WO1995006144A1 - Water electrolyzing method and apparatus - Google Patents

Water electrolyzing method and apparatus Download PDF

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Publication number
WO1995006144A1
WO1995006144A1 PCT/JP1994/001366 JP9401366W WO9506144A1 WO 1995006144 A1 WO1995006144 A1 WO 1995006144A1 JP 9401366 W JP9401366 W JP 9401366W WO 9506144 A1 WO9506144 A1 WO 9506144A1
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WIPO (PCT)
Prior art keywords
water
vibration
molecules
molecule
hydrogen
Prior art date
Application number
PCT/JP1994/001366
Other languages
French (fr)
Japanese (ja)
Inventor
Yoshihiko TAKESHITA (deceased)
Original Assignee
OSHIDA, Hisako +hf
KAMIYA, Yoshiko +hf
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OSHIDA, Hisako +hf, KAMIYA, Yoshiko +hf filed Critical OSHIDA, Hisako +hf
Publication of WO1995006144A1 publication Critical patent/WO1995006144A1/en

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the electrode placed in water is vibrated at a frequency of a natural vibration at which any one of oxygen molecules, hydrogen molecules, and water molecules resonates, or is vibrated at a multiple wavelength of the wavelength of the natural vibration to produce the oxygen.
  • one of the molecules, hydrogen, or water molecules resonates, it is energized in water, or resonates as described above, and the electrodes are magnetized in a magnetic field, and the water is energized in water to excite water.
  • the present invention relates to a water electrolysis method and apparatus for performing electrolysis.
  • the proposal to promote the separation of hydrogen bubbles by vibration of a vehicle body, etc. can be expected to reduce the electricity required for electrolysis even if the efficiency is slightly improved.
  • the purpose of the present invention is different from that of the present invention because the purpose of the present invention is to provide clean energy and is not to improve the efficiency of water electrolysis.
  • the technology for raising the temperature inside the electrolytic cell has a different purpose from that of the present invention, and the solution is completely different, so that the same effect cannot be expected as a result.
  • the present invention focuses on the natural vibration of oxygen molecules, hydrogen molecules, or water molecules of water, and by generating resonance in any one of them, dramatically improves the electrolysis efficiency of water. This made edible the electrolysis of water with extremely high efficiency that could not be achieved with the improved technology.
  • the wave number 2 of the natural oscillation of the time of generating the hydrogen molecule 2 5 0 cm- vibration or wavelength 4. 4 X 1 0 _ 4 cm water hydrogen partial child by applying vibration by multiple wavelengths in 1 was resonated, and the desorption of hydrogen molecules was promoted. Furthermore, it is also possible to simultaneously apply vibration of the natural frequency of the oxygen molecule or water molecule or vibration at a multiple of the wavelength of the natural vibration to simultaneously resonate the oxygen and water molecules.
  • each of the 5 ⁇ can be easily resonated when the vibration of the frequency of the natural vibration of each molecule is given or when the vibration of a multiple wavelength of the wavelength of the natural vibration is given.
  • a vibration having a wavelength that is a multiple of the wavelength is given, not only the resonance can be easily performed, but also the multiple wavelength can be radiated, so that it is easy to match the conditions under which each molecule can resonate. Can be.
  • water can be extremely efficiently generated.
  • the amount of hydrogen generated during electrolysis at 144 W in the past and the amount of hydrogen generated during electrolysis at 36 W to 48 W according to the present invention are substantially equal. Therefore, it can be seen that the power consumption is 1/3 to 1/4 that of the conventional electrolysis method and equipment, even if the efficiency is slightly higher or lower depending on the conditions of implementation.
  • the electrolysis method proposed by the invention of the present invention is based on the vibration at the frequency of the natural vibration of any one of oxygen, hydrogen, and water molecules of water or a multiple wavelength of the wavelength of the natural vibration of any one of the molecules.
  • a water electrolysis method characterized by applying any of the following vibrations to resonate one of oxygen, hydrogen, and water molecules, and energizing water.
  • Another invention of the electrolysis method is that the electrodes are magnetized and the oxygen molecules, hydrogen molecules or water molecules of water are vibrated at the frequency of the natural frequency of one of the molecules or the characteristic of one of the molecules.
  • a water electrolysis method characterized by applying vibration at a wavelength that is a multiple of the wavelength of vibration to resonate one of oxygen molecules, hydrogen molecules, and water molecules, and energizing water.
  • the vibration at the frequency of the natural vibration or the vibration at a multiple wavelength of the wavelength of the natural vibration is an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave, Applied to electrodes or non-electrode diaphragms or electrolytes using at least one of generating means or mechanical vibration applying means.
  • the electrolyte is a weak alkaline aqueous solution of water or a salt of caustic alkali or quaternary ammonium hydroxide or a salt of caustic alkali or a salt of quaternary ammonium hydroxide.
  • the quaternary ammonium hydroxide or a salt thereof it is effective to use an aqueous solution of a quaternary ammonium hydroxide such as tetramethylammonium hydroxide having a low surface tension or a salt thereof.
  • the invention of the electrolysis apparatus of the present invention is to install the electrode in the water in the water tank so as to be movable up and down. Then, by applying vibration at the frequency of the natural vibration of any one of oxygen molecules, hydrogen molecules, and water molecules of water or vibration at a wavelength that is a multiple of the wavelength of the natural vibration of any one of the molecules, oxygen
  • An electrolytic device characterized by having a vibration means for resonating any one of a molecule, a hydrogen molecule and a water molecule.
  • Another invention of an electrolysis apparatus is that an electrode is set up and down in water in a water tank so as to be movable up and down at a frequency of the natural vibration of any one of oxygen, hydrogen and water molecules of water.
  • Means for alternating magnetizing L is an electrolytic apparatus characterized in that a means for applying an alternating magnetic field of an electromagnet to an electrode on the magnetic field of a permanent magnet to provide an alternating magnetizing method is provided.
  • the vibration means includes at least one of an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave generating means, or a mechanical vibration applying means. It is to be applied to an electrode or a diaphragm that is not an electrode, or an electrolytic solution.
  • a single DC battery power source such as a lead storage battery for an automobile, a DC power source using a transformer or a rectifier instead of an AC power source, a solar cell, a fuel cell, or the like can be used alone or in combination.
  • the on / off switching of the electrolysis current and the electromagnet current is performed by providing an input switching circuit by contacting the rotor and brushes in the power supply, or by using a pulse generation circuit such as a transistor, multivibrator, or charging and discharging capacitors in the power supply. On / off switching by control pulse.
  • input switching using a brush can be performed in a range of about 100 to 2,000 cycles per second using a distributor having 2 to 20 electrodes.
  • Ultrasonic waves for generating vibration are generated at 5, 000 to 175, 000 cycles per second. Anything can be used.
  • the vibration is performed in a range of 100 to 2,000 cycles per second using a vibrator or the like.
  • the diaphragm which is not an electrode can be provided at an arbitrary position in the electrolytic cell. Vibration plates that are not electrodes are also vibrated using ultrasonic waves, electromagnetic waves, electromagnets, and vibrators. Although it is possible to vibrate each of the vibrating plate and the electrode plate that are not electrodes separately, it is preferable to vibrate simultaneously and in parallel because the effect can be further enhanced.
  • the pulse width can be used in the range of about 5 to 500 microseconds.
  • a device for generating an electromagnetic wave can be provided outside the electrolytic device to generate the electromagnetic wave, and the hydrogen molecule, the oxygen molecule, or the water molecule can be resonated by the action of the electromagnetic wave.
  • an electromagnetic wave of 50 to 30 GHz can be used depending on the capacity of the electrolyzer.
  • Either permanent magnets, electromagnets, or both can be used to magnetize the electrodes.
  • vibration can be generated by applying an alternating magnetic field by turning the current on and off.
  • a method of applying an alternating magnetic field can be achieved by alternately turning on and off the current to electromagnets of the same polarity (N or S).
  • alloys such as alnico or iron'chromium / cobalt, ferrites, and rare earths such as samarium and neodymium, which have a gauss of 5,000 to 12,500 gauss or more, must be used. Yes, but especially rare: fc ⁇ sintered or bonded magnets have high magnetic flux density and are preferred.
  • iron core of the electromagnet pure iron, gay steel sheet, permalloy or ferrite can be used.
  • electrode of the present invention iron, nickel, titanium and alloys thereof, and a metal obtained by plating these metals with gold, platinum, rhodium, indium, etc., are used in a monopolar or bipolar type.
  • an electrode or a catalyst-carrying electrode that has been subjected to a known surface enlargement treatment such as roughening or elution in the present invention.
  • the electrolytic cell of the present invention can use metals and plastics such as stainless steel and aluminum, and does not require a particular membrane between the cathode and the anode. Therefore, it can have an extremely simple structure, but has an ion exchange capability.
  • a solid polymer membrane a solid electrolyte type electrolytic cell having negative and positive plates disposed on both sides can also be used.
  • the device of the present invention can be mounted on an automobile to form a hydrogen engine vehicle. It can be used in combination with heavy oil and methanol, but by using it with gasoline, it can dramatically improve the mileage per liter of gasoline. Hydrogen itself is clean energy, has a high combustion rate, is easy to obtain a uniform gas mixture, and has a characteristic that it burns in a wide range of combustible areas with a small ignition energy. Dramatically improve fuel combustion efficiency, reduce unburned hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NO x) in combustion exhaust gas, and reduce environmental pollution .
  • HC unburned hydrocarbons
  • CO carbon monoxide
  • NO x nitrogen oxides
  • the magnetizing of the electrode according to the present invention is described in the prior art. However, it has been recognized that the addition of the alternating magnetic field by the magnetizing to give the resonance-induced vibration produces an additional effect.
  • the temperature of the electrolytic solution increases as the electrolysis proceeds, the liquid resistance and the cell voltage decrease, and the electrolytic efficiency improves.
  • the electrolysis can be performed efficiently by keeping the electrolytic bath warm and warm, the present invention allows high-efficiency electrolysis without the need for a special heating device.
  • the electrolytic efficiency can be increased by circulating the electrolytic solution using a pump, a diaphragm valve, etc., in the present invention, a large amount of generated gas is generated, and the liquid is circulated by injecting a replenisher into the tank bottom. High-efficiency electrolysis can be performed without any additional circulating device.
  • the present invention can be used as a vehicle, power plant, ship, aircraft, rocket propulsion and other multi-purpose energy sources, and since the energy returns to water after use, there is no danger of secondary pollution.
  • One of the features of the present invention is that there is no danger because water can be electrolyzed according to the required amount of hydrogen or the like used.
