WO2003067045A1 - Exhaust emission control system - Google Patents

Exhaust emission control system Download PDF

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Publication number
WO2003067045A1
WO2003067045A1 PCT/JP2002/001022 JP0201022W WO03067045A1 WO 2003067045 A1 WO2003067045 A1 WO 2003067045A1 JP 0201022 W JP0201022 W JP 0201022W WO 03067045 A1 WO03067045 A1 WO 03067045A1
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WO
WIPO (PCT)
Prior art keywords
exhaust gas
tank
water
exhaust
activated carbon
Prior art date
Application number
PCT/JP2002/001022
Other languages
French (fr)
Japanese (ja)
Inventor
Yukio Toyama
Original Assignee
Yukio Toyama
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Yukio Toyama filed Critical Yukio Toyama
Priority to PCT/JP2002/001022 priority Critical patent/WO2003067045A1/en
Publication of WO2003067045A1 publication Critical patent/WO2003067045A1/en

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/04—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/02—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
    • B01D47/021—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath by bubbling the gas through a liquid bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F01N2370/40—Activated carbon or charcoal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Definitions

  • the present invention relates to an exhaust gas purifying apparatus that purifies exhaust gas from a combustion apparatus, thereby preventing harmful substances from being discharged into the atmosphere, and improving exhaust gas pollution.
  • diesel cars in particular have the advantage that fuel (light oil) is inexpensive, energy efficient, and their service life is extremely long compared to gasoline cars. Therefore, despite their impact on exhaust gas pollution, diesel engines are widely used as engines for large vehicles such as trucks and buses, and the number of diesel engines used in various fields in the industrial field has been increasing. Is increasing year by year.
  • an exhaust gas purification device generally refers to a device that removes suspended particulate matter in exhaust gas from diesel vehicles. For example, installing a muffler instead to burn black smoke to the maximum and reduce the amount of suspended particulate matter by about 80%, resulting in low pollution of diesel vehicles It is.
  • Such an exhaust gas purification device can be manufactured for about 200,000 yen if a structure using a catalyst is adopted.
  • the sulfur contained in the diesel diesel fuel corrodes the metal part of the exhaust gas purifying device (DPF) itself. It must be made of very expensive ceramic.
  • the exhaust gas purifying apparatus disclosed in Japanese Patent Application Laid-Open No. 7-189658 / 1994 and Japanese Patent Application Laid-Open No. 6-123217 separates and collects harmful substances such as dust containing SPM. Is possible, but its ability to remove other harmful substances such as N ⁇ x, SOx, and HC is not sufficient.
  • the exhaust gas purifying apparatus disclosed in Japanese Patent Application Laid-Open No. Hei 7-224648 can remove NOx and SOx, but requires the use of a special aqueous solution, and is therefore troublesome to handle. Yes, maintenance costs are high. Furthermore, even if the two are simply combined, handling remains difficult as long as a special aqueous solution is used.
  • the present invention has been proposed in order to solve the above-mentioned problems of the prior art, and it is possible to reliably and efficiently reduce the emission of various harmful substances with an inexpensive and simple configuration.
  • the aim is to improve exhaust gas pollution promptly and contribute to environmental protection by providing easy-to-handle exhaust gas purification equipment. Disclosure of the invention
  • an exhaust gas purifying apparatus of the present invention includes a tank in which water is sealed, a connecting pipe for sending exhaust gas from a combustion device into the water in the tank, and a water pipe in the tank.
  • the exhaust gas from the combustion device is sent into the water from the connecting pipe, and harmful substances such as strongly acidic NO X and SOX come in contact with the alkaline limestone and become harmful. Sum, removed. Furthermore, when the exhaust gas passes through the mesh, the bubbles become finer and the contact area with water increases, so that dust such as SPM in the exhaust gas is efficiently captured in the water.
  • the purified exhaust gas is discharged to the outside via the exhaust stack.
  • the vibration of the second metal mesh having a fine mesh allows water and exhaust gas to be separated. Contact is promoted and particulate matter can be trapped more efficiently.
  • FIG. 1 is a side sectional view showing one embodiment of an exhaust gas purifying apparatus of the present invention. You.
  • FIG. 2 is a front sectional view of the embodiment of FIG.
  • FIG. 3 is a rear sectional view of the embodiment of FIG.
  • FIG. 4 is a front sectional view showing a net portion of the embodiment of FIG.
  • FIG. 5 is a front view showing the partition plate of the embodiment shown in FIG.
  • FIG. 6 is a perspective view showing the activated carbon filter of the first embodiment.
  • FIG. 7 is a transparent side view of the activated carbon filter of FIG.
  • FIG. 8 is a side sectional view of the activated carbon filter of FIG. BEST MODE FOR CARRYING OUT THE INVENTION
  • the exhaust gas purifying apparatus of the present embodiment has an overall configuration as shown in FIGS. 1 to 3, and includes a tank 1, a connecting pipe 2, and an exhaust pipe 3. Inside the tank 1, limestone 4, activated carbon 5, wire mesh 6, and partition plate 7 are provided. Limestone 4 and activated carbon 5 are spread on the inner bottom of tank 1 so as to be mixed. As limestone 4, it is desirable to use Ryukyu limestone produced from the central and southern part of Okibashi main island. Further, in order to promote the reaction described later, it is preferable to use one obtained by increasing the calcined lime (CaO) component by firing.
  • CaO calcined lime
  • the wire mesh portion 6 is disposed at an intermediate portion in the height direction in the tank 1, and is constituted by a first wire mesh 6a and a second wire mesh 6b.
  • the first wire mesh 6a is coarse, and is provided two above and below at predetermined intervals.
  • the second wire mesh 6b is fine and is arranged so as to be folded between the two first wire meshes 6a as shown in FIG.
  • the partition plate 7 is a vertical plate having a large number of holes formed therein for allowing air to flow therethrough, and a plurality of the partition plates 7 are provided at predetermined intervals.
  • the tank 1 is filled with a predetermined amount of water 9 so that a space 8 filled with the atmosphere is provided.
