WO2002060812A3 - Processus de derivatisation de nanotubes de carbone avec des especes chimiques diazonium et compositions de celles-ci - Google Patents

Processus de derivatisation de nanotubes de carbone avec des especes chimiques diazonium et compositions de celles-ci Download PDF

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Publication number
WO2002060812A3
WO2002060812A3 PCT/US2002/002562 US0202562W WO02060812A3 WO 2002060812 A3 WO2002060812 A3 WO 2002060812A3 US 0202562 W US0202562 W US 0202562W WO 02060812 A3 WO02060812 A3 WO 02060812A3
Authority
WO
WIPO (PCT)
Prior art keywords
nanotubes
carbon nanotubes
derivatization
properties
modified
Prior art date
Application number
PCT/US2002/002562
Other languages
English (en)
Other versions
WO2002060812A2 (fr
Inventor
James M Tour
Jeffrey L Bahr
Jiping Yang
Original Assignee
Univ Rice William M
James M Tour
Jeffrey L Bahr
Jiping Yang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US10/470,517 priority Critical patent/US7250147B2/en
Priority to DE10295944T priority patent/DE10295944T5/de
Priority to KR10-2003-7010023A priority patent/KR20030091977A/ko
Priority to JP2002560970A priority patent/JP4308527B2/ja
Priority to GB0319871A priority patent/GB2389847B/en
Priority to AU2002240159A priority patent/AU2002240159A1/en
Application filed by Univ Rice William M, James M Tour, Jeffrey L Bahr, Jiping Yang filed Critical Univ Rice William M
Publication of WO2002060812A2 publication Critical patent/WO2002060812A2/fr
Publication of WO2002060812A3 publication Critical patent/WO2002060812A3/fr
Priority to US10/632,948 priority patent/US7384815B2/en
Priority to US10/632,284 priority patent/US7304103B2/en
Priority to US10/632,419 priority patent/US7691359B2/en
Priority to US11/840,433 priority patent/US7892517B2/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C09C1/56—Treatment of carbon black ; Purification
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C09C1/56—Treatment of carbon black ; Purification
    • C09C1/565—Treatment of carbon black ; Purification comprising an oxidative treatment with oxygen, ozone or oxygenated compounds, e.g. when such treatment occurs in a region of the furnace next to the carbon black generating reaction zone
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/36—Diameter
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)

