WO1986005796A1 - A curable elastic composition consisting of liquid urethane polymer and solid, cured rubber and use thereof - Google Patents

A curable elastic composition consisting of liquid urethane polymer and solid, cured rubber and use thereof Download PDF

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Publication number
WO1986005796A1
WO1986005796A1 PCT/SE1986/000146 SE8600146W WO8605796A1 WO 1986005796 A1 WO1986005796 A1 WO 1986005796A1 SE 8600146 W SE8600146 W SE 8600146W WO 8605796 A1 WO8605796 A1 WO 8605796A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
curing
solid
composition according
curable
Prior art date
Application number
PCT/SE1986/000146
Other languages
French (fr)
Inventor
Erik A. Haeffner
Original Assignee
Innocap Aktiebolag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Innocap Aktiebolag filed Critical Innocap Aktiebolag
Publication of WO1986005796A1 publication Critical patent/WO1986005796A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes

Definitions

  • This invention relates to a hardenable (curable) product com ⁇ position consisting of a liquid curable polymer part (prior to curing) and a vulcanized, or cured elastic part in solid form present as a reinforcement or elastic filler of the mix- ture after curing.
  • the curable polymer part can preferably consist of a two com ⁇ ponent curable urethane polymer, and the second part, e.g., of a vulcan-zed, natural or synthetic rubber in the form of spherical particles having a diameter, preferably less than about 1 mm, or of fiber form having a length of 5 to 15 mm, and a diameter less than 1 mm.
  • the part of vulcanized rubber shall have such an elasticity modulus, and hardness that cor ⁇ respond to the use of the final mixed product.
  • the incorporation by mixing of solid particles and/or fibres can be 10 to 40 % by weight of the mixture depending on the properties wanted of the final product. After mixing of the parts, and application, and shaping, respectively, the mix- ture is cured in situ.
  • the product composition intended can be used for a number of purposes.
  • the composition can be applied on a surface which shall be protected from mechanical damage, e.g., wear- mg surfaces on transport devices.
  • the composition can also be sprayed, rolled, apinted, and stopped, or in any other way be applied onto a surface of a material as a protection against corrosion, water, and aggresive liquids.
  • the compo ⁇ sition can be cast in a mould prior to curing, e.g., at the production of vehicle tires, and other cast products. Lt can also be used in tightening of tube joints and closures.litis,,, .
  • the product composition can be provided with agents that pro ⁇ vide particular properties to the finished composition,..such as colour by adding a colour pigment, increased-adhesiveness by adding a tar fraction, tixotrophy by adding zeolithes. fire restistance by adding organic chloro compounds, and cor ⁇ rosion inhibiting properties by adding inhibitors such as hexamethylene diamine.
  • agents that pro ⁇ vide particular properties to the finished composition ..such as colour by adding a colour pigment, increased-adhesiveness by adding a tar fraction, tixotrophy by adding zeolithes. fire restistance by adding organic chloro compounds, and cor ⁇ rosion inhibiting properties by adding inhibitors such as hexamethylene diamine.
  • a product composition according to the invention can contain a binding agent for the rubber particles, and fibres, respectively, present, consist ⁇ ing of a mixture of the following components:
  • DESMOPHEN 1150 Branched polyalcohol having ether and ester groups present.
  • DESMODUR VL Polyisocyanate, prepolymer based on diphenyl methane - diisocyanate. (Viscosity about half of that of DESMO- • PHEN 1150) .

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A curable elastic product composition consisting of a liquid curable polymer part, and a vulcanized, or cured elastic part in solid form as a reinforcement or elastic filler of the mixture after curing.

