WO2002051877A2 - Catalyst components for the polymerization of olefins - Google Patents
Catalyst components for the polymerization of olefins Download PDFInfo
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- WO2002051877A2 WO2002051877A2 PCT/EP2001/015024 EP0115024W WO02051877A2 WO 2002051877 A2 WO2002051877 A2 WO 2002051877A2 EP 0115024 W EP0115024 W EP 0115024W WO 02051877 A2 WO02051877 A2 WO 02051877A2
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Definitions
- the present invention relates to components of catalysts for the polymerization of olefins and the process for their preparation, the catalysts obtained from them and the use of the said catalysts in the polymerization of olefins.
- Homogeneous catalysts for the polymerization of olefins obtained from compounds of formula ML x in which M is a transition metal especially Ti, Zr, Hf, Cr, Pd and Ni, L is a ligand that is coordinated to the metal, and x is the valence of the metal, are known from the literature.
- catalysts of this type with very high activity are those obtained by reacting metallocene compounds Cp ZrCl or Cp TiCl , or their derivatives substituted in the cyclopentadienyl ring, with polyalumoxane compounds containing the -(R)AlO- repeating unit, in which R is preferably methyl (USP 4,542,199 and EP-A-129368).
- Catalysts of the aforementioned type in which the metallocene compound contains two indenyl or tetrahydroindenyl rings with a bridging bond to lower alkylenes or to other divalent radicals are suitable for the preparation of stereoregular polymers of propylene and of other alpha olefins (EP-A- 185918).
- Stereospecific catalysts are also obtained from dicyclopentadienyl compounds in which the two rings are substituted in various ways with groups with steric hindrance such as to impede the rotation of the rings about the axis with the metal.
- the substitution of the cyclopentadienyl ring of indenyl or tetrahydroindenyl in suitable positions supplies catalysts that are endowed with very high stereospecificity (EP-A-485823, EP-A-485820, EP-A- 519237, USP 5,132,262 and USP 5,162,278).
- the catalysts described above supply polymers with very narrow molecular weight distribution (Mw/Mn of about 2).
- some of these catalysts have the property of forming copolymers of ethylene with alpha olefins of the LLDPE type or elastomeric ethylene/propylene copolymers with very uniform distribution of the comonomeric units.
- the LLDPE polyethylene obtained is further characterized by low solubility in solvents such as xylene or n-decane.
- the polypropylene obtained with the more stereospecific catalysts mentioned above exhibits greater crystallinity and a higher distortion temperature relative to the polymer obtainable with the conventional heterogeneous Ziegler-Natta catalysts. Homogeneous catalysts with a different structure are described in international patent application WO 96/23010.
- catalysts comprising a complex between a transition metal and at least one bidentate ligand that has a particular structure, are capable of polymerizing olefins to give a wide range of polymers including copolymers comprising olefins and polar monomers such as carbon monoxide, vinylacetate, (meta)acrylates etc.
- polar monomers such as carbon monoxide, vinylacetate, (meta)acrylates etc.
- the homogeneous catalysts in fact, are not able to provide polymers with a regular morphology when used in processes such as polymerization in gas-phase, hi order to make it possible their use in non-solution polymerization processes, the homogeneous catalysts have to be made heterogeneous by supporting them on suitable supports that are able to endow the catalyst with appropriate morphological properties.
- suitable supports can be used for this purpose including, among others, metal oxides such as silica, magnesium halides or polymeric supports such as polyethylene, polypropylene and polystyrene.
- a characteristic that is common to these supports is that they are porous and so enable the metallocene compound to be fixed by being deposited in the pores.
- the catalytic components thus obtained are therefore in the form of particles of inert material, organic or inorganic, carrying in the surface layer, in correspondence of the pores, the transition metal compound that constitutes one of the components of the catalyst.
- the porosity of the support must be accurately controlled.
- the extent of supportation depends mainly on the porosity of the support particles, it also proves very difficult to achieve homogeneous distribution of the quantity of compound supported because the individual support particles or fractions have differences in porosity that are sometimes very considerable, hi any case, the upper limit of the amount of transition metal compound that can be supported is always determined by the porosity of the support.