  • hydrogen gas or oxygen gas is sealed in cylinders, and the required amount is taken out at the time of use. Therefore, there was a risk of gas leaking in the event of an accident or a major disaster due to the destruction of the cylinder.
  • the present invention electrolyzes water by a required amount, hydrogen gas or oxygen gas is only present in a pipe connecting the electrolyzer with a place of use (for example, Endin). Therefore, even if a pipe breaks due to an accident, the remaining amount of hydrogen gas and the like is extremely small, so there is no danger of a catastrophic disaster, and water simply flows out.
  • a method is also known in which hydrogen generated for the purpose of compensating the generation speed of the 7k element generator is absorbed and stored in a hydrogen storage alloy.However, according to the method of the present invention, hydrogen can be obtained when required. This eliminates the need for extra expensive and heavy storage.
  • the generation of hydrogen and the like can be easily controlled by changing the electrode area immersed in the electrolyte.
  • the amount of generated gas depends on the amount of electricity immersed in the electrolyte. Since it is proportional to the pole area, it can be easily adjusted by controlling the electrode position (elevation). However, in this case, it is necessary to keep the electrolysis constant.
  • the natural frequencies themselves are different.
  • the vibration of the equipment is selected from among the three natural frequencies and their multiple wavelengths. Since the most stable frequency should be selected for, the objective can be easily achieved.
  • the vibration at the frequency of one of the natural vibrations of the hydrogen molecule, the oxygen molecule, or the water molecule or the vibration at a wavelength that is a multiple of the wavelength of any one of the natural vibrations is applied. Resonance occurs in any one of the molecules and the like, and the molecular bond of water is weakened. Therefore, if electricity is supplied, electrolysis can be easily performed with a small current.
  • electrolyzed water as, for example, weakly caustic water
  • placing the electrodes in an alternating magnetic field vibration, reduction in surface tension, and magnetic field effects act additively, increasing the amount of power required for electrolysis. Can be effectively reduced.
  • hydrogen molecules, oxygen molecules or water molecules resonate, so that water is easily electrolyzed. Therefore, by energizing, there is an effect that electrolysis can be efficiently performed with relatively little power.
  • the electrolyzed water is made into a solution with low surface tension such as weak water, and the electrodes are put in a magnetic field, and an alternating magnetic field is applied as necessary to generate a surplus effect with the resonance of hydrogen molecules, etc.
  • the electrolytic efficiency can be dramatically improved.
  • FIG. 1 is a longitudinal sectional view in which a part of an apparatus according to the present invention is omitted
  • FIG. 2 is an enlarged view of an electrode used in the apparatus of FIG. 1
  • FIG. 3 is provided with mechanical vibration means.
  • Fig. 4 is an enlarged view of the electrode
  • Fig. 4 is a cross-sectional view with some of the other difficult examples omitted
  • Fig. 5 is a schematic diagram showing the connection and disconnection of the input to the electromagnet
  • Fig. 6 is another implementation.
  • FIG. 7 is an enlarged sectional view of a composite magnet of a permanent magnet and an electromagnet.
  • FIGS. 3.6 Weak alkaline water 2 (5% caustic soda water) is placed in an electrolyzed water tank 1 made of PVC, and seven pieces each made of iron-nickel alloy with a width of 9.4 cm and a length of 15 cm are placed in the weak alkaline water 2. Electrodes 3 and 4 (Fig. 2) are installed facing each other at an interval of 2 m / m. The electrodes 3 and 4 are formed in a comb shape, and an insulating piece 15 (FIG. 3) is interposed between the positive pole and one pole.
  • the electrodes 3 and 4 are fixed to a bracket 16, the bracket 16 is supported by a lifting rod 17, and the lifting rod 17 is connected to a rod 19 (drive device) of an air cylinder 18. Therefore, according to the required amount of hydrogen gas, etc., by raising and lowering the port 19 of the air cylinder 18 via the control system, the immersion area of the electrodes 3, 4 is adjusted, and the amount of generated hydrogen gas, etc. is adjusted. can do.
  • the electrodes 3 and 4 are connected to brushes 22 and 23 via cords 20 and 21, and the brushes 22 and 23 are mounted on the outer circumference of the rotors 25 and 26 fixed to the rotating shaft 24. Sliding contact (Fig. 1).
  • the driving device 18 has a function of reciprocating the lifting rod 17 and reciprocatingly move up and down.
  • all the conventionally known reciprocating moving devices such as a port of an air cylinder, a rack of a pinion or a screw device are used. can do. Therefore, the most suitable driving device will be adopted depending on various conditions such as the purpose of use of the electrolysis device, the installation place, the capacity, the amount of fluctuation in electrolysis, and the like.
  • the bracket 16 has a permanent magnet 12 of NdFeB series 12 and a diameter of 0.0000 gauss and a diameter of 30 m / m and a thickness of 5 m / m. 3 is fixed (Fig. 1) o
  • the permanent magnet 1 2 forms a stationary magnetic field
  • the electromagnet 13 switches the input of the current obtained from a normal automotive power supply battery. To form an alternating magnetic field of 400 cycles per second.
  • reference numeral 14 denotes a water level float
  • reference numeral 14a denotes an arm of the water level float.
  • Fig. 1 When weak water is supplied and the water level float 14 is lifted above the specified height, the arm 14a rises as shown by arrow 47 and the angular force changes, and the detector 27 operates. Solenoid valve 28 is closed, and the supply of weak alkaline water is stopped. When the electrolysis advances and the float 14 falls below the specified force, the arm 14a descends as indicated by the arrow 48 and the angle changes, the detector 27 acts to open the solenoid valve 28, which is weak. Al power water is supplied. Therefore, the water level 29 is always kept constant.
  • one of oxygen molecules, hydrogen molecules and water molecules in the electrolytic solution is vibrated at the frequency of its natural vibration or at a multiple of the wavelength of any of the natural vibrations to give resonance.
  • the means for causing this will be described below.
  • the first means is to turn on and off the electrolysis current.
  • the electrodes 3 and 4 are connected to the brushes 22 and 23 via the cords 20 and 21, and the brushes 22 and 23 are the rotors 2 fixed to the rotating shaft 24. It is in sliding contact with the outer circumference of 5, 26. Therefore, the input to the electrodes 3 and 4 can be cut off by rotating the rotors 25 and 26.
  • the input switching by the brush is preferably performed in a range of about 100 to 2,000 cycles per second.
  • the electrodes 3 and 4 Since the on and off of the electrolytic current flowing through the electrodes 3 and 4 occur under the presence of the permanent magnet 12 described above while the electrodes are magnetized, the electrodes generate vibration. As a result, vibration is given to the electrolyte, and the above-described resonance vibration is applied to one of the oxygen molecules, hydrogen molecules, and water molecules in the electrolyte, and a desired resonance is generated.
  • the second means is to apply the above-described vibration to one of the enzyme molecules, hydrogen molecules, and water in the electrolytic solution by the alternating magnetic field generated by the electromagnet 13 described above.
  • the electromagnet 13 forms an alternating magnetic field of 400 cycles per second by switching inputs, but forms an alternating magnetic field of about 100 to 2,000 cycles per second by switching inputs. It is the power to do. Changes in this alternating magnetic field
  • the electrodes are alternately magnetized by controlling the temperature of the electrodes, thereby causing the electrodes to vibrate and, at the same time, vibrating the electrolytic solution.
  • any one of oxygen molecules, hydrogen molecules, and water molecules in the electrolytic solution is described above. By giving a resonance vibration, a desired resonance can be generated.
  • first means and the second means described above can be simultaneously operated to generate a desired vibration.
  • FIG. 3 shows a third means for giving the above-described resonance to any one of oxygen molecules, hydrogen molecules, and water molecules in the electrolytic solution.
  • a U-shaped member 5 that covers the outside of both electrodes is connected to one of the electrodes 3 and 4, and the electromagnets 6a and 6b are placed inside the side plates 5a and 5b of the U-shaped member 5. Then, the free end faces of the electromagnets 6a and 6b are opposed to the electrodes 3 and 4 with a small gap.
  • the electromagnets 6a and 6b are provided with rotors 41 and 42 and brushes 43 and 44, respectively, in which an on / off current flows and a magnetic field is turned on / off, and connected with cords 45 and 46. It is.
  • the electrodes 3, 4 are attracted to the electromagnet 6a, and when the electromagnet 6b is energized, the electrodes 3, 4 are attracted to the electromagnet 6b. It oscillates in synchronization with.
  • the vibration of the electrodes 3 and 4 becomes the vibration of the electrolyte as it is, and induces the resonance of molecules such as hydrogen. Therefore, if the connection and disconnection of the electromagnet is controlled by the rotation of the mouth 41, 42, a predetermined frequency can be obtained, so that any of hydrogen molecules, oxygen molecules, or water molecules is resonated. Become.
  • the permanent magnets 10 and 10a may be fixed to the U-shaped member, and the electrodes 3 and 4 may be placed in a magnetic field.
  • the switching of the input to the electromagnet by the rotation of the rotors 41 and 42 be performed in a range of about 100 to 2,000 cycles per second.
  • a target vibration in the range of 100 to 2,000 cycles per second can be applied to the electrode.
  • the above-mentioned resonance is given to one of the oxygen molecules, hydrogen or water in the electrolyte.
  • the generation of vibration is controlled by turning on and off the electrolytic current or turning on and off the current to the electromagnet.
  • the turning on and off of these currents can be accurately controlled by rotating the rotor combined with the brush. Therefore, it is possible to vibrate the electrode and the electrolyte at an extremely accurate frequency.
  • the hydrogen generating electrolyzer of the present invention was mounted on a car having an average mileage of 10.2 km per liter of gasoline, and when used in combination with gasoline, an average mileage of 1 liter of gasoline of 26.7 km was obtained. .
  • Example 2 The same steady-state electrolysis was performed using the same device as in Example 1 without applying an alternating current to the electromagnet.
  • the amount of gas generated per minute was 0.8 for hydrogen and 0.4 for oxygen. Met.
  • the electrodes 3 and 4 are immersed in the water of the water tank 1 and held by the bracket 7.
  • the bracket 7 is fixed to the wall of the water tank 1 by a support rod 8.
  • An ultrasonic oscillator 9 of 20.000 cycles per second is fixed to the inner wall of the water tank 1.
  • the permanent magnet 49 and the electromagnet 11 are fixed to the bracket 7.
  • the electrode and the electrolyte near the electrode are vibrated using an ultrasonic oscillator 9 so that any one of oxygen ⁇ , hydrogen molecule, and water molecule in the electrolyte is solidified.
  • FIG. 5 is a schematic diagram showing connection and disconnection of the input of the electromagnets 6, 11 and 13 in FIGS.
