WO1995006770A1 - Multilayer thermally bonded nonwoven fabric - Google Patents

Multilayer thermally bonded nonwoven fabric Download PDF

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Publication number
WO1995006770A1
WO1995006770A1 PCT/US1994/009893 US9409893W WO9506770A1 WO 1995006770 A1 WO1995006770 A1 WO 1995006770A1 US 9409893 W US9409893 W US 9409893W WO 9506770 A1 WO9506770 A1 WO 9506770A1
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WO
WIPO (PCT)
Prior art keywords
webs
prebonded
nonwoven
thermally bonded
web
Prior art date
Application number
PCT/US1994/009893
Other languages
French (fr)
Inventor
James O. Reeder
David D. Newkirk
Original Assignee
Fiberweb North America, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fiberweb North America, Inc. filed Critical Fiberweb North America, Inc.
Publication of WO1995006770A1 publication Critical patent/WO1995006770A1/en

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs

Definitions

  • the present invention relates to nonwoven fabrics and to processes for producing the nonwoven fabrics. More specifically, the invention relates to nonwoven fabrics suitable for use in absorbent products, such as disposable diapers, adult incontinence pads and sanitary napkins, and the like. Backcrround of the Invention Nonwoven fabrics are desirable for use in a variety of products, including bandaging materials, garments, diapers, supportive clothing and personal hygiene products. Nonwoven fabrics that are capable of transmitting body fluids to an absorbent layer while maintaining skin dryness are particularly desirable for use as a coverstock layer in disposable personal care products.
  • Disposable absorbent products such as disposable diapers, sanitary napkins, and the like, typically include a liquid impermeable outer covering, an absorbent layer, and an inner layer which contacts the skin of the wearer.
  • the inner layer ideally permits liquid to flow through it rapidly into the absorbent layer ("rapid strike through") but does not permit or, at a minimum does not facilitate, re-transmission of liquid from the absorbent layer to the "wearer" side of said inner layer (“resists rewet").
  • Such inner layers are referred to in the art as coverstock, topsheet, or, in diaper applications, diaper liner.
  • the coverstock In addition to liquid transport properties described above, the coverstock must have sufficient strength to allow for converting it, i.e., incorporating it into the final product, and for resistance to failure during vigorous movements by the user. On the other hand, while strength is essential, the coverstock should also present a soft comfortable feel against the user's skin. Currently these conflicting requirements, both softness coupled with strength and rapid strike-through coupled with low surface rewet, are met only imperfectly, typically with the use of coverstock stock made from thin, low basis weight (about 22 grams per square meter or about 20 grams per square yard) carded or spunbonded nonwoven fabrics.
  • U.S. Patent No. 4,041,951 to Sanford discloses a topsheet containing a multiplicity of depressed areas which intimately contact the uppermost surface of a substantially planar, moisture absorbent layer, while the non-depressed areas of the topsheet contact the skin of the wearer in use.
  • the depressed areas are formed by embossing a nonwoven web between a patterned steel roll having male projections thereon and a rubber coated roll.
  • a pattern is formed on the nonwoven web such that the caliper or the density of the web at the depressed embossed sites is not changed from that seen in the un-embossed part of the roll.
  • U.S. Patent No. 4,854,984 to Ball et. al. teaches a method for dynamically bonding a plurality of laminae together wherein the laminae are forwarded in face to face relation through a pressure-biased nip between a patterned nip and opposing nip, each independently driven to maintain a predetermined surface velocity differential between them.
  • the differential velocity is stated to contribute to shear energy to enable dynamic, mechanically induced bonding.
  • Suzuki et. al. in U.S. Patent. No. 4,704,112 describe a diaper topsheet made by combining two layers of nonwoven webs at their interface by fiber fusion or by hydroentangling. At least one of the webs must be apertured. Meyer et.al.
  • U.S. Patent No. 4,798,603 teach an absorbent article, i.e., a diaper, that includes a second nonwoven layer under the topsheet and above the absorbent core composed of a material less hydrophilic than said absorbent core and having an average pore size smaller than the topsheet layer pore size.
  • the patent states that bonds used to attach the transport layer to the rest of the diaper construction should not extend completely through the transport layer thickness.
  • Datta et. al. in U.S. Patent No. 4,892,534 describe a nonwoven liner fabric particularly useful for feminine care applications that contains at least three layers of thermoplastic filaments which are laid down via spunbond methods and then bonded together.
  • 5,045,387 is directed to a topical treatment of polyolefin containing nonwoven webs.
  • the patent describes the use of a facing or cover sheet for sanitary products such as diapers wherein the webs are made from polypropylene and can be formed by spunbonding.
  • the patent further states that the nonwovens can be formed of one or more bonded webs, and that the nonwoven fabric can be embossed and/or calendar printed with various designs and colors.
  • 4,762,520, 4,883,707; 4,304,234 all disclose the use of plural layers of nonwoven fabrics as the topsheet in a sanitary product.
  • Braun in U.S. Patent No. 4,668,566; Raley in U.S. Patent No. 4,761,322; and Modrak in European Patent Application 0490476-A1 teach the combination of one bonded nonwoven web with an unbonded nonwoven web. The resulting combination is bonded together so a final structure results .
  • Meitener in U.S. Patent No. 4,493,868 teaches methods to put multiple bond patterns on a nonwoven web.
  • U. S. Patent No. 3,934,588 to Mesek et al discloses a diaper topsheet with areas of preferential flow, surrounded by borders having less transmissivity for aqueous liquids than the preferential flow areas.
  • Mesek teaches the use of areas of reduced thickness via a lesser amount of fibers, areas of increased surfactant concentration, or areas of increased hydrophobic binder application to produce his areas of preferential flow or resistance to flow.
  • U.S. Patent No. 4,863,785 to Ber an et. al teaches the combination of a meltblown fabric layer between two prebonded spunbonded nonwoven layers, all continuously bonded together, to form a composite that is highly resistant to the penetration of liquids and thus useful as a sterilization wrap for medical applications.
  • U.S. Patent No. 4,041,203 to Brock et al teaches the combination of a meltblown fabric layer between two spunbonded layers, all bonded together by discrete bond regions, to form a composite that is also useful in medical applications which require a barrier layer to prevent the passage of liquid and bacteria. Summary of the Invention
  • the present invention provides a multilayer thermally bonded nonwoven fabric which is particularly useful as a component in an absorbent article.
  • the nonwoven fabrics of the present invention provide improved surface visual patterns or designs.
  • Hydrophilic nonwoven fabrics of the present invention can provide superior liquid transport properties and thus are particularly useful as the liner layer in an absorbent article. These desirable properties are achieved at reasonable cost while preserving acceptable softness and strength properties.
  • the nonwoven fabrics of the invention include at least two prebonded nonwoven webs.
  • the term "prebonded” refers to the use of nonwoven webs that are each individually bonded to form coherent webs. That is, each of the prebonded webs includes a multiplicity of intralaminar bonds between fibers that bond the fibers of the prebonded nonwoven webs together.
  • the prebonded webs are bonded by discrete point bonds located at spaced locations throughout each of the webs.
  • the multilayer thermally bonded nonwoven fabric also includes a plurality of interlaminar thermal bonds which secure the prebonded webs together.
  • interlaminar thermal bonds discrete areas of the fibers of the prebonded webs are thermally treated so that the fibers are compressed and fused together.
  • the discrete areas of compressed and fused fibers form continuous line bonds, which in turn form a pattern of intersecting continuous lines. Further, using such a bond pattern, a quilted, or pillowy texture can be imparted to the surface of the fabrics of the invention.
  • disposable absorbent articles which include as a component a multilayer thermally bonded fabric according to the invention.
  • Certain hydrophilic fabrics of the invention are particularly useful as a component, such as a liner or topsheet layer, in disposable absorbent products such as diapers and the like.
  • an absorbent body or layer is sandwiched between the fabric of the invention and an outer backsheet ' layer of a substantially liquid impermeable layer.
  • Hydrophilic nonwoven fabrics of the present invention can provide superior liquid transport properties, i.e., permit liquid to flow through the fabric rapidly while retarding re-transmission of the liquid to the surface of the fabrics. Further, the fabrics of the invention provide a soft, comfortable feel while also having good strength properties.
  • Figure 1 is a schematic illustration of one method for producing a multilayer thermally bonded nonwoven fabric in accordance with the invention
  • Figure 2 is a fragmentary top plan view of a nonwoven fabric in accordance with the invention.
  • Figure 3 is a cross sectional view of the nonwoven fabric of Figure 2 taken along line 3-3;
  • Figure 4 is a fragmentary top plan view of one embodiment of an absorbent article incorporating a nonwoven fabric in accordance with the invention;
  • Figures 5A and 5B are photomicrographs taken at 4X and 8.5X magnification, respectively, of one side of a nonwoven fabric in accordance with the invention
  • Figures 6A and 6B are photomicrographs taken at 8X and 12.5X magnification, respectively, at an angle of the nonwoven fabric of Figures 5A and 5B;
  • Figures 7A and 7B are photomicrographs taken at 25X and 206X magnification, respectively, of the nonwoven fabric of Figures 5A and 5B;
  • Figure 8 is a photomicrograph taken at 5OX magnification of the photomicrograph of Figures 7A and 7B;
  • Figure 9 is a photomicrograph taken at 4X magnification of one side of another nonwoven fabric in accordance with the invention;
  • Figures 10A and 10B are photomicrographs taken at 12.5X and 50X magnification, respectively, at an angle of the nonwoven fabric of Figure 9;
  • Figures 11A and 11B are photomicrographs taken at 25X and 206X magnification, respectively, of the nonwoven fabric of Figure 9;
  • Figure 12 is a photomicrograph taken at 5OX magnification of the photomicrograph of Figures 11A and 11B. Detailed Description of the Invention
  • Figure 1 is a schematic illustration of one method for producing a multilayer thermally bonded nonwoven fabric in accordance with the invention.
  • First and second prebonded nonwoven webs 10, 12 are unrolled from respective supply rolls 14 and 16, and directed by suitable guide rolls, such as rolls 18, 20, into opposing, face-to-face relationship to form a two layered structure 22.
  • Each of the prebonded nonwoven webs 10 and 12 may be formed of substantially continuous filaments or formed of staple fibers. In one embodiment of the invention, at least two prebonded nonwoven webs formed of substantially continuous filaments are provided. In another embodiment of the invention, at least two prebonded nonwoven webs formed of staple fibers are provided.
  • the nonwoven fabrics of the present invention may also include at least one prebonded web of continuous filaments and at least one prebonded web of staple fibers.
  • the webs may be of similar or different fiber compositions and basis weight.
  • the term "prebonded” refers to the presence of a multiplicity of intralaminar bonds between fibers in each of the individual webs. The intralaminar bonds bond the fibers of the webs together to give the webs sufficient strength and integrity to withstand handling.
  • the intralaminar bonds are discrete point bond sites located at spaced locations throughout the prebonded nonwoven webs.
  • the bond sites have a bond area of about 5 to 30 percent of the area of the web.
  • the bonds are thermal bonds formed by heating the fibers so that they soften and become tacky, and fuse together contacting portions of the fibers.
  • the thermal bonds may be formed using any of the techniques known in the art for forming discrete thermal bonds, such as calendering. Other thermal bonding techniques, such as thru-air bonding and the like, may also be used.