- US Patent 5,106,804 describes catalysts comprising a metallocene compound supported on MgCl 2 in spherical form and partially complexed with an electron-donor compound in which the amount of Zr compound supported on MgCl 2 is relatively low (the Zr/Mg ratio in the catalyst is less than about 0.05). Furthermore, the polymerization yields are not such as to make it possible to obtain polymers containing sufficiently low residues of the catalyst. It is in fact known that supporting tends to lower the activity of homogeneous catalysts considerably.
- European patent EP 798315 describes a method of preparing homogeneous mixtures consisting of a metallocene, a cocatalyst and a dispersing medium having a oily or waxy consistency that is selected among the non-aromatic long- chain hydrocarbons that have boiling point above 150°C and viscosity of at least 1 Pa-s at 25°C. According to the inventors these mixtures are endowed with improved stability. Although included in the generic description, the use of a specific hydrocarbon matrix with a melting point above 70°C as a dispersing medium it is never described specifically.
- Example 3 describing the preparation of solid mass of a paraffinic wax having a melting point between 65 and 70°C and containing methyl alumoxane in an amount equal to approx. 66 wt.%, which has then been mechanically comminuted to a fine grain powder.
- the metallocene compound is not present in the formulation of example 3.
- the said matrix is preferably selected from the group comprising solid paraffinic waxes, polyolefins or their mixtures.
- the use of solid paraffinic waxes is particularly preferred.
- the said matrix in contrast to the supports commonly employed in this technology, is characterized by very low porosity.
- the porosity measured by the mercury method, is less than 0.3 cm 3 /g and preferably below 0.15 cm 3 /g.
- the solid paraffinic waxes are generally indicated as the products that are derived from the fraction of lubricating oils that is in its turn obtained by fractional distillation of crude oil. When this fraction is cooled the waxes separate from the oils and are deposited as solid products, which are then recovered by filtration.
- the waxes are mixtures comprising straight-chain, branched-chain or cyclic hydrocarbons.
- the polyolefins that can be used as solid matrix of the present invention comprise the polyolefins- generally known in the art such as (co)polymers of ethylene (HDPE, LLDPE), of propylene (isotactic, atactic and syndiotactic homopolymeric polypropylene, random copolymers with ethylene, butene-1, hexene-1 or their mixtures) of butene as well as polyolefins obtained by the polymerization of vinylaromatic monomers such as styrene, divinylbenzene, etc.
- the preferred ones are the (co)polymers of ethylene of low and very low molecular weight (i.e. those having an intrinsic viscosity lower than 5 and preferably comprised between 0.1 and 4), the ethylene copolymers that have a percentage by weight of comonomer greater than 10%, the l ighly modified copolymers of propylene and the elastomeric ethylene- ⁇ -olefm copolymers possibly containing minor proportions of diene or polyene.
- the (co)polymers of ethylene of low and very low molecular weight i.e. those having an intrinsic viscosity lower than 5 and preferably comprised between 0.1 and 4
- the ethylene copolymers that have a percentage by weight of comonomer greater than 10%
- the l ighly modified copolymers of propylene and the elastomeric ethylene- ⁇ -olefm copolymers possibly containing minor proportions of diene or polyene.
- the said polymers can be obtained for example by polymerization of the starting olefins carried out in the presence of catalysts of the Ziegler-Natta type comprising the product of reaction between an organo-metallic compound and a transition metal compound preferably selected from Ti or V.
- the catalyst components of the invention comprise a compound containing a transition metal M selected from the Groups 3 to 11 or the lanthanide or actinide groups of the Periodic Table of the Elements (new IUPAC version).
- the transition metal is preferably selected among Ti, V, Zr, Hf, Sc, Cr, Fe, Co, Ni, and Pd.