  • the brushes 31 and 32 are connected to the ends 30a and 30b of the windings 30 of the electromagnets 6, 11 and 13 respectively, and the brushes 3 and 3 are connected to the rotors 3 and 3 4.
  • the input to each electromagnet can be connected and disconnected at 500 cycles per second.
  • the switching of the input by the rotation of the rotor can be performed by 100 to 2,000 cycling tests per second.
  • FIG. 6 shows an example in which a gas produced by electrolysis of water is separated into hydrogen gas and oxygen gas and collected separately.
  • a partition wall 36 is installed between the electrodes 3 and 4, and an ultrasonic oscillator 9 is installed at the bottom of the water tank.
  • Discharge pipes 39, 40 for discharging hydrogen gas and oxygen gas, respectively, are connected to the top wall 35 of the water tank 1 divided by the partition wall 36.
  • hydrogen molecules, oxygen molecules or water molecules are resonated by the ultrasonic oscillator 9 and the electrodes 3 and 4 are energized, hydrogen gas and oxygen gas are easily electrolyzed and the hydrogen gas and oxygen gas are separated into the upper space of the water tank 1. They are collected in 1a and 1b and discharged to specified places through discharge pipes 39 and 40. In this case, an ultrasonic wave having a cycle of 5,000 to 175,000 cycles per second can be used.
  • a semipermeable membrane 36 may be vertically provided as a partition at the center of the water tank 1.
  • a magnet having an electromagnet 37 attached outside the permanent magnet 38 as shown in FIG. 7 may be attached to each of the electrodes 3 and 4, so that the electrodes 3 and 4 can be placed in a magnetic field.
  • the electrolytic solution is more easily decomposed by the action of vibration and magnetic force, and the electrolytic solution is efficiently electrolyzed with a small current.
  • the water electrolysis method and apparatus according to the present invention are useful for water electrolysis.
  • water can be electrolyzed very efficiently to generate hydrogen gas. Therefore, the method and apparatus of the present invention can be used for automobiles, power plants, ships, airplanes, rocket propulsion, etc. Can be used as a multipurpose energy source.

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  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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Abstract

This invention relates to a water electrolyzing method and apparatus for improving the electrolysis efficiency to a great extent. The electrolysis of water is known well, and a large number of improvement techniques have heretofore been proposed. However, all of these techniques have attained only a little (for example, not more than 10 %) improvement in the electrolytic efficiency, which does not constitute a satisfactory improvement. This invention enables water to be electrolyzed with a very high efficiency by resonating the oxygen molecules or hydrogen molecules or water molecules of water by applying thereto vibration having a vibration frequency of natural vibration thereof, or vibration having a wavelength the value of which is a multiple of the wavelength of natural vibration of the selected molecules, and supplying an electric current to the water. The method and apparatus according to the present invention can be used to produce a multi-purpose energy source for automobiles, power plants, ships, aircrafts, rockets propulsion and the like.

Description

明 細 発明の名称 水の電解方法及び装置  Description Title of the Invention Water electrolysis method and apparatus
技術分野  Technical field
この発明は、 水中に入れた電極を、 酸素分子、 水素分子又は水分子の何れか一 つが共振する固有振動の振動数で振動させ、 又は固有振動の波長の倍数波長で振 動させて前記酸素分子、 水素 又は水分子のいずれか一つを共振させると共 に、水中に通電し、 又は前記のようにして共振させると共に、 電極を磁界内にお いて帯磁させ、 水中に通電して水を電解することを目的とした水の電解方法及び 装置に関するものである。  According to the present invention, the electrode placed in water is vibrated at a frequency of a natural vibration at which any one of oxygen molecules, hydrogen molecules, and water molecules resonates, or is vibrated at a multiple wavelength of the wavelength of the natural vibration to produce the oxygen. When one of the molecules, hydrogen, or water molecules resonates, it is energized in water, or resonates as described above, and the electrodes are magnetized in a magnetic field, and the water is energized in water to excite water. The present invention relates to a water electrolysis method and apparatus for performing electrolysis.
背景技術  Background art
従来水の電解については、 広く知られており、 改善について幾多の改善技術が 提案されている。  Conventional water electrolysis is widely known, and many improvement techniques have been proposed for improvement.
例えば水を電解して発生する水素と酸素を燃料に混合して用いるエネルギー装 置においては、 自動車などに設置した際に車の振動により電極の水素泡を振り、 効率を高める提案がある （日本特開平 4 - 8 8 5 3号公報） 。  For example, in energy devices that use hydrogen and oxygen generated by electrolyzing water mixed with fuel, there is a proposal to increase the efficiency by shaking the hydrogen bubbles on the electrodes due to the vibration of the car when installed in a car. Japanese Unexamined Patent Publication No. Hei 4-88853).
また電解槽内を高温 （例えば 8 0 °C以上） にして化学変化を させる提案も ある （日本特開平 4 - 9 4 8 5号公報） 。  There is also a proposal for making the inside of an electrolytic cell a high temperature (for example, 80 ° C. or more) to cause a chemical change (Japanese Patent Application Laid-Open No. 4-94885).
次に水の電解時に電極間に磁場を作用させて効率を数％向上させる提案がある (日本特開平 1 _ 2 7 5 7 8 8号公報） o  Next, there is a proposal to improve the efficiency by applying a magnetic field between the electrodes during the electrolysis of water by several percent (Japanese Patent Application Laid-Open No. 1-2757888).
更に塩化アル力リ水溶液中の電極を磁場の印加下において通電することによ り、 電流効率を向上させ、 電解のコスト低減に効果 （例えば電流効率 9 2. 5 %) を奏するという提案もある （日本特開昭 6 4— 2 9 0号公報） 0  In addition, there is a proposal to improve the current efficiency by energizing the electrodes in the aqueous solution of alkaline chloride under the application of a magnetic field, thereby reducing the cost of electrolysis (eg, current efficiency of 92.5%). (Japanese Unexamined Patent Publication No. 64-2900) 0
前記従来の提案技術中、 車体等の振動により水素泡の分離を促進する提案は、 若干の効率向上になるとしても、 電解に要する電 の低減を期待することはで きない。 例えば、 クリーンなエネルギーの提供を目的としナ; ものであって、 水の 電解を高能率化するものではないので、 本願発明とは目的を異にし、 従って解決 課題も自ら異なる。 Among the above-mentioned conventional proposal techniques, the proposal to promote the separation of hydrogen bubbles by vibration of a vehicle body, etc., can be expected to reduce the electricity required for electrolysis even if the efficiency is slightly improved. I can't. For example, the purpose of the present invention is different from that of the present invention because the purpose of the present invention is to provide clean energy and is not to improve the efficiency of water electrolysis.
また電解槽内を高温にする技術もこの発明とは目的を異にし、 解決手段も全然 異なり、 結果的に同一効果を期待することはできない。  Also, the technology for raising the temperature inside the electrolytic cell has a different purpose from that of the present invention, and the solution is completely different, so that the same effect cannot be expected as a result.
次に電極を磁場におく提案は、 効率を若干向上 （例えば数％以下） することが 認められるが、 未だ本,明で期待する程の効果は認められない。  Next, a proposal to place the electrodes in a magnetic field can be seen to slightly improve the efficiency (eg, a few percent or less), but the effect as expected in this book has not yet been recognized.
更に塩化アル力リ水溶液や濃厚アル力リ水溶液を使用する提案は、 若干の向上 Furthermore, the proposal to use aqueous chloride solution and concentrated aqueous solution slightly improved
(例えば 1 0 %以下） が見受けられるが、 満足すべきものではない。 (For example, less than 10%), but this is not satisfactory.
発明の開示  Disclosure of the invention
然るにこの発明は、 水の酸素分子、 水素分子又は水分子の固有振動に着目し、 その何れか一つに共振を生成させることにより、 水の電解効率を飛躍的に向上さ せて、 前記従来の改善技術では到達し得なかった極めて高い効率で水を電解する ことを可食 にしたのである。  However, the present invention focuses on the natural vibration of oxygen molecules, hydrogen molecules, or water molecules of water, and by generating resonance in any one of them, dramatically improves the electrolysis efficiency of water. This made edible the electrolysis of water with extremely high efficiency that could not be achieved with the improved technology.
例えば、 水素分子の生成時の固有振動の波数 2， 2 5 0 cm— 1での振動又はその 波長 4. 4 X 1 0 _4cmの倍数波長による振動を付与することにより水中の水素分 子を共振させ、 水素分子の離脱を促進させることができた。 更に、 酸素分子又は 水分子の各々の固有振動の振動数の振動又は固有振動の波長の倍数波長での振動 を並行して付与し酸素;^又は水分子を同時に共振させることも可能である。 前記において、各分子の固有振動の振動数の振動を与える場合でも固有振動の 波長の倍数波長の振動を与える場合でも容易に各 5 ^を共振させることができる が、 特に各分子の固有振動の波長の倍数波長の振動を与える場合には、 容易に共 振させることができるのみならず、 倍数波長を迸定すればよいので、 各分子が共 振することのできる条件に容易に適合させることができる。 For example, the wave number 2 of the natural oscillation of the time of generating the hydrogen molecule, 2 5 0 cm- vibration or wavelength 4. 4 X 1 0 _ 4 cm water hydrogen partial child by applying vibration by multiple wavelengths in 1 Was resonated, and the desorption of hydrogen molecules was promoted. Furthermore, it is also possible to simultaneously apply vibration of the natural frequency of the oxygen molecule or water molecule or vibration at a multiple of the wavelength of the natural vibration to simultaneously resonate the oxygen and water molecules. In the above, each of the 5 ^ can be easily resonated when the vibration of the frequency of the natural vibration of each molecule is given or when the vibration of a multiple wavelength of the wavelength of the natural vibration is given. When a vibration having a wavelength that is a multiple of the wavelength is given, not only the resonance can be easily performed, but also the multiple wavelength can be radiated, so that it is easy to match the conditions under which each molecule can resonate. Can be.
本願発明の方法と装置によれば、 水を極めて効率よく ¾ ^することができる。 例えば、 従来 1 4 4 Wで電解した際に発生する水素量と、 この発明により 3 6 W〜4 8Wで電解した際に発生する水素量がほぼ等しいことが確認されている。 従って実施の諸条件により、 効率には多少の高下はあるにしても、 消費電力量が 従来の電解方法と装置を使用した場合の 1/3〜 1/4となることが判る。 According to the method and apparatus of the present invention, water can be extremely efficiently generated. For example, it has been confirmed that the amount of hydrogen generated during electrolysis at 144 W in the past and the amount of hydrogen generated during electrolysis at 36 W to 48 W according to the present invention are substantially equal. Therefore, it can be seen that the power consumption is 1/3 to 1/4 that of the conventional electrolysis method and equipment, even if the efficiency is slightly higher or lower depending on the conditions of implementation.
