WO2002058200A2 - Quantum dot lasers - Google Patents

Quantum dot lasers Download PDF

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Publication number
WO2002058200A2
WO2002058200A2 PCT/US2001/031256 US0131256W WO02058200A2 WO 2002058200 A2 WO2002058200 A2 WO 2002058200A2 US 0131256 W US0131256 W US 0131256W WO 02058200 A2 WO02058200 A2 WO 02058200A2
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WIPO (PCT)
Prior art keywords
quantum
laser
optical
inas
layer
Prior art date
Application number
PCT/US2001/031256
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French (fr)
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WO2002058200A9 (en
WO2002058200A3 (en
Inventor
Andreas Stintz
Petros N. Varangis
Kevin J. Malloy
Luke F. Lester
Timothy C. Newell
Hua Li
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Science & Technology Corporation @ Unm
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/961,560 external-priority patent/US6600169B2/en
Application filed by Science & Technology Corporation @ Unm filed Critical Science & Technology Corporation @ Unm
Priority to CA002423782A priority Critical patent/CA2423782A1/en
Priority to AU2002246489A priority patent/AU2002246489A1/en
Priority to JP2002558378A priority patent/JP2004528705A/en
Priority to EP01994056A priority patent/EP1354380A2/en
Priority to IL15502601A priority patent/IL155026A0/en
Publication of WO2002058200A2 publication Critical patent/WO2002058200A2/en
Priority to IL155026A priority patent/IL155026A/en
Publication of WO2002058200A9 publication Critical patent/WO2002058200A9/en
Publication of WO2002058200A3 publication Critical patent/WO2002058200A3/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y20/00Nanooptics, e.g. quantum optics or photonic crystals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/10Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • H01S5/12Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region the resonator having a periodic structure, e.g. in distributed feedback [DFB] lasers
    • H01S5/1228DFB lasers with a complex coupled grating, e.g. gain or loss coupling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/10Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • H01S5/14External cavity lasers
    • H01S5/141External cavity lasers using a wavelength selective device, e.g. a grating or etalon
    • H01S5/143Littman-Metcalf configuration, e.g. laser - grating - mirror
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/34Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
    • H01S5/341Structures having reduced dimensionality, e.g. quantum wires
    • H01S5/3412Structures having reduced dimensionality, e.g. quantum wires quantum box or quantum dash
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/40Arrangement of two or more semiconductor lasers, not provided for in groups H01S5/02 - H01S5/30
    • H01S5/4025Array arrangements, e.g. constituted by discrete laser diodes or laser bar
    • H01S5/4031Edge-emitting structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/40Arrangement of two or more semiconductor lasers, not provided for in groups H01S5/02 - H01S5/30
    • H01S5/4025Array arrangements, e.g. constituted by discrete laser diodes or laser bar
    • H01S5/4031Edge-emitting structures
    • H01S5/4043Edge-emitting structures with vertically stacked active layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/40Arrangement of two or more semiconductor lasers, not provided for in groups H01S5/02 - H01S5/30
    • H01S5/4025Array arrangements, e.g. constituted by discrete laser diodes or laser bar
    • H01S5/4087Array arrangements, e.g. constituted by discrete laser diodes or laser bar emitting more than one wavelength

Definitions

  • the present invention relates generally to self-assembled
  • the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is a semiconductor quantum dot lasers. More particularly, the present invention is
  • Quantum dot lasers are of interest for a variety of applications.
  • quantum dot of a quantum dot laser is a three dimensional quantum-confined
  • room temperature e.g., less than about 100 nanometers in many applications.
  • the quantum confinement produces quantum confined energy states within each
  • a quantum dot laser typically includes a substantial total number of
  • quantum dots within a gain producing region are quantum dots within quantum dots.
  • a quantum dot laser has a lower fill factor (volume of material to be pumped)
  • FIG. 1A shows a theoretical density of
  • FIG. IB shows the theoretical density of states function for a quantum
  • FIG. 1C shows the theoretical density of states
  • FIG. ID ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇
  • InAs tends to form islands when a
  • the InAs islands may be embedded
  • FIG. 2A shows
  • FIG. 2B shows measured current density versus cavity length for
  • wavelength is further blue shifted to about 1.05 microns.
  • maximum wavelength is shorter than desired, particularly for cavity lengths less
  • a wavelength of greater than 1.260 nanometers (1.260 microns) is desired. This is because a
  • wavelength of at least 1260 nanometers is of interest for use in the OC-48 and
  • OC-48 and OC-192 are optical carrier (OC) standards for fiber
  • OC-48 has a data rate of
  • OC-192 has a data rate of 9.952 Gbps.
  • the desired laser length depends upon the application.
  • the threshold gain, gth is a threshold gain
  • R is the facet reflectivity of both facets, and on is the internal optical loss.
  • micron long cavity with uncoated facets and preferably greater than 40 cm -1 for a
  • FIG. 2A it can be seen that the quantum dot laser structure disclosed by Lester,
  • et al. lases at a wavelength of about 1.05 microns for a cavity length of 500
  • microns or less associated with an abrupt jump to lasing at higher excited
  • quantum dot lasers may lack sufficient saturated modal gain at a desired
  • dot active regions having desirable optical gain characteristics.
  • the quantum dots are self-assembled InAs quantum dots formed in InGaAs quantum wells that are grown on a GaAs substrate by molecular beam epitaxy.
  • a first barrier layer of AlGaAs or GaAs is grown.
  • a first well layer of InGaAs is grown.
  • optical gain characteristics of the quantum dot layers are influenced by
  • compositional uniformity of surrounding layers the dot size distribution
  • dot density the number of layers of dots that can be placed in an active
  • the density of dots is adjusted by selecting the
  • the growth temperature also serves as the growth temperature of the dots.
  • the growth temperature also serves as the growth temperature of the dots.
  • the well to achieve a desired size distribution of the dots.
  • the well In one embodiment, the well
  • Indium alloy material has an Indium alloy composition of between about InO.15Gao.ssAs to
  • the growth temperature of the dots is selected
  • compositional uniformity of the composition is in the range of between about 450 °C to 540 °C .
  • the dots nucleate may have a thickness of about two nanometers or less
  • the in one embodiment has a thickness of about one nanometer.
  • the spatial uniformity of the dots is improved
  • the desorption step may be carried out at
  • the desoprtion is performed at a temperature of between 560 °C to 650 °C. In one embodiment, the desoprtion
  • quantum dots may be selected to prevent a blue-shift of the emission wavelength
  • cladding layers grown subsequent to the dots is selected to be less than 610 °C.
  • quantum dot lasers are formed having one or
  • the growth conditions are:
  • the layer structure and growth conditions are selected to
  • FIGS. 1A, IB, 1C, and ID illustrate the density of states function for
  • FIG. 2A is a prior art plot showing quantum dot light output intensity
  • FIG. 2B is a prior art plot showing threshold current versus laser cavity
  • FIG. 3 is a perspective view illustrating an idealized quantum dot layer
  • FIGS. 4A-4C each illustrate portions of a growth layer sequence form
  • FIG. 5 is an atomic force microscopy image of InAs quantum dots.
  • FIG. 6 shows plots of quantum dot density versus growth temperature
  • FIG. 7 is a plot showing photoluminescence intensity versus
  • FIG. 8 shows plots of photoluminescence intensity versus wavelength
  • FIG. 9 is a prior art plot of the surface segregated indium coverage for
  • FIG. 10 illustrates a growth sequence for pre-saturatihg a bottom
  • InGaAs well layer with a floating layer of indium InGaAs well layer with a floating layer of indium.
  • FIG. 11 A is a side view illustrating how size variation in the thickness
  • quantum dots may cause a portion of some quantum dots to protrude from
  • FIG. 11B illustrates a first growth sequence of layers with asymmetric
  • FIG. 11C illustrates a growth sequence of layer in which the quantum
  • dots are trimmed in thickness after the well layer is grown.
  • FIG. 12 illustrates a growth sequence for an active region having a
  • FIG. 13 shows a plot of a relationship for calculating a critical thickness
  • FIG. 14A shows a growth sequence for a quantum dot laser.
  • FIG. 14 B shows a conduction band diagram for the laser structure of
  • FIG. 14A is a diagrammatic representation of FIG. 14A.
  • FIG. 15 shows a growth sequence for a quantum dot laser
  • FIG. 16 shows plots of measured modal gain versus threshold current
  • FIG. 17 shows plots of ground state modal gain versus threshold
  • FIG. 18 shows a plot of modal gain versus threshold current density
  • FIG. 19 shows a growth sequence for quantum dot laser having a
  • sequence of quantum dot layers selected to achieve a high ground state modal
  • FIG. 20A illustrates transition energies for a single, ideal quantum dot.
  • FIG. 20B illustrates inhomogenous broadening of transition energies
  • FIG. 21 illustrates a method of forming a continuous quantum dot
  • optical gain spectrum over an extended wavelength range is optical gain spectrum over an extended wavelength range.
  • FIG. 22 shows plots of electroluminescence intensity versus
  • FIG. 23 shows plots of wavelength tuning range for quantum dot
  • FIG. 24 is a block diagram of a generic external cavity laser structure.
  • FIGS. 25A and 25B are block diagrams illustrating two external cavity
  • FIG. 26 is a perspective view of tunable laser.
  • FIG. 27A shows single wavelength laser structure with Bragg gratings.
  • FIG. 27B shows a comparison of wavelength response versus
  • FIG. 28 shows a multi-wavelength array of lasers having a quantum
  • FIG. 29 is a block diagram illustrating an embodiment in which the
  • multi-wavelength array of FIG. 28 is coupled by an optical multiplexer to an
  • optical fiber optical fiber
  • FIG. 30 shows plots of optical gain spectrum for an array at two
  • FIG. 31 is a side view of a quantum dot laser cavity.
  • the present invention is directed towards techniques for fabricating
  • gain characteristics including the density of the dots, size distribution of the
  • FIG. 3 is a perspective view of an idealized quantum dot layer 330
  • the individual quantum dots 320 comprise a low bandgap semiconductor material
  • quantum well layer 310 comprises a semiconductor with an intermediate
  • the barrier layers 305 comprise a high bandgap
  • the semiconductor materials preferably comprise III-V
  • the quantum dot layer may be included in
  • the laser structure may comprise a bottom optical
  • dots 320 will depend upon the optical gain characteristics of the ensemble of
  • quantum dots The modal gain of an active region including a single quantum
  • dot layer 330 or a sequence of quantum dot layers is the result of the cumulative
  • the modal gain as a function of wavelength is often described as the
  • An individual quantum dot 320 has an optical gain responsive to
  • dot can be modeled as a quantum box having a height, a width, and a length.
  • the height corresponds to the as-grown thickness of the dot.
  • n3 ⁇ Eo(n ⁇ 2 /Lx 2 + n ⁇ /Ly 2 + n 3 2 /Lz 2 ), where ni, nz, and n 3 each integers equal to or
  • each dot For an ensemble of dots, the size of each dot varies about
  • Embodiments of the present invention include growth techniques
  • FIGS. 4A-4C are diagrams of growth layer sequences illustrating
  • the arsenic flux is preferably chosen
  • a bottom barrier As shown in FIG. 4A, a bottom barrier
  • layer 402 is formed on a substrate 401.
  • the substrate is a GaAs substrate and bottom barrier layer 402 is a layer of GaAs or a layer of
  • a bottom well layer 404 preferably comprised of InGaAs, is deposited
  • Twl thickness of bottom well layer
  • the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the first layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the second layer 404 is between about 0.5 to 5 nanometers. In one embodiment, the
  • bottom barrier layer 402 is pre-saturated with an Indium floating layer of about
  • a dot layer preferably comprised of InAs.
  • monolayers of deposited InAs include the InAs deposited on the bottom well
  • thickness of the larger lattice constant material is grown upon an initial wetting
  • InAs islands 406 grow on the bottom InGaAs layer 404.
  • coveragage is used for denser and/or larger quantum dots.
  • a thin wetting layer is used for denser and/or larger quantum dots.
  • InAs may remain on the bottom InGaAs well layer 404 for some growth
  • 408 may have a thickness of between four to twelve nanometers. If desired, a
  • growth interruption may be performed after the dot layer to adjust the growth
  • a top barrier layer 410 of GaAs or AlGaAs is then grown to complete
  • layers may be selected to preserve the optical quality of the quantum dots.
  • the bandgap of an InGaAs well is intermediate between that of InAs
  • the Iri ⁇ Ga ⁇ - ⁇ As has an alloy fraction of between about 0.1 to 0.3.
  • Each quantum dot consists of an
  • FIG. 5 is an atomic force microscopy image showing a perspective
  • the dots have a mean diameter of between about 20
  • the dots have a width-to-
  • the dots have a size distribution such that the dots can be characterized by a mean size and an associated variance. Over a sufficiently large area, the dots in a layer of
  • dots can also be characterized by a dot density (e.g., dots per unit area).
  • FIG. 6 is a plot of quantum dot density versus growth temperature for
  • the dot density can be achieved at a growth temperature of about 470 °C.
  • the dot density is at least a
  • the InGaAs alloy composition is increased from Ino. ⁇ Gao. As to Ino. 2 Gao.sAs.
  • the bottom well layer need only have a
  • the bottom well layer may have a thickness as low as 0.5 nm
  • the quantum dot density may be selected over a
  • the growth temperature increases. Additionally, the dot size increases and the dot density
  • the variance in dot size may be inferred from photoluminescence measurements
  • a series of quantum dots may be grown under different temperature
  • FIG. 7 shows photolumiscence measurements of
  • the change in photoluminescence is attributed to decomposition of the upper (capping) well layer at elevated temperatures.