- the said transition metal compound is selected among the compounds of formula (I) wherein Q is selected from substituted or unsubstituted cyclopentadienyl radicals, which can carry one or more condensed cycles, which can contain heteroatoms; such as indenyl, tetrahydroindenyl, fluorenyl, octaidrofluorenyl, tetrahydrofluorenyl, indolyl, thiopenthyl, dithiophenecyclopentadienyl;
- L is a divalent bridge connecting the moieties Q and Z preferebaly it is selected from the group consisting of C 1 -C 20 -alkylidene, C 3 -C 20 -cycloalkylidene, C 2 -C 20 -alkenylidene,
- R3 is selected from the group consisting of from hydrogen, a
- M is an atom of a transition metal M selected from the Groups 3 to 10 or the lanthanide or actinide groups of the Periodic Table of the Elements (new TUPAC version),
- X 1 is a ligand selected from hydrogen, a halogen, R 9 , OR 9 , OSO 2 CF 3 ,
- R 9 is selected from hydrogen, a C ⁇ -C 20 -alkyl,
- Another class of preferred catalysts is that comprising late transition metal complexes corresponding to formula (H) or (HI):
- L is a bidentate or tridentate ligand of formula (IV): wherein:
- B is a Ci-C5 0 bridging group linking E and E , optionally containing one or more atoms belonging to Groups 13-17 of the Periodic Table;
- E 1 and E 2 are elements belonging to Group 15 or 16 of the Periodic Table and are bonded to said metal M;
- the substituents R 1 are selected from the group consisting of hydrogen, linear or branched, saturated or unsaturated CJ.-C 2 0 alkyl, C 1 -C 20 alkyliden, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C -C 20 alkylaryl and C 7 -C 20 arylalkyl radicals, optionally containing one or more atoms belonging to groups 13-17 of the Periodic Table of the Elements (such as B, Al, Si, Ge, N, P, O, S, F and Cl atoms); or two R 1 substituents attached to the same atom E or E form a saturated, unsaturated or aromatic C 4 -C 8 ring, having from 4 to 20 carbon atoms; m and n are independently 0, 1 or 2, depending on the
- X are monoanionic sigma ligands selected from the group consisting of hydrogen, halogen, -R, -OR, -OSO 2 CF 3 , -OCOR, -SR, -NR 2 and -PR 2 groups, wherein the R substituents are linear or branched, saturated or unsaturated, C1 .
- X' is a coordinating ligand selected from mono-olefins and neutral Lewis bases wherein the coordinating atom is N, P, O or S; p is an integer ranging from 0 to 3, so that the final compound (H) or (TH) is overall neutral; s ranges from 0 to 3; and A is a 7r-allyl or a 7T-benzyl group.
- the bridging group B corresponds to a structural formula selected from the group consisting of:
- G is an element belonging to Group 14 of the Periodic Table, and is preferably C, Si or Ge; r is an integer ranging from 1 to 5; E 3 is an element belonging to Group 16 and E 4
- substituents R are selected from the group consisting of hydrogen, linear or branched, saturated or unsaturated C ⁇ -C 20 alkyl, C C ⁇ alkoxy, C -C 2 o cycloalkyl, C 6 -C 20 aryl, C -C2o alkylaryl and C 7 -C 20 arylalkyl radicals, optionally containing one or more atoms belonging to groups 13-17 of the Periodic Table (such as B, Al, Si, Ge, N, P, O, S, F and CI atoms); or two R 2 substituents form a saturated, unsaturated or aromatic C 4 -C 8 ring, having from 4 to 20 carbon atoms, or they form a polycyclic ring system, optionally containing one or more Group 13-16 elements; a substituent R 1 and a substituent R 2 may form a substituted or unsubstituted
- E and E belong to Group 15 or 16 of the Periodic Table, and preferably are selected from the group consisting of N, P, O, and S.
- the substituents R 1 are preferably bulky groups; more preferably, they are C 6 -C 20 aryl groups, and even more preferably are substituted in the 2 and 6 positions with a Ci- o alkyl group.
- the substituents X are preferably hydrogen, methyl, phenyl, Cl, Br or I; p is preferably 1, 2 or 3.
- X' is a neutral Lewis base wherein the coordinating atom is N, P, O or S, it is preferably selected from the group consisting of phosphines, amines, pyridines, nitriles, sulfides and ethers; even more preferably, it is selected from the group consisting of triphenylphosphine, tri(C 1 -C 6 alkyl)phosphines, tricycloalkyl phosphines, diphenyl alkyl phosphines, dialkyl phenyl phosphines, triphenoxyphosphine, pyridine, di(C ⁇ -C 3 alkyl) ether, tefrahydrofuran and nitriles, especially acetonitrile.