すなわち、 本願発明の提案する電解方法は、 水の酸素 、 水素分子又は水分 子のいずれか一つの分子の固有振動の振動数での振動又はいずれか一つの分子の 固有振動の波長の倍数波長での振動を付与して、 酸素分子、 水素分子又は水分子 のいずれか一つの分子を共振させると共に、 水に通電することを特徴とした水の 電解方法である。 また他の電解方法の発明は、 電極を帯磁させると共に、 水の酸 素分子、水素分子又は水分子の 、ずれか一つの分子の固有振動の振動数での振動 又はいずれか一つの分子の固有振動の波長の倍数波長での振動を付与して、 酸素 分子、 水素分子又は水分子のいずれか一つの分子を共振させると共に、水に通電 することを特徴とした水の電解方法である。  That is, the electrolysis method proposed by the invention of the present invention is based on the vibration at the frequency of the natural vibration of any one of oxygen, hydrogen, and water molecules of water or a multiple wavelength of the wavelength of the natural vibration of any one of the molecules. A water electrolysis method characterized by applying any of the following vibrations to resonate one of oxygen, hydrogen, and water molecules, and energizing water. Another invention of the electrolysis method is that the electrodes are magnetized and the oxygen molecules, hydrogen molecules or water molecules of water are vibrated at the frequency of the natural frequency of one of the molecules or the characteristic of one of the molecules. A water electrolysis method characterized by applying vibration at a wavelength that is a multiple of the wavelength of vibration to resonate one of oxygen molecules, hydrogen molecules, and water molecules, and energizing water.
前記において、 固有振動の振動数での振動又は固有振動の波長の倍数波長での 振動は、 電極電流のオン、 オフ切り替え手段、 電磁石の電流のオン、 オフ切り替 え手段、 超音波発生手段、 電磁波発生手段、 又は機械的振動付与手段の中の少な くとも一つを用いて電極あるいは電極でない振動板、 又は電解液に付与するもの あ o。  In the above, the vibration at the frequency of the natural vibration or the vibration at a multiple wavelength of the wavelength of the natural vibration is an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave, Applied to electrodes or non-electrode diaphragms or electrolytes using at least one of generating means or mechanical vibration applying means.
また、 前記において、 電解液は、 水又は苛性アルカリもしくは第四級アンモニ ゥム水酸化物又は苛性アル力リの塩もしくは第四級ァンモニゥム水酸化物の塩の 弱アルカリ水溶液としたものである。 特に、 前記の第四級アンモニゥム水酸化物 もしくはその塩としては、 表面張力の少ないテトラメチルアンモニゥムハイドロ ォキサイド等の第 4級アンモニゥム水酸化物又はその塩の水溶液を用いることが 有効である。  In the above, the electrolyte is a weak alkaline aqueous solution of water or a salt of caustic alkali or quaternary ammonium hydroxide or a salt of caustic alkali or a salt of quaternary ammonium hydroxide. In particular, as the quaternary ammonium hydroxide or a salt thereof, it is effective to use an aqueous solution of a quaternary ammonium hydroxide such as tetramethylammonium hydroxide having a low surface tension or a salt thereof.
次に、 本願発明の電解装置の発明は、 水槽内の水中に電極を昇降自在に設置 し、 水の酸素分子、 水素分子又は水分子のいずれか一つの分子の固有振動の振動 数での振動又はいずれか一つの分子の固有振動の波長の倍数波長での振動を付与 して、 酸素分子、 水素分子又は水分子のいずれか一つの分子を共振させる振動手 段を付与したことを特徴とする電解装置である。 また、 他の電解装置の発明は、 水槽内の水中に電極を昇降自在に設置し、 水の酸素分子、 水素分子又は水分子の いずれか一つの分子の固有振動の振動数での振動又はいずれか一つの分子の固有 振動の波長の倍数波長での振動を付与して、 酸素分子、 水素分子又は水分子のい ずれか一つの分子を共振させる振動手段を付与すると共に、 電極を電磁石によつ て交番帯磁させる手段ある L、は電極を永久磁石の磁界の上に電磁石の交番磁界を 加えて交番帯磁させる手段を付与したことを特徴とする電解装置である。 Next, the invention of the electrolysis apparatus of the present invention is to install the electrode in the water in the water tank so as to be movable up and down. Then, by applying vibration at the frequency of the natural vibration of any one of oxygen molecules, hydrogen molecules, and water molecules of water or vibration at a wavelength that is a multiple of the wavelength of the natural vibration of any one of the molecules, oxygen An electrolytic device characterized by having a vibration means for resonating any one of a molecule, a hydrogen molecule and a water molecule. Another invention of an electrolysis apparatus is that an electrode is set up and down in water in a water tank so as to be movable up and down at a frequency of the natural vibration of any one of oxygen, hydrogen and water molecules of water. Vibration at a multiple of the wavelength of the natural vibration of one of the molecules is applied, and vibration means for resonating one of the oxygen, hydrogen, or water molecules is provided, and the electrodes are electromagnetized. Means for alternating magnetizing L is an electrolytic apparatus characterized in that a means for applying an alternating magnetic field of an electromagnet to an electrode on the magnetic field of a permanent magnet to provide an alternating magnetizing method is provided.
前記において、 振動手段は、 電極電流のオン、 オフ切り替え手段、 電磁石の電 流のオン、 オフ切り替え手段、 超音波発生手段、 電磁波発生手段、 又は機械的振 動付与手段の中の少なくとも一つを用いて電極あるいは電極でない振動板、 又は 電解液に付与することとしたものである。  In the above, the vibration means includes at least one of an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave generating means, or a mechanical vibration applying means. It is to be applied to an electrode or a diaphragm that is not an electrode, or an electrolytic solution.
電解用の電源としては自動車用の鉛蓄電池等の直流バッテリ一電源や、交流電 源よりトランス、 整流器により直流電源としたものや、 太陽電池、 燃料電池等を 単独又は並用して用いることができる。  As a power source for electrolysis, a single DC battery power source such as a lead storage battery for an automobile, a DC power source using a transformer or a rectifier instead of an AC power source, a solar cell, a fuel cell, or the like can be used alone or in combination.
電解電流並びに電磁石の電流のオン ·オフ切り替えは、 電源にロータ一、 ブラ シの接触による入力切替え回路を設けて行うか、 または電源にトランジスター、 マルチバイブレーター、 コンデンサーの充放電等のパルス発生回路を設けて、 制 御パルスによりオン ·オフスィツチングを行う。  The on / off switching of the electrolysis current and the electromagnet current is performed by providing an input switching circuit by contacting the rotor and brushes in the power supply, or by using a pulse generation circuit such as a transistor, multivibrator, or charging and discharging capacitors in the power supply. On / off switching by control pulse.
例えばブラシによる入力切替えは、 2〜2 0個の電極を有するディストリビュ 一ターを用いて毎秒 1 0 0〜2， 0 0 0サイクル程度の範囲で行うことができ る  For example, input switching using a brush can be performed in a range of about 100 to 2,000 cycles per second using a distributor having 2 to 20 electrodes.
振動を発生させるための超音波は毎秒 5， 0 0 0〜1 7 5 , 0 0 0サイクルの ものを使用できる。 Ultrasonic waves for generating vibration are generated at 5, 000 to 175, 000 cycles per second. Anything can be used.
電極板を機械的に振動させる場合にはバイブレータ一等を用いて毎秒 1 0 0〜 2 , 0 0 0サイクルの範囲で行う。  When the electrode plate is vibrated mechanically, the vibration is performed in a range of 100 to 2,000 cycles per second using a vibrator or the like.
電極でない振動板は電解槽内の任意の位置に設けることができる。 電極でない 振動板も同じく超音波、 電磁波、 電磁石、 バイブレーターを用いて振動させる。 電極でない振動板と電極板は各々別個に振動させることも可能であるが、 同時 に並行して振動させるとより効果を高めることができて好ましい。  The diaphragm which is not an electrode can be provided at an arbitrary position in the electrolytic cell. Vibration plates that are not electrodes are also vibrated using ultrasonic waves, electromagnetic waves, electromagnets, and vibrators. Although it is possible to vibrate each of the vibrating plate and the electrode plate that are not electrodes separately, it is preferable to vibrate simultaneously and in parallel because the effect can be further enhanced.
この他に、 電磁石に流れる電流をオン ·オフスイッチングすることによりパル スを発生させ、 当該パルスの作用によって水素分子、 酸素分子あるいは水分子を 共振させることもできる。 この場合、 パルス幅 5〜5 0 0マイクロセコンド程度 の範囲で利用することができる。  In addition, it is also possible to generate a pulse by switching the current flowing through the electromagnet on and off, and resonate hydrogen molecules, oxygen molecules or water molecules by the action of the pulse. In this case, the pulse width can be used in the range of about 5 to 500 microseconds.
また、 電磁波を発生させる装置を電解装置の外側に設置し、 電磁波を発生さ せ、 当該電磁波の作用によって水素分子、 酸素分子あるいは水分子を共振させる こともできる。 この場合、 電磁波は電解装置の容量に応じて 5 0〜3 0 Gヘルツ のものを使用できる。 '  Further, a device for generating an electromagnetic wave can be provided outside the electrolytic device to generate the electromagnetic wave, and the hydrogen molecule, the oxygen molecule, or the water molecule can be resonated by the action of the electromagnetic wave. In this case, an electromagnetic wave of 50 to 30 GHz can be used depending on the capacity of the electrolyzer. '
電極の帯磁には永久磁石、 電磁石の何れか一方又は両方を使用することができ る。 電磁石を使用する場合に電流のオン ·オフによって交番磁界を与えて振動を 生成させることもできる。 また交番磁界を与える方法としては、 同極 （N又は S ) の電磁石に交互に電流をオン ·オフさせることにより可能となる。  Either permanent magnets, electromagnets, or both can be used to magnetize the electrodes. When an electromagnet is used, vibration can be generated by applying an alternating magnetic field by turning the current on and off. A method of applying an alternating magnetic field can be achieved by alternately turning on and off the current to electromagnets of the same polarity (N or S).
7 久磁石にはアルニコや鉄'クロム ·コバルト等の合金系、 フェライト系およ びサマリウムやネオジゥム等の希土類系の 5， 0 0 0〜1 2， 5 0 0ガウス以上 のものを用いることができるが、 特に希： fc^系の焼結又はボンド磁石が高磁束密 度を有し、 好ましい。  For magnets, alloys such as alnico or iron'chromium / cobalt, ferrites, and rare earths such as samarium and neodymium, which have a gauss of 5,000 to 12,500 gauss or more, must be used. Yes, but especially rare: fc ^ sintered or bonded magnets have high magnetic flux density and are preferred.
