WO2002090113A1 - Film made of thermoplastic resin, which may be used for packaging foods - Google Patents

Film made of thermoplastic resin, which may be used for packaging foods Download PDF

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Publication number
WO2002090113A1
WO2002090113A1 PCT/IT2002/000297 IT0200297W WO02090113A1 WO 2002090113 A1 WO2002090113 A1 WO 2002090113A1 IT 0200297 W IT0200297 W IT 0200297W WO 02090113 A1 WO02090113 A1 WO 02090113A1
Authority
WO
WIPO (PCT)
Prior art keywords
pvc
film according
film
eva
stretchable
Prior art date
Application number
PCT/IT2002/000297
Other languages
French (fr)
Inventor
Lorenzo Francesconi
Original Assignee
Vismore Company S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vismore Company S.A. filed Critical Vismore Company S.A.
Publication of WO2002090113A1 publication Critical patent/WO2002090113A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B32B2307/734—Dimensional stability
    • B32B2307/736—Shrinkable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2325/00—Polymers of vinyl-aromatic compounds, e.g. polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2331/00—Polyvinylesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging

Definitions

  • the aim of the present invention is to keep the PVC film still stretchable and thus suitable for use, but make it inert, that is to say prevent the transfer of foreign substances to the packaged food.
  • the subject of the invention is a stretchable film made of synthetic resin, which can be used for packaging foods, characterized in that it comprises an internal thickness made of polyvinyl chloride (PVC) with plasticizers that may be of the phthalate type, and thin external thicknesses made of non-toxic thermoplastic synthetic resins and the like to block the transmission of particles present in the PVC.
  • Said thin external thicknesses may consist of substances included in the group comprising polystyrene (PS), ethylene/vinyl acetate (EVA), polyethylene (PE), ionomeric resins (Surlyn), polybutadiene, "K” resins and the like, and also resins such as Barex, EVOH, Nylon, etc. capable of making the film impermeable to gases so as to allow the product to be wrapped under vacuum or in a modified atmosphere to keep the wrapped product fresh for longer.
  • PS polystyrene
  • EVA ethylene/vinyl acetate
  • PE polyethylene
  • the stretchable PVC film with another two (minimum) layers outside the PVC, made of other thermoplastic materials, for instance polystyrene (PS), ethylene/vinyl acetate (EVA), ionomeric resins such as "Surlyn", polybutadiene, "K” resin and various others, which block the migration of particles present in the PVC and which are non-toxic.
  • PS polystyrene
  • EVA ethylene/vinyl acetate
  • ionomeric resins such as "Surlyn", polybutadiene, "K” resin and various others, which block the migration of particles present in the PVC and which are non-toxic.
  • the co-extrusion must be of at least three layers since, otherwise, the problem of transfer would not be eliminated; it is essential that the stretchable PVC film must be in an internal structure, and thus isolated.
  • Co-extrusion with three or more layers may be envisaged, which may be carried out as for normal extrusion, either from the top downward or, conversely, from the bottom upward.
  • the mechanical properties of the film are maintained unaltered, these properties being intrinsic to PVC - especially the elastic memory, the stretchability, the rupture strength and the chemical properties, for instance the equilibrated permeability to atmospheric agents.
  • the wrapped product - such as meat, cheese and the like - remains free of foreign substances, which cannot be transferred from the PVC packaging film, due to the isolation provided by the two external layers of the sandwich.
  • the film with three or more layers may be suitably supplemented with "antifog” substances, so as to make the multiple film totally transparent.
  • the PS/PVC/PS structure may also be used in automated or manual machines, with a particular type of sealer which is already the subject of another previous patent (Italian patent application No. FI2000A000161 of July 11 , 2000) from the same inventor.
  • a plasticized PVC- based film of this type may also be produced with heat-shrinkability properties, again constructed with a minimum of three layers, with the "two- bubble" system - the invention consists in obtaining a stretchable film by co- extrusion of three or more layers, in which the main layer is made of plasticized PVC.
  • FIG. 1 shows, on a very enlarged scale, a film made according to the invention
  • Figs. 2 and 3 are sketches of construction schemes for producing a film according to the invention, of stretchable and heat-shrinkable type.
  • Fig. 1 indicates the internal thickness of stretchable polyvinyl chloride (PVC) with various additives including plasticizers that may be of the phthalate type, for instance dioctyl phthalate (DOP), and 3 and 5 indicate two thin layers of EVA stretchable polystyrene (PS).
  • PVC polyvinyl chloride
  • DOP dioctyl phthalate
  • PS EVA stretchable polystyrene
  • the layers 3 and 5 may also be made of other synthetic resins, which may be identical or different.
  • Fig. 2 shows a scheme of a plant with a co-extrusion die 11 , of which 13 indicates two of the three or four or more extruders that feed this die.
  • the bubble B1 being produced downward passes between two rollers 15 and may be collected by a rotating unit 17 to make a stretchable film.
  • the material in film form is conveyed along a path P1 to an oven 19, and is then collected in an essentially identical manner.
  • Fig. 3 shows a scheme of a plant with an extrusion die 111 , of which 113 indicates one of the extruders feeding it.
  • the bubble B2 is produced upward to reach a set of rollers 115, after which the material may be collected as a stretchable film at 117, or diverted into the path P2 leading to an oven 119, after which the heat-shrinkable film is collected.
  • the same path may be envisaged to collect the stretchable film without running the oven.
  • a heat-shrinkable film may also be prepared by the "two-bubble" system.

