WO2003101408A1 - Preparation cosmetique a base d'huile auto-emulsionnable - Google Patents

Preparation cosmetique a base d'huile auto-emulsionnable Download PDF

Info

Publication number
WO2003101408A1
WO2003101408A1 PCT/JP2003/006935 JP0306935W WO03101408A1 WO 2003101408 A1 WO2003101408 A1 WO 2003101408A1 JP 0306935 W JP0306935 W JP 0306935W WO 03101408 A1 WO03101408 A1 WO 03101408A1
Authority
WO
WIPO (PCT)
Prior art keywords
self
och
oil
oily cosmetic
mass
Prior art date
Application number
PCT/JP2003/006935
Other languages
English (en)
Japanese (ja)
Inventor
Masaaki Fujisawa
Tamaki Hikita
Yumi Ootsu
Keiichi Ooyama
Original Assignee
The Nisshin Oillio Group, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Nisshin Oillio Group, Ltd. filed Critical The Nisshin Oillio Group, Ltd.
Priority to AU2003241734A priority Critical patent/AU2003241734A1/en
Priority to JP2004508766A priority patent/JP4242830B2/ja
Publication of WO2003101408A1 publication Critical patent/WO2003101408A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids

Definitions

  • the present invention relates to a self-emulsifying oily cosmetic, which has excellent dispersibility in water, is easily emulsified, has excellent long-term storage and stability, and has a good feeling in use. It relates to a type oily cosmetic. Background art
  • Self-emulsifying oily cosmetics generally undergo phase inversion when in contact with water
  • a ZW emulsion is formed and emulsified in water.
  • products such as cleansing agents and bath agents are generally known. The process is thought to form a gel-like substance during phase inversion upon contact with water, and to prepare and emulsify a fine O / W emulsion.
  • Self-emulsifying oil-based cosmetics have the property of producing fine O / W-type emulsions when they come in contact with water, and are used for various purposes by utilizing this property.
  • a self-emulsifying oil-based cleansing agent is used to remove sebum and make-up cosmetics remaining on the skin, and is applied to the skin to dissolve the dirt, followed by water. It is a cleansing agent used after washing.
  • the self-emulsifying oil-based bath agent is of a liquid type and is used by dispersing it in bath water.
  • the bath water becomes an emulsified state, which is used to prevent rough skin, cracks and irritations and to improve the skin condition.
  • conventional self-emulsifying oily cosmetics when they are brought into contact with water and emulsified, the gel-like substance becomes sticky and hard, resulting in poor dispersibility in water. For this reason, conventional self-emulsifying oil-based cleansing agents can easily wash off dirt, resulting in insufficient cleaning. In such cases, cosmetics and active agents may remain on the skin, reducing the feeling of use such as sliminess, oiliness, and squeaky feeling, and improving skin safety. There's a problem.
  • the amount of the surfactant may be reduced to soften the gel substance, but the amount of the surfactant may be reduced. If the amount is reduced, the emulsifiability becomes insufficient. Therefore, as a cleansing agent, its components and dirt remain when it is poured into water, leaving a slimy and oily feeling. Also, as a bath agent, there are problems such as oil floating. Therefore, there is a problem that the function as a product is impaired.
  • the emulsifying property can be improved by adding a large amount of a surfactant, but the addition of a large amount of a surfactant further hardens the gel-like substance. However, dispersibility in water becomes poor.
  • insufficient cleansing charges may result in insufficient rinsing due to poor dispersibility, leaving unwashed dirt, slickness, oiliness and squeaky feeling.
  • As a bath agent there is a problem that it does not disperse or is difficult to disperse.
  • when a large amount of surfactant is added long-term storage, separation at high temperatures, precipitation at low temperatures, etc. occur due to compatibility between the surfactant and oily components, etc., and the function and appearance of the product There is also a problem that is lost.
  • an object of the present invention is to provide a self-emulsifying type oily cosmetic which is excellent in dispersibility in water, excellent in long-term storage and stability, and has a good feeling in use. Disclosure of the invention
  • the present inventors have conducted intensive studies and have found that a self-emulsifying oil containing an ester compound containing a branched fatty acid and Z or a branched alcohol and a specific polyoxyethylene sorbite derivative.
  • Cosmetic softens gel-like substances formed by contact with water, improves dispersibility in water, improves water compatibility, and preserves for long periods of time, high temperature and low temperature.
  • the present inventors have found that the present invention is excellent in stability at the time, and completed the present invention.
