WO2004009645A3 - Copolímeros en bloque que contienen grupos funcionales - Google Patents

Copolímeros en bloque que contienen grupos funcionales Download PDF

Info

Publication number
WO2004009645A3
WO2004009645A3 PCT/MX2003/000058 MX0300058W WO2004009645A3 WO 2004009645 A3 WO2004009645 A3 WO 2004009645A3 MX 0300058 W MX0300058 W MX 0300058W WO 2004009645 A3 WO2004009645 A3 WO 2004009645A3
Authority
WO
WIPO (PCT)
Prior art keywords
copolymer
microstructure
block
miscible
controlled
Prior art date
Application number
PCT/MX2003/000058
Other languages
English (en)
French (fr)
Other versions
WO2004009645A2 (es
Inventor
Guerra Enrique Saldivar
Montiel Alfonso Gonzalez
Original Assignee
Cid Ct Investigacion Desarrollo Tecnologico Sa De Cv
Guerra Enrique Saldivar
Montiel Alfonso Gonzalez
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cid Ct Investigacion Desarrollo Tecnologico Sa De Cv, Guerra Enrique Saldivar, Montiel Alfonso Gonzalez filed Critical Cid Ct Investigacion Desarrollo Tecnologico Sa De Cv
Priority to EP03741620A priority Critical patent/EP1553105B1/en
Priority to CA2495213A priority patent/CA2495213C/en
Priority to AU2003281535A priority patent/AU2003281535A1/en
Priority to MXPA05000654A priority patent/MXPA05000654A/es
Priority to DE60329206T priority patent/DE60329206D1/de
Priority to AT03741620T priority patent/ATE442389T1/de
Publication of WO2004009645A2 publication Critical patent/WO2004009645A2/es
Publication of WO2004009645A3 publication Critical patent/WO2004009645A3/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invención proporciona un copolímero en bloque de estireno y un anhídrido cíclico insaturado, tal como anhídrido maleico, un proceso para hacer el copolímero utilizando polimerización por radicales libres controlada en la cual ciertos parámetros se ajustan para controlar la microestructura y el peso molecular del copolímero, y un método para utilizar el copolímero en bloque, incluyendo su uso como compatibilizante. La microestructura y el peso molecular del copolímero en bloque puede controlarse ajustando la relación de iniciador a monómero y/o ajustando la relación de radical libre estable a iniciador. El copolímero puede hacerse en un proceso de un solo paso y posee una microestructura controlada que permite que un bloque sea reactivo hacia varios grupos químicos disponibles en los polímeros de ingeniería y el otro bloque que sea complamente miscible con poliestireno o miscible con polímeros miscibles con poliestireno tales como éter de polifenileno.
PCT/MX2003/000058 2002-07-19 2003-07-18 Copolímeros en bloque que contienen grupos funcionales WO2004009645A2 (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP03741620A EP1553105B1 (en) 2002-07-19 2003-07-18 Block copolymers containing functional groups
CA2495213A CA2495213C (en) 2002-07-19 2003-07-18 Block copolymers containing functional groups
AU2003281535A AU2003281535A1 (en) 2002-07-19 2003-07-18 Block copolymers containing functional groups
MXPA05000654A MXPA05000654A (es) 2002-07-19 2003-07-18 Copolimeros en bloque que contienen grupos funcionales.
DE60329206T DE60329206D1 (de) 2002-07-19 2003-07-18 Blockcopolymere mit funktionellen gruppen
AT03741620T ATE442389T1 (de) 2002-07-19 2003-07-18 Blockcopolymere mit funktionellen gruppen

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US39742002P 2002-07-19 2002-07-19
US60/397,420 2002-07-19
US10/621,929 US7323528B2 (en) 2002-07-19 2003-07-16 Block copolymers containing functional groups
US10/621,929 2003-07-16

Publications (2)

Publication Number Publication Date
WO2004009645A2 WO2004009645A2 (es) 2004-01-29
WO2004009645A3 true WO2004009645A3 (es) 2004-05-06

Family

ID=30773019

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/MX2003/000058 WO2004009645A2 (es) 2002-07-19 2003-07-18 Copolímeros en bloque que contienen grupos funcionales

Country Status (8)