Landscapes

  • Laminated Bodies (AREA)
  • Wrappers (AREA)
  • Packages (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The film consists of an internal thickness made of polyvinyl chloride (PVC) with plasticizers also of the phthalate type, co-extruded with two thin external thickness of non-toxic synthetic resins - for instance stretchable polystyrene (PS) or ethylene/vinyl acetate (EVA) or other thermoplastic materials that are also impermeable to gases - and which are capable of blocking the transmission of particles present in the PVC.

Description

FILM MADE OF THERMOPLASTIC RESIN , WHICH MAY BE USED FOR PACKAGING FOODS .
DESCRIPTION The wrapping or packaging of fresh products - such as meat, cheese, fruit, vegetables and various other products - in supermarkets and in prepackaging centers, has been performed hitherto using a stretchable plasticized PVC (polyvinyl chloride) film, which is applied onto trays made of polystyrene, wood pulp and similar containers made of rigid plastic. Stretchable PVC film is known as "stretch film" or "cling film". To obtain the correct physicochemical and mechanical properties for the stretchable PVC film, it is necessary to add to the PVC-based thermoplastic resin many other chemical substances, for instance stabilizers, lubricants, plasticizers, etc. The "compounds" thus obtained are then extruded using systems known in the industry, performed by various extrusion techniques from the top downwards or vice-versa. All these systems have been known for a long time to those skilled in the art.
Recently, the problem has emerged of plasticizers in general and phthalates (DOP and the like) in particular, which appear to be carcinogenic. These substances migrate from the film to the wrapped product and this may be hazardous to the health of consumers.
Italian and European law has recently banned the use of these types of plasticizers. The producers of these films adapted to the legislative provisions by varying the nature of the plasticizers, but this does not alter the fact that these substances also - which appear to be recognized as non-toxic - can still migrate into the wrapped product, transferring substances which are at the very least foreign to the packaged food and which may therefore be more or less harmful. The film is therefore not inert.
The aim of the present invention is to keep the PVC film still stretchable and thus suitable for use, but make it inert, that is to say prevent the transfer of foreign substances to the packaged food.
Numerous attempts have been made hitherto to achieve this aim by those skilled in the field of plastics engineering, by replacing stretchable PVC film with stretchable PE (polyethylene) film, sometimes using co-extrusion systems in two or more layers, and even up to five layers, in addition to mono- extrusion; however, no positive results have been achieved to date. This may be due to the nature of the plastic materials used, the lack of mechanical or chemical properties, for instance the correct and equilibrated permeability to C02, O2 and H20, and also the lack of elastic memory and rupture strength of the film. Problems relating to the use of automated, semi-automated or even manual machines have also emerged.
Essentially, the subject of the invention is a stretchable film made of synthetic resin, which can be used for packaging foods, characterized in that it comprises an internal thickness made of polyvinyl chloride (PVC) with plasticizers that may be of the phthalate type, and thin external thicknesses made of non-toxic thermoplastic synthetic resins and the like to block the transmission of particles present in the PVC. Said thin external thicknesses may consist of substances included in the group comprising polystyrene (PS), ethylene/vinyl acetate (EVA), polyethylene (PE), ionomeric resins (Surlyn), polybutadiene, "K" resins and the like, and also resins such as Barex, EVOH, Nylon, etc. capable of making the film impermeable to gases so as to allow the product to be wrapped under vacuum or in a modified atmosphere to keep the wrapped product fresh for longer.
