WO1997013573A1 - Apparatus for and a method of removing gaseous pollutants - Google Patents

Apparatus for and a method of removing gaseous pollutants Download PDF

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Publication number
WO1997013573A1
WO1997013573A1 PCT/GB1996/002495 GB9602495W WO9713573A1 WO 1997013573 A1 WO1997013573 A1 WO 1997013573A1 GB 9602495 W GB9602495 W GB 9602495W WO 9713573 A1 WO9713573 A1 WO 9713573A1
Authority
WO
WIPO (PCT)
Prior art keywords
members
solvent
pollutants
gas
spray
Prior art date
Application number
PCT/GB1996/002495
Other languages
French (fr)
Inventor
Sidney Wedgwood
Original Assignee
Sidney Wedgwood
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sidney Wedgwood filed Critical Sidney Wedgwood
Priority to AU72242/96A priority Critical patent/AU7224296A/en
Publication of WO1997013573A1 publication Critical patent/WO1997013573A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2047Hydrofluoric acid

Definitions

  • the present invention relates to apparatus for and a method of
  • the invention is particularly but not exclusively applicable to the
  • liquid solvent to a unit comprising one or more members, means for
  • a method of removing pollutants from gas comprising the steps of supplying
  • the solvent is water.
  • the or each member may have a generally planar form advantageously in the
  • shape of a disc although other, for example polygonal shapes, may be used.
  • the members are arranged parallel or
  • the dimensions of the gaps may be varied as desired, but is preferably less than 10mm and advantageously
  • the or each member may be provided with formations in order
  • each member may
  • the means for moving the or each member may comprise an electric motor driving through a belt drive connected to a shaft to which the
  • polluted air may comprise a pipe extending through the or
  • each member and defining outlets through which polluted air flows out.
  • means for supplying water may also comprise a pipe extending through the or each member also defining outlets through which water may flow.
  • the water may be pumped through the pipe by a pump and the
  • Impellers may be arranged on the periphery of the or each members so that in operation air is drawn therethrough.
  • Figure I is a diagrammatic cross-sectional view of one form of
  • Figure 2a is a partial plan view of a modification of the arrangement
  • Figure 2b is a cross-section along line II-II of figure 2a
  • Figure 3a is a partial plan view of another modification of the
  • Figure 3b is a cross-section along line Ill-Ill of Figure 3a.
  • Figure 4 is a diagrammatic end elevational view in cross section of a
  • Figure 5 is a diagrammatic side elevational view in cross-section of
  • Figure 6 is a plan view of one of the discs forming part of the
  • Figure 7 is a diagrammatic cross-sectional view of the disc of Figure 6.
  • the apparatus comprises a housing I defining a
  • An electrically driven pump 3 is
  • This pump 3 is operative to pump water through a pipe 4 to a unit disposed in the upper part of the housing I which
  • An air pipe 6 leads through the wall of the housing I and the water in the lower part of the housing through the members 5. That part of the
  • the unit comprising the disc form members is connected to a
  • the disc form members 5 are advantageously
  • These members may also be formed with surface
  • the member may be stepped, for example, or provided with dimples.
  • Figure 2b shows in cross-section of this member along
  • Impeller blades 22 are attached to the periphery of the disc
  • Figures 3a and 3b show another modification.
  • Figure 3a shows a
  • FIG. 3b a cross-section along the line Ill-Ill of Figure 3a.
  • This step 31 is circular in plan view. Impeller blades are shown at 32.
  • the disc form members are
  • the water droplets absorb the pollutants from
  • a housing 41 defining a tank 42 in its lower part for holding
  • An electrically driven pump 43 is disposed to pump solvent
  • members 45 are respectively disposed in regularly spaced apart vertical planes. This spacing is varied as desired preferably in the range 3 to 10mm.
  • the axle 46 supports a pulley 49 at one end. This pulley is drivably
  • exhaust duct 53 leads from the housing.
  • a part-semicircular shroud 54 surrounds the members 45. This shroud which may optionally have coolant
  • the shroud may serve as a condenser of vaporised solvent. It may also help
  • water outlet pipe 55 leads from the tank 42.
  • Each of the disc form members 45 has surface formations. Referring
  • a further ring 61 of mixing plates 62 is
  • spaced fins 64 on a 10° pitch adjacent the ring 61 are spaced fins 64 on a 10° pitch adjacent the ring 61.
  • a liquid solvent usually water
  • the members 45 are rotated at high speed by
  • the solvent is sprayed radially outwardly through the gaps between
  • shroud also collects fine mist or spray exiting the members 45 which
  • the members may be varied as required. Other formations whether proud
  • a fan may be any of or indented into the member surface.
  • a fan may be any of or indented into the member surface.
  • a fan may be any of or indented into the member surface.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Particles Using Liquids (AREA)