  • Each web contains thermoplastic fibers, and may also include other, non-thermoplastic fibers.
  • thermoplastic polymers include, but are not limited to, polyolefins such as polypropylene and polyethylene, polyesters such as poly(ethylene terephthalate) , polyamides such as poly(hexamethylene adipamide) and poly(caproamide) , and blends and copolymers thereof.
  • the thermoplastic polymer is present in the fibers of the prebonded webs in an amount sufficient so that upon thermal bonding, the fibers in at least one of the webs is compressed and melt-fused with fibers of the other webs to thereby secure the webs together, as described in more detail below.
  • the webs may be formed by any of the methods known in the art for forming a nonwoven web of staple fibers, such as carding, air laying, garnetting, and similar processes known in the art.
  • the nonwoven web may also include other staple thermoplastic and/or natural fibers, such as fibers formed from a polyolefin such as polypropylene and polyethylene, polyester, polyamides, polyacrylates, rayon, cellulose acetate and the like.
  • Natural fibers include cotton fibers, wool fibers, wood pulp fibers and the like. Blends of such fibers can also be used.
  • the staple fibers employed can be sheath/core or similar bicomponent fibers.
  • Preferred bicomponent fibers include polyolefin/polyolefin sheath/core fibers such as a polyethylene/polypropylene sheath/core fibers and polyolefin/polyester sheath/core fibers, such as a polyethylene/polyethylene terephthalate sheath/core fiber.
  • spunbonding processes generally include the following steps: (1) extruding continuous filaments; (2) quenching the filaments; (3) drawing or attenuating the filaments by a high velocity fluid; and (4) collecting the filaments on a surface to form a web.
  • Exemplary spunbonding techniques are described in U.S. Patent Nos. 3,338,992; 3,341,394; 3,276,944; 3,502,538; 3,502,763; 3,509,009; 3,542,615; and 3,692,618.
  • An exemplary list of prebonded nonwoven webs used in accordance with the .present invention includes, but is not limited to, spunbond polypropylene nonwoven webs, spunbond polyethylene nonwoven webs, thru-air bonded carded webs of bicomponent fibers, thermobonded carded polypropylene fiber webs, and webs of thermobonded carded blends of polypropylene fiber and rayon fiber.
  • Spunbond polypropylene nonwoven fabrics having a basis weight from about 5 to 30 gsm and thermobonded carded polypropylene fiber nonwoven fabrics having a basis weight -from about 10 to 30 gsm are especially preferred and are available from FIBERWEB North America, Simpsonville., S.C.
  • two layered structure 22 is conveyed in the longitudinal direction as indicated in Figure 1 to a thermal treatment station 24, illustrated in Figure 1 as heated calender rolls 26 and 28.
  • the two layered structure 22 is treated to form a plurality of interlaminar thermal bonds which secure prebonded webs 10 and 12 together to form the product of the invention, fabric 30.
  • the fibers of prebonded webs 10 and 12 are compressed and fused at discrete areas of the prebonded webs.
  • the operating temperature of heated rolls 26 and 28 should be adjusted to a surface temperature such that the fibers of the prebonded nonwoven webs are compressed and fused together.
  • the term "fusing" refers to heating the fibers so that the fibers soften and become tacky, thus adhering to one another.
  • the fibers do not completely melt but rather soften without significant loss of individual fiber structural integrity. Bonding conditions, including temperature and pressure, vary according to the particular polymer used and are known in the art for differing polymers.
  • the thermally bonded nonwoven fabric 30 is then removed from the thermal treatment station 24 and wound by conventional means onto roll 32.
  • the nonwoven fabric can be stored on roll 32 or immediately passed to end use manufacturing processes, for example, for use in bandages, diapers, disposable undergarments, personal hygiene products, and the like.
  • the heated calender rolls 26 and 28 in Figure 1 may consist of a pair of pattern rolls, a pattern roll and a smooth steel roll, a pattern roll and a rubber roll or other roll combinations known in the art.
  • the pattern of the calender rolls may be any of those known in the art, including spot bonding patterns, helical bonding patterns, line bonding patterns, and the like.
  • spot bonding is used herein to be inclusive of continuous or discontinuous pattern bonding, uniform or random point bonding, or a combination thereof, all as are well known in the art.
  • FIG 2 a fragmentary top plan view of one embodiment of a bonding pattern useful for bonding the nonwoven fabrics of the present invention is illustrated.
  • Figure 2 illustrates a nonwoven fabric 36 thermally bonded via interlaminar continuous line bonds, designated generally at 38.
  • the continuous line bonds comprise lines of discrete areas of compressed and fused fibers of the prebonded webs, as described above, and form a pattern of intersecting lines. That is, intersecting bond lines are arranged so that a repeating "diamond" pattern is formed. By proper choice of the embossing pattern, a wide variety of visual patterns can be produced.
  • Figure 2 illustrates intralaminar discrete point bond sites, designated generally at 40, in the prebonded webs as described above.
  • Figure 2 illustrates another feature of the nonwoven fabrics of the invention.
  • Figure 2 illustrates a distinct pattern of "pillows" or portions of the surfaces of the individual prebonded webs raised between the intersecting bond lines. This gives a quilt-like appearance to the surface, or topography, of the fabric.
  • Figures 6A and 6B This surface feature of the fabrics of the present invention is best illustrated in Figures 6A and 6B, described below.
  • Figure 3 is a cross-section view of the fabric illustrated in Figure 2 taken along line 3-3.
  • Figure 3 illustrates a two layer structure, the intralaminar bonds 40 bonding the fibers of each of the webs together to form coherent webs, and interlaminar bonds 38 bonding the webs together to form a unitary structure.
  • the heated calender rolls 26 and 28 can, in other embodiments of the invention, be replaced by other thermal activation zones which compress and fuse the fibers of the prebonded webs.
  • the thermal treatment station may be in the form of a through-air bonding oven or in the form of a microwave or other RF treatment zones, so long as thermal bonds are formed by compressing and fusing the fibers of the prebonded nonwoven webs.
  • Other heating stations such as ultrasonic welding stations can also be advantageously used in the invention. Such conventional heating stations are known to those skilled in the art and are capable of effecting substantial thermal fusion of the nonwoven webs via thermal bonds.
  • a process similar to the Pinsonic process taught in U.S. Patent No. 3,733,238, the entirety of which is hereby incorporated by reference, can be used.
  • a horn could supply sonic energy to two or more prebonded nonwoven webs held against a rotary pattered Anvil roll.
  • the pattern on the rotary Anvil roll a wide variety of visual patterns or designs can be achieved on the fabric.
  • the resultant multilayer thermally bonded fabric has hydrophilic properties.
  • the prebonded webs are formed of a hydrophobic material, such as polypropylene, hydrophilic properties are imparted using any of the techniques known in the art.
  • an additive may be added to the polymer which upon extrusion or upon post formation treatment migrates to the surface of the fibers to impart hydrophilic properties to the surface of the fibers.
  • either of the prebonded webs or the resultant fabric can be treated with any of the surfactants known in the art to thereby impart hydrophilic properties to the fabric.
  • U.S. Patent No. 5,104,728 to Obermeyer and Cashin the entire disclosure of which is hereby incorporated by reference, describes one such surfactant treatment.
  • the multilayer thermally bonded nonwoven fabrics of the present invention provide several desirable and yet apparently opposing properties in one fabric. Superior liquid transport properties are exhibited by the hydrophilic fabrics of the invention.
  • the unique improvement in liquid transport seen in the hydrophilic multilayer nonwoven fabrics of the invention may be due to the interlaminar thermal bonds formed by compressing and melt-fusing fibers of the prebonded nonwoven webs. Modification of the capillary nature of the webs in these bonding regions may promote very rapid liquid transport through the nonwoven fabrics.
  • the balance of the surface of the nonwoven fabrics, comprising multiple layers of initially bonded nonwoven webs, then provides a barrier to rewet back from the diaper core.
  • the method illustrated in Figure 1 is susceptible to numerous preferred variations.
  • the schematic illustration of Figure 1 shows nonwoven webs supplied as rolls of preformed webs, it will be apparent that the webs can be formed directly during the in-line process.
  • the multilayer fabric 30 of Figure 1 comprises a two layer structure, but there may be two or more similar or dissimilar webs depending upon the particular properties sought for the fabric.
  • hydrophilic nonwoven fabrics of the present invention may be used as a nonwoven component in a disposable absorbent personal care product, such as a liner or "topsheet” layer in a diaper, an incontinence pad, a sanitary napkin, and the like; as a wipe; and the like.
  • a disposable absorbent personal care product such as a liner or "topsheet” layer in a diaper, an incontinence pad, a sanitary napkin, and the like; as a wipe; and the like.
  • FIG 4 illustrates a fragmentary top plan view of one aspect of this embodiment of the invention.
  • the hydrophilic nonwoven fabric of the invention is used as a topsheet layer in a disposable diaper, designated generally at 42.
  • Disposable diaper 42 includes a substantially liquid impermeable backsheet layer 44, an absorbent layer 46 positioned on backsheet layer 44, and a topsheet layer 48 positioned on absorbent layer 46, formed of a nonwoven fabric in accordance with the present invention.
  • topsheet layer 48 and backsheet layer 44 are essentially coextensive and extend out past the edges of absorbent layer 46 to form marginal edges about the periphery of diaper 42.
  • diaper 42 is illustrated as having a general hourglass or I-shape, but as will be appreciated by the skilled artisan, other product shapes may be used, depending upon the desired properties and end use of the product.
  • Diaper 42 can also include means 50 for fastening the diaper on the wearer. As illustrated, fastening means 50 are adhesive tape tabs; however, any of the fastening means known in the art, such as hooks, clips, snaps, and the like, may be used.
  • Backsheet layer 44 may be any of the types of substantially liquid impermeable layers known in the art for use with disposable absorbent products.
  • backsheet layer 44 may be a polymer film, such as a polyolefin film, such as polypropylene or polyethylene.
  • Backsheet layer 44 can also include a nonwoven material, such as a spunbonded nonwoven web, which has been suitably treated to impart a desired degree of liquid impermeability thereto, for example, by combining the nonwoven material with a polymer film.
  • Absorbent layer 46 can be any of the absorbent layers known in the art for use in an absorbent disposable product.
  • absorbent layer 46 can be a preformed web substantially made of cotton-like woody pulp.
  • Wood pulp may be included in the absorbent layer, preferably by incorporating the wood fiber from a hammer milled water laid web or from an air laid web which may contain staple textile fibers, such as cotton, reconstituted cellulose fibers, e.g., rayon and cellulose acetate, polyolefins, polyamides, polyesters, and acrylics.
  • the absorbent layer may also include an effective amount of an inorganic or organic high-absorbency (e.g., superabsorbency) material as known in the art to enhance the absorptive capability of the absorbent layer.
  • an inorganic or organic high-absorbency e.g., superabsorbency
  • the nonwoven fabric may be combined with absorbent layer 46 and substantially liquid impermeable backsheet layer 44 in any of the ways known in the art, such as gluing with lines of hot-melt adhesive, seaming with ultrasonic welding, thermal bonding, high pressure bonding and the like.
  • the topsheet layer advantageously permits liquid to rapidly flow through it into the absorbent layer but does not facilitate re-transmission of liquid back from the absorbent layer to the body side of the topsheet.
