19g. (0.15 ml, 0.15% with respect to liquid fuel, filled with a few drops) should be enclosed.
- the vapor pressure at 100 ° C. of a 60 wt% aqueous methanol solution is 250 kPa. If the pressure can be increased at a pressure higher than this, boiling of the liquid fuel F to be filled can be prevented.
- the total of the pressurized chamber 14 and the liquid fuel capacity is 120 ml.
- the amount of methanol that can pressurize this space to 250 kPa or higher is required. Since lOOkPa is pressurized with air (strictly, air is also pressurized by heating. 100kPa ⁇ 127kPa). The remaining 150kPa will be pressurized by methanol.
- the volatile liquid G sealed in the pressurizing chamber 14 is sealed in such an amount that the saturated vapor pressure can be obtained by adding at least the volume of the pressurizing chamber 14 and the volume of the fuel storage chamber 13. Is preferred. With this configuration, it can be changed depending on the volume, the type of liquid fuel, and the type of volatile liquid.
- the present invention is not limited to the above examples of methanol, and the volatile liquids shown in Table 3 can be used. Further, the case where the methanol aqueous solution is used as the liquid fuel F has been described as an example. However, as the liquid fuel of the present invention, dimethyl ether (DME), ethanol solution, formic acid, hydrazine, ammonia solution, ethylene glycol, shochu, as described above. Aqueous sugar liquid and liquid fuel such as sodium borohydride are also known vapors at each temperature The volatile liquid G preferred for each liquid fuel can be used in the same manner as described above with reference to the pressure.
- DME dimethyl ether
- ethanol solution formic acid, hydrazine, ammonia solution, ethylene glycol, shochu, as described above.
- Aqueous sugar liquid and liquid fuel such as sodium borohydride are also known vapors at each temperature
- the volatile liquid G preferred for each liquid fuel can be used in the same manner as described above with reference to the pressure.
- the sealing body 15 having the sealing valve, the volatile liquid G evaporates with the liquid fuel consumption F as described above, whereby the liquid fuel F
- the temperature drops or the pressure becomes constant due to volatilization of the volatile liquid G When fuel is used, it can be pressurized from outside or inhaled.
- the sealing body 15 is provided with a sealing valve that can be opened and closed.
- This sealing valve should also be a closed valve that does not leak even under the vapor pressure of volatile liquid at 100 ° C.
- methanol at 100 ° C is about 350 kPa, so it is sufficient if it has a pressure resistance of about 500 kPa together with air. Since this is not a very high target, any valve structure is considered to be sufficient, and as long as the valve structure satisfies this condition, the structure is not particularly limited.
- the fuel outflow shown in Fig. 2 A valve having a slit structure having the same structure as that provided in the part 11 can be used, that is, a fuel outflow including the valve body 11a having the structure shown in FIG.
- the part 11 can be used, and a valve shown in FIG. 6 (a valve with the direction reversed (upward)) described later can also be used.
- the fuel cell fuel reservoir A configured as described above is freely connectable to the fuel cell main body N and is used.
- the fuel cell main body N has an electrolyte layer 23 formed on the outer surface portion of the fuel electrode body 21 made of a fine carbon porous body, and an air electrode on the outer surface portion of the electrolyte layer 23.
- Unit cells (fuel cells) 20 and 20 formed by constructing the layer 24, a fuel supply body 30 having a permeation structure connected to the fuel reservoir A, and an end of the fuel supply body 30 The unit cells 20 and 20 are connected in series so that fuel is sequentially supplied by the fuel supply body 30, and the fuel storage body A is replaced.
- the cartridge structure is capable of being inserted into the support 16 of the fuel cell main body N.
- liquid fuel F is directly stored as shown in FIG. 1, FIG. 2 (a) and FIG.
- the fuel is supplied by the fuel supply body 30 inserted into the valve body 11a provided in the fuel outflow portion 11 at the lower part of the fuel storage container 10 for storing the liquid fuel F.
- the fuel storage container 10 of the fuel storage body A, the valve body l la provided in the fuel outflow portion 11, and the fuel supply body 30 are joined together by fitting or the like.
- each member is higher than the surface free energy of the liquid fuel F, the possibility of the liquid fuel F leaking easily increases easily into the gaps in the joint. Therefore, it is desirable that at least the wall surfaces of these members that are in contact with the liquid fuel F are adjusted to be lower than the surface free energy of the liquid fuel.
