WO2003035809A1 - Composition huileuse lubrifiante - Google Patents

Composition huileuse lubrifiante Download PDF

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Publication number
WO2003035809A1
WO2003035809A1 PCT/JP2002/011043 JP0211043W WO03035809A1 WO 2003035809 A1 WO2003035809 A1 WO 2003035809A1 JP 0211043 W JP0211043 W JP 0211043W WO 03035809 A1 WO03035809 A1 WO 03035809A1
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WO
WIPO (PCT)
Prior art keywords
oil
water
fat
vegetable
fatty acid
Prior art date
Application number
PCT/JP2002/011043
Other languages
English (en)
Japanese (ja)
Inventor
Masaaki Takayanagi
Tadashiro Hirose
Original Assignee
The Nisshin Oillio, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Nisshin Oillio, Ltd. filed Critical The Nisshin Oillio, Ltd.
Priority to JP2003538311A priority Critical patent/JP4205585B2/ja
Publication of WO2003035809A1 publication Critical patent/WO2003035809A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00—Moulds; Cores; Mandrels
    • B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
    • B28B7/384—Treating agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/091—Water solubility
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/24—Emulsion properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents

Definitions

  • the present invention relates to a water-soluble lubricating oil composition, and more particularly, to a metal working oil such as a cutting oil and a plastic working oil, an antifouling mixture adhesion inhibitor, and a concrete.
  • the present invention relates to a water-soluble lubricating oil composition suitable as a release oil such as a release agent.
  • Examples of lubricating oils used as metal working oils such as cutting oils and plastic working oils used in the processing of metals and ceramics are water-insoluble types using mineral oils or synthetic oils as base oils. However, emulsion-type ones containing these substances are used. In recent years, in the processing of metals and ceramics, water-soluble metal processing oils and the like are frequently used in consideration of the danger of ignition due to high processing speed and high feed rate. Since such water-soluble metalworking oils are usually used after being diluted in water, emulsification stability at the time of dilution is important. Poor emulsification stability causes variations in processing accuracy and contamination of the machine periphery. Therefore, a metal working oil (lubricating oil) having excellent emulsion stability is desired.
  • mineral oils such as heavy oil, light oil, waste engine oil, and water have been widely used for the purpose of preventing asphalt mixture from adhering to rollers and the like.
  • the drainage type asphalt mixture whose use has been rapidly increasing in recent years, has a problem that the adhesion is strong due to its high viscosity and the adhesion preventing effect is low with mineral oils.
  • mineral oils were sown on the ground and underground as a result of asphalt construction, which was a major environmental problem.
  • mineral oils when mineral oils are used, they have high solubility in the asphalt mixture, and may damage the painted surface such as discoloration and reduced viscosity.
  • Japanese Patent No. 2736660 discloses an asphaltic adhesion inhibitor containing a nonionic surfactant of a sorbitan fatty acid ester or a polyoxyethylene sorbitan fatty acid ester.
  • Japanese Patent Application Laid-Open No. H10-112018 discloses adhesion of a heated asphalt mixture containing sodium alkyl sulfate, sodium alkyl ether sulfate, water and coconut oil. Inhibitors are disclosed. According to the asphalt adhesion preventing agent disclosed in the above publication, the asphalt adhesion preventing effect is exhibited to some extent, but the asphalt adhesion preventing effect is not sufficient.
  • a concrete release agent is used for the purpose of facilitating removal of the formwork without sticking the formwork and concrete and protecting the formwork.
  • the concrete release agent is used by being applied to the inner surface of the mold in advance before the concrete is driven.
  • Conventionally used concrete release agents are based on mineral oils such as light oil and machine oil, and require various additives such as waxes, metal lithographs, and fire retardants. It was added accordingly. They are also classified into oil-based types, emulsion types, and soluble types, depending on how they are used.