Abstract

Apparatus for removing gaseous pollutants from air comprises a unit having a plurality of regularly spaced horizontally or vertically oriented disc form members (5). Polluted air is fed to the member (5) simultaneously with water or other solvent while the members are rotated by an electric motor (11) at high speed. This atomises the water which absorbs pollutants from the gas in its passage between adjacent members (5). Polluted water drains down to a tank (2) from which it can be removed while the cleaned gas is exhausted through a pipe (17). Formations on the members (5) promote mixing of pollutants and solvent.

Description

APPARATUS FOR AND A METHOD OF REMOVING GASEOUS POLLUTANTS
The present invention relates to apparatus for and a method of
removing gaseous pollutants from a gas such as air.
The invention is particularly but not exclusively applicable to the
removal of hydrogen fluoride. This is produced from fluoride found naturally
in clay in the production of pottery from that clay. Fluoride scrubbers are
available but these are complicated and expensive to install.
According to one aspect of the invention there is provided, apparatus
for removing gaseous pollutants from gas comprising means for supplying
a liquid solvent to a unit comprising one or more members, means for
moving the said one or more members, in order to create spray comprising
a mu-tiplicitγ of droplets from the solvent supplied and means for supplying
polluted air to the unit to mix with the droplets of the spray in order to
remove pollutants from the gas, means for removing solvent bearing the
pollutants from the unit and means for exhausting gas from which the pollutants have been removed.
According to another aspect of the present invention there is provided
a method of removing pollutants from gas comprising the steps of supplying
a liquid solvent, producing spray of droplets of solvent, passing polluted
gas through the spray so that it mixes with the droplets and so that the
droplets absorb the pollutants draining away the solvent with the pollutants
and exhausting the cleaned gas.
In a preferred embodiment of the invention, the solvent is water. The or each member may have a generally planar form advantageously in the
shape of a disc although other, for example polygonal shapes, may be used.
In the case of a plurality of members, the members are arranged parallel or
substantially parallel to each other defining passages therebetween through
which the water may in use pass. The dimensions of the gaps may be varied as desired, but is preferably less than 10mm and advantageously
about 3mm. The or each member may be provided with formations in order
to promote the formation of a spray in use. Thus the or each member may
be stepped and/or the surface thereof may be provided with dimples or
other shapes. The means for moving the or each member may comprise an electric motor driving through a belt drive connected to a shaft to which the
or each member is connected operation of the motor results in rotation of
the shaft and through it the or each member. The means for supplying
polluted air (or other gas) may comprise a pipe extending through the or
each member and defining outlets through which polluted air flows out. The
means for supplying water may also comprise a pipe extending through the or each member also defining outlets through which water may flow.
Preferably, the water may be pumped through the pipe by a pump and the
water and air pipes are coaxial along those parts of their lengths through the
member or members. Impellers may be arranged on the periphery of the or each members so that in operation air is drawn therethrough.
In order that the invention may be more clearly understood
embodiments thereof will now be described, by way of example, with reference to the accompanying drawing, in which :-
Figure I is a diagrammatic cross-sectional view of one form of