- a water repellent film forming process is performed on a wall surface in contact with the liquid fuel such as the fuel container 10 by a coating using a silicon-based, key resin or fluorine-based water repellent. be able to.
- Each fuel cell 20 as a unit cell has a fuel electrode body 21 made of a micro-columnar carbon porous body as shown in FIGS. 4 (a) and 4 (b), and fuel is supplied to the center thereof.
- the fuel electrode body 21 has a through-hole 22 that penetrates the body 30, an electrolyte layer 23 is constructed on the outer surface of the fuel electrode body 21, and an air electrode layer 24 is constructed on the outer surface of the electrolyte layer 23.
- a theoretical electromotive force of about 1.2 V is generated for each fuel cell 20.
- the fine columnar carbon porous body constituting the fuel electrode body 21 may be a porous structure having minute communication holes, for example, a three-dimensional network structure or a point-sintered structure.
- Examples include carbon composite moldings composed of amorphous carbon and carbon powder, isotropic high-density carbon moldings, carbon fiber papermaking moldings, and activated carbon moldings.
- reaction control at the fuel electrode of a fuel cell a carbon composite molded body having fine communication holes made of amorphous carbon and carbon powder is desirable from the viewpoint of easy improvement of reaction efficiency.
- the carbon powder used for the production of the carbon composite having a porous structural force includes highly oriented pyrolytic graphite (HOPG), quiche graphite, natural graphite, artificial graphite from the viewpoint of further improving the reaction efficiency. At least one selected from carbon nanotubes and fullerenes (single or a combination of two or more) is preferred.
- a platinum-ruthenium (Pt—Ru) catalyst an iridium murthenium (Ir Ru) catalyst, a platinum soot (Pt—Sn) catalyst, etc. It is formed by impregnation with a solution containing a metal fine particle precursor such as metal complex or by a reduction treatment after immersion treatment or a method of electrodeposition of metal fine particles.
- Examples of the electrolyte layer 23 include ion-exchange membranes having proton conductivity or hydroxide ion conductivity, for example, fluorine-based ion exchange membranes including naphthion (manufactured by Nafion, Du Pont). Good heat resistance and methanol crossover suppression, for example, a composite film using an inorganic compound as a proton conductive material and a polymer as a film material, specifically using zeolite as an inorganic compound, Examples of the polymer include a composite film having a styrene-butadiene rubber force and a hydrocarbon graft film.
- the air electrode layer 24 a porous structural force or the like in which platinum (Pt), palladium (Pd), rhodium (Rh) or the like is supported by a method using a solution containing the above-mentioned metal fine particle precursor or the like.
- platinum Pt
- palladium Pd
- rhodium Rh
- Examples of the carbon porous material are as follows.
- the fuel supply body 30 is not particularly limited as long as the fuel supply body 30 is inserted into the valve body ib of the fuel reservoir A and has a permeation structure capable of supplying the liquid fuel to each unit cell 20.
- Felt, sponge, porous body having a capillary force composed of sintered bodies such as a sintered body of a resin particle and a sintered fiber fiber, natural fiber, animal fiber, polyacetal resin, acrylic Resin, polyester resin, polyamide resin, polyurethane resin, polyolefin resin, polybule resin, polycarbonate resin, polyether resin, polyolefin resin, etc.
- Examples include one having one or two or more kinds of combined fiber bundles, and the porosity of these porous bodies and fiber bundles is appropriately set according to the amount supplied to each unit cell 20. is there.
- the spent fuel storage tank 40 is arranged at the end of the fuel supply body 30. At this time, even if the spent fuel storage tank 40 is brought into direct contact with the end of the fuel supply body 30 and the spent fuel is directly occluded by the occlusion body, etc. Or a porous body or a fiber bundle may be provided as a relay core to form a spent fuel discharge passage.
- liquid fuel supplied by the fuel supply body 30 is used for the reaction in the fuel cell 20, and the fuel supply amount is linked to the fuel consumption amount.
- liquid fuel that is not used in the reaction can be stored in the storage tank 40 to prevent an obstructive reaction when it reaches oversupply due to operating conditions.
