WO2004113600A1 - Drawing method and apparatus - Google Patents

Drawing method and apparatus Download PDF

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Publication number
WO2004113600A1
WO2004113600A1 PCT/JP2004/008457 JP2004008457W WO2004113600A1 WO 2004113600 A1 WO2004113600 A1 WO 2004113600A1 JP 2004008457 W JP2004008457 W JP 2004008457W WO 2004113600 A1 WO2004113600 A1 WO 2004113600A1
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WO
WIPO (PCT)
Prior art keywords
fiber bundle
support
fiber
roller
heating
Prior art date
Application number
PCT/JP2004/008457
Other languages
French (fr)
Japanese (ja)
Inventor
Takaaki Suzuki
Takafumi Kouno
Akinori Nemoto
Takatoshi Suzuki
Original Assignee
Denki Kagaku Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo Kabushiki Kaisha filed Critical Denki Kagaku Kogyo Kabushiki Kaisha
Priority to JP2005507220A priority Critical patent/JP4263721B2/en
Publication of WO2004113600A1 publication Critical patent/WO2004113600A1/en

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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J13/00Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch

Definitions

  • the present invention relates to a method and an apparatus for drawing synthetic fibers, and in particular, is used for decorating hair such as wigs, hairpieces, blades, and extension hair, or used for various dolls as a doll hair.
  • the present invention relates to a stretching method and a stretching apparatus for obtaining artificial hair.
  • a synthetic fiber drawing device As a synthetic fiber drawing device, a first roller for supplying fibers, a second roller for drawing fibers, and a roller between the first roller and the second roller are provided.
  • a heating tank having a resistor provided with a resistance is known (for example, see Patent Document 1).
  • the degree of engagement between the resistor and the fiber that imparts running resistance to the fiber is adjusted by adjusting means so that the running resistance applied to the fiber from the resistor can be adjusted.
  • the unstretched fibers are 120 to 320 denier and have a fiber diameter larger than that of synthetic fibers for general use.
  • the expression of softening due to heating is significantly different from synthetic fibers that use other raw materials.
  • the obtained product is a special field called artificial hair, and extremely strict quality control is required. Was extremely difficult.
  • Whitening of a fiber is a phenomenon in which when a fiber is stretched, a resin composition constituting the fiber is cut microscopically, and the surface of the fiber becomes white. Progress Or a phenomenon in which the fibers themselves are cut as a result of excessive melting or melting.
  • Patent Document 1 Japanese Patent No. 3274253
  • the present invention solves the above-mentioned conventional problems, that is, a stretching method and a stretching method capable of preventing fiber whitening and yarn breakage even when stretching a fiber bundle composed of 120 or more single fibers. It is intended to provide a device.
  • the present inventors have conducted intensive studies and as a result, by providing a resistance applying device for deforming the fiber bundle into a belt shape and applying sliding resistance at a specific position of the heating tank, the fiber bundle can be uniformly heated and softened.
  • the present inventors have found that the fibers can be whitened and that fiber whitening and yarn breakage can be prevented, and the present invention has been accomplished.
  • the drawing method of the present invention supplies a fiber bundle of synthetic fibers to a first roller and then rotates the fiber bundle at a peripheral speed higher than that of the first roller.
  • the fiber bundle is supplied to the rotating second roller to stretch the fiber bundle, the fiber bundle is introduced into a hollow box-shaped heating tank disposed between the first roller and the second roller to heat the fiber bundle.
  • the width of the fiber bundle is widened in a strip shape in the heating tank, and the fiber bundle is heated by contact heating.
  • the drawing method of the present invention differs from the drawing method of claim 1 in that the synthetic fiber is made of a polychlorinated vinyl resin. is there.
  • the drawing method of the present invention is the drawing method of claim 2, wherein the synthetic fiber is a synthetic fiber for artificial hair.
  • the drawing device of the present invention as described in claim 4, a first roller for supplying a fiber bundle of synthetic fibers, and rotates at a peripheral speed higher than the first roller.
  • a second roller that stretches the fiber bundle by a peripheral speed difference from the first roller, and a fiber roller that is disposed between the second roller and the second roller and that introduces the fiber bundle into the inside to heat and soften the fiber bundle
  • a synthetic fiber drawing apparatus having a hollow box-shaped heating tank, the fiber bundle is heated in the heating tank and a sliding resistance is applied to the fiber bundle while widening the fiber bundle in a band shape.
  • a heating resistance-imparting device comprising a plurality of supports each capable of being heated and a pressurizable body which can be heated, which is provided near the middle between two adjacent supports.
  • the pressurizing members are both rod-like members placed in parallel with the axis of the second roller and are in contact with the respective fiber bundles.
  • the pressurizing member is a fiber bundle of two supports adjacent to the pressurizing member. This is a stretching device that is placed away from a plane that includes both sliding surfaces.
  • the stretching apparatus of the present invention is the stretching apparatus according to claim 4, wherein the stretching apparatus has two support members and one pressing body.
  • the first support installed on the upstream side in the fiber bundle traveling direction is disposed at a position between the fiber bundle inlet of the heating tank and the center of the heating tank, and the second support
  • the body is disposed at a distance of 65550 mm from the first support in a downstream direction in the fiber bundle advance direction
  • the pressurizing body is arranged between the fiber bundle sliding contact surface of the first support and the second support.
  • This drawing device is disposed at a position on the plane including the fiber bundle sliding contact surface, which is vertically separated from the first support by 10 200 mm from a position of 50 350 mm in a downstream direction of the fiber bundle in the traveling direction of the fiber bundle.
  • both the support and the pressurized body are used.
  • This is a stretching device that can be heated by the electric energy supplied to it.
  • the stretching apparatus of the present invention is, as described in claim 7, in the stretching apparatus according to claim 4 or claim 5, wherein both the support and the pressurized body are externally connected to the support and the pressurizing body. It is a stretching device that can be heated by the heating fluid supplied inside the pressure body
  • the drawing device of the present invention is the same as the drawing device according to any one of claims 4 to 7, wherein the synthetic fiber is a polychlorinated vinyl resin.
  • This is a stretching device that is made of steel.
  • the stretching apparatus of the present invention is the stretching apparatus according to claim 8, wherein the synthetic fibers are synthetic fibers for artificial hair.
  • the surface layer and the center of the fiber bundle can be uniformly heated. Even in the core portion, as in the surface layer portion, it is possible to perform drawing without causing both whitening and thread breakage of the fiber.
  • both the surface layer portion and the center portion of the fiber bundle can be uniformly heated. Even in the central portion, as in the case of the surface layer portion, it is possible to extend the fiber without causing both whitening and thread breakage of the fiber.
  • FIG. 1 is a cross-sectional view schematically showing a main part of a synthetic fiber drawing apparatus (Example 1) according to the present invention.
  • FIG. 2 is a partial perspective view schematically showing the state of a resistance applying device 4 and a fiber bundle 5 of synthetic fibers in Example 1.
  • FIG. 3 is a model diagram showing an example in which a first support can be heated by electric energy supplied thereto.
  • FIG. 4 is a model diagram showing an example in which heating can be performed by a heating fluid supplied from the outside to the inside of the support.
  • FIG. 5 is an enlarged sectional view of a model in the vicinity of a heating / resistance applying device 4 of a heating tank 3.
  • the heating / resistance applying device is used for sandwiching a fiber bundle having a circular cross section from above and below or right and left to widen and deform it into a band shape, and to provide sliding resistance to the fiber bundle.
  • the fiber bundle that has been subjected to the widening deformation is effectively heated.
  • the shape of the resistance applying device includes a plurality of supports that can be heated, and a pressurizable body that can be heated and is provided at or near the middle of two adjacent supports. .
  • the heating and resistance imparting device expands and deforms the fiber bundle in a belt-like shape, thereby bringing the surface layer portion and the center portion of the fiber bundle close to each other and uniformly heating and softening the entire fiber bundle. Further, by giving sliding resistance to the fiber bundle, the drawing start position of the fiber is fixed so that the fiber can be drawn uniformly.
  • the plurality of rod-shaped supports in the heating and resistance applying device usually have a contact surface with the fiber on a plane including the fiber bundle contact surface of the first roller and the fiber bundle contact surface of the second roller. However, this does not apply when it is necessary to manufacture the equipment or when it is intended to provide particularly high sliding resistance.
  • the shapes of the support and the pressurizing body in the present invention are not particularly limited as long as the effects of the present invention are not impaired.
  • these are contact members that come into contact with the fiber bundle, they have a smooth shape.
  • a rod, plate, or the like having a circular, elliptical, or polygonal cross section may be used, and one or a combination of these may be employed.
  • the diameter is 10-150 mm
  • the thickness is 5-30 mm. It is desirable to have done it.
  • Examples of the material of the support and the pressing body in the present invention include metal materials such as iron, stainless steel, copper, and brass, and inorganic materials such as ceramics. Just fine.
  • the materials of the support and the pressing body in the present invention need to be heatable. Caro Even if the temperature of the heating tank is large, even if the temperature of the heating tank is huge, even if the temperature of the heating tank is enormous, it is not possible to sufficiently heat the fiber itself. Since the support and the heating element that come into contact with the fiber bundle are heated, the fiber bundle is Can be reliably heated up to the part.
  • Heating of the support and the pressurized body can be performed by resistance heating or the like using electric energy supplied thereto, or heating as a heat medium supplied from the outside to the inside thereof. It can be performed with a working fluid.