  • Japanese Patent Application Laid-Open No. 5-64828 includes a phospholipid and a sorbitan fatty acid ester or an ethylene oxide adduct thereof.
  • a concrete release agent comprising a mineral oil-based solvent is disclosed.
  • the concrete release agent disclosed in this publication achieves the effect of reducing the contamination of the mold and preventing the mold, but uses a mineral oil-based solvent, and thus is environmentally and safety-friendly. Was inadequate.
  • functional and environmental At present there is no product developed from the aspect point of view.
  • metal working oils such as cutting oils and plastic working oils, asphalt mixture adhesion preventives and concretes which can reduce environmental pollution while having excellent emulsification stability.
  • a water-soluble lubricating oil composition suitable as a release oil such as a release agent is desired.
  • an object of the present invention is to provide a metal working oil such as a cutting oil and a plastic working oil, an anti-adhesive mixture adhering agent, and a concrete, which are capable of reducing environmental pollution while having excellent emulsion stability.
  • An object of the present invention is to provide a water-soluble lubricating oil composition suitable as a release oil such as a release agent. Disclosure of the invention
  • the present inventors have made intensive studies and have found that a water-soluble lubricating oil composition containing animal fats and oils or vegetable fats and oils and a specific surfactant can achieve the above object.
  • the present invention has been made based on the above findings, and is a water-soluble lubricating oil composition comprising an animal fat and / or vegetable fat and a non-ionic surfactant of a polyoxyethylene sorbite fatty acid ester. It provides
  • water-soluble lubricating oil is a concept that includes release oil and metal working oil.
  • Metal working oil includes cutting oil and plastic working oil. Includes a mixture of anti-fouling agent and concrete release agent.
  • the present invention also provides a water-soluble metalworking oil composition
  • a water-soluble metalworking oil composition comprising an animal fat or oil or a vegetable oil or fat, and a non-ionic surfactant of a polyoxyethylene sorbite fatty acid ester.
  • the present invention relates to an animal oil and fat or a vegetable oil or fat, It is intended to provide a release oil containing a non-ionic surfactant of an unsorbitol fatty acid ester.
  • the present invention also provides an asphalt mixture adhesion inhibitor composition comprising an animal fat and / or vegetable fat and / or a polyoxyethylene sorbite fatty acid ester nonionic surfactant. is there.
  • the present invention also provides a concrete release agent composition containing an animal fat and / or vegetable fat and / or a non-ionic surfactant of polyoxyethylene sorbite fatty acid esters.
  • water-soluble means that it is diluted with water and used in the form of emulsion when used. That is, the water-soluble lubricating oil composition of the present invention is diluted with water at the time of use and used in the form of an emulsion.
  • a water-soluble lubricating oil composition has been used as a metal lubricating oil such as a cutting oil or a rolling oil, or a flame-retardant hydraulic oil. It has features such as a low flash point.
  • the water-soluble lubricating oil composition of the present invention contains animal fats and / or vegetable fats and oils and non-ionic surfactants of polyoxyethylene sorbite fatty acid esters.
  • the water-soluble lubricating oil composition of the present invention comprises animal fat and / or vegetable fat as a base oil.
  • animal fats and oils examples include beef tallow, lard and fish oil.
  • vegetable fats and oils examples include soybean oil, rapeseed oil, corn oil, safflower oil, castor oil, cottonseed oil, rice oil, sesame oil, olive oil, peanut oil, palm oil, and the like. Palm kernel oil, coconut oil, linseed oil and the like.
  • the above animal fats and vegetable fats are used alone. Or a mixture of two or more. Further, only animal fats and oils or vegetable fats and oils may be used, or animal fats and oils may be mixed and used.