- X' is a mono-olefin, it is a hydrocarbyl group having one carbon-carbon double bond, having from 2 to 20 carbon atoms; preferably is a substituted or unsubstituted C 2 -C 6 alkene.
- the variable s is preferably 0 or 1.
- A is 7T-allyl or a 7T-benzyl group.
- a 7r-allyl group is meant a monoanionic ligand with 3 adjacent sp 2 carbon atoms bound to a metal center in an ⁇ fashion.
- the three sp carbon atoms may be substituted with other hydrocarbyl groups or functional groups.
- Typical 7r-allyl groups include:
- R is hydrocarbyl
- 7T-benzyl group 7T-allyl ligand in which two of the sp 2 carbon atoms are part of an aromatic ring.
- Typical 7T-benzyl groups include:
- the quantity of transition metal compound present in the component of the present invention can vary over a wide range. Generally the said quantity varies between 0.01 and 50 wt.% relative to the total weight of the component, preferably between 0.5 and 25% and more preferably between 1 and 10%. In particular, when the transition metal compound is selected from among the compounds of formula (I) its quantity is preferably between 1 and 6%.
- the components of the invention form, with one or more compounds capable of activating the transition metal compound, catalysts that are particularly suitable for the polymerization of olefins.
- a class of activator compounds that are particularly preferred comprises organometallic compounds of aluminium. Particularly preferred are the alumoxanes and/or a compound able to form an alkylmetal cation. Suitable activating agents are linear alumoxanes having formula:
- R 17 substituents are selected from the group consisting of hydrogen, linear or branched, saturated or unsaturated CrC 20 -alkyl, C 3 -C 20 -cycloalkyl, C 6 -C 20 -aryl, C 7 -C2o-alkylaryl and C 7 -C 2 o-arylalkyl radicals, optionally containing Si or Ge atoms; and t is an integer ranging from 0 to 40 and R 17 has the meaning reported above; or cyclic alumoxanes having formula:
- alumoxanes suitable as activating cocatalysts in the catalysts system according to the present invention are methylalumoxane (MAO), 2,4,4-trimethyl-pentylalumoxane (TIOAO), 2-methyl-pentylalumoxane and 2,3-dimenthyl-butylalumoxane. Mixtures of different alumoxanes can also be used.
- Activating cocatalysts suitable as component (B) in the catalysts of the invention are also the product of the reaction between water and an organometallic aluminum compound; particularly suitable are the organometallic aluminum compounds described in the European patent application EP 0 575 875 (formula (H)) and in the international patent applications WO 96/02580 (formula (IT)), WO 99/21899 (formula (II)) and in the European patent application no. 99203110.4 (formula (H)).
- organometallic aluminum compounds are: tris(methyl)aluminum, Ms(isobutyl)alummum,
- the molar ratio between aluminum and the metal M of the bridged metallocene compound is preferably comprised between 10:1 and 50,000:1, and more preferably between 100:1 and 4,000:1.
- alumoxanes suitable as activating agents in the process of the present invention are alky aloalumii oxanes, as described in the International Patent Application WO 00/22007, and in particular l,3-dichloro-l,3-diethyldialuminoxane [EtAlCl] 2 O and l,3-dicHoro-l,3-diisobutylaltrminoxane [iBuAlCl] 2 O.
- Other compounds capable of activating the transition metal compounds described previously are the compounds able to form an alkylmetallocene cation; preferably said compounds have formula Y + Z " , wherein Y "1" is a Br ⁇ nsted acid, able to donate a proton and to react irreversibly with a substituent X of the metallocene compound of formula (I), and Z " is a compatible non- coordinating anion, able to stabilize the active catalytic species which results from the reaction of the two compounds and which is sufficiently labile to be displaceable by an olefin substrate.
- the anion 77 consists of one or more boron atoms.
- the anion Z " is an anion of the formula BAr (_) , wherein the substituents Ar, the same or different from each other, are aryl radicals such as phenyl, pentafluorophenyl or bis(trifluoromethy ⁇ )phenyl. Tefrakis-pentafluorophenyl borate is particularly preferred.
- Other useful non-coordinating anions Z " can be SbF “ , PF 6 “ , BF 4 " , trifluoromethanesulphonate and p- toluenesulphonate.