  • Figures 5A and 5B are Scanning Electron Microscope (SEM) photomicrographs of the nonwoven fabric of Example 1, taken perpendicular to the plane of the fabric at 4X and 8.5X magnifications, respectively.
  • Figures 5A and 5B illustrate interlaminar continuous calender bonds of the fabric of the invention as well as intralaminar point bond sites of the prebonded nonwoven webs used to construct the fabric.
  • Figures 6A and 6B are photomicrographs taken at an angle to the plane of the fabric of Example 1 at 8X and 12.5X magnifications, respectively.
  • Figures 6A and 6B illustrate the quilted-like topography of the fabric.
  • Figures 7A and 7B are photomicrographs taken of the product of Example 1 taken at magnifications of 25X and 206X, respectively.
  • Figures 7A and 7B illustrate the interlaminar continuous calender bonds used to secure together the fabric of Example 1, and also illustrate bond formation by compression and elt- fusion or partial melt-fusion of fibers from the prebonded webs used to construct this product of the invention.
  • Figure 8 is a photomicrograph taken at 5OX magnification of the interlaminar continuous calender bond featured in photographs 7A and 7B used to secure together the webs of the fabric of Example 1.
  • Figure 8 illustrates, to a greater degree, the level of melt- fusion or partial melt-fusion of fibers from prebonded webs used to construct this product of the invention.
  • a hand-made diaper was produced using material from Example 1 as the topsheet.
  • a generic diaper having elastic leg bands was anchored to a stationary stand using clamps and stretched to overcome the effect of the elasticity of the leg bands so that the surface of the diaper was flat with no existing wrinkles.
  • the existing nonwoven topsheet was detached from the diaper body by carefully cutting the topsheet alongside the inside of the existing elastic leg bands and waist shield, leaving both the leg bands and waist shield intact as part of the diaper construction.
  • the nonwoven topsheet and underlying tissue layer was carefully removed from the diaper body without destroying the diaper core.
  • the tissue layer was replaced with a commercially available tissue product.
  • the nonwoven topsheet was replaced with Example 1 material and secured with hot melt glue using a commercially available hot-glue gun applicator. The pattern was clearly visible on the diaper, and the diaper had an attractive hand feel.
  • Example 2 Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 138°C (280°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
  • Example 3 Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about
  • hydrophilic spunbonded webs each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 137°C (278°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 138°C (280°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
  • Example 5 Two hydrophilic carded webs, each having a basis weight of approximately 14 gsm (12.0 g/yd 2 ) and consisting of 100 percent 1.5 dpf polypropylene staple fiber and prebonded having a total bonded area of approximately 25 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 134°C (274°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of about 893 kg/m (50 pli) and the webs were passed between the rolls at a speed of about 6 mpm (20 fpm) .
  • Example 7 The two-layered assembly was then secured together via calendering between a smooth surfaced steel roll maintained at about 136°C (276°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 135°C (275°F) .
  • the rolls were compressed together under a pressure of about 839 kg/m (50 pli) and the webs were passed between the rolls at a speed of about 6 mpm (20 fpm) .
  • Example 7 Example 7
  • hydrophilic spunbonded webs each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 135°C (275°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
  • hydrophilic carded web not a product of the invention, having a basis weight of 32 gsm (27.0 g/yd 2 ) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent was calendering between a smooth surfaced steel roll maintained at about 136°C (276°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The sample was compressed under a pressure of about 1785 kg/m (100 pli) and was passed between the rolls at a speed of about 4 mpm (12 fpm) .
  • Example 10 Two hydrophilic carded webs, each having a basis weight of 16 gsm (13.5 g/yd 2 ) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 137°C (279°F) and a steel roll having a wavy line pattern on its surface and maintained at about 136°C (277°F).
  • the wavy line pattern consisted of multiple lines approximately 1 mm in width with a 5 mm spacing between lines, having a wavelength of approximately 40 mm with an approximately 7 mm modulation on each side of the axis running parallel with and intersecting the wavelength.
  • the rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
  • Example 11 One hydrophilic carded web, product not part of the invention, having a basis weight of about 32 gsm (27.0 g/yd 2 ) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent was calendering between a smooth surfaced steel roll maintained at about 135°C (275°F) and a steel roll having a wavy line pattern on its surface and maintained at about 136°C (276°F) .
  • the wavy line pattern consisted of multiple lines approximately 1 mm in width with a 5 mm spacing between lines, having a wavelength of approximately 40 mm with an approximately 7 mm modulation on each side of the axis running parallel with and intersecting the wavelength.
  • the rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
  • Example 12 Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between two rolls, each having raised continuous helical lands as described in U.S. Pat. No. 4,863,785 to Berman et al. The bottom of the two rolls was maintained at about 137°C (278°F) and the top of the two rolls maintained at about 136°C (276°F) .
  • Figure 9 is a photomicrograph of the fabric of Example 12 taken perpendicular to the plane of the fabric at 4X magnification.
  • Figure 9 illustrates interlaminar discontinuous calender bonds of the invention created by calendering the prebonded webs between two rolls, each having raised continuous helical lands as described in U.S. Patent No. 4,863,785 above, as well as intralaminar discontinuous discrete point bonds of the prebonded spunbonded nonwoven webs used to construct the fabric of the invention.
  • Figures 10A and 10B are photomicrographs taken at an angle to the plane of the fabric of Example 12 at 12.5X and 50X magnifications, respectively.
  • Figures 10A and 10B illustrate the textured-like topography of the fabric of Example 12. These photographs again show interlaminar discontinuous calender bonds of the invention created by calendering the prebonded webs between two rolls, each having raised continuous helical lands as described in U.S. Patent No. 4,863,785 above, as well as intralaminar discontinuous bonds of the prebonded spunbonded nonwoven webs used to construct the fabric of the invention.
  • Figures 11A and 11B are photomicrographs taken at 25X and 206X magnifications, respectively, of the fabric of Example 12.
  • Figures 11A and 11B illustrate the interlaminar discontinuous calender bonds used to secure together the fabric of Example 12.
  • Figures 11A and 11B also illustrate bond formation by compression and melt-fusion or partial melt-fusion of fibers from prebonded webs used to construct this product.
  • Figure 12 is a photomicrograph taken at 5OX magnification of the interlaminar discontinuous calender bond featured in Figures 11A and 11B that was used to secure together Example 12.
  • Figure 12 illustrates, to a greater degree, the level of melt- fusion or partial melt-fusion of fibers from prebonded webs used to construct this product.
  • a hand-made diaper was produced using material from Example 12 as the topsheet.
  • a generic diaper having elastic leg bands was anchored to a stationary stand using clamps and stretched to overcome the effect of the elasticity of the leg bands so that the surface of the diaper was flat with no existing wrinkles.
  • the existing nonwoven topsheet was detached from the diaper body by carefully cutting the topsheet alongside the inside of the existing elastic leg bands and waist shield, leaving both the leg bands and waist shield intact as part of the diaper construction.
  • the nonwoven topsheet and underlying tissue layer was carefully removed from the diaper body without destroying the diaper core.
  • the tissue layer was replaced with a commercially available tissue product.
  • the nonwoven topsheet was replaced with Example 12 material and secured with hot melt glue using a commercially available hot-glue gun applicator. The pattern was visible on the diaper, and the diaper had an attractive handfeel.
  • Control Example 1A One hydrophilic spunbonded web similar to commercially available products of FIBERWEB North America having a basis weight of approximately 10 gsm (8.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 1.
  • Control Example IB Three hydrophilic spunbonded webs, each having a basis weight of approximately 10 gsm (8.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid ih a three-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 1. The basis weight and caliper were evaluated on the one- layer uncalendered control samples and tripled for the uncalendered multi-layered control examples.
  • Control Example IC One hydrophobic spunbonded web similar to commercially available products of FIBERWEB North
  • Control Example 2 A One hydrophilic spunbonded web similar to commercially available products of FIBERWEB North America having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 2.
  • Control Example 2B Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 2.
  • Control Example 3 A Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 2.
  • hydrophilic spunbonded web similar to commercially available products of FIBERWEB North America having a basis weight of approximately 18 gsm (15.0 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 3.
  • Control Example 3B Two hydrophilic spunbonded webs, each having a basis weight of approximately 18 gsm (15.0 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 3.
  • Control Exampl e 4 A One hydrophilic carded web having a basis weight of approximately 21 gsm (17.7 g/yd 2 ) and consisting of 100 percent 1.8 denier per filament (dpf) polypropylene staple fiber (commercially available from Amoco Fabrics and Fibers Company under the trade name of Amoco Type 030) and prebonded having a total bonded area of approximately 25 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 4.
  • dpf denier per filament
  • Control Exampl e 4B Two hydrophilic carded webs, each having a basis weight of approximately 21 gsm (17.7 g/yd 2 ) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Control Example 4A above and prebonded having a total bonded area of approximately 25 percent, were overlaid in a two- layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 4.
  • Control Example 12 A One hydrophilic spunbonded web having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent but not post-processed via calendering was evaluated as characterized in Table I-B as a control against Illustrative Example 12.
  • Control Example 12B Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd 2 ) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-B as a control against Illustrative Example 12.
  • Control Example 13 Typical physical and moisture transport properties as measured from commercially available spunbond polypropylene diaper topsheet material available from Fiberweb North America, Inc. are characterized in Table I-B.
  • Control Example 14 Typical physical and moisture transport properties as measured from commercially available reduced basis weight spunbond polypropylene diaper topsheet available from Fiberweb, North America, Inc. are characterized in Table I-B. Control Exampl e 15
  • Typical physical and moisture transport properties as measured from commercially available carded polypropylene diaper topsheet material available from Fiberweb North America, Inc. are characterized in Table I-B.
  • the strip tensile strength, caliper (under compression) , strike-through and surface rewet properties of the samples in the foregoing examples were tested according to the procedures outlined below. Additionally, softness, fuzz level, handle-o-meter and drape length of certain of the examples were also tested according to the procedures outlined below.
  • the basis weight and caliper values for the multiple-layer control examples were not measured but the values measured for the single-layer control examples were multiplied by the applicable factor and listed in Tables I-A and I-B.
  • Strip tensile strength was evaluated by breaking a one inch long sample generally following ASTM D1682-64, the One-Inch Cut Strip Test. The instrument crosshead speed was set at 2 inches per minute and the gauge length was set at 3 inches. The tensile strength in both the machine direction (MD) and the cross machine direction (CD) was evaluated. The strip tensile strength or breaking load, reported in grams per inch, is the average of at least eight measurements. Caliper (Under Compression)
  • Strike-Through Strike-through was evaluated by a method similar to that described in U.S. Patent Nos. 4,041,951 and 4,391,869, incorporated herein by reference. Strike-through was measured as the time for 5 ml of synthetic urine solution, placed in the cavity of the strike-through plate, to pass through the sample fabric into an absorbent pad. The result, reported in seconds, is generally the average of four tests.
  • Surface Wetness was evaluated by a method similar to that described in U.S. Patent Nos. 4,041,951 and 4,391,869, incorporated herein by reference. Surface Wetness, reported in grams, was evaluated by adding synthetic urine through the sample into the absorbent pad until the absorbent pad was nearly saturated. Thus, the sample fabric was wet at the beginning of the surface rewet test. For results denoted as Surface Wetness A, the loading factor was slightly less than 4 grams of synthetic urine per gram of absorbent sample. A uniform pressure loading of 0.5 psi was then applied and the procedure concluded as disclosed in the above patents.