  • the layer is selected to improve the optical quality of the quantum dot layer.
  • the growth temperature of the upper well layer is
  • FIG. 8 shows
  • the quantum dot layers e.g., a growth temperature of AlGaAs cladding layers of
  • bottom layer 404 have a reproducible InGaAs alloy compositon. This is, in part, due to the strong dependence of dot density on the InGaAs alloy composition of
  • InGaAs include indium, such as GaAs or AlGaAs, that the InGaAs may have a graded
  • FIG. 9 shows a
  • InGaAs may have to be grown to reach steady state conditions if the initial
  • FIG. 10 shows an embodiment of a growth sequence in which the
  • the equilibrium monolayer coverage (e.g., about one monolayer equivalent of
  • the bottom well layer 404 is then grown. As indicated in FIG. 9, if
  • the InGaAs layer begins with an indium monolayer coverage close to its
  • a bottom well layer 404 may be grown having a thickness of
  • bottom well layer 404 bottom well layer
  • monolayer coverage for forming InAs dots 406 includes the InAs monolayers
  • quantum dots is 2.4 monolayers and one monolayer of InAs is deposited as a
  • FIG. 11A illustrate a portion of the growth process after the top InGaAs well
  • protruding portions 1105 that are not embedded within top well layer 408 unless
  • well layer 408 is made thicker than the largest thickness variation of islands 406.
  • protruding portions 1105 may reduce the optical quality of the structure
  • protruding portions 1105 may cause a substantial change in the optical
  • FIG. 1 IB is a side view showing a layer sequence for ensuring that the
  • quantum dots are completely embedded in the quantum well.
  • the thickness, d 2 , of the upper well layer 408, is
  • d 2 is much thicker than the thickness, di, of lower well layer 404.
  • the thickness of bottom well layer 404 is selected to be as thin
  • lower well layer 404 may have a nominal
  • thickness of 2 nanometers and the upper well layer 408 may have a nominal
  • FIG. 11C illustrates a growth sequence for an embodiment in which
  • protruding portions 1105 of dots 406 are removed using a desorption step.
  • GaAs may be grown prior to the desorption process. The growth is resumed
  • Photoluminescence or other characterization techniques may be used
  • Typical times and temperatures are a desorption temperature of 590 °C for
  • the temperature is selected so that a GaAs surface is stable
  • the desorption step ensures that the resulting quantum dots 406 do not
  • thickness of the as-grown islands is selected to be greater than the thickness of
  • emission wavelengths of commercial interest such as emission wavelengths
  • FIG. 12 shows a growth layer sequence and layer thicknesses for an
  • active region 1200 of an optical device It will be understood that active region
  • 1200 may comprise part or all of a waveguide core within other optical
  • layers having a low strain-thickness product facilitates stacking four or more
  • An InGaAs layer grown on a GaAs substrate is a strained layer. If the
  • strain-thickness product of the strained layer is sufficiently low, a high quality
  • strained layer may be achieved. However, if the strain-thickness product is
  • FIG. 13 is a plot of the commonly used Matthews-Blakeslee
  • uniform alloy composition (which may be used to calculate a lower bound for an
  • Curve 1305 is a curve indicating a critical
  • Blakeslee curve 1305 indicates that a single quantum dot layer having an average
  • composition of well layers and dots of Ino. 2 Gao.sAs has a critical thickness of at
  • an average strain-thickness product should be below a threshold average
  • strain (e.g., 0.5%).
  • EwTw EwTw
  • strain thickness product of an individual barrier layer is EbTb, where Eb
  • Tb is the thickness of the barrier layer.
  • Equation 1 can be re-expressed as a relationship between the barrier
  • ⁇ b nTw(Ew-Eav) 3
  • the barrier thickness is:
  • Equation 4 can be used to derive a relationship for a minimum barrier
  • quantum dot layers is about 20 nanometers.
  • the quantum dots may be utilized in a variety of laser structures.
  • AlGaAs cladding layers 3120 and 3125 may be
  • optical cavity may be provided using any suitable means, such as reflective facets
  • Lateral optical confinement may be provided using any combination
  • a ridge waveguide may be used to provide lateral
  • Individuals lasers may be fabricated as Fabry-Perot lasers,
  • distributed bragg reflector lasers distributed feedback lasers, or external cavity
  • the size of the quantum dots may be selected to provide gain
  • FIG. 14A is an illustration of a growth sequence for a laser having a
  • FIG. 14B shows a corresponding conduction
  • FIG. 14A an n-type GaAs buffer layer is grown on a GaAs substrate.
  • a presaturation layer which is preferably undoped to reduce absorption losses.
  • the growth temperature is adjusted to approximately
  • layer 1440 is then grown. In one embodiment, several monolayers of GaAs are
  • the growth interruption step preferably
  • cladding layer 1450 is then grown, followed by a GaAs cap layer 1455.
  • Layers 1410, 1420, 1430, 1440, and 1445 form a waveguide core region
  • the p-type layers, undoped layers, n-type layers form a p-i-n laser
  • well layers 1420 and 1440 provide an additional benefit of providing a means to
  • individual quantum dot layer is low, typically less than 10%, depending upon
  • the dot density and mean dot size are less than 5%.
  • the well layer of the quantum wells may enter the quantum dots.
  • barrier layers of the quantum well also serve to reduce
  • FIG. 15 shows a similar layer sequence as FIG. 14. However, as
  • the growth temperature of the active region may be varied
  • FIG. 16 shows plots of measured modal gain versus current density for
  • ground state modal gain increases approximately linearly with dot density.
  • FIG. 17 shows plots of ground state modal gain for a laser structure
  • FIG. 18 shows a plot 1805 of modal gain versus
  • quantum dot layers a 10 nanometer thick barrier layer.
  • the quantum dot layers a 10 nanometer thick barrier layer.
  • quantum dot layers are spaced sufficiently close that the optical confinement for
  • each layer of quantum dots is about the same as for a single layer of quantum
  • the growth conditions and layer sequence of a quantum dot laser may
  • This wavelength may be achieved by designing
  • the laser to operate off of the ground state (longest wavelength emission) and by
  • cap layer and thick cladding are appropriately selected to minimize blue-shifting as described above.
  • One benefit of the quantum dot layers of the present invention is that
  • the linewidth enhancement factor can be expressed mathematically as:
  • the low linewidth enhancement factor correspondingly reduces wavelength
  • the present invention attractive for applications in which the laser has a wavelength
  • fr , where P is the photon density, ⁇ the effective
  • a laser that is directly modulated at high data rates which implies a cavity length of less than 500 microns and preferably no more than 300 microns.
  • the saturated ground state modal gain should be at least about 25 c ⁇ r 1 for a 500
  • lasers be operated at a threshold gain that is selected to be sufficiently below the threshold gain
  • plurality of quantum dot layers are preferably included within a waveguide core
  • a thickness between 200 to 300 nanometers corresponds to a distance comparable
  • AlGaAs waveguiding layers for which a high optical confinement per quantum
  • dot layer may be achieved). Since a saturated ground state modal gain of greater
  • quantum dot layers in the range of four to eight is sufficient for many
  • FIG. 19 An exemplary growth sequence of a laser having 4 to 8 quantum dot layers is shown in FIG. 19. The total
  • waveguide core thickness is preferably in the range of about 200 to 300
  • the corresponding AlGaAs cladding layers are preferably ALGai ⁇ As
  • AlGaAs cladding layers may be grown with a lower
  • the laser may be a ridge waveguide laser
  • quantum dot layer with as high a dot size uniformity (minimal inhomogenous
  • quantum dot layer laser the growth sequence of each quantum dot layer is
  • saturated ground state modal gain may be desirable to facilitate wavelength
  • FIG. 20A is an illustrative diagram of optical transition energies for a
  • An individual quantum dot has quantum confined energy
  • transition energy transition energy, a first excited state transition energy, a second excited state
  • transition energy and possibly additional transition energies, depending upon
  • quantum dots are pumped, homogeneous broadening will also occur.
  • the homogenous broadening may be
  • inhomogenous broadening may more than double the width of the gain
  • a lasing-mode photon will receive gain from not only the
  • transition energies that is between about 30 to 80 meV.
  • transition energies that is between about 30 to 80 meV.
  • growth conditions may be selected to vary the mean size of the
  • the growth conditions are:
  • the inhomogeneous broadening is selected to be any one of the inhomogeneous broadening.
  • the inhomogeneous broadening is selected to any one of the inhomogeneous broadening.
  • the inhomogeneous broadening is selected to be about 20-30 meV below the
  • a semiconductor laser including a quantum dot active region may be
  • FIG. 21 is an illustrative plot 2110 of cavity optical gain (e 2 s L where g is
  • a quantum dot active region may be designed to have a ground state quantum
  • a resonator loss that includes a mirror loss and an absorption loss. If an extended
  • the drive current is selected to populate the excited
  • the first excited quantum states e.g., first excited state 2110
  • length and width of the dots may be designed to provide additional higher
  • the second excited state transition energy is selected to permit a continuous
  • optical gain spectrum of at least 150 nanometers for a maximum threshold current density is preferably selected to at least saturate the
  • the growth parameters of the dots in different layers may be adjusted such
  • each layer of quantum dots has a different sequence of optical transition
  • first quantum dot layer could have a first ground state transition energy
  • the second quantum dot layer has associated excited state transition energy levels.
  • dot characteristics e.g., size, shape, and composition
  • FIG. 22 is plot of amplified spontaneous emission intensity versus
  • FIG. 14B and having a single quantum dot layer.
  • the nominal dot height is
  • the front facet is anti-reflection
  • Plot 2205 is for a drive current of 500 mA
  • plot 2210 is for a drive current of 600 mA
  • plot 2215 is for a drive current of 700 mA. The drive current for all
  • the drive current is sufficiently large that excited quantum dot states are
  • FIG. 23 is an illustrative plot of tuning range versus current density for
  • quantum dot plot 2380 is based upon experimental data of the inventors. The
  • quantum well plot 2390 is based upon various numbers published in the
  • quantum dot lasers permit about 70 nm of
  • quantum well lasers used in tunable lasers are commonly
  • present invention may be tuned to greater than 150 nm (e.g., greater than 200
  • single quantum dot laser to be used to achieve a tuning range of 180 nanometers
  • a quantum dot laser of the present invention may be used as the active
  • FIG. 24 is a top view of a generic
  • the threshold condition for lasing is that the summation of
  • a wavelength selector 2440 is included that
  • laser diode 2402 retains a high reflectivity whereas a front facet 2410 is processed
  • g is the gain per unit length of the laser diode
  • ⁇ i is the
  • ⁇ e the reflectivity of the wavelength selector
  • the wavelength selector may be any wavelength of the external cavity, and L2 is the effective length of the external cavity.
  • a function of wavelength may be controlled such as to limit the optical feedback
  • an external cavity semiconductor laser typically one facet of a
  • An external grating is typically
  • the laser cavity are preferably selected to suppress Fabry-Perot (FP) modes in
  • Fabry-Perot modes from the cleaved facets over a range of wavelength may also be used.
  • reflectivity of the AR coated facet is selected so that the laser is incapable of lasing off the ground state and at least the first excited state of the quantum dots
  • saturated laser gain for the ground state should be selected to be greater than the
  • the grating selected wavelength only depletes the optical gain within
  • g P peak gain at high quantum states
  • FIG. 25B is an illustration of a
  • FIG. 25A is an illustration of a Littrow laser cavity
  • grating 2530 from the laser 2510 is such that the beam is reflected back to the
  • grating determines the wavelength.
  • An etalon is sometimes included in a Littrow configuration to decrease the cavity bandwidth. In the Littman-Metcalf
  • the grating 2530 diffracts the light towards a tuning mirror
  • Collimating lenses 2505 are typically included in an external cavity laser to
  • T&M testing & monitoring
  • T&M applications must have a maximum operating current selected to achieve a
  • quantum well lasers using quantum well gain medium the quantum well lasers have useful
  • the quantum dot lasers of the present invention have a
  • present invention may be used in laser structures having an integrated
  • wavelength selector element to tune the lasing wavelength.
  • a variety of other semiconductor laser structure with wavelength selector elements are known in
  • DBR distributed Bragg reflector
  • DFB distributed feedback laser structures
  • DBR lasers include a grating that define a Bragg wavelength condition given by
  • is the grating period
  • n is the refractive index of the material
  • the Bragg wavelength condition defines a
  • laser may be modified to include a quantum dot active region 2630 of the present
  • quantum dot active region may be temperature tuned. Referring to FIG. 27A, a
  • distributed feedback laser having a quantum dot active region 2705 may include
  • the temperature dependence of the refractive index causes a shift in the Bragg wavelength of about 0.1 nm/°C.
  • the gain peak In conventional 1.3 micron lasers the gain peak
  • the DFB laser tends to have too high a threshold current or has poor mode
  • FIG. 27B shows the shift in
  • Quantum dot active regions have a delta function density of states
  • quantum dots have a measured shift in peak gain of
  • the Bragg wavelength is selected to operate on the
  • the quantum dot active region of the present invention may also be any quantum dot active region of the present invention.
  • FIG. 28 is a perspective
  • Each laser 2820 may be
  • Each laser has a longitudinal cavity
  • a conventional cleaving or etching process may be used to form a
  • the array 2800 is formed on a common substrate 2805 having a
  • quantum dot active region 2810 The growth parameters of the quantum dot
  • active region 2810 are selected to achieve a desired wavelength tuning range
  • Each laser is a laser (e.g., 100 to 200 nm) within a desired range of current densities.