  • the present inventors have found that the content of an oleyl group as an acyl group in polytetraethylene oxyethylene sorbite, which has been conventionally used, is low and the above object cannot be achieved.
  • the finding that the above object can be achieved by using a high content of oleyl group as an acyl group in polyoxyethylene sorbite traoleic acid polyoxyethylene sorbite was obtained, and the present invention was completed. .
  • the present invention has been made based on the above findings, and includes a polyoxyethylene sorbite derivative represented by the following general formula (I) and a branched fatty acid and an ester compound containing Z or a branched alcohol as a constituent.
  • a self-emulsifying oil-based cosmetic wherein the content of the polyoxyethylene sorbite derivative is 5 to 30% by mass of the entire self-emulsifying oil-based cosmetic, and is represented by the following formula (I): 85% by mass or more of the total of the groups are oleyl groups, and the content of the ester compound is 20 to 95% by mass.
  • a self-emulsifying oily cosmetic is provided.
  • R 1 R 2 , R 3 and R 4 may be the same or different and each is an acyl group having 14 to 20 carbon atoms represented by the general formula R 5 CO. 5 is a saturated or unsaturated hydrocarbon group, and the sum of a + b + c + d + e + f is 20 to 60 mol per mol of the polyoxyethylene sorbite derivative.
  • the present invention also provides a cleansing agent, a bath agent, and the like, which are the self-emulsifying oil-based cosmetics.
  • the self-emulsifying oily cosmetic of the present invention contains the polyoxyethylene sorbite derivative represented by the general formula (I) and an ester compound having a branched fatty acid and / or a branched alcohol as a constituent.
  • RR 2 , R 3 and R 4 may be the same or different and each is an acyl group having 14 to 20 carbon atoms represented by the general formula R 5 CO .
  • the content of the oleyl group is less than 85% by mass of the total of the acyl group, the dispersibility of the gel-like substance in water is not sufficient, and it is difficult to obtain the effect of long-term product stability.
  • acyl group other than the oleyl group examples include a myristyloyl group, a pentadecyloyl group, a myristolyl group, a palmitoyl group, a palmitoyl group, a stearoyl group, a linoleoyl group, and a linolenoyl group. Examples include, but are not limited to, an inole group.
  • R 5 is a saturated or unsaturated hydrocarbon group.
  • saturated or unsaturated group include those capable of forming the above-mentioned acyl group.
  • the ratio of saturated hydrocarbon group for R 5 includes a this is not more than 5 wt% of the sum of the saturated carbon hydrocarbon group and unsaturated hydrocarbon group laid preferred, with 4 wt% or less Something is even better.
  • the proportion of the saturated hydrocarbon group exceeds 5% by mass of the total of the saturated hydrocarbon group and the unsaturated hydrocarbon group, the resulting self-emulsifying oily cosmetic may cause precipitation or odor, and the stability may deteriorate. It may be deteriorated, and the dispersibility in water may not be sufficient. Therefore, it is preferable to be within the above range.
  • the sum of a + b + c + d + e + f is 20-60 mol per 1 mol of the polyoxyethylene sorbite derivative. If the sum of a + b + c + d + e + f is less than 20, the dispersibility and emulsifying property of the gel-like substance in water will be insufficient, and oil will float. On the other hand, if it exceeds 60, sedimentation or separation in the product will occur, causing problems in stability. It is preferable that the sum of a + b + c + d + e + f is 25 to 40.
  • HLB is preferably from 10 to I4.
  • HLB means a hydrophilic lipophilic balance, and the hydrophilic group and the lipophilic group of the surfactant at the interface between the two layers indicate the hydrophilicity of each layer. A number determined from the balance between gender and lipophilicity.
  • the method for producing the polyoxyethylene sorbite derivative represented by the above general formula (I) is not particularly limited. For example, after adding sodium hydroxide to sorbitol, and then adding ethylene oxide, And a method in which a fatty acid such as oleic acid is added, and the mixture is heated at a temperature of 130 to 150 ° C. for a long time to produce an esterification reaction.
  • Fatty acid raw materials used for producing the polyoxyethylene sorbite derivative represented by the above general formula (I) contain 85% by mass or more, preferably 90% by mass of oleic acid among all fatty acids. Use something.
  • Examples of such fatty acids rich in oleic acid include soybean fatty acids, rapeseed fatty acids, corn fatty acids, safflower fatty acids, rice bran fatty acids, cottonseed fatty acids, sunflower fatty acids, sesame fatty acids, Examples include vegetable-derived fatty acid raw materials such as olive fatty acid, peanut fatty acid, palm fatty acid, palmolein fatty acid, and pine fatty acid, and animal-derived fatty acid raw materials such as beef tallow and lard.