  • Drape Length was measured as the distance required for the test specimen to break a predetermined plane when extended horizontally from the test surface as defined in the specified procedure. The results, reported in centimeters (cm) , is generally the average of eight tests.
  • Control 1A 8.5 4.5 530 440 2.09 0.76 2.10
  • Control 3A 15.0 7.5 1095 1160 2.45 0.12 1.45
  • MD CD A B (0.5 psi Compression) (1.0 psi Compression)
  • Example 6 27.7 11.8 1565 670 1.60 0.37 n.a.
  • Example 7 25.0 10.3 1560 1425 1.52 0.09 n.a.
  • Example 8 28.8 12.4 1200 194 2.08 0.39 n.a.
  • Example 9 1 28.5 14.2 718 205 1.84 0.20 n.a.
  • Example 10 30.0 15.3 1420 298 1.73 0.12 n.a.
  • Example l l 1 30.0 16.3 1125 214 1.73 0.12 n.a.
  • Example 12 26.2 12.4 1830 1555 1.53 0.12 0.73 Control 12 A 12.6 6.1 875 745 1.93 0.17 1.87 Control 12B 25.2 12.2 . n.a. n.a. 1.89 0.14 0.51
  • Control 13 18.5 10.0 1165 870 1.70 0.11 n.a.
  • Control 14 15.6 10.0 1290 900 1.86 0.20 n.a.
  • Example 8 1.0 0.1 19.9 20.1 49.0 50.9 3.4 5.6 35

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Abstract

A multilayer thermally bonded nonwoven fabric which is particularly useful as a liner in an absorbent product is described. The fabric includes at least two prebonded nonwoven webs having a multiplicity of intralaminar bonds bonding the fibers of the prebonded nonwoven webs together. The prebonded webs are secured together to form the fabric of the invention by a plurality of interlaminar thermal bonds formed of discrete areas of compressed and fused fibers of the prebonded webs.

Description

MULTILAYER THERMALLY BONDED NONWOVEN FABRIC
Field of the Invention The present invention relates to nonwoven fabrics and to processes for producing the nonwoven fabrics. More specifically, the invention relates to nonwoven fabrics suitable for use in absorbent products, such as disposable diapers, adult incontinence pads and sanitary napkins, and the like. Backcrround of the Invention Nonwoven fabrics are desirable for use in a variety of products, including bandaging materials, garments, diapers, supportive clothing and personal hygiene products. Nonwoven fabrics that are capable of transmitting body fluids to an absorbent layer while maintaining skin dryness are particularly desirable for use as a coverstock layer in disposable personal care products.
Disposable absorbent products, such as disposable diapers, sanitary napkins, and the like, typically include a liquid impermeable outer covering, an absorbent layer, and an inner layer which contacts the skin of the wearer. To provide a comfortable yet effective product, the inner layer ideally permits liquid to flow through it rapidly into the absorbent layer ("rapid strike through") but does not permit or, at a minimum does not facilitate, re-transmission of liquid from the absorbent layer to the "wearer" side of said inner layer ("resists rewet"). Such inner layers are referred to in the art as coverstock, topsheet, or, in diaper applications, diaper liner.
In addition to liquid transport properties described above, the coverstock must have sufficient strength to allow for converting it, i.e., incorporating it into the final product, and for resistance to failure during vigorous movements by the user. On the other hand, while strength is essential, the coverstock should also present a soft comfortable feel against the user's skin. Currently these conflicting requirements, both softness coupled with strength and rapid strike-through coupled with low surface rewet, are met only imperfectly, typically with the use of coverstock stock made from thin, low basis weight (about 22 grams per square meter or about 20 grams per square yard) carded or spunbonded nonwoven fabrics.
Others have attempted to provide products having improved coverstock performance. U.S. Patent No. 4,041,951 to Sanford discloses a topsheet containing a multiplicity of depressed areas which intimately contact the uppermost surface of a substantially planar, moisture absorbent layer, while the non-depressed areas of the topsheet contact the skin of the wearer in use. The depressed areas are formed by embossing a nonwoven web between a patterned steel roll having male projections thereon and a rubber coated roll. A pattern is formed on the nonwoven web such that the caliper or the density of the web at the depressed embossed sites is not changed from that seen in the un-embossed part of the roll.
U.S. Patent No. 4,854,984 to Ball et. al. teaches a method for dynamically bonding a plurality of laminae together wherein the laminae are forwarded in face to face relation through a pressure-biased nip between a patterned nip and opposing nip, each independently driven to maintain a predetermined surface velocity differential between them. The differential velocity is stated to contribute to shear energy to enable dynamic, mechanically induced bonding. Suzuki et. al. in U.S. Patent. No. 4,704,112 describe a diaper topsheet made by combining two layers of nonwoven webs at their interface by fiber fusion or by hydroentangling. At least one of the webs must be apertured. Meyer et.al. in U.S. Patent No. 4,798,603 teach an absorbent article, i.e., a diaper, that includes a second nonwoven layer under the topsheet and above the absorbent core composed of a material less hydrophilic than said absorbent core and having an average pore size smaller than the topsheet layer pore size. The patent states that bonds used to attach the transport layer to the rest of the diaper construction should not extend completely through the transport layer thickness. Datta et. al. in U.S. Patent No. 4,892,534 describe a nonwoven liner fabric particularly useful for feminine care applications that contains at least three layers of thermoplastic filaments which are laid down via spunbond methods and then bonded together. Schmalz U.S. Patent No. 5,045,387 is directed to a topical treatment of polyolefin containing nonwoven webs. The patent describes the use of a facing or cover sheet for sanitary products such as diapers wherein the webs are made from polypropylene and can be formed by spunbonding. The patent further states that the nonwovens can be formed of one or more bonded webs, and that the nonwoven fabric can be embossed and/or calendar printed with various designs and colors. U.S. Patent Nos. 4,077,410; 4,332,253 and
4,762,520, 4,883,707; 4,304,234 all disclose the use of plural layers of nonwoven fabrics as the topsheet in a sanitary product. Braun in U.S. Patent No. 4,668,566; Raley in U.S. Patent No. 4,761,322; and Modrak in European Patent Application 0490476-A1 teach the combination of one bonded nonwoven web with an unbonded nonwoven web. The resulting combination is bonded together so a final structure results . Meitener in U.S. Patent No. 4,493,868 teaches methods to put multiple bond patterns on a nonwoven web.
U. S. Patent No. 3,934,588 to Mesek et al . discloses a diaper topsheet with areas of preferential flow, surrounded by borders having less transmissivity for aqueous liquids than the preferential flow areas. Mesek teaches the use of areas of reduced thickness via a lesser amount of fibers, areas of increased surfactant concentration, or areas of increased hydrophobic binder application to produce his areas of preferential flow or resistance to flow.
U.S. Patent No. 4,863,785 to Ber an et. al . teaches the combination of a meltblown fabric layer between two prebonded spunbonded nonwoven layers, all continuously bonded together, to form a composite that is highly resistant to the penetration of liquids and thus useful as a sterilization wrap for medical applications. U.S. Patent No. 4,041,203 to Brock et al . teaches the combination of a meltblown fabric layer between two spunbonded layers, all bonded together by discrete bond regions, to form a composite that is also useful in medical applications which require a barrier layer to prevent the passage of liquid and bacteria. Summary of the Invention
The present invention provides a multilayer thermally bonded nonwoven fabric which is particularly useful as a component in an absorbent article. The nonwoven fabrics of the present invention provide improved surface visual patterns or designs.
Hydrophilic nonwoven fabrics of the present invention can provide superior liquid transport properties and thus are particularly useful as the liner layer in an absorbent article. These desirable properties are achieved at reasonable cost while preserving acceptable softness and strength properties. The nonwoven fabrics of the invention include at least two prebonded nonwoven webs. The term "prebonded" refers to the use of nonwoven webs that are each individually bonded to form coherent webs. That is, each of the prebonded webs includes a multiplicity of intralaminar bonds between fibers that bond the fibers of the prebonded nonwoven webs together. Preferably, the prebonded webs are bonded by discrete point bonds located at spaced locations throughout each of the webs. The multilayer thermally bonded nonwoven fabric also includes a plurality of interlaminar thermal bonds which secure the prebonded webs together. To form the interlaminar thermal bonds, discrete areas of the fibers of the prebonded webs are thermally treated so that the fibers are compressed and fused together. In a preferred embodiment of the invention, the discrete areas of compressed and fused fibers form continuous line bonds, which in turn form a pattern of intersecting continuous lines. Further, using such a bond pattern, a quilted, or pillowy texture can be imparted to the surface of the fabrics of the invention.
In another embodiment of the invention, disposable absorbent articles are provided which include as a component a multilayer thermally bonded fabric according to the invention. Certain hydrophilic fabrics of the invention are particularly useful as a component, such as a liner or topsheet layer, in disposable absorbent products such as diapers and the like. In this embodiment of the invention, an absorbent body or layer is sandwiched between the fabric of the invention and an outer backsheet' layer of a substantially liquid impermeable layer.
Hydrophilic nonwoven fabrics of the present invention can provide superior liquid transport properties, i.e., permit liquid to flow through the fabric rapidly while retarding re-transmission of the liquid to the surface of the fabrics. Further, the fabrics of the invention provide a soft, comfortable feel while also having good strength properties. Brief Description of the Drawings
In the drawings which form a portion of the original disclosure of the invention:
Figure 1 is a schematic illustration of one method for producing a multilayer thermally bonded nonwoven fabric in accordance with the invention;
Figure 2 is a fragmentary top plan view of a nonwoven fabric in accordance with the invention;
Figure 3 is a cross sectional view of the nonwoven fabric of Figure 2 taken along line 3-3; Figure 4 is a fragmentary top plan view of one embodiment of an absorbent article incorporating a nonwoven fabric in accordance with the invention;
Figures 5A and 5B are photomicrographs taken at 4X and 8.5X magnification, respectively, of one side of a nonwoven fabric in accordance with the invention; Figures 6A and 6B are photomicrographs taken at 8X and 12.5X magnification, respectively, at an angle of the nonwoven fabric of Figures 5A and 5B;
Figures 7A and 7B are photomicrographs taken at 25X and 206X magnification, respectively, of the nonwoven fabric of Figures 5A and 5B;
Figure 8 is a photomicrograph taken at 5OX magnification of the photomicrograph of Figures 7A and 7B; Figure 9 is a photomicrograph taken at 4X magnification of one side of another nonwoven fabric in accordance with the invention; Figures 10A and 10B are photomicrographs taken at 12.5X and 50X magnification, respectively, at an angle of the nonwoven fabric of Figure 9;
Figures 11A and 11B are photomicrographs taken at 25X and 206X magnification, respectively, of the nonwoven fabric of Figure 9; and
Figure 12 is a photomicrograph taken at 5OX magnification of the photomicrograph of Figures 11A and 11B. Detailed Description of the Invention
In the following detailed description of preferred embodiments of the invention, specific terms are used in describing the invention; however these are used in a descriptive sense only and not for the purpose of limitation. It will be apparent that the invention is susceptible to numerous variations and modifications within its spirit and scope.