  • a DFB or DBR laser having at least one grating section 2830 with the
  • array 2800 may be used for wide wavelength division
  • WWDM multiplexed
  • array 2800 could be used to cover the wavelength range of 1270 nanometers to 1355 nanometers (e.g., a 75-85 nanometer range).
  • array 2800 could be used to cover the wavelength range of 1270 nanometers to 1355 nanometers (e.g., a 75-85 nanometer range).
  • array 2800 also permits each laser to be directly modulated at high data rates.
  • lasers should have a linewidth enhancement factor that is approximately a factor
  • dot lasers at high data rates (e.g., 10 - 40 Gbit/s) with acceptable chirp. This is in
  • present invention facilitate direct laser modulation. Typically, directly
  • modulated high-frequency lasers require drive currents that are several times the
  • multiwavelength array 2800 facilitates direct modulation at high data rates.
  • each laser of the multiwavelength array is directly modulated by varying its drive current. This eliminates the needs for
  • MUX optical combiner
  • each laser is driven by a wire bond.
  • a wire bond has a parasitic inductance such that long lengths of bonding wire
  • microwave transmission lines are fabricated on array 2900 to facilitate coupling
  • array 2900 is
  • submount mounted on a submount adapted to provide microwave current to each laser.
  • temperature tuning may be used to fine-tune the wavelength of a large
  • FIG. 30 illustrates a gain spectrum for two different
  • the nominal DFB wavelengths at a first temperature, Ti are selected to cover an upper wavelength range of the gain
  • Another benefit of array 280 is that the low threshold current density
  • characteristics of array 2800 may facilitate operating the array junction up, i.e.,
  • junction down configuration (epitaxial layer mounted to the heat sink) has less
  • thermal resistance but typically increased the packaging complexity and cost.
  • array 2800 is that for some applications, such as WWDM,
  • the need for the heat sink to be cooled may be eliminated.

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Abstract

A quantum dot active region is disclosed in which quantum dot layers are formed using a self-assembled growth technique. In one embodiment, growth parameters are selected to control the dot density and dot size distribution to achieve desired optical gain spectrum characteristics. In one embodiment, the distribution in dot size and the sequence of optical transition energy values associated with the quantum confined states of the dots are selected to facilitate forming a continuous optical gain spectrum over an extended wavelength range. In another embodiment, the optical gain is selected to increase the saturated ground state gain for wavelengths of 1260 nanometers and greater. In other embodiments, the quantum dots are used as the active region in laser devices, including tunable lasers and monolithic multi-wavelength laser arrays.

Description

QUANTUM DOT LASERS
STATEMENT AS TO FEDERALLY SPONSORED RESEARCH AND
DEVELOPMENT
[0001] The U.S. Government may have certain rights in this invention
pursuant to research conducted under the following grants: Grant No. F49620-
95-1-0530 awarded by the Air Force Office Of Science and Research, Grant No.
DAALOl-96-02-0001 awarded by the Army Research Lab, Grant No. F4920-99-1-
330 awarded by the Air Force Office of Science and Research, and Grant No.
MDA972-98-1-0002 awarded by the Defense Advanced Research Projects
Agency.
RELATED APPLICATIONS
[0002] This application claims priority under 35 U.S.C.§ 119(e) to the
following United States Patent Application Nos.: 60/238,030 entitled "Broadband
Continuously Tunable-Wavelength Quantum Dot and Quantum Dash
Semiconductor Lasers with Low-Threshold Injection Current" filed October 6,
2000; 60/252,084 entitled "Quantum Dot and Quantum Dash Semiconductor
Lasers For Wavelength Division Multiplexing (WDM) System Applications" filed November 21, 2000; 60/276,186, entitled "Semiconductor Quantum Dot Laser
Active Regions Based On Quantum Dots in a Optimized Strained Quantum
Well," filed March 16, 2001; 60/272,307, entitled "Techniques for Using
Quantum Dot Active Regions In Vertical Cavity Surface Emitting Lasers," filed
March 2, 2001; and Attorney Docket No. 22920-06322, entitled "Quantum Dot
And Quantum Dash Active Region Devices," filed August 31, 2001 (Application
number not received from the United States Patent and Trademark Office at the
time of filing of the instant application). The contents of all of the above
applications are hereby each incorporated by reference in their entirety in the
present patent application.
[0003] This application is also related to Attorney Docket No. 22920-6391
"Quantum Dash Devices," by Stintz et al., filed in the United States Patent and
Trademark Office on September 20, 2001, commonly owned by the assignee of
the present patent application, the contents of which are hereby incorporated by
reference in their entirety.
BACKGROUND OF THE INVENTION
1. Field of the Invention [0004] The present invention relates generally to self-assembled
semiconductor quantum dot lasers. More particularly, the present invention is
directed towards quantum dot lasers with improved optical gain characteristics.
2. Description of Background Art
[0005] Quantum dot lasers are of interest for a variety of applications. Each
quantum dot of a quantum dot laser is a three dimensional quantum-confined
heterostructure which confines electrons and holes in a region having a size,
along each of three dimensions, that is less than a thermal de Broglie wavelength
at room temperature (e.g., less than about 100 nanometers in many applications).
The quantum confinement produces quantum confined energy states within each
dot for electrons and holes. There are also corresponding optical transition
energies for both electrons and holes associated with a ground state transition
energy, first excited state transition energy, second excited state transition
energy, etc. A quantum dot laser typically includes a substantial total number of
quantum dots within a gain producing region.
[0006] Theoretical studies indicate that quantum dot lasers have many
potential performance advantages over conventional quantum well lasers. First,
a quantum dot laser has a lower fill factor (volume of material to be pumped)
and an improved density of states function compared with a quantum well laser. Referring to FIG. 1, the theoretical density of states function becomes sharper as
the carrier dimensionality decreases. FIG. 1A shows a theoretical density of
states function for a bulk material, which has a square root dependence on
energy. FIG. IB shows the theoretical density of states function for a quantum
well (one dimension of quantum confinement) that increases in steps at each
quantum well energy level. FIG. 1C shows the theoretical density of states
function for a quantum wire (two dimensions of quantum confinement). FIG. ID
shows the theoretical density of states function for a quantum dot (three
dimensions of quantum confinement) that has a delta-like density of states
function (e.g., a finite number of states available only at the quantum dot).
Theoretical calculations indicate that the threshold current of a semiconductor
laser may be improved by using quantum dot active regions due to the smaller
volume of material and reduced number of states.
[0007] One technique to fabricate a quantum dot laser exploits the tendency
of strained layer semiconductors to form islands when the strain exceeds a
certain threshold strain. In particular, InAs tends to form islands when a
sufficient thickness of InAs is grown on a layer that is psuedomorphically
strained on a GaAs substrate due to strain associated with the difference in
relaxed lattice constant of the two materials. The InAs islands may be embedded
in another layer, such as a GaAs quantum well, to form quantum dots. [0008] Self-assembled quantum dot lasers having a low threshold current
density are disclosed by Lester, et. al. in the article entitled "Optical
Characteristics of 1.24-μm InAs Quantum Dot Laser Diodes," IEEE Photonics
Technology Letters, Vol. 11, No. 8, August (1999). The quantum dot laser
structure disclosed in this reference includes a single layer of InAs quantum dots
formed by a self-assembled growth process on a GaAs substrate. FIG. 2A shows
measured laser spectra for different cavity lengths for the quantum dot lasers of
Lester, et al. FIG. 2B shows measured current density versus cavity length for
conventional Fabry-Perot lasers having uncoated facets.
[0009] Referring to FIG. 2B, the lowest threshold current density operation
occurs for a cavity length of almost 3.94 millimeters, for which an emission
wavelength of 1.24 microns was achieved. The emission wavelength at 1.24
microns is attributed to a ground state transition energy. When the cavity length
is reduced to less than about one millimeter, the lasing wavelength blue-shifts to
below 1.15 microns, which is attributed to lasing off of the first excited state.
When the cavity length is further reduced to about 500 microns, the emission
wavelength is further blue shifted to about 1.05 microns.
[0010] One drawback of the quantum dot lasers of Lester, et al., is that the
maximum wavelength is shorter than desired, particularly for cavity lengths less
than one millimeter. In a variety of commercial applications, a wavelength of greater than 1.260 nanometers (1.260 microns) is desired. This is because a
wavelength of at least 1260 nanometers is of interest for use in the OC-48 and
OC-192 standard compliant lasers used in short and medium length optical
network links. OC-48 and OC-192 are optical carrier (OC) standards for fiber
optic networks conforming to the SONET standard. OC-48 has a data rate of
2.4888 Gbps whereas OC-192 has a data rate of 9.952 Gbps.
[0011] Another drawback of the quantum dot lasers of Lester, et al. is that the
modal gain of the ground state is lower than desired, making it impractical to
design short-cavity lasers that lase from the ground state transition energy level.
The desired laser length depends upon the application. First, many
commercially available packages are designed for a cavity length no greater than
500 microns. Second, directly modulated lasers with conventional facet coatings
must typically have a cavity length less than 500 microns, and preferably less
than about 300 microns, in order to have a photon lifetime that is sufficiently
short to permit high speed direct current modulation. The threshold gain, gth,
of the Fabry-Perot lasers is
Figure imgf000007_0001
where Lcav is the length of the
cavity, R is the facet reflectivity of both facets, and on is the internal optical loss.
This corresponds to a minimum modal gain of at least 25 cm-1 for a typical 500
micron long cavity with uncoated facets and preferably greater than 40 cm-1 for a
typical 300 micron long cavity with uncoated facets. Unfortunately, the ground state saturated gain reported by Lester, et. al., is less than 9 cm-1. Referring to
FIG. 2A, it can be seen that the quantum dot laser structure disclosed by Lester,
et al. lases at a wavelength of about 1.05 microns for a cavity length of 500
microns or less, associated with an abrupt jump to lasing at higher excited
energy states.
[0012] A general problem with self-assembled quantum dot fabrication
processes is that heretofore the growth processes have not been understood well
enough to adjust quantum dot parameters that determine the optical gain
characteristics. Consequently, the optical gain spectrum of self -assembled
quantum dot lasers may lack sufficient saturated modal gain at a desired
wavelength, have a larger than desired separation between the ground state and
excited state transition energies, or have either too little or too much
inhomogenous broadening.
[0013] What is needed are techniques for forming self-assembled quantum
dot active regions having desirable optical gain characteristics.
SUMMARY OF THE INVENTION
[0014] Techniques for forming optical devices having layers of quantum dots
having desirable optical gain characteristics are disclosed. In one embodiment,
the quantum dots are self-assembled InAs quantum dots formed in InGaAs quantum wells that are grown on a GaAs substrate by molecular beam epitaxy.
A first barrier layer of AlGaAs or GaAs is grown. A first well layer of InGaAs is
grown on the first barrier layer. A sufficient monolayer equivalent thickness of
InAs is grown on the InGaAs to form self-assembled islands. A second well
layer of InGaAs is grown over the InAs islands to embed the quantum dots. A
second AlGaAs or GaAs barrier layer is then grown to complete the quantum
well. The optical gain characteristics of the quantum dot layers are influenced by
the compositional uniformity of surrounding layers, the dot size distribution, the
dot density, and the number of layers of dots that can be placed in an active
region without exceeding a critical thickness for forming dislocations.
[0015] In one embodiment, the density of dots is adjusted by selecting the
composition of the underlying well material that the dots nucleate on and by
selecting the growth temperature of the dots. The growth temperature also
influences the size distribution of the dots such that in one embodiment the
temperature and equivalent monolayer coverage of InAs for the dots is selected
to achieve a desired size distribution of the dots. In one embodiment, the well
material has an Indium alloy composition of between about InO.15Gao.ssAs to
Ino.2oGao.sAs. In one embodiment the growth temperature of the dots is selected
to be in the range of between about 450 °C to 540 °C . [0016] In one embodiment, the compositional uniformity of the
underlying InGaAs is improved by depositing a floating layer of InAs to pre-
saturate the InGaAs, thereby permitting an extremely thin bottom well layer to
be grown prior to dot formation. The underlying bottom well layer of InGaAs
that the dots nucleate may have a thickness of about two nanometers or less, and
in one embodiment has a thickness of about one nanometer.
[0017] In one embodiment the spatial uniformity of the dots is improved
by performing a desorption process to desorb excess InAs from the top InGaAs
well layer that is grown over the dots. The desorption step may be carried out at
a temperature of between 560 °C to 650 °C. In one embodiment, the desoprtion
process is continued for a sufficient length of time to planarize portions of InAs
dots extending above the top InGaAs well layer, thereby improving the
uniformity of the InAs dots.
[0018] The growth temperature of layers grown subsequent to the
quantum dots may be selected to prevent a blue-shift of the emission wavelength
of the dots to shorter wavelength. In one embodiment, the growth temperature
of cladding layers grown subsequent to the dots is selected to be less than 610 °C.
[0019] In one embodiment, quantum dot lasers are formed having one or
more quantum dot layers. In one embodiment, the growth conditions are
selected to achieve a size distribution of the dots that produces substantial inhomogenous broadening of the optical gain spectrum, which is beneficial for
tunable laser and arrays of lasers having a wide range of operating wavelength.
In another embodiment, the layer structure and growth conditions are selected to
achieve a saturated ground state modal gain greater than about 25 cm-1.
BRIEF DESCRIPTION OF THE DRAWINGS
[0020] FIGS. 1A, IB, 1C, and ID illustrate the density of states function for
bulk semiconductors, quantum wells, quantum wires, and quantum dots,
respectively.