- 50 connects the fuel reservoir A and the spent fuel storage tank 40, and reliably supplies liquid fuel directly from the fuel storage tank 10 to each of the unit cells 20, 20 via the fuel supply body 30. It is a powerful member such as a mesh structure.
- the fuel cell using the fuel reservoir A configured as described above is supplied from the fuel reservoir A to the fuel supply body 30 inserted into the valve body 11a serving as a fuel outlet, and the liquid fuel is supplied by the permeation structure. It is introduced into the fuel battery cells 20 and 20.
- the fuel reservoir A that can be connected to the fuel cell main body includes a tube-type fuel storage container 10 that stores the liquid fuel F, a fuel outflow portion 11, and a rear end portion of the liquid fuel F.
- the liquid fuel F is sealed and provided with a follower 12 that moves as the liquid fuel F is consumed, and a fuel storage chamber 13 in which the inside of the fuel storage container 10 is sealed at least by the follower 12, and an outside air Is provided with a pressurizing chamber 14 that seals the follower 12 in a state of being isolated and sealed, so that the fuel reservoir A is heated and the temperature of the liquid fuel F is increased.
- the opposite side of the follower 12 that seals the liquid fuel F also pushes the follower 12 in the pressurizing chamber 14. Since the volatile liquid G as a stage is heated and pressurized to the saturated vapor pressure of the liquid fuel F, And thus capable of preventing boiling body fuel F. More specifically, in the fuel cell fuel reservoir A having the structure in which the liquid fuel F according to the present invention is sealed by the follower 12, the rear end portion of the fuel storage container (tank) 11 is sealed.
- a volatile liquid G which serves as a means to press the follower 12 having a higher vapor pressure than the liquid fuel F, is sealed in the pressurizing chamber 14, and the liquid fuel F is passed through the follower 12 by the vapor pressure of the volatile liquid G that is sealed. Can be pressurized. This prevents the liquid fuel from leaking and evaporating from the fuel reservoir A due to vaporization of the liquid fuel F that does not boil even when the temperature of the liquid fuel F reaches the boiling point under atmospheric pressure. .
- a check valve that serves as a top closed valve Open and replace air.
- At least the fuel electrode body 21 and Z or the fuel supply body 30 in contact with the fuel electrode body 21 has a capillary force, and this unit force causes each unit cell from the fuel storage chamber 13. It will be possible to supply fuel stably and continuously without causing backflow or disruption of liquid fuel directly to 20 and 20 respectively. More preferably, by setting the fuel electrode body 21 and ⁇ or the capillary force of the fuel supply body 30 in contact with the fuel electrode body 21 and the capillary force of the spent fuel storage tank 40, the fuel storage chamber 13, each unit cell 20, It will be possible to create a stable and continuous fuel flow without any direct backflow or disruption of liquid fuel directly from 20 to the spent fuel storage tank.
- this fuel cell has a structure that can smoothly supply liquid fuel without vaporization without using a pump, blower, fuel vaporizer, condenser and other auxiliary devices. It is possible to reduce the size.
- the entire fuel cell can be cartridged, and a small fuel cell that can be used as a power source for portable electronic devices such as a mobile phone and a notebook personal computer is provided. It will be.
- the power using two fuel cells 20 is shown.
- the number of connected fuel cells 20 (in series or parallel) is increased to obtain the required electromotive force, etc. be able to.
- FIG. 5 shows a fuel reservoir according to the second embodiment of the present invention.
- the same components and effects as those of the fuel cell fuel reservoir of the first embodiment are denoted by the same reference numerals as those in FIG. 1 and the description thereof is omitted.
- the liquid fuel consumption rate is high, or a tube-type fuel container 10 having a large diameter is used to mount a large amount of liquid fuel. From the fuel reservoir ⁇ ⁇ due to the vaporization of the liquid fuel F, which makes the body follow well without causing follow-up, and does not boil even when the temperature of the liquid fuel F reaches the boiling point under atmospheric pressure 1 shows a preferred embodiment for preventing leakage and evaporation of liquid fuel.
- the fuel storage body B of the second embodiment includes a cylindrical follow-up auxiliary member 1 as a follow-up body 12 to be used. It is different from the first embodiment only in that 2a is inserted, and is used in the same manner as in the first embodiment.
- auxiliary member 12a for example, polypropylene, ethylene butyl alcohol copolymer resin, polyacryl-tolyl, nylon, polyethylene terephthalate, polycarbonate, polystyrene, polyvinyl chloride, polyvinyl chloride, various rubbers, etc.