  • the production cost of the support, the pressurized body and the equipment for heating them is reduced, and the force running cost is increased.
  • the heating fluid is easily heated, so that the running cost is lower than in the former case, and the manufacturing cost of these supports, pressurizing bodies and equipment for heating them is higher.
  • means for heating and softening the fiber bundle may be a conventionally known means, for example, electric heating, steam, hot water, hot oil and the like.
  • the heating temperature may be appropriately set according to the material of the synthetic fiber to be drawn.
  • the fiber bundle when the fiber bundle is introduced into the hollow box-shaped heating tank disposed between the first roller and the second roller to be heated and softened, the fiber bundle is strip-shaped in the heating tank.
  • the contact heating by bringing the fiber bundle into contact with the heated contact member, that is, the support and the pressurized body that were heated together, could not be achieved by heating in the heating tank alone.
  • Sufficient heating of the fiber in the center of the fiber bundle is also possible, and as a result, it is possible to stretch the film at a predetermined magnification by the first roller and the second roller while preventing whitening and yarn breakage. .
  • Examples of the synthetic resin used in the stretching method and the stretching apparatus of the present invention include a conventionally known synthetic resin that can be molded as a fiber, such as a polystyrene resin, a polyphenylene ether resin, a polyolefin resin, a polyamide resin, and a polyester. Resin, polyphenylene sulfide resin, polymethacrylate resin, polyvinyl chloride resin and the like.
  • polystyrene resins include polystyrene, polystyrene-acrylonitrile copolymer, styrene- (meth) atalylate copolymer and the like.
  • Polyphenylene ether resins include poly (2,6_dimethyl-1,4-phenylene ether), poly (2,6-getyl-1,4_phenylene ether), and poly (2-methyl_6_ Ethyl-1, 4-phenylene ether).
  • Polyolefin resins include polyethylene and polypropylene. Examples of the polyamide resin include nylon 6, nylon 66, and the like. Polyester resins include polyalkylene terephthalate, polyarylate, polycarbonate And others. Examples of the polymethacrylate resin include polymethyl methacrylate and polybutyl methacrylate.
  • polyvinyl chloride resin polyvinyl chloride homopolymer, vinyl chloride vinylidene chloride copolymer, vinyl chloride acrylonitrile copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-propylene copolymer,
  • a butyl chloride-alkyl butyl ether copolymer a butyl chloride monoacetic acid butyl copolymer, a butyl chloride monoacrylate copolymer, a vinyl chloride-maleic acid ester copolymer and the like.
  • additives used in the polyvinyl chloride resin composition may be used according to the purpose without impairing the effects of the present invention.
  • Additives include processing aids, strengthening agents, ultraviolet absorbers, antioxidants, antistatic agents, fillers, flame retardants, pigments, initial color improvers, conductivity-imparting agents, surface treatment agents, light stabilizers, There are fragrances.
  • the first support member installed on the upstream side in the traveling direction of the fiber bundle is the first support member.
  • the fiber bundle supplied from one roller is stably introduced into the fiber bundle inlet of the heating tank.
  • the fiber bundle cannot be stably introduced into the heating tank, causing fiber whitening and yarn breakage.
  • the fiber bundle is located downstream of the center of the heating tank in the direction in which the fiber bundle travels, the fiber bundle vibrates at the time of drawing, causing whitening or breakage of the fiber. It should be located between the center of the tank.
  • the second support which is provided downstream of the first support in the direction of travel of the fiber bundle, discharges the fiber bundle, to which sliding resistance has been imparted by the pressurizing body described later, from the heating tank. This is for stable discharge from the exit.
  • the installation position of the second support depends on the total length of the heating tank and the moving speed of the fiber east, but the first support is also located at a position of 65-55 Omm in the downstream direction in the fiber bundle traveling direction. Is preferred.
  • the position is less than 65 mm, the resistance to covering the fiber bundle becomes too large, and the fiber breaks.
  • the position is more than 550 mm, the fiber bundle expands and deforms into a belt shape. As a result, the fibers are not uniformly heated and whitening of the fibers occurs.
  • Pressurizing The pressurizing body of the resistance applying device, together with the first support and the second support, is cut off. This is for sandwiching a plane-shaped fiber bundle, widening and deforming it into a belt shape, and for imparting sliding resistance to the fiber bundle.
  • the pressing body is 50-degree in the direction downstream of the first supporting member force fiber bundle advancing direction on the plane including the fiber bundle sliding contact surface of the first support and the fiber bundle sliding contact surface of the second support.
  • Position force of 350mm It is desirable to be placed vertically 10-200mm apart.
  • the displacement from the first support in the fiber bundle advancing direction is less than 50 mm, the resistance applied to the fiber bundle becomes too large, and the fiber is likely to be broken. If it is more than 550 mm, the fiber bundle is effective. The band is not widened and deformed, and uniform heating becomes difficult. As a result, the fiber is apt to whiten.
  • the vertical separation distance of the pressurized body from the plane is less than 10 mm, the fiber bundle does not deform into a belt shape, is not uniformly heated, and the fiber is apt to whiten. If the pressure exceeds the limit, the resistance to the fiber bundle becomes too large and the fiber is apt to break, so the vertical distance of the pressurized body from the above plane is preferably 10 to 200 mm.
  • FIGS. 1 and 2 An embodiment of a synthetic fiber drawing apparatus according to the present invention will be described with reference to FIGS. 1 and 2.
  • FIG. 1 is a cross-sectional view schematically showing a main part of a synthetic fiber drawing apparatus (Example 1) according to the present invention.
  • reference numeral 1 denotes a first roller for supplying a fiber bundle 5 of synthetic fibers made of polyvinyl chloride vinyl resin
  • reference numeral 2 denotes a roller that rotates at a higher peripheral speed than the first roller 1.
  • Reference numeral 3 denotes a second roller that stretches the fiber bundle by a peripheral speed difference from the first roller 1, and reference numeral 3 is disposed between the first roller 1 and the second roller 2 to introduce the fiber bundle 5 therein.
  • a hollow box-shaped heating tank 4 for heating and softening (in this example, the total length is 2 m) is shown, and reference numerals 31 and 32 indicate a fiber bundle introduction port and a fiber bundle discharge port of the heating tank 3, respectively.
  • a plurality of supports 41 each capable of heating each fiber (a fiber bundle advance) for heating the fiber bundle 5 and imparting sliding resistance while widening and deforming the fiber bundle 5 in a band shape.
  • the first support installed on the upstream side in the direction, and 4 2 (the second support installed in the downstream direction of the fiber bundle from the first support).
  • a heating / resistance applying device 4 including a heatable pressurizing body 43 provided near the middle between the two supports 41 and 42 is provided.
  • FIG. 2 shows the resistance applying device 4 of Example 1 (both of which are round bars each having a cross-section of a circle having a diameter of 30 mm, made of stainless steel, the first support 41 and the second support 41). 42 and a pressurizing body 43.
  • these heating means are electric heaters incorporated in each of them) and a partial perspective view schematically showing the state of the fiber bundle 5 of synthetic fibers. is there.
  • the arrows in FIGS. 1 and 2 indicate the flow direction of the fiber bundle.
  • FIG. 3 is a model diagram showing a state in which an electric heater is incorporated as a heating means as an example in which the first support can be heated by a supplied current
  • FIG. FIG. 3 is a model diagram showing an example in which heating can be performed by a heating fluid supplied inside.
  • the drawing apparatus of the present invention uses synthetic fibers made of polychlorinated vinyl resin
  • the first support, the second support, and the heating body can be heated to 90 ° C or more and 150 ° C or less. Desirably. If the temperature is lower than 90 ° C, these heating effects are not obtained. On the other hand, if the temperature is higher than 150 ° C, the temperature is too high, and the fibers are melted to cause yarn breakage.
  • the first support, the second support, and the heating element may all be set at the same temperature, or may be set at different temperatures to obtain the best results.
  • the position of 42 and the pressure body 43 can be moved respectively.
  • the first support, the second support, and the pressurizing body can be fixed at desired positions (the distance of the fiber bundle introduction port force and the position in the vertical direction).
  • FIG. 5 which is an enlarged cross-sectional view of the positions of the first support 41, the second support 42, and the pressurizing body 43, that is, the heating / resistance applying device 4 of the heating tank 3, FIG.
  • the distance dl between the fiber bundle introduction port 41 and the first support, and the distance d2, d3 between the first support 41 and the second support are the distance d3 between the first support 41 and the pressing body 43, and 1 Adjust the separation distance of the pressurized body from the plane including the sliding surface of the fiber bundle of the support and the sliding surface of the fiber bundle of the second support (hereinafter also referred to as the “separation distance of the pressed body”), h. The effect on the state of the drawn fiber at that time was examined.
  • a fiber bundle (undrawn yarn) composed of 120 single fibers made of 200 denier and polychlorinated vinyl resin was fed from the first roller 1 into a heating tank 3 heated to 130 ° C. at a speed of 100 m / min. And heated and stretched by a resistance applying device 4 including a first support 41, a second support 42, and a pressurizing body 43, which are heated by a built-in electric heater, and 400 m / min by a second roller. It was pulled at the speed and stretched 4 times. The stretched fiber bundle 100m was visually checked. If none of the whitened fibers was found, it was passed ( ⁇ ), and even if one of the fibers was whitened, it was rejected (X). . In addition, at this time, the case where no thread was broken was judged as pass ( ⁇ ), and the case where even one thread was broken was judged as failed (X). This evaluation is very strict in accordance with the very strict quality control required for artificial hair.