  • the tank 1 is provided with a water inlet 1a for supplying water and a drain 1b for discharging water, and a level gauge 10 so that the internal water level can be checked from outside. Are arranged.
  • a connecting pipe 2 is inserted into the section, and an exhaust pipe 3 is provided at the upper part.
  • the connecting pipe 2 has one end connected to an exhaust port of an internal combustion engine A such as a diesel engine, and the other end inserted near the bottom of the tank 1.
  • a large number of exhaust holes 2 a are formed in the connecting pipe 2 in the tank 1 so that the exhaust gas is directed toward the limestone 4 and the activated carbon 5.
  • the exhaust stack 3 is connected with an activated carbon filter 11.
  • the activated carbon filter 11 is obtained by packing activated carbon 13 in a cylindrical container 12.
  • An introduction pipe 14 and a discharge pipe 15 are provided in the axial direction of the container 12.
  • the introduction pipe 14 has one end connected to the exhaust pipe 3 and the other end inserted into the activated carbon 13.
  • a plurality of holes 14 a for supplying the exhaust gas from the exhaust stack 3 to the activated carbon 13 are formed around the vicinity of the other end of the introduction pipe 14. Between the container 12 and the activated carbon 13, there is provided a gap 12 a through which the exhaust gas passing through the activated carbon 13 passes. Further, a space 12 c having a plurality of holes 12 b communicating with the gap 12 a is formed on the discharge pipe 15 side in the container 12, and the space 12 c is discharged. It communicates with tube 15.
  • the exhaust gas purifying apparatus of the present invention has the above-described configuration as an example. To be discharged to The details will be described below.
  • the exhaust gas discharged from the exhaust port of the internal combustion engine A to the connecting pipe 2 is discharged from the many exhaust holes 2a of the connecting pipe 2 arranged at the bottom of the tank 1 and the water 9 in the tank 1. And is sprayed against limestone 4. Then, the strongly acidic exhaust gas reacts and is neutralized by the alkaline limestone 4. At this time, calcium oxide (C a O) in the limestone 4 reacts with water to form a hydroxide hydroxide (C a (OH) 2 ), and harmful substances such as NO x and SO x a Removed from exhaust gas by reacting with (OH) 2 .
  • C a (OH) 2 reacts with nitrogen dioxide (N 0 2) calcium hydroxide (C a (OH) 2) , an expression that the calcium nitrate neutral (C a (N 0 3) 2), shown below.
  • sulfur dioxide (S0 2) is calcium hydroxide (Ca (OH) 2 )
  • CaSO calcium sulfite
  • the exhaust gas moves from the water 9 to the space portion 8, and when passing through the activated carbon filter 11 from the exhaust stack 3, the remaining harmful substances are captured and discharged to the atmosphere.
  • dust such as SPM trapped in the water 9 is adsorbed on a large number of pores of the activated carbon 5 arranged at the bottom of the tank 1 by stirring the water 9 with bubbles of exhaust gas.
  • the water 9 in which the harmful substances are dissolved is discharged from the drain port lb, is treated by a treatment device (not shown), and fresh water is newly supplied into the tank 1 from the water inlet port 1a.
  • a treatment device not shown
  • limestone 4 and activated carbon 5 to which dust such as SPM and substances generated by the reaction are attached and adsorbed are appropriately replaced according to the degree of contamination.
  • the harmful substances contained in the exhaust gas discharged from the internal combustion engine such as a diesel engine are discharged into the water 1 in the tank 1, the limestone 4, the activated carbon before being released into the atmosphere. 5 removes most of it.
  • the formation of bubbles and the contact between the water 9 and the exhaust gas are promoted by the coarse mesh first wire mesh 6 a and the fine mesh second wire mesh 6 b in the wire mesh portion 6.
  • the constituent materials required in the present embodiment are air, water, limestone, activated carbon, wire mesh, etc., which are safe and harmless and inexpensive or very easily available. All of the components are easy to handle without any danger, and are therefore easy to put into practical use.
  • Ryukyu limestone when Ryukyu limestone is used, it has many burrows because it is a stone that was deposited several hundred thousand years ago. Therefore, the harmful substance removing effect by the above reaction is high.
  • the particulate matter (SPM) captured in the water is adsorbed by the activated carbon 5, so that the cleanliness of the water can be easily maintained.
  • the activated carbon filter 11 also removes harmful substances remaining in the exhaust gas, so that the gas released to the outside can have a very high degree of cleanliness. Further, since the inside of the tank 1 is partitioned by a plurality of partition plates 7, even when the vehicle starts and stops, the water is prevented from being washed away.
  • the present invention is not limited to the above-described embodiment, and the material, shape, size, quantity, and the like of each member can be appropriately changed.
  • the material of the net portion not only metal but also other materials such as ceramic may be used.
  • the size of the mesh of the mesh is not limited to a specific size.
  • other materials such as nonwoven fabric and ceramic can be used instead of activated carbon or activated carbon filter, or other materials can be used together with activated carbon.
  • Limestone is not limited to Ryukyu limestone.
  • limestone or activated carbon at a place other than the bottom of the tank to more effectively contact the limestone / activated carbon with the exhaust gas and the stirred water.
  • limestone may be arranged on the net.
  • air bubbles can be generated in the entire area of the tank by branching the connection pipe into multiple sections or by changing the size and number of exhaust holes provided in the connection pipe at the root and tip of the connection pipe.
  • stirring fins may be installed in the water in the tank so as to further increase the chance of contact between the exhaust gas and water.
  • the inside of the tank is divided into a plurality of sections, and the exhaust gas is sequentially passed through each section, so that the processing described above is repeated a plurality of times, whereby the exhaust gas cleaning ability can be improved.
  • combustion device to which the present invention can be applied is not limited to a diesel engine, but can be used for various combustion devices such as other internal combustion engines, external combustion engines, incinerators, incinerators, and the like. Availability on the monkey t industry
  • an exhaust gas purifying apparatus which is cheap and has a simple configuration, can reliably and efficiently reduce the discharge amount of various harmful substances, and is easy to handle. It becomes possible. Therefore, the exhaust gas can be easily and reliably purified, so that the exhaust gas pollution can be promptly improved and the environment can be protected.