電磁石の鉄心としては純鉄、 ゲイ素鋼板、 パーマロイやフェライトを用いるこ とができる。 この発明の電極には、 鉄、 ニッケル、 チタンやこれらの合金、 およびこれらの 金属に金、 白金、 ロジウム、 インジウム等のメツキを施したもの力、 単極又は複 極型で用いられる。 As the iron core of the electromagnet, pure iron, gay steel sheet, permalloy or ferrite can be used. As the electrode of the present invention, iron, nickel, titanium and alloys thereof, and a metal obtained by plating these metals with gold, platinum, rhodium, indium, etc., are used in a monopolar or bipolar type.
特に粗化、 溶出等の公知の表面拡大処理を施した電極や触媒担持電極を本発明 に用いることは好ましい。  In particular, it is preferable to use an electrode or a catalyst-carrying electrode that has been subjected to a known surface enlargement treatment such as roughening or elution in the present invention.
この発明の電解槽はステンレス、 アルミ等の金属やプラスチックを用いること ができ、 陰 ·陽極間に特に隔膜は必要でなく、 従って極めて簡単な構造とするこ とができるが、 イオン交換能のある固体高分子膜の隔膜を用いて、 両サイドに陰 •陽極板を配した固体電解質型電解槽とすることもできる。  The electrolytic cell of the present invention can use metals and plastics such as stainless steel and aluminum, and does not require a particular membrane between the cathode and the anode. Therefore, it can have an extremely simple structure, but has an ion exchange capability. Using a solid polymer membrane, a solid electrolyte type electrolytic cell having negative and positive plates disposed on both sides can also be used.
この発明の装置を自動車に搭載して水素ェンジン車とすることができる。 また 重油ゃメ夕ノールと併用することもできるが、 ガソリンと共に使用することによ り、 ガソリン 1リツトル当りの走行距離を飛躍的に向上させることもできる。 水 素自体はクリーンなエネルギーであり、 燃焼速度が大きく、 均一なガス混合が得 やすく、 ゎづかな着火エネルギーで広範囲な可燃域で燃焼する特徴があるのでガ ソリン等の燃料に添加することにより燃料の燃焼効率を飛躍的に高め、 燃焼排ガ ス中の未燃焼炭化水素 (H C) 、 一酸化炭素 (C O) 、 窒素酸化物 (N O x) を 減少し、環境公害を低減することができる。  The device of the present invention can be mounted on an automobile to form a hydrogen engine vehicle. It can be used in combination with heavy oil and methanol, but by using it with gasoline, it can dramatically improve the mileage per liter of gasoline. Hydrogen itself is clean energy, has a high combustion rate, is easy to obtain a uniform gas mixture, and has a characteristic that it burns in a wide range of combustible areas with a small ignition energy. Dramatically improve fuel combustion efficiency, reduce unburned hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NO x) in combustion exhaust gas, and reduce environmental pollution .
この発明における電極に帯磁させることについては、 先行技術に記載されてい るが、 帯磁により交番磁界を与えて共振誘起振動を与えることにより、 相剰効果 を奏することが認められた。  The magnetizing of the electrode according to the present invention is described in the prior art. However, it has been recognized that the addition of the alternating magnetic field by the magnetizing to give the resonance-induced vibration produces an additional effect.
またアルカリ水溶液を用いる点についても、 先行技術に記載されているが、 こ の発明においては共振の生成、 帯磁効果との相剰作用により、 水又は弱アルカリ 水を用いて飛躍的効果を生じることができた。  The use of an alkaline aqueous solution is also described in the prior art.However, in the present invention, a remarkable effect is produced by using water or weakly alkaline water due to the generation of resonance and the additive effect of the magnetizing effect. Was completed.
本発明の電解液は電解につれて液温は上昇し、 液抵抗、 槽電圧の低下が起り、 電解効率が向上する。 電解槽を保温 ·加温することにより効率よく電解を行うことができるが、本発 明では特別な加温装置を付設することなく高効率電解を行うことができる。 またポンプ、 ダイヤフラム弁等を用いて電解液を循環させることにより電解効 率を高めることもできるが、 本発明では生成ガスの大量発生、 補充液の槽底への 注入により液循環が起り、 特別な循環装置を付設することなく高効率電解を行う ことができる。 In the electrolytic solution of the present invention, the temperature of the electrolytic solution increases as the electrolysis proceeds, the liquid resistance and the cell voltage decrease, and the electrolytic efficiency improves. Although the electrolysis can be performed efficiently by keeping the electrolytic bath warm and warm, the present invention allows high-efficiency electrolysis without the need for a special heating device. Although the electrolytic efficiency can be increased by circulating the electrolytic solution using a pump, a diaphragm valve, etc., in the present invention, a large amount of generated gas is generated, and the liquid is circulated by injecting a replenisher into the tank bottom. High-efficiency electrolysis can be performed without any additional circulating device.
この発明は、 自動車、 発電所、 船舶、 航空機、 ロケット推進その他多目的エネ ルギ一源として使用し得ると共に、 当該エネルギーは、 使用後再び水に戻るの で、二次公害を生じるおそれはない。  The present invention can be used as a vehicle, power plant, ship, aircraft, rocket propulsion and other multi-purpose energy sources, and since the energy returns to water after use, there is no danger of secondary pollution.
この発明の特徴の 1つは、 水素等の必要とする使用量に応じて水を電解するこ とができるので、 危険性が皆無となることである。 従来水素ガス又は酸素ガスは ボンベに封入されており、 使用時に必要量宛取り出しているので、 不慮の災害時 にガス洩れを生じたり、 ボンベの破壊によって、 大災害を生じる危険性があつ た。 然るにこの発明は、 必要とする使用量だけ水を電解するので、 水素ガス又は 酸素ガスは、 電解装置と使用場所 （例えばェンヂン） を結ぶパイプ内に存在する だけである。 従って不慮の事故により、 パイプが破壊しても、 水素ガスなどの残 留量がきわめて少ないので、 大災害になるおそれはなく、単に水が流れ出るにす ぎない。  One of the features of the present invention is that there is no danger because water can be electrolyzed according to the required amount of hydrogen or the like used. Conventionally, hydrogen gas or oxygen gas is sealed in cylinders, and the required amount is taken out at the time of use. Therefore, there was a risk of gas leaking in the event of an accident or a major disaster due to the destruction of the cylinder. However, since the present invention electrolyzes water by a required amount, hydrogen gas or oxygen gas is only present in a pipe connecting the electrolyzer with a place of use (for example, Endin). Therefore, even if a pipe breaks due to an accident, the remaining amount of hydrogen gas and the like is extremely small, so there is no danger of a catastrophic disaster, and water simply flows out.
また、 7k素発生装置の発生速度を補う目的で発生した水素を水素吸蔵合金に吸 収させて貯蔵する方法も知られているが、 本発明の方法によれば所要時に の 水素を得ることができるので、特別に高価で重量のある貯蔵器を付設することが 不要となる。  A method is also known in which hydrogen generated for the purpose of compensating the generation speed of the 7k element generator is absorbed and stored in a hydrogen storage alloy.However, according to the method of the present invention, hydrogen can be obtained when required. This eliminates the need for extra expensive and heavy storage.
尤も自動車などにおいて使用量が変化する場合においては （例えばアクセルを 踏んだ時と、 踏まない時） 電解液内に浸漬する電極面積の変化により水素等の発 を簡単に制御することができる。 例えば発生ガス量は、 電解液に浸潰した電 極面積に比例するので、電極の位置 （昇降） を制御すれば簡単に調節できる。 尤 もこの場合には電解 を常時一定にしておく必要がある。 However, when the amount of use changes in an automobile or the like (for example, when the accelerator is depressed and when it is not depressed), the generation of hydrogen and the like can be easily controlled by changing the electrode area immersed in the electrolyte. For example, the amount of generated gas depends on the amount of electricity immersed in the electrolyte. Since it is proportional to the pole area, it can be easily adjusted by controlling the electrode position (elevation). However, in this case, it is necessary to keep the electrolysis constant.
前記における水素分子、 酸素分子又は水分子は、 夫々分子量が異なるので、 固 有振動数も自ら異なる力^ 実際使用に際しては、.三つの固有振動数とその倍数波 長の中から、 機器の振動に対して一番安定性のある振動数を選定すればよいの で、 容易に目的を達成することができる。  Since the hydrogen molecule, oxygen molecule, and water molecule in the above have different molecular weights, the natural frequencies themselves are different.In actual use, in the case of actual use, the vibration of the equipment is selected from among the three natural frequencies and their multiple wavelengths. Since the most stable frequency should be selected for, the objective can be easily achieved.
この発明によれば、 水素分子、 酸素分子又は水分子の何れか 1つの固有振動の 振動数での振動又はいずれか一つの固有振動の波長の倍数波長での振動を付与す るので、 前記水素分子等の何れか一つに共振が生じ、 水の分子結合が弱化する。 そこで通電すれば少電流で容易に電解することができる。  According to the present invention, the vibration at the frequency of one of the natural vibrations of the hydrogen molecule, the oxygen molecule, or the water molecule or the vibration at a wavelength that is a multiple of the wavelength of any one of the natural vibrations is applied. Resonance occurs in any one of the molecules and the like, and the molecular bond of water is weakened. Therefore, if electricity is supplied, electrolysis can be easily performed with a small current.
また電解水を例えば弱苛性アル力リ水とし、 電極を交番磁界の中に位置させる ことにより、 振動と、 表面張力低下および磁界作用などが相剰的に作用し、 電解 に要する電力量を飛躍的に低減させることができる。  Also, by using electrolyzed water as, for example, weakly caustic water, and placing the electrodes in an alternating magnetic field, vibration, reduction in surface tension, and magnetic field effects act additively, increasing the amount of power required for electrolysis. Can be effectively reduced.
即ちこの発明によれば、 水素分子、酸素分子又は水分子を共振させるので、 水 は電解し易くなる。 そこで通電することにより、 比較的少電力で効率よく電解し 得る効果がある。  That is, according to the present invention, hydrogen molecules, oxygen molecules or water molecules resonate, so that water is easily electrolyzed. Therefore, by energizing, there is an effect that electrolysis can be efficiently performed with relatively little power.