- the power can also be composed.
- Examples of the shape of the follow-up auxiliary member 12a include a cylindrical shape, a quadrangular prism shape, a triangular prism shape, a spherical shape, or a shape similar to the cross section of the fuel reservoir, and the length thereof is 30 to 70% is preferable.
- the fuel consumption speed is high, and the diameter of the fuel container such as a tube type is large.
- the follower 12 in which the follow-up auxiliary member 12a is inserted moves without causing follow-up due to fuel consumption by power generation of the fuel cell.
- the fuel reservoir liquid fuel
- the opposite side of the follower 12 that seals the liquid fuel F will be supported.
- the volatile liquid G which serves as a means for pressing the follower 12 in the pressurizing chamber 14
- the boiling of the liquid fuel F is prevented. To do is to become a satire.
- FIG. 6 shows another embodiment (third embodiment) of the fuel cell fuel reservoir according to the present invention.
- the fuel reservoir C for a fuel cell according to the third embodiment is configured so that the fuel outflow portion 11 according to the first embodiment is made of an elastic member such as a spring member or a spring member.
- the valve body 60 is structured to be closed by a natural body and opened by inserting a liquid fuel supply member.
- This valve body 60 has a valve receiving portion 6 la in a main body portion 61, and a valve member 63 having a reverse T-shaped cross section is constantly biased to the valve receiving portion 61 by an elastic body 62 such as a spring member or a spring member.
- the liquid fuel supply member 30 is closed and is opened to supply liquid fuel.
- the sealing body 16 at the upper end has a valve body that also has the slit valve force of FIG. [0045]
- the fuel inserted into the valve body 60 serving as the fuel outflow portion 11 in addition to the fuel reservoir C is the same as in the first embodiment.
- the fuel reservoir C of this embodiment which is supplied to the feeder 30 and introduces liquid fuel into the fuel cells 20 and 20 by the permeation structure, is heated to a high temperature state.
- liquid fuel can be prevented from boiling, bubble formation, fuel blowout, etc., and liquid fuel can be stably supplied directly to the fuel cell body. There is no loss and the fuel cell can be miniaturized.
- This embodiment differs from the first embodiment in that it is connected to the fuel supply body 30 via a fuel supply pipe 31 inserted into the valve body 11a as shown in FIGS. 7 and 8. It is. Although not shown, the tip of the fuel supply body 30 (in the direction of the arrow in FIGS. 7 and 8) is connected in series or in parallel to the fuel cells 20, 20... As in the first embodiment (FIG. 3). It has a structure.
- a fuel cell fuel reservoir that can stably supply liquid fuel directly to the battery body, eliminates the loss of liquid fuel even when stored at high temperatures, and can reduce the size of the fuel cell. Provided.
- the fuel cell storage body of the present invention can be variously modified within the scope of the technical idea of the present invention, which is not limited to the above embodiments.
- the fuel cell 20 may have a cylindrical shape, a prismatic shape, or a plate-like shape, and the fuel supply cell 30 may be connected not only in series but also in parallel. It may be.
- the fuel outlet portion having the valve body 11a shown in FIGS. 2 (a) to (h) is used, but it is directly accommodated in the fuel storage tank 10 due to atmospheric pressure, temperature change, etc. Liquid This is to prevent foreign substances such as air entering the fuel F from the vicinity of the fuel supply pipe 31, and is particularly limited as long as the fuel supply 30 is inserted and liquid fuel can be supplied to the fuel supply 30. Is not to be done.
- the direct methanol type fuel cell has been described.
- the fuel storage body can be connected to the fuel cell main body, and the fuel storage body stores the liquid fuel in the fuel storage body.
- a trailing body that seals the liquid fuel at the rear end of the liquid fuel and moves as the liquid fuel is consumed the present invention provides the direct methanol
- the present invention can be suitably applied to a high molecular reforming membrane type fuel cell including a reforming type that is not limited to the type of fuel cell, and has a large capacity (for example, 100 ml or more). If the diameter of a tube-type fuel container is increased when mounting liquid fuel, the amount of the follower is increased accordingly, or a follow-up auxiliary member is inserted as in the second embodiment. To cause the follower to follow up. Nag can be good follow-up.