[0021] FIG. 2A is a prior art plot showing quantum dot light output intensity
versus wavelength for quantum dot lasers of various lengths.
[0022] FIG. 2B is a prior art plot showing threshold current versus laser cavity
length for the lasers of FIG. 2A.
[0023] FIG. 3 is a perspective view illustrating an idealized quantum dot layer
of quantum dots embedded in a quantum well.
[0024] FIGS. 4A-4C each illustrate portions of a growth layer sequence form
forming quantum dot layers.
[0025] FIG. 5 is an atomic force microscopy image of InAs quantum dots. [0026] FIG. 6 shows plots of quantum dot density versus growth temperature
for two different compositions of a nucleation layer.
[0027] FIG. 7 is a plot showing photoluminescence intensity versus
wavelength of quantum dots for several different capping layer growth
temperatures.
[0028] FIG. 8 shows plots of photoluminescence intensity versus wavelength
of quantum dots for several different annealing temperatures and times.
[0029] FIG. 9 is a prior art plot of the surface segregated indium coverage for
different nominal InGaAs growth thicknesses.
[0030] FIG. 10 illustrates a growth sequence for pre-saturatihg a bottom
InGaAs well layer with a floating layer of indium.
[0031] FIG. 11 A is a side view illustrating how size variation in the thickness
of quantum dots may cause a portion of some quantum dots to protrude from
the quantum well into the barrier layer.
[0032] FIG. 11B illustrates a first growth sequence of layers with asymmetric
placement of dots within the well to facilitate embedding quantum dots in wells.
[0033] FIG. 11C illustrates a growth sequence of layer in which the quantum
dots are trimmed in thickness after the well layer is grown.
[0034] FIG. 12 illustrates a growth sequence for an active region having a
plurality of quantum dot layers. [0035] FIG. 13 shows a plot of a relationship for calculating a critical thickness
for a single layer.
[0036] FIG. 14A shows a growth sequence for a quantum dot laser.
[0037] FIG. 14 B shows a conduction band diagram for the laser structure of
FIG. 14A.
[0038] FIG. 15 shows a growth sequence for a quantum dot laser with
preferred temperature ranges for growing each layer.
[0039] FIG. 16 shows plots of measured modal gain versus threshold current
density for quantum dot laser having two different quantum dot densities.
[0040] FIG. 17 shows plots of ground state modal gain versus threshold
current density for quantum dot lasers having a single layer of quantum dots
with three different compositions of the InGaAs quantum well.
[0041] FIG. 18 shows a plot of modal gain versus threshold current density
for a quantum dot lasers having one and three layers of quantum dots.
[0042] FIG. 19 shows a growth sequence for quantum dot laser having a
sequence of quantum dot layers selected to achieve a high ground state modal
gain.
[0043] FIG. 20A illustrates transition energies for a single, ideal quantum dot.
[0044] FIG. 20B illustrates inhomogenous broadening of transition energies
associated with variance in quantum dot size for an ensemble of dots. [0045] FIG. 21 illustrates a method of forming a continuous quantum dot
optical gain spectrum over an extended wavelength range.
[0046] FIG. 22 shows plots of electroluminescence intensity versus
wavelength for a quantum dot laser structure with three different driver currents
selected to achieve a continuous optical gain spectrum over and extended
wavelength range.
[0047] FIG. 23 shows plots of wavelength tuning range for quantum dot and
quantum well lasers versus current.
[0048] FIG. 24 is a block diagram of a generic external cavity laser structure.
[0049] FIGS. 25A and 25B are block diagrams illustrating two external cavity
laser arrangements.
[0050] FIG. 26 is a perspective view of tunable laser.
[0051] FIG. 27A shows single wavelength laser structure with Bragg gratings.
[0052] FIG. 27B shows a comparison of wavelength response versus
temperature for conventional quantum well active regions and quantum dot
active regions compared with the wavelength response of a Bragg grating.
[0053] FIG. 28 shows a multi-wavelength array of lasers having a quantum
dot active region. [0054] FIG. 29 is a block diagram illustrating an embodiment in which the
multi-wavelength array of FIG. 28 is coupled by an optical multiplexer to an
optical fiber.
[0055] FIG. 30 shows plots of optical gain spectrum for an array at two
different operating temperature with corresponding DFB wavelengths
superimposed.
[0056] FIG. 31 is a side view of a quantum dot laser cavity.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0057] The present invention is directed towards techniques for fabricating
self-assembled layers of quantum dots for optical devices, including techniques
for improved control of quantum dot characteristics that determine the optical
gain characteristics, including the density of the dots, size distribution of the
dots, uniformity of the dots, position of dots within wells, and the strain-
thickness product that limits the spacing between neighboring layers of quantum
dots. Additionally, laser structures are disclosed having improved optical gain
characteristics.
[0058] FIG. 3 is a perspective view of an idealized quantum dot layer 330
that includes a multiplicity of individual quantum dots 320 embedded in a
quantum well layer 310 sandwiched between barrier layers 305. The individual quantum dots 320 comprise a low bandgap semiconductor material, the
quantum well layer 310 comprises a semiconductor with an intermediate
bandgap energy, and the barrier layers 305 comprise a high bandgap
semiconductor material. The semiconductor materials preferably comprise III-V
compound semiconductors.
[0059] It will be understood that the quantum dot layer may be included in
the active region of a p-i-n laser diode structure that includes an optical
waveguide structure to provide optical confinement for light generated in the
active region. For example, the laser structure may comprise a bottom optical
cladding layer grown having a first doping polarity; a first undoped
waveguiding core layer; a quantum dot active region, a second undoped
waveguiding core layer, and a top optical cladding layer of a second doping
polarity.
[0060] The macroscopic optical gain provided by a multiplicity quantum
dots 320 will depend upon the optical gain characteristics of the ensemble of
quantum dots. The modal gain of an active region including a single quantum
dot layer 330 or a sequence of quantum dot layers is the result of the cumulative
gain of the ensemble of dots within the active region and the coupling (often
known as the "optical confinement" for transverse optical waveguide modes) of
light to the quantum dots 320 due to other waveguiding layers (not shown in FIG. 3). The modal gain as a function of wavelength is often described as the
"optical gain spectrum."
[0061] An individual quantum dot 320 has an optical gain responsive to
an injected current associated with optical transitions of its quantum-confined
states. A single, ideal quantum dot would have a sharp atomic-like density of
states and would have an emission spectrum having sharp peaks at transition
energies determined by the size of the dot. Homogeneous broadening occurs
due to the effects of injected current, resulting in a broadening of the emission
energy from an individual dot by more than 20 meV.
[0062] Inhomogeneous broadening of the transition energies of an
ensemble of quantum dots occurs due to the influence of dot size. A quantum
dot can be modeled as a quantum box having a height, a width, and a length.
The height corresponds to the as-grown thickness of the dot. The width and
length correspond to the dimensions in the plane of the well. As is well known,
to a first order approximation, the first confined quantum states along each
dimension of an ideal quantum box have energy levels that vary inversely with
the square of the length, i.e. the energy levels, E ni,n2,n3, of an ideal quantum box
with infinite barriers having a length Lx, a width Ly, and a height Lz is: E nι,n2,
n3=ΔEo(nι2/Lx2 + n^/Ly2 + n3 2/Lz2), where ni, nz, and n3 each integers equal to or
greater than 1 and ΔEois a material constant. For a quantum box with finite energy barriers, the separation in energy between quantum states tends to vary '
more slowly due to the penetration of the quantum mechanical wave function
into the barrier layers. For an ensemble of dots, the size of each dot varies about
a mean value, broadening the quantum confined energy levels for electrons and
holes in each dot.
[0063] Embodiments of the present invention include growth techniques
that permit improved control over the characteristics of individual dots,
individual quantum dot layers, and sequences of quantum dot layers. As
described below in more detail, these techniques facilitate forming laser
structures with desirable optical gain characteristics for various device
applications.
[0064] FIGS. 4A-4C are diagrams of growth layer sequences illustrating
some of the steps used to form self-assembled quantum dots layers, although it
will be understood that additional layers (e.g., waveguiding layers) may be
required to form a complete laser or optical amplifier structure. A preferred
growth technique is molecular beam epitaxy with the quantum dot layer grown
at a temperature between 450 °C to 540 °C. A conventional optical pyrometer
may be used to determine the temperature. The arsenic flux is preferably chosen
to achieve an arsenic stabilized surface. As shown in FIG. 4A, a bottom barrier
layer 402 is formed on a substrate 401. In one embodiment the substrate is a GaAs substrate and bottom barrier layer 402 is a layer of GaAs or a layer of
AlGaAs.
[0065] A bottom well layer 404, preferably comprised of InGaAs, is deposited
having a thickness, Twl. In one embodiment, the thickness of bottom well layer
404 is between about 0.5 to 5 nanometers. In one embodiment, the surface of the
bottom barrier layer 402 is pre-saturated with an Indium floating layer of about
0.5 to 1.6 monolayers prior to growth of the bottom InGaAs well layer.
[0066] As shown in FIG. 4B, a dot layer, preferably comprised of InAs, is
deposited on the bottom well layer 404, forming InAs islands 406. Since the InAs
has a relaxed lattice constant that is more than about 2% greater than the
underlying semiconductor layers, a Stranski-Krastanow (S-K) growth mode
occurs once a sufficient number of equivalent monolayers of InAs is deposited.
(As described below in more detail, in one embodiment the equivalent
monolayers of deposited InAs include the InAs deposited on the bottom well
layer 404 and the InAs monolayer thickness associated with depositing a pre-
saturation layer of InAs on bottom barrier layer 402 prior to growth of the
bottom well layer 404.) In the S-K growth mode, the driving force for the
formation of islands is the reduction in strain energy afforded by elastic
deformation, i.e., for S-K growth it is more energetically favorable to increase
surface energy by islanding than by relaxing strain by dislocation generation. In a S-K growth mode, the growth becomes three dimensional after a critical
thickness of the larger lattice constant material is grown upon an initial wetting
layer. Consequently, InAs islands 406 grow on the bottom InGaAs layer 404.
Typical ranges of equivalent InAs monolayer coverage for forming islands 404 is
between about 1.8 to 4.0 monolayers depending upon other growth parameters
and the desired dot size and density. A larger InAs equivalent monolayer
coveragage is used for denser and/or larger quantum dots. A thin wetting layer
405 of InAs may remain on the bottom InGaAs well layer 404 for some growth
conditions.
[0067] A top well layer 408, preferably comprised of InGaAs, is then grown to
cap (embed) the InAs islands 404. In one embodiment, the top InGaAs well layer
408 may have a thickness of between four to twelve nanometers. If desired, a
growth interruption may be performed after the dot layer to adjust the growth
temperature for the top well layer and/or to allow for Ostwald ripening of the
dots.
[0068] A top barrier layer 410 of GaAs or AlGaAs is then grown to complete
the quantum well. In one embodiment, after several monolayers of GaAs are
grown in the top barrier layer 410 a growth interruption is performed during
which the temperature is raised to between 580 °C to 650 °C to desorb excess Indium floating on the growth surface. The growth temperature of subsequent
layers may be selected to preserve the optical quality of the quantum dots.
[0069] The bandgap of an InGaAs well is intermediate between that of InAs
islands and surrounding GaAs or AlGaAs barrier layers. In one embodiment,
the IriχGaι-χAs has an alloy fraction of between about 0.1 to 0.3. A high indium
alloy fraction has the advantage of increasing carrier confinement to quantum
dots but also increases the strain of the layer. Each quantum dot consists of an
island of low bandgap material surrounded on all sides by a higher bandgap
material. It will be understood that interdiffusion, phase segregation, and
spinodal decomposition during the embedding process need to be taken into
account because they may affect the shape and composition of the quantum dots.
[0070] The InAs islands that form the core of the quantum dots in grown
structures have statistical characteristics that depend upon the growth
conditions. FIG. 5 is an atomic force microscopy image showing a perspective
view of InAs islands 505 deposited on an InGaAs layer. The islands were grown
by molecular beam epitaxy. The dots have a mean diameter of between about 20
to 30 nanometers in the plane of the InGaAs layer and a height (perpendicular to
the plane of the InGaAs layer) of about 7 nanometers. The dots have a width-to-
length ratio that is typically less than 2:1. It can be seen, however, that the dots
have a size distribution such that the dots can be characterized by a mean size and an associated variance. Over a sufficiently large area, the dots in a layer of
dots can also be characterized by a dot density (e.g., dots per unit area).
[0071] FIG. 6 is a plot of quantum dot density versus growth temperature for
quantum dots grown on two different InGaAs well layer compositions. It can be
seen that the dot density depends strongly upon temperature and also upon the
composition of the bottom well layer. Dot densities of greater than 1 x 10" cm~2
may be achieved at a growth temperature of about 470 °C. The dot density can
be adjusted by more than a factor of five by selecting a growth temperature
between 470 °C to 540 °C. Experiments indicate that the dot density is at least a
factor of two higher when the dots are grown on an InGaAs layer compared with
a GaAs layer at a comparable temperature. The dot density also increases when
the InGaAs alloy composition is increased from Ino.ιGao. As to Ino.2Gao.sAs.