また電解水を弱アル力リ水などの表面張力の小さい溶液とすると共に、 電極を 磁場内に入れ、 必要に応じて交番磁界を^^することにより、 水素分子等の共振 との相剰作用により、 電解効率を飛躍的に向上し得るなどの諸効果がある。 図面の簡単な説明  In addition, the electrolyzed water is made into a solution with low surface tension such as weak water, and the electrodes are put in a magnetic field, and an alternating magnetic field is applied as necessary to generate a surplus effect with the resonance of hydrogen molecules, etc. Thus, there are various effects such as the electrolytic efficiency can be dramatically improved. BRIEF DESCRIPTION OF THE FIGURES
第 1図は、 この発明の実施装置の一部を省略した縦断面図、 第 2図は、 第 1図 の装置に用いられる電極の拡大図、 第 3図は、 機械的振動手段を備えた電極の拡 大図、 第 4図は、 他の難例の一部を省略した横断面図、 第 5図は、 電磁石への 入力断接を現わす概略図、 第 6図は、 他の実施例の一部断面図、 第 7図は、永久 磁石と電磁石の複合磁石の拡大断面図である。 発明を実施するための最良の形態 FIG. 1 is a longitudinal sectional view in which a part of an apparatus according to the present invention is omitted, FIG. 2 is an enlarged view of an electrode used in the apparatus of FIG. 1, and FIG. 3 is provided with mechanical vibration means. Fig. 4 is an enlarged view of the electrode, Fig. 4 is a cross-sectional view with some of the other difficult examples omitted, Fig. 5 is a schematic diagram showing the connection and disconnection of the input to the electromagnet, and Fig. 6 is another implementation. FIG. 7 is an enlarged sectional view of a composite magnet of a permanent magnet and an electromagnet. BEST MODE FOR CARRYING OUT THE INVENTION
以下本願発明の好ましい実施例を説明する。  Hereinafter, preferred embodiments of the present invention will be described.
(実施例 1 )  (Example 1)
この発明の実施例を第 1図乃至第 3図について説明する。 塩ビ製電解水槽 1内 に、 弱アルカリ水 2 ( 5 %苛性ソーダ水） を 3. 6 入れ、 弱アルカリ水 2内に 各々 7枚の巾 9. 4cm、長さ 1 5 cmの鉄一ニッケル合金製の電極 3、 4 (第 2 図） を 2 m/mの間隔で対向設置する。 該電極 3、 4は櫛歯状に形成され、 +極と 一極の間に絶縁片 1 5 (第 3図） を介装してある。  An embodiment of the present invention will be described with reference to FIGS. 3.6 Weak alkaline water 2 (5% caustic soda water) is placed in an electrolyzed water tank 1 made of PVC, and seven pieces each made of iron-nickel alloy with a width of 9.4 cm and a length of 15 cm are placed in the weak alkaline water 2. Electrodes 3 and 4 (Fig. 2) are installed facing each other at an interval of 2 m / m. The electrodes 3 and 4 are formed in a comb shape, and an insulating piece 15 (FIG. 3) is interposed between the positive pole and one pole.
前記電極 3、 4はブラケット 1 6に固定され、 ブラケット 1 6は昇降杆 1 7に 支持され、 昇降杆 1 7はエアシリンダ 1 8のロッド 1 9 (駆動装置） と連結して ある。 そこで水素ガス等の必要量に応じて、 制御系を介しエアシリンダ 1 8の口 ッド 1 9を昇降することにより、 電極 3、 4の浸漬面積を調節し、 水素ガス等の 生成量を調節することができる。 前記電極 3、 4は、 コード 2 0、 2 1を介して ブラシ 2 2、 2 3に連結し、 ブラシ 2 2、 2 3は回転軸 2 4に固定したロー夕 2 5、 2 6の外周に摺接してある （第 1図） 。  The electrodes 3 and 4 are fixed to a bracket 16, the bracket 16 is supported by a lifting rod 17, and the lifting rod 17 is connected to a rod 19 (drive device) of an air cylinder 18. Therefore, according to the required amount of hydrogen gas, etc., by raising and lowering the port 19 of the air cylinder 18 via the control system, the immersion area of the electrodes 3, 4 is adjusted, and the amount of generated hydrogen gas, etc. is adjusted. can do. The electrodes 3 and 4 are connected to brushes 22 and 23 via cords 20 and 21, and the brushes 22 and 23 are mounted on the outer circumference of the rotors 25 and 26 fixed to the rotating shaft 24. Sliding contact (Fig. 1).
前記駆動装置 1 8は、昇降杆 1 7を往復昇降させる機能を有するもので、 例え ばエアシリンダ一の口ッド、 ラックピニォンのラック又はねじ装置など、 従来公 知の往復移動装置は総て使用することができる。 従って電解装置の使用目的、 設 置場所、 容量、 電解変動量など諸条件により最も適する駆動装置を採用する。 前記ブラケット 1 6には N d F e B系の 1 2， 0 0 0ガウスの直径 3 0 m /m、 厚み 5 m/mの永久磁石 1 2と純鉄に銅線コイルをまいた電磁石 1 3が固定し てある （第 1図） o 永久磁石 1 2は定常的磁場を形成し、電磁石 1 3は、 通常の 自動車用電源バッテリーより得た電流の入力の切替え （ロータとブラシの接触に よる） により毎秒 4 0 0サイクルの交番磁場を形成する。  The driving device 18 has a function of reciprocating the lifting rod 17 and reciprocatingly move up and down.For example, all the conventionally known reciprocating moving devices such as a port of an air cylinder, a rack of a pinion or a screw device are used. can do. Therefore, the most suitable driving device will be adopted depending on various conditions such as the purpose of use of the electrolysis device, the installation place, the capacity, the amount of fluctuation in electrolysis, and the like. The bracket 16 has a permanent magnet 12 of NdFeB series 12 and a diameter of 0.0000 gauss and a diameter of 30 m / m and a thickness of 5 m / m. 3 is fixed (Fig. 1) o The permanent magnet 1 2 forms a stationary magnetic field, and the electromagnet 13 switches the input of the current obtained from a normal automotive power supply battery. To form an alternating magnetic field of 400 cycles per second.
図中 1 4は水位フロート、 1 4 aは水位フロートのアームである。 第 1図にお いて、 弱アル力リ水が供給され水位フロート 1 4が規定高さより上方へ持ち上げ られると、 アーム 1 4 a力く矢示 4 7のように上昇して角度力変り、 検出器 2 7が 働いて電磁弁 2 8を閉鎖し、 弱アルカリ水の供給は中止される。 また電解が進み フロート 1 4力規定高さより下り、 アーム 1 4 aが矢示 4 8のように下降して角 度が変ると、 検出器 2 7力働いて電磁弁 2 8を開放するので弱アル力リ水は供給 される。 従って水位 2 9は常時一定に保たれる。 In the figure, reference numeral 14 denotes a water level float, and reference numeral 14a denotes an arm of the water level float. Fig. 1 When weak water is supplied and the water level float 14 is lifted above the specified height, the arm 14a rises as shown by arrow 47 and the angular force changes, and the detector 27 operates. Solenoid valve 28 is closed, and the supply of weak alkaline water is stopped. When the electrolysis advances and the float 14 falls below the specified force, the arm 14a descends as indicated by the arrow 48 and the angle changes, the detector 27 acts to open the solenoid valve 28, which is weak. Al power water is supplied. Therefore, the water level 29 is always kept constant.
この実施例において、 電解液中の酸素分子、 水素分子又は水分子のいずれか一 つにその固有振動の振動数での振動又はいずれかの固有振動の波長の倍数波長で の振動を与えて共振させる手段を以下に説明する。  In this embodiment, one of oxygen molecules, hydrogen molecules and water molecules in the electrolytic solution is vibrated at the frequency of its natural vibration or at a multiple of the wavelength of any of the natural vibrations to give resonance. The means for causing this will be described below.
第一の手段は、 電解電流をオン、 オフさせることである。 前述したように、 電 極 3、 4は、 コード 2 0、 2 1を介してブラシ 2 2、 2 3に連結されており、 ブ ラシ 2 2、 2 3は回転軸 2 4に固定したロータ 2 5、 2 6の外周に摺接してい る。 したがって、 ロータ 2 5、 2 6を回転させることにより、 電極 3、 4への入 力を断切することができる。 このブラシによる入力切り替えは、 毎秒 1 0 0〜 2， 0 0 0サイクル程度の範囲で行うことが好ましい。  The first means is to turn on and off the electrolysis current. As described above, the electrodes 3 and 4 are connected to the brushes 22 and 23 via the cords 20 and 21, and the brushes 22 and 23 are the rotors 2 fixed to the rotating shaft 24. It is in sliding contact with the outer circumference of 5, 26. Therefore, the input to the electrodes 3 and 4 can be cut off by rotating the rotors 25 and 26. The input switching by the brush is preferably performed in a range of about 100 to 2,000 cycles per second.
この電極 3、 4を流れる電解電流のオン、 オフが、 前述した永久磁石 1 2の存 在によって電極力帯磁している下で生じるため、 電極は振動を生じる。 そしてこ れによって電解液に振動が与えられ、 電解液中の酸素分子、 水素分子又は水分子 の 、ずれか一つに前述した共振振動が与えられ、 所望の共振を生成させる事がで さ 0  Since the on and off of the electrolytic current flowing through the electrodes 3 and 4 occur under the presence of the permanent magnet 12 described above while the electrodes are magnetized, the electrodes generate vibration. As a result, vibration is given to the electrolyte, and the above-described resonance vibration is applied to one of the oxygen molecules, hydrogen molecules, and water molecules in the electrolyte, and a desired resonance is generated.
第二の手段は、 前述した電磁石 1 3によって生じる交番磁場によって電解液中 の酵素分子、 水素分子又は水 の Iゝずれか一つに前述した振動を付与するもの である。 この実施例では、 電磁石 1 3は入力の切り替えによって毎秒 4 0 0サイ クルの交番磁場を形成しているが、 入力の切り替えによって毎秒 1 0 0〜2, 0 0 0サイクル程度の交番磁場を形成すること力河能である。 この交番磁場の変化 を制御することにより電極を交番帯磁させ、 これによつて電極を振動させるとと もに電解液に振動を与え、 電解液中の酸素分子、 水素分子又は水分子のいずれか —つに前述した共振振動を与え、 所望の共振を生成させる事ができる。 The second means is to apply the above-described vibration to one of the enzyme molecules, hydrogen molecules, and water in the electrolytic solution by the alternating magnetic field generated by the electromagnet 13 described above. In this embodiment, the electromagnet 13 forms an alternating magnetic field of 400 cycles per second by switching inputs, but forms an alternating magnetic field of about 100 to 2,000 cycles per second by switching inputs. It is the power to do. Changes in this alternating magnetic field The electrodes are alternately magnetized by controlling the temperature of the electrodes, thereby causing the electrodes to vibrate and, at the same time, vibrating the electrolytic solution. Thus, any one of oxygen molecules, hydrogen molecules, and water molecules in the electrolytic solution is described above. By giving a resonance vibration, a desired resonance can be generated.