- an electrolyte layer was constructed on the outer surface portion of the fuel electrode body made of a fine carbon porous body, and the fuel cell body was constructed by constructing an air electrode layer on the outer surface portion of the electrolyte layer.
- the structure of the fuel cell main body is not particularly limited.
- a fuel cell having a structure in which liquid fuel is infiltrated into the base material via a fuel supply body, and also has a structural force to expose the electrode surface formed on the outer surface of the base material to air The main body may be used.
- Tube 1 Length 100mm, outer diameter 8mm, inner diameter 6mm, polypropylene extruded tube [0051] (Composition of fuel outlet)
- Example 1 slit valve, according to figure 2
- valve body 61 made of polypropylene, elastic body 62
- valve body 63 Polypropylene
- a gel-like follower (specific gravity 0.90) having the following composition was used.
- Mineral oil Diana process oil MC—W90 (made by Idemitsu Kosan Co., Ltd.) 93 parts by weight
- Hydrophobic silica Aerosil R-974D 6 parts by weight
- Silicone surfactant SILWET FZ-2171 1 part by weight
- the liquid fuel reservoir of the present invention can be used for fuel storage in a small fuel cell suitable for use as a power source for portable electronic devices such as mobile phones, notebook computers and PDAs. .
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Closures For Containers (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05765062A EP1770808A4 (en) | 2004-06-25 | 2005-06-27 | FUEL CELL FUEL STORAGE BODY |
JP2006528666A JP4956186B2 (ja) | 2004-06-25 | 2005-06-27 | 燃料電池用燃料貯留体 |
US11/629,874 US7727657B2 (en) | 2004-06-25 | 2005-06-27 | Fuel reservoir for fuel cell |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004188178 | 2004-06-25 | ||
JP2004-188178 | 2004-06-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006001418A1 true WO2006001418A1 (ja) | 2006-01-05 |
Family
ID=35781854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/011732 WO2006001418A1 (ja) | 2004-06-25 | 2005-06-27 | 燃料電池用燃料貯留体 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7727657B2 (ja) |
EP (1) | EP1770808A4 (ja) |
JP (1) | JP4956186B2 (ja) |
KR (1) | KR100840046B1 (ja) |
CN (1) | CN100454642C (ja) |
WO (1) | WO2006001418A1 (ja) |
Cited By (2)
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JP2010015936A (ja) * | 2008-07-07 | 2010-01-21 | Casio Comput Co Ltd | 燃料供給装置及び燃料供給システム |
US20100279205A1 (en) * | 2007-12-28 | 2010-11-04 | Sony Corporation | Fuel cartridge, fuel cell, and electronic device |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5063935B2 (ja) * | 2006-06-02 | 2012-10-31 | 東洋製罐株式会社 | 燃料電池カートリッジ用ポリエステル製容器 |
US8518599B2 (en) * | 2010-03-02 | 2013-08-27 | Microvast, Inc. | Fuel and oxidant storage device and fuel cell system employing the same |
GB2579779B (en) * | 2018-12-12 | 2021-05-05 | Dha Contracting Ltd | Power generation for subsea marine applications |
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- 2005-06-27 JP JP2006528666A patent/JP4956186B2/ja not_active Expired - Fee Related
- 2005-06-27 WO PCT/JP2005/011732 patent/WO2006001418A1/ja active Application Filing
- 2005-06-27 EP EP05765062A patent/EP1770808A4/en not_active Withdrawn
- 2005-06-27 US US11/629,874 patent/US7727657B2/en not_active Expired - Fee Related
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JP2010015936A (ja) * | 2008-07-07 | 2010-01-21 | Casio Comput Co Ltd | 燃料供給装置及び燃料供給システム |
Also Published As
Publication number | Publication date |
---|---|
KR20070041719A (ko) | 2007-04-19 |
EP1770808A1 (en) | 2007-04-04 |
EP1770808A4 (en) | 2009-05-13 |
KR100840046B1 (ko) | 2008-06-19 |
US7727657B2 (en) | 2010-06-01 |
CN1977414A (zh) | 2007-06-06 |
JPWO2006001418A1 (ja) | 2008-04-17 |
US20080292915A1 (en) | 2008-11-27 |
CN100454642C (zh) | 2009-01-21 |
JP4956186B2 (ja) | 2012-06-20 |
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