WO1999044732B1 - A composition for mixing oil and water to form a solution - Google Patents
A composition for mixing oil and water to form a solutionInfo
- Publication number
- WO1999044732B1 WO1999044732B1 PCT/GB1999/000644 GB9900644W WO9944732B1 WO 1999044732 B1 WO1999044732 B1 WO 1999044732B1 GB 9900644 W GB9900644 W GB 9900644W WO 9944732 B1 WO9944732 B1 WO 9944732B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- oil
- mass
- concentration
- present
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract 8
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract 7
- 150000002148 esters Chemical class 0.000 claims abstract 7
- -1 ethoxylated sorbitan ester Chemical class 0.000 claims abstract 7
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 6
- 229930195729 fatty acid Natural products 0.000 claims abstract 6
- 239000000194 fatty acid Substances 0.000 claims abstract 6
- 150000004665 fatty acids Chemical class 0.000 claims abstract 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 3
- 238000002844 melting Methods 0.000 claims abstract 3
- 230000008018 melting Effects 0.000 claims abstract 3
- 239000003921 oil Substances 0.000 claims 12
- 238000000034 method Methods 0.000 claims 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims 4
- 150000001298 alcohols Chemical class 0.000 claims 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000004606 Fillers/Extenders Substances 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000000446 fuel Substances 0.000 claims 2
- 239000000295 fuel oil Substances 0.000 claims 2
- 125000003158 alcohol group Chemical group 0.000 claims 1
- BGRJTUBHPOOWDU-UHFFFAOYSA-N sulpiride Chemical group CCN1CCCC1CNC(=O)C1=CC(S(N)(=O)=O)=CC=C1OC BGRJTUBHPOOWDU-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/682—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of chemical compounds for dispersing an oily layer on water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Medicinal Preparation (AREA)
Abstract
A composition for mixing oil and water to form a solution includes a non-ionic ethoxylated sorbitan ester. The invention extends to a composition for mixing oil and water to form a solution which includes an oil-soluble grade of alcohol ethoxylate having a hydroxyl number greater than 160, a melting point below -15 °C, and a hydrophile-lipophile balance value less than 9, a diethanolamide of at least one higher fatty acid, and a polyethylene glycol ester of a higher fatty acid.
Claims
1 . A composition for mixing oil and water to form a solution, the composition including a non-ionic ethoxylated sorbitan ester; and an oil-soluble grade of alcohol ethoxylate having a hydroxyl number greater than 1 60, a melting point below -1 5 °C, and a hydrophile-lipophile balance value of less than 9.
2. A composition as claimed in claim 1 , in which the sorbitan ester is present in the composition in a concentration of from 12% to 58% by mass.
3. A composition as claimed in claim 2, in which the sorbitan ester is present in the composition in a concentration of from 29% to 41 % by mass.
4. A composition as claimed in any one of claims 1 to 3 inclusive, in which the alcohol ethoxylate is present in the composition in a concentration of from 7% to 29% by mass.
5. A composition as claimed in claim , in which the alcohol ethoxylate is present in the composition in a concentration of from 5% to 20% by mass.
6. A composition as claimed in any one of claims 1 to 5 inclusive, in which the alcohol ethoxylate is in the form of a mixture of
ethoxylates based on Co and Cη ^ alcohols.
7. A composition as claimed in claim 6, in which the mixture of ethoxylatεs also includes ethoxylates of alcohols having chains of even numbers of carbon atoms.
8. A composition as claimed in any one of the preceding claims, which includes a diethanolamide of at least one higher fatty acid.
9. A composition as claimed in claim δ, in which the diethanolamide is present in the composition in a concentration of from 20% to 61 % by mass.
10. A composition as claimed in claim 9, in which the diethanolamide is present in the composition in a concentration of from 34% to 44% by mass.
1 1 . A composition as claimed in any one of the preceding claims, which includes a polyethylene glycol ester of a higher fatty acid.
12. A composition as claimed in claim 1 1 , in which the polyethylene glycol ester has a molecular weight of at least 400.
13. A composition as claimed in claim 12, in which the polyethylene glycol ester is present in the composition in a concentration of from 4.9% to 6.5% by mass .
1 . A composition as claimed in any one of the preceding claims, which includes ethylene glycol monobutyl ether or ethylene glycol monoethy! ether.
15. A composition as claimed in claim 14, in which the ethylene glycol monobutyl ether or ethylene glycol monoethyl ether, as the case may be, is present in the composition in a concentration of from 1 .1 % to 1 .7% by mass.
1 6. A composition for mixing oil and water to form a solution, the composition including an oil-soluble grade of alcohol ethoxylate having a hydroxyl number greater than 160, a melting point below -1 5 °C, and a hydrophile-lipophile balance value less than 9; a diethanolamide of at least one higher fatty acid; and a polyethylene glycol ester of a higher fatty acid.
17. A composition as claimed in claim 16, which includes a non-ionic ethoxylated sorbitan ester.
18. A composition as claimed in claim 17, in which the sorbitan ester is present in the composition in a concentration of from 1 2% to 58% by mass.
19. A composition as claimed in claim 1 8, in which the sorbitan ester is present in the composition in a concentration of from 29% to 41 % by mass.
20 A composition as claimed in any one of claims 1 6 to 1 9 inclusive, in which the alcohcl ethoxylate is Dresent in the composition in a concentration of from 7% to 29% by mass
21 A composition as claimed in claim 20, in which the alcohol ethoxylate is present in the composition in a concentration of from 1 5 % to 20% by mass
22 A composition as claimed in any one of claims 1 6 to 21 inclusive, in which the alcohol ethoxylate is in the form of a mixture of ethoxylates based on Cg and C^ alcohols
23 A composition as claimed in Ciaim 22, in which the mixture of ethoxylates also includes ethoxylates of alcohols having chains of even numbers of carbon atoms.