  • Tables 1 and 2 show the results of these experiments.
  • Tables 1 and 2 show the results of these experiments.
  • the distance h of the pressurized body from a plane including the fiber bundle sliding contact surface of the first support and the fiber bundle sliding contact surface of the second support is a positive value.
  • the state in which the first support 41 and the second support 42 are in contact with the fiber bundle from above and the pressing body 43 is in contact with the fiber bundle 5 from below (the state shown in FIG. 1) )
  • the value of the vertical position of the pressing body is a negative value
  • the first support 41 and the second support 42 And the pressing body 43 is in a state of contacting from above.
  • the distance dl between the fiber bundle inlet 41 of the heating tank 3 and the first support is negative, it is determined that the first support is provided outside the Show.
  • Append Distance between first support and second support 400 400 60 600 400 400 400 400 400 400 400 400
  • Tables 1 and 2 show that the stretching apparatus of the present invention can provide fibers suitable for artificial hair without whitening or thread breakage.
  • the present invention it is possible to realize a method and an apparatus for drawing synthetic fibers for artificial hair which can prevent whitening and breakage of fibers even when a fiber bundle composed of 120 or more single fibers is drawn. As a result, the productivity of synthetic fibers for artificial hair could be increased.

Abstract

[PROBLEMS] When a fiber bundle constituted of 120 or more fibers is drawn with a conventional synthetic fiber drawing apparatus, fibers particularly those in the center portion are not sufficiently heated and softened, and this results in fiber whitening and breakage. [MEANS FOR SOLVING PROBLEMS] A synthetic fiber drawing method where, when a synthetic resin fiber bundle is fed to first rollers (1) and then fed for drawing to second rollers (2) rotating at a higher peripheral speed than the first rollers (1), the fiber bundle is led to inside a hollow box-like heating vessel provided between the first rollers and the second rollers. In the heating vessel, the fiber bundle is expanded in width and heated by contact heating.

Description

明 細 書  Specification
延伸方法及び延伸装置  Stretching method and stretching device
技術分野  Technical field
[0001] 本発明は、合成繊維の延伸方法及び延伸装置に係り、特に、ウイッグ、ヘアピース 、ブレード、エクステンションヘアー等の頭髪装飾用等に用いられ、あるいはドールへ ァーなどとして各種人形に用いられる人工毛髪を得るための、延伸方法及び延伸装 置に関するものである。  The present invention relates to a method and an apparatus for drawing synthetic fibers, and in particular, is used for decorating hair such as wigs, hairpieces, blades, and extension hair, or used for various dolls as a doll hair. The present invention relates to a stretching method and a stretching apparatus for obtaining artificial hair.
^景技術  ^ Scenic technology
[0002] 合成繊維の延伸装置としては、繊維を供給する第 1ローラと、繊維を延伸する第 2口 ーラと、これら第 1ローラと第 2ローラとの間に配置され、繊維に走行抵抗を付与する 抵抗体を有する加熱槽からなるものが知られている(例えば、特許文献 1参照)。 これらの延伸装置は、繊維に走行抵抗を付与する抵抗体と繊維との係合度合を調 節手段によって調整し、抵抗体から繊維に付与する走行抵抗を加減できるようにした ものである。これらの延伸装置にあっては、単繊維あるいは数本の繊維を延伸する際 には何ら問題なかった。  [0002] As a synthetic fiber drawing device, a first roller for supplying fibers, a second roller for drawing fibers, and a roller between the first roller and the second roller are provided. A heating tank having a resistor provided with a resistance is known (for example, see Patent Document 1). In these drawing apparatuses, the degree of engagement between the resistor and the fiber that imparts running resistance to the fiber is adjusted by adjusting means so that the running resistance applied to the fiber from the resistor can be adjusted. In these stretching apparatuses, there was no problem when stretching a single fiber or several fibers.
[0003] し力 ながら、未延伸の繊維を 120本以上の繊維束として同時に延伸しょうとすると 、表層部と中心部では均一に加熱できないため、特に中心部の繊維が充分に軟ィ匕さ れないため、その中心部にある繊維の白化や糸切れが発生してしまうという問題があ つた。また、中心部を充分に軟化させようとすると、加熱されすぎた表層部が溶融され て糸切れが生じるという新たな課題が生じた。  [0003] However, if unstretched fibers are to be simultaneously drawn as a bundle of 120 or more fibers while heating, the surface layer and the center cannot be heated uniformly, so that the fibers in the center in particular are sufficiently softened. As a result, there was a problem that the fiber in the center portion was whitened or the yarn was broken. In addition, if the central portion is to be sufficiently softened, a new problem arises in that the surface layer portion that has been excessively heated is melted and thread breakage occurs.
[0004] 特に、ポリ塩化ビュル樹脂製の人工毛髪用合成繊維の場合、未延伸の繊維は 120 一 320デニールであって一般用との合成繊維より比較的繊維径が大きい繊維であり 、さらに、加熱による軟化の発現が他の原料力 成る合成繊維と大きく異なり、また、 得られた製品が人工毛髪と云う特殊な分野であるとともに、極めて厳しい品質管理が 求められるため、他分野の技術の応用が極めて困難であった。  [0004] In particular, in the case of synthetic fibers for artificial hair made of polychlorinated vinyl resin, the unstretched fibers are 120 to 320 denier and have a fiber diameter larger than that of synthetic fibers for general use. The expression of softening due to heating is significantly different from synthetic fibers that use other raw materials.The obtained product is a special field called artificial hair, and extremely strict quality control is required. Was extremely difficult.
[0005] 繊維の白化とは繊維が延伸された際に、繊維を構成する樹脂組成物がミクロ的に 切断して繊維の表面が白くなつてしまう現象をいい、糸切れとは、白化現象が進行し たり、溶融しすぎた結果、繊維自体が切断してしまう現象を云う。 [0005] Whitening of a fiber is a phenomenon in which when a fiber is stretched, a resin composition constituting the fiber is cut microscopically, and the surface of the fiber becomes white. Progress Or a phenomenon in which the fibers themselves are cut as a result of excessive melting or melting.
特許文献 1:特許第 3274253号公報  Patent Document 1: Japanese Patent No. 3274253
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems the invention is trying to solve
[0006] 本発明は、上記した従来の問題点を改善する、すなわち、 120本以上の単繊維か らなる繊維束を延伸する際でも、繊維の白化や糸切れを防止できる延伸方法及び延 伸装置を提供することを目的とする。 [0006] The present invention solves the above-mentioned conventional problems, that is, a stretching method and a stretching method capable of preventing fiber whitening and yarn breakage even when stretching a fiber bundle composed of 120 or more single fibers. It is intended to provide a device.
課題を解決するための手段  Means for solving the problem
[0007] 本発明者等は、鋭意検討した結果、繊維束を帯状に変形させると共に摺動抵抗を 付与させる抵抗付与装置を加熱槽の特定の位置に設けることにより、繊維束を均一 に加熱軟ィ匕することができ、繊維の白化や糸切れを防止できることを見出し本発明に 至った。 [0007] The present inventors have conducted intensive studies and as a result, by providing a resistance applying device for deforming the fiber bundle into a belt shape and applying sliding resistance at a specific position of the heating tank, the fiber bundle can be uniformly heated and softened. The present inventors have found that the fibers can be whitened and that fiber whitening and yarn breakage can be prevented, and the present invention has been accomplished.
[0008] すなわち、本発明の延伸方法は上記課題を解決するため、請求項 1に記載の通り 、合成繊維の繊維束を第 1ローラに供給した後、該第 1ローラより大きい周速度で回 転する第 2ローラに供給して前記繊維束を延伸させる際に、該繊維束を該第 1ローラ と該第 2ローラとの間に配置した中空箱状の加熱槽の内部に導入して加熱軟化させ る合成繊維の延伸方法において、上記加熱槽内で、上記繊維束を帯状にその幅を 広げると共に、該繊維束を接触加熱により加熱する合成繊維の延伸方法である。  [0008] That is, in order to solve the above-mentioned problems, the drawing method of the present invention supplies a fiber bundle of synthetic fibers to a first roller and then rotates the fiber bundle at a peripheral speed higher than that of the first roller. When the fiber bundle is supplied to the rotating second roller to stretch the fiber bundle, the fiber bundle is introduced into a hollow box-shaped heating tank disposed between the first roller and the second roller to heat the fiber bundle. In the method for stretching a synthetic fiber to be softened, the width of the fiber bundle is widened in a strip shape in the heating tank, and the fiber bundle is heated by contact heating.
[0009] また、本発明の延伸方法は請求項 2に記載の通り、請求項 1に記載の延伸方法に ぉレ、て、前記合成繊維がポリ塩化ビュル樹脂製である合成繊維の延伸方法である。  [0009] Further, as described in claim 2, the drawing method of the present invention differs from the drawing method of claim 1 in that the synthetic fiber is made of a polychlorinated vinyl resin. is there.