  • the animal fats and vegetable fats and oils used in the water-soluble lubricating oil composition of the present invention are preferably liquid fats and oils at normal temperature.
  • the use of oils and fats that are liquid at normal temperature facilitates production, does not coagulate during storage, and is easy to use. Even if the above-mentioned animal fats and oils are not liquid at room temperature alone, they can be preferably used if they are liquid at room temperature when two or more kinds are mixed.
  • waste edible oils can be used as the above-mentioned animal fats and vegetable fats.
  • the content of the above-mentioned animal fats and / or vegetable fats is preferably 65% by mass or more, more preferably 75% by mass or more, based on the total mass of the water-soluble lubricating oil composition. If the content of animal fats and / or vegetable fats is less than 65% by mass, the effect of reducing environmental pollution may be inferior, so that the content is preferably within the above range.
  • nonionic surfactants of the polyoxyethylene sorbite fatty acid esters include, for example, polyoxyethylene sorbit tetrastearate, polyoxyethylene sorbit tetraoleate and monolau. And polyoxyethylene sorbite phosphate.
  • the above-mentioned nonionic surfactant may be used alone or in combination of two or more.
  • the content of the nonionic surfactant of the polyoxyethylene sorbite fatty acid ester is preferably 1 to 50 parts by mass with respect to 100 parts by mass of the total amount of animal fats and / or vegetable fats and oils. And more preferably 5 to 30 parts by mass. When the content of the nonionic surfactant is equal to or less than the animal fat and oil,
  • the amount is less than 1 part by mass based on 100 parts by mass of Z or vegetable oil, emulsification In some cases, the stability may be insufficient, and if the content exceeds 50 parts by mass, the effect cannot be expected to be improved by the addition of a surfactant, and the cost may be increased. It is preferable to be within the above range.
  • the water-soluble lubricating oil composition of the present invention can contain any conventionally used optional components conventionally contained in lubricating oil compositions.
  • optional components include an antioxidant, a pour point depressant, an extreme pressure agent, a viscosity index improver, an antioxidant, an antifoaming agent, a preservative, and a dispersant.
  • the content is usually about 0.1 to 10% by mass based on the total mass of the water-soluble lubricating oil composition.
  • the water-soluble lubricating oil composition of the present invention is used after being diluted with water.
  • the dilution concentration when diluted with water is preferably 1 to 50 times, and more preferably 3 to 30 times.
  • the water-soluble lubricating oil composition of the present invention can be produced as follows.
  • animal fats and oils or Z or vegetable fats and oils and non-ionic surfactants of polyoxyethylene sorbite fatty acid esters are heated to an appropriate temperature, respectively, and mixed and dissolved with good stirring to obtain the water-soluble compound of the present invention.
  • the obtained water-soluble lubricating oil composition is used after being diluted with water as necessary.
  • the above optional components may be added before heating or after obtaining the water-soluble lubricating oil composition.
  • the water-soluble metalworking oil composition of the present invention contains animal fats and / or vegetable fats and oils and a non-ionic surfactant of a polyoxyethylene sorbite fatty acid ester.
  • the water-soluble metalworking oil composition of the present invention comprises an animal fat and / or a vegetable fat as a base oil.
  • the above-mentioned animal fats and oils and vegetable fats and oils are the above-mentioned water-soluble lubricating oil compositions. And the content thereof is as described above.
  • the nonionic surfactants of the polyoxyethylene sorbite fatty acid esters those used in the above-mentioned water-soluble lubricating oil composition are used, and the contents and the like are as described above.
  • animal oils and fats or the content of nonionic surfactants of Z or vegetable oils and polyoxyshethylene sorbite fatty acid esters, optional components, etc. are the same as those in the water-soluble lubricating oil composition described above. Is the same as