Figure 1 is a schematic illustration of one method for producing a multilayer thermally bonded nonwoven fabric in accordance with the invention.
First and second prebonded nonwoven webs 10, 12 are unrolled from respective supply rolls 14 and 16, and directed by suitable guide rolls, such as rolls 18, 20, into opposing, face-to-face relationship to form a two layered structure 22.
Each of the prebonded nonwoven webs 10 and 12 may be formed of substantially continuous filaments or formed of staple fibers. In one embodiment of the invention, at least two prebonded nonwoven webs formed of substantially continuous filaments are provided. In another embodiment of the invention, at least two prebonded nonwoven webs formed of staple fibers are provided. The nonwoven fabrics of the present invention may also include at least one prebonded web of continuous filaments and at least one prebonded web of staple fibers. The webs may be of similar or different fiber compositions and basis weight. As used herein, the term "prebonded" refers to the presence of a multiplicity of intralaminar bonds between fibers in each of the individual webs. The intralaminar bonds bond the fibers of the webs together to give the webs sufficient strength and integrity to withstand handling. Preferably, the intralaminar bonds are discrete point bond sites located at spaced locations throughout the prebonded nonwoven webs. Advantageously, the bond sites have a bond area of about 5 to 30 percent of the area of the web.
Preferably the bonds are thermal bonds formed by heating the fibers so that they soften and become tacky, and fuse together contacting portions of the fibers. The thermal bonds may be formed using any of the techniques known in the art for forming discrete thermal bonds, such as calendering. Other thermal bonding techniques, such as thru-air bonding and the like, may also be used.
Each web contains thermoplastic fibers, and may also include other, non-thermoplastic fibers.
Exemplary thermoplastic polymers include, but are not limited to, polyolefins such as polypropylene and polyethylene, polyesters such as poly(ethylene terephthalate) , polyamides such as poly(hexamethylene adipamide) and poly(caproamide) , and blends and copolymers thereof. The thermoplastic polymer is present in the fibers of the prebonded webs in an amount sufficient so that upon thermal bonding, the fibers in at least one of the webs is compressed and melt-fused with fibers of the other webs to thereby secure the webs together, as described in more detail below.
When webs 10 and/or 12 are formed of staple fibers, the webs may be formed by any of the methods known in the art for forming a nonwoven web of staple fibers, such as carding, air laying, garnetting, and similar processes known in the art. Further, when prebonded nonwoven webs 10 and/or 12 are webs of thermoplastic staple fibers, the nonwoven web may also include other staple thermoplastic and/or natural fibers, such as fibers formed from a polyolefin such as polypropylene and polyethylene, polyester, polyamides, polyacrylates, rayon, cellulose acetate and the like. Natural fibers include cotton fibers, wool fibers, wood pulp fibers and the like. Blends of such fibers can also be used. In one embodiment of the invention, the staple fibers employed can be sheath/core or similar bicomponent fibers. Preferred bicomponent fibers include polyolefin/polyolefin sheath/core fibers such as a polyethylene/polypropylene sheath/core fibers and polyolefin/polyester sheath/core fibers, such as a polyethylene/polyethylene terephthalate sheath/core fiber.
When webs 10 and/or 12 are formed of continuous filaments, the webs may be formed by any of the methods known in the art for forming a nonwoven web of continuous filaments, such as spunbonding processes. As known to the skilled artisan, spunbonding processes generally include the following steps: (1) extruding continuous filaments; (2) quenching the filaments; (3) drawing or attenuating the filaments by a high velocity fluid; and (4) collecting the filaments on a surface to form a web. Exemplary spunbonding techniques are described in U.S. Patent Nos. 3,338,992; 3,341,394; 3,276,944; 3,502,538; 3,502,763; 3,509,009; 3,542,615; and 3,692,618.
An exemplary list of prebonded nonwoven webs used in accordance with the .present invention includes, but is not limited to, spunbond polypropylene nonwoven webs, spunbond polyethylene nonwoven webs, thru-air bonded carded webs of bicomponent fibers, thermobonded carded polypropylene fiber webs, and webs of thermobonded carded blends of polypropylene fiber and rayon fiber. Spunbond polypropylene nonwoven fabrics having a basis weight from about 5 to 30 gsm and thermobonded carded polypropylene fiber nonwoven fabrics having a basis weight -from about 10 to 30 gsm are especially preferred and are available from FIBERWEB North America, Simpsonville., S.C. The preparation of thru-air bonded carded webs of bicomponent fibers is described in U.S. Patent No. 4,883,707. Referring back to Figure 1, two layered structure 22 is conveyed in the longitudinal direction as indicated in Figure 1 to a thermal treatment station 24, illustrated in Figure 1 as heated calender rolls 26 and 28. Here the two layered structure 22 is treated to form a plurality of interlaminar thermal bonds which secure prebonded webs 10 and 12 together to form the product of the invention, fabric 30.
To form the interlaminar thermal bonds, the fibers of prebonded webs 10 and 12 are compressed and fused at discrete areas of the prebonded webs. The operating temperature of heated rolls 26 and 28 should be adjusted to a surface temperature such that the fibers of the prebonded nonwoven webs are compressed and fused together. As used herein, the term "fusing" refers to heating the fibers so that the fibers soften and become tacky, thus adhering to one another. Preferably, the fibers do not completely melt but rather soften without significant loss of individual fiber structural integrity. Bonding conditions, including temperature and pressure, vary according to the particular polymer used and are known in the art for differing polymers.
The thermally bonded nonwoven fabric 30 is then removed from the thermal treatment station 24 and wound by conventional means onto roll 32. The nonwoven fabric can be stored on roll 32 or immediately passed to end use manufacturing processes, for example, for use in bandages, diapers, disposable undergarments, personal hygiene products, and the like.
The heated calender rolls 26 and 28 in Figure 1 may consist of a pair of pattern rolls, a pattern roll and a smooth steel roll, a pattern roll and a rubber roll or other roll combinations known in the art. The pattern of the calender rolls may be any of those known in the art, including spot bonding patterns, helical bonding patterns, line bonding patterns, and the like. The term spot bonding is used herein to be inclusive of continuous or discontinuous pattern bonding, uniform or random point bonding, or a combination thereof, all as are well known in the art. Referring to Figure 2, a fragmentary top plan view of one embodiment of a bonding pattern useful for bonding the nonwoven fabrics of the present invention is illustrated. Specifically, Figure 2 illustrates a nonwoven fabric 36 thermally bonded via interlaminar continuous line bonds, designated generally at 38. In Figure 2, the continuous line bonds comprise lines of discrete areas of compressed and fused fibers of the prebonded webs, as described above, and form a pattern of intersecting lines. That is, intersecting bond lines are arranged so that a repeating "diamond" pattern is formed. By proper choice of the embossing pattern, a wide variety of visual patterns can be produced. In addition, Figure 2 illustrates intralaminar discrete point bond sites, designated generally at 40, in the prebonded webs as described above.
The diamond pattern of Figure 2 illustrates another feature of the nonwoven fabrics of the invention. Figure 2 illustrates a distinct pattern of "pillows" or portions of the surfaces of the individual prebonded webs raised between the intersecting bond lines. This gives a quilt-like appearance to the surface, or topography, of the fabric. This surface feature of the fabrics of the present invention is best illustrated in Figures 6A and 6B, described below. Figure 3 is a cross-section view of the fabric illustrated in Figure 2 taken along line 3-3. Figure 3 illustrates a two layer structure, the intralaminar bonds 40 bonding the fibers of each of the webs together to form coherent webs, and interlaminar bonds 38 bonding the webs together to form a unitary structure. Although a preferred method of bonding has been illustrated in Figure 1, the heated calender rolls 26 and 28 can, in other embodiments of the invention, be replaced by other thermal activation zones which compress and fuse the fibers of the prebonded webs. For example, the thermal treatment station may be in the form of a through-air bonding oven or in the form of a microwave or other RF treatment zones, so long as thermal bonds are formed by compressing and fusing the fibers of the prebonded nonwoven webs. Other heating stations such as ultrasonic welding stations can also be advantageously used in the invention. Such conventional heating stations are known to those skilled in the art and are capable of effecting substantial thermal fusion of the nonwoven webs via thermal bonds.
For example, a process similar to the Pinsonic process taught in U.S. Patent No. 3,733,238, the entirety of which is hereby incorporated by reference, can be used. In this embodiment of the process, a horn could supply sonic energy to two or more prebonded nonwoven webs held against a rotary pattered Anvil roll. By choice of the pattern on the rotary Anvil roll a wide variety of visual patterns or designs can be achieved on the fabric. In a preferred embodiment, the resultant multilayer thermally bonded fabric has hydrophilic properties. When the prebonded webs are formed of a hydrophobic material, such as polypropylene, hydrophilic properties are imparted using any of the techniques known in the art. For example, an additive may be added to the polymer which upon extrusion or upon post formation treatment migrates to the surface of the fibers to impart hydrophilic properties to the surface of the fibers. Alternatively, either of the prebonded webs or the resultant fabric can be treated with any of the surfactants known in the art to thereby impart hydrophilic properties to the fabric. U.S. Patent No. 5,104,728 to Obermeyer and Cashin, the entire disclosure of which is hereby incorporated by reference, describes one such surfactant treatment. The multilayer thermally bonded nonwoven fabrics of the present invention provide several desirable and yet apparently opposing properties in one fabric. Superior liquid transport properties are exhibited by the hydrophilic fabrics of the invention. As noted in results for the samples described in the following examples, very rapid strike-through, nearly 0.5 second faster than current commercially available topsheet, is often seen. Further, surface rewet values are similar to that seen with current commercially available topsheet. This combination of contradictory properties of rapid strike-through yet low surface wetness is highly desirable for liner applications in absorbent articles, such as diaper topsheets.
While not limited to a particular theory of the invention, it is believed that the unique improvement in liquid transport seen in the hydrophilic multilayer nonwoven fabrics of the invention may be due to the interlaminar thermal bonds formed by compressing and melt-fusing fibers of the prebonded nonwoven webs. Modification of the capillary nature of the webs in these bonding regions may promote very rapid liquid transport through the nonwoven fabrics. The balance of the surface of the nonwoven fabrics, comprising multiple layers of initially bonded nonwoven webs, then provides a barrier to rewet back from the diaper core.
The method illustrated in Figure 1 is susceptible to numerous preferred variations. For example, although the schematic illustration of Figure 1 shows nonwoven webs supplied as rolls of preformed webs, it will be apparent that the webs can be formed directly during the in-line process. The multilayer fabric 30 of Figure 1 comprises a two layer structure, but there may be two or more similar or dissimilar webs depending upon the particular properties sought for the fabric.
The hydrophilic nonwoven fabrics of the present invention may be used as a nonwoven component in a disposable absorbent personal care product, such as a liner or "topsheet" layer in a diaper, an incontinence pad, a sanitary napkin, and the like; as a wipe; and the like.
Figure 4 illustrates a fragmentary top plan view of one aspect of this embodiment of the invention. In Figure 4, the hydrophilic nonwoven fabric of the invention is used as a topsheet layer in a disposable diaper, designated generally at 42. Disposable diaper 42 includes a substantially liquid impermeable backsheet layer 44, an absorbent layer 46 positioned on backsheet layer 44, and a topsheet layer 48 positioned on absorbent layer 46, formed of a nonwoven fabric in accordance with the present invention.