Abstract

La présente invention concerne de nouveaux processus permettant de modifier chimiquement des nanotubes de carbone. Ces processus consistent en une dérivatisation de nanotubes de carbone à parois multiples ou à paroi simple, comprenant des nanotubes de carbone à paroi simple de petit diamètre, (ca. 0.7 nm), avec des espèces chimiques diazonium. Ce procédé permet de fixer chimiquement une variété de composés organiques sur le côté ou sur les extrémités de ces nanotubes de carbone. Ces nanotubes chimiquement modifiés présentent des applications dans des matériaux composites polymères, des applications électroniques moléculaires et dans des applications de dispositifs de détection. Les procédés de dérivatisation comprennent des réactions induites de façon électrochimique, de façon thermique (via la génération in-situ de composés diazonium ou de composés diazonium préformés), et de façon photochimique. La dérivatisation entraîne des modifications importantes des propriétés spectroscopiques de ces nanotubes. Le degré de fonctionnalité estimé est ca. 1 parmi 20 à 30 carbones d'un nanotube portant un groupe de fonctionnalité. Ces processus de réduction électrochimiques peuvent être adaptés pour appliquer une fonctionnalisation chimique à site sélectif de ces nanotubes. De plus, lorsqu'ils sont modifiés avec des groupes chimiques adaptés, ces nanotubes dérivatisés sont chimiquement compatibles avec une matrice polymère, ce qui permet de transférer les propriétés de ces nanotubes ( telles que la résistance mécanique ou la conductivité électrique) aux propriétés du matériau composite dans son ensemble. Enfin, lorsqu'ils sont modifiés avec des groupes chimiques adaptés, ces groupes peuvent être polymérisés de façon à former un polymère qui comprend des nanotubes de carbone.
PCT/US2002/002562 2001-01-29 2002-01-29 Processus de derivatisation de nanotubes de carbone avec des especes chimiques diazonium et compositions de celles-ci WO2002060812A2 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
DE10295944T DE10295944T5 (de) 2001-01-29 2002-01-29 Verfahren zur Derivatisierung von Kohlenstoff-Nanoröhrchen mit Diazonium-Spezies und Zusammensetzungen davon
KR10-2003-7010023A KR20030091977A (ko) 2001-01-29 2002-01-29 디아조늄종을 가진 탄소 나노튜브 유도 공정 및 조성물
JP2002560970A JP4308527B2 (ja) 2001-01-29 2002-01-29 ジアゾニウム種を用いてカーボンナノチューブを誘導体化する方法及びその組成物
GB0319871A GB2389847B (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
AU2002240159A AU2002240159A1 (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
US10/470,517 US7250147B2 (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species
US10/632,948 US7384815B2 (en) 2001-01-29 2003-08-01 Process for attaching molecular wires and devices to carbon nanotubes and compositions thereof
US10/632,284 US7304103B2 (en) 2001-01-29 2003-08-01 Process for making polymers comprising derivatized carbon nanotubes and compositions thereof
US10/632,419 US7691359B2 (en) 2001-01-29 2003-08-01 Carbon nanotubes derivatized with diazonium species
US11/840,433 US7892517B2 (en) 2001-01-29 2007-08-17 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US26478401P 2001-01-29 2001-01-29
US60/264,784 2001-01-29
US27290301P 2001-03-02 2001-03-02
US60/272,903 2001-03-02
US31650101P 2001-08-31 2001-08-31
US31652101P 2001-08-31 2001-08-31
US60/316,501 2001-08-31
US60/316,521 2001-08-31

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US10470517 A-371-Of-International 2002-01-29
US10/632,419 Division US7691359B2 (en) 2001-01-29 2003-08-01 Carbon nanotubes derivatized with diazonium species
US10/632,948 Division US7384815B2 (en) 2001-01-29 2003-08-01 Process for attaching molecular wires and devices to carbon nanotubes and compositions thereof
US10/632,284 Division US7304103B2 (en) 2001-01-29 2003-08-01 Process for making polymers comprising derivatized carbon nanotubes and compositions thereof

Publications (2)

Publication Number Publication Date
WO2002060812A2 WO2002060812A2 (fr) 2002-08-08
WO2002060812A3 true WO2002060812A3 (fr) 2002-11-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/002562 WO2002060812A2 (fr) 2001-01-29 2002-01-29 Processus de derivatisation de nanotubes de carbone avec des especes chimiques diazonium et compositions de celles-ci

Country Status (7)

Country Link
JP (1) JP4308527B2 (fr)
KR (1) KR20030091977A (fr)
CN (1) CN1309887C (fr)
AU (1) AU2002240159A1 (fr)
DE (1) DE10295944T5 (fr)
GB (2) GB2413123B (fr)
WO (1) WO2002060812A2 (fr)

Cited By (4)

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US7780918B2 (en) 2003-05-14 2010-08-24 Nantero, Inc. Sensor platform using a horizontally oriented nanotube element
KR101004819B1 (ko) * 2009-08-27 2010-12-28 삼성전자주식회사 경화성 작용기로 표면수식된 탄소나노튜브를 포함하는 조성물
US8506779B2 (en) 2007-06-07 2013-08-13 Sensor Innovations, Inc. Electrochemical sensors
US8758584B2 (en) 2010-12-16 2014-06-24 Sensor Innovations, Inc. Electrochemical sensors

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AU2002240159A1 (en) 2002-08-12
GB2389847A (en) 2003-12-24
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WO2002060812A2 (fr) 2002-08-08
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