  • the water-soluble metalworking oil composition of the present invention like the water-soluble lubricating oil composition of the present invention, is used after being diluted with water, and the dilution ratio is preferably 1 to 50 times, more preferably. Is 3 to 30 times.
  • the water-soluble metal working oil composition of the present invention can be used as a cutting oil or a plastic working oil.
  • a cutting oil or a plastic working oil There is no particular limitation on the method of use as cutting oil or plastic working oil, and it can be used in the same manner as conventional cutting oil or plastic working oil.
  • the method for producing the water-soluble metal working oil composition of the present invention is the same as the method for producing the water-soluble lubricating oil composition described above.
  • the release oil of the present invention comprises an animal oil and a Z or vegetable oil, and a non-ionic surfactant of a polyoxyethylene sorbite fatty acid ester. Is used as the base oil.
  • the above-mentioned animal fats and oils and vegetable fats and oils those used in the above-mentioned water-soluble lubricating oil composition are used, and the contents thereof are also as described above.
  • the nonionic surfactant of the polyoxyethylene sorbite fatty acid ester the one used in the above-mentioned water-soluble lubricating oil composition is used, and the content thereof is also as described above.
  • the content, optional components, etc. of the above-mentioned animal fats and oils or Z or vegetable fats and non-ionic surfactants of the polyoxyethylene sorbite fatty acid esters are the same as those in the water-soluble lubricating oil composition described above.
  • the release oil of the present invention can be used as an asphalt mixture adhesion inhibitor and a concrete release agent.
  • the method for producing the release oil of the present invention is also the same as the method for producing the water-soluble lubricating oil composition described above.
  • the asphalt mixture adhesion inhibitor composition of the present invention contains animal fats and oils and / or vegetable fats and oils and non-ionic surfactants of polyoxyethylene sorbite fatty acid esters.
  • the antifouling mixture adhesion inhibitor composition of the present invention comprises an animal fat and / or vegetable fat as a base oil.
  • the above animal fats and oils and vegetable fats and oils those used in the above-mentioned water-soluble lubricating oil composition are used, and the contents thereof are also as described above.
  • the nonionic surfactant of the polyoxyethylene sorbite fatty acid ester the one used in the above-mentioned water-soluble lubricating oil composition is used, and the content thereof is as described above.
  • the content and optional components of the above animal fats and oils or non-ionic surfactants of Z or vegetable fats and polyoxyethylene sorbite fatty acid esters are the same as those in the water-soluble lubricating oil composition described above.
  • the method for producing the antifouling mixture adhesion inhibitor composition of the present invention is the same as the method for producing the water-soluble lubricating oil composition described above.
  • the asphalt mixture adhesion inhibitor composition of the present invention is also used after being diluted with water, similarly to the water-soluble lubricating oil composition of the present invention, and the dilution ratio is preferably It is 1 to 50 times, and more preferably 3 to 30 times. If the dilution ratio exceeds 50 times, the content ratio of animal fats or vegetable fats decreases, and it may not be possible to obtain a sufficient effect of preventing the adhesion of the asphalt mixture.Therefore, the dilution ratio is 50 times or less. I prefer that there be. In order to improve the emulsion stability, 0.1 to 10 mass of the asphalt mixture adhesion inhibitor composition of the present invention is used. Water of about / 0 may be mixed.
  • asphalt mixture includes binders such as asphalt or resin binders, and further includes other materials such as aggregates. Used for paving roads.
  • asphalt mixture adhesion inhibitor of the present invention will be described.
  • the asphalt mixture adhesion inhibitor of the present invention is obtained by diluting the above-described asphalt mixture adhesion inhibitor composition of the present invention with water.