Experiments by the inventors indicate that the thickness of the bottom InGaAs
well layer may be extremely thin and still have the same effect as a thick layer in
regards to the nucleation of quantum dots on the bottom InGaAs layer. Thus, to
achieve a reproducible dot density, the bottom well layer need only have a
thickness consistent with it having a reproducible thickness and alloy
composition. The bottom well layer may have a thickness as low as 0.5 nm,
although a thickness of about one nanometer may be easier to reproducibly
grow. [0072] As can be seen in FIG. 6, there is a strong effect of growth temperature
on dot density. Thus, the quantum dot density may be selected over a
considerable range by choosing the composition of the bottom InGaAs layer and
the growth temperature. Additionally, the dot size increases and the dot density
decreases with increased growth temperature. The dots also tend to become
more uniform in size with increasing growth temperature. The variance in dot
size with growth conditions can be characterized with atomic force microscopy.
However, for structures with the dots embedded in a higher bandgap material,
the variance in dot size may be inferred from photoluminescence measurements
of the full width half maximum (FWHM) for different growth conditions.
Generally speaking, a larger variance in quantum dot size tends causes a
corresponding increase in photoluminescence FWHM. Thus, for a particular
application, a series of quantum dots may be grown under different temperature
and the FWHM of photoluminescence used as an indication of the size variation.
[0073] The growth conditions of layers grown subsequent to the quantum
dots influences the optical quality of the quantum dots. In particular, the growth
temperature of the top quantum well layer influences the photoluminescence
quality of the quantum dots. FIG. 7 shows photolumiscence measurements of
InAs quantum dot test structures having upper well InGaAs layers grown at
different temperatures. The change in photoluminescence is attributed to decomposition of the upper (capping) well layer at elevated temperatures.
Consequently, in one embodiment the growth temperature of the upper well
layer is selected to improve the optical quality of the quantum dot layer. In one
embodiment of a laser, the growth temperature of the upper well layer is
selected to be between about 460 °C to 490 °C, since this temperature range
facilitates achieving a combination of both good material quality and a ground
state transition energy corresponding to a comparatively long emission
wavelength.
[0074] The growth of thick layers subsequent to the quantum dot layers may
also influence the optical characteristics of the quantum dots. FIG. 8 shows
photoluminescence spectra for quantum dot test structures annealed at different
temperatures to simulate the growth of waveguide cladding layers in a laser
structure. A considerable blue-shift (shift to shorter wavelengths) occurs for high
annealing temperatures. This indicates that for a long wavelength laser (e.g., one
having a wavelength beyond 1.24 microns) it is desirable to select a
comparatively low growth temperature of cladding layers grown subsequent to
the quantum dot layers (e.g., a growth temperature of AlGaAs cladding layers of
less than about 610 °C).
[0075] It is desirable that the surface of the InGaAs semiconductor comprising
bottom layer 404 have a reproducible InGaAs alloy compositon. This is, in part, due to the strong dependence of dot density on the InGaAs alloy composition of
bottom layer 404, as shown in FIG. 6. However, it is known in the art of field
effect transistors that when an InGaAs is grown on top of a layer that does not
include indium, such as GaAs or AlGaAs, that the InGaAs may have a graded
alloy composition for a finite thickness. This is because indium tends to
segregate on the surface of InGaAs during molecular beam epitaxy growth. The
segregated indium is sometimes known as a "floating layer" of indium. The
amount of indium in the floating layer eventually builds up to a steady state
value for a particular growth temperature and nominal (thick film) InGaAs
growth temperature. For an Ino.2Gao.sAs grown at around 500 °C, the floating
layer of Indium may correspond to about one monolayer of InAs. FIG. 9 shows a
prior art calculation of the segregated indium (equivalent monolayer coverage)
versus nominal InGaAs thickness. It can be seen that three to four nanometers of
InGaAs may have to be grown to reach steady state conditions if the initial
concentration of Indium on the surface (where Xo, in monolayers (MLs) is zero).
[0076] FIG. 10 shows an embodiment of a growth sequence in which the
growth is interrupted subsequent to bottom barrier layer 402 and a floating layer
of InAs 1010 is deposited having an Indium monolayer thickness approximating
the equilibrium monolayer coverage (e.g., about one monolayer equivalent of
InAs, although an equivalent monolayer coverage between 0.5 to 1.5 may be beneficial). The bottom well layer 404 is then grown. As indicated in FIG. 9, if
the InGaAs layer begins with an indium monolayer coverage close to its
equilibrium value, only a comparatively thin layer of InGaAs need to be grown
to achieve a reproducible alloy composition. Consequently, the inventors have
recognized that a a bottom well layer 404 may be grown having a thickness of
less than two nanometers while also achieving a reproducible alloy composition
of the surface of bottom well layer 404. In one embodiment, bottom well layer
404 has a thickness of one nanometer or less. Note that the floating layer of InAs
1010 contributes to the total InAs monolayer coverage on the surface which
results in the formation of dots when InAs is deposited for forming dots 406.
Consequently, it will be understood that in one embodiment the equivalent
monolayer coverage for forming InAs dots 406 includes the InAs monolayers
deposited after the growth of bottom well layer 404 combined with the InAs
monolayer coverage of presaturation floating layer 1010. As an illustrative
example, if the desired equivalent InAs monolayer coverage for forming
quantum dots is 2.4 monolayers and one monolayer of InAs is deposited as a
floating layer of InAs 1010, then only about 1.4 monolayers of InAs needs to be
deposited subsequent to the growth of bottom well layer 404 to achieve the
desired equivalent monolayer coverage of InAs of 2.4 equivalent monolayers. [0077] Photoluminescence studies by the inventors indicate that it is desirable
that all of the quantum dots not significantly penetrate the upper barrier layer
410. FIG. 11A illustrate a portion of the growth process after the top InGaAs well
layer 408 has been grown over InAs islands 406. As previously discussed, there
is a random size distribution of the InAs islands 406 due to the statistical nature
of the growth process. Consequently, some of the islands 406 may have
protruding portions 1105 that are not embedded within top well layer 408 unless
well layer 408 is made thicker than the largest thickness variation of islands 406.
Studies by the inventors of the present patent application indicate that
protruding portions 1105 may reduce the optical quality of the structure,
especially upon annealing, and may have other deleterious effects. Since
protruding portions 1105 may cause a substantial change in the optical
properties of its corresponding quantum dot 406 it is desirable to reduce the
percentage of dots having a protruding portion 1105.
[0078] FIG. 1 IB is a side view showing a layer sequence for ensuring that the
quantum dots are completely embedded in the quantum well. In the
embodiment shown in FIG. 11B, the thickness, d2, of the upper well layer 408, is
selected to be greater than the mean dot thickness td. Note that the dots do not
have to be symmetrically placed in the center of the well. For example, in one
embodiment, d2 is much thicker than the thickness, di, of lower well layer 404. In one embodiment, the thickness of bottom well layer 404 is selected to be as thin
as practical while achieving a reproducible composition (e.g., 1 to 2 nanometers
thickness). As an illustrative example, lower well layer 404 may have a nominal
thickness of 2 nanometers and the upper well layer 408 may have a nominal
thickness of 8 nanometers. For a constant total well thickness, tw, this
configuration permits the widest possible variation in dot height with all of the
dots embedded in the well.
[0079] FIG. 11C illustrates a growth sequence for an embodiment in which
protruding portions 1105 of dots 406 are removed using a desorption step. In
this embodiment after the upper well layer 408 is grown the growth is
interrupted at a sufficiently high temperature and for a sufficient length of time
to desorb InAs from protruding regions 1105 (shown in phantom in FIG. 11C
because they are removed during the desorption process resulting in a
substantially planar surface). In one embodiment, a small number of monolayers
of GaAs may be grown prior to the desorption process. The growth is resumed
after the desorption step and the barrier layer 410 is grown.
[0080] Photoluminescence or other characterization techniques may be used
to select a desorption time and temperature that removes protruding regions
1105. Typical times and temperatures are a desorption temperature of 590 °C for
one minute at a sufficient arsenic flux to maintain an arsenic stable GaAs surface. In one embodiment, the temperature is selected so that a GaAs surface is stable
but an InAs surface desorbs. As previously described, in one embodiment, a
small number of monolayers of GaAs may be deposited prior to the desorption
process to facilitate preserving the quality of planar portions of the upper
InGaAs well layer during the desorption process. As indicated by the hatched
regions, the desorption step ensures that the resulting quantum dots 406 do not
extend into the upper barrier layer 410 in the final structure. Photoluminescence
experiments indicate that the processs illustrated in FIG. 11C has a
photoluminescence FWHM for the quantum dots of about 25 to 35 meV, which is
about a factor of two lower than the FWHM for quantum dots formed using the
process illustrated in FIG. 11B, which is attributed to an improved uniformity in
quantum dot thickness. Consequently, the embodiment shown in FIG. 11B
provides two benefits: it eliminates protruding portions and also improves the
thickness uniformity of the quantum dots. In one embodiment, the mean
thickness of the as-grown islands is selected to be greater than the thickness of
the upper InGaAs well layer. Consequently, in this embodiment all of the dots
are trimmed in height by the desoption step and will have a thickness that is
approximately the same as the upper InGaAs well layer.
[0081] One benefit of the growth techniques of the present invention is that
they permit a high density of quantum dots to be grown in a comparatively thin quantum well, which reduced the strain-thickness product to achieve a particular
dot density and corresponding peak optical gain of the quantum dot layer.
Moreover, this can be simultaneously achieved at comparatively long ground
state emission wavelengths of commercial interest, such as emission wavelengths
of at least 1260 nanometers. For example, with a well thickness of 9 nanometers,
a well Indium alloy fraction of 0.15, an InAs monolayer coverage of 2.1
monolayers grown at a temperature corresponding to a dot density of 1 x 1011 per
square centimeter, the corresponding average strain-thickness product
(calculating an average indium alloy fraction in the well of 20% by a weighted
average of the equivalent InAs thickness associated with the InAs dots and the
InGaAs well layers) is the strain associated with the average composition (1.45%)
multiplied by the well thickness (90 Angstroms), or a strain thickness product of
130.5 A-%.
[0082] FIG. 12 shows a growth layer sequence and layer thicknesses for an
active region 1200 of an optical device. It will be understood that active region
1200 may comprise part or all of a waveguide core within other optical
waveguide cladding layers. The capability to form individual quantum dot
layers having a low strain-thickness product facilitates stacking four or more
quantum dot layers in the active region of a suitable laser waveguide having a core waveguide thickness, Tactive, of between about 200 nanometers to 300
nanometers.
[0083] An important limitation in designing an individual quantum dot layer
or a sequence of quantum dot layers is the strain-thickness product of the active
region. An InGaAs layer grown on a GaAs substrate is a strained layer. If the
strain-thickness product of the strained layer is sufficiently low, a high quality
strained layer may be achieved. However, if the strain-thickness product is
excessively high, deleterious misfit dislocations tend to form if a critical thickness
is exceeded. There are a variety of techniques used in the art to calculate the
critical thickness of a single strained layer.
[0084] FIG. 13 is a plot of the commonly used Matthews-Blakeslee
relationship for calculating a critical thickness for strained layers having a
uniform alloy composition (which may be used to calculate a lower bound for an
embedded quantum dot layer). Curve 1305 is a curve indicating a critical
thickness. Regions above curve 1305 tend to form dislocations. The Matthews-
Blakeslee curve 1305 indicates that a single quantum dot layer having an average
composition of well layers and dots of Ino.2Gao.sAs has a critical thickness of at
most 12 nanometers. However, provided the quantum dots are not dislocated
themselves, the Matthews-Blakeslee critical thickness is a conservative estimate
for non-equilibrium crystal growth. [0085] Additionally, for a sequence of quantum dot layers of an active region
1200, an average strain-thickness product should be below a threshold average
strain (e.g., 0.5%). The strain thickness product of an individual quantum dot
layer is EwTw, where Ew is the strain of a well layer and Tw is the thickness of the
well. The strain thickness product of an individual barrier layer is EbTb, where Eb
is the strain of the barrier layer and Tb is the thickness of the barrier layer. For a
sequence of n layers of dots, the average strain, Eav, is:
[0086] R^ (» + Wπ + ήEwT* (n + ϊ)Tb + nTw ^
[0087] For GaAs barriers (which are unstrained), this simplifies to:
Figure imgf000032_0001
[0089] Equation 1 can be re-expressed as a relationship between the barrier
thickness, well thickness, modified average strain, strain in the barriers, and
strain in the well:
[0090] τb= nTw(Ew-Eav) 3
1 (n + ϊ)(Eav- Eb) ^
[0091] For GaAs or AlGaAs layers grown on a GaAs substrate Eb »0 so that
the barrier thickness is:
[0092] Tb= nTw(Ew-Εav EqΛ. (n + l)Eav [0093] Equation 4 can be used to derive a relationship for a minimum barrier
layer thickness. If the average strain is selected to be less than a maximum
average strain (for example, and average strain less than about 0.51%), Eavmax,then
the following relationship holds:
r~~ ^ rr-n Tw[n(Ew -Eav max)] ^ _
[0094] Tb> — — -Eq.5.
(n + l)Eα max
[0095] As an illustrative example, if Eavmax is 0.4 and Ew =1.45 for an average In
alloy composition of about Ino.2Gao.sAs then Tb>2.625Tw(n/(n+l)). If Tw is 9 nm
for a structure, then the minimum barrier thickness for a structure with 6
quantum dot layers is about 20 nanometers.