  • rapeseed fatty acids, palm fatty acids, palm oleic fatty acids, beef tallow and lard are preferably used because they are inexpensive and can be supplied stably.
  • the above fatty acids are concentrated by molecular distillation, purified by columns, hydrogenated, wintering, solvent fractionation, squeezing method, surfactant fractionation, liquid-liquid extraction, supercritical extraction, distillation, urea
  • the oleic acid content can be increased by carrying out an addition method, an acidic soap separation method, a molecular sieve, a silver complex, an enzyme and the like.
  • Polyoxyethylene sorbite derivatives represented by the above general formula (I) 85% by mass or more of the total of the acyl groups is an oleyl group, and R 1 , R 2 , R 3 and R 4 in the general formula (I) are composed of two or more kinds of acyl groups. Therefore, the polyoxyethylene sorbite derivative represented by the general formula (I) can be obtained as a mixture of those having various substituents.
  • the content of the polyoxyethylene sorbite derivative represented by the above general formula (I) is 5 to 30% by mass, preferably 5 to 25% by mass of the whole self-emulsifying oily cosmetic. And more preferably 10 to 20% by mass.
  • the content of the polyoxyethylene sorbite derivative represented by the above general formula (I) is less than 5% by mass, the emulsification is not sufficient, the obtained effect is insufficient, and the effect of improving stability is also obtained. Is insufficient. On the other hand, if the content exceeds 30% by mass, sedimentation, separation, etc. will occur, and the effect of improving the stability will not be obtained.
  • the ester compound contained in the self-emulsifying oily cosmetic composition of the present invention comprises a branched fatty acid and a phenol or a branched alcohol.
  • the carbon number of the branched fatty acid and the branched alcohol constituting the ester compound is preferably 3 to 22.
  • the ester compound may be a monoester compound containing a branched fatty acid and / or a branched alcohol as a component.
  • ester compound contained in the self-emulsifying oily cosmetic of the present invention examples include glycerol tri-2-ethylhexanoate, glyceryl trisopalmitate and the like.
  • Examples of the above-mentioned monoester compounds include, for example, isonosonic acid, isotridecyl isononanoate, isopropyl myristate, isostearyl myristate, and palmitic acid.
  • 2 O such as isonoyl isonanoate, isotridecyl isononanoate, isopropyl myristate, octyl palmitate, and cetyl 2-ethylhexanoate Those having a low viscosity of not more than mPa'S (20 ° C) are preferably used.
  • ester compounds may be used alone or as a mixture of two or more. It may be.
  • the content of the ester compound in the self-emulsifying oily cosmetic is from 20 to 95% by mass, preferably from 50 to 95% by mass, and more preferably from 60 to 90% by mass. More preferably, it is / 0 .
  • the content of the ester compound is 20 mass. If it is less than / 0 , the formed gel will be hard and poor in dispersibility in water. On the other hand, if it exceeds 95% by mass, the emulsification becomes insufficient, the effect of dispersibility in water becomes insufficient, and the effect of improving stability becomes insufficient.
  • the self-emulsifying oily cosmetic of the present invention does not substantially contain water, but it is possible to incorporate water as long as its function is not impaired.
  • the water content is preferably less than 5% by mass.
  • Water content is 5 mass. If it is more than / 0 , precipitation or separation may occur, and the effect of improving stability may not be obtained. Therefore, the content is preferably less than 5% by mass. If the water content is less than 5% by mass, the polyoxyethylene sorbite derivative represented by the general formula (I) and the water are in a solubilized state, which is preferable.
  • the solubilized state refers to a state in which oil is present as a dispersion medium, and the polyoxyethylene sorbite derivative and water have become reverse micelles.
  • polyhydric alcohols which are compounds having generally two or more hydroxyl groups, such as glycerin diol alcohols, have a gel-like substance that is harder, and The dispersibility may be insufficient, so it is preferable not to add them, but if they are used in small amounts, they may be added.