[0010] また、本発明の延伸方法は請求項 3に記載の通り、請求項 2に記載の延伸方法に おいて、前記合成繊維が人工毛髪用合成繊維である合成繊維の延伸方法である。  [0010] Further, as set forth in claim 3, the drawing method of the present invention is the drawing method of claim 2, wherein the synthetic fiber is a synthetic fiber for artificial hair.
[0011] また、本発明の延伸装置は上記課題を解決するため、請求項 4に記載の通り、合 成繊維の繊維束を供給する第 1ローラ、該第 1ローラより大きい周速度で回転し該第 1ローラとの周速度差により該繊維束を延伸する第 2ローラ、及び、該第丄ローラと該 第 2ローラとの間に配置され該繊維束をその内部に導入して加熱軟化するための中 空箱状の加熱槽を有する合成繊維の延伸装置において、上記加熱槽内に、該繊維 束を加熱するとともに該繊維束に帯状に拡幅変形させながら摺動抵抗を付与するた めの、それぞれ加熱可能な複数の支持体と、隣り合う 2つの支持体の中間付近に設 けられた、加熱可能な加圧体とからなる加熱'抵抗付与装置が設けられ、これら支持 体及び加圧体はともに上記第 2ローラの軸に平行に設置された棒状体であってそれ ぞれ該繊維束に接し、加圧体は、その加圧体に隣接する 2つの支持体の繊維束摺 接面を共に含む平面から離間して配置されている延伸装置である。 [0011] Further, in order to solve the above-mentioned problems, the drawing device of the present invention, as described in claim 4, a first roller for supplying a fiber bundle of synthetic fibers, and rotates at a peripheral speed higher than the first roller. A second roller that stretches the fiber bundle by a peripheral speed difference from the first roller, and a fiber roller that is disposed between the second roller and the second roller and that introduces the fiber bundle into the inside to heat and soften the fiber bundle In a synthetic fiber drawing apparatus having a hollow box-shaped heating tank, the fiber bundle is heated in the heating tank and a sliding resistance is applied to the fiber bundle while widening the fiber bundle in a band shape. For this purpose, there is provided a heating resistance-imparting device comprising a plurality of supports each capable of being heated and a pressurizable body which can be heated, which is provided near the middle between two adjacent supports. The pressurizing members are both rod-like members placed in parallel with the axis of the second roller and are in contact with the respective fiber bundles. The pressurizing member is a fiber bundle of two supports adjacent to the pressurizing member. This is a stretching device that is placed away from a plane that includes both sliding surfaces.
[0012] また、本発明の延伸装置は請求項 5に記載の通り、請求項 4に記載の延伸装置に おいて、上記支持体を 2つ、加圧体を 1つ有する延伸装置であって、これら 2つの支 持体のうち、繊維束進行方向上流側に設置された第 1支持体が、加熱槽の繊維束導 入口と加熱槽の中央との間の位置に配置され、第 2支持体は、該第 1支持体から繊 維束進行方向下流の方向へ 65 550mmの位置に配置され、かつ、加圧体が、該 第 1支持体の繊維束摺接面と第 2支持体の繊維束摺接面とを含む平面の、第 1支持 体から繊維束進行方向下流の方向に 50 350mmの位置から垂直に 10 200mm 離間した位置に配置されている延伸装置である。  [0012] Further, as described in claim 5, the stretching apparatus of the present invention is the stretching apparatus according to claim 4, wherein the stretching apparatus has two support members and one pressing body. Of these two supports, the first support installed on the upstream side in the fiber bundle traveling direction is disposed at a position between the fiber bundle inlet of the heating tank and the center of the heating tank, and the second support The body is disposed at a distance of 65550 mm from the first support in a downstream direction in the fiber bundle advance direction, and the pressurizing body is arranged between the fiber bundle sliding contact surface of the first support and the second support. This drawing device is disposed at a position on the plane including the fiber bundle sliding contact surface, which is vertically separated from the first support by 10 200 mm from a position of 50 350 mm in a downstream direction of the fiber bundle in the traveling direction of the fiber bundle.
[0013] また、本発明の延伸装置は請求項 6に記載の通り、請求項 4または請求項 5に記載 の延伸装置において、上記支持体及び加圧体がともに、これら支持体及び加圧体に 供給される電気エネルギーにより加熱可能となっている延伸装置である。  [0013] Further, as described in claim 6, in the stretching apparatus according to the present invention, in the stretching apparatus according to claim 4 or 5, both the support and the pressurized body are used. This is a stretching device that can be heated by the electric energy supplied to it.
[0014] また、本発明の延伸装置は請求項 7に記載の通り、請求項 4または請求項 5に記載 の延伸装置において、上記支持体及び加圧体がともに、外部からこれら支持体及び 加圧体の内部に供給される加熱用流体により加熱可能となっている延伸装置である  [0014] Further, the stretching apparatus of the present invention is, as described in claim 7, in the stretching apparatus according to claim 4 or claim 5, wherein both the support and the pressurized body are externally connected to the support and the pressurizing body. It is a stretching device that can be heated by the heating fluid supplied inside the pressure body
[0015] また、本発明の延伸装置は請求項 8に記載の通り、請求項 4ないし請求項 7のいず れかに記載の延伸装置にぉレ、て、前記合成繊維がポリ塩化ビュル樹脂製である延 伸装置である。 [0015] Further, as set forth in claim 8, the drawing device of the present invention is the same as the drawing device according to any one of claims 4 to 7, wherein the synthetic fiber is a polychlorinated vinyl resin. This is a stretching device that is made of steel.
[0016] また、本発明の延伸装置は請求項 9に記載の通り、請求項 8に記載の延伸装置に おいて前記合成繊維が人工毛髪用合成繊維である延伸装置である。  [0016] Further, as described in claim 9, the stretching apparatus of the present invention is the stretching apparatus according to claim 8, wherein the synthetic fibers are synthetic fibers for artificial hair.
発明の効果  The invention's effect
[0017] 本発明の延伸方法によれば、 120本以上の繊維束を同時に延伸しょうとした場合 であって、繊維束の表層部及び中心部を共に均一に加熱できるので、繊維束の中 心部であっても、表層部と同様に、繊維の白化及び糸切れが共に発生しない延伸が 可能となる。 According to the drawing method of the present invention, when 120 or more fiber bundles are to be simultaneously drawn, the surface layer and the center of the fiber bundle can be uniformly heated. Even in the core portion, as in the surface layer portion, it is possible to perform drawing without causing both whitening and thread breakage of the fiber.
[0018] また、本発明の延伸装置によれば、 120本以上の繊維束を同時に延伸しょうとした 場合であって、繊維束の表層部及び中心部を共に均一に加熱できるので、繊維束 の中心部であっても、表層部と同様に、繊維の白化及び糸切れが共に発生しない延 伸が可能となる。  [0018] Further, according to the drawing apparatus of the present invention, in a case where 120 or more fiber bundles are to be simultaneously drawn, both the surface layer portion and the center portion of the fiber bundle can be uniformly heated. Even in the central portion, as in the case of the surface layer portion, it is possible to extend the fiber without causing both whitening and thread breakage of the fiber.
図面の簡単な説明  BRIEF DESCRIPTION OF THE FIGURES
[0019] [図 1]本発明に係る合成繊維の延伸装置 (実施例 1)の主要部を模式的に示した断面 図である。  FIG. 1 is a cross-sectional view schematically showing a main part of a synthetic fiber drawing apparatus (Example 1) according to the present invention.
[図 2]実施例 1の抵抗付与装置 4と合成繊維の繊維束 5との状態を模式的に示した部 分斜視図  FIG. 2 is a partial perspective view schematically showing the state of a resistance applying device 4 and a fiber bundle 5 of synthetic fibers in Example 1.
[図 3]第 1支持体が供給される電気エネルギーにより加熱可能となっている例を示す モデル図である。  FIG. 3 is a model diagram showing an example in which a first support can be heated by electric energy supplied thereto.
[図 4]外部から支持体内部に供給される加熱用流体により加熱可能となっている例を 示すモデル図である。  FIG. 4 is a model diagram showing an example in which heating can be performed by a heating fluid supplied from the outside to the inside of the support.
[図 5]加熱槽 3の加熱 ·抵抗付与装置 4付近のモデル拡大断面図である。  FIG. 5 is an enlarged sectional view of a model in the vicinity of a heating / resistance applying device 4 of a heating tank 3.
符号の説明  Explanation of reference numerals
[0020] 1 第 1ローラ [0020] 1 First roller
2 第 2ローラ  2 Second roller
3 加熱槽  3 Heating tank
31 繊維束導入口  31 Fiber bundle inlet
32 繊維束排出口  32 Fiber bundle outlet
4 抵抗付与装置  4 Resistance applying device
41 支持体 (第 1支持体)  41 Support (first support)
42 支持体 (第 2支持体)  42 support (second support)
43 加圧体  43 Pressing body
5 繊維束  5 Fiber bundle
発明を実施するための最良の形態 [0021] 本発明における加熱 ·抵抗付与装置は、断面が円状の繊維束を上下方向又は左 右方向より挟み込んで帯状に拡幅変形させると共に、繊維束に摺動抵抗を付与する ためのものであるとともに、拡幅変形させた繊維束を効果的に加熱するものである。こ こで、抵抗付与装置の形状は、それぞれ加熱可能な複数の支持体と、隣り合う 2つの 支持体の中間ないし中間付近に設けられた、加熱可能な加圧体とからなるものであ る。 BEST MODE FOR CARRYING OUT THE INVENTION [0021] The heating / resistance applying device according to the present invention is used for sandwiching a fiber bundle having a circular cross section from above and below or right and left to widen and deform it into a band shape, and to provide sliding resistance to the fiber bundle. In addition, the fiber bundle that has been subjected to the widening deformation is effectively heated. Here, the shape of the resistance applying device includes a plurality of supports that can be heated, and a pressurizable body that can be heated and is provided at or near the middle of two adjacent supports. .