- neutral Lewis acids such as BAr 3 , SbF 5 and BF 3 can conveniently be used.
- the solid components according to the present invention can be prepared by a process comprising (a) dispersing a homogeneous transition metal compound according one or more of formulae ⁇ -(DT) above, in a hydrocarbon matrix having a melting point above 70°C which has been brought in a liquid form and (b) solidifying the said matrix, containing the said transition metal compound, in the form of spherical particles.
- the transition metal compound is dispersed, with the aid of a mixer, in the molten hydrocarbon matrix and the mixture thus obtained is sprayed under temperature conditions such as to cause immediate solidification of the droplets as spherical particles.
- the conditions under which spraying and immediate cooling take place can be properly selected according to the knowledge of the skilled in the art, in order to obtain average diameters of the solid particles over quite a wide range, hi particular the solid particles that constitute the solid components of the present invention have a spherical morphology and dimensions between 1 and 400 ⁇ m and preferably between 10 and 300 ⁇ m.
- the term spherical morphology means, according to the present invention, particles possessing a ratio between maximum diameter and minimum diameter of less than 1.5 and preferably less than 1.3.
- the transition metal compound is preferably dissolved with a minimum amount of solvent.
- any inert hydrocarbon medium in which the transition metal compound is soluble for example toluene, benzene and similar hydrocarbons.
- a hydrocarbon solvent that has a boiling point below 120°C so as to facilitate its removal from the final product.
- the use of a low boiling solvent assisting both the dispersion of the transition metal compound and the availability of the hydrocarbon matrix in liquid form is particularly preferred when the transition metal compound can decompose at temperatures at which the hydrocarbon matrix melts in absence of solvent, hi this case the concomitant use of a solvent which is able to at least partially solubilize the matrix can allow to lower the temperature at which the hydrocarbon matrix/solvent system becomes sufficiently and homogeneously liquid to permit the dispersion of the transition metal compound.
- the solution of the said transition metal compound is brought into contact with the matrix in the solid state which is then melted, while stirring.
- An alternative method of preparation of the components of the invention comprises:
- CH 2 CHR olefins with polar monomers such as carbon monoxide, vinylacetate, maleic anhydride, halogenated olefins, for the preparation of modified polyolefins such as ethylene- vinylacetate (EVA) copolymers, copolymers of ethylene or propylene with maleic anhydride, or copolymers of ethylene and carbon monoxide (polyketones).
- EVA ethylene- vinylacetate
- polyketones copolymers of ethylene or propylene with maleic anhydride
- the catalysts obtained from compounds of the type C 2 H 4 ( d) 2 ZrCl 2 , C 2 H 4 (H 4 rnd)ZrCi2 and Me 2 Si(Me 4 C ⁇ ) 2 ZrCl 2 are suitable for production of LLPDE (copolymers of ethylene containing smaller proportions, generally less than 20 mol.%, of C 3 -C 12 alpha olefin) characterized by relatively low values of density relative to the content of alpha olefin, by reduced solubility in xylene at room temperature (less than approx. 10 wt.%) and by molecular weight distribution Mw/Mn between about 2.5 and 5.
- LLPDE copolymers of ethylene containing smaller proportions, generally less than 20 mol.%, of C 3 -C 12 alpha olefin
- the catalysts of the present invention can be used in the polymerization of olefins either carried out in the liquid phase, such as solution or suspension, or in gas-phase processes, hi particular the use of the catalysts of the invention in the gas-phase processes is especially preferred as it makes it possible to obtain polymers that have good morphological properties.
- the said gas-phase process can be carried out working in one or more fluidized- bed or mechanically-stirred reactors. Polymerization is generally carried out at temperatures between 40 and 120°C, preferably between 50 and 90°C. When working in the gas phase, the working pressure is generally between 0.5 and 10 MPa, preferably between 1 and 2 MPa. Hydrogen or other compounds known in the art having the same function can be used as molecular weight regulators.
- pre-polymerization stage is particularly recommended whenever a solid hydrocarbon matrix is used that has a melting point below the temperature of the polymerization stage.
- pre-polymerization is carried out at temperatures below the melting point of the hydrocarbon matrix with the aim of avoiding the loss of morphological properties owing to melting of the hydrocarbon matrix in the reactor.