  • the self-emulsifying oily cosmetic of the present invention may contain, if necessary, a surfactant other than the polyoxyethylene sorbite derivative of the present invention, a higher fatty acid, a higher alcohol, a hydrocarbon, a silicone compound, Ester oils other than the ester compounds comprising the branched fatty acid and Z or branched alcohol of the invention, powder components, humectants, ultraviolet absorbers, sequestering agents, lower alcohols, amino acids, organic amines, Synthetic resin emulsion, pH adjuster, vitamin , Antioxidants, antioxidant aids, plant extracts, fragrances, etc., cosmetic raw material standards, cosmetic varieties-specific ingredients, quasi-drug raw material standards, Japanese Pharmacopoeia, Japanese Pharmacopoeia, Standards for Food Additives Components such as the described raw materials may be added. These components may be used alone or as a mixture of two or more.
  • surfactant other than the above-mentioned polyoxyethylene sorbite derivative of the present invention examples include sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester, and polyglycerol.
  • Linoleic fatty acid ester ethylene oxide derivative of glycerin fatty acid ester, propylene glycol fatty acid ester, ethylene oxide derivative of propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester , Polyoxyethylene alkyl ether, Polyoxypropylene alkyl ether, Polyoxyethylene alkyl phenyl ether, Polyoxyethylene castor oil conductor, Polyoxyethylene hydrogenated castor oil, Polyoxyethylene fite Data node on ether, Po the Rio carboxymethyl ethylene Fi Tosutero one Noree one Tenore, Po Li oxyethylene blast Leste Li ether, Po Li Okishiaruki Ren modified organo Po Li white etc. like et be.
  • higher fatty acids examples include, for example, rauric acid, myristic acid, panolemitic acid, stearic acid, behenic acid (beheninic acid), oleic acid, pendecilenic acid, and tolic acid. , Isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) and the like.
  • high-quality alcohols examples include, but are not limited to, Rauril Alcohol, Cetyl Vanore Konore, Steari Noleanole Ko—Nore, Beheninorenore Ko—Nore, Miristinore Vanore Konore, Orey Lulanore Straight chain, such as coconut and set steal ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇
  • hydrocarbons examples include liquid paraffin, isoparaffin, ozokerite, squalane, pristane, seresin, squalene, decelin, and microcrystalline starch wax. And ⁇ -olefin oligomers.
  • silicone compound examples include chain polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydridoenepolysiloxane, octamethylcyclotetrasiloxane, decamethynoresic pentasiloxane, and dodecamethynoresic syrup.
  • chain polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydridoenepolysiloxane
  • octamethylcyclotetrasiloxane decamethynoresic pentasiloxane
  • dodecamethynoresic syrup examples include cyclic polysiloxanes such as oxasiloxane and tetrahydrotetramethylcyclotetrasiloxane, and polyoxyethylene polyalkylsiloxane.
  • ester oil other than the ester compound having the branched fatty acid and / or branched alcohol of the present invention as a component examples include, for example, butyl stearate, myristyl myristate, and decyl oleate.
  • Examples of the above powder components include talc, porcelain ore, mica, sericite, muscovite, phlogopite, synthetic mica, phlogopite, biotite, lithium mica, permikilite, Magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, sulfuric acid Barium, calcined calcium sulfate, (calcined ⁇ ), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, metal stone (zinc myristate, calcium palmitate, stainless steel) Inorganic powders such as aluminum aluminate, boron nitride, polyamide resin powder (polyethylene powder), polyethylene Organic powders such as powders, polymethyl methacrylate powder, polystyrene powder, styrene / acrylic acid copolymer resin powder, benzoguanamine
  • inorganic white pigments such as titanium dioxide, zinc oxide, etc.
  • inorganic red pigments such as iron oxide (iron oxide), iron titanate, etc.
  • inorganic brown pigments such as ⁇ -iron oxide, iron yellow oxide, loess etc.
  • Inorganic yellow pigments black iron oxide, carbon black, inorganic black pigments such as titanium hypooxide, etc., inorganic purple pigments such as mango violett and cobalt violet, chromium oxide, chromium hydroxide , Inorganic blue pigments such as cobalt titanate, inorganic blue pigments such as ultramarine, navy blue, etc., titanium oxide-titanium oxide, titanium oxide titanium oxide bismuth chloride, titanium oxide coated Pearl, pigmented pigments such as oxychloride bismuth, fish scale foil, metal powder pigments such as aluminum powder, copper-padder, etc., red No. 201, red No.
  • humectant examples include chondroitin sulfate, hyaluronic acid, mucotin sulfate, caronic acid, atherocollagen, cholesteryl-112-hydroxyl cystate, sodium lactate, and the like.
  • UV absorber examples include paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester
  • PABA paraaminobenzoic acid
  • Benzoic acid-based ultraviolet absorbers such as tenore, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, and anthranil such as homomethyl-N-acetylethyl tranylate
  • Acid-based UV absorbers amylzali silicate, menthyl salicylate, homomethyl salicylate, octyl salicylate, phenylol salicylate, benzyl salicylate, p-isoprono, o-norphenyl salicylate
  • ester oils are ester oils.