As illustrated, topsheet layer 48 and backsheet layer 44 are essentially coextensive and extend out past the edges of absorbent layer 46 to form marginal edges about the periphery of diaper 42. Further, diaper 42 is illustrated as having a general hourglass or I-shape, but as will be appreciated by the skilled artisan, other product shapes may be used, depending upon the desired properties and end use of the product. Diaper 42 can also include means 50 for fastening the diaper on the wearer. As illustrated, fastening means 50 are adhesive tape tabs; however, any of the fastening means known in the art, such as hooks, clips, snaps, and the like, may be used. Backsheet layer 44 may be any of the types of substantially liquid impermeable layers known in the art for use with disposable absorbent products. For example, backsheet layer 44 may be a polymer film, such as a polyolefin film, such as polypropylene or polyethylene. Backsheet layer 44 can also include a nonwoven material, such as a spunbonded nonwoven web, which has been suitably treated to impart a desired degree of liquid impermeability thereto, for example, by combining the nonwoven material with a polymer film. Absorbent layer 46 can be any of the absorbent layers known in the art for use in an absorbent disposable product. For example, absorbent layer 46 can be a preformed web substantially made of cotton-like woody pulp. Wood pulp may be included in the absorbent layer, preferably by incorporating the wood fiber from a hammer milled water laid web or from an air laid web which may contain staple textile fibers, such as cotton, reconstituted cellulose fibers, e.g., rayon and cellulose acetate, polyolefins, polyamides, polyesters, and acrylics. The absorbent layer may also include an effective amount of an inorganic or organic high-absorbency (e.g., superabsorbency) material as known in the art to enhance the absorptive capability of the absorbent layer.
The nonwoven fabric may be combined with absorbent layer 46 and substantially liquid impermeable backsheet layer 44 in any of the ways known in the art, such as gluing with lines of hot-melt adhesive, seaming with ultrasonic welding, thermal bonding, high pressure bonding and the like. By using a topsheet layer comprising the hydrophilic multilayer nonwoven fabric of the present invention, the topsheet layer advantageously permits liquid to rapidly flow through it into the absorbent layer but does not facilitate re-transmission of liquid back from the absorbent layer to the body side of the topsheet.
The following examples serve to illustrate the invention but are not intended to be limitations thereon.
ILLUSTRATIVE EXAMPLES Exampl e 1 Three hydrophilic spunbonded webs, each having a basis weight of approximately 10 gsm (8.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 137°C (278°F) and a steel roll having an inverse diamond pattern on its surface and maintained at about 133°C (272°F) . The inverse diamond pattern consists of two sets of raised parallel lands approximately 1 mm in height and 1 mm in width and spaced approximately between 4.85 and 4.90 mm from each other. The intersection of the two sets of parallel lands at 4.85 to 4.90 mm intervals results in a configuration of squares with the diagonals of the squares aligned in the machine and cross-machine directions, giving the perception of a diamond pattern when viewed in the machine direction. The rolls were compressed together under a pressure of about 890 kg/ (50 pounds per linear inch (pli) ) and the webs were passed between the rolls at a speed of about 4 meters/minute (12 feet per minute (fpm) ) . We observed a good visible diamond pattern that imparted a quilted or "pillowy" texture to the fabric. Figures 5A and 5B are Scanning Electron Microscope (SEM) photomicrographs of the nonwoven fabric of Example 1, taken perpendicular to the plane of the fabric at 4X and 8.5X magnifications, respectively. Figures 5A and 5B illustrate interlaminar continuous calender bonds of the fabric of the invention as well as intralaminar point bond sites of the prebonded nonwoven webs used to construct the fabric. Figures 6A and 6B are photomicrographs taken at an angle to the plane of the fabric of Example 1 at 8X and 12.5X magnifications, respectively. Figures 6A and 6B illustrate the quilted-like topography of the fabric. These photographs again show the interlaminar continuous bonds of the fabric as well as the intralaminar point bond sites of the prebonded spunbonded nonwoven webs used to construct the fabric. Figures 7A and 7B are photomicrographs taken of the product of Example 1 taken at magnifications of 25X and 206X, respectively. Figures 7A and 7B illustrate the interlaminar continuous calender bonds used to secure together the fabric of Example 1, and also illustrate bond formation by compression and elt- fusion or partial melt-fusion of fibers from the prebonded webs used to construct this product of the invention.
Figure 8 is a photomicrograph taken at 5OX magnification of the interlaminar continuous calender bond featured in photographs 7A and 7B used to secure together the webs of the fabric of Example 1. Figure 8 illustrates, to a greater degree, the level of melt- fusion or partial melt-fusion of fibers from prebonded webs used to construct this product of the invention. A hand-made diaper was produced using material from Example 1 as the topsheet. A generic diaper having elastic leg bands was anchored to a stationary stand using clamps and stretched to overcome the effect of the elasticity of the leg bands so that the surface of the diaper was flat with no existing wrinkles. The existing nonwoven topsheet was detached from the diaper body by carefully cutting the topsheet alongside the inside of the existing elastic leg bands and waist shield, leaving both the leg bands and waist shield intact as part of the diaper construction. The nonwoven topsheet and underlying tissue layer was carefully removed from the diaper body without destroying the diaper core. The tissue layer was replaced with a commercially available tissue product. The nonwoven topsheet was replaced with Example 1 material and secured with hot melt glue using a commercially available hot-glue gun applicator. The pattern was clearly visible on the diaper, and the diaper had an attractive hand feel.
Example 2 Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 138°C (280°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) . Example 3
Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 137°C (278°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 138°C (280°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
Exampl e 4 Two hydrophilic carded webs, each having a basis weight of approximately 21 gsm (17.7 g/yd2) and consisting of 100 percent 1.8 denier per filament (dpf) polypropylene staple fiber (commercially available from Amoco Fabrics and Fibers Company under the trade name of Amoco Type 030) and prebonded having a total bonded area of approximately 25 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 134°C (274°F) and a steel roll having a inverted diamond pattern on its surface as described in Example 1 and maintained at about 134°C (273°F) . The rolls were compressed together under a pressure of about 893 kg/m (50 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
Example 5 Two hydrophilic carded webs, each having a basis weight of approximately 14 gsm (12.0 g/yd2) and consisting of 100 percent 1.5 dpf polypropylene staple fiber and prebonded having a total bonded area of approximately 25 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 134°C (274°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of about 893 kg/m (50 pli) and the webs were passed between the rolls at a speed of about 6 mpm (20 fpm) . Exampl e 6 A hydrophilic spunbonded web having a basis weight of approximately 15 gsm (12.5 g/yd2) and composed of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent was overlaid with a hydrophilic carded web having a basis weight of approximately about 16 gsm (13.5 g/yd2) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent. The two-layered assembly was then secured together via calendering between a smooth surfaced steel roll maintained at about 136°C (276°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 135°C (275°F) . The rolls were compressed together under a pressure of about 839 kg/m (50 pli) and the webs were passed between the rolls at a speed of about 6 mpm (20 fpm) . Example 7
Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 135°C (275°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
Exampl e 8 Two hydrophilic carded webs, each having a basis weight of 16 gsm (13.5 g/yd2) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 135°C (275°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 135°C (275°F) . The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) . Example 9
One hydrophilic carded web, not a product of the invention, having a basis weight of 32 gsm (27.0 g/yd2) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent was calendering between a smooth surfaced steel roll maintained at about 136°C (276°F) and a steel roll having an inverse diamond pattern on its surface as described in Example 1 and maintained at about 136°C (276°F) . The sample was compressed under a pressure of about 1785 kg/m (100 pli) and was passed between the rolls at a speed of about 4 mpm (12 fpm) .
Example 10 Two hydrophilic carded webs, each having a basis weight of 16 gsm (13.5 g/yd2) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent, were secured together via calendering between a smooth surfaced steel roll maintained at about 137°C (279°F) and a steel roll having a wavy line pattern on its surface and maintained at about 136°C (277°F). The wavy line pattern consisted of multiple lines approximately 1 mm in width with a 5 mm spacing between lines, having a wavelength of approximately 40 mm with an approximately 7 mm modulation on each side of the axis running parallel with and intersecting the wavelength. The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
Example 11 One hydrophilic carded web, product not part of the invention, having a basis weight of about 32 gsm (27.0 g/yd2) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Example 4 and prebonded having a total bonded area of approximately 17 percent was calendering between a smooth surfaced steel roll maintained at about 135°C (275°F) and a steel roll having a wavy line pattern on its surface and maintained at about 136°C (276°F) . The wavy line pattern consisted of multiple lines approximately 1 mm in width with a 5 mm spacing between lines, having a wavelength of approximately 40 mm with an approximately 7 mm modulation on each side of the axis running parallel with and intersecting the wavelength. The rolls were compressed together under a pressure of about 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) .
Example 12 Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent, were secured together via calendering between two rolls, each having raised continuous helical lands as described in U.S. Pat. No. 4,863,785 to Berman et al. The bottom of the two rolls was maintained at about 137°C (278°F) and the top of the two rolls maintained at about 136°C (276°F) . The rolls were compressed together under a pressure of 1785 kg/m (100 pli) and the webs were passed between the rolls at a speed of about 4 mpm (12 fpm) . Figure 9 is a photomicrograph of the fabric of Example 12 taken perpendicular to the plane of the fabric at 4X magnification. Figure 9 illustrates interlaminar discontinuous calender bonds of the invention created by calendering the prebonded webs between two rolls, each having raised continuous helical lands as described in U.S. Patent No. 4,863,785 above, as well as intralaminar discontinuous discrete point bonds of the prebonded spunbonded nonwoven webs used to construct the fabric of the invention.
Figures 10A and 10B are photomicrographs taken at an angle to the plane of the fabric of Example 12 at 12.5X and 50X magnifications, respectively. Figures 10A and 10B illustrate the textured-like topography of the fabric of Example 12. These photographs again show interlaminar discontinuous calender bonds of the invention created by calendering the prebonded webs between two rolls, each having raised continuous helical lands as described in U.S. Patent No. 4,863,785 above, as well as intralaminar discontinuous bonds of the prebonded spunbonded nonwoven webs used to construct the fabric of the invention.
Figures 11A and 11B are photomicrographs taken at 25X and 206X magnifications, respectively, of the fabric of Example 12. Figures 11A and 11B illustrate the interlaminar discontinuous calender bonds used to secure together the fabric of Example 12. Figures 11A and 11B also illustrate bond formation by compression and melt-fusion or partial melt-fusion of fibers from prebonded webs used to construct this product.
Figure 12 is a photomicrograph taken at 5OX magnification of the interlaminar discontinuous calender bond featured in Figures 11A and 11B that was used to secure together Example 12. Figure 12 illustrates, to a greater degree, the level of melt- fusion or partial melt-fusion of fibers from prebonded webs used to construct this product.
A hand-made diaper was produced using material from Example 12 as the topsheet. A generic diaper having elastic leg bands was anchored to a stationary stand using clamps and stretched to overcome the effect of the elasticity of the leg bands so that the surface of the diaper was flat with no existing wrinkles. The existing nonwoven topsheet was detached from the diaper body by carefully cutting the topsheet alongside the inside of the existing elastic leg bands and waist shield, leaving both the leg bands and waist shield intact as part of the diaper construction. The nonwoven topsheet and underlying tissue layer was carefully removed from the diaper body without destroying the diaper core. The tissue layer was replaced with a commercially available tissue product. The nonwoven topsheet was replaced with Example 12 material and secured with hot melt glue using a commercially available hot-glue gun applicator. The pattern was visible on the diaper, and the diaper had an attractive handfeel.
