WO1995006144A1 - Procede et dispositif d'electrolyse de l'eau - Google Patents

Procede et dispositif d'electrolyse de l'eau Download PDF

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Publication number
WO1995006144A1
WO1995006144A1 PCT/JP1994/001366 JP9401366W WO9506144A1 WO 1995006144 A1 WO1995006144 A1 WO 1995006144A1 JP 9401366 W JP9401366 W JP 9401366W WO 9506144 A1 WO9506144 A1 WO 9506144A1
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WO
WIPO (PCT)
Prior art keywords
water
vibration
molecules
molecule
hydrogen
Prior art date
Application number
PCT/JP1994/001366
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English (en)
Japanese (ja)
Inventor
Yoshihiko TAKESHITA (deceased)
Original Assignee
OSHIDA, Hisako +hf
KAMIYA, Yoshiko +hf
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OSHIDA, Hisako +hf, KAMIYA, Yoshiko +hf filed Critical OSHIDA, Hisako +hf
Publication of WO1995006144A1 publication Critical patent/WO1995006144A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the electrode placed in water is vibrated at a frequency of a natural vibration at which any one of oxygen molecules, hydrogen molecules, and water molecules resonates, or is vibrated at a multiple wavelength of the wavelength of the natural vibration to produce the oxygen.
  • one of the molecules, hydrogen, or water molecules resonates, it is energized in water, or resonates as described above, and the electrodes are magnetized in a magnetic field, and the water is energized in water to excite water.
  • the present invention relates to a water electrolysis method and apparatus for performing electrolysis.
  • the proposal to promote the separation of hydrogen bubbles by vibration of a vehicle body, etc. can be expected to reduce the electricity required for electrolysis even if the efficiency is slightly improved.
  • the purpose of the present invention is different from that of the present invention because the purpose of the present invention is to provide clean energy and is not to improve the efficiency of water electrolysis.
  • the technology for raising the temperature inside the electrolytic cell has a different purpose from that of the present invention, and the solution is completely different, so that the same effect cannot be expected as a result.
  • the present invention focuses on the natural vibration of oxygen molecules, hydrogen molecules, or water molecules of water, and by generating resonance in any one of them, dramatically improves the electrolysis efficiency of water. This made edible the electrolysis of water with extremely high efficiency that could not be achieved with the improved technology.
  • the wave number 2 of the natural oscillation of the time of generating the hydrogen molecule 2 5 0 cm- vibration or wavelength 4. 4 X 1 0 _ 4 cm water hydrogen partial child by applying vibration by multiple wavelengths in 1 was resonated, and the desorption of hydrogen molecules was promoted. Furthermore, it is also possible to simultaneously apply vibration of the natural frequency of the oxygen molecule or water molecule or vibration at a multiple of the wavelength of the natural vibration to simultaneously resonate the oxygen and water molecules.
  • each of the 5 ⁇ can be easily resonated when the vibration of the frequency of the natural vibration of each molecule is given or when the vibration of a multiple wavelength of the wavelength of the natural vibration is given.
  • a vibration having a wavelength that is a multiple of the wavelength is given, not only the resonance can be easily performed, but also the multiple wavelength can be radiated, so that it is easy to match the conditions under which each molecule can resonate. Can be.
  • water can be extremely efficiently generated.
  • the amount of hydrogen generated during electrolysis at 144 W in the past and the amount of hydrogen generated during electrolysis at 36 W to 48 W according to the present invention are substantially equal. Therefore, it can be seen that the power consumption is 1/3 to 1/4 that of the conventional electrolysis method and equipment, even if the efficiency is slightly higher or lower depending on the conditions of implementation.
  • the electrolysis method proposed by the invention of the present invention is based on the vibration at the frequency of the natural vibration of any one of oxygen, hydrogen, and water molecules of water or a multiple wavelength of the wavelength of the natural vibration of any one of the molecules.
  • a water electrolysis method characterized by applying any of the following vibrations to resonate one of oxygen, hydrogen, and water molecules, and energizing water.