  • sequestering agent examples include 1-hydroxyxetane-11,1 diphosphonic acid, 1-hydroxyxetane-11,1—tetrasodium diphosphonate, and edetate ninato Sodium, sodium edetate, sodium edetate, sodium citrate, sodium polyphosphate, sodium metalate, darco Acid, phosphoric acid, cunic acid, ascorbic acid, succinic acid, edetic acid, ethylenediaminehydroxicetyl triacetate 3 sodium and the like.
  • the lower alcohols include, for example, methanol, ethanol, pupanone-no-nore, and isopro. And monobutanol, isobutinoleanorecone, t-butinorea alcohol, and the like.
  • Examples of the above-mentioned amino acids include neutral amino acids such as threonine and cystine, and basic amino acids such as hydroxylysine.
  • Examples of the amino acid derivatives include, for example, asilsarcocinnatrium (lauuroyl sarcosine sodium), asiglutamate, asil / 3-araninesodium, glutathione, and pyrrolidonecarboxylic acid. And the like.
  • Examples of the above-mentioned organic amine include monoethanolamine, jetanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino2—. Examples thereof include methyl-1,3-phenyldiol and 2-amino-1-methyl-1-propanol.
  • Examples of the synthetic resin emulsion include, for example, acryl resin emulsion, polyacrylic acid ethynolemane resin, acryl resin resin, and polyacryl alkyl ester emulsion. Polyvinyl acetate resin emuljo And the like.
  • pH adjuster examples include buffers such as sodium lactate-lactate and sodium citrate-monoatenoate.
  • the above vitamins include, for example, vitamin AB! , B 2 B 6 E and its derivatives, pan Toten acid and its derivatives, Biochin the like.
  • antioxidants examples include tocoproles, dibutylhydroxytoluene, butylhydroxyanisole, and gallic esters.
  • antioxidant aid examples include phosphoric acid, cunic acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumanoleic acid, kephalin, hexameta phosphate, Phytic acid, ethylenediaminetetraacetic acid and the like can be mentioned.
  • Examples of the above plant extracts include akajiaji, asenjak, amachya, al-niki, aloe, apricot, squid liquor, ginkgo, nettle, ikeki, konkon, umbeyuaoi, mushroom, orange.
  • Natural flavors include, for example, rose oil, jasmine oil, neroli oil, lavender oil, Iran ylang oil, tuberose oil, clarage oil, clove oil and pepper.
  • fragrances examples include limonene, j3—force phenylene, cis-13—hexeno-norre, lina-guchi honore, phanolene sonole, ⁇ —pheninole ethinolenorre konore, 2 , 6—Nanogena, citranole, ⁇ -Ixyl cinnamic aldehyde, —ionon, 1—force norebon, cyclopentadecanonone, linolenoreacetate, benlupenzole, ⁇ — Pendecalactone, Eugenol, Loose Oxide, Indole, Phenylacetaldehyde Dodecimetyl Acetal, Auranthiol, Geranio Ile, Citronellonore, Tarpineo Ile, Mente Ile, Santa Lonore, Baku Dano-Nore, Bramano-Nore, Li-La-Nore, Li-Ria Nore,
  • compositions of the present invention include, for example, preservatives such as methylparaben, ethylparaben, propylparaben, butylparaben, phenoxyethanol, and the like.
  • Anti-inflammatory agents such as glycyrrhizic acid, glycyrrhizic acid derivatives, glycyrrhetinic acid, glycyrrhetic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, alanthin, placental extracts, yukinoshita extracts, etc.
  • Whitening agents extracts of royal jelly, pearl protein, silk, etc., photosensitizers, cholesterol derivatives, activators of infant blood extracts, etc., nonyl acid ⁇ renylamide, nicotinic acid benzyl ester, nicotinic acid ⁇ —Butoxycinolenoester, capsaicin, zingerone, canteric tincture, dicta , Tannic acid, ⁇ -bonole neole, nicotinic acid tocopherone, inositol hexanenicotine, cyclanderate, cinnaridine, trazolin, acetylcholine, verapamil, cepharanthin, ⁇ - Examples include blood circulation promoters such as oryzanol, antiseborrheic agents such as sulfur and thiathanol, tranexamic acid, thiotaurine, hibotapulin, and extracted water.
  • blood circulation promoters such
  • the compounding amount of the above components is within a range that does not impair the function of the self-emulsifying oily cosmetic of the present invention, and is about 0 to 70% by mass.
  • the self-emulsifying oily cosmetic of the present invention can be used as a cleansing agent, a bath agent and the like.
  • the method for producing the cleansing agent and the bath agent, which are the self-emulsifying oily cosmetics of the present invention is not particularly limited.
  • polyoxyethylene which is a component of the self-emulsifying oily cosmetic of the present invention is used. After mixing an ester compound having a sorbitol derivative, a branched fatty acid and / or a branched alcohol, and other components such as a hydrocarbon, a preservative, and a fragrance, the mixture is heated to a temperature of 60 to 70 ° C. Dissolves by heating and becomes more uniform And then cooled to room temperature.
  • Example 1 Example 1
  • Self-emulsifying oily cosmetics were produced using various surfactants (polyoxyethylene sorbite derivatives represented by the general formula (I)), and their evaluation was performed.