  • the dilution ratio is preferably 1 to 50 times, and more preferably 3 to 30 times.
  • the asphalt mixture adhesion inhibitor of the present invention is used, for example, by directly spraying it on a truck bed or a road. Also, it can be used by an appropriate spraying method such as applying or spraying to a construction machine such as a tire roller or a mouth roller. If sprayed into tracks loading platform and road, there is no particular limitation on the scatterplot amount, typically Ru 1 0 0 ⁇ 1 0 0 0 m LZ m 2 about der. There is no particular limitation on the amount of application when applied to a construction machine, but it is usually about 50 to 200 mL / m2.
  • the concrete release agent composition of the present invention contains animal fats and / or vegetable fats and oils and nonionic surfactants of polyoxyethylene sorbite fatty acid esters.
  • the concrete release agent composition of the present invention comprises an animal fat and / or vegetable fat as a base oil.
  • the above-mentioned animal fats and oils and vegetable fats and oils are the above-mentioned water-soluble lubricating oil compositions. And the content thereof is also as described above.
  • the nonionic surfactant of the above-mentioned polyoxyethylene sorbite fatty acid esters those used in the above-mentioned water-soluble lubricating oil composition are used, and the content thereof is also as described above.
  • the content and optional components of the non-ionic surfactants of the above-mentioned animal fats and / or vegetable fats and polyoxyethylene sorbite fatty acid esters are the same as those in the water-soluble lubricating oil composition described above. .
  • the method for producing the concrete release agent composition of the present invention is also the same as the method for producing the water-soluble lubricating oil composition described above.
  • the concrete release agent composition of the present invention is also used after being diluted with water, similarly to the water-soluble lubricating oil composition of the present invention, and the dilution ratio is preferably 1 to 50 times. More preferably, it is 3 to 30 times. If the dilution ratio exceeds 50 times, the content ratio of animal fats or vegetable fats decreases, and a sufficient concrete release effect may not be obtained.Therefore, the dilution ratio is 50 times or less. It is preferred that In order to improve the emulsion stability, about 0.1 to 10% by mass of water may be mixed with the concrete release agent composition of the present invention.
  • the concrete release agent of the present invention is obtained by diluting the above-described concrete release agent composition of the present invention with water.
  • the dilution ratio is preferably 1 to 50 times, and more preferably 3 to 30 times.
  • the concrete release agent of the present invention can be applied directly to the inner surface of the mold when the concrete is solidified using the mold to produce a concrete product. Used. There is no particular limitation on the method of application, and it can be carried out by an appropriate application method. When applied to a mold, the amount of application is not particularly limited, but is usually about 20 to 10 Om LZ m2.
  • the concrete release agent composition and concrete release agent include nonionic surfactants of animal fats and oils or vegetable fats and oils and polyoxyethylene sorbite fatty acid esters.
  • mineral oils conventionally used in water-soluble lubricating oil compositions, water-soluble metalworking oil compositions, asphalt mixture antiadhesive compositions, and asphalt mixture antiadhesive agents, etc. May be used together within a range that does not impair the performance.
  • mineral oil When mineral oil is included, its content is less than the total amount of animal fats and oils or vegetable fats and oils.
  • Friction coefficient The obtained water-soluble lubricating oil composition was diluted 10-fold with water, and the friction coefficient of the diluted solution was measured using a vibration friction and wear tester (Optimol). The measurement conditions are as follows.
  • the obtained water-soluble lubricating oil composition was diluted 10-fold with water, stirred well, allowed to stand for 8 hours, and the emulsified state was visually observed, and evaluated according to the following evaluation criteria. .