Description

and use thereof
This invention relates to a hardenable (curable) product com¬ position consisting of a liquid curable polymer part (prior to curing) and a vulcanized, or cured elastic part in solid form present as a reinforcement or elastic filler of the mix- ture after curing.
The curable polymer part can preferably consist of a two com¬ ponent curable urethane polymer, and the second part, e.g., of a vulcan-zed, natural or synthetic rubber in the form of spherical particles having a diameter, preferably less than about 1 mm, or of fiber form having a length of 5 to 15 mm, and a diameter less than 1 mm. The part of vulcanized rubber shall have such an elasticity modulus, and hardness that cor¬ respond to the use of the final mixed product.
The incorporation by mixing of solid particles and/or fibres can be 10 to 40 % by weight of the mixture depending on the properties wanted of the final product. After mixing of the parts, and application, and shaping, respectively, the mix- ture is cured in situ.
The product composition intended can be used for a number of purposes. Thus the composition can be applied on a surface which shall be protected from mechanical damage, e.g., wear- mg surfaces on transport devices. The composition can also be sprayed, rolled, apinted, and stopped, or in any other way be applied onto a surface of a material as a protection against corrosion, water, and aggresive liquids. The compo¬ sition can be cast in a mould prior to curing, e.g., at the production of vehicle tires, and other cast products. Lt can also be used in tightening of tube joints and closures. „,, .
The product composition can be provided with agents that pro¬ vide particular properties to the finished composition,..such as colour by adding a colour pigment, increased-adhesiveness by adding a tar fraction, tixotrophy by adding zeolithes. fire restistance by adding organic chloro compounds, and cor¬ rosion inhibiting properties by adding inhibitors such as hexamethylene diamine.
Working example.
A product composition according to the invention (airless rubber mass without tar) can contain a binding agent for the rubber particles, and fibres, respectively, present, consist¬ ing of a mixture of the following components:
DESMOPHEN 1150 Branched polyalcohol having ether and ester groups present.
REACTIVE DILUENT PU Ether alcohol
(having low viscosity, maximum 15 % can be added, and improves thereby elastici¬ ty and adhesiveness) .
DESMODUR VL Polyisocyanate, prepolymer based on diphenyl methane - diisocyanate. (Viscosity about half of that of DESMO- •PHEN 1150) .
. These products are marketed by BAYER AG. By using a high amount of binding agent and a suitable compo- ' sition elasticity, wearing resistance, adhesiveness, and chemical resistance have improved considerably.
Base % by weight
Desmophen 1150 40.1 40.1 40.1
Reactive diluent PU 4.5- 4.5 4.5
Zeolith paste 6.4 6.4 6.4
Rubber powder 49.0 .49.0 49.0
100.0 100.0 100.0
Hardener % by weight
Desmodur VL 8.9 8.0 9.8 Des odur KL(E23) 22.2 20.6 24.4
31.1 28.6 34.2 Cross linking 100% 90% 110%
Base/hardener 3.2 3.5 2.9
Rubber powder 37.5% 38.2% 36.5%
Binder 58 % 57 % 59 %
Standard specification.
If so requested a suitable combination can be selected,

Claims

1. Curable product composition, characterized in that it con¬ sists of a mixture of a liquid, curable polymer part (prior to curing) and a vulcanized, or cured elastic part in solid form as a reinforcement, or elastic filler of the mixture after vulcanization or curing.
2. Composition according to claim 1, characterized in that the curable polymer part consists of a two component urethane polymer.
3. Composition according to claim 1, characterized in that the solid part consists of natural or synthetic rubber.
4. Composition according to claim 3, characterized in that the solid part consists of spherical particles.
5. Composition according to claim 3, characterized in that the solid part consists of fibres.
6. Composition according to claim 1, characterized in that the solid part has an elasticity modulus and hardness which differ from that of the curable part after having been cured whereby the elasticity and other strength properties of the composite material having been used can be adopted to the use intended.
7. Method for using the composition of claims 1 to 6 , charac¬ terized in that the mixture prior to curing is applied onto the surface to be protected against corrosion, contact with water, or aggresive solutions.
8 Method according to claim 7, characterized in that the mix¬ ture is applied onto a surface to be protected against mecha¬ nical damage.
9. Method according to claim 7, characterized in that the mixture prior to curing is cast in a mould, e.g., for the production of vehicle tires, or other products.
10. A method for applying the composition of claims 1 to 6, characterized in that a space room intended for tightening purposes between tubes is filled with a composition by means of spraying or extrusion of a string, which is then allowed to cure in situ.
PCT/SE1986/000146 1985-04-01 1986-04-01 A curable elastic composition consisting of liquid urethane polymer and solid, cured rubber and use thereof WO1986005796A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO851332A NO851332L (en) 1985-04-01 1985-04-01 HARDENABLE MIXING.
NO851332 1985-04-01

Publications (1)

Publication Number Publication Date
WO1986005796A1 true WO1986005796A1 (en) 1986-10-09

Family

ID=19888212

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1986/000146 WO1986005796A1 (en) 1985-04-01 1986-04-01 A curable elastic composition consisting of liquid urethane polymer and solid, cured rubber and use thereof

Country Status (5)

Country Link
EP (1) EP0218673A1 (en)
AU (1) AU5694186A (en)
NO (1) NO851332L (en)
SE (1) SE8600551L (en)
WO (1) WO1986005796A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989003860A1 (en) * 1987-10-14 1989-05-05 Tyndale Plains-Hunter, Ltd. Moisture sensitive elastomer compositions
US4920172A (en) * 1989-01-30 1990-04-24 Tyndale Plains-Hunter Ltd. Hydrophilic polyurethane emulsions and materials produced therefrom
EP0606379A1 (en) * 1991-10-02 1994-07-20 Urethane Technologies, Incorporated Non-cellular polyurethane composite
EP0860486A1 (en) * 1997-02-20 1998-08-26 Procoat Aktiebolag Composition for coating, sealing and protection purposes
WO2005056666A1 (en) * 2003-12-11 2005-06-23 Laurentiu Daniel Tigau Polimeric compound including rubber particles, obtaining procedure, it's applyance and resulting coating using this material