  • Another invention of the electrolysis method is that the electrodes are magnetized and the oxygen molecules, hydrogen molecules or water molecules of water are vibrated at the frequency of the natural frequency of one of the molecules or the characteristic of one of the molecules.
  • a water electrolysis method characterized by applying vibration at a wavelength that is a multiple of the wavelength of vibration to resonate one of oxygen molecules, hydrogen molecules, and water molecules, and energizing water.
  • the vibration at the frequency of the natural vibration or the vibration at a multiple wavelength of the wavelength of the natural vibration is an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave, Applied to electrodes or non-electrode diaphragms or electrolytes using at least one of generating means or mechanical vibration applying means.
  • the electrolyte is a weak alkaline aqueous solution of water or a salt of caustic alkali or quaternary ammonium hydroxide or a salt of caustic alkali or a salt of quaternary ammonium hydroxide.
  • the quaternary ammonium hydroxide or a salt thereof it is effective to use an aqueous solution of a quaternary ammonium hydroxide such as tetramethylammonium hydroxide having a low surface tension or a salt thereof.
  • the invention of the electrolysis apparatus of the present invention is to install the electrode in the water in the water tank so as to be movable up and down. Then, by applying vibration at the frequency of the natural vibration of any one of oxygen molecules, hydrogen molecules, and water molecules of water or vibration at a wavelength that is a multiple of the wavelength of the natural vibration of any one of the molecules, oxygen
  • An electrolytic device characterized by having a vibration means for resonating any one of a molecule, a hydrogen molecule and a water molecule.
  • Another invention of an electrolysis apparatus is that an electrode is set up and down in water in a water tank so as to be movable up and down at a frequency of the natural vibration of any one of oxygen, hydrogen and water molecules of water.
  • Means for alternating magnetizing L is an electrolytic apparatus characterized in that a means for applying an alternating magnetic field of an electromagnet to an electrode on the magnetic field of a permanent magnet to provide an alternating magnetizing method is provided.
  • the vibration means includes at least one of an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave generating means, or a mechanical vibration applying means. It is to be applied to an electrode or a diaphragm that is not an electrode, or an electrolytic solution.
  • a single DC battery power source such as a lead storage battery for an automobile, a DC power source using a transformer or a rectifier instead of an AC power source, a solar cell, a fuel cell, or the like can be used alone or in combination.
  • the on / off switching of the electrolysis current and the electromagnet current is performed by providing an input switching circuit by contacting the rotor and brushes in the power supply, or by using a pulse generation circuit such as a transistor, multivibrator, or charging and discharging capacitors in the power supply. On / off switching by control pulse.
  • input switching using a brush can be performed in a range of about 100 to 2,000 cycles per second using a distributor having 2 to 20 electrodes.
  • Ultrasonic waves for generating vibration are generated at 5, 000 to 175, 000 cycles per second. Anything can be used.
  • the vibration is performed in a range of 100 to 2,000 cycles per second using a vibrator or the like.
  • the diaphragm which is not an electrode can be provided at an arbitrary position in the electrolytic cell. Vibration plates that are not electrodes are also vibrated using ultrasonic waves, electromagnetic waves, electromagnets, and vibrators. Although it is possible to vibrate each of the vibrating plate and the electrode plate that are not electrodes separately, it is preferable to vibrate simultaneously and in parallel because the effect can be further enhanced.
  • the pulse width can be used in the range of about 5 to 500 microseconds.
  • a device for generating an electromagnetic wave can be provided outside the electrolytic device to generate the electromagnetic wave, and the hydrogen molecule, the oxygen molecule, or the water molecule can be resonated by the action of the electromagnetic wave.
  • an electromagnetic wave of 50 to 30 GHz can be used depending on the capacity of the electrolyzer.
  • Either permanent magnets, electromagnets, or both can be used to magnetize the electrodes.
  • vibration can be generated by applying an alternating magnetic field by turning the current on and off.