  • the degree of biodegradation after 28 days was measured by a test method according to OECCD301C, which is a certification standard of Eco Mark.
  • the result using rapeseed oil was 87%.
  • LC50 was measured after 96 hours by a test method based on OECD203 (Acute toxicity test of medaka), which is a certification standard of Eco Mark.
  • the criteria for Eco Mark certification are that the biodegradation after 28 days in the above test (5) -1 is 60% or more and the LC50 after 96 hours in the test (5) -2. Is 10 O mg / L or more.
  • the biological effect test was performed using 1000 mg L of the composition, and it was determined whether or not all the medaka were alive even with the 1000 mg / L composition. Beta.
  • Mild steel was drilled (100 rpm) using a center drill A type 60 ° HSS (edge diameter 4) manufactured by Iwata Tool Co., Ltd. and evaluated as a water-soluble cutting oil.
  • the obtained water-soluble lubricating oil composition was used after being diluted 30-fold with water, and the angular accuracy was measured and evaluated.
  • Press formability evaluation Press formability was evaluated using a cylindrical punch hydraulic forming tester. The measurement conditions are as follows. The evaluation was performed using an electro-zinc plated steel sheet.
  • the obtained water-soluble lubricating oil composition was used after being diluted 10-fold with water, and the mold seizure was visually observed by observing the appearance of the side wall and evaluated according to the following evaluation criteria. ⁇ : Moldable Yes, there is no defect on the surface of the steel sheet.
  • a water-soluble lubricating oil composition obtained by diluting the obtained water-soluble lubricating oil composition five-fold with water was applied to an iron mold having a length of 10 cm, a width of 10 cm and a height of 30 cm by using a sprayer to apply 4 ml. Concrete that was kneaded with the following composition was poured into this formwork. The driving was performed while vibrating for 30 seconds using a table vibrator of 300 Vpm. After being left for 2 S, the mold was released, and the releasability was evaluated according to the following evaluation criteria. ⁇ : Almost no concrete adhering to the formwork.
  • the water-soluble lubricating oil composition of the present invention was added to the water-soluble lubricating oil composition obtained in Example 1 while well stirring 1% of water with respect to the total mass of the composition. I got The obtained water-soluble lubricating oil composition was evaluated in the same manner as in Example 1. The evaluation results are shown in Table 1 (tests (1) to (5)) and Table 2 (tests (6) to (8)).
  • Example 1 The same evaluation as in Example 1 was performed using the following as Comparative Examples 1 to 3. The evaluation results are shown in Table 1 (tests (1) to (5)) and Table 2 (tests (6) to (8)).
  • Comparative Example 1 Commercial light oil.
  • Example 1 0.11 ⁇ ⁇ ⁇ 60% or more 1000mg / L or more
  • Example 2 0.12 ⁇ ⁇ ⁇ 60% or more 1000mg / L or more
  • Example 3 0.12 ⁇ ⁇ ⁇ 60% or more 1000mg / L or more
  • Example 4 0.11 ⁇ ⁇ ⁇ 60% or more 1000 mg / L or more Comparative Example 1 X ⁇
  • the water-soluble lubricating oil composition of the present invention has excellent emulsion stability and low solubility of asphalt when used as an asphalt mixture adhesion inhibitor. It is excellent in the effect of preventing the adhesion of asphalt mixture. Further, the water-soluble lubricating oil composition of the present invention is excellent in environmental safety.
  • the water-soluble lubricating oil composition of the present invention has excellent cutting properties, press formability and concrete release properties, and is excellent in cutting oil (cutting). Oil), press working oil, and concrete release agent.
  • the water-soluble lubricating oil composition of the present invention has excellent emulsion stability and can reduce environmental pollution.
  • the antifouling mixture adhesion inhibitor of the present invention has excellent emulsification stability, It has a low asphalt solubility, can reduce environmental pollution, and has an excellent effect of preventing the asphalt mixture from adhering.
  • the concrete release agent composition of the present invention is excellent in emulsification stability, can reduce environmental pollution, and has a concrete release effect. It is excellent.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)