CONTROLS FOR ILLUSTRATIVE EXAMPLES Control Example 1A One hydrophilic spunbonded web similar to commercially available products of FIBERWEB North America having a basis weight of approximately 10 gsm (8.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 1.
Control Example IB Three hydrophilic spunbonded webs, each having a basis weight of approximately 10 gsm (8.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid ih a three-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 1. The basis weight and caliper were evaluated on the one- layer uncalendered control samples and tripled for the uncalendered multi-layered control examples.
Control Example IC One hydrophobic spunbonded web similar to commercially available products of FIBERWEB North
America, a product not part of the invention, having a basis weight of approximately 34 gsm (28.4 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent was post-processed via calendering between a smooth surfaced steel roll maintained at about 138°C (281°F) and a steel roll having an inverse diamond pattern on its surface and maintained at about 137°C (278°F) for evaluation of visible pattern against Illustrative Example 1.
This sample had a visible diamond pattern but did not have the quilted or "pillowy" hand-feel as seen with Illustrative Example 1.
Control Example 2 A One hydrophilic spunbonded web similar to commercially available products of FIBERWEB North America having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 2.
Control Example 2B Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 2. Control Example 3 A
One hydrophilic spunbonded web similar to commercially available products of FIBERWEB North America having a basis weight of approximately 18 gsm (15.0 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 3.
Control Example 3B Two hydrophilic spunbonded webs, each having a basis weight of approximately 18 gsm (15.0 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 3.
Control Exampl e 4 A One hydrophilic carded web having a basis weight of approximately 21 gsm (17.7 g/yd2) and consisting of 100 percent 1.8 denier per filament (dpf) polypropylene staple fiber (commercially available from Amoco Fabrics and Fibers Company under the trade name of Amoco Type 030) and prebonded having a total bonded area of approximately 25 percent but not post-processed via calendering was evaluated as characterized in Table I-A as a control against Illustrative Example 4.
Control Exampl e 4B Two hydrophilic carded webs, each having a basis weight of approximately 21 gsm (17.7 g/yd2) and consisting of 100 percent of the same 1.8 dpf polypropylene staple fiber used in Control Example 4A above and prebonded having a total bonded area of approximately 25 percent, were overlaid in a two- layered assembly without being secured together via calendering and then evaluated as characterized in Table I-A as a control against Illustrative Example 4.
Control Example 12 A One hydrophilic spunbonded web having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 to 10 percent but not post-processed via calendering was evaluated as characterized in Table I-B as a control against Illustrative Example 12.
Control Example 12B Two hydrophilic spunbonded webs, each having a basis weight of approximately 15 gsm (12.5 g/yd2) and consisting of 100 percent polypropylene filaments prebonded using a total bonded area of approximately 6 and 10 percent, were overlaid in a two-layered assembly without being secured together via calendering and then evaluated as characterized in Table I-B as a control against Illustrative Example 12.
Control Example 13 Typical physical and moisture transport properties as measured from commercially available spunbond polypropylene diaper topsheet material available from Fiberweb North America, Inc. are characterized in Table I-B.
Control Example 14 Typical physical and moisture transport properties as measured from commercially available reduced basis weight spunbond polypropylene diaper topsheet available from Fiberweb, North America, Inc. are characterized in Table I-B. Control Exampl e 15
Typical physical and moisture transport properties as measured from commercially available carded polypropylene diaper topsheet material available from Fiberweb North America, Inc. are characterized in Table I-B.
The strip tensile strength, caliper (under compression) , strike-through and surface rewet properties of the samples in the foregoing examples were tested according to the procedures outlined below. Additionally, softness, fuzz level, handle-o-meter and drape length of certain of the examples were also tested according to the procedures outlined below. The basis weight and caliper values for the multiple-layer control examples were not measured but the values measured for the single-layer control examples were multiplied by the applicable factor and listed in Tables I-A and I-B.
Strip Tensile Strength
Strip tensile strength was evaluated by breaking a one inch long sample generally following ASTM D1682-64, the One-Inch Cut Strip Test. The instrument crosshead speed was set at 2 inches per minute and the gauge length was set at 3 inches. The tensile strength in both the machine direction (MD) and the cross machine direction (CD) was evaluated. The strip tensile strength or breaking load, reported in grams per inch, is the average of at least eight measurements. Caliper (Under Compression)
Caliper was determined by measuring the distance between the top and the bottom surface of the sheet generally following ASTM D1777-64 while the sheet was held under a compression loading of 95 grams per square inch. The result, reported in mils, is generally the average of ten measurements. Strike-Through Strike-through was evaluated by a method similar to that described in U.S. Patent Nos. 4,041,951 and 4,391,869, incorporated herein by reference. Strike-through was measured as the time for 5 ml of synthetic urine solution, placed in the cavity of the strike-through plate, to pass through the sample fabric into an absorbent pad. The result, reported in seconds, is generally the average of four tests. Surface Wetness
Surface Wetness was evaluated by a method similar to that described in U.S. Patent Nos. 4,041,951 and 4,391,869, incorporated herein by reference. Surface Wetness, reported in grams, was evaluated by adding synthetic urine through the sample into the absorbent pad until the absorbent pad was nearly saturated. Thus, the sample fabric was wet at the beginning of the surface rewet test. For results denoted as Surface Wetness A, the loading factor was slightly less than 4 grams of synthetic urine per gram of absorbent sample. A uniform pressure loading of 0.5 psi was then applied and the procedure concluded as disclosed in the above patents. For results denoted as Surface Wetness B, the loading factor was increased to slightly more than 4 grams of synthetic urine per gram of absorbent sample so that the absorbent pad was saturated with synthetic urine. A uniform loading pressure of 1.0 psi was then applied and the procedure concluded as disclosed in the above patents. The results, reported in grams, is generally the average of four tests. Surface Wetness A is believed to be a good indicator for baby diapers that do not include Super Absorbent Powder. Surface Wetness B is believed to be a good indicator for adult diapers. Softness
Softness of selected examples was evaluated by an organoleptic method wherein an expert panel compared the surface feel of Example Fabrics with that of controls. Results are reported as a softness score with the higher values denoting a more pleasing hand. Each reported value is for a single fabric test sample but reflects the input of several panel members. Fuzz
The surface of selected samples was evaluated for fuzz by rubbing a slightly abrasive surface cyclically over the fabric surface. The fibers removed from the surface of the sample are weighed and the results reported as a fuzz level with the lower values denoting an increased resistance to fuzz generation. The results, reported in milligrams (mg) , are generally the average of four tests. Handle-0-Meter
Stiffness of selected examples was evaluated following INDA 1ST 90.0-75 (R82) Handle-O-Meter Stiffness test procedure. Handle-O-Meter was measured as the force required to deform the fabric into a slot with parallel edges by means of a moving blade. The results, reported in grams, is generally the average of eight tests. Drape Length
Flexibility of selected examples was evaluated following ASTM D 1388-64 (1975) Cantilever test procedure. Drape Length was measured as the distance required for the test specimen to break a predetermined plane when extended horizontally from the test surface as defined in the specified procedure. The results, reported in centimeters (cm) , is generally the average of eight tests.
Table I-A MULTILAYER THERMALLY BONDED NONWONEN FABRIC FOR SANITARY APPLICATIONS
SAMPLE BASIS WEIGHT CALIPER TENSILES (g/in) STRIKETHROUGH REWET <g)
(g/yd2) (mils) (sec)
MD CD A B
(0.5 psi Compression) (1.0 psi Compression)
Example 1 30.2 15.6 1765 1355 1.19 0.12 1.17
Control 1A 8.5 4.5 530 440 2.09 0.76 2.10
Control IB 25.5 13.5 n.a. n.a. 1.78 0.14 0.31
Example 2 26.2 13.7 1950 1615 1.48 0.13 2.40
Control 2A 12.6 6.1 875 745 1.93 0.17 1.87
Control 2B 25.2 12.2 n.a. n.a. 1.89 0.14 0.51
Example 3 32.2 17.3 2390 2080 1.20 0.12 1.90
Control 3A 15.0 7.5 1095 1160 2.45 0.12 1.45
Control 3B 30.0 15.0 n.a. n.a. 1.76 0.11 0.48
Example 4 37.4 17.4 2975 620 1.19 0.84 2.96
Control 4A 17.7 6.7 1375 690 2.02 0.76 3.34
Control 4B 35.4 13.4 n.a. n.a. 1.97 1.15 3.30
Example 5 25.4 11.6 2105 460 1.56 0.17 2.68 n.a. = Not Available
Table I-B MULTILAYER THERMALLY BONDED NONWONEN FABRICS FOR SANITARY APPLICATIONS
Figure imgf000034_0001
SAMPLE BASIS WEIGHT CALIPER TENSILES (g/in) STRIKETHROUGH REWET (g)
(g/yd2) (mils) (sec)
MD CD A B (0.5 psi Compression) (1.0 psi Compression)
Example 6 27.7 11.8 1565 670 1.60 0.37 n.a.
Example 7 25.0 10.3 1560 1425 1.52 0.09 n.a.
Example 8 28.8 12.4 1200 194 2.08 0.39 n.a.
Example 91 28.5 14.2 718 205 1.84 0.20 n.a.
Example 10 30.0 15.3 1420 298 1.73 0.12 n.a.
Example l l1 30.0 16.3 1125 214 1.73 0.12 n.a.
Example 12 26.2 12.4 1830 1555 1.53 0.12 0.73 Control 12 A 12.6 6.1 875 745 1.93 0.17 1.87 Control 12B 25.2 12.2 . n.a. n.a. 1.89 0.14 0.51
Control 13 18.5 10.0 1165 870 1.70 0.11 n.a.
Control 14 15.6 10.0 1290 900 1.86 0.20 n.a.
Control 15 19.2 11.2 2550 440 2.06 0.18 n.a. n.a. = Not Available
--Not a product of our invention .
Table II MULTILAYER THERMALLY BONDED NONWOVEN FABRIC FOR SANITARY APPLICATIONS
SAMPLE FUZZ (mg) HANDLE-O-METER (g) DRAPE LENGTH (cm) SOFTNESS
Top1 Bottom CD CD MD MD CD MD Top Bottom Top Bottom
Example 8 1.0 0.1 19.9 20.1 49.0 50.9 3.4 5.6 35
Example 92 4.2 2.4 22.6 25.5 40.9 46.1 3.4 4.6 55
Example 10 2.2 0.6 36.8 36.6 48.4 46.5 4.4 5.2 53
Example ll2 3.1 5.9 39.1 41.7 49.9 51.4 3.9 4.7 53
Figure imgf000035_0001
--Top represents patterned surface of the sample. Bottom represents the side of the sample contacting the smooth roll during calendering.
2Not a product of our invention.
The invention has been described in considerable detail with reference to its preferred embodiments. However, it will be apparent that numerous variations and modifications can be made without departure from the spirit and scope of the invention as described in the foregoing specification and defined in the appended claims.

