WO2000066646A3 - Oil-free oxidatively curable polyester compositions - Google Patents

Oil-free oxidatively curable polyester compositions Download PDF

Info

Publication number
WO2000066646A3
WO2000066646A3 PCT/US2000/012044 US0012044W WO0066646A3 WO 2000066646 A3 WO2000066646 A3 WO 2000066646A3 US 0012044 W US0012044 W US 0012044W WO 0066646 A3 WO0066646 A3 WO 0066646A3
Authority
WO
WIPO (PCT)
Prior art keywords
oil
free
oxidatively curable
polyester compositions
curable polyester
Prior art date
Application number
PCT/US2000/012044
Other languages
French (fr)
Other versions
WO2000066646A2 (en
Inventor
Thauming Kuo
Jeffrey E G Powell
Original Assignee
Eastman Chem Co
Thauming Kuo
Jeffrey E G Powell
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co, Thauming Kuo, Jeffrey E G Powell filed Critical Eastman Chem Co
Priority to JP2000615673A priority Critical patent/JP2003502446A/en
Priority to EP00941121A priority patent/EP1177236A2/en
Priority to MXPA01011110A priority patent/MXPA01011110A/en
Priority to BR0010268-7A priority patent/BR0010268A/en
Publication of WO2000066646A2 publication Critical patent/WO2000066646A2/en
Publication of WO2000066646A3 publication Critical patent/WO2000066646A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C09D167/07—Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/56—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds other than from esters thereof
    • C08G63/58—Cyclic ethers; Cyclic carbonates; Cyclic sulfites ; Cyclic orthoesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/918—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The invention relates to oil-free polyesters and carboxyl functional aligomeric adducts modified with 3,4-epoxy-1-butene to yield resins with allyl groups. These allyl functional resins were found to be oxidatively curable in the presence of metal catalysts such as cobalt and zirconium coupounds. As a result, the 3,4-epoxy-1-butene modified polyesters and oligomeric adducts of the present invention have utility as binders for ambient-cured coating applications.

Description

Figure imgf000003_0001
Patent document Publication Patent family Publication cited in search report date member(s) date
EP 0859021 19-08-1998 JP 5117314 14-05- 1993 JP 5140270 08-06- 1993 JP 6001934 11-01- 1994 JP 6001829 11-01- 1994 JP 6033012 08-02- 1994 JP 6032868 08-02- 1994 JP 6080764 22-03- 1994 JP 6080922 22-03- 1994 JP 6095380 08-04- 1994 JP 6100800 12-04- 1994 JP 6116348 26-04- 1994 DE 69229383 15-07- 1999 EP 0540027 05-05- 1993 US 5510428 23-04- 1996 US 5494977 27-02- 1996 JP 6041275 15-02- 1994 JP 6049115 22-02- 1994
US 3716508 A 13-02-1973 NONE EP 0217660 A 08-04-1987 US 4644038 17-02-1987
CA 1244187 01-11-1988 JP 2014390 02-02-1996 JP 7030171 05-04-1995 JP 62104836 15-05-1987
Form PCT/ISA 210 (patent family annex) (July 1992)
PCT/US2000/012044 1999-05-04 2000-05-04 Oil-free oxidatively curable polyester compositions WO2000066646A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2000615673A JP2003502446A (en) 1999-05-04 2000-05-04 Oil-free oxidatively curable polyester composition
EP00941121A EP1177236A2 (en) 1999-05-04 2000-05-04 Oil-free oxidatively curable polyester compositions
MXPA01011110A MXPA01011110A (en) 1999-05-04 2000-05-04 Oil-free oxidatively curable polyester compositions.
BR0010268-7A BR0010268A (en) 1999-05-04 2000-05-04 Oxidatively curable modified polyester, oxidatively curable coating formulation, oxidatively curable oligomeric adduct, and oxidatively cured film

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13236899P 1999-05-04 1999-05-04
US60/132,368 1999-05-04

Publications (2)

Publication Number Publication Date
WO2000066646A2 WO2000066646A2 (en) 2000-11-09
WO2000066646A3 true WO2000066646A3 (en) 2001-04-19

Family

ID=22453696

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/012044 WO2000066646A2 (en) 1999-05-04 2000-05-04 Oil-free oxidatively curable polyester compositions

Country Status (6)

Country Link
EP (1) EP1177236A2 (en)
JP (1) JP2003502446A (en)
CN (1) CN1359400A (en)
BR (1) BR0010268A (en)
MX (1) MXPA01011110A (en)
WO (1) WO2000066646A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555595B1 (en) * 2001-10-10 2003-04-29 Rensselaer Polytechnic Institute Photopolymerizable compositions
DE10206565A1 (en) 2002-02-18 2003-08-21 Bayer Ag Water-dilutable polyurethane with repeat units derived from 3,4-epoxy-1-butene, used as a binder in oxidatively-drying or UV-curable, aqueous coating materials
CN102108202B (en) * 2010-12-31 2012-09-26 内蒙古普力司达体育设施工程有限公司 Rare-earth carboxylate modified polyurethane water-proof material and preparation method thereof
CN104342007B (en) * 2013-08-02 2016-10-05 鹤山市君子兰涂料有限公司 PU light woodcare paint that high rigidity quickly can polish and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716508A (en) * 1971-07-09 1973-02-13 Rohm & Haas Air-dried coatings compositions comprising polyester resins and a saturated aliphatic aldehyde
EP0217660A2 (en) * 1985-09-30 1987-04-08 A.E. Staley Manufacturing Company Poly (alpha hydroxy acid) copolymers
EP0859021A2 (en) * 1991-10-31 1998-08-19 Daicel Chemical Industries, Ltd. Epoxidised compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716508A (en) * 1971-07-09 1973-02-13 Rohm & Haas Air-dried coatings compositions comprising polyester resins and a saturated aliphatic aldehyde
EP0217660A2 (en) * 1985-09-30 1987-04-08 A.E. Staley Manufacturing Company Poly (alpha hydroxy acid) copolymers
EP0859021A2 (en) * 1991-10-31 1998-08-19 Daicel Chemical Industries, Ltd. Epoxidised compositions

Also Published As

Publication number Publication date
BR0010268A (en) 2002-01-15
EP1177236A2 (en) 2002-02-06
MXPA01011110A (en) 2002-06-04
WO2000066646A2 (en) 2000-11-09
CN1359400A (en) 2002-07-17
JP2003502446A (en) 2003-01-21

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