Country Link
US (2) US7323528B2 (es)
EP (1) EP1553105B1 (es)
AT (1) ATE442389T1 (es)
AU (1) AU2003281535A1 (es)
CA (1) CA2495213C (es)
DE (1) DE60329206D1 (es)
ES (1) ES2333418T3 (es)
WO (1) WO2004009645A2 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2487721A1 (en) * 2002-06-20 2003-12-31 Ciba Specialty Chemicals Holding Inc. Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers
MXPA03008714A (es) * 2002-09-26 2004-09-10 Oreal Polimeros secuenciados y composiciones cosmeticas que comprenden tales polimeros.
EP1565148B1 (fr) * 2002-09-26 2011-03-30 L'Oréal Composition liquide brillante comprenant un polymère séquencé
FR2860142B1 (fr) * 2003-09-26 2007-08-17 Oreal Produit cosmetique bicouche, ses utilisations et kit de maquillage contenant ce produit
FR2860143B1 (fr) * 2003-09-26 2008-06-27 Oreal Composition cosmetique comprenant un polymere sequence et une huile siliconee non volatile
US20050220731A1 (en) * 2004-03-23 2005-10-06 Philippe Ilekti Nail varnish composition comprising at least one polymer and at least one plasticizer
US8728451B2 (en) 2004-03-25 2014-05-20 L'oreal Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof
JP4315866B2 (ja) * 2004-06-29 2009-08-19 横浜ゴム株式会社 硬化性エポキシ樹脂組成物
US20060173142A1 (en) * 2005-02-01 2006-08-03 Hildeberto Nava Functionalized thermosetting resin systems
US8357759B2 (en) * 2005-08-26 2013-01-22 CID Centro de Investigación y Desarrollo Tecnológico S.A. de C.V. Reactive block copolymers
US8344058B2 (en) * 2005-08-26 2013-01-01 CID Centro de Investigación y Desarrollo Technológico S.A. de C.V. Reactive block copolymers as additives for the preparation of silicate-polymer composites
US20100311920A1 (en) * 2005-08-26 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
US7651791B2 (en) 2005-12-15 2010-01-26 Idemitsu Kosan Co., Ltd. Material for organic electroluminescence device and electroluminescence device employing the same
FR2904320B1 (fr) * 2006-07-27 2008-09-05 Oreal Polymeres sequences, et leur procede de preparation
US20100311849A1 (en) 2006-08-23 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
JP2008189856A (ja) * 2007-02-06 2008-08-21 Seiko Epson Corp グラフト重合層の形成方法、電子デバイスおよび電子機器
FR2933978B1 (fr) * 2008-07-18 2012-12-21 Arkema France Fabrication d'anhydride maleique a partir de matieres renouvelables, anhydride maleique obtenu et utilisations
WO2018119422A1 (en) * 2016-12-22 2018-06-28 Duke University Polycationic microfibers and methods of using the same
AU2018203941B2 (en) * 2017-06-27 2024-04-18 Dow Global Technologies Llc Glycidyl ether alkoxylate block copolymers
CN112279966B (zh) * 2020-11-12 2021-09-24 大连理工大学 一类含二苯基乙基的苯乙烯衍生物共聚物及其接枝聚合物的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6262206B1 (en) * 1997-07-15 2001-07-17 Ciba Specialty Chemicals Corporation Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953404A (en) 1974-02-07 1976-04-27 General Electric Company Solid state polymerization of poly(1,4-butylene terephthalate)
US4217438A (en) 1978-12-15 1980-08-12 General Electric Company Polycarbonate transesterification process
US4315086A (en) 1979-08-08 1982-02-09 Sumitomo Chemical Company, Limited Resin compositions
JPS5655410A (en) 1979-10-15 1981-05-16 Daicel Chem Ind Ltd Continuous bulk polymerization of styrene type copolymer
US4581429A (en) 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
US4644053A (en) 1984-05-11 1987-02-17 General Electric Company Cyclic polycarbonate oligomers and methods for their preparation and use
US4600741A (en) 1984-09-27 1986-07-15 General Electric Company Polyphenylene ether-polyamide blends
US4605731A (en) 1985-04-16 1986-08-12 General Electric Company Method for preparing linear polycarbonate from cyclic oligomer with aryl carbanion generating catalyst
NL8600671A (nl) 1986-03-17 1987-10-16 Gen Electric Polymeermengsel met pc en hips.
US4732937A (en) 1986-05-27 1988-03-22 General Electric Company Epoxide-functionalized polyphenylene ethers and method of preparation
CA1332015C (en) 1987-08-17 1994-09-13 Yuichi Orikasa Thermoplastic resin composition and method for preparing the same
US4844163A (en) 1987-12-29 1989-07-04 Mobil Oil Corporation In-situ foaming of polymer profile control gels
US5204394A (en) 1988-09-22 1993-04-20 General Electric Company Polymer mixture having aromatic polycarbonate, styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom
US5231146A (en) 1990-09-20 1993-07-27 General Electric Company Polyphenylene ether-polyetheramide blends
US5189114A (en) 1990-12-31 1993-02-23 General Electric Company Compatibilization of polyphenylene ether with polyester using polystyrene-polycarbonate copolymer
EP0523259B1 (en) 1991-06-19 1995-03-08 General Electric Company Polymer composition, and moulded objects obtained thereform
EP0546497A3 (en) 1991-12-10 1993-11-18 Idemitsu Kosan Co Thermoplastic resin composition
US5322912A (en) 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom
TW377367B (en) 1994-06-21 1999-12-21 Asahi Kasei Corp Aromatic polycarbonate-styrene polymer resin composition
SE503841C2 (sv) * 1994-09-07 1996-09-16 Bofors Ab Laddsystem
US5449724A (en) 1994-12-14 1995-09-12 Xerox Corporation Stable free radical polymerization process and thermoplastic materials produced therefrom
US6066686A (en) 1996-07-05 2000-05-23 Daicel Chemical Industries, Ltd. Polycarbonate compositions
WO1997027233A1 (de) * 1996-01-25 1997-07-31 Basf Aktiengesellschaft Blockcopolymere
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
US6143848A (en) 1997-10-23 2000-11-07 The B.F.Goodrich Company End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom
FR2773158B1 (fr) * 1997-12-30 2000-02-04 Atochem Elf Sa Procede de polymerisation radicalaire controlee faisant intervenir une faible quantite de radical libre stable
TW400337B (en) 1998-03-17 2000-08-01 Akzo Nobel Nv Process to make low-molecular weight sma
CA2265345A1 (en) * 1998-03-25 1999-09-25 The Lubrizol Corporation Vinyl aromatic-(vinyl aromatic-co-acrylic) block copolymers prepared by stabilized free radical polymerization
CN1159354C (zh) * 1998-07-10 2004-07-28 约翰逊聚合物公司 自由基聚合和缩合反应生产聚合物的方法及相关设备和产物
DE60015553T2 (de) 1999-08-12 2005-10-27 Ciba Speciality Chemicals Holding Inc. Polymermischungen mit verbesserter schlagfestigkeit
AU2003297182A1 (en) * 2002-12-18 2004-07-22 Crompton Corporation Styrenic polymer composites