apparatus according to the invention,
Figure 2a is a partial plan view of a modification of the arrangement
of Figure I,
Figure 2b is a cross-section along line II-II of figure 2a,
Figure 3a is a partial plan view of another modification of the
arrangement of Figure I,
Figure 3b is a cross-section along line Ill-Ill of Figure 3a.
Figure 4 is a diagrammatic end elevational view in cross section of a
further embodiment of the invention,
Figure 5 is a diagrammatic side elevational view in cross-section of
the embodiment of Figure 4,
Figure 6 is a plan view of one of the discs forming part of the
embodiment of figures I and 2, and
Figure 7 is a diagrammatic cross-sectional view of the disc of Figure 6.
Referring to Figure I, the apparatus comprises a housing I defining a
tank in its lower part 2 for holding water. An electrically driven pump 3 is
also disposed in this lower part. This pump 3 is operative to pump water through a pipe 4 to a unit disposed in the upper part of the housing I which
comprises a plurality of disc form members 5 coaxially arranged around the
pipe 4. An air pipe 6 leads through the wall of the housing I and the water in the lower part of the housing through the members 5. That part of the
pipe extending through the members 5 is coaxial with the corresponding part of the water pipe 4.
The unit comprising the disc form members is connected to a
vertically mounted drive shaft 7 mounted in bearings 8. The shaft 7
supports a pulley 9 in which a drive belt 10 is disposed driven, in operation,
by an electric motor II through a further pulley 12 arranged on the output
shaft 13 of the motor II. The disc form members 5 are advantageously
disposed about 3mm apart but this spacing may be varied as required possibly up to 10mm. These members may also be formed with surface
formation to promote the formation of spray from the water supplied to
them. The member may be stepped, for example, or provided with dimples.
Referring to Figure 2a, a partial plan view of modified disc form
member is shown. Figure 2b shows in cross-section of this member along
the line II-II of Figure 2a. This disc comprises two steps 20 and 24 in its
surface. These steps are circular in plan view and aid the formation of spray
in operation. Impeller blades 22 are attached to the periphery of the disc
form member. In operation these blades draw air and water across the
surface of the disc form member. Six such blades are disposed at regular
intervals around the periphery of the member only three being shown as
only half of the member is shown.
Figures 3a and 3b show another modification. Figure 3a shows a
partial plan view and Figure 3b a cross-section along the line Ill-Ill of Figure 3a. There are six discs form members 30 arranged coaxially and parallel
with an inter member spacing of about 3mm. Each member is stepped at
31. This step 31 is circular in plan view. Impeller blades are shown at 32.
In operation polluted air is supplied to the apparatus through pipe 6
and water is pumped through pipe 4 by pump 3. The disc form members are
rotated at high speed by the motor 1 1 through the belt IO and shaft 7. Air
flow through the apparatus is indicated by dotted lines 15 and water flow by full lines 16. Both air and water emerge through outlets in their respective
pipes 6 and 4 and travel through the gaps between adjacent disc form
members to the periphery of the members. Where fitted, the impellers help
to draw the air and water through these gaps. As the water is forced
through these gaps between the rotating disc form members a fine spray of
water droplets is formed. The spray formation is aided by the formations on
the surface of the members. The water droplets absorb the pollutants from
the polluted air which is thoroughly mixed with the water as they pass
through the gaps. Water carrying the pollutants drains back from the peripheral edges of the members to the water tank from which it can be