  • a method of applying an alternating magnetic field can be achieved by alternately turning on and off the current to electromagnets of the same polarity (N or S).
  • alloys such as alnico or iron'chromium / cobalt, ferrites, and rare earths such as samarium and neodymium, which have a gauss of 5,000 to 12,500 gauss or more, must be used. Yes, but especially rare: fc ⁇ sintered or bonded magnets have high magnetic flux density and are preferred.
  • iron core of the electromagnet pure iron, gay steel sheet, permalloy or ferrite can be used.
  • electrode of the present invention iron, nickel, titanium and alloys thereof, and a metal obtained by plating these metals with gold, platinum, rhodium, indium, etc., are used in a monopolar or bipolar type.
  • an electrode or a catalyst-carrying electrode that has been subjected to a known surface enlargement treatment such as roughening or elution in the present invention.
  • the electrolytic cell of the present invention can use metals and plastics such as stainless steel and aluminum, and does not require a particular membrane between the cathode and the anode. Therefore, it can have an extremely simple structure, but has an ion exchange capability.
  • a solid polymer membrane a solid electrolyte type electrolytic cell having negative and positive plates disposed on both sides can also be used.
  • the device of the present invention can be mounted on an automobile to form a hydrogen engine vehicle. It can be used in combination with heavy oil and methanol, but by using it with gasoline, it can dramatically improve the mileage per liter of gasoline. Hydrogen itself is clean energy, has a high combustion rate, is easy to obtain a uniform gas mixture, and has a characteristic that it burns in a wide range of combustible areas with a small ignition energy. Dramatically improve fuel combustion efficiency, reduce unburned hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NO x) in combustion exhaust gas, and reduce environmental pollution .
  • HC unburned hydrocarbons
  • CO carbon monoxide
  • NO x nitrogen oxides
  • the magnetizing of the electrode according to the present invention is described in the prior art. However, it has been recognized that the addition of the alternating magnetic field by the magnetizing to give the resonance-induced vibration produces an additional effect.
  • the temperature of the electrolytic solution increases as the electrolysis proceeds, the liquid resistance and the cell voltage decrease, and the electrolytic efficiency improves.
  • the electrolysis can be performed efficiently by keeping the electrolytic bath warm and warm, the present invention allows high-efficiency electrolysis without the need for a special heating device.
  • the electrolytic efficiency can be increased by circulating the electrolytic solution using a pump, a diaphragm valve, etc., in the present invention, a large amount of generated gas is generated, and the liquid is circulated by injecting a replenisher into the tank bottom. High-efficiency electrolysis can be performed without any additional circulating device.
  • the present invention can be used as a vehicle, power plant, ship, aircraft, rocket propulsion and other multi-purpose energy sources, and since the energy returns to water after use, there is no danger of secondary pollution.
  • One of the features of the present invention is that there is no danger because water can be electrolyzed according to the required amount of hydrogen or the like used.
  • hydrogen gas or oxygen gas is sealed in cylinders, and the required amount is taken out at the time of use. Therefore, there was a risk of gas leaking in the event of an accident or a major disaster due to the destruction of the cylinder.
  • the present invention electrolyzes water by a required amount, hydrogen gas or oxygen gas is only present in a pipe connecting the electrolyzer with a place of use (for example, Endin). Therefore, even if a pipe breaks due to an accident, the remaining amount of hydrogen gas and the like is extremely small, so there is no danger of a catastrophic disaster, and water simply flows out.
  • a method is also known in which hydrogen generated for the purpose of compensating the generation speed of the 7k element generator is absorbed and stored in a hydrogen storage alloy.However, according to the method of the present invention, hydrogen can be obtained when required. This eliminates the need for extra expensive and heavy storage.
  • the generation of hydrogen and the like can be easily controlled by changing the electrode area immersed in the electrolyte.
  • the amount of generated gas depends on the amount of electricity immersed in the electrolyte. Since it is proportional to the pole area, it can be easily adjusted by controlling the electrode position (elevation). However, in this case, it is necessary to keep the electrolysis constant.