- the pre-polymerization is carried out in particular at temperatures between -10 and 70°C and preferably at temperatures between 0 and 50°C.
- the pre-polymerization can be carried out in the liquid phase, comprising an inert hydrocarbon solvent such as propane, hexane, heptane, isobutane or a monomer, or in the gas phase working at temperatures generally below 100°C, preferably between 20 and 70°C.
- the prepolymerization in gas-phase is especially preferred because it allows to preserve the morphology of the catalysts component.
- the prepolymerization is carried out by polymerizing small amounts of monomer for the time necessary to obtain quantities of polymer between 0.5 g and 2000 g per g of solid component, preferably between 5 and 500 g per g of solid component and more preferably between 10 and 100 g per gram of solid component.
- pre-polymerization is carried out with ethylene, propylene or their mixtures.
- the pre-polymerized catalyst thus obtained is then used in the next polymerization stage.
- the process for the polymerization of olefins according to the invention can be carried out in the liquid phase in the presence or absence of an inert hydrocarbon solvent, or in the gas phase.
- the hydrocarbon solvent can either be aromatic such as toluene, or aliphatic such as propane, hexane, heptane, isobutane or cyclohexane.
- the polymerization temperature is generally comprised between -100°C and +100°C and, particularly between 10°C and +90°C.
- the polymerization pressure is generally comprised between 0,5 and 100 bar.
- SIZE OF THE CATALYST PARTICLES is determined by a method based on the principle of the optical diffraction of monochromatic laser light with the "Malvern Instr. 2600" apparatus. The average size is given as P50.
- TIOA triisooctyl aluminium
- MAO methyl alumoxane
- MAO methyl alumoxane
- rac-ethylene-bis-(dimethyl-indenyl)- zirconium dichloride is added to this mixture and they are left to pre-contact for 10 minutes at room temperature.
- 9.9 g of a paraffinic wax with a melting point of 105-110°C (Lubriol C109) is added to the solution thus obtained.
- the suspension is kept stirred and is heated to a temperature of 100°C, and is connected to a vacuum pump to remove the solvent. When boiling is no longer observed, the temperature is raised again to 120°C, obtaining a homogeneous liquid phase of a yellowish-brown colour.
- the melt thus obtained is transferred to the jacketed vessel, heated to 130°C, which supplies the sprayer.
- the molten mixture is then sprayed, collecting the droplets in an N 2 atmosphere at a temperature of approx. 10°C to speed up the solidification of the droplets.
- EXAMPLE 3 Polymerization of ethylene A 4L stainless-steel reactor, equipped with a thermosetting jacket ,a magnetic stirrer , pressure indicator, temperature indicator feed line for monomer equipped with a thermal mass flowmeter to measure the ethylene uptake is used. 1600 ml of hexane is loaded into the reactor at approximately 30°C, followed by 0.2 g of tri-isobutyl aluminum as the scavenger. The polymerization is started by injecting 670 mg of the catalyst prepared as in Example 1 by means of nitrogen overpressure. The reactor temperature is increased up to 70 °C in 10-15 minutes. At 70°C ethylene is continuously fed to maintain a pressure of 10 barg.
- the polymerization is stopped after 2 hours by venting and cooling the reactor:
- the polymer suspension discharged is dried in an oven at 80°C under nitrogen atmosphere.
- a fluidized bed reactor equipped with a compressor to re-circulate the gas to the reactor after passing though a heat exchanger unit was used.
- the equipment is provided with a small pre-polymerization vessel connected to the gas phase reactor.
- 600mg of the catalyst prepared as in example 2 was loaded in the 0.5L pre-polymerization reactor equipped with a stirrer and previously purged with propane and TIBA as scavenger at 90°C for 2 hours.
- the pre-polymerization was carried out in slurry at 30°C in 0.3L of liquid propane and 30 g of ethylene. After 30 minutes the slurry was transferred to the fluidized bed to continue the polymerization in gas phase at 70°C and 12 bar of ethylene partial pressure.