Thus, according to the invention, it has been envisaged to maintain the predominant presence of PVC with the chemical and physical properties that are intrinsic to this material and - to overcome the problems of transfer of the substances added to the PVC resin (which would migrate directly from the film to the wrapped product, and to maintain the particular properties of the stretchable PVC film - to co-extrude, in a bubble or with a flat die, the stretchable PVC film with another two (minimum) layers outside the PVC, made of other thermoplastic materials, for instance polystyrene (PS), ethylene/vinyl acetate (EVA), ionomeric resins such as "Surlyn", polybutadiene, "K" resin and various others, which block the migration of particles present in the PVC and which are non-toxic.
Advantageously, the co-extrusion must be of at least three layers since, otherwise, the problem of transfer would not be eliminated; it is essential that the stretchable PVC film must be in an internal structure, and thus isolated.
Basically, it is necessary to achieve a sandwich structure, with the PVC on the inside and in a sufficient thickness to provide the physicochemical properties intrinsic thereto, especially the stretchability, and with external thicknesses of inert and non-hazardous resins.
Co-extrusion with three or more layers may be envisaged, which may be carried out as for normal extrusion, either from the top downward or, conversely, from the bottom upward.
A number of construction schemes are attached as illustrative solutions.
With this arrangement, the mechanical properties of the film are maintained unaltered, these properties being intrinsic to PVC - especially the elastic memory, the stretchability, the rupture strength and the chemical properties, for instance the equilibrated permeability to atmospheric agents. In this way, it is also possible to use the commercially available range of machines. However, with this arrangement, the wrapped product - such as meat, cheese and the like - remains free of foreign substances, which cannot be transferred from the PVC packaging film, due to the isolation provided by the two external layers of the sandwich.
The film with three or more layers may be suitably supplemented with "antifog" substances, so as to make the multiple film totally transparent.
The PS/PVC/PS structure may also be used in automated or manual machines, with a particular type of sealer which is already the subject of another previous patent (Italian patent application No. FI2000A000161 of July 11 , 2000) from the same inventor.
Besides the condition of being a stretchable film, a plasticized PVC- based film of this type may also be produced with heat-shrinkability properties, again constructed with a minimum of three layers, with the "two- bubble" system - the invention consists in obtaining a stretchable film by co- extrusion of three or more layers, in which the main layer is made of plasticized PVC.
In the drawing,
Fig. 1 shows, on a very enlarged scale, a film made according to the invention; Figs. 2 and 3 are sketches of construction schemes for producing a film according to the invention, of stretchable and heat-shrinkable type.
In Fig. 1 , 1 indicates the internal thickness of stretchable polyvinyl chloride (PVC) with various additives including plasticizers that may be of the phthalate type, for instance dioctyl phthalate (DOP), and 3 and 5 indicate two thin layers of EVA stretchable polystyrene (PS). The layers 3 and 5 may also be made of other synthetic resins, which may be identical or different.
Fig. 2 shows a scheme of a plant with a co-extrusion die 11 , of which 13 indicates two of the three or four or more extruders that feed this die. The bubble B1 being produced downward passes between two rollers 15 and may be collected by a rotating unit 17 to make a stretchable film. On the other hand, to obtain a heat-shrinkable film, the material in film form is conveyed along a path P1 to an oven 19, and is then collected in an essentially identical manner.
Fig. 3 shows a scheme of a plant with an extrusion die 111 , of which 113 indicates one of the extruders feeding it. The bubble B2 is produced upward to reach a set of rollers 115, after which the material may be collected as a stretchable film at 117, or diverted into the path P2 leading to an oven 119, after which the heat-shrinkable film is collected. The same path may be envisaged to collect the stretchable film without running the oven. A heat-shrinkable film may also be prepared by the "two-bubble" system.
It is understood that the drawing shows merely one illustration given purely as a practical arrangement of the invention, it being possible for the invention to be modified in its forms and arrangements without, however, departing from the scope of the underlying concept of the invention.