Abstract

An exhaust emission control system comprising a tank (1) sealing water (9) therein, a coupling pipe (2) for feeding exhaust gas from a combustor into the tank (1), a metal mesh section (6) disposed into the water in the tank (1) and making small the bubbles in exhaust gas, and an exhaust tube (3) for interconnecting the tank (1) and the outside. The metal mesh section (6) comprises a first rough metal mesh (6a) and a second fine metal mesh (6b) oscillated by exhaust gas. Mixture of limestone (4) for neutralizing exhaust gas and active carbon (5) for adsorbing particulate substance are spread over the inner bottom part of the tank (1). A partition plate (7) partitions the inside of the tank (1) into a plurality of sections. The exhaust tube (3) is coupled with an active carbon filter (11).

Description

明 細 書 排ガス浄化装置 技術分野  Description Exhaust gas purification equipment Technical field
本発明は、 燃焼装置の排気ガスを浄化することにより、 大気中に有害物質が排 出されるのを防止して、 排ガス汚染を改善する排ガス浄化装置に係る。 背景技術  The present invention relates to an exhaust gas purifying apparatus that purifies exhaust gas from a combustion apparatus, thereby preventing harmful substances from being discharged into the atmosphere, and improving exhaust gas pollution. Background art
一般に、 ガソリンや軽油等の炭化水素を利用して動力を発生する内燃機関は、 完全燃焼が困難であるため、 その稼動によって種々の未燃成分や高温燃焼成分な どが含まれたガスが大気中に排出されることとなる。 特に、 ディーゼルエンジン は、呼吸器疾患の原因とされる浮遊粒子状物質（SPM: Su s p ende d P a r t i c u l a t e Ma t t e r )、 窒素酸化物 （NOx)、 硫黄酸化物 （S Ox) などの排出量が多く、 さらに、 酸化や NO Xとの反応でアルデヒド、 ナイ トレート強酸等の有害物質が発生する炭化水素 （HC) なども排出されるため、 排ガス汚染に深刻な影響を与えることとなる。  In general, since internal combustion engines that generate power using hydrocarbons such as gasoline and light oil are difficult to completely burn, gas containing various unburned components and high-temperature combustion components is generated by the operation. Will be discharged inside. In particular, diesel engines emit low amounts of suspended particulate matter (SPM), nitrogen oxides (NOx), and sulfur oxides (SOx), which can cause respiratory illness. In addition, hydrocarbons (HC), which generate harmful substances such as aldehydes and nitrate strong acids due to oxidation and reaction with NOx, are also emitted, which has a serious effect on exhaust gas pollution.
しかしながら、 自動車の中でも、特にディーゼル車は、 ガソリン車と比較して、 燃料 （軽油） が安価でエネルギー効率が良く且つその耐用年数が極めて長いとい う利点がある。 よって、 ディーゼルエンジンは、 上記のような排ガス汚染への影 響にも関わらず、 トラックやバスなどの大型車用のエンジンとして数多く採用さ れており、 産業分野の多方面に亘つてその利用台数は年々増加しているのが現状 である。  However, among automobiles, diesel cars in particular have the advantage that fuel (light oil) is inexpensive, energy efficient, and their service life is extremely long compared to gasoline cars. Therefore, despite their impact on exhaust gas pollution, diesel engines are widely used as engines for large vehicles such as trucks and buses, and the number of diesel engines used in various fields in the industrial field has been increasing. Is increasing year by year.
このような状況下で、 排ガス汚染が社会問題にまで至ったことから、 各国で排 出ガス規制が行われ、 特にその主要な発生源として指摘されたディ一ゼル車によ る排ガス対策として、 業務用ディ一ゼル車のガソリン車への代替ゃ排ガス浄化装 置の装着などが推進されていた。  Under such circumstances, exhaust gas pollution has become a social problem, and exhaust gas regulations have been implemented in various countries.Especially as a measure to reduce exhaust gas by diesel vehicles, which has been pointed out as a major source, Replacement of commercial diesel vehicles with gasoline vehicles and installation of exhaust gas purification equipment were being promoted.
ここで、 業務用ディーゼル車のガソリン車への代替とは、 ディーゼル車数自体 を減少させることによって、 有害物質の排出量を抜本的に削減しょうとするもの である。 しかし、 コストパフォーマンスなどの要請から、 ガソリン車への代替を 普及させることは非常に困難であり、 現実的といえるものではない。 Here, replacing commercial diesel vehicles with gasoline vehicles means drastically reducing harmful substance emissions by reducing the number of diesel vehicles. It is. However, it is very difficult to spread the alternative to gasoline vehicles due to cost performance and other demands, and it is not realistic.
一方、 排ガス浄化装置とは、 一般に、 ディーゼル車の排ガス中の浮遊粒子状物 質を除去する装置を指す。 例えば、 マフラーの代わりに取り付けて、 黒煙を最燃 焼し、 浮遊粒子状物質の排出量を約 8割程度削減することによって、 結果的にデ イーゼル車の低公害ィ匕を図ろうとするものである。このような排ガス浄化装置は、 触媒を利用した構造を採用すると、 約 2 0万円程度で生産することができる。 しかし、 このような排ガス浄ィ匕装置の構造によると、 ディーゼル車の燃料の軽 油中に含まれる硫黄によって、 排ガス浄化装置 （D P F) 自体の金属部分が腐食 してしまうため、 実用化に際しては非常に高価格のセラミック製のものとせざる を得ない。 なお、 硫黄による腐食を防止するために軽油中の硫黄成分を削減する ことも考えられるが、 このような燃料成分の改良には多額な設備投資が必要とな る。  On the other hand, an exhaust gas purification device generally refers to a device that removes suspended particulate matter in exhaust gas from diesel vehicles. For example, installing a muffler instead to burn black smoke to the maximum and reduce the amount of suspended particulate matter by about 80%, resulting in low pollution of diesel vehicles It is. Such an exhaust gas purification device can be manufactured for about 200,000 yen if a structure using a catalyst is adopted. However, according to the structure of such an exhaust gas purifying device, the sulfur contained in the diesel diesel fuel corrodes the metal part of the exhaust gas purifying device (DPF) itself. It must be made of very expensive ceramic. Although it is conceivable to reduce the sulfur component in light oil in order to prevent corrosion due to sulfur, such a fuel component improvement requires a large capital investment.