[0022] すなわち、加熱'抵抗付与装置は、繊維束を帯状に拡幅させて変形させることで、 繊維束の表層部と中心部を近接させて、繊維束全体を均一に加熱し、軟化させるこ とができるものであり、さらに繊維束に摺動抵抗を与えることで、繊維の延伸開始位 置を固定して繊維を均一に延伸できるようにしたものである。  [0022] That is, the heating and resistance imparting device expands and deforms the fiber bundle in a belt-like shape, thereby bringing the surface layer portion and the center portion of the fiber bundle close to each other and uniformly heating and softening the entire fiber bundle. Further, by giving sliding resistance to the fiber bundle, the drawing start position of the fiber is fixed so that the fiber can be drawn uniformly.
[0023] なお、加熱'抵抗付与装置における複数の、棒状の支持体は、通常、第 1ローラの 繊維束接触面と第 2ローラの繊維束接触面と含む平面に、その繊維との接触面が位 置するように配するが、装置製作上の必要がある場合、あるいは、特に高い摺動抵抗 を付与しょうとする場合などではこの限りでない。  [0023] The plurality of rod-shaped supports in the heating and resistance applying device usually have a contact surface with the fiber on a plane including the fiber bundle contact surface of the first roller and the fiber bundle contact surface of the second roller. However, this does not apply when it is necessary to manufacture the equipment or when it is intended to provide particularly high sliding resistance.
[0024] 本発明における支持体及び加圧体の形状は本発明の効果を損なわない限りにお いて特に限定されないが、これらは繊維束と接摺する接触部材であるため、なめらか な形状であることが必要で、例えば断面が円形、楕円形、多角形の棒状体や板状体 などが挙げられ、これらの 1種またはこれらを組み合わせて採用できる。なお、形状と して棒状体を採用した際には直径 10— 150mm、板状体を採用した際には厚さ 5— 30mmとし、共に繊維との接触部に半径 5— 75mmの曲面加工を施したものが望ま しい。  [0024] The shapes of the support and the pressurizing body in the present invention are not particularly limited as long as the effects of the present invention are not impaired. However, since these are contact members that come into contact with the fiber bundle, they have a smooth shape. For example, a rod, plate, or the like having a circular, elliptical, or polygonal cross section may be used, and one or a combination of these may be employed. When a rod-shaped body is used, the diameter is 10-150 mm, and when a plate-shaped body is used, the thickness is 5-30 mm. It is desirable to have done it.
[0025] また、本発明における支持体及び加圧体の材料としては、鉄、ステンレス、銅、真鍮 等の金属材料や、セラミックス等の無機材料が挙げられ、これらから適宜選択して採 用すればよい。  [0025] Examples of the material of the support and the pressing body in the present invention include metal materials such as iron, stainless steel, copper, and brass, and inorganic materials such as ceramics. Just fine.
[0026] 本発明における支持体及び加圧体の材料は加熱可能であることが必要である。カロ 熱槽で雰囲気温度を高めても、繊維自体が延伸可能な温度とするには、加熱槽の大 きさを巨大なものとしても充分な加温ができなレ、。繊維束と接触する支持体及び加熱 体が加熱されていることで、それらと繊維束との接触による伝熱で、繊維束をその内 部まで確実に加熱することができる。 [0026] The materials of the support and the pressing body in the present invention need to be heatable. Caro Even if the temperature of the heating tank is large, even if the temperature of the heating tank is huge, even if the temperature of the heating tank is enormous, it is not possible to sufficiently heat the fiber itself. Since the support and the heating element that come into contact with the fiber bundle are heated, the fiber bundle is Can be reliably heated up to the part.
[0027] これら支持体及び加圧体の加熱は、これらに供給される電気エネルギーによる抵 抗加熱等により行うことができ、あるいは、外部からこれらの内部に供給される熱媒と しての加熱用流体によりおこなうことができる。前者の場合では、これら支持体、加圧 体及びこれらの加熱のための設備の製造コストは安価となる力 ランニングコストが高 くなる。後者の場合では加熱流体を加熱しやすいため、前者よりもランニングコストが 低くなるとともに、これら支持体、加圧体及びこれらの加熱のための設備の製造コスト が高いものとなる。  [0027] Heating of the support and the pressurized body can be performed by resistance heating or the like using electric energy supplied thereto, or heating as a heat medium supplied from the outside to the inside thereof. It can be performed with a working fluid. In the former case, the production cost of the support, the pressurized body and the equipment for heating them is reduced, and the force running cost is increased. In the latter case, the heating fluid is easily heated, so that the running cost is lower than in the former case, and the manufacturing cost of these supports, pressurizing bodies and equipment for heating them is higher.
[0028] 本発明の加熱槽において、繊維束を加熱軟化させる手段は従来公知のものを採用 でき、例えば、電熱、蒸気、温水、温油等がある。なお、加熱温度は、延伸する合成 繊維の素材に合わせて適宜設定すればよい。  [0028] In the heating tank of the present invention, means for heating and softening the fiber bundle may be a conventionally known means, for example, electric heating, steam, hot water, hot oil and the like. The heating temperature may be appropriately set according to the material of the synthetic fiber to be drawn.
[0029] 本発明では、このような第 1ローラと第 2ローラとの間に配置した中空箱状の加熱槽 の内部に導入して加熱軟化させるときに、加熱槽内で、繊維束を帯状にその幅を広 げると共に、繊維束を加熱された接触部材、すなわち、共に加熱された支持体及び 加圧体と接触させることによる接触加熱により、加熱槽だけでの加熱では果たせなか つた、繊維束中央部の繊維の充分な加熱も可能となり、その結果、白化や、糸切れを 未然に防止しながら、第 1ローラと第 2ローラとにより所定の倍率に延伸することが可 能となる。  [0029] In the present invention, when the fiber bundle is introduced into the hollow box-shaped heating tank disposed between the first roller and the second roller to be heated and softened, the fiber bundle is strip-shaped in the heating tank. In addition to increasing the width of the fiber bundle, the contact heating by bringing the fiber bundle into contact with the heated contact member, that is, the support and the pressurized body that were heated together, could not be achieved by heating in the heating tank alone. Sufficient heating of the fiber in the center of the fiber bundle is also possible, and as a result, it is possible to stretch the film at a predetermined magnification by the first roller and the second roller while preventing whitening and yarn breakage. .
[0030] 本発明の延伸方法や延伸装置に供される合成樹脂としては、繊維として成形可能 な従来公知の合成樹脂があり、ポリスチレン樹脂、ポリフエ二レンエーテル樹脂、ポリ ォレフィン樹脂、ポリアミド樹脂、ポリエステル樹脂、ポリフエ二レンスルフイド樹脂、ポ リメタクリレート樹脂、ポリ塩化ビニル樹脂等がある。具体的には、ポリスチレン樹脂で は、ポリスチレン、ポリスチレン一アクリロニトリル共重合体、スチレン一 (メタ)アタリレー ト共重合体等がある。ポリフエ二レンエーテル樹脂では、ポリ(2, 6_ジメチルー 1 , 4- フエ二レンエーテル)、ポリ(2, 6—ジェチル— 1, 4_フエ二レンエーテル)、ポリ(2—メ チル _6_ェチル _1, 4—フエ二レンエーテル)等がある。ポリオレフイン樹脂ではポリエ チレン、ポリプロピレン等がある。ポリアミド樹脂では、ナイロン 6、ナイロン 66等がある 。ポリエステル樹脂ではポリアルキレンテレフタレート、ポリアリレート、ポリカーボネー ト等がある。ポリメタタリレート樹脂ではポリメチルメタタリレート、ポリブチルメタクリレー ト等がある。ポリ塩化ビエル樹脂では、ポリ塩化ビニル単独重合体、塩ィ匕ビ二ルー塩 化ビニリデン共重合体、塩ィヒビ二ルーアクリロニトリル共重合体、塩化ビニルーェチレ ン共重合体、塩化ビュル一プロピレン共重合体、塩化ビュル一アルキルビュルエーテ ル共重合体、塩化ビュル一酢酸ビュル共重合体、塩化ビュル一アクリル酸エステル共 重合体、塩化ビニルーマレイン酸エステル共重合体等がある。 [0030] Examples of the synthetic resin used in the stretching method and the stretching apparatus of the present invention include a conventionally known synthetic resin that can be molded as a fiber, such as a polystyrene resin, a polyphenylene ether resin, a polyolefin resin, a polyamide resin, and a polyester. Resin, polyphenylene sulfide resin, polymethacrylate resin, polyvinyl chloride resin and the like. Specifically, polystyrene resins include polystyrene, polystyrene-acrylonitrile copolymer, styrene- (meth) atalylate copolymer and the like. Polyphenylene ether resins include poly (2,6_dimethyl-1,4-phenylene ether), poly (2,6-getyl-1,4_phenylene ether), and poly (2-methyl_6_ Ethyl-1, 4-phenylene ether). Polyolefin resins include polyethylene and polypropylene. Examples of the polyamide resin include nylon 6, nylon 66, and the like. Polyester resins include polyalkylene terephthalate, polyarylate, polycarbonate And others. Examples of the polymethacrylate resin include polymethyl methacrylate and polybutyl methacrylate. For polyvinyl chloride resin, polyvinyl chloride homopolymer, vinyl chloride vinylidene chloride copolymer, vinyl chloride acrylonitrile copolymer, vinyl chloride-ethylene copolymer, vinyl chloride-propylene copolymer, There are a butyl chloride-alkyl butyl ether copolymer, a butyl chloride monoacetic acid butyl copolymer, a butyl chloride monoacrylate copolymer, a vinyl chloride-maleic acid ester copolymer and the like.