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10022192A1 (en) * 2000-05-03 2001-11-15 Mannesmann Ag Device for removing injection molded parts

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1594284A1 (en) * 1965-09-08 1971-04-15 Teerbau Gmbh Strassenbau Use of a mixture of synthetic resin, bituminous binder and rubber as a joint sealing compound and for the production of sealing connections and the like.
US3628585A (en) * 1963-09-09 1971-12-21 Goodyear Tire & Rubber Pneumatic tire containing a sealant
GB1484740A (en) * 1974-10-05 1977-09-01 Bayer Ag Process for the production of composites
GB1509108A (en) * 1975-11-27 1978-04-26 Ceintrey M Covering for sports-ground surfaces
GB2023624A (en) * 1978-06-21 1980-01-03 Dunlop Ltd Resilient Compositions
GB2025988A (en) * 1978-07-13 1980-01-30 Michelin & Cie Self-sealing pneumatic tyres
GB2035336A (en) * 1978-11-17 1980-06-18 Ryburn Foam Ltd Method of producing a rubber- based product, preferably using waste rubbers
EP0057488A2 (en) * 1981-02-04 1982-08-11 Appalachian Corporation S.A. Spray-on corrosion inhibiting composition
FR2509743A1 (en) * 1981-07-15 1983-01-21 Polychrome Corp Photopolymerisable compsn. for forming relief images or inks - contains polyurethane or polyurea polymer, activator, comonomer and a rubber giving soft resilient surface to cured compsn.
GB2119806A (en) * 1982-04-28 1983-11-23 Furnamite Int Ltd Durable elastomer-based sealants
EP0156941A2 (en) * 1983-06-10 1985-10-09 The Dow Chemical Company Polyurethane plastics with improved impact resistance

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3628585A (en) * 1963-09-09 1971-12-21 Goodyear Tire & Rubber Pneumatic tire containing a sealant
DE1594284A1 (en) * 1965-09-08 1971-04-15 Teerbau Gmbh Strassenbau Use of a mixture of synthetic resin, bituminous binder and rubber as a joint sealing compound and for the production of sealing connections and the like.
GB1484740A (en) * 1974-10-05 1977-09-01 Bayer Ag Process for the production of composites
GB1509108A (en) * 1975-11-27 1978-04-26 Ceintrey M Covering for sports-ground surfaces
GB2023624A (en) * 1978-06-21 1980-01-03 Dunlop Ltd Resilient Compositions
GB2025988A (en) * 1978-07-13 1980-01-30 Michelin & Cie Self-sealing pneumatic tyres
GB2035336A (en) * 1978-11-17 1980-06-18 Ryburn Foam Ltd Method of producing a rubber- based product, preferably using waste rubbers
EP0057488A2 (en) * 1981-02-04 1982-08-11 Appalachian Corporation S.A. Spray-on corrosion inhibiting composition
FR2509743A1 (en) * 1981-07-15 1983-01-21 Polychrome Corp Photopolymerisable compsn. for forming relief images or inks - contains polyurethane or polyurea polymer, activator, comonomer and a rubber giving soft resilient surface to cured compsn.
GB2119806A (en) * 1982-04-28 1983-11-23 Furnamite Int Ltd Durable elastomer-based sealants
EP0156941A2 (en) * 1983-06-10 1985-10-09 The Dow Chemical Company Polyurethane plastics with improved impact resistance

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989003860A1 (en) * 1987-10-14 1989-05-05 Tyndale Plains-Hunter, Ltd. Moisture sensitive elastomer compositions
US4920172A (en) * 1989-01-30 1990-04-24 Tyndale Plains-Hunter Ltd. Hydrophilic polyurethane emulsions and materials produced therefrom
EP0606379A1 (en) * 1991-10-02 1994-07-20 Urethane Technologies, Incorporated Non-cellular polyurethane composite
EP0606379A4 (en) * 1991-10-02 1994-08-03 Urethane Technologies, Incorporated
EP0860486A1 (en) * 1997-02-20 1998-08-26 Procoat Aktiebolag Composition for coating, sealing and protection purposes
WO1998037145A1 (en) * 1997-02-20 1998-08-27 Procoat Ab Composition for coating, sealing and protection purposes
WO2005056666A1 (en) * 2003-12-11 2005-06-23 Laurentiu Daniel Tigau Polimeric compound including rubber particles, obtaining procedure, it's applyance and resulting coating using this material

Also Published As

Publication number Publication date
SE8600551L (en) 1986-10-02
SE8600551D0 (en) 1986-02-07
EP0218673A1 (en) 1987-04-22
NO851332L (en) 1986-10-02
AU5694186A (en) 1986-10-23

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