[0096] The quantum dots may be utilized in a variety of laser structures. For
example, referring to FIG. 31, AlGaAs cladding layers 3120 and 3125 may be
used to provide vertical optical confinement of light to a quantum dot active
region 3105 of an optical cavity having a length L. Optical feedback for the
optical cavity may be provided using any suitable means, such as reflective facets
or a Bragg grating. Lateral optical confinement may be provided using any
suitable process. For example, a ridge waveguide may be used to provide lateral
optical confinement. Individuals lasers may be fabricated as Fabry-Perot lasers,
distributed bragg reflector lasers, distributed feedback lasers, or external cavity
lasers. By selecting growth conditions to avoid deleterious blue-shifting, the size of the quantum dots (height, width, and length) may be selected to provide gain
at a variety of wavelengths, such as the commercially important 1.3 wavelength
range.
[0097] FIG. 14A is an illustration of a growth sequence for a laser having a
single layer of quantum dots and FIG. 14B shows a corresponding conduction
band energy diagram. It will be understood from the conduction band energy
diagram that the quantum well assists the quantum dots to capture and retain
injected carriers due to the lower bandgap energy of the central quantum well
layer compared with surrounding quantum well barrier layers. Referring back to
FIG. 14A, an n-type GaAs buffer layer is grown on a GaAs substrate. An
approximately two micron thick first AlGaAs cladding layer is then grown. This
is followed by an undoped GaAs waveguiding layer about 0.11 microns thick,
which is preferably undoped to reduce absorption losses. A presaturation layer
1415 comprising approximately one monolayer of InAs is deposited during a
growth interruption step. The growth temperature is adjusted to approximately
490 °C during the growth interruption. An approximately 2 nanometer InGaAs
bottom well layer 1420 is then grown. An InAs layer corresponding to a
monolayer coverage of about 1.4 monolayers is deposited to form InAs islands.
Note that since a one monolayer presaturation layer 1415 of InAs was deposited
prior to the bottom well layer 1420 that the total InAs coverage on the surface of the bottom InGaAs well that produces the InAs islands is approximately 2.4
equivalent monolayers. An approximately 7.6 nanometer thick InGaAs top well
layer 1440 is then grown. In one embodiment, several monolayers of GaAs are
then grown, followed by a growth interruption step in which the substrate
temperature is raised to about 610 °C. The growth interruption step preferably
lasts sufficiently long to desorb excess segregated indium from the surface prior
to commencing growth of a second GaAs waveguidng layer 1445 which has
about the same thickeness as the first waveguiding layer. An upper AlGaAs
cladding layer 1450 is then grown, followed by a GaAs cap layer 1455.
[0098] Layers 1410, 1420, 1430, 1440, and 1445 form a waveguide core region
having a higher refractive index than surrounding AlGaAs cladding layers 1405
and 1450. Consequently, a transverse optical mode will be confined by the laser
structure. A fraction of the waveguide mode wβl be confined in the portion of
the structure occupied by the quantum dots.
[0099] The p-type layers, undoped layers, n-type layers form a p-i-n laser
structure. While one substrate polarity is shown, it will be understood that
doping polarity of the layers may be reversed from what is shown. The quantum
well layers 1420 and 1440 provide an additional benefit of providing a means to
improve carrier capture to the quantum dots and also serve to reduce thermionic
emission of carriers out of the dots. This provides an important benefit for quantum dots lasers. In a quantum dot laser the fill factor of quantum dots in an
individual quantum dot layer is low, typically less than 10%, depending upon
the dot density and mean dot size. In some cases, the fill factor is less than 5%.
Since the quantum dots are disposed within the quantum wells, carriers captured
by the well layer of the quantum wells may enter the quantum dots.
Additionally, the barrier layers of the quantum well also serve to reduce
thermionic emission out of the quantum dots.
[00100] FIG. 15 shows a similar layer sequence as FIG. 14. However, as
indicated by FIG. 15, the growth temperature of the active region may be varied
to control the density of quantum dots.
[00101] FIG. 16 shows plots of measured modal gain versus current density for
laser structures grown at growth temperatures producing two different dot
densities. Referring to FIG. 16, experiments data indicates that the saturated
ground state modal gain increases approximately linearly with dot density.
[00102] FIG. 17 shows plots of ground state modal gain for a laser structure
similar to that of FIG. 14 with the alloy composition of the InGaAs well layers
varied. It can be seen that the saturated (maximum) ground state modal gain
increases as the In alloy fraction increases.
[00103] As previously discussed, multiple quantum dot layers can be used in
an active region as long as the separation between quantum dot layers is large enough that the strain within a quantum well remains below a critical thickness
for forming dislocation and the average strain with the waveguide core remains
below a threshold average strain. FIG. 18 shows a plot 1805 of modal gain versus
current density for a laser structure having a single layer of quantum dots and a
corresponding plot 1820 for a laser structure having three quantum dot layers,
with the quantum well of each quantum dot layer separated from its neighboring
quantum dot layers a 10 nanometer thick barrier layer. For this example, the
quantum dot layers are spaced sufficiently close that the optical confinement for
each layer of quantum dots is about the same as for a single layer of quantum
dots, resulting in a cumulative three-fold increase in total modal gain.
[00104] The growth conditions and layer sequence of a quantum dot laser may
be adapted for a particular application. In some applications a comparatively
high ground state saturated modal gain is desired. For example, in some
commercial laser applications, such as OC-48 and OC-192 compliant lasers, an
emission wavelength of at least 1260 nanometers and a cavity length of no more
than 500 microns is required, with a cavity length of 300 microns being desirable
to reduce the photon lifetime. This wavelength may be achieved by designing
the laser to operate off of the ground state (longest wavelength emission) and by
selecting growth conditions that minimize blue-shifting of the quantum dots
during growth (e.g., by appropriately selecting the growth conditions of cap layer and thick cladding to minimize blue-shifting as described above).
Moreover, the dot height, dot diameter, dot composition and the InGaAs well
width and composition influence the ground state transition energy and may be
selected to achieve a ground state optical transition having an emission
wavelength of greater than 1260 nanometers.
[00105] One benefit of the quantum dot layers of the present invention is that
they have an extremely low linewidth enhancement factor. A low linewidth
enhancement factor reduces the deleterious chirp when a laser is directly
modulated by changing its drive current (the current injected into the p-i-n laser
diode to change its light output. The linewidth enhancement factor, , describes
the degree to which variations in the carrier density, N, alter the index of
refraction, n, of an active layer for a particular gain, g, at the lasing wavelength, Λ
. The linewidth enhancement factor can be expressed mathematically as:
Figure imgf000038_0001
[00107] Experiments by the inventors indicate that the linewidth enhancement
factor of the quantum dot lasers is as low as 0.1, which almost twenty times
lower than for comparable quantum well lasers at about the same wavelength.
The low linewidth enhancement factor correspondingly reduces wavelength
chirp for high frequency direct modulation of the lasers. Chirp becomes a progressively more severe problem in conventional lasers used in fiber-optics
systems as the modulation data rate increases. Consequently, in some
conventional fiber optics system, an external modulator (a modulator distinct
from the laser) is used to modulate a constant power output of a laser. By way of
contrast, a low linewidth enhancement factor of less than 0.2 for the quantum dot
lasers of the present invention would permit direct high speed modulation of the
lasers with extremely little chirp. This makes the quantum dot lasers of the
present invention attractive for applications in which the laser has a wavelength
of at least 1260 nanometers and is directly modulated at data rates of greater than
one Gbps, thereby eliminating the need for external modulators.
[00108] A variety of commercial applications, such as OC-48 and OC-192
compliant lasers, require modulation rates in excess of one Gbps. In a directly
modulated laser the relaxation oscillation frequency, fr is given by the
expression:
[00109] fr= , where P is the photon density, η the effective
Figure imgf000039_0001
refractive index of the waveguide, c the speed of light in vacuum, τ the photon
lifetime, and dg/dN the differential gain.
[00110] For direct modulation of a quantum dot laser, a low photon lifetime is
required for a laser that is directly modulated at high data rates, which implies a cavity length of less than 500 microns and preferably no more than 300 microns.
The saturated ground state modal gain should be at least about 25 cπr1 for a 500
micron long cavity with 10%/90% facet reflectivity of front and rear facets,
respectively; and at least 40 cm-1 for a 300 micron long cavities with 10%/90%
facet reflectivity of front and rear facets, respectively. It is also desirable that the
lasers be operated at a threshold gain that is selected to be sufficiently below the
saturated ground state modal gain that the differential gain (dg/dN) still remains
high.
[00111] For applications requiring a high saturated ground state modal gain, a
plurality of quantum dot layers are preferably included within a waveguide core
region no greater than about 300 nanometers in thickness, since a waveguide
core thickness of between about 200 to 300 nanometers provides the optimum
optical confinement per quantum dot layer. (Note that a waveguide core having
a thickness between 200 to 300 nanometers corresponds to a distance comparable
to about a half wavelength for 1.3 micron emission for the refractive index of
AlGaAs waveguiding layers, for which a high optical confinement per quantum
dot layer may be achieved). Since a saturated ground state modal gain of greater
than 7 cm-1 can be obtained for a single quantum dot layer, a total number of
quantum dot layers in the range of four to eight is sufficient for many
applications requiring a high peak optical gain. An exemplary growth sequence of a laser having 4 to 8 quantum dot layers is shown in FIG. 19. The total
waveguide core thickness is preferably in the range of about 200 to 300
nanometers, since this provides the highest optical confinement per quantum dot
layer. The corresponding AlGaAs cladding layers are preferably ALGaiAs
cladding layers with the molar fraction, x, between x=0.6 to x= 0.8 (which can also
be described in percentage terms as an aluminum arsenide percentage of
between 60% to 80%), since this range tends to produce a high optical
confinement consistent with growing high quality optical layers. However, it
will be understood that the AlGaAs cladding layers may be grown with a lower
molar fraction of aluminum but that the optical confinement may decrease,
somewhat, as the molar fraction of aluminum in the AlGaAs is decreased.
[00112] It will be understood that a directly modulated laser structure may use
any known packaging and contacts for supplying a modulated current to the
laser p-i-n diode. For example, the laser may be a ridge waveguide laser
packaged to provided a current to the diode that may be modulated at rates in
excess of one Gbps.
[00113] It will also be understood that there are tradeoffs between growth
conditions that increase dot density and the size uniformity of the dots. A high
number density of dots in each laser increases the number of dots available to
provide gain. However, this is offset, somewhat, by the fact that growth conditions that increase the dot density may also increase the size variance of the
dots. For a laser structure with a high saturated ground state optical gain it is
desirable to select growth conditions consistent with a high dot density per
quantum dot layer with as high a dot size uniformity (minimal inhomogenous
broadening) as possible. Consequently, in one embodiment of a multiple
quantum dot layer laser, the growth sequence of each quantum dot layer is
selected to trim the quantum dots similar to the embodiment shown in FIG. 11C.
[00114] In some laser applications it is desirable to have an optical gain
spectrum that extends over a substantial range of wavelengths and at a
comparatively low pumping level. For this situation, a comparatively low
saturated ground state modal gain may be desirable to facilitate wavelength
tuning. FIG. 20A is an illustrative diagram of optical transition energies for a
single quantum dot. An individual quantum dot has quantum confined energy
states associated with its length, width, and height. There will be a ground state
transition energy, a first excited state transition energy, a second excited state
transition energy, and possibly additional transition energies, depending upon
the dot size, composition, and shape. For InAs quantum dots with a nominal 7
nanometer height and 30 nanometer diameter, the difference in transition energy
between the ground state transition and the first excited state transition is about
80 meV. Referring to FIG. 20B, for an ensemble of quantum dots having a distribution in size about a mean size, there will be a corresponding
inhomogeneous broadening, as indicated by the hatched areas. When the
quantum dots are pumped, homogeneous broadening will also occur. The
degree of inhomogenous broadening can be adjusted be selecting the growth
conditions that increase or decrease the size variation of the dots.
Photoluminescence studies indicate that the growth conditions may be adjusted
to vary the inhomogeneous broadening from a minimum of about 30 meV to at
least 70 meV. Homogenous broadening of greater than 24 meV may be achieved
at pump levels of several kA/cm2. The homogenous broadening may be
attributed, for example, to collisions of electrons with phonons and other
electrons.
[00115] The interplay of homogeneous and inhomogeneous broadening acts to
broaden the optical gain spectrum. The interplay of homogenous and
inhomogenous broadening may more than double the width of the gain
response. A lasing-mode photon will receive gain from not only the
energetically resonant dots but also from other non-resonant dots that lie within
the range of homogenous broadening. Consequently, if the difference between
the central ground state transition energy and successive excited states is the
range of between about 30 meV to 80 meV, a continuous optical gain spectrum
may be achieved at a comparatively low current density because the combination C of homogeneous and inhomogeneous broadening produces a continuous gain
spectrum.
[00116] In one embodiment of the present invention, the growth parameters
are selected to achieve a difference in energy value of successive quantum dot
transition energies that is between about 30 to 80 meV. In particular, in one
embodiment, growth conditions may be selected to vary the mean size of the
quantum dots to adjust their transition energies. The growth conditions are
preferably further selected to achieve a sufficient degree of inhomogeneous
broadening. In one embodiment, the inhomogeneous broadening is selected to
be at least half the difference in energy value between the ground state transition
energy value and the first excited energy state value. In another embodiment,
the inhomogeneous broadening is selected to be about 20-30 meV below the
difference in energy levels such that the combination of homogeneous and
inhomogeneous broadening forms a continuous optical gain spectrum at
comparatively low threshold current.