  • Fatty acid compositions constituting various polyoxyethylene sorbite derivatives, that is, R 1 R 2 , R 3 and R 4 represented by the general formula (I) were analyzed by gas chromatography, and the results were tabulated. See Table 1 and Table 2.
  • the numbers in 1 and Table 2 are% by mass.
  • the oleyl group is represented as C 18: 1.
  • commercially available surfactants C, D, E and F were used.
  • the HLB of surfactants A, B, C, D, E and F are 11.2, 12.5, 10.5, 11.8,
  • cleansing agents which are self-emulsifying oily cosmetics having the formulations shown in Tables 3 and 4 were produced.
  • the numbers in Tables 3 and 4 are parts by mass.
  • the components shown in Tables 3 and 4 were mixed, then heated and dissolved at a temperature of 60 to 70 ° C, and mixed until uniform. After it became uniform, it was left to cool to room temperature to obtain a cleansing agent.
  • Example 1 Example 2
  • Example 3 Example 4
  • Surfactant B 2.0.3.0
  • the obtained cleansing fee was evaluated according to the following [Method for evaluating cleansing fee].
  • Example 14 The cleansing materials of Example 14 and Comparative Example 14 were left at a temperature of 50 ° C (stability at high temperature) or 5 ° C (stability at low temperature) for one month, and the change in appearance was observed. It was visually observed and evaluated according to the following evaluation criteria. The results are shown in Tables 5 and 6. ⁇ : No change in appearance.
  • the foundation was applied to the skin of 10 female panelists, and the foundation applied to the skin was applied to the skin using the cleansing ingredients (5 ml) of Examples 1-4 and Comparative Examples 1-4. After massage for 2 seconds, it was rinsed with a shower for 10 seconds, and the slimy feeling and dirt removal after washing were evaluated based on the following evaluation criteria.
  • the evaluations of 10 people were totaled, the average score was calculated, and the evaluation was performed using the average score.
  • the evaluation was performed according to the following evaluation criteria. The results are shown in Tables 5 and 6. ⁇ : The average score is 4.5 or more.
  • the average score is 3.5 or more and less than 4.5.
  • the average score is 2.5 or more and less than 3.5.
  • the average point is less than 2.5 points.
  • the self-emulsifying oily cosmetic of the present invention is excellent in dispersibility in water, excellent in stability and excellent in use feeling and dirt removal. Is what it is.
  • Oreiru group content in the poly oxyethylene Sorubi' bets derivative is 8 less than 5 mass 0/0 of the sum of all ⁇ sill group, in cleanse fee Comparative Example 1 4, all items In this case, it was inferior to the cleansing fee of Example 14.
  • bath agents as self-emulsifying oily cosmetics having the formulations shown in Tables 7 and 8 were produced.
  • the numbers in Tables 7 and 8 are parts by mass.
  • To manufacture the bath agent mix the components shown in Table 7 and Table 8, then heat and dissolve at a temperature of 60 to 70 ° C, and mix And mixed until After it became uniform, it was left to cool to room temperature to obtain a bath agent.
  • the obtained bath agent was evaluated according to the following [Method for evaluating bath agent]. (Evaluation method of bath agent)
  • the bath agents (5 ml) of Examples 5 to 8 and Comparative Examples 5 to 8 were dispersed in hot water (500 ml) at a temperature of 40 ° C., stirred for 3 seconds, and the state was observed.
  • the evaluation was performed according to the following evaluation criteria. The results are shown in Tables 5 and 6. The results are shown in Tables 9 and 10.
  • Example 5 to 8 Ten women were evaluated as panelists.
  • the bath preparations (20 ml) of Examples 5 to 8 and Comparative Examples 5 to 8 were put into a bath (including 200 L of hot water) containing hot water at a temperature of 40 ° C., and lightly lightened by hand for 3 seconds. After stirring, the patient was bathed for 5 minutes, and the firmness after bathing was evaluated based on the following evaluation criteria. Very good: 5 points
  • the average score is 4.5 or more.
  • the average score is 3.5 or more and less than 4.5.
  • the average score is 2.5 or more and less than 3.5.
  • the average point is less than 2.5 points.
  • the bath agent which is a self-emulsifying oily cosmetic of the present invention, has good dispersibility in hot water, excellent stability, and excellent feeling in use. Things.
  • the content of oleyl group in the polyoxyethylene sorbite derivative was 85 mass of the sum of all the acyl groups.
  • the self-emulsifying oily cosmetic of the present invention comprises a polyoxyethylene sorbit derivative represented by the general formula (I), a branched fatty acid and / or a branched alcohol.
  • a polyoxyethylene sorbit derivative represented by the general formula (I) a branched fatty acid and / or a branched alcohol.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