これに対処するため、排ガスを水や特別な水溶液等の液体に通すことによって、 有害物質を分離、 除去する装置が提案されている。 例えば、 特開平 7 — 1 8 9 6 5 8号公報、 特開平 6— 1 2 3 2 1 7号公報、 特開平 7— 2 2 4 6 3 8号公報に は、 排ガスを液体中で気泡化させることによって、 液体に対する排ガスの接触面 積を大きくして、 排ガス中の S P M、 N O X等を除去する排ガス浄ィ匕装置が開示 されている。  To cope with this, a device has been proposed to separate and remove harmful substances by passing exhaust gas through liquids such as water and special aqueous solutions. For example, Japanese Patent Application Laid-Open Nos. 7-189658 / 1994, 6-12 / 32/17 and 7-224648 / 1994 disclose that exhaust gas is bubbled in a liquid. An exhaust gas purifying apparatus that removes SPM, NOX, and the like in the exhaust gas by increasing the contact area of the exhaust gas with the liquid by performing the operation is disclosed.
しかしながら、 特開平 7— 1 8 9 6 5 8号公報ゃ特開平 6— 1 2 3 2 1 7号公 報に開示された排ガス浄化装置は、 有害物質のうち S P Mを含む粉塵等の分離回 収は可能であっても、 他の有害物質である N〇x、 S O x、 H C等に対する除去 能力は十分ではない。 一方、 特開平 7— 2 2 4 6 3 8号公報に開示された排ガス 浄化装置は、 N O x、 S O xの除去は可能であるが、 特別な水溶液を用いる必要 があるので、 取扱いが面倒であり、 維持管理にコストがかかる。 さらに、 両者を 単純に組み合わせたとしても、 特別な水溶液を用いる限り、 取扱いの困難性は残 る。  However, the exhaust gas purifying apparatus disclosed in Japanese Patent Application Laid-Open No. 7-189658 / 1994 and Japanese Patent Application Laid-Open No. 6-123217 separates and collects harmful substances such as dust containing SPM. Is possible, but its ability to remove other harmful substances such as N〇x, SOx, and HC is not sufficient. On the other hand, the exhaust gas purifying apparatus disclosed in Japanese Patent Application Laid-Open No. Hei 7-224648 can remove NOx and SOx, but requires the use of a special aqueous solution, and is therefore troublesome to handle. Yes, maintenance costs are high. Furthermore, even if the two are simply combined, handling remains difficult as long as a special aqueous solution is used.
このように、 ディーゼル車に対する実用的で有効な排ガス対策が見つからない にも関わらず、 特に大都市圏での交通量は増大する一方であるため、 排ガス汚染 はますます深刻な状況に至っていた。 In spite of the fact that no practical and effective emission control measures for diesel vehicles have been found, the traffic volume, especially in metropolitan areas, is increasing. Had come to an increasingly serious situation.
本発明は、 以上のような従来技術の問題点を解決するために提案されたもので あり、 安価且つ簡易な構成で、 種々の有害物質の排出量を確実且つ効率的に削減 することができ、 取扱いが容易な排ガス浄化装置を提供することにより、 早急に 排ガス汚染を改善し、 環境保護に資することを目的とする。 発明の開示  The present invention has been proposed in order to solve the above-mentioned problems of the prior art, and it is possible to reliably and efficiently reduce the emission of various harmful substances with an inexpensive and simple configuration. The aim is to improve exhaust gas pollution promptly and contribute to environmental protection by providing easy-to-handle exhaust gas purification equipment. Disclosure of the invention
本発明の排ガス浄化装置は、 上記の目的を達成するために、 内部に水を封入し たタンクと、燃焼装置からの排ガスを、前記タンク内の水中に送り込む連結管と、 前記タンク内の水中に配置され、 前記排ガスを中和する石灰石と、 前記タンク内 の水中に配置され、 前記排ガスの気泡を小さくする網部と、 前記タンクと外部を 連通する排気筒とを備えたことを特徴とする。  In order to achieve the above object, an exhaust gas purifying apparatus of the present invention includes a tank in which water is sealed, a connecting pipe for sending exhaust gas from a combustion device into the water in the tank, and a water pipe in the tank. A limestone that is disposed in the tank and neutralizes the exhaust gas, a net portion that is disposed in water in the tank and reduces bubbles of the exhaust gas, and an exhaust pipe that communicates the tank with the outside. I do.
以上のような本発明によれば、 燃焼装置からの排ガスが、 連結管から水中に送 りこまれ、 強酸性の NO Xや S O X等の有害物質が、 アル力リ性の石灰石に接触 して中和、 除去される。 さらに、 排ガスが網部を通過する際に、 気泡が細かくな り水との接触面積が大きくなるので、 排ガス中の S P M等の粉塵が効率良く水中 に捕捉される。 浄化された排ガスは、 排気筒を介して外部へ排出される。  According to the present invention as described above, the exhaust gas from the combustion device is sent into the water from the connecting pipe, and harmful substances such as strongly acidic NO X and SOX come in contact with the alkaline limestone and become harmful. Sum, removed. Furthermore, when the exhaust gas passes through the mesh, the bubbles become finer and the contact area with water increases, so that dust such as SPM in the exhaust gas is efficiently captured in the water. The purified exhaust gas is discharged to the outside via the exhaust stack.
また、 網部を、 目の粗い第 1の網と、 排ガスにより振動する目の細かい第 2の 網とを有する構成とすれば、 目の細かい第 2の金網の振動によって、 水と排ガス との接触が促進され、 粒子状物質をより効率良く捕捉することができる。  In addition, if the net has a first mesh having a coarse mesh and a second mesh having a fine mesh vibrating due to exhaust gas, the vibration of the second metal mesh having a fine mesh allows water and exhaust gas to be separated. Contact is promoted and particulate matter can be trapped more efficiently.