なお、 前述した第一の手段と第二の手段を同時に作用させて、 所望の振動を生 じさせる事ももちろん可能である。  It should be noted that the first means and the second means described above can be simultaneously operated to generate a desired vibration.
第3図は、 電解液中の酸素分子、 水素分子又は水分子のいずれか一つに前述し た共振を与える第三の手段を現すものである。 FIG. 3 shows a third means for giving the above-described resonance to any one of oxygen molecules, hydrogen molecules, and water molecules in the electrolytic solution.
即ち第 3図は電極 3、 4の一方に両電極の外側を覆うコ状部材 5を連設し、 該 コ状部材 5の側板 5 a、 5 bの内側へ、 電磁石 6 a、 6 bを固定し、 該電磁石 6 a、 6 bの自由端面と、 前記電極 3、 4とを微小間隙で対向させる。 前記電磁石 6 a、 6 bにはオン ·オフ電流が流れ磁界にオン ·オフが生じるようにしたロー タ 4 1、 4 2とブラシ 4 3、 4 4を備えコード 4 5、 4 6で連結してある。 そこで電磁石 6 aに通電すると、 電極 3、 4は電磁石 6 aに吸着され、 電磁石 6 bに通電すると、電極 3、 4は電磁石 6 bに吸着されるので、結局電極 3、 4 は電流の切換えに同期して振動することになる。 電極 3、 4の振動はそのまま電 解液の振動となって、 水素等の分子の共振を誘発することになる。 そこで前記口 一夕 4 1、 4 2の回転により電磁石の断接を制御すれば、 所定の振動数とするこ とができるので、 水素分子、 酸素分子又は水分子の何れかを共振させることにな る。  That is, in FIG. 3, a U-shaped member 5 that covers the outside of both electrodes is connected to one of the electrodes 3 and 4, and the electromagnets 6a and 6b are placed inside the side plates 5a and 5b of the U-shaped member 5. Then, the free end faces of the electromagnets 6a and 6b are opposed to the electrodes 3 and 4 with a small gap. The electromagnets 6a and 6b are provided with rotors 41 and 42 and brushes 43 and 44, respectively, in which an on / off current flows and a magnetic field is turned on / off, and connected with cords 45 and 46. It is. When the electromagnet 6a is energized, the electrodes 3, 4 are attracted to the electromagnet 6a, and when the electromagnet 6b is energized, the electrodes 3, 4 are attracted to the electromagnet 6b. It oscillates in synchronization with. The vibration of the electrodes 3 and 4 becomes the vibration of the electrolyte as it is, and induces the resonance of molecules such as hydrogen. Therefore, if the connection and disconnection of the electromagnet is controlled by the rotation of the mouth 41, 42, a predetermined frequency can be obtained, so that any of hydrogen molecules, oxygen molecules, or water molecules is resonated. Become.
前記コ状部材には永久磁石 1 0、 1 0 aを固定し、 電極 3、 4を磁場内におく ようにすることもできる。  The permanent magnets 10 and 10a may be fixed to the U-shaped member, and the electrodes 3 and 4 may be placed in a magnetic field.
ここで、 ロータ 4 1、 4 2の回転による電磁石への入力の切り替えは、 毎秒 1 0 0〜2， 0 0 0サイクル程度の範囲で行うことが好ましい。 こうして電極に毎 秒 1 0 0〜2， 0 0 0サイクルの範囲の 的振動を与えることができる。  Here, it is preferable that the switching of the input to the electromagnet by the rotation of the rotors 41 and 42 be performed in a range of about 100 to 2,000 cycles per second. Thus, a target vibration in the range of 100 to 2,000 cycles per second can be applied to the electrode.
電解液中の酸素分子、 水素 又は水 の 、ずれか一つに前述した共振を与 えるための前述した三つの手段では、 振動の発生を電解電流のオン、 オフあるい は電磁石への電流のオン、 オフによって制御している。 これらの電流のオン、 ォ フは前述したように、 ブラシと組み合わせられたロータを回転させることにより 正確に制御できる。 したがって、 電極及び電解液を極めて正確な振動数で振動さ せる事が可能になる。 The above-mentioned resonance is given to one of the oxygen molecules, hydrogen or water in the electrolyte. In the three methods described above, the generation of vibration is controlled by turning on and off the electrolytic current or turning on and off the current to the electromagnet. As described above, the turning on and off of these currents can be accurately controlled by rotating the rotor combined with the brush. Therefore, it is possible to vibrate the electrode and the electrolyte at an extremely accurate frequency.
第 1図の電解槽を用いて、 通常の自動車用電源バッテリーとは別に組込んだ自 動車用鉛蓄電池を電源として電解電圧 1 2 V、 電解電流密度 1 6 AZd nfで電解 したところ電極が完全に電解液中に浸潰した状態で 1分間に水素ガス 1. 8 、 酸素ガス 0. 9 力《発生した。  Using the electrolytic cell shown in Fig. 1 and carrying out electrolysis at an electrolysis voltage of 12 V and an electrolysis current density of 16 AZd nf, using a lead-acid battery for automobiles incorporated separately from a normal automobile power supply battery, the electrodes were completely completed. In a state of being immersed in the electrolyte, hydrogen gas 1.8 and oxygen gas 0.9 were generated per minute.
本発明の水素発生用電解装置を、 ガソリン 1リットル当りの平均走行距離が 1 0. 2kmの自動車に搭載し、 ガソリンと併用した処、 ガソリン 1リットルの平均 走行距離 2 6. 7 kmを得た。  The hydrogen generating electrolyzer of the present invention was mounted on a car having an average mileage of 10.2 km per liter of gasoline, and when used in combination with gasoline, an average mileage of 1 liter of gasoline of 26.7 km was obtained. .
(比較例 1 )  (Comparative Example 1)
電磁石への交番電流を印加することなしに実施例 1と同様の装置を用いて、 同 様の定常電解を行つたところ 1分間当りの発生ガス量は水素が 0. 8 、 酸素が 0. 4 であった。  The same steady-state electrolysis was performed using the same device as in Example 1 without applying an alternating current to the electromagnet.The amount of gas generated per minute was 0.8 for hydrogen and 0.4 for oxygen. Met.
(実施例 2)  (Example 2)
第 4図の実施例は、 水槽 1の水の中へ電極 3、 4を浸漬すると共に、 ブラケッ ト 7で保持する。 ブラケット 7は支杆 8により水槽 1の壁に固定されている。 前記水槽 1の内壁には毎秒 2 0, 0 0 0サイクルの超音波発振器 9が固定して める。  In the embodiment shown in FIG. 4, the electrodes 3 and 4 are immersed in the water of the water tank 1 and held by the bracket 7. The bracket 7 is fixed to the wall of the water tank 1 by a support rod 8. An ultrasonic oscillator 9 of 20.000 cycles per second is fixed to the inner wall of the water tank 1.
前記実施例において、 ブラケット 7には、 永久磁石 4 9と電磁石 1 1が固定し てある。  In the above embodiment, the permanent magnet 49 and the electromagnet 11 are fixed to the bracket 7.
この実施例においては、 超音波発振器 9を使用して電極及び電極付近の電解液 を振動させ、 電解液中の酸素^^、 水素分子又は水分子のいずれか一つにその固  In this embodiment, the electrode and the electrolyte near the electrode are vibrated using an ultrasonic oscillator 9 so that any one of oxygen ^^, hydrogen molecule, and water molecule in the electrolyte is solidified.
2 一 有振動の振動数での振動又はいずれかの固有振動の波長の倍数波長での振動を与 えて共振させる事ができる。 超音波は毎秒 5， 0 0 0〜1 7 5， 0 0 0サイクル のものを使用することが好ましい。 2 one It is possible to resonate by giving vibration at a vibrating frequency or vibration at a wavelength that is a multiple of the wavelength of any natural vibration. It is preferable to use an ultrasonic wave having a frequency of 5,000 to 1,750,000 cycles per second.
また、 前記永久磁石 4 9と電磁石 1 1との作用によって生じる交番磁場で電極 を帯磁させることにより電極を振動させることを同時に行うこともできる。 第 5図は図 1、 2、 3、 4における電磁石 6、 1 1、 1 3の入力の断接を示す 概略図である。  Also, the electrodes can be vibrated simultaneously by magnetizing the electrodes with an alternating magnetic field generated by the action of the permanent magnet 49 and the electromagnet 11. FIG. 5 is a schematic diagram showing connection and disconnection of the input of the electromagnets 6, 11 and 13 in FIGS.
即ち電磁石 6、 1 1、 1 3の夫々の卷線 3 0の端部 3 0 a、 3 O bにブラシ 3 1、 3 2を連結し、 ブラシ 3 1、 3 2をロータ 3 3、 3 4に摺接したものであつ て、 例えばロータ 3 3、 3 4を 5， 0 0 0 r p mで回転させれば各電磁石への入 力を毎秒 5 0 0サイクルで断接することができる。 このロータの回転による入力 の切り替えは、 毎秒 1 0 0〜2， 0 0 0サイクソレ驗で行うことができる。  That is, the brushes 31 and 32 are connected to the ends 30a and 30b of the windings 30 of the electromagnets 6, 11 and 13 respectively, and the brushes 3 and 3 are connected to the rotors 3 and 3 4. For example, if the rotors 33 and 34 are rotated at 5,000 rpm, the input to each electromagnet can be connected and disconnected at 500 cycles per second. The switching of the input by the rotation of the rotor can be performed by 100 to 2,000 cycling tests per second.
(難例 3 )  (Problem 3)
第 6図の実施例は、 水の電解による生成ガスを水素ガスと酸素ガスに分離し、 別々に集める場合の一例を示す。  The embodiment of FIG. 6 shows an example in which a gas produced by electrolysis of water is separated into hydrogen gas and oxygen gas and collected separately.