Cette invention concerne une préparation cosmétique à base d'huile auto-émulsionnable comprenant un dérivé de polyoxyéthylène sorbitol représenté par la formule générale (I) et un composé ester comprenant un acide gras ramifié et/ou un alcool ramifié, 85 % en poids au moins de tous les groupes alcyle de la formule générale (I) étant des groupes oléyle. Cette préparation cosmétique à base d'huile, auto-émulsionnable, donne une sensation agréable et est remarquable sous l'angle de l'aptitude au stockage et de la stabilité à long terme. De plus, sa dispersibilité dans l'eau est excellente.
PCT/JP2003/006935 2002-06-03 2003-06-02 Preparation cosmetique a base d'huile auto-emulsionnable WO2003101408A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2003241734A AU2003241734A1 (en) 2002-06-03 2003-06-02 Self-emulsifiable oil-based cosmetic preparation
JP2004508766A JP4242830B2 (ja) 2002-06-03 2003-06-02 自己乳化型油性化粧料

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002-160946 2002-06-03
JP2002160946 2002-06-03

Publications (1)

Publication Number Publication Date
WO2003101408A1 true WO2003101408A1 (fr) 2003-12-11

Family

ID=29706565

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2003/006935 WO2003101408A1 (fr) 2002-06-03 2003-06-02 Preparation cosmetique a base d'huile auto-emulsionnable

Country Status (3)