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01988045A EP1265933B1 (de) | 2000-12-22 | 2001-12-17 | Katalysatorkomponente fur die polymerisation von olefinen |
DE60135311T DE60135311D1 (de) | 2000-12-22 | 2001-12-17 | Katalysatorkomponente fur die polymerisation von olefinen |
JP2002552969A JP2004516363A (ja) | 2000-12-22 | 2001-12-17 | オレフィンの重合用触媒成分 |
US10/182,038 US6703458B2 (en) | 2000-12-22 | 2001-12-17 | Catalyst components for the polymerization of olefins |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP00204706.6 | 2000-12-22 | ||
EP00204706 | 2000-12-22 |
Publications (2)
Publication Number | Publication Date |
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WO2002051877A2 true WO2002051877A2 (en) | 2002-07-04 |
WO2002051877A3 WO2002051877A3 (en) | 2002-08-22 |
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PCT/EP2001/015024 WO2002051877A2 (en) | 2000-12-22 | 2001-12-17 | Catalyst components for the polymerization of olefins |
Country Status (5)
Country | Link |
---|---|
US (1) | US6703458B2 (de) |
EP (1) | EP1265933B1 (de) |
JP (1) | JP2004516363A (de) |
DE (1) | DE60135311D1 (de) |
WO (1) | WO2002051877A2 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6979663B2 (en) * | 2002-12-19 | 2005-12-27 | Süd-Chemie Inc. | Method and apparatus for the production of enrobed catalyst pastilles |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090318663A1 (en) * | 2006-03-09 | 2009-12-24 | Makoto Fujita | Polymerizable Spherical Transition Metal Complex, Spherical Transition Metal Complex, and Production Method Thereof |
KR101084677B1 (ko) * | 2008-05-14 | 2011-11-22 | 주식회사 엘지화학 | 올레핀 중합체의 제조방법 |
CA2749835C (en) | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
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EP0447070A1 (de) * | 1990-03-12 | 1991-09-18 | BP Chemicals Limited | Katalysator und Prepolymere für die Polymerisation von Olefinen und daraus erhältliches Ethylen(co)polymer |
US5081322A (en) * | 1989-02-15 | 1992-01-14 | Hoechst Aktiengesellschaft | Polypropylene wax and process for the production thereof |
EP1181979A2 (de) * | 2000-08-22 | 2002-02-27 | Rohm And Haas Company | Matrix einer Katalysatorkomponente und eines freie Olefinengruppen enthaltenden Materials und Verfahren zur Herstellung von Polyolefinen |
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DE3443087A1 (de) | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
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FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
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DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
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2001
- 2001-12-17 DE DE60135311T patent/DE60135311D1/de not_active Expired - Fee Related
- 2001-12-17 EP EP01988045A patent/EP1265933B1/de not_active Expired - Lifetime
- 2001-12-17 WO PCT/EP2001/015024 patent/WO2002051877A2/en active IP Right Grant
- 2001-12-17 JP JP2002552969A patent/JP2004516363A/ja active Pending
- 2001-12-17 US US10/182,038 patent/US6703458B2/en not_active Expired - Fee Related
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US5081322A (en) * | 1989-02-15 | 1992-01-14 | Hoechst Aktiengesellschaft | Polypropylene wax and process for the production thereof |
EP0447070A1 (de) * | 1990-03-12 | 1991-09-18 | BP Chemicals Limited | Katalysator und Prepolymere für die Polymerisation von Olefinen und daraus erhältliches Ethylen(co)polymer |
EP1181979A2 (de) * | 2000-08-22 | 2002-02-27 | Rohm And Haas Company | Matrix einer Katalysatorkomponente und eines freie Olefinengruppen enthaltenden Materials und Verfahren zur Herstellung von Polyolefinen |
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US6979663B2 (en) * | 2002-12-19 | 2005-12-27 | Süd-Chemie Inc. | Method and apparatus for the production of enrobed catalyst pastilles |
Also Published As
Publication number | Publication date |
---|---|
US6703458B2 (en) | 2004-03-09 |
JP2004516363A (ja) | 2004-06-03 |
EP1265933A2 (de) | 2002-12-18 |
WO2002051877A3 (en) | 2002-08-22 |
DE60135311D1 (de) | 2008-09-25 |
EP1265933B1 (de) | 2008-08-13 |
US20030018146A1 (en) | 2003-01-23 |
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