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6262206B1 (en) * 1997-07-15 2001-07-17 Ciba Specialty Chemicals Corporation Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds

Also Published As

Publication number Publication date
EP1553105A4 (en) 2005-11-09
WO2004009645A2 (es) 2004-01-29
ATE442389T1 (de) 2009-09-15
DE60329206D1 (de) 2009-10-22
ES2333418T3 (es) 2010-02-22
EP1553105B1 (en) 2009-09-09
EP1553105A2 (en) 2005-07-13
US20040077788A1 (en) 2004-04-22
AU2003281535A8 (en) 2004-02-09
AU2003281535A1 (en) 2004-02-09
CA2495213C (en) 2011-05-31
US8030409B2 (en) 2011-10-04
CA2495213A1 (en) 2004-01-29
US20080108752A1 (en) 2008-05-08
US7323528B2 (en) 2008-01-29

Similar Documents

Publication Publication Date Title
WO2004009645A3 (es) Copolímeros en bloque que contienen grupos funcionales
Wieland et al. A new additive for controlled radical polymerization
CA2277164A1 (en) Method of controlling polymer molecular weight and structure
ES2122135T3 (es) Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados.
WO2002055575A8 (en) Process for preparing high diblock content multiblock interpolymers via chain transfer
JP2001316409A (ja) アルコキシアミン存在下の制御されたラジカル重合による多モードポリマー
Wang et al. Free‐Radical Acrylic Polymerization Kinetics at Elevated Temperatures
ATE237646T1 (de) Verfahren zur kontrollierten radikalpolymerisation mit verwendung geringer mengen eines stabilen freien radikalen
Vishnevetskii et al. Controlled radical copolymerization of styrene with acrylic acid and tert-butyl acrylate under conditions of reversible addition-fragmentation chain transfer: Control of the chain microstructure
AU2484002A (en) N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW200635966A (en) Process for preparing silicone-modified polymers
ATE276292T1 (de) Herstellungsverfahren von siliciumorganischen hybridcopolymeren durch kontrollierte radikalische polymerisation
DK0717756T3 (da) Fremgangsmåde til fremstilling af koblede asymmetriske polymerer
EP2045277A3 (fr) Procédé de polymérisation radicalaire pour préparer des copolymères à blocs et copolymères à blocs
SI1408056T1 (sl) Priprava ekspanzibilnih stirenskih polimerov
WO2004089999A3 (en) Dosing of peroxide to a suspension process wherein styrene is polymerized
Herrera et al. Morphology control in polystyrene/poly (methyl methacrylate) composite latex particles
DE69624252D1 (de) Polymere emulgatoren für die vinylchlorid-polymerisation
WO2004077160A3 (en) Method of controlling the differential dissolution rate of photoresist compositions
AU2001278398A1 (en) Chlorine-free polyolefin-based plastisol or organosol and method for producing the same
MXPA02002458A (es) Metodo para controlar distribuciones de peso molecular durante un proceso de polimerizacion.
EP1000954A4 (en) POLYMERS AND METHOD FOR PRODUCING POLYMERS
ATE502966T1 (de) Verfahren zur herstellung wässriger dispersionen von blockmischpolymerisaten
DE60105190D1 (de) Perfluorcyclobutan polymere mit hohem molekulargewicht und verfahren zu deren herstellung
DE69926543D1 (de) Zusammensetzung und kontrollierte radikal polymerisationsverfahren mittels multifunktionellen initiator/regler verbindungen

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: PA/a/2005/000654

Country of ref document: MX

ENP Entry into the national phase

Ref document number: 2495213

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2003741620

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2003741620

Country of ref document: EP

ENPW Started to enter national phase and was withdrawn or failed for other reasons

Ref document number: 03130028

Country of ref document: BR

Free format text: PEDIDO CONSIDERADO COMO RETIRADO EM VIRTUDE DO ARTIGO 24(1)III DO PCT.

NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Ref document number: JP