Country Link
JP (1) JP4242830B2 (fr)
AU (1) AU2003241734A1 (fr)
WO (1) WO2003101408A1 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03115208A (ja) * 1989-09-28 1991-05-16 Kobayashi Kose Co Ltd 皮膚用油性化粧料
JPH0489420A (ja) * 1990-08-01 1992-03-23 Kao Corp クレンジング用組成物
JPH04211010A (ja) * 1990-03-05 1992-08-03 Nisshin Oil Mills Ltd:The 白濁浴用剤
JPH04224507A (ja) * 1990-12-25 1992-08-13 Kose Corp 透明ゲル組成物
JPH1095707A (ja) * 1996-09-20 1998-04-14 Kose Corp 水中油型化粧料
JPH10236922A (ja) * 1997-02-25 1998-09-08 Kao Corp クレンジング剤組成物
WO2000037029A1 (fr) * 1998-12-22 2000-06-29 The Procter & Gamble Company Compositions transparentes de soins pour la peau
JP2000297029A (ja) * 1999-04-12 2000-10-24 Nof Corp 入浴剤
JP2001288036A (ja) * 2000-01-31 2001-10-16 Kose Corp 透明クレンジング料

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03115208A (ja) * 1989-09-28 1991-05-16 Kobayashi Kose Co Ltd 皮膚用油性化粧料
JPH04211010A (ja) * 1990-03-05 1992-08-03 Nisshin Oil Mills Ltd:The 白濁浴用剤
JPH0489420A (ja) * 1990-08-01 1992-03-23 Kao Corp クレンジング用組成物
JPH04224507A (ja) * 1990-12-25 1992-08-13 Kose Corp 透明ゲル組成物
JPH1095707A (ja) * 1996-09-20 1998-04-14 Kose Corp 水中油型化粧料
JPH10236922A (ja) * 1997-02-25 1998-09-08 Kao Corp クレンジング剤組成物
WO2000037029A1 (fr) * 1998-12-22 2000-06-29 The Procter & Gamble Company Compositions transparentes de soins pour la peau
JP2000297029A (ja) * 1999-04-12 2000-10-24 Nof Corp 入浴剤
JP2001288036A (ja) * 2000-01-31 2001-10-16 Kose Corp 透明クレンジング料

Also Published As

Publication number Publication date
JP4242830B2 (ja) 2009-03-25
JPWO2003101408A1 (ja) 2005-09-29
AU2003241734A1 (en) 2003-12-19

Similar Documents

Publication Publication Date Title
KR101703373B1 (ko) 화장료 조성물, 화장료, 수중유형 유화 화장료의 제조방법 및 이층 분리형 화장료
KR101224345B1 (ko) 화장료 조성물 및 화장료
KR101102797B1 (ko) 폴리글리세린 중쇄 지방산 에스테르 함유 조성물
WO2005051334A1 (fr) Preparation cosmetique a emulsion de type a phase continue aqueuse et procede de production associe
KR20120060833A (ko) Ｏ／ｗ 유화 조성물의 제조 방법
JP7058943B2 (ja) 水中油型乳化組成物
JP2010254624A (ja) マイクロエマルション
JP5410650B2 (ja) 化粧料用組成物及び化粧料
KR101988673B1 (ko) 향상된 모이스처라이저 블렌드
JP5382974B2 (ja) 化粧料用組成物及び化粧料
JP5058457B2 (ja) 化粧料用組成物及び化粧料
JP2006316003A (ja) 水素添加ロジンのアルコールエステルを含有する安定な液状組成物およびそれを含有する化粧料
JPH0686373B2 (ja) 化粧料
JP2006069979A (ja) 化粧料用組成物及び化粧料
JPH04290810A (ja) 三層型化粧料
JP2004256514A (ja) 自己乳化型油性液状化粧料
JP6666737B2 (ja) 皮膚外用剤または化粧料として有用な組成物
JP6498987B2 (ja) 透明油性化粧料
WO2003101408A1 (fr) Preparation cosmetique a base d'huile auto-emulsionnable
JP4041475B2 (ja) 自己乳化型油性固形状化粧料
JPH01238518A (ja) オイル含有組成物
JP3520173B2 (ja) 可溶化化粧料
JP2009029758A (ja) メイククレンジング用洗浄剤
TW201922202A (zh) 水中油型乳化固形化妝料
JP4809052B2 (ja) クレンジング化粧料

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2004508766

Country of ref document: JP

122 Ep: pct application non-entry in european phase