  • the natural frequencies themselves are different.
  • the vibration of the equipment is selected from among the three natural frequencies and their multiple wavelengths. Since the most stable frequency should be selected for, the objective can be easily achieved.
  • the vibration at the frequency of one of the natural vibrations of the hydrogen molecule, the oxygen molecule, or the water molecule or the vibration at a wavelength that is a multiple of the wavelength of any one of the natural vibrations is applied. Resonance occurs in any one of the molecules and the like, and the molecular bond of water is weakened. Therefore, if electricity is supplied, electrolysis can be easily performed with a small current.
  • electrolyzed water as, for example, weakly caustic water
  • placing the electrodes in an alternating magnetic field vibration, reduction in surface tension, and magnetic field effects act additively, increasing the amount of power required for electrolysis. Can be effectively reduced.
  • hydrogen molecules, oxygen molecules or water molecules resonate, so that water is easily electrolyzed. Therefore, by energizing, there is an effect that electrolysis can be efficiently performed with relatively little power.
  • the electrolyzed water is made into a solution with low surface tension such as weak water, and the electrodes are put in a magnetic field, and an alternating magnetic field is applied as necessary to generate a surplus effect with the resonance of hydrogen molecules, etc.
  • the electrolytic efficiency can be dramatically improved.
  • FIG. 1 is a longitudinal sectional view in which a part of an apparatus according to the present invention is omitted
  • FIG. 2 is an enlarged view of an electrode used in the apparatus of FIG. 1
  • FIG. 3 is provided with mechanical vibration means.
  • Fig. 4 is an enlarged view of the electrode
  • Fig. 4 is a cross-sectional view with some of the other difficult examples omitted
  • Fig. 5 is a schematic diagram showing the connection and disconnection of the input to the electromagnet
  • Fig. 6 is another implementation.
  • FIG. 7 is an enlarged sectional view of a composite magnet of a permanent magnet and an electromagnet.
  • FIGS. 3.6 Weak alkaline water 2 (5% caustic soda water) is placed in an electrolyzed water tank 1 made of PVC, and seven pieces each made of iron-nickel alloy with a width of 9.4 cm and a length of 15 cm are placed in the weak alkaline water 2. Electrodes 3 and 4 (Fig. 2) are installed facing each other at an interval of 2 m / m. The electrodes 3 and 4 are formed in a comb shape, and an insulating piece 15 (FIG. 3) is interposed between the positive pole and one pole.
  • the electrodes 3 and 4 are fixed to a bracket 16, the bracket 16 is supported by a lifting rod 17, and the lifting rod 17 is connected to a rod 19 (drive device) of an air cylinder 18. Therefore, according to the required amount of hydrogen gas, etc., by raising and lowering the port 19 of the air cylinder 18 via the control system, the immersion area of the electrodes 3, 4 is adjusted, and the amount of generated hydrogen gas, etc. is adjusted. can do.
  • the electrodes 3 and 4 are connected to brushes 22 and 23 via cords 20 and 21, and the brushes 22 and 23 are mounted on the outer circumference of the rotors 25 and 26 fixed to the rotating shaft 24. Sliding contact (Fig. 1).
  • the driving device 18 has a function of reciprocating the lifting rod 17 and reciprocatingly move up and down.
  • all the conventionally known reciprocating moving devices such as a port of an air cylinder, a rack of a pinion or a screw device are used. can do. Therefore, the most suitable driving device will be adopted depending on various conditions such as the purpose of use of the electrolysis device, the installation place, the capacity, the amount of fluctuation in electrolysis, and the like.
  • the bracket 16 has a permanent magnet 12 of NdFeB series 12 and a diameter of 0.0000 gauss and a diameter of 30 m / m and a thickness of 5 m / m. 3 is fixed (Fig. 1) o
  • the permanent magnet 1 2 forms a stationary magnetic field
  • the electromagnet 13 switches the input of the current obtained from a normal automotive power supply battery. To form an alternating magnetic field of 400 cycles per second.