また、 タンクの内底部に活性炭を配設することによって、 水中へ捕捉された S P M等の粉塵を吸着させることができる。  In addition, by arranging activated carbon on the inner bottom of the tank, dust such as SPM captured in water can be adsorbed.
また、 排気筒に活性炭フィルターを接続することによって、 排気に残留する有 害物質を捕捉することができる。  By connecting an activated carbon filter to the exhaust stack, harmful substances remaining in the exhaust can be captured.
また、タンク内を複数の区画に分ける隔壁板を設けることによって、車の発進、 停止の際に水の浪打ちが防止される。 図面の簡単な説明  In addition, by providing a partition plate that divides the inside of the tank into a plurality of compartments, it is possible to prevent water from being swamped when the vehicle starts and stops. BRIEF DESCRIPTION OF THE FIGURES
第 1図は、 本発明の排ガス浄化装置の一つの実施の形態を示す側面断面図であ る。 FIG. 1 is a side sectional view showing one embodiment of an exhaust gas purifying apparatus of the present invention. You.
第 2図は、 第 1図の実施の形態の正面断面図である。  FIG. 2 is a front sectional view of the embodiment of FIG.
第 3図は、 第 1図の実施の形態の背面断面図である。  FIG. 3 is a rear sectional view of the embodiment of FIG.
第 4図は、 第 1図の実施の形態の網部を示す正面断面図である。  FIG. 4 is a front sectional view showing a net portion of the embodiment of FIG.
第 5図は、 第 1図の実施の形態の隔壁板を示す正面図である。  FIG. 5 is a front view showing the partition plate of the embodiment shown in FIG.
第 6図は、 第 1の実施の形態の活性炭フィルターを示す斜視図である。  FIG. 6 is a perspective view showing the activated carbon filter of the first embodiment.
第 7図は、 第 6図の活性炭フィルタ一の透視側面図である。  FIG. 7 is a transparent side view of the activated carbon filter of FIG.
第 8図は、 第 6図の活性炭フィルターの側面断面図である。 発明を実施するための最良の形態  FIG. 8 is a side sectional view of the activated carbon filter of FIG. BEST MODE FOR CARRYING OUT THE INVENTION
以下、 本発明の実施形態を、 第 1図〜第&図に基づいて具体的に説明する。 ( 1 ) 実施の形態の構成  Hereinafter, embodiments of the present invention will be specifically described with reference to FIGS. 1 to &. (1) Configuration of the embodiment
本実施の形態の排ガス浄化装置は、 第 1図〜第 3図に示すような全体的構成を 有するものであり、 タンク 1、 連結管 2及び排気筒 3を備えている。 タンク 1の 内部には、 石灰石 4、 活性炭 5、 金網部 6、 隔壁板 7が設けられている。 石灰石 4と活性炭 5は、 タンク 1の内底部に、 混在するように敷き詰められている。 石 灰石 4としては、 沖縛本島中南部から産出される琉球石灰岩を用いることが望ま しい。 また、 後述する反応を促進するために、 焼成により生石灰 （C a O) 成分 を多くしたものを用いるとよい。  The exhaust gas purifying apparatus of the present embodiment has an overall configuration as shown in FIGS. 1 to 3, and includes a tank 1, a connecting pipe 2, and an exhaust pipe 3. Inside the tank 1, limestone 4, activated carbon 5, wire mesh 6, and partition plate 7 are provided. Limestone 4 and activated carbon 5 are spread on the inner bottom of tank 1 so as to be mixed. As limestone 4, it is desirable to use Ryukyu limestone produced from the central and southern part of Okibashi main island. Further, in order to promote the reaction described later, it is preferable to use one obtained by increasing the calcined lime (CaO) component by firing.
金網部 6は、 タンク 1内の高さ方向の中間部に配設されており、 第 1の金網 6 a及び第 2の金網 6 bによって構成されている。 第 1の金網 6 aは目が粗く、 所 定の間隔をおいて上下に 2っ配設されている。 第 2の金網 6 bは目が細かく、 第 5図に示すように、 2つの第 1の金網 6 aの間に折り畳むように配設されている。 さらに、 隔壁板 7は、 第 5図に示すように、 上部に空気が流通するための多数の 穴が形成された垂直方向の板であり、 所定の間隔で複数配設されている。  The wire mesh portion 6 is disposed at an intermediate portion in the height direction in the tank 1, and is constituted by a first wire mesh 6a and a second wire mesh 6b. The first wire mesh 6a is coarse, and is provided two above and below at predetermined intervals. The second wire mesh 6b is fine and is arranged so as to be folded between the two first wire meshes 6a as shown in FIG. Further, as shown in FIG. 5, the partition plate 7 is a vertical plate having a large number of holes formed therein for allowing air to flow therethrough, and a plurality of the partition plates 7 are provided at predetermined intervals.
このようなタンク 1内には、 大気が満たされた空間部 8が設けられるように、' 所定量の水 9が満たされている。 また、 タンク 1には、 水を供給するための吸水 口 1 a、 水を排出するための排水口 1 bが設けられるとともに、 内部の水位を外 部から確認できるように、 液面計 1 0が配設されている。 さらに、 タンク 1の下 部には連結管 2が挿入され、 上部に排気筒 3が設けられている。 The tank 1 is filled with a predetermined amount of water 9 so that a space 8 filled with the atmosphere is provided. The tank 1 is provided with a water inlet 1a for supplying water and a drain 1b for discharging water, and a level gauge 10 so that the internal water level can be checked from outside. Are arranged. In addition, under tank 1 A connecting pipe 2 is inserted into the section, and an exhaust pipe 3 is provided at the upper part.