[00117] A semiconductor laser including a quantum dot active region may be
designed to operate over a wide range of wavelengths at a comparatively low
current. FIG. 21 is an illustrative plot 2110 of cavity optical gain (e2sL where g is
the gain per unit length and L is the length of the gain medium in the cavity) of a
laser quantum dot active region at a selected current. Referring to FIG. 21, a quantum dot active region may be designed to have a ground state quantum
level corresponding to a peak 2105 at a wavelength λi. In the illustrative
diagram the current is selected such that the ground state modal gain at λi is
saturated with a saturated value greater than g in, a minimum gain, to overcome
a resonator loss that includes a mirror loss and an absorption loss. If an extended
tuning range is desired, the drive current is selected to populate the excited
states. For example, the first excited quantum states (e.g., first excited state 2110
and second excited state 2115) associated with quantum confinement along the
length and width of the dots may be designed to provide additional higher
energy states, as indicated by the peaks 2110 and 2115 between Λi and . By way
of contrast, a conventional quantum well active region providing gain over a
comparable wavelength would not have a saturable gain at the first ground state
of the quantum well, necessitating an extremely high current density to achieve
the minimum gain over the entire wavelength range. Rough estimates by the
inventors indicate that a quantum dot laser can achieve a wide tuning range with
approximately ten times less current than a comparable quantum well laser. In
one embodiment the inhomogeneous broadening and the difference in energy of
the ground state transition energy, the first excited state transition energy, and
the second excited state transition energy is selected to permit a continuous
optical gain spectrum of at least 150 nanometers for a maximum threshold current density. The drive current is preferably selected to at least saturate the
ground state modal gain. In one embodiment with multiple layers of quantum
dots, the growth parameters of the dots in different layers may be adjusted such
that each layer of quantum dots has a different sequence of optical transition
energies selected to form a sequence of transition energies for the layers that
facilitates forming a broad, continuous optical gain spectrum. For example, a
first quantum dot layer could have a first ground state transition energy and
associated excited state transition energy levels. The second quantum dot layer
could have dot characteristics (e.g., size, shape, and composition) selected to
have its ground state transition energy and excited state transition energy levels
(e.g., first and second excited state transition energy) offset in value (e.g., by 10-
40 meV) with respect to corresponding transition energy levels of the first layer
of quantum dots.
[00118] FIG. 22 is plot of amplified spontaneous emission intensity versus
wavelength for a laser cavity fabricated from a structure similar to that shown in
FIG. 14B and having a single quantum dot layer. The nominal dot height is
about 7 nanometers grown at a temperature of approximately 490 °C with a dot
density corresponding to about 7.5 x 1010 cm2. The front facet is anti-reflection
coating to suppress Fabry-Perot lasing and the cavity length is about 1.7 mm.
Plot 2205 is for a drive current of 500 mA, plot 2210 is for a drive current of 600 mA, and plot 2215 is for a drive current of 700 mA. The drive current for all
three plots is sufficiently high that the ground state modal gain is saturated,
which accounts for the convergence of the curves between 1.20 to 1.30 microns.
The drive current is sufficiently large that excited quantum dot states are
populated, corresponding to a continuous gain over more than 200 nanometers.
At the higher pump levels of plots 2210 and 2215, the onset of lasing at the
second excited state (1.05 microns) begins to occur.
[00119] FIG. 23 is an illustrative plot of tuning range versus current density for
a nominal 1.3 micron wavelength laser tuned to shorter wavelengths. The
quantum dot plot 2380 is based upon experimental data of the inventors. The
quantum well plot 2390 is based upon various numbers published in the
literature. Referring to plot 2280, quantum dot lasers permit about 70 nm of
tuning per each 1 kA/cm2 increase in pump current density. By way of contrast a
conventional quantum well requires about 2.3 kA/ cm2 to achieve a 70 nm tuning
range. It can be seen in plot 2390 that the quantum well has an abrupt increase
in threshold current range when the tuning range exceeds 10% of the nominal
wavelength (150 nm for this case). Above a 10% tuning range, the bias current
increases dramatically, typically exceeding 10 kA/ cm2. However, for a long
lifetime operation, quantum well lasers used in tunable lasers are commonly
operated with a maximum current density corresponding to about a 70 nm tuning range. As can be seen in plot 2380 a quantum dot active region of the
present invention may be tuned to greater than 150 nm (e.g., greater than 200
nm) with current densities in the 2-3 kA/ cm2 range. This permits, for example, a
single quantum dot laser to be used to achieve a tuning range of 180 nanometers
at a current density of less than about 3 kA/ cm2 which is impractical with
conventional quantum well lasers.
[00120] A quantum dot laser of the present invention may be used as the active
gain medium of a tunable external cavity laser. FIG. 24 is a top view of a generic
external cavity laser. The threshold condition for lasing is that the summation of
the resonator losses (mirror and internal losses) is balanced by the optical gain of
the gain medium. In a tunable laser, a wavelength selector 2440 is included that
has a reflectivity that is a function of wavelength. Typically a rear facet 2405 of a
laser diode 2402 retains a high reflectivity whereas a front facet 2410 is processed
to have an extremely low reflectivity. The threshold condition for the external
cavity system is: Rιe2te-αi>L1R(λ)e(-2αeL2)=l, where RI is the reflectivity of the rear
facet of the laser diode, g is the gain per unit length of the laser diode, αi is the
loss per unit length of the laser diode, LI the cavity length of the laser diode, R(λ)
the reflectivity of the wavelength selector, αe is the average loss per unit length
of the external cavity, and L2 is the effective length of the external cavity. [00121] In an external cavity tunable laser, the wavelength selector may be any
combination of external elements whose transmissivity or reflectivity response as
a function of wavelength may be controlled such as to limit the optical feedback
to the laser to a narrow wavelength band. Tunable external cavity lasers
typically use an external grating arranged to provide wavelength-selective
optical feedback based on wavelength-selective dispersion. Referring to FIGS.
25A and 25B, in an external cavity semiconductor laser typically one facet of a
laser diode is coated with a high reflectivity (HR) material and the other facet is
coated with an antireflection (AR) coating. An external grating is typically
arranged to provide wavelength selective feedback back to the laser diode and to
also serve as an output coupler. The reflectivity of the AR coating and the length
of the laser cavity are preferably selected to suppress Fabry-Perot (FP) modes in
the laser. It will also be understood that any known technique to suppress
Fabry-Perot modes from the cleaved facets over a range of wavelength may also
be used, such as incorporating unguided window regions or tilting the laser
stripe with respect to the facet during device fabrication. The length of the
semiconductor laser and residual reflectivity of the AR coated facet is preferably
selected such that the external grating solely determines the lasing wavelength.
In one embodiment, the length of the semiconductor laser and the residual
reflectivity of the AR coated facet is selected so that the laser is incapable of lasing off the ground state and at least the first excited state of the quantum dots
without feedback from the external grating.
[00122] In an external cavity laser, the minimum gain must exceed the cavity
losses. Thus, referring back to FIG. 24, to achieve a wide tuning range the
saturated laser gain for the ground state should be selected to be greater than the
total resonator losses, which include the absorption losses and mirror losses.
However, the grating selected wavelength only depletes the optical gain within
the homogenous gain broadening range such that the grating selected
wavelength only suppress the Fabry-Perot mode only within approximately 20
nm of the free-run emission wavelength. Consequently, in one embodiment, the
peak gain at high quantum states, gP, is preferably selected to be sufficiently low
to prevent deleterious lasing from FP modes due to residual facet reflectivity of
the front facet.
[00123] Two common external cavity configuration are the Littman-Metcalf
external cavity and the Littrow external cavity. FIG. 25B is an illustration of a
Littman-Metcalf laser cavity. FIG. 25A is an illustration of a Littrow laser cavity
2508. In the Littrow cavity the angle of incidence of the light received by the
grating 2530 from the laser 2510 is such that the beam is reflected back to the
laser serving the function of one mirror of the laser cavity. The angle of the
grating determines the wavelength. An etalon is sometimes included in a Littrow configuration to decrease the cavity bandwidth. In the Littman-Metcalf
configuration 2500, the grating 2530 diffracts the light towards a tuning mirror
2510 (also known as a retroreflector), which determines the feedback.
Collimating lenses 2505 are typically included in an external cavity laser to
improve the coupling of the laser output to the grating.
[00124] One application of a tunable laser in accord with the present invention
is for testing & monitoring (T&M) applications. A practical tunable laser for
T&M applications must have a maximum operating current selected to achieve a
reasonable laser lifetime (e.g., a current density of greater than 10 kA/cm2 is
typically correlated with a degraded lifetime). In commercially available tunable
lasers using quantum well gain medium the quantum well lasers have useful
wavelength range of about 70 nanometers. However, in many applications it is
desirable to have a larger tuning range. Conventionally, three tunable lasers,
each having quantum well gain media optimized for different wavelength
ranges, would be required for T & M over a 200 nanometer tuning range. By
way of contrast, the quantum dot lasers of the present invention have a
continuous tuning range of at least 200 nanometers at practical current densities.
[00125] It will be also be understood that the quantum dot active regions of the
present invention may be used in laser structures having an integrated
wavelength selector element to tune the lasing wavelength. A variety of other semiconductor laser structure with wavelength selector elements are known in
the art. In particular, a variety of tunable distributed Bragg reflector (DBR) and
distributed feedback laser structures (DFB) are known in the lasing art. DFB and
DBR lasers include a grating that define a Bragg wavelength condition given by
Figure imgf000052_0001
where Λ is the grating period, n is the refractive index of the material,
and m is the diffraction order. The Bragg wavelength condition defines a
wavelength having a high effective reflectivity associated with the grating. As
shown in FIG. 26, multi-section DFB and DBR lasers are known in the art having
a plurality of sections 2605, 2610, 2615 in which a current may be adjusted in one
section of the laser to adjust the refractive index of a portion of the grating 2620
of the laser and hence its Bragg wavelength. A suitable tunable DFB or DBR
laser may be modified to include a quantum dot active region 2630 of the present
invention.
[00126] Additionally, the output wavelength of a semiconductor laser having a
quantum dot active region may be temperature tuned. Referring to FIG. 27A, a
distributed feedback laser having a quantum dot active region 2705 may include
any suitable grating structure to establish a Bragg lasing condition from the
periodicity of a grating fabricated on waveguide layers 2720, 2730 having
different refractive indices. In a conventional DFB laser, thermal expansion and
the temperature dependence of the refractive index causes a shift in the Bragg wavelength of about 0.1 nm/°C. In conventional 1.3 micron lasers the gain peak
shifts by about 0.4°C. The result is that there is a limited temperature range (e.g.,
typically about 40 °C) over which the DFB laser retains good modal properties,
i.e., the DFB laser tends to have too high a threshold current or has poor mode
discrimination if the temperature rises such that the gain peak is substantially
longer in wavelength than the Bragg wavelength. FIG. 27B shows the shift in
Bragg wavelength and gain peak versus temperature for conventional 1.3 micron
lasers. Quantum dot active regions have a delta function density of states
associated with the three dimensional quantum confinement of the quantum
dots that results in reduced temperature sensitivity. Experiments by the
inventors indicated that quantum dots have a measured shift in peak gain of
only about 0.17 nm/°C due to the delta function density of states associated with
the three dimensional quantum confinement. The reduced temperature
sensitivity of the gain peak along with the broad gain function permits a
temperature tuned DFB quantum dot laser to achieve an increased tuning range
compared to a conventional bulk or quantum well DFB laser. In one
embodiment of a DFB laser, the Bragg wavelength is selected to operate on the
long wavelength side of the optical gain spectrum at a first operating
temperature to facilitate operating the laser at higher operating temperatures
(which shifts the optical gain spectrum to longer wavelengths). [00127] The quantum dot active region of the present invention may also be
used in monolithic multi-wavelength arrays of lasers. FIG. 28 is a perspective
view of a multiwavelength array 2800 of lasers 2820. Each laser 2820 may be
fabricated as a ridge laser, buried heterostructure laser, or other laser structure
providing lateral optical confinement. Each laser has a longitudinal cavity
length, L. A conventional cleaving or etching process may be used to form a
laser facet 2815. The array 2800 is formed on a common substrate 2805 having a
quantum dot active region 2810. The growth parameters of the quantum dot
active region 2810 are selected to achieve a desired wavelength tuning range
(e.g., 100 to 200 nm) within a desired range of current densities. Each laser is
preferably a DFB or DBR laser having at least one grating section 2830 with the
grating periodicity, Λ, of its grating selected to achieve a desired wavelength of
the laser. One benefit of the monolithic multi-wavelength array 2800 is that the
large tuning range of the quantum dot active region 2810 permits DFB or DBR
lasers 2820 having a large number of different output wavelengths to be
simultaneously fabricated for dense wavelength division multiplexed (DWDM)
applications. Alternately, array 2800 may be used for wide wavelength division
multiplexed (WWDM) applications in which it is desirable to have a smaller
number of wavelengths but with a significant wavelength spacing. For
example, in one embodiment, array 2800 could be used to cover the wavelength range of 1270 nanometers to 1355 nanometers (e.g., a 75-85 nanometer range). In
one embodiment the inhomogeneous broadening and the difference in energy of
the ground state transition energy and the first excited state transition energy is
selected to permit a continuous optical gain spectrum of at least 75 nanometers
for a maximum threshold current density.
[00128] The optical characteristics of the quantum dot active region 2810 of
array 2800 also permits each laser to be directly modulated at high data rates.
Theoretical investigations by the inventors indicate that optimized quantum dot
lasers should have a linewidth enhancement factor that is approximately a factor
of five -to- ten lower than for conventional quantum well lasers along with a
higher differential gain. This makes it practical to directly modulate quantum
dot lasers at high data rates (e.g., 10 - 40 Gbit/s) with acceptable chirp. This is in
contrast to conventional quantum well lasers, which are typically modulated
with external modulator at high data rates to reduce chirping effects.