  • reference numeral 14 denotes a water level float
  • reference numeral 14a denotes an arm of the water level float.
  • Fig. 1 When weak water is supplied and the water level float 14 is lifted above the specified height, the arm 14a rises as shown by arrow 47 and the angular force changes, and the detector 27 operates. Solenoid valve 28 is closed, and the supply of weak alkaline water is stopped. When the electrolysis advances and the float 14 falls below the specified force, the arm 14a descends as indicated by the arrow 48 and the angle changes, the detector 27 acts to open the solenoid valve 28, which is weak. Al power water is supplied. Therefore, the water level 29 is always kept constant.
  • one of oxygen molecules, hydrogen molecules and water molecules in the electrolytic solution is vibrated at the frequency of its natural vibration or at a multiple of the wavelength of any of the natural vibrations to give resonance.
  • the means for causing this will be described below.
  • the first means is to turn on and off the electrolysis current.
  • the electrodes 3 and 4 are connected to the brushes 22 and 23 via the cords 20 and 21, and the brushes 22 and 23 are the rotors 2 fixed to the rotating shaft 24. It is in sliding contact with the outer circumference of 5, 26. Therefore, the input to the electrodes 3 and 4 can be cut off by rotating the rotors 25 and 26.
  • the input switching by the brush is preferably performed in a range of about 100 to 2,000 cycles per second.
  • the electrodes 3 and 4 Since the on and off of the electrolytic current flowing through the electrodes 3 and 4 occur under the presence of the permanent magnet 12 described above while the electrodes are magnetized, the electrodes generate vibration. As a result, vibration is given to the electrolyte, and the above-described resonance vibration is applied to one of the oxygen molecules, hydrogen molecules, and water molecules in the electrolyte, and a desired resonance is generated.
  • the second means is to apply the above-described vibration to one of the enzyme molecules, hydrogen molecules, and water in the electrolytic solution by the alternating magnetic field generated by the electromagnet 13 described above.
  • the electromagnet 13 forms an alternating magnetic field of 400 cycles per second by switching inputs, but forms an alternating magnetic field of about 100 to 2,000 cycles per second by switching inputs. It is the power to do. Changes in this alternating magnetic field
  • the electrodes are alternately magnetized by controlling the temperature of the electrodes, thereby causing the electrodes to vibrate and, at the same time, vibrating the electrolytic solution.
  • any one of oxygen molecules, hydrogen molecules, and water molecules in the electrolytic solution is described above. By giving a resonance vibration, a desired resonance can be generated.
  • first means and the second means described above can be simultaneously operated to generate a desired vibration.
  • FIG. 3 shows a third means for giving the above-described resonance to any one of oxygen molecules, hydrogen molecules, and water molecules in the electrolytic solution.
  • a U-shaped member 5 that covers the outside of both electrodes is connected to one of the electrodes 3 and 4, and the electromagnets 6a and 6b are placed inside the side plates 5a and 5b of the U-shaped member 5. Then, the free end faces of the electromagnets 6a and 6b are opposed to the electrodes 3 and 4 with a small gap.
  • the electromagnets 6a and 6b are provided with rotors 41 and 42 and brushes 43 and 44, respectively, in which an on / off current flows and a magnetic field is turned on / off, and connected with cords 45 and 46. It is.
  • the electrodes 3, 4 are attracted to the electromagnet 6a, and when the electromagnet 6b is energized, the electrodes 3, 4 are attracted to the electromagnet 6b. It oscillates in synchronization with.
  • the vibration of the electrodes 3 and 4 becomes the vibration of the electrolyte as it is, and induces the resonance of molecules such as hydrogen. Therefore, if the connection and disconnection of the electromagnet is controlled by the rotation of the mouth 41, 42, a predetermined frequency can be obtained, so that any of hydrogen molecules, oxygen molecules, or water molecules is resonated. Become.