Claims

C AIMS
1. Stretchable film made of synthetic resin, which can be used for packaging foods, characterized in that it comprises an internal thickness made of polyvinyl chloride (PVC) with plasticizers that may be of the phthalate type, and thin external thicknesses made of non-toxic thermoplastic synthetic resins and the like to block the transmission of particles present in the PVC.
2. Film according to claim 1 , characterized in that said thin external thicknesses consist of substances included in the group consisting of polystyrene (PS), ethylene/vinyl acetate (EVA), polyethylene (PE), ionomeric resins, polybutadiene, "K" resins and the like.
3. Film according to claims 1 and 2, characterized in that it consists of PS-PVC-PS.
4. Film according to claims 1 and 2, characterized in that it consists of PS-PVC-EVA.
5. Film according to claims 1 and 2, characterized in that it consists of EVA-PVC-EVA.
6. Film according to claims 1 and 2, characterized in that it consists of PE-PVC-PE.
7. Film according to claims 1 and 2, characterized in that it consists of PE-PVC-PS.
8. Film according to claims 1 and 2, characterized in that it consists of PE-PVC-EVA.
9. Film according to at least one of the preceding claims, characterized in that it is obtained by tubular co-extrusion.
10. Film according to at least one of the preceding claims, characterized in that it is co-extruded with barrier materials such as EVOH,
Barex, Nylon, etc., and optional adhesives.
11. Film according to at least one of the preceding claims, characterized in that it is made heat-shrinkable by the "two-bubble" system.
12. Plant for producing a film according to one of the preceding claims.
PCT/IT2002/000297 2001-05-10 2002-05-06 Film made of thermoplastic resin, which may be used for packaging foods WO2002090113A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITFI2001A000085 2001-05-10
IT2001FI000085A ITFI20010085A1 (en) 2001-05-10 2001-05-10 AN EXTENDABLE FILM IN THERMOPLASTIC RESIN, USABLE FOR FOOD PACKAGES

Publications (1)

Publication Number Publication Date
WO2002090113A1 true WO2002090113A1 (en) 2002-11-14

Family

ID=11442189

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IT2002/000297 WO2002090113A1 (en) 2001-05-10 2002-05-06 Film made of thermoplastic resin, which may be used for packaging foods

Country Status (4)

Country Link
AR (1) AR033882A1 (en)
IT (1) ITFI20010085A1 (en)
UY (1) UY27286A1 (en)
WO (1) WO2002090113A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004041536A1 (en) * 2002-11-05 2004-05-21 Vismore Company S.A. Stretchable thermoplastic resin film, for use in the packaging of food
WO2009026194A1 (en) * 2007-08-21 2009-02-26 E. I. Du Pont De Nemours And Company Product comprising ionomer and plasticizer

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4855181A (en) * 1986-12-12 1989-08-08 Kuraray Co., Ltd. Laminate with a blend layer of polyesteramide and ethylene-vinyl acetate copolymer
US6214477B1 (en) * 1998-07-17 2001-04-10 Cryovac, Inc. Multilayer film with polyolefin and polyvinyl chloride

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4855181A (en) * 1986-12-12 1989-08-08 Kuraray Co., Ltd. Laminate with a blend layer of polyesteramide and ethylene-vinyl acetate copolymer
US6214477B1 (en) * 1998-07-17 2001-04-10 Cryovac, Inc. Multilayer film with polyolefin and polyvinyl chloride

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004041536A1 (en) * 2002-11-05 2004-05-21 Vismore Company S.A. Stretchable thermoplastic resin film, for use in the packaging of food
WO2009026194A1 (en) * 2007-08-21 2009-02-26 E. I. Du Pont De Nemours And Company Product comprising ionomer and plasticizer
US7858681B2 (en) 2007-08-21 2010-12-28 E. I. Du Pont De Nemours And Company Product comprising ionomer and plasticizer

Also Published As

Publication number Publication date
ITFI20010085A1 (en) 2002-11-10
AR033882A1 (en) 2004-01-07
UY27286A1 (en) 2002-09-30

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