drained away for appropriate disposal when required. Cleaned air exhausts
through an outlet pipe 17.
Referring to Figures 4 to 1, the apparatus shown in these figures
comprises a housing 41 defining a tank 42 in its lower part for holding
solvent. An electrically driven pump 43 is disposed to pump solvent
(usually water) through inlet pipes 44 to a unit supported in the housing 41 and comprising a plurality of cast aluminium disc form members 45 coaxially
supported on a horizontally arranged hollow axle 46 supported on bearings
47 and 48 at opposite ends respectively thereof. In this example, there are
thirty members 45 although the number may be varied as desired. The
members 45 are respectively disposed in regularly spaced apart vertical planes. This spacing is varied as desired preferably in the range 3 to 10mm.
The axle 46 supports a pulley 49 at one end. This pulley is drivably
connected via a belt 50 to an electric drive motor 51. Two gas inlet ducts
52 and 53 lead into the housing 41 at opposite axial ends thereof and a gas
exhaust duct 53 leads from the housing. A part-semicircular shroud 54 surrounds the members 45. This shroud which may optionally have coolant
flowing through it is spaced away from the members 45. On the upper side
of the members 45 this spacing may be approximately 15cm. In operation
the shroud may serve as a condenser of vaporised solvent. It may also help
to collect fine spray of solvent droplets suspended in the moving gas. A
water outlet pipe 55 leads from the tank 42.
Each of the disc form members 45 has surface formations. Referring
particularly to Figures 6 and 7 and moving from the outer periphery of the
member 45 radially inwards, there is first of all a ring 56 of sixteen equally
spaced fins 57 on a 10° pitch. Adjacent the ring 56 is a ring 58 of equally spaced mixing plates 59. These plates are 1 square cm in size but their
size can be varied as desired. Adjacent the ring 58 is a raised annulus 60
which is operative to slow the flow of gas across the member 45 and increase the swirl of water. A further ring 61 of mixing plates 62 is
disposed adjacent the annulus 60 and a further ring 63 of twelve equally
spaced fins 64 on a 10° pitch adjacent the ring 61.
The operation of the embodiment of figures 4 to 7 is similar to that
of the embodiments already described. Polluted gas enters the apparatus
in the direction of arrows 65 via gas inlet ducts 52 and 53 and flows
through the centre of the members 45. A liquid solvent, usually water
enters the apparatus through inlet pipes 44 and leaves these tubes via holes
arranged along their length. The members 45 are rotated at high speed by
the electric motor 51 driving through the belt 50, pulley 49 and hollow axle
46. The solvent is sprayed radially outwardly through the gaps between
adjacent members 45. The formations 57, 59, 60, 62 and 64 on the
members 45 promote mixing between the polluted gas and solvent as they
pass between the member 45 in the direction of arrows 66. Vaporised
solvent condenses on the inner surface of the shroud 54 and drains down
into the tank 42 from which it may be drained off through the pipe 55. The
shroud also collects fine mist or spray exiting the members 45 which
similarly drains down into the tank 42. Cleaned gas exits through the gas
exhaust duct 53.
It will be appreciated that the above embodiment has been described
by way of example only and that many variations are possible without
departing from the scope of the invention. Although the members are
described as disc form they may be any other suitable shape. Any number of members from one upwards may be used. Step formations or blades on
the members may be varied as required. Other formations whether proud
of or indented into the member surface may be used. A fan may be
associated with the outlet pipe to draw air through the apparatus. Baffles
could be included downstream of the fan to reduce residual moisture
content.