  • the permanent magnets 10 and 10a may be fixed to the U-shaped member, and the electrodes 3 and 4 may be placed in a magnetic field.
  • the switching of the input to the electromagnet by the rotation of the rotors 41 and 42 be performed in a range of about 100 to 2,000 cycles per second.
  • a target vibration in the range of 100 to 2,000 cycles per second can be applied to the electrode.
  • the above-mentioned resonance is given to one of the oxygen molecules, hydrogen or water in the electrolyte.
  • the generation of vibration is controlled by turning on and off the electrolytic current or turning on and off the current to the electromagnet.
  • the turning on and off of these currents can be accurately controlled by rotating the rotor combined with the brush. Therefore, it is possible to vibrate the electrode and the electrolyte at an extremely accurate frequency.
  • the hydrogen generating electrolyzer of the present invention was mounted on a car having an average mileage of 10.2 km per liter of gasoline, and when used in combination with gasoline, an average mileage of 1 liter of gasoline of 26.7 km was obtained. .
  • Example 2 The same steady-state electrolysis was performed using the same device as in Example 1 without applying an alternating current to the electromagnet.
  • the amount of gas generated per minute was 0.8 for hydrogen and 0.4 for oxygen. Met.
  • the electrodes 3 and 4 are immersed in the water of the water tank 1 and held by the bracket 7.
  • the bracket 7 is fixed to the wall of the water tank 1 by a support rod 8.
  • An ultrasonic oscillator 9 of 20.000 cycles per second is fixed to the inner wall of the water tank 1.
  • the permanent magnet 49 and the electromagnet 11 are fixed to the bracket 7.
  • the electrode and the electrolyte near the electrode are vibrated using an ultrasonic oscillator 9 so that any one of oxygen ⁇ , hydrogen molecule, and water molecule in the electrolyte is solidified.
  • FIG. 5 is a schematic diagram showing connection and disconnection of the input of the electromagnets 6, 11 and 13 in FIGS.
  • the brushes 31 and 32 are connected to the ends 30a and 30b of the windings 30 of the electromagnets 6, 11 and 13 respectively, and the brushes 3 and 3 are connected to the rotors 3 and 3 4.
  • the input to each electromagnet can be connected and disconnected at 500 cycles per second.
  • the switching of the input by the rotation of the rotor can be performed by 100 to 2,000 cycling tests per second.
  • FIG. 6 shows an example in which a gas produced by electrolysis of water is separated into hydrogen gas and oxygen gas and collected separately.
  • a partition wall 36 is installed between the electrodes 3 and 4, and an ultrasonic oscillator 9 is installed at the bottom of the water tank.
  • Discharge pipes 39, 40 for discharging hydrogen gas and oxygen gas, respectively, are connected to the top wall 35 of the water tank 1 divided by the partition wall 36.
  • hydrogen molecules, oxygen molecules or water molecules are resonated by the ultrasonic oscillator 9 and the electrodes 3 and 4 are energized, hydrogen gas and oxygen gas are easily electrolyzed and the hydrogen gas and oxygen gas are separated into the upper space of the water tank 1. They are collected in 1a and 1b and discharged to specified places through discharge pipes 39 and 40. In this case, an ultrasonic wave having a cycle of 5,000 to 175,000 cycles per second can be used.
  • a semipermeable membrane 36 may be vertically provided as a partition at the center of the water tank 1.
  • a magnet having an electromagnet 37 attached outside the permanent magnet 38 as shown in FIG. 7 may be attached to each of the electrodes 3 and 4, so that the electrodes 3 and 4 can be placed in a magnetic field.
  • the electrolytic solution is more easily decomposed by the action of vibration and magnetic force, and the electrolytic solution is efficiently electrolyzed with a small current.
  • the water electrolysis method and apparatus according to the present invention are useful for water electrolysis.