Additionally, the low threshold current density of the quantum dot lasers of the
present invention facilitate direct laser modulation. Typically, directly
modulated high-frequency lasers require drive currents that are several times the
threshold current. The comparatively low threshold current of each laser of
multiwavelength array 2800 facilitates direct modulation at high data rates.
Consequently, in one embodiment, each laser of the multiwavelength array is directly modulated by varying its drive current. This eliminates the needs for
external modulators, filters, and optical isolators used in conventional DWDM
systems.
[00129] As shown in FIG. 29, if each laser of the array is directly modulated
their outputs may be directly received by an optical combiner (MUX) 2950
module and coupled to an optical fiber. It will be understood that in a direct
current modulation embodiment that any suitable high frequency packaging
technique may be used to facilitate coupling microwave frequency drive currents
to each laser. In one embodiment, each laser is driven by a wire bond. However,
a wire bond has a parasitic inductance such that long lengths of bonding wire
may degrade performance at very high data rates. In another embodiment,
microwave transmission lines are fabricated on array 2900 to facilitate coupling
microwave drive current to each laser. In still another embodiment, array 2900 is
mounted on a submount adapted to provide microwave current to each laser.
[00130] One benefit of a multiwavelength array 2800 of the present invention is
that temperature tuning may be used to fine-tune the wavelength of a large
number of wavelengths. FIG. 30 illustrates a gain spectrum for two different
temperature with Bragg wavelengths of an array of lasers (having a "picket"
fence shape for an optical network grid) superimposed on the same plot.
Referring to FIG. 30, in one embodiment, the nominal DFB wavelengths at a first temperature, Ti, are selected to cover an upper wavelength range of the gain
spectrum. Tuning the temperature of array 2800 to a higher temperature T2 shifts
the gain spectrum at a slightly higher rate than the Bragg wavelengths. Due to
the large initial width of the gain curve and the reduced temperature shift of the
gain response of quantum dot lasers, a monolithic array of DFB lasers spanning a
large wavelength range can be simultaneously tuned over a wide range.
[00131] Another benefit of array 280 is that the low threshold current density
and slow drift of the gain response with temperature renders the lasers less
susceptible to heating and thermal cross-talk. This may permit, for example,
individual lasers to be more closely packed (e.g., a small inter-laser separation)
compared with conventional quantum well lasers. Additionally, the thermal
characteristics of array 2800 may facilitate operating the array junction up, i.e.,
with the substrate mounted to a heat sink. As is well known in the laser art, a
junction down configuration (epitaxial layer mounted to the heat sink) has less
thermal resistance but typically increased the packaging complexity and cost.
Still another benefit of array 2800 is that for some applications, such as WWDM,
the need for the heat sink to be cooled may be eliminated.
[00132] While embodiments of the present invention have been discussed in
detail in regards to quantum dot layers comprising InAs embedded in InGaAs
quantum wells, it will be understood that invention may be practices in related III-V compound semiconductor materials. For example, the InGaAs quantum
wells may be replaced with AlInGaAs wells. Similarly, the barrier layers may
comprise a variety of III-V materials, such as AlGaAs or AlGalnAsP. It will be
understood, for example, that the barrier layers may be comprised of a material
having a lattice constant selected so that the barrier layers between quantum dot
layers serve as strain compensation layers.
[00133] The present invention has been discussed in detail in regards to laser
structures grown on GaAs substrates. GaAs substrates have many advantages
over other III-V semiconductor substrates, such as a comparatively large wafer
size. However, while the present invention has been discussed in regards to
materials formed on a GaAs substrate, it will be understood that embodiments of
the present invention may be practiced on other types of substrates, such as InP
substrates. Additionally, while molecular beam epitaxy has been described as a
preferred fabrication technique, it will be understood that embodiments of the
present invention may be practiced using other epitaxial techniques as well.
[00134] While particular embodiments and applications of the present
invention have been illustrated and described, it is to be understood that the
invention is not limited to the precise construction and components disclosed
herein and that various modifications, changes and variations which will be
apparent to those skilled in the art may be made in the arrangement, operation and details of the method and apparatus of the present invention disclosed
herein without departing from the spirit and scope of the invention as defined in
the appended claims.

Claims

CLAIMSWhat is claimed is:
1. A semiconductor laser, comprising:
a semiconductor optical waveguide;
quantum dot means optically coupled to the optical waveguide having an
ensemble of quantum dots for providing a saturated ground state modal gain of
greater than about 25 cm"1 at an emission wavelength of at least about 1260 nm
responsive to an injected current; and
quantum well means for providing carrier confinement of injected current
to the quantum dot means.
2. The laser of claim 1, wherein the laser has a cavity length not greater
than 500 microns.
3. A directly modulated laser, comprising:
a semiconductor optical waveguide;
quantum dot means optically coupled to the optical waveguide having an
ensemble of quantum dots for providing a saturated ground state modal gain of
greater than about 25 cm-1 at an emission wavelength of at least about 1260 nm
responsive to an injected current, the quantum dot means having a linewidth
enhancement factor of less than about 0.2; means for injecting a modulated current into the quantum dot means to vary the
light output of the laser; and
quantum well means for providing carrier confinement of injected current
to the quantum dot means.
4. The laser of claim 3, wherein the laser has a cavity length not greater
than 500 microns.
5. The laser of claim 3, wherein the laser has a cavity length not greater
than 300 microns.
6. A semiconductor laser, comprising:
a semiconductor optical waveguide;
quantum dot means optically coupled to the optical waveguide having an
ensemble of quantum dots with a sequence of at least two inhomogeneously
broadened optical transition energies for providing a continuous optical gain
spectrum over a wavelength range of greater than 75 nanometers responsive to a
threshold drive current; and
quantum well means for providing carrier confinement of injected current
to the quantum dot means.
7. A semiconductor laser, comprising:
a semiconductor optical waveguide; quantum dot means optically coupled to the optical waveguide having an
ensemble of quantum dots with a sequence of at least three inhomogeneously
broadened optical transition energies for providing a continuous optical gain
spectrum over a wavelength range of greater than 150 nanometers responsive to
a threshold drive current; and
quantum well means for providing carrier confinement of injected current
to the quantum dot means.
8. A semiconductor laser, comprising:
a semiconductor optical waveguide including a plurality of spaced-apart
quantum wells within an active region disposed within the waveguide; and
a plurality of quantum dots embedded in the plurality of spaced-apart quantum
wells, the quantum dots shaped and positioned within each quantum well to
provide a saturated ground state modal gain to the waveguide of greater than
about 25 cm-1 at an emission wavelength of at least about 1260 nm responsive to
an injected current.
9. The laser of claim 8, wherein the laser has a saturated ground state
modal gain of at least 40 cm4.
10. The laser of claim 8, wherein there are between four to eight quantum
wells layers and the active region has a thickness of not more than 300
nanometers.
11. The laser of claim 10, wherein the thickness of the active region is in
the range of between 200 nanometers to 300 nanometers.
12. The laser of claim 8, wherein a barrier layer thickness between
neighboring quantum wells is greater than 20 nanometers.
13. A semiconductor laser, comprising:
a semiconductor optical waveguide formed on a GaAs substrate including a
plurality of spaced-apart quantum wells within an active region disposed in the
waveguide; and
a plurality of quantum dots embedded in the plurality of spaced-apart
quantum wells, the quantum dots having a size distribution forming a sequence
of at least three inhomogeneously broadened optical transition energies for
providing a continuous optical gain spectrum over a wavelength range of greater
than 150 nanometers responsive to a threshold drive current.
14. A semiconductor laser, comprising:
a semiconductor optical waveguide including a plurality of spaced-apart
quantum wells within an active region disposed in the waveguide; and
a plurality of quantum dots embedded in the plurality of spaced-apart
quantum wells, the quantum dots having a size distribution forming a sequence
of at least two inhomogeneously broadened optical transition energies for providing a continuous optical gain spectrum over a wavelength range of at least
75 nanometers responsive to a threshold drive current.
15. A semiconductor active region for providing optical gain, comprising:
an InGaAs quantum well semiconductor quantum well having a
substantially planar well layer sandwiched between first and second barrier
layers; and
a plurality of InAs quantum dots embedded in the InGaAs quantum well;
the quantum dots sized to have a ground state emission energy at room
temperature of at least 1260 nanometers.
16. A semiconductor active region for providing optical gain, comprising:
an InGaAs quantum well semiconductor quantum well having a
substantially planar well layer sandwiched between first and second barrier
layers;
a plurality of InAs quantum dots embedded in the InGaAs quantum well, the
quantum dots having a ground state with an associated first optical transition
energy value and a first excited state having an associated second optical
transition energy value, the second optical transition energy value being in the
range of between 30 meV to 80 meV greater than the first optical transition
energy value; and p-type and n-type diode layers positioned to inject current into the quantum
dots;
the quantum dots having an inhomogenous broadening associated with size
variations of the quantum dots sufficient with respect to the energy separation of
the optical transition energies for the quantum dots to have a continuous optical
gain spectrum responsive to a threshold electrical current density.
17. A tunable laser, comprising:
a first optical cavity having a first end and a spaced-apart second end;
quantum dot active region means positioned in the first optical cavity
having a sequence of quantum confined energy states with energy levels selected
to provide continuous optical gain over a wavelength range of greater than 150
nanometers at a preselected current density;
a first reflector reflecting light into the first end of the first optical
cavity; and
an external optical cavity including an optical element reflecting a
selected wavelength of light into the second end of the first optical cavity.
18. A monolithic multiwavelength array of lasers, comprising:
a substrate;
quantum dot active region means disposed on the substrate for
providing an extended optical gain spectrum; quantum well means for confining carriers in the quantum dot active
region means; and
a plurality of lasers formed on the quantum dot active region means,
each of the plurality of lasers having a Bragg grating with an associated a grating
period positioned to provide optical feedback to the laser.
19. A method of growing self-assembled InAs quantum dots embedded in
InGaAs quantum wells, comprising:
growing a first AlxGal-xAs barrier layer with the molar fraction, x, less
than 1.0;
preadsorbing a floating layer of InAs to substantially match a steady-
state surface segregated layer of InAs for growth of bulk InGaAs;
growing a first InGaAs layer on the bottom AlGaAs barrier layer
having a thickness of less than about 2 nanometers;
depositing a sufficient equivalent monolayer coverage of InAs to form
InAs islands;
growing a second InGaAs layer over the InAs islands to embed the
InAs islands in InGaAs; and
growing a second AlxGal-xAs barrier layer with the molar fraction, x,
less than 1.0.
20. The method of claim 19, further comprising: selecting a growth
temperature of the InAs for a desired dot density.
21. The method of claim 19, further comprising: selecting the In alloy
composition of the first InGaAs layer to achieve a desired quantum dot density.
22. The method of claim 19, further comprising: stopping growth after the
second InGaAs layer is grown and desorbing exposed InAs for a sufficient length
of time to planarize tops of the InAs islands.
23. The method of claim 22, wherein at least one monolayer of GaAs is
deposited prior to desorbing exposed InAs.
24. A method for growing quantum dots with a controllable dot density,
the method comprising:
growing a first InGaAs layer having a reproducible surface InGaAs alloy
composition;
selecting a growth temperature for forming InAs islands with in a range of
between about 450 °C to 540 °C;
growing InAs for a selected equivalent monolayer coverage of between
about 1.8 to 4.0 at the growth temperature to form InAs islands; and
growing a second InGaAs layer to embed the islands, forming a plurality of
quantum dots; the plurality of quantum dots having a density determined by the alloy
composition of the first InGaAs layer and the growth temperature.
25. A method of growing self-assembled InAs quantum dots embedded in
InGaAs quantum wells, comprising:
growing a first AlxGal-xAs barrier layer with the molar fraction, x, less
than 1.0;
preadsorbing a floating layer of InAs to substantially match a steady-
state surface segregated layer of InAs for growth of bulk InGaAs;
growing a first InGaAs layer on the bottom AlGaAs barrier layer
having a thickness not greater than about 2 nanometers;
depositing a sufficient equivalent monolayer coverage of InAs to form
InAs islands;
growing a second InGaAs layer over the InAs islands, the second
InGaAs layer having a thickness selected to embed substantially all of the InAs
islands in InGaAs; and
growing a second AlxGal-xAs barrier layer with the molar fraction, x,
less than 1.0.
26. For a quantum dot laser having an ensemble of quantum dots for
providing optical gain at a wavelength of at least 1260 nanometers with a linewidth enhancement factor of less than about 0.2, a method of operating the
laser, the method comprising:
selecting a modulation bit rate in excess of about one Gbps; and
supplying a drive current to directly modulate the laser at the modulation
bit rate.
27. For a quantum dot laser having an ensemble of quantum dots with a
sequence of inhomogeneousy broadened optical transition energies extended
over a wavelength range of at least 150 nanometers, a method of operating the
laser, the method comprising:
providing a drive current for which the optical gain spectrum is continuous
over the the wavelength range; and
supplying wavelength-selective optical feedback to generate a lasing
wavelength within the wavelength range.
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WO2005069387A1 (en) * 2004-01-20 2005-07-28 Cyrium Technologies Incorporated Solar cell with epitaxially grown quantum dot material
US7863516B2 (en) 2004-01-20 2011-01-04 Cyrium Technologies Incorporated Solar cell with epitaxially grown quantum dot material
US9018515B2 (en) 2004-01-20 2015-04-28 Cyrium Technologies Incorporated Solar cell with epitaxially grown quantum dot material
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