Abstract

L'invention concerne une composition huileuse lubrifiante soluble dans l'eau comprenant une huile et une graisse animales et/ou une huile et une graisse végétales ainsi qu'un tensioactif non ionique d'un ester d'acide gras de polyoxyéthylène sorbitol. Cette composition huileuse lubrifiante soluble dans l'eau présente une stabilité d'émulsion élevée et un pouvoir polluant réduit. Ainsi, on peut l'utiliser comme un lubrifiant de travail de métaux, tel qu'une huile de coupe et une huile de traitement de déformation, et comme une huile de démoulage, telle qu'un agent antiadhérent d'un mélange asphaltique et un agent de démoulage pour béton.
PCT/JP2002/011043 2001-10-26 2002-10-24 Composition huileuse lubrifiante WO2003035809A1 (fr)

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JP2003538311A JP4205585B2 (ja) 2001-10-26 2002-10-24 潤滑油組成物

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JP2001329601 2001-10-26
JP2001-329601 2001-10-26

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WO2003035809A1 true WO2003035809A1 (fr) 2003-05-01

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CN (1) CN100532518C (fr)
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Cited By (17)

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EP1743753A1 (fr) * 2005-06-20 2007-01-17 Heraeus Kulzer GmbH Pâte de modelage, l'utilisation et procédé pour la fabrication de corps céramiques
JP2007231093A (ja) * 2006-02-28 2007-09-13 Sakai Heavy Ind Ltd アスファルト付着防止剤
EP2287268A2 (fr) 2009-08-20 2011-02-23 NOF Corporation Composition d'agent anti-adhésion pour asphalte
JP2011246998A (ja) * 2010-05-27 2011-12-08 Tanaka Tekko Kk 付着防止剤供給装置および付着防止剤供給方法並びに付着防止剤
CN102816557A (zh) * 2012-08-01 2012-12-12 新疆蛛蛛网科技股份有限公司 环境友好型钻井液(efd)
CN102851006A (zh) * 2012-09-30 2013-01-02 中国石油集团西部钻探工程有限公司 钻井用生物油润滑剂及其制备方法
CN102942499A (zh) * 2012-10-12 2013-02-27 陕西师范大学 一种沥青脱模剂的制备方法
JP2013091691A (ja) * 2011-10-24 2013-05-16 Nof Corp アスファルト合材付着防止剤組成物
WO2014024801A1 (fr) 2012-08-10 2014-02-13 日油株式会社 Agent anti-adhésif pour mélange d'asphalte
CN103992861A (zh) * 2014-04-25 2014-08-20 蚌埠市鸿安精密机械有限公司 一种薄层防锈油
WO2015034343A1 (fr) * 2013-05-20 2015-03-12 Malaysian Palm Oil Board Lubrifiant de démoulage
JP2015078297A (ja) * 2013-10-16 2015-04-23 日油株式会社 アスファルト合材付着防止剤
US9029306B2 (en) 2009-11-30 2015-05-12 Idemitsu Kosan., Ltd. Water-soluble metalworking oil agent and usage thereof
WO2018018423A1 (fr) * 2016-07-26 2018-02-01 顾湘 Agent de démoulage de béton équarri et son procédé de préparation
CN111378519A (zh) * 2018-12-27 2020-07-07 膳魔师（江苏）家庭制品有限公司 一种水涨液的制备方法
KR102144960B1 (ko) * 2020-04-01 2020-08-14 (주)씨엔루브 폐유를 이용한 콘크리트유성탈형제 제조방법
JP2020131464A (ja) * 2019-02-14 2020-08-31 ボーソー油脂株式会社 コンクリート型枠剥離剤

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US8709534B2 (en) * 2008-05-30 2014-04-29 Construction Research & Technology Gmbh Formwork release composition and use thereof
CN102205390B (zh) * 2011-04-28 2013-05-08 苏州兴业材料科技股份有限公司 环保型压铸脱模剂及其制备方法
TWI467002B (zh) * 2012-02-24 2015-01-01 Univ Nat Formosa 稻桿生質潤滑油
CN104531309A (zh) * 2014-12-18 2015-04-22 蒙城县科技创业服务中心 一种水性聚氨酯混凝土脱模剂及其制备方法
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CN104498161A (zh) * 2014-12-18 2015-04-08 蒙城县科技创业服务中心 一种以动物油脂制成的混凝土脱模剂
CN104479842A (zh) * 2014-12-18 2015-04-01 蒙城县科技创业服务中心 一种绿色环保混凝土脱模剂及其制备方法
KR101635457B1 (ko) * 2016-01-11 2016-07-01 주식회사 누보켐 아스팔트 혼합물 부착 방지제 및 그의 제조방법
CN107088648B (zh) * 2017-04-18 2019-07-02 奎克化学（中国）有限公司 一种铅酸蓄电池板栅浇铸用油性脱模剂
CN110747046B (zh) * 2019-10-25 2022-09-23 泉州凯平肯拓化工有限公司 一种环保脱模剂及其制备方法