[0031] 本発明において合成樹脂として人工毛髪に最適なポリ塩化ビュル樹脂を採用する 場合、 目的に応じてポリ塩化ビニル樹脂組成物に使用される公知の添加剤を本発明 の効果を阻害しない範囲で添加できる。添加剤としては、加工助剤、強化剤、紫外線 吸収剤、酸化防止剤、帯電防止剤、充填剤、難燃剤、顔料、初期着色改善剤、導電 性付与剤、表面処理剤、光安定剤、香料等がある。  [0031] When the polyvinyl chloride resin most suitable for artificial hair is employed as the synthetic resin in the present invention, known additives used in the polyvinyl chloride resin composition may be used according to the purpose without impairing the effects of the present invention. Can be added. Additives include processing aids, strengthening agents, ultraviolet absorbers, antioxidants, antistatic agents, fillers, flame retardants, pigments, initial color improvers, conductivity-imparting agents, surface treatment agents, light stabilizers, There are fragrances.
[0032] ここで、支持体を 2つ、加圧体を 1つそれぞれ有する加熱'抵抗付与装置での場合 には、その繊維束の進行方向上流側に設置された第 1支持体は、第 1ローラから供 給された繊維束を加熱槽の繊維束導入口へ安定的に導入するものである。ここで第 1支持体の設置位置は、加熱槽の繊維束の導入口より第 1ローラ側であると、繊維束 を加熱槽に安定的に導入できなくなって繊維の白化や糸切れが発生し、あるいは、 加熱槽の中央部より繊維束進行方向下流の方向側であると繊維束が延伸時に振動 して繊維の白化や糸切れが発生してしまうため、加熱槽の繊維束導入口と加熱槽の 中央との間の位置であることがよい。  [0032] Here, in the case of a heating resistance applying device having two support members and one pressurizing member, the first support member installed on the upstream side in the traveling direction of the fiber bundle is the first support member. The fiber bundle supplied from one roller is stably introduced into the fiber bundle inlet of the heating tank. Here, if the first support is installed on the first roller side from the fiber bundle inlet of the heating tank, the fiber bundle cannot be stably introduced into the heating tank, causing fiber whitening and yarn breakage. Alternatively, if the fiber bundle is located downstream of the center of the heating tank in the direction in which the fiber bundle travels, the fiber bundle vibrates at the time of drawing, causing whitening or breakage of the fiber. It should be located between the center of the tank.
[0033] さらに、第 1支持体よりも繊維束の進行方向下流側に設置された第 2支持体は、後 述する加圧体によって摺動抵抗が付与された繊維束を、加熱槽の排出口から安定し て排出するためのものである。ここで第 2支持体の設置位置は、加熱槽の全長ゃ繊 維東の移動速度にもよるが、第 1支持体力も繊維束進行方向下流の方向へ 65— 55 Ommの位置に配置されていることが好ましい。ここで、 65mm未満の位置であると繊 維束にカゝかる抵抗が大きくなりすぎて繊維が糸切れしてしまレヽ、 550mmを超えた位 置であると繊維束が帯状に拡幅 ·変形しなくなって均一に加熱されなくなり繊維の白 化が発生してしまう。  [0033] Further, the second support, which is provided downstream of the first support in the direction of travel of the fiber bundle, discharges the fiber bundle, to which sliding resistance has been imparted by the pressurizing body described later, from the heating tank. This is for stable discharge from the exit. Here, the installation position of the second support depends on the total length of the heating tank and the moving speed of the fiber east, but the first support is also located at a position of 65-55 Omm in the downstream direction in the fiber bundle traveling direction. Is preferred. Here, if the position is less than 65 mm, the resistance to covering the fiber bundle becomes too large, and the fiber breaks.If the position is more than 550 mm, the fiber bundle expands and deforms into a belt shape. As a result, the fibers are not uniformly heated and whitening of the fibers occurs.
[0034] 加圧 ·抵抗付与装置の加圧体は、上記第 1支持体及び第 2支持体と相俟って、断 面円状の繊維束を挟み込んで、帯状に拡幅 ·変形させるとともに、繊維束に摺動抵 抗を付与するためのものである。ここで、加圧体が、該第 1支持体の繊維束摺接面と 第 2支持体の繊維束摺接面とを含む平面の、第 1支持体力 繊維束進行方向下流 の方向に 50— 350mmの位置力 垂直に 10— 200mm離間した位置に配置されて レ、ることが望ましい。 [0034] Pressurizing The pressurizing body of the resistance applying device, together with the first support and the second support, is cut off. This is for sandwiching a plane-shaped fiber bundle, widening and deforming it into a belt shape, and for imparting sliding resistance to the fiber bundle. In this case, the pressing body is 50-degree in the direction downstream of the first supporting member force fiber bundle advancing direction on the plane including the fiber bundle sliding contact surface of the first support and the fiber bundle sliding contact surface of the second support. Position force of 350mm It is desirable to be placed vertically 10-200mm apart.
[0035] すなわち、第 1支持体から繊維束進行方向への変位が 50mm未満であると繊維束 にかかる抵抗が大きくなりすぎて繊維が糸切れしやすくなり、 550mm超であると繊維 束が効果的に帯状に拡幅 ·変形されなくなって、均一加熱が困難となり、その結果、 繊維の白化が発生しやすくなる。  That is, if the displacement from the first support in the fiber bundle advancing direction is less than 50 mm, the resistance applied to the fiber bundle becomes too large, and the fiber is likely to be broken. If it is more than 550 mm, the fiber bundle is effective. The band is not widened and deformed, and uniform heating becomes difficult. As a result, the fiber is apt to whiten.
[0036] また、加圧体の上記平面からの垂直な離間距離が、 10mm未満であると、繊維束 が帯状に変形しなくなって均一に加熱されなくなり繊維の白化が発生しやすくなり、 2 00mmを超えてしまうと繊維束に力かる抵抗が大きくなりすぎて繊維が糸切れしやす くなるため、加圧体の上記平面からの垂直な離間距離は 10— 200mmの位置がよい 実施例  [0036] When the vertical separation distance of the pressurized body from the plane is less than 10 mm, the fiber bundle does not deform into a belt shape, is not uniformly heated, and the fiber is apt to whiten. If the pressure exceeds the limit, the resistance to the fiber bundle becomes too large and the fiber is apt to break, so the vertical distance of the pressurized body from the above plane is preferably 10 to 200 mm.
[0037] 本発明に係る合成繊維の延伸装置の実施例を図 1及び図 2を参照しつつ説明する  An embodiment of a synthetic fiber drawing apparatus according to the present invention will be described with reference to FIGS. 1 and 2.
[0038] 図 1は本発明に係る合成繊維の延伸装置(実施例 1)の主要部を模式的に示した 断面図である。 FIG. 1 is a cross-sectional view schematically showing a main part of a synthetic fiber drawing apparatus (Example 1) according to the present invention.
[0039] 図 1中、符号 1はポリ塩ィ匕ビニル樹脂からなる合成繊維の繊維束 5を供給する第 1口 ーラを示し、符号 2は第 1ローラ 1より大きい周速度で回転し該第 1ローラ 1との周速度 差により該繊維束を延伸する第 2ローラを、符号 3は第 1ローラ 1と該第 2ローラ 2との 間に配置され繊維束 5をその内部に導入して加熱軟化するための中空箱状の加熱 槽 4 (本例では全長が 2m)を示し、符号 31及び 32は加熱槽 3の繊維束導入口及び 繊維束排出口をそれぞれ示している。この加熱槽 3内には、繊維束 5を加熱するとと もに繊維束 5に帯状に拡幅変形させながら摺動抵抗を付与するための、それぞれカロ 熱可能な複数の支持体 41 (繊維束進行方向上流側に設置された第 1支持体)及び 4 2 (第 1支持体から繊維束進行方向下流の方向に設置された第 2支持体)と、これら 2 つの支持体 41及び 42の中間付近に設けられた、加熱可能な加圧体 43とからなる加 熱'抵抗付与装置 4が設けられている。 In FIG. 1, reference numeral 1 denotes a first roller for supplying a fiber bundle 5 of synthetic fibers made of polyvinyl chloride vinyl resin, and reference numeral 2 denotes a roller that rotates at a higher peripheral speed than the first roller 1. Reference numeral 3 denotes a second roller that stretches the fiber bundle by a peripheral speed difference from the first roller 1, and reference numeral 3 is disposed between the first roller 1 and the second roller 2 to introduce the fiber bundle 5 therein. A hollow box-shaped heating tank 4 for heating and softening (in this example, the total length is 2 m) is shown, and reference numerals 31 and 32 indicate a fiber bundle introduction port and a fiber bundle discharge port of the heating tank 3, respectively. In the heating tank 3, a plurality of supports 41 each capable of heating each fiber (a fiber bundle advance) for heating the fiber bundle 5 and imparting sliding resistance while widening and deforming the fiber bundle 5 in a band shape. The first support installed on the upstream side in the direction, and 4 2 (the second support installed in the downstream direction of the fiber bundle from the first support). A heating / resistance applying device 4 including a heatable pressurizing body 43 provided near the middle between the two supports 41 and 42 is provided.