Claims

CLAIMS :
1. A multilayer thermally bonded nonwoven fabric which is particularly useful as a component in an absorbent product, said fabric comprising first and second prebonded nonwoven webs and a plurality of interlaminar thermal bonds securing together said first and second prebonded nonwoven webs.
2. The multilayer thermally bonded nonwoven fabric according to Claim 1, wherein said first and second prebonded nonwoven webs each comprise a multiplicity of intralaminar bonds bonding the fibers of said prebonded nonwoven webs together to form a coherent web.
3. The multilayer thermally bonded nonwoven fabric according to Claim 1 or 2, wherein said intralaminar bonds comprise discrete point bonds at spaced locations throughout said webs.
4. The multilayer thermally bonded nonwoven fabric according to Claim 3 wherein said point bonds have a bond area of from about 5 to 30 percent of the area of the webs.
5. The multilayer thermally bonded nonwoven fabric according to any one of Claims 1 to 4, wherein said first and second prebonded nonwoven webs are arranged in opposing face-to-face relationship and wherein said interlaminar thermal bonds comprise discrete areas of compressed and fused fibers of said face-to-face prebonded nonwoven webs.
6. The multilayer thermally bonded nonwoven fabric according to any one of Claims 1 to 5, wherein said interlaminar thermal bonds comprise continuous line bonds securing together fibers of said first and second prebonded nonwoven webs.
7. The multilayer thermally bonded nonwoven fabric according to Claim 6, wherein said continuous line bonds comprise lines of compressed and fused fibers of said first and second prebonded nonwoven webs.
8. The multilayer thermally bonded nonwoven fabric according to Claim 7 wherein said continuous line bonds form a pattern of intersecting continuous lines, and further comprising raised portions of the surfaces of said first and second nonwoven webs between said intersecting continuous lines to give the surface of said fabric a quilt-like topography.
9. The multilayer thermally bonded nonwoven fabric according to any preceding claim wherein at least one of said first and second prebonded nonwoven webs has hydrophilic properties.
10. The multilayer thermally bonded nonwoven fabric according to any preceding claim wherein said nonwoven fabric is liquid permeable.
11. The multilayer thermally bonded fabric according to any one of Claims 1 to 10 wherein the first prebonded nonwoven web comprises thermoplastic substantially continuous filaments and the second prebonded nonwoven web comprises thermoplastic staple fibers.
12. The multilayer thermally bonded nonwoven fabric according to Claim 11 wherein said first prebonded nonwoven web is a spunbonded nonwoven web formed of continuous filaments of a thermoplastic polymer, said web having a basis weight of about 5 to 30 g/m2, and having a multiplicity of intralaminar bond sites bonding the continuous filaments together to form a coherent web; and wherein said second prebonded nonwoven web is a carded nonwoven web formed of staple fibers of a thermoplastic polymer, and arranged in opposing face-to-face relationship with said first web, said second web having a basis weight of about 10 to 30 g/m2, and having a multiplicity of intralaminar bond sites bonding the staple fibers together to form a coherent web; and wherein said plurality of interlaminar thermal bonds securing together said first and second nonwoven webs, comprises areas wherein the first and second webs are compressed and fused together.
13. The multilayer thermally bonded fabric according to any one of Claims 1 to 10 wherein each of said first and second prebonded nonwoven webs comprise thermoplastic substantially continuous filaments.
14. The multilayer thermally bonded fabric according to claim 13 wherein said first and second continuous filament nonwoven webs are arranged in opposing face-to-face relationship, said webs each having a basis weight of about 5 to 30 g/m2, and said webs each including a multiplicity of intralaminar bond sites bonding the continuous filaments together to form a coherent web; and wherein said plurality of interlaminar thermal bonds comprise areas wherein the filaments of said first and second webs are compressed and fused together.
15. The multilayer thermally bonded nonwoven fabric according to any one of Claims 11 to 14 wherein said continuous filaments are polypropylene continuous filaments.
16. The multilayer thermally bonded fabric according to any one of Claims 1 to 10 wherein each of said first and second prebonded nonwoven webs comprise thermoplastic staple fibers.
17. The multilayer thermally bonded nonwoven fabric, according to Claim 16, wherein said first and second staple fiber nonwoven webs are arranged in opposing face-to-face relationship, said webs each having a basis weight of about 10 to 30 g/m2, and said webs each including a multiplicity of intralaminar bond sites bonding the staple fibers together to form a coherent web; and wherein said plurality of interlaminar thermal bonds comprise areas wherein the fibers of said first and second webs are compressed and fused together.
18. The multilayer thermally bonded nonwoven fabric according to Claim 16 or 17 wherein said staple fibers are polypropylene staple fibers.
19. The multilayer thermally bonded nonwoven fabric according to Claim 16 or 17 wherein said staple fibers are bicomponent staple fibers.
20. The multilayer thermally bonded nonwoven fabric according to Claim 19 wherein said bicomponent staple fibers have a polyester core and a polyethylene sheath.
21. The multilayer thermally bonded nonwoven fabric according to any preceding claim additionally comprising an absorbent layer adjacent one side of said thermally bonded nonwoven fabric and a substantially liquid impermeable layer adjacent an opposite side of said absorbent layer, said thermally bonded layer, said absorbent layer and said liquid impermeable layer being secured together to form an absorbent article.
22. The multilayer thermally bonded nonwoven fabric according to Claim 21, wherein said absorbent article is a diaper.
23. The multilayer thermally bonded nonwoven fabric according to Claim 21, wherein said absorbent article is a feminine sanitary napkin.
24. A method for producing a multilayer thermally bonded nonwoven fabric which is particularly useful as a component in an absorbent product, comprising: directing a first prebonded nonwoven web and a second prebonded nonwoven web into opposing face-to- face relationship; and forming interlaminar thermal bonds between said first and second prebonded webs at a plurality of areas to secure together said first and second prebonded nonwoven webs.
25. The method according to Claim 24 further comprising, prior to said directing step, the step of bonding the fibers of said first and second nonwoven webs together at a multiplicity of intralaminar bonds to form coherent webs.
26. The method according to Claim 24 or 25 wherein said step of bonding the fibers of said first and second webs comprises forming a multiplicity of discrete point bonds having a bond area of about 5 to 30 percent of the area of the webs.
27. The method according to any one of Claims 24 to 26 wherein said step of forming interlaminar thermal bonds comprises compressing and fusing the fibers of said first and second prebonded nonwoven webs.
28. The method according to any one of Claims 24 to 27 wherein said step of compressing and fusing comprises forming continuous line bonds securing said first and second prebonded nonwoven webs.
29. The method according to Claim 28 wherein said step of forming continuous line bonds comprises forming a pattern of intersecting lines, and forming raised portions of the surfaces of said first and second nonwoven webs located between said intersecting continuous lines to give the surface of said fabric a quilt-like topography.
30. The method according to any one of Claims 24 to 29 further comprising, after said step of forming interlaminar thermal bonds, the step of securing an absorbent layer to one side of said multilayer thermally bonded fabric.
31. The method according to Claim 30 further comprising the step of securing a substantially liquid impermeable layer to the opposite side of said absorbent layer.
32. The method according to any one of Claims 24 to 31 including forming said first prebonded nonwoven web and said second prebonded nonwoven web from continuous filaments of a thermoplastic polymer and forming a multiplicity of discrete intralaminar bond sites at spaced locations throughout each of said first and second nonwoven webs to form coherent webs, and wherein said step of forming interlaminar thermal bonds comprises directing said first prebonded nonwoven web and said second prebonded nonwoven web into opposing face-to-face relationship and compressing and fusing the filaments of said webs to form said interlaminar thermal bonds between said first and second webs.
33. The method according to any one of
Claims 24 to 31 including forming said first prebonded nonwoven web and said second prebonded nonwoven web from staple fibers of a thermoplastic polymer and forming a multiplicity of discrete intralaminar bond sites at spaced locations throughout each of said first and second nonwoven webs to form coherent webs, and wherein said step of forming interlaminar thermal bonds comprises directing said first prebonded nonwoven web and said second prebonded nonwoven web into opposing face-to-face relationship and compressing and fusing the fibers of said webs to form said interlaminar thermal bonds between said first and second webs.
34. The method according to any one of Claims 24 to 31 including forming said first prebonded nonwoven web from continuous filaments of a thermoplastic polymer; forming said second nonwoven web of staple fibers of a thermoplastic polymer; forming a multiplicity of discrete intralaminar bond sites at spaced locations throughout each of said first and second nonwoven webs to form coherent webs, and wherein said step of forming interlaminar thermal bonds comprises directing said first prebonded nonwoven web and said second prebonded nonwoven web into opposing face-to-face relationship and compressing and fusing the fibers and filaments of said webs to form said interlaminar thermal bonds between said first and second webs.
PCT/US1994/009893 1993-09-03 1994-09-02 Multilayer thermally bonded nonwoven fabric WO1995006770A1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19626997A1 (en) * 1996-07-05 1998-01-08 Saueressig Gmbh & Co Point bonding of sanitary cellulose layers
WO2002031245A2 (en) * 2000-10-13 2002-04-18 The Procter & Gamble Company Abrasion resistant, soft nonwoven
US11020932B2 (en) 2017-06-30 2021-06-01 The Procter & Gamble Company Tip bonded formed laminates of film
US11020938B2 (en) 2018-12-20 2021-06-01 The Procter & Gamble Company Bonded laminate including a formed nonwoven substrate

Citations (4)

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Publication number Priority date Publication date Assignee Title
CH351527A (en) * 1956-11-12 1961-01-15 Mueller Paul A Endless card web made of loose fiber material as well as method and device for their production
EP0106604A2 (en) * 1982-09-30 1984-04-25 Chicopee Patterned belt bonded material and method for making the same
GB2239215A (en) * 1988-06-11 1991-06-26 Vita Fibres Ltd Fibre insulating pads
EP0586937A1 (en) * 1992-08-26 1994-03-16 Kimberly-Clark Corporation Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH351527A (en) * 1956-11-12 1961-01-15 Mueller Paul A Endless card web made of loose fiber material as well as method and device for their production
EP0106604A2 (en) * 1982-09-30 1984-04-25 Chicopee Patterned belt bonded material and method for making the same
GB2239215A (en) * 1988-06-11 1991-06-26 Vita Fibres Ltd Fibre insulating pads
EP0586937A1 (en) * 1992-08-26 1994-03-16 Kimberly-Clark Corporation Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19626997A1 (en) * 1996-07-05 1998-01-08 Saueressig Gmbh & Co Point bonding of sanitary cellulose layers
WO2002031245A2 (en) * 2000-10-13 2002-04-18 The Procter & Gamble Company Abrasion resistant, soft nonwoven
WO2002031245A3 (en) * 2000-10-13 2002-07-11 Procter & Gamble Abrasion resistant, soft nonwoven
US11020932B2 (en) 2017-06-30 2021-06-01 The Procter & Gamble Company Tip bonded formed laminates of film
US11345119B2 (en) 2017-06-30 2022-05-31 The Procter & Gamble Company Methods of forming laminates
US11020938B2 (en) 2018-12-20 2021-06-01 The Procter & Gamble Company Bonded laminate including a formed nonwoven substrate
US11833805B2 (en) 2018-12-20 2023-12-05 The Procter & Gamble Company Bonded laminate including a formed nonwoven substrate

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