連結管 2は、 第 1図に示すように、 その一端がディーゼルエンジン等の内燃機 関 Aの排気口に接続されており、 他端側がタンク 1内の底部近傍に挿入されてい る。 タンク 1内における連結管 2には、 排ガスが石灰石 4及び活性炭 5側に向か うように、 多数の排気穴 2 aが形成されている。 一方、 排気筒 3には、 活性炭フ ィルター 1 1が接続されている。 この活性炭フィルタ一 1 1は、 第 6図及び第 7 図に示すように、 円柱状の容器 1 2内に活性炭 1 3を詰めたものである。 この容 器 1 2の軸方向には、導入管 1 4と排出管 1 5が設けられている。導入管 1 4は、 第 8図に示すように、 その一端が排気筒 3に連通され、 他端が活性炭 1 3内に揷 入されている。 そして、 導入管 1 4の他端近傍の周囲には、 排気筒 3からの排ガ スを活性炭 1 3へ供給する複数の穴 1 4 aが形成されている。 容器 1 2と活性炭 1 3との間には、 活性炭 1 3を通過した排ガスが通過する間隙部 1 2 aが設けら れている。 さらに、 容器 1 2内における排出管 1 5側には、 間隙部 1 2 aに連通 する複数の穴 1 2 bが形成された空間部 1 2 cが形成され、 この空間部 1 2 cが 排出管 1 5に連通している。  As shown in FIG. 1, the connecting pipe 2 has one end connected to an exhaust port of an internal combustion engine A such as a diesel engine, and the other end inserted near the bottom of the tank 1. A large number of exhaust holes 2 a are formed in the connecting pipe 2 in the tank 1 so that the exhaust gas is directed toward the limestone 4 and the activated carbon 5. On the other hand, the exhaust stack 3 is connected with an activated carbon filter 11. As shown in FIG. 6 and FIG. 7, the activated carbon filter 11 is obtained by packing activated carbon 13 in a cylindrical container 12. An introduction pipe 14 and a discharge pipe 15 are provided in the axial direction of the container 12. As shown in FIG. 8, the introduction pipe 14 has one end connected to the exhaust pipe 3 and the other end inserted into the activated carbon 13. A plurality of holes 14 a for supplying the exhaust gas from the exhaust stack 3 to the activated carbon 13 are formed around the vicinity of the other end of the introduction pipe 14. Between the container 12 and the activated carbon 13, there is provided a gap 12 a through which the exhaust gas passing through the activated carbon 13 passes. Further, a space 12 c having a plurality of holes 12 b communicating with the gap 12 a is formed on the discharge pipe 15 side in the container 12, and the space 12 c is discharged. It communicates with tube 15.
( 2 ) 実施の形態の作用  (2) Operation of the embodiment
本発明の排ガス浄化装置は、 一例として前記のような構成を有し、 内燃機関 A の排気口から排出された排ガスを連結管 2によってタンク 1内へ導入し、 これを 排気筒 3から大気中へ排出するものである。 以下にその詳細を説明する。  The exhaust gas purifying apparatus of the present invention has the above-described configuration as an example. To be discharged to The details will be described below.
すなわち、 内燃機関 Aの排気口から連結管 2へ排出された排ガスは、 タンク 1 内の底部に配置された連結管 2の多数の排気穴 2 a力、ら、 タンク 1内の水 9の中 へ排出され、 石灰石 4に対して吹き付けられる。 すると、 アルカリ性の石灰石 4 によって、 強酸性の排気ガスが反応して中和される。 このとき、 石灰石 4の中の 酸化カルシウム ( C a O) と水とが反応して水酸化力ルシゥム (C a (OH) 2) ができ、 N O x、 S O x等の有害物質は、 この C a (OH) 2と反応することに よって、 排ガス中から除去される。 That is, the exhaust gas discharged from the exhaust port of the internal combustion engine A to the connecting pipe 2 is discharged from the many exhaust holes 2a of the connecting pipe 2 arranged at the bottom of the tank 1 and the water 9 in the tank 1. And is sprayed against limestone 4. Then, the strongly acidic exhaust gas reacts and is neutralized by the alkaline limestone 4. At this time, calcium oxide (C a O) in the limestone 4 reacts with water to form a hydroxide hydroxide (C a (OH) 2 ), and harmful substances such as NO x and SO x a Removed from exhaust gas by reacting with (OH) 2 .
例えば、 二酸化窒素 （N 02) が水酸化カルシウム （C a (OH) 2) と反応し て、 中性の硝酸カルシウム （C a (N 03) 2) となる式を、 以下に示す。 C a (OH) 2+ 2N02+ 1/202→C a (N〇3) 2 + H20 …式 1 また、 例えば、 二酸化硫黄 （S02) が水酸化カルシウム （Ca (OH) 2) と 反応して、 亜硫酸カルシウム （CaSO となる式を、 以下に示す。 For example, reacts with nitrogen dioxide (N 0 2) calcium hydroxide (C a (OH) 2) , an expression that the calcium nitrate neutral (C a (N 0 3) 2), shown below. C a (OH) 2 + 2N0 2 + 1/20 2 → C a ( N_〇 3) 2 + H 2 0 ... Formula 1 Further, for example, sulfur dioxide (S0 2) is calcium hydroxide (Ca (OH) 2 ) To react with calcium sulfite (CaSO) is shown below.
Ca (OH) 2+S02→C a S03+H20 …式 2 そして、 排ガスがタンク 1内を上昇すると、 目の粗い第 1の金網 6 aの網目を 通ることによつて気泡が小さくなり、水 9と排ガスの接触面積が大きくなるので、 水 9によって SPM等の粉塵が効率良く捕捉される。 さらに、 排ガスが、 折り曲 げた目の細かい第 2の金網 6 bを通過する際には、 第 2の金網 6 bが振動するの で、 水 9と排ガスとの接触がより一層促進され、 SPM等の粉塵の捕捉効果が増 す。 Ca (OH) 2 + S0 2 → C a S0 3 + H 2 0… Equation 2 Then, when the exhaust gas rises in the tank 1, bubbles are generated by passing through the mesh of the coarse first wire mesh 6a. Since the water becomes smaller and the contact area between the water 9 and the exhaust gas increases, dust such as SPM is efficiently captured by the water 9. Further, when the exhaust gas passes through the bent second wire mesh 6b, the second wire mesh 6b vibrates, so that the contact between the water 9 and the exhaust gas is further promoted, and the SPM The effect of trapping dust and the like increases.