[0040] 一方、図 2は、実施例 1の抵抗付与装置 4 (いずれも断面形状が直径が 30mmの円 である丸棒形状であり、ステンレスからなる、第 1支持体 41、第 2支持体 42及び加圧 体 43から構成される。本例ではこれらの加熱手段はそれぞれに内蔵された電熱ヒー タである)と合成繊維の繊維束 5との状態を模式的に示した部分斜視図である。なお 、これら図 1及び図 2中の矢印は、繊維束の流れ方向を示したものである。  [0040] On the other hand, Fig. 2 shows the resistance applying device 4 of Example 1 (both of which are round bars each having a cross-section of a circle having a diameter of 30 mm, made of stainless steel, the first support 41 and the second support 41). 42 and a pressurizing body 43. In this example, these heating means are electric heaters incorporated in each of them) and a partial perspective view schematically showing the state of the fiber bundle 5 of synthetic fibers. is there. The arrows in FIGS. 1 and 2 indicate the flow direction of the fiber bundle.
[0041] 図 3は第 1支持体が供給される電流により加熱可能となっている例として、加熱手段 として電熱ヒータを内蔵させた状態を示すモデル図であり、図 4は、外部から支持体 内部に供給される加熱用流体により加熱可能となっている例を示すモデル図である 。なお、本発明における延伸装置では、ポリ塩化ビュル樹脂からなる合成繊維を用い ることから、これら第 1支持体、第 2支持体及び加熱体は 90°C以上 150°C以下に加 熱可能であることが望ましい。 90°C未満であるとこれらの加熱の効果が得られに《、 また、 150°C超であると温度が高すぎ、繊維が溶融して糸切れが発生してしまう。な お、これら第 1支持体、第 2支持体及び加熱体はすべて同じ温度に設定しても良ぐ あるいは、最良の結果を得るために、それぞれの温度を変えて設定しても良い。  FIG. 3 is a model diagram showing a state in which an electric heater is incorporated as a heating means as an example in which the first support can be heated by a supplied current, and FIG. FIG. 3 is a model diagram showing an example in which heating can be performed by a heating fluid supplied inside. Since the drawing apparatus of the present invention uses synthetic fibers made of polychlorinated vinyl resin, the first support, the second support, and the heating body can be heated to 90 ° C or more and 150 ° C or less. Desirably. If the temperature is lower than 90 ° C, these heating effects are not obtained. On the other hand, if the temperature is higher than 150 ° C, the temperature is too high, and the fibers are melted to cause yarn breakage. The first support, the second support, and the heating element may all be set at the same temperature, or may be set at different temperatures to obtain the best results.
[0042] 実施例 1の延伸装置では、その加熱'抵抗付与装置 4で第 1支持体 41、第 2支持体  [0042] In the stretching apparatus of Example 1, the first support 41 and the second support
42と加圧体 43の位置をそれぞれ移動可能としてある。  The position of 42 and the pressure body 43 can be moved respectively.
[0043] ここで、第 1支持体、第 2支持体及び加圧体はそれぞれ所望の位置 (繊維束導入口 力 の距離及び上下方法の位置)に固定可能となっている。ここで、これら第 1支持 体 41、第 2支持体 42及び加圧体 43の位置、すなわち、加熱槽 3の加熱 ·抵抗付与 装置 4付近のモデル拡大断面図である図 5において、加熱槽 3の繊維束導入口 41と 第 1支持体との距離 dl、第 1支持体 41と第 2支持体の距離 d2、 d3は第 1支持体 41と 加圧体 43までの距離 d3、そして、第 1支持体の繊維束摺接面と第 2支持体の繊維束 摺接面とを含む平面からの加圧体の離間距離 (以下「加圧体の離間距離」とも云う) h をそれぞれ調整し、そのときの延伸後の繊維の状態への影響を調べた。  Here, the first support, the second support, and the pressurizing body can be fixed at desired positions (the distance of the fiber bundle introduction port force and the position in the vertical direction). Here, in FIG. 5, which is an enlarged cross-sectional view of the positions of the first support 41, the second support 42, and the pressurizing body 43, that is, the heating / resistance applying device 4 of the heating tank 3, FIG. The distance dl between the fiber bundle introduction port 41 and the first support, and the distance d2, d3 between the first support 41 and the second support are the distance d3 between the first support 41 and the pressing body 43, and 1 Adjust the separation distance of the pressurized body from the plane including the sliding surface of the fiber bundle of the support and the sliding surface of the fiber bundle of the second support (hereinafter also referred to as the “separation distance of the pressed body”), h. The effect on the state of the drawn fiber at that time was examined.
[0044] すなわち、 200デニール、ポリ塩化ビュル樹脂製の単繊維 120本からなる繊維束( 未延伸糸)を、第 1ローラ 1から 130°Cに加熱した加熱槽 3内に 100m/minの速度 で供給し、共に内蔵された電熱ヒータにより加熱された第 1支持体 41、第 2支持体 42 及び加圧体 43からなる抵抗付与装置 4によって加熱延伸し、第 2ローラで 400m/m inの速度で引き取って 4倍の延伸を行った。この延伸後の繊維束 100mを目視にて 確認し、白化した繊維が 1本も確認されなかった場合を合格(〇)、 1本でも白化して レ、た場合を不合格(X )とした。また、このとき、糸切れが 1本もなかった場合を合格( 〇)、 1本でも糸切れしていた場合を不合格(X )とした。なお、この評価は、人工毛髪 として求められる非常に厳格な品質管理に即した非常に厳しいものである。 That is, a fiber bundle (undrawn yarn) composed of 120 single fibers made of 200 denier and polychlorinated vinyl resin was fed from the first roller 1 into a heating tank 3 heated to 130 ° C. at a speed of 100 m / min. And heated and stretched by a resistance applying device 4 including a first support 41, a second support 42, and a pressurizing body 43, which are heated by a built-in electric heater, and 400 m / min by a second roller. It was pulled at the speed and stretched 4 times. The stretched fiber bundle 100m was visually checked. If none of the whitened fibers was found, it was passed (合格), and even if one of the fibers was whitened, it was rejected (X). . In addition, at this time, the case where no thread was broken was judged as pass (〇), and the case where even one thread was broken was judged as failed (X). This evaluation is very strict in accordance with the very strict quality control required for artificial hair.
[0045] それら実験の結果を表 1及び表 2に示す。なお、これら表中、第 1支持体の繊維束 摺接面と第 2支持体の繊維束摺接面とを含む平面からの加圧体の離間距離 hが正の 値となっている場合には、繊維束に対して、第 1支持体 41及び第 2支持体 42は繊維 束 5に対して上方から接し、かつ、加圧体 43は下方から接している状態(図 1に示し た状態)であることを示し、加圧体の垂直位置の値が負の値となっている場合には、 繊維束に対して、第 1支持体 41及び第 2支持体 42は繊維束 5に対して下方から接し 、かつ、加圧体 43は上方から接している状態であることを示す。また、加熱槽 3の繊 維束導入口 41と第 1支持体との距離 dlが負となっている場合には、第 1支持体はカロ 熱ネ曹 3の外に設けられていることを示す。  [0045] Tables 1 and 2 show the results of these experiments. In these tables, when the distance h of the pressurized body from a plane including the fiber bundle sliding contact surface of the first support and the fiber bundle sliding contact surface of the second support is a positive value. The state in which the first support 41 and the second support 42 are in contact with the fiber bundle from above and the pressing body 43 is in contact with the fiber bundle 5 from below (the state shown in FIG. 1) ), And when the value of the vertical position of the pressing body is a negative value, the first support 41 and the second support 42 And the pressing body 43 is in a state of contacting from above. When the distance dl between the fiber bundle inlet 41 of the heating tank 3 and the first support is negative, it is determined that the first support is provided outside the Show.