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JPS5773088A (en) * 1980-10-22 1982-05-07 Kao Corp Cold rolling lubricating oil of metallic material
JPH0418169A (ja) * 1990-05-02 1992-01-22 Yushiro Chem Ind Co Ltd 繊維処理用油剤
JPH0741785A (ja) * 1993-07-26 1995-02-10 Nippon Steel Corp チタン板用冷間圧延油組成物
JPH07179878A (ja) * 1993-12-22 1995-07-18 Kyoeisha Chem Co Ltd 医療器具の潤滑・防錆用乳化液組成物
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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1743753A1 (fr) * 2005-06-20 2007-01-17 Heraeus Kulzer GmbH Pâte de modelage, l'utilisation et procédé pour la fabrication de corps céramiques
JP2007231093A (ja) * 2006-02-28 2007-09-13 Sakai Heavy Ind Ltd アスファルト付着防止剤
EP2287268A2 (fr) 2009-08-20 2011-02-23 NOF Corporation Composition d'agent anti-adhésion pour asphalte
US8114930B2 (en) * 2009-08-20 2012-02-14 Nof Corporation Anti-adhesion agent composition for asphalt
US9029306B2 (en) 2009-11-30 2015-05-12 Idemitsu Kosan., Ltd. Water-soluble metalworking oil agent and usage thereof
JP2011246998A (ja) * 2010-05-27 2011-12-08 Tanaka Tekko Kk 付着防止剤供給装置および付着防止剤供給方法並びに付着防止剤
JP2013091691A (ja) * 2011-10-24 2013-05-16 Nof Corp アスファルト合材付着防止剤組成物
CN102816557A (zh) * 2012-08-01 2012-12-12 新疆蛛蛛网科技股份有限公司 环境友好型钻井液(efd)
US9416249B2 (en) 2012-08-10 2016-08-16 Nof Corporation Anti-adhesive agent for asphalt mixtures
KR20150043320A (ko) 2012-08-10 2015-04-22 니치유 가부시키가이샤 아스팔트 합재 부착 방지제
WO2014024801A1 (fr) 2012-08-10 2014-02-13 日油株式会社 Agent anti-adhésif pour mélange d'asphalte
CN102851006A (zh) * 2012-09-30 2013-01-02 中国石油集团西部钻探工程有限公司 钻井用生物油润滑剂及其制备方法
CN102942499A (zh) * 2012-10-12 2013-02-27 陕西师范大学 一种沥青脱模剂的制备方法
WO2015034343A1 (fr) * 2013-05-20 2015-03-12 Malaysian Palm Oil Board Lubrifiant de démoulage
US9809776B2 (en) 2013-05-20 2017-11-07 Malaysian Palm Oil Board Mould release lubricant
JP2015078297A (ja) * 2013-10-16 2015-04-23 日油株式会社 アスファルト合材付着防止剤
CN103992861A (zh) * 2014-04-25 2014-08-20 蚌埠市鸿安精密机械有限公司 一种薄层防锈油
WO2018018423A1 (fr) * 2016-07-26 2018-02-01 顾湘 Agent de démoulage de béton équarri et son procédé de préparation
CN111378519A (zh) * 2018-12-27 2020-07-07 膳魔师（江苏）家庭制品有限公司 一种水涨液的制备方法
JP2020131464A (ja) * 2019-02-14 2020-08-31 ボーソー油脂株式会社 コンクリート型枠剥離剤
JP7193064B2 (ja) 2019-02-14 2022-12-20 ボーソー油脂株式会社 コンクリート型枠剥離剤
KR102144960B1 (ko) * 2020-04-01 2020-08-14 (주)씨엔루브 폐유를 이용한 콘크리트유성탈형제 제조방법

Also Published As

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JPWO2003035809A1 (ja) 2005-02-10
CN1575330A (zh) 2005-02-02
TW583309B (en) 2004-04-11
JP4205585B2 (ja) 2009-01-07
CN100532518C (zh) 2009-08-26

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