次に、 排ガスは、 水 9の中から空間部 8へと移動し、 排気筒 3から活性炭フィ ルター 11内を通過する際に、 残留する有害物質が捕捉されて、 大気中へ排出さ れる。 一方、 水 9に捕捉された SPMなどの粉塵は、 排ガスの気泡で水 9が攪拌 されることによって、 タンク 1の底部に配置された活性炭 5の多数の細孔に吸着 される。  Next, the exhaust gas moves from the water 9 to the space portion 8, and when passing through the activated carbon filter 11 from the exhaust stack 3, the remaining harmful substances are captured and discharged to the atmosphere. On the other hand, dust such as SPM trapped in the water 9 is adsorbed on a large number of pores of the activated carbon 5 arranged at the bottom of the tank 1 by stirring the water 9 with bubbles of exhaust gas.
そして、 このように有害物質が溶け込んだ水 9は、 排水口 l bから排出され、 図示しない処理装置によって処理されるとともに、 新たに新鮮な水が吸水口 1 a からタンク 1内へ補給される。 また、 SPMなどの粉塵や反応により生成された 物質等が付着、 吸着した石灰石 4や活性炭 5は、 その汚れ具合に応じて適度に交 換される。  Then, the water 9 in which the harmful substances are dissolved is discharged from the drain port lb, is treated by a treatment device (not shown), and fresh water is newly supplied into the tank 1 from the water inlet port 1a. In addition, limestone 4 and activated carbon 5 to which dust such as SPM and substances generated by the reaction are attached and adsorbed are appropriately replaced according to the degree of contamination.
(3) 実施の形態の効果  (3) Effects of the embodiment
以上のような本実施の形態によれば、 ディーゼルエンジン等の内燃機関から排 出される排ガスに含まれる有害物質は、 大気中に放出される前に、 タンク 1内の 水 9、 石灰石 4、 活性炭 5によってその大部分が除去される。 特に、 金網部 6に おける目の粗い第 1の金網 6 aと、振動する目の細かい第 2の金網 6 bによって、 気泡の生成と水 9と排ガスの接触が促進されるので、 S PM等の捕捉効果が高い。 また、 本実施の形態で必要な構成物質は、 安全無害で安価又は非常に入手し易 い空気、 水、 石灰石、 活性炭、 金網等であり、 その構造上必要となるタンク 1及 び配管などの構成部材は、 いずれも何ら危険性を伴わない取扱いの容易な部材で あるので、 実用化も容易である。 特に、 琉球石灰岩を用いた場合は、 数十万年前 位に堆積されてできた石材であるため、 巣穴が多く空いている。 従って、 上記の ような反応による有害物質除去効果が高い。 According to the present embodiment as described above, the harmful substances contained in the exhaust gas discharged from the internal combustion engine such as a diesel engine are discharged into the water 1 in the tank 1, the limestone 4, the activated carbon before being released into the atmosphere. 5 removes most of it. In particular, the formation of bubbles and the contact between the water 9 and the exhaust gas are promoted by the coarse mesh first wire mesh 6 a and the fine mesh second wire mesh 6 b in the wire mesh portion 6. High trapping effect. The constituent materials required in the present embodiment are air, water, limestone, activated carbon, wire mesh, etc., which are safe and harmless and inexpensive or very easily available. All of the components are easy to handle without any danger, and are therefore easy to put into practical use. In particular, when Ryukyu limestone is used, it has many burrows because it is a stone that was deposited several hundred thousand years ago. Therefore, the harmful substance removing effect by the above reaction is high.
また、 水中に捕捉された粒子状物質（S P M) は、 活性炭 5に吸着されるので、 水の清浄度を保ちやすい。 また、 活性炭フィルター 1 1によって、 排ガス中の残 留有害物質も除去されるので、 外部への放出ガスは非常に高い清浄度を得ること ができる。 さらに、 タンク 1内は、複数の隔壁板 7によって仕切られているので、 車の発進、 停止の際にも、 水の浪打ちが防止される。  Further, the particulate matter (SPM) captured in the water is adsorbed by the activated carbon 5, so that the cleanliness of the water can be easily maintained. In addition, the activated carbon filter 11 also removes harmful substances remaining in the exhaust gas, so that the gas released to the outside can have a very high degree of cleanliness. Further, since the inside of the tank 1 is partitioned by a plurality of partition plates 7, even when the vehicle starts and stops, the water is prevented from being washed away.
( 4 ) 他の実施の形態  (4) Other embodiments
なお、 本発明は、 上述した実施の形態に限定されるものではなく、 各部材の材 質、 形状、 大きさ、 数量等は適宜変更可能である。 例えば、 網部の素材としては、 金属ばかりでなく、 セラミックなどの他の材料を使用してもよい。 網部の網目の 大きさも、 特定のものには限定されない。 また、 活性炭や活性炭フィルタ一の代 わりに不織布やセラミックなどの他の材料を使用したり、 他の材料と活性炭と併 用することも可能である。 石灰石も、 琉球石灰岩に限定するものではない。  Note that the present invention is not limited to the above-described embodiment, and the material, shape, size, quantity, and the like of each member can be appropriately changed. For example, as the material of the net portion, not only metal but also other materials such as ceramic may be used. The size of the mesh of the mesh is not limited to a specific size. In addition, other materials such as nonwoven fabric and ceramic can be used instead of activated carbon or activated carbon filter, or other materials can be used together with activated carbon. Limestone is not limited to Ryukyu limestone.