[0046] [表 1] [Table 1]
実施例 Example
1 2 3 4 5 6 7 8 9 1 0 1 1 加執摔の 人ロと笛 1 ΐ 50 q R Π c: n r: n  1 2 3 4 5 6 7 8 9 1 0 1 1 ロ q 50 q R Π c: n r: n
抗 持体との距離 d 1 (mm) Distance from support d 1 (mm)
付 第 1支持体と第 2支持体 400 400 400 70 530 400 400 400 400 400 400 与 との距離 d 2 (rim) Append Distance between first support and second support 400 400 400 70 530 400 400 400 400 400 400 Gi d 2 (rim)
装 第 1支持体と加圧体との 200 200 200 50 200 50 350 200 200 200 200 置 距離 d 3 (ram) 200 200 200 50 200 50 350 200 200 200 200 Distance between first support and pressurized body d 3 (ram)
加圧体の離間距離 h (mm) 35 -35 35 35 35 35 35 1 0 200 35 35 第 1支持体、第 2支持体 110°C 110。C 110°C 110°C 110°C 110°C 110。C 110°C 110°C 90°C 150°C 及び加圧体の加熱温度  Separation distance of pressurized body h (mm) 35 -35 35 35 35 35 35 1 0 200 35 35 First support, second support 110 ° C 110. C 110 ° C 110 ° C 110 ° C 110 ° C 110. C 110 ° C 110 ° C 90 ° C 150 ° C and heating temperature of pressurized body
評価 白化 O O O o 〇 〇 O O O O O 結果 糸切れ 〇 o O o O O o o O O O Evaluation Whitening OOO o 〇 〇 OOOOO Result Thread break 〇 o O o OO oo OOO
[z [ oo] ム 800請 zdf/ェ:) d ζ\ οο9επ請 ZOA 比較例 [z [oo] mu 800 contract zdf / e :) d ζ \ οο9επ contract ZOA Comparative example
1 2 3 4 5 6 7 8 9 10 抵 加熱槽の導入口と第 1支持 — 50 1 10 50 50 50 50 50 5 o 5 o 50 抗 体との距離 d 1 (mm) 0  1 2 3 4 5 6 7 8 9 10 Resistor Inlet of heating tank and first support — 50 1 10 50 50 50 50 50 5 o 5 o 50 Distance from antibody d 1 (mm) 0
付 第 1支持体と第 2支持体と 400 400 60 600 400 400 400 400 400 400 与 の距離 d 2 (im Append Distance between first support and second support 400 400 60 600 400 400 400 400 400 400
装 第 1支持体と加圧体との距 200 200 50 200 40 200 200 200 200 200 置 離 d 3 (mm) Device Distance between first support and pressurized body 200 200 50 200 40 200 200 200 200 200 Distance d 3 (mm)
加圧体の離間距離 h (mm) 35 35 35 35 35 5 210 35 35 -35 第 1 支持体、第 2支持体及 110°C 110¾ 110°C 110°C 110°C 110°C 110。C 110°C 非加熱 160°C び加圧体の加熱温度  Separation distance of pressurized body h (mm) 35 35 35 35 35 5 210 35 35 -35 1st support, 2nd support and 110 ° C 110¾ 110 ° C 110 ° C 110 ° C 110 ° C 110. C 110 ° C Unheated 160 ° C and heating temperature of pressurized body
評価 白化 X X o X o X X O X O 結果 糸切れ X X X O X O O X X X Evaluation Whitening XX o X o XXOXO Result Yarn break XXXOXOOXXX
[0048] 表 1及び表 2により、本発明の延伸装置によれば、白化や糸切れなしで、人工毛髪 に適した繊維を得ることができることが判る。 [0048] Tables 1 and 2 show that the stretching apparatus of the present invention can provide fibers suitable for artificial hair without whitening or thread breakage.
産業上の利用可能性  Industrial applicability
[0049] 本発明によれば、 120本以上の単繊維からなる繊維束を延伸する際でも、繊維の 白化や糸切れを防止できる人工毛髪用合成繊維の延伸方法及び延伸装置を実現 することができ、人工毛髪用合成繊維の生産性を高めることができた。 According to the present invention, it is possible to realize a method and an apparatus for drawing synthetic fibers for artificial hair which can prevent whitening and breakage of fibers even when a fiber bundle composed of 120 or more single fibers is drawn. As a result, the productivity of synthetic fibers for artificial hair could be increased.

Claims

請求の範囲 The scope of the claims
[1] 合成繊維の繊維束を第 1ローラに供給した後、該第 1ローラより大きい周速度で回 転する第 2ローラに供給して前記繊維束を延伸させる際に、該繊維束を該第 1ローラ と該第 2ローラとの間に配置した中空箱状の加熱槽の内部に導入して加熱軟化させ る合成繊維の延伸方法にぉレ、て、  [1] After supplying the fiber bundle of the synthetic fiber to the first roller, when supplying the fiber bundle to the second roller rotating at a higher peripheral speed than the first roller, the fiber bundle is According to a method for drawing synthetic fibers which are introduced into a hollow box-shaped heating tank disposed between the first roller and the second roller to be heated and softened,
上記加熱槽内で、上記繊維束を帯状にその幅を広げると共に、該繊維束を接触加 熱により加熱する合成繊維の延伸方法。  A method of drawing a synthetic fiber in which the width of the fiber bundle is expanded in a belt shape in the heating tank and the fiber bundle is heated by contact heating.
[2] 前記合成繊維がポリ塩化ビュル樹脂製である請求項 1に記載の合成繊維の延伸 方法。  [2] The method for stretching synthetic fibers according to claim 1, wherein the synthetic fibers are made of polychlorinated vinyl resin.
[3] 前記合成繊維が人工毛髪用合成繊維である請求項 2に記載の合成繊維の延伸方 法。  3. The method for drawing a synthetic fiber according to claim 2, wherein the synthetic fiber is a synthetic fiber for artificial hair.
[4] 合成繊維の繊維束を供給する第 1ローラ、該第 1ローラより大きい周速度で回転し 該第 1ローラとの周速度差により該繊維束を延伸する第 2ローラ、及び、該第 1ローラ と該第 2ローラとの間に配置され該繊維束をその内部に導入して加熱軟化するため の中空箱状の加熱槽を有する合成繊維の延伸装置において、  [4] a first roller that supplies a fiber bundle of synthetic fibers, a second roller that rotates at a higher peripheral speed than the first roller, and stretches the fiber bundle by a peripheral speed difference from the first roller; In a synthetic fiber drawing device having a hollow box-shaped heating tank arranged between one roller and the second roller for introducing the fiber bundle into the inside and heating and softening the bundle,
上記加熱槽内に、該繊維束を加熱するとともに該繊維束に帯状に拡幅変形させな がら摺動抵抗を付与するための、それぞれ加熱可能な複数の支持体と、隣り合う 2つ の支持体の中間付近に設けられた、加熱可能な加圧体とからなる加熱'抵抗付与装 置が設けられ、  In the heating tank, a plurality of heatable supports and two adjacent supports are provided for heating the fiber bundle and imparting sliding resistance to the fiber bundle while widening the fiber bundle in a band shape. A heating resistance-imparting device comprising a heatable pressurizing body provided near the middle of
これら支持体及び加圧体はともに上記第 2ローラの軸に平行に設置された棒状体 であってそれぞれ該繊維束に接し、  Both the support and the pressure body are rod-like bodies installed in parallel with the axis of the second roller, and are in contact with the fiber bundle, respectively.
加圧体は、その加圧体に隣接する 2つの支持体の繊維束摺接面を共に含む平面 から離間して配置されている延伸装置。  A drawing device in which the pressurizing body is disposed away from a plane including both the fiber bundle sliding surfaces of two supports adjacent to the pressurizing body.
[5] 上記支持体を 2つ、加圧体を 1つ有する延伸装置であって、これら 2つの支持体のう ち、繊維束進行方向上流側に設置された第 1支持体が、加熱槽の繊維束導入口と 加熱槽の中央との間の位置に配置され、 [5] A drawing apparatus having two support members and one pressurizing member, wherein a first support member installed upstream of the two support members in the fiber bundle traveling direction is a heating tank. Is located between the fiber bundle inlet and the center of the heating tank,
第 2支持体は、該第 1支持体から繊維束進行方向下流の方向へ 65— 550mmの 位置に配置され、かつ、 加圧体が、該第 1支持体の繊維束摺接面と第 2支持体の繊維束摺接面とを含む平 面の、第 1支持体から繊維束進行方向下流の方向に 50— 350mmの位置から垂直 に 10— 200mm離間した位置に配置されている請求項 4に記載の延伸装置。 The second support is disposed at a position of 65 to 550 mm downstream from the first support in the fiber bundle traveling direction, and The pressurizing body is 50 to 350 mm in a plane including the fiber bundle sliding contact surface of the first support and the fiber bundle sliding contact surface of the second support in a downstream direction from the first support in the fiber bundle traveling direction. 5. The stretching apparatus according to claim 4, wherein the stretching apparatus is disposed at a position vertically separated by 10 to 200 mm from the position.
[6] 上記支持体及び加圧体がともに、これら支持体及び加圧体に供給される電気エネ ルギ一により加熱可能となっている請求項 4または請求項 5に記載の延伸装置。  6. The stretching apparatus according to claim 4, wherein both the support and the pressurized body can be heated by electric energy supplied to the support and the pressurized body.
[7] 上記支持体及び加圧体がともに、外部からこれら支持体及び加圧体の内部に供給 される加熱用流体により加熱可能となっている請求項 4または請求項 5に記載の延伸  7. The stretching according to claim 4, wherein the support and the pressurized body are both heatable by a heating fluid supplied from the outside to the inside of the support and the pressurized body.
[8] 前記合成繊維がポリ塩化ビニル樹脂製である請求項 4なレ、し請求項 7のレ、ずれ力2 に記載の延伸装置。 [8] The synthetic fiber according to claim 4 which Le is made of polyvinyl chloride resin, teeth claim 7 Les, stretching apparatus according to the deviation force 2.
[9] 前記合成繊維が人工毛髪用合成繊維である請求項 8に記載の延伸装置。  9. The stretching apparatus according to claim 8, wherein the synthetic fiber is a synthetic fiber for artificial hair.
PCT/JP2004/008457 2003-06-18 2004-06-16 Drawing method and apparatus WO2004113600A1 (en)

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