水槽 1内に弱アルカリ水 2 (テトラメチルアンモニゥムハイドロォキサイドの 0. 1 %水溶液） を入れて水の表面張力を減少させ、 水素並びに酸素の発生を容 易にすると共に、 電極 3、 4を設置する。  Weak alkaline water 2 (0.1% aqueous solution of tetramethylammonium hydroxide) is placed in water tank 1 to reduce the surface tension of water and facilitate the generation of hydrogen and oxygen. Install 4
前記水槽 1の上部は、 電極 3、 4の間に隔壁 3 6を設置し、 水槽底に超音波発 振器 9が設置してある。 また前記隔壁 3 6で区画された水槽 1の頂壁 3 5には、 水素ガスと酸素ガスを夫々排出する為の排出パイプ 3 9、 4 0が連結してある。 前記実施例において、超音波発振器 9によって水素分子、酸素分子又は水分子 を共振させると共に、 各電極 3、 4へ通電すれば、 容易に電解して水素ガスと酸 素ガスが水槽 1の上部空間 1 a、 1 bに集められ、排出パイプ 3 9、 4 0から所 定の場所に排出される。 この場合、 超音波は毎秒 5 , 0 0 0〜1 7 5， 0 0 0サイクルのものを使用で きる。 At the upper part of the water tank 1, a partition wall 36 is installed between the electrodes 3 and 4, and an ultrasonic oscillator 9 is installed at the bottom of the water tank. Discharge pipes 39, 40 for discharging hydrogen gas and oxygen gas, respectively, are connected to the top wall 35 of the water tank 1 divided by the partition wall 36. In the above embodiment, while hydrogen molecules, oxygen molecules or water molecules are resonated by the ultrasonic oscillator 9 and the electrodes 3 and 4 are energized, hydrogen gas and oxygen gas are easily electrolyzed and the hydrogen gas and oxygen gas are separated into the upper space of the water tank 1. They are collected in 1a and 1b and discharged to specified places through discharge pipes 39 and 40. In this case, an ultrasonic wave having a cycle of 5,000 to 175,000 cycles per second can be used.
前記水槽 1の中央部に隔壁として半透膜 3 6を縦設することもできる。  A semipermeable membrane 36 may be vertically provided as a partition at the center of the water tank 1.
また各電極 3、 4には、 第 7図のように永久磁石 3 8の外側へ電磁石 3 7を装 着した磁石を付設し、 電極 3、 4を磁場内におくこともできる。  Further, a magnet having an electromagnet 37 attached outside the permanent magnet 38 as shown in FIG. 7 may be attached to each of the electrodes 3 and 4, so that the electrodes 3 and 4 can be placed in a magnetic field.
前記のようにすれば、 電解液は、 振動及び磁力の作用により一層分解し易くな り、 少電流で効率よく電解されることになる。  According to the above, the electrolytic solution is more easily decomposed by the action of vibration and magnetic force, and the electrolytic solution is efficiently electrolyzed with a small current.
産業上の利用可食  Industrial use
以上のように本願発明にかかる水の電解方法及び装置は水の電気分解に有用で ある。 本願発明の方法と装置によれば水を極めて効率よく電解し、 水素ガスを発 生させることができるので、 本願発明の方法と装置を自動車、 発電所、船舶、 航 空機、 ロケット推進その他の多目的エネルギー源として使用することができる。  As described above, the water electrolysis method and apparatus according to the present invention are useful for water electrolysis. According to the method and apparatus of the present invention, water can be electrolyzed very efficiently to generate hydrogen gas. Therefore, the method and apparatus of the present invention can be used for automobiles, power plants, ships, airplanes, rocket propulsion, etc. Can be used as a multipurpose energy source.

Claims

請求の範囲 The scope of the claims
1. 水の酸素分子、 水素分子又は水分子のいずれか一つの分子の固有振動の振動 数での振動又はいずれか一つの分子の固有振動の波長の倍数波長での振動を付与 して、 酸素分子、 水素分子又は水分子のいずれか一つの分子を共振させると共 に、 水に通電することを特徴とした水の電解方法。 1. Oxygen by applying vibration at the natural vibration frequency of any one molecule of water, oxygen molecule, hydrogen molecule or water molecule or vibration at a wavelength multiple of the wavelength of the natural vibration of any one molecule. A water electrolysis method characterized by resonating one of a molecule, a hydrogen molecule, and a water molecule and energizing water.
2. 電極を帯磁させると共に、 水の酸素分子、 水素分子又は水^ ίのいずれか一 つの分子の固有振動の振動数での振動又はいずれか一つの分子の固有振動の波長 の倍数波長での振動を付与して、 酸素分子、 水素分子又は水分子のいずれか一つ の を共振させると共に、 水に通電することを特徴とした水の電解方法。 2. At the same time as magnetizing the electrode, vibration at the frequency of the natural vibration of one of the oxygen molecules, hydrogen molecule or water of water, or at a wavelength that is a multiple of the wavelength of the natural vibration of any one of the molecules. A water electrolysis method comprising applying vibration to resonate one of oxygen molecules, hydrogen molecules, and water molecules, and energizing water.
3. 固有振動の振動数での振動又は固有振動の波長の倍数波長での振動は、 電極 電流のオン、 オフ切り替え手段、 電磁石の電流のオン、 オフ切り替え手段、 超音 波発生手段、電磁波発生手段、 又は,的振動付 ^段の中の少なくとも一つを 用いて電極あるいは電極でない振動板、 又は電解液に付与することを特徴とした 請求項 1または 2記載の水の電解方法。 3. Vibration at the frequency of the natural vibration or at a multiple of the wavelength of the natural vibration is the electrode current on / off switching means, electromagnet current on / off switching means, supersonic wave generation means, electromagnetic wave generation 3. The method for electrolyzing water according to claim 1, wherein the method is applied to an electrode or a non-electrode vibrating plate or an electrolytic solution using at least one of a means and / or a target vibrating stage.
4. 電解液は、 水又は苛性アル力リもしくは第四級アンモニゥム水酸化物又は苛 性アル力リの塩もしくは第四級ァンモニゥム水酸化物の塩の弱アル力リ水溶液と したことを特徴とする請求項 1または 2記載の水の電解方法。  4. The electrolyte is a weak alkaline aqueous solution of water or caustic alkaline or quaternary ammonium hydroxide or a salt of caustic alkaline hydroxide or a salt of quaternary ammonium hydroxide. The method for electrolyzing water according to claim 1 or 2, wherein
5. 電解液は、 テトラメチルアンモニゥムハイド口オキサイド等の第 4級アンモ ニゥム水酸化物又はその塩の水溶液としたことを特徴とする請求項 1または 2記 載の水の電解方法。  5. The method according to claim 1, wherein the electrolyte is an aqueous solution of a quaternary ammonium hydroxide or a salt thereof, such as tetramethylammonium hydroxide.
6. 水槽内の水中に電極を昇降自在に設置し、 水の酸素分子、 水素分子又は水分 子のいずれか一つの分子の固有振動の振動数での振動又はいずれか一つの分子の 固有振動の波長の倍数波長での振動を付与して、 酸素分子、 水素分子又は水分子 の L、ずれか一つの分子を共振させる振動手段を付与したことを特徴とする電解装 6. The electrode is set up and down freely in the water in the water tank, and the vibration at the frequency of the natural vibration of any one molecule of oxygen molecule, hydrogen molecule or water molecule of water or the natural vibration of any one molecule An electrolytic device characterized by providing vibration at a multiple wavelength of the wavelength, and vibration means for resonating one of the oxygen molecules, hydrogen molecules, or water molecules.
7. 水槽内の水中に電極を昇降自在に設置し、 水の酸素分子、 水素分子又は水分 子のいずれか一つの分子の固有振動の振動数での振動又はいずれか一つの分子の 固有振動の波長の倍数波長での振動を付与して、 酸素分子、 水素分子又は水分子 のいずれか一つの分子を共振させる振動手段を付与すると共に、電極を電磁石に よつて交番帯磁させる手段を付与したことを特徵とする電解装置。 7. An electrode is installed in the water in the water tank so as to be able to move up and down, and the vibration at the frequency of the natural vibration of any one of oxygen molecules, hydrogen molecules or water molecules of the water or the natural vibration of any one molecule Vibration at a multiple of the wavelength is applied to provide vibration means to resonate any one of oxygen, hydrogen, and water molecules, and means to alternately magnetize the electrodes using an electromagnet. Electrolyzer characterized by.
8. 水槽内の水中に電極を昇降自在に設置し、 水の酸素分子、 水素分子又は水分 子のいずれか一つの分子の固有振動の振動数での振動又はいずれか一つの分子の 固有振動の波長の倍数波長での振動を付与して、 酸素分子、 水素分子又は水分子 のいずれか一つの分子を共振させる振動手段を付与すると共に、電極を永久磁石 の磁界の上に電磁石の交番磁界を加えて交番帯磁させる手段を付与したことを特 徵とする電解装置。  8. The electrode is placed in the water in the water tank so as to be able to move up and down, and the vibration at the natural vibration frequency of any one of oxygen molecules, hydrogen molecules or water molecules of water or the natural vibration of any one molecule Vibration at a multiple of the wavelength is applied to provide vibration means for resonating any one of oxygen, hydrogen, and water molecules. In addition, an electrolytic apparatus characterized in that a means for alternating magnetization is provided.
9. 振動手段は、電極電流のオン、 オフ切り替え手段、 電磁石の電流のオン、 ォ フ切り替え手段、超音波発生手段、 電磁波発生手段、 又は機械的振動付与手段の 中の少なくとも一つを用いて電極あるいは電極でない振動板、 又は電解液に付与 することを特徴とした請求項 6乃至 8の ゝずれか一つに記載の電解装置。  9. The vibrating means is at least one of an electrode current on / off switching means, an electromagnet current on / off switching means, an ultrasonic wave generating means, an electromagnetic wave generating means, or a mechanical vibration applying means. The electrolytic device according to any one of claims 6 to 8, wherein the electrolytic device is applied to an electrode or a diaphragm other than an electrode, or an electrolytic solution.
PCT/JP1994/001366 1993-08-27 1994-08-18 Water electrolyzing method and apparatus WO1995006144A1 (en)

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JP2007508454A (en) * 2003-10-14 2007-04-05 ビールバウマー，ハンス−ペーター Energy converter
JP2006272051A (en) * 2005-03-28 2006-10-12 Mitsui Chemicals Inc Waste water treatment method
JP2012515845A (en) * 2009-01-20 2012-07-12 パルミル Electrolysis method, apparatus and system
WO2012169977A1 (en) * 2011-06-10 2012-12-13 Sukij Tridsadeerak Wdh3 hydrogen separation tank
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CN106244269A (en) * 2016-08-07 2016-12-21 玉灵华科技有限公司 A kind of safe high fever value gas preparation method and system
EP3495457A4 (en) * 2016-08-07 2020-03-25 Yulinghua Technology Co. Ltd Method and system for preparing safe high heating value fuel gas
WO2018070061A1 (en) * 2016-10-13 2018-04-19 正裕 井尻 Acid hydrogen generating device, and hybrid vehicle or fuel-cell vehicle provided with acid hydrogen generating device
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