2 A composition as claimed in any one of claims 1 6 to 23 inclusive, in which the diethanolamide is present in the composition in a concentration of from 20% to 61 % by mass
25 A composition as claimed ir claim 24, in which the dietharolamide is present in the composition in a concentration of from 34% to 4% by mass.
26 A composition as claimed in any one of claims 1 6 tc 25 inclusive, in which the polyethylene glycol ester has a molecular weiαnt of at least 400
27. A compcsition as claimed in claim 26, in which the polyethylene glycol ester is present in the composition in a concentration of from 4.9% to 6.5 % by mass.
23. A composition as claimed in any one of claims 1 6 to 27 inclusive, which includes ethylene glycol monobutyl ether or ethylene glycol monoethyl ether.
29. A composition as claimed in claim 28, in which the ethylene glycol monobutyl ether or ethylene glycol monoethyl ether, as the case may be, is present in the composition in a concentration of from 1 .1 % to 1 .7% by mass.
30. A solution of oil and water, which includes a composition as claimed in any one of the preceding claims.
31 . A solution as claimed in claim 30, in which the oil is a fuel oil and which includes a fuel extender.
32. A solution as claimed in claim 31 , in which the fuel extender is an alcohol.
33. A method of forming a solution of oil and water, the method including adding and mixing a composition as claimed in any one of claims 1 to 29 inclusive, oil and water togethεr, the composition being added in an amount sufficient to provide a clear solution on mixing .
34. A method as claimed in claim 33, in which the volumetric ratio of the composition to the combined oil and water is between 5: 100 and 20: 100 and the volumetric ratio of the water to the oil is between 1 : 100 and 10: 100.
35. A method as claimed in claim 34, in which the volumetric ratio of the composition to the combined oil and water is between 12,7: 100 and 19,8:100 and the volumetric ratio of the water to the oil is between 1 ,7: 100 and 8,6: 100.
36. A method as claimed in any one of claims 33 to 35 inclusive, in which the oil is a fuel oil.
37. A composition as claimed in claim 1 or claim 1 6, substantially as herein described.
38. A solution as claimed in claim 30, substantially as herein described.
39. A method of forming a solution of oil and water as claimed in claim 33, substantially as herein described.
40. A new composition, a new solution, or a new method of forming a solution, substantially as herein described and illustrated.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU29417/99A AU2941799A (en) | 1998-03-05 | 1999-03-03 | A composition for mixing oil and water to form a solution |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA981880 | 1998-03-05 | ||
| ZAZA98/1880 | 1998-03-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1999044732A1 WO1999044732A1 (en) | 1999-09-10 |
| WO1999044732B1 true WO1999044732B1 (en) | 1999-10-14 |
Family
ID=25586888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB1999/000644 WO1999044732A1 (en) | 1998-03-05 | 1999-03-03 | A composition for mixing oil and water to form a solution |
Country Status (2)
| Country | Link |
|---|---|
| AU (1) | AU2941799A (en) |
| WO (1) | WO1999044732A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0004522D0 (en) * | 2000-02-26 | 2000-04-19 | Aae Holdings Plc | Compositions |
| CA2400946A1 (en) * | 2000-02-26 | 2001-08-30 | Aae Technologies International Public Limited Company | Fuel additive |
| PT1227143E (en) * | 2001-01-29 | 2005-07-29 | Cognis Deutschland Gmbh | COMBUSTION ADDITIVES |
| GB0110354D0 (en) * | 2001-04-27 | 2001-06-20 | Aae Technologies Internat Ltd | Fuel additives |
| CN104178231B (en) * | 2014-09-18 | 2015-05-20 | 陕西宝姜新能源技术研发有限公司 | High-flash-point alcohol ether diesel oil |
| BR102015025584A2 (en) * | 2015-10-07 | 2017-05-02 | Oxiteno S A Indústria E Comércio | POWDER EMULSIFIER |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1484512A (en) * | 1974-04-01 | 1977-09-01 | Exxon Research Engineering Co | Use of microorganisms in combination with surface active agents to synergistically disperse oil slicks |
| FR2479251A1 (en) * | 1980-03-28 | 1981-10-02 | Labofina Sa | Compsn. for dispersing oil spills on the surface of water - contg. polyethylene glycol or sorbitan ester(s) of fatty acids, glycol ether solvent and calcium or magnesium sulphonate |
| FR2515062B1 (en) * | 1981-10-27 | 1986-04-04 | Labofina Sa | SURFACE-ACTIVE COMPOSITIONS FOR THE DISPERSION OF OIL PATCHES AND METHOD OF TREATMENT AND DISPERSION THEREOF |
| GB2121779B (en) * | 1982-06-12 | 1985-06-19 | British Petroleum Co Plc | Dispersant composition |
| US4502962A (en) * | 1982-09-13 | 1985-03-05 | Exxon Research & Engineering Co. | Hydrocarbon solvent-based dispersant formulation and its use in the dispersion of viscous oil spills |
| US4560482A (en) * | 1983-12-08 | 1985-12-24 | Exxon Research And Engineering Co. | Chemical dispersant for viscous oils |
| WO1994013397A1 (en) * | 1992-12-15 | 1994-06-23 | Exxon Research And Engineering Co. | Chemical dispersant for oil spills |
| GB9320230D0 (en) * | 1993-10-01 | 1993-11-17 | Ici Plc | Defoamers |
-
1999
- 1999-03-03 AU AU29417/99A patent/AU2941799A/en not_active Abandoned
- 1999-03-03 WO PCT/GB1999/000644 patent/WO1999044732A1/en active Search and Examination
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999044732A1 (en) | 1999-09-10 |
| AU2941799A (en) | 1999-09-20 |
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