  • water can be electrolyzed very efficiently to generate hydrogen gas. Therefore, the method and apparatus of the present invention can be used for automobiles, power plants, ships, airplanes, rocket propulsion, etc. Can be used as a multipurpose energy source.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

Ce procédé et ce dispositif améliorent considérablement le rendement de l'électrolyse. Le principe de l'électrolyse de l'eau étant bien connu, de nombreuses améliorations technologiques y ont été apportées. Toutefois, ces améliorations ne constituent pas un progrès satisfaisant car elles n'ont guère procuré une progression de rendement supérieure à 10 %. Le très haut rendement procuré par cette invention pour l'électrolyse de l'eau est obtenu en faisant résonner les molécules d'oxygène, d'hydrogène ou d'eau. Le procédé consiste à appliquer à ces molécules une vibration de fréquence identique à celle qu'elles ont naturellement, ou encore une vibration dont la longueur d'onde est un multiple de celle que les molécules sélectionnées ont naturellement. Il suffit alors d'appliquer le courant électrique à l'eau. Ces procédé et dispositif sont applicables à la production de sources d'énergie polyvalentes pour les automobiles, les centrales électriques, les bateaux, l'aéronautique, et les moteurs-fusées ou analogues.
PCT/JP1994/001366 1993-08-27 1994-08-18 Procede et dispositif d'electrolyse de l'eau WO1995006144A1 (fr)

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JP5/213123 1993-08-27
JP21312393 1993-08-27

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WO2004092059A1 (fr) * 2003-04-18 2004-10-28 Japan Techno Co., Ltd. Combustible pour batterie de piles a combustible, batterie de piles a combustible, et procede de production d'energie associe
JPWO2004092059A1 (ja) * 2003-04-18 2006-07-06 日本テクノ株式会社 燃料電池用燃料、燃料電池およびそれを用いた発電方法
CN100364880C (zh) * 2003-04-18 2008-01-30 日本科技股份有限公司 燃料电池用燃料、燃料电池及利用燃料电池的发电方法
JP2007508454A (ja) * 2003-10-14 2007-04-05 ビールバウマー，ハンス−ペーター エネルギー変換装置
JP2006272051A (ja) * 2005-03-28 2006-10-12 Mitsui Chemicals Inc 排水の処理方法
JP2012515845A (ja) * 2009-01-20 2012-07-12 パルミル 電解方法、装置及びシステム
WO2012169977A1 (fr) * 2011-06-10 2012-12-13 Sukij Tridsadeerak Cuve de séparation d'hydrogène wdh3
WO2013165322A1 (fr) * 2012-04-30 2013-11-07 Sukij Tridsadeerak Cuve de séparation d'hydrogène de type wdh7
WO2016052002A1 (fr) * 2014-09-29 2016-04-07 富士フイルム株式会社 Module de photosynthèse artificielle
JPWO2016052002A1 (ja) * 2014-09-29 2017-07-20 富士フイルム株式会社 人工光合成モジュール
CN106118769A (zh) * 2016-08-07 2016-11-16 玉灵华科技有限公司 一种燃气重整装置及燃气制备方法
CN106190378A (zh) * 2016-08-07 2016-12-07 玉灵华科技有限公司 一种燃气重整液及燃气重整与制备方法
CN106244269A (zh) * 2016-08-07 2016-12-21 玉灵华科技有限公司 一种安全高热值燃气制备方法及***
EP3495457A4 (fr) * 2016-08-07 2020-03-25 Yulinghua Technology Co. Ltd Procédé et système de préparation de gaz combustible à valeur calorifique élevée sans danger
WO2018070061A1 (fr) * 2016-10-13 2018-04-19 正裕 井尻 Dispositif de génération d'hydrogène acide, et véhicule hybride ou véhicule à pile à combustible pourvu d'un dispositif de génération d'hydrogène acide
JP2018090882A (ja) * 2016-12-07 2018-06-14 武次 廣田 水素の製造方法
CN113415867A (zh) * 2021-06-29 2021-09-21 上海亮靓生物科技有限公司 一种量子能量微纳米气泡富氢水机

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