また、 石灰石若しくは活性炭をタンク底部以外の箇所に配置して、 石灰石ゃ活 性炭と排ガスおよび攪拌された水との接触をより効果的に行なうことも可能であ る。 例えば、 網部の上に石灰石を配置してもよい。 タンク内において、 連結管を 複数に分岐させたり、 連結管に設ける排気穴の寸法や数を連結管の根本と先端で 異ならせることにより、タンクの全域で気泡が発生するようにすることもできる。 また、 排気ガスと水との接触の機会をより増加させるようにタンク内の水中に 攪拌用フィンを設置してもよい。 また、 タンク内を複数の区画に分けて、 各区画 に排ガスを順次通過させることによって、 上記のような処理を複数回繰り返す構 造とすることによって、 排ガスの清浄能力を向上させることもできる。  It is also possible to arrange limestone or activated carbon at a place other than the bottom of the tank to more effectively contact the limestone / activated carbon with the exhaust gas and the stirred water. For example, limestone may be arranged on the net. In the tank, air bubbles can be generated in the entire area of the tank by branching the connection pipe into multiple sections or by changing the size and number of exhaust holes provided in the connection pipe at the root and tip of the connection pipe. . In addition, stirring fins may be installed in the water in the tank so as to further increase the chance of contact between the exhaust gas and water. Further, the inside of the tank is divided into a plurality of sections, and the exhaust gas is sequentially passed through each section, so that the processing described above is repeated a plurality of times, whereby the exhaust gas cleaning ability can be improved.
さらに、本発明が適用できる燃焼装置は、ディーゼルエンジンには限定されず、 他の内燃機関、 外燃機関、 焼却器、 焼却炉等、 種々の燃焼装置に用いることがで さる t 産業上の利用可能性 Furthermore, the combustion device to which the present invention can be applied is not limited to a diesel engine, but can be used for various combustion devices such as other internal combustion engines, external combustion engines, incinerators, incinerators, and the like. Availability on the monkey t industry
以上説明したように、 本発明によれば、 安価で且つ簡易な構成で、 種々の有害 物質の排出量を確実且つ効率的に削減することができ、 取扱いが容易な排ガス浄 化装置を提供することが可能となる。 従って、 簡単且つ確実に排ガスの浄化が実 現できるため、 早急に排ガス汚染を改善し、 環境保護に資することができる。  As described above, according to the present invention, there is provided an exhaust gas purifying apparatus which is cheap and has a simple configuration, can reliably and efficiently reduce the discharge amount of various harmful substances, and is easy to handle. It becomes possible. Therefore, the exhaust gas can be easily and reliably purified, so that the exhaust gas pollution can be promptly improved and the environment can be protected.

Claims

請 求 の 範 囲 The scope of the claims
1 . 内部に水を封入したタンクと、  1. A tank filled with water inside,
燃焼装置からの排ガスを前記タンク内に送り込む連結管と、 A connection pipe for sending exhaust gas from the combustion device into the tank,
前記タンク内の水中に配置され、 前記排ガスを中和する石灰石と、 Limestone that is arranged in water in the tank and neutralizes the exhaust gas;
前記タンク内の水中に配置され、 前記排ガスの気泡を小さくする網部と、 前記夕ンクと外部を連通する排気筒と、 A mesh portion arranged in water in the tank to reduce bubbles of the exhaust gas, and an exhaust pipe communicating the evening and the outside,
を備えたことを特徴とする排ガス浄化装置。 An exhaust gas purifying device comprising:
2 . 前記網部は、 目の粗い第 1の網と、 排ガスにより振動する目の細かい 第 2の網とを有することを特徴とする請求項 1に記載の排ガス浄化装置。 2. The exhaust gas purifying apparatus according to claim 1, wherein the net has a first net having a coarse mesh and a second net having a fine mesh vibrated by exhaust gas.
3 . 前記夕ンクの内底部に活性炭が配設されていることを特徴とする請求項 1 又は 2に記載の排ガス浄ィヒ装置。 3. The exhaust gas purifying apparatus according to claim 1, wherein an activated carbon is disposed on an inner bottom portion of the sunset.
4. 前記排気筒には、 活性炭フィル夕が接続されていることを特徴とする請求 項 1乃至 3のいずれか 1に記載の排ガス浄化装置。  4. The exhaust gas purifying apparatus according to any one of claims 1 to 3, wherein an activated carbon filter is connected to the exhaust stack.
5 . 前記タンク内を複数の区画に分ける隔壁板が設けられていることを特徴と する請求項 1乃至 4のいずれか 1に記載の排ガス浄化装置。  5. The exhaust gas purifying apparatus according to any one of claims 1 to 4, wherein a partition plate for dividing the inside of the tank into a plurality of sections is provided.
PCT/JP2002/001022 2002-02-07 2002-02-07 Exhaust emission control system WO2003067045A1 (en)

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CN103557052A (en) * 2013-11-06 2014-02-05 苏州佑瑞检测技术有限公司 Sustainable type automobile tail gas purifying device
CN104989497A (en) * 2015-06-08 2015-10-21 含山县全兴内燃机配件有限公司 Efficient filtration neutralization buffering system
CN105032146A (en) * 2011-02-01 2015-11-11 沙文环境与基础设施有限公司 Emission control system
CN105363300A (en) * 2015-11-26 2016-03-02 马一先 Smoke dust filter
CN107930322A (en) * 2017-11-29 2018-04-20 宁夏三和日升化工有限公司 A kind of furnace flue gas desulfurization dust-removal system and method
CN113521937A (en) * 2020-04-14 2021-10-22 骆用玲 Atmosphere pollution prevention and control equipment

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105032146A (en) * 2011-02-01 2015-11-11 沙文环境与基础设施有限公司 Emission control system
CN105032146B (en) * 2011-02-01 2017-10-13 沙文环境与基础设施有限公司 Emission control systems
CN103557052A (en) * 2013-11-06 2014-02-05 苏州佑瑞检测技术有限公司 Sustainable type automobile tail gas purifying device
CN104989497A (en) * 2015-06-08 2015-10-21 含山县全兴内燃机配件有限公司 Efficient filtration neutralization buffering system
CN105363300A (en) * 2015-11-26 2016-03-02 马一先 Smoke dust filter
CN107930322A (en) * 2017-11-29 2018-04-20 宁夏三和日升化工有限公司 A kind of furnace flue gas desulfurization dust-removal system and method
CN113521937A (en) * 2020-04-14 2021-10-22 骆用玲 Atmosphere pollution prevention and control equipment

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