Claims

C AIMS
1. Apparatus for removing gaseous pollutants from gas comprising
means (3,4,44) for supplying a liquid solvent to a unit comprising one or
more members (5,45), means for moving (10,1 ,50,51)the said one or more
members, in order to create spray comprising a multiplicity of droplets from
the solvent supplied and means for supplying polluted air (6,52,53) to the
unit to mix with the droplets of the spray in order to remove pollutants from
the gas, means for removing solvent (2,42) bearing the pollutants from the
unit and means for exhausting gas ( 17,53) from which the pollutants have
been removed.
2. Apparatus as claimed in claim 1 , in which the or each member (5,45)
is of substantially planar form.
3. Apparatus as claimed in claim 1 or 2, in which the or each member
(5,45) is a disc.
4. Apparatus as claimed in claim 1 , 2 or 3, in which the members (45)
are substantially horizontal.
5. Apparatus as claimed in claim 2, 3 or 4, in which the members (5) are
substantially vertical.
6. Apparatus as claimed in any preceding claim, in which the members
(5,45) are arranged parallel or substantially parallel to each other defining
passages therebetween through which solvent may, in use, pass.
7. Apparatus as claimed in any preceding claim, in which there are at
least two members and the gap between the members of the or each pair is less than 10mm.
8. Apparatus as claimed in claim 7, in which the gap between the
members (5,45) of the or each pair is 3mm.
9. Apparatus as claimed in any preceding claim, in which the or each
member (5,45) is provided with formations (20, 21, 22, 30, 31 , 32, 57, 59,
60, 62, 64) to promote the formation of spray.
10. Apparatus as claimed in claim 9, in which the surface of the or each
member (5, 45) is stepped.
11. Apparatus as claimed in claim 9 or 10, in which the surface of the or
each member (5,45) is dimpled.
12. Apparatus as claimed in claim 9, 10 or 11 , in which the surface of
the or each member (5,45) is provided with fins.
13. Apparatus as claimed in any preceding claim, in which, the means for
moving the or each member comprises an electric motor (11 ,51 ) operative to drive a shaft on which the members are supported through a belt.
14. Apparatus as claimed in any preceding claim, in which the means for
supplying polluted air comprises one or more inlet pipes (6,52,53).
15. Apparatus as claimed in any preceding claim, in which the means for
exhausting gas comprises an exhaust pipe (17,53).
16. Apparatus as claimed in any preceding claim, in which the means for
removing solvent comprises a tank (2,42) into which polluted bearing
solvent may drain.
17. A method of removing pollutants from gas comprising the steps of supplying a liquid solvent, producing spray of droplets of solvent, passing
polluted gas through the spray so that it mixes with the droplets and so that
the droplets absorb the pollutants draining away the solvent with the pollutants and exhausting the cleaned gas.
PCT/GB1996/002495 1995-10-13 1996-10-11 Apparatus for and a method of removing gaseous pollutants WO1997013573A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU72242/96A AU7224296A (en) 1995-10-13 1996-10-11 Apparatus for and a method of removing gaseous pollutants

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9521027.4 1995-10-13
GBGB9521027.4A GB9521027D0 (en) 1995-10-13 1995-10-13 Apparatus for and a method of removing gaseous pollutants

Publications (1)

Publication Number Publication Date
WO1997013573A1 true WO1997013573A1 (en) 1997-04-17

Family

ID=10782283

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1996/002495 WO1997013573A1 (en) 1995-10-13 1996-10-11 Apparatus for and a method of removing gaseous pollutants

Country Status (3)

Country Link
AU (1) AU7224296A (en)
GB (1) GB9521027D0 (en)
WO (1) WO1997013573A1 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2601519A (en) * 1948-04-10 1952-06-24 Air Purification Inc Air cleaner
FR1202388A (en) * 1957-05-23 1960-01-11 Koppers Gmbh Heinrich Device for the exchange of heat or matter between a gas or vapor and a liquid
DD106269A1 (en) * 1972-09-21 1974-06-12
EP0084410A2 (en) * 1982-01-19 1983-07-27 Imperial Chemical Industries Plc The removal of hydrogen sulphide from gas streams
EP0249068A1 (en) * 1986-06-02 1987-12-16 Stubinen Utveckling AB Method and apparatus for purifying polluted gases
US5439618A (en) * 1994-08-09 1995-08-08 Trapasso; Michael A. Turbine water atomizer
FR2721537A1 (en) * 1994-06-23 1995-12-29 Tecnoma Dust extraction and/or cooling of gas containing particles

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2601519A (en) * 1948-04-10 1952-06-24 Air Purification Inc Air cleaner
FR1202388A (en) * 1957-05-23 1960-01-11 Koppers Gmbh Heinrich Device for the exchange of heat or matter between a gas or vapor and a liquid
DD106269A1 (en) * 1972-09-21 1974-06-12
EP0084410A2 (en) * 1982-01-19 1983-07-27 Imperial Chemical Industries Plc The removal of hydrogen sulphide from gas streams
EP0249068A1 (en) * 1986-06-02 1987-12-16 Stubinen Utveckling AB Method and apparatus for purifying polluted gases
FR2721537A1 (en) * 1994-06-23 1995-12-29 Tecnoma Dust extraction and/or cooling of gas containing particles
US5439618A (en) * 1994-08-09 1995-08-08 Trapasso; Michael A. Turbine water atomizer

Also Published As

Publication number Publication date
GB9521027D0 (en) 1995-12-13
AU7224296A (en) 1997-04-30

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