Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
  • B01J37/20—Sulfiding

Definitions

• This invention relates to a method of presulfiding a supported metal oxide catalyst for use in hydrotreating hydrocarbon feed stocks and, a hydrotreating process utilizing a presulfided metal oxide catalyst.
• a hydrotreating catalyst may be defined as any catalyst composition which may be employed to catalyze the hydrogenation of hydrocarbon feedstocks. Such catalyst compositions are well known to those of ordinary skill in the art and several are commercially available. Metal oxide catalysts which come within this definition include cobalt-molybdenum, nickel-tungsten, and nickel-molybdenum. Typical supports for hydrotreating metal oxide catalysts include alumina, silica and silica-alumina supports.
• a high boiling oil is defined as an oil whose initial boiling point is greater than 400° F.
• Hydrotreating catalysts are typically presulfided by incorporating sulfur compounds into the porous catalyst prior to hydrotreating a hydrocarbon feedstock.
• U.S. Pat. No. 4,530,917 to Berrebi discloses a method of presulfiding a hydrotreating catalyst with organic polysulfides.
• the present invention relates to an improved method of presulfiding a hydrotreating catalyst which minimizes sulfur stripping upon start-up of a hydrotreating reactor and improves catalyst activity.
• the catalyst is preferably presulfided by one of two methods. The first method comprises the steps of
• the second method comprises the steps of
• the catalyst is mixed with elemental sulfur at a temperature below the melting point of sulfur and then heated, in the absence of oil and hydrocarbon solvents to a temperature above the melting point of sulfur but below temperatures where activity loss is observed.
• Powdered sulfur may be physically mixed with the catalyst particles prior to loading the catalyst particles in a reactor.
• the elemental sulfur and the catalyst particles may be mixed together at a temperature below the melting point of sulfur, preferably in the range of from 180° F. to 210° F. In this temperature range, the elemental sulfur sublimes and is incorporated into the pores of the catalyst particles where, upon cooling, it condenses.
• the sulfur-catalyst mixture is then heated to a temperature above the melting point of sulfur preferably in the range of from 250° F. to 390° F. In the presence of hydrogen, activation of the catalyst takes place. That is, the metal oxides react with substantially all of the sulfur incorporated into the catalyst pores, thus producing H 2 S and metal sulfides.
• Mixing times for the powdered elemental sulfur and the catalyst can be minimized by heating the mixture at higher temperatures, within specified limitations, due to the increased vapor pressure of the sulfur.
• the amount of sulfur employed is 2 to 15% by weight of the catalyst charged. Most preferably, the amount of sulfur employed is about 6% to 8% by weight of the catalyst charged. Mixing times of the powdered sulfur and the catalyst particles are also minimized due to the reduced quantity of sulfur. While the use of greater amounts of sulfur does result in more sulfur being incorporated into the pores of the catalyst, the amount of sulfur stripping during reactor start-up is much greater than that of a 6 to 8% charge. When 6 to 8% sulfur by weight is employed, a minimum stripping effect is observed upon reactor start-up.
• a significant aspect of the present invention is that improved results are obtained when catalyst presulfiding is accomplished by mixing the catalyst particles with powdered elemental sulfur and sequentially or simultaneously contacting the sulfur-catalyst mixture with a high boiling oil or hydrocarbon solvent and heating to a temperature above the melting point of sulfur.
• this step will be referred to as prewetting.
• Subsequent activity tests on catalysts produced using such a technique have shown excellent results.
• oils and hydrocarbon solvents may be used as prewetting agents according to the claimed invention. Good results have been achieved when using oils with boiling ranges from approximately 700° F. to 1000° F. In particular, vacuum gas oils with low sulfur contents have been shown to be successful.
• the prewetting step is independent of mixing the powdered sulfur with the catalyst, it may be performed in-situ or off-site of the reactor. If prewetted in-situ, the feedstock used in the reactor can be used as the prewetting oil, minimizing costs for the refinery.
• catalyst particles are sequentially contacted with first, elemental sulfur, then an oil or solvent.
• the catalyst particles are contacted with the powdered elemental sulfur at a temperature below the melting point of sulfur and preferably in the range of from 180° F. to 210° F.
• the catalyst and the sulfur are then mixed for a sufficient amount of time to allow incorporation of the sulfur into the catalyst pores.
• a catalyst-sulfur mixture is thus produced.
• a high boiling oil or hydrocarbon solvent is added thus producing a prewet mixture.
• the prewet mixture is preferably further heated to a temperature above the melting point of sulfur. Most preferably, to a temperature in the range of 250° F. to 450° F.
• the presulfided prewet catalyst so prepared may be conveniently activated by heating in the presence of hydrogen.
• the catalyst particles are contacted with both the powdered elemental sulfur and the high boiling oil or hydrocarbon solvent simultaneously.
• a mixture of elemental sulfur and a high boiling oil or hydrocarbon solvent is first produced. A ratio of approximately 4:1 oil to sulfur by weight is preferred.
• the mixture is then heated to approximately 100° F. to promote homogenous mixing of the components. Toluene or other light weight hydrocarbon solvents may be added to decrease the viscosity of the mixture. Also, increased heat will achieve the same effect.
• the mixture is then added to a preweighed catalyst sample and mixed.
• catalyst particles prewet by the simultaneous method described above are further heat treated at a temperature in the range of from 250° F. to 450° F. under a nitrogen atmosphere or other inert atmosphere.
• a versatile hydrotreating catalyst which shows good activity under various reactor conditions is a nickel-molybdenum catalyst.
• Cobalt-molybdenum and nickel-tungsten catalysts are also preferred although many other metal oxide catalysts may be presulfided according to the claimed invention.
• the processes of the present invention are further applicable to the sulfiding of spent catalysts which have been oxy-regenerated.
• an oxy-regenerated catalyst may be presulfided as would fresh catalyst in the manner set forth above and specifically in a manner set forth by way of the following examples.
• a sample of a Nickel-Molybdenum catalyst was dried at 700° F. for one hour and then cooled to ambient under vacuum. The sample was then placed in a flask and enough elemental sulfur was added to produce a sulfur level of 6%. The flask was then sealed and placed in a 231° F. oven for one hour. During this time period, the flask was rotated continually to provide uniform distribution of sulfur. The final sulfur level was 6% sulfur.
• a sample of a Nickel-Molybdenum catalyst was dried at 700° F. for one hour and then cooled to ambient under vacuum.
• the mixture was heated to 102° F. and mixed. The mixture was removed from the heat and 15.51 grams of toluene were added and mixed.
• a sample of a Nickel-Molybdenum catalyst was dried at 700° F. for one hour and then cooled to ambient under vacuum. The sample was then placed in a flask and enough elemental sulfur was added to produce a sulfur level of 6.6%. The flask was then sealed and placed in a 231° F. oven for one hour. During this time period, the flask was rotated continually to provide uniform distribution of sulfur.
• Example IIA The catalyst prepared in Example IIA was heat treated at 392° F. for one hour under a nitrogen blanket. The sample was also cooled under a nitrogen blanket. The final sulfur level was 4.9%. It is expected that the Standard Method, Sequential Prewet and Heat would produce comparable results.
• the hydrogen feed rate and reactor pressure are established at ambient temperature.
• the liquid feed is introduced and the reactor temperature is increased to 250° F. during the first hour on stream.
• the reactor temperature is then increased at a rate of about 45° F./hour to 650° F.
• the reactor is then allowed to cool to 475° F. during the next two hours.
• the diesel is discontinued and the standard 1.8 wt. % sulfur gas oil feedstock is started.
• the standard gas oil feedstock consists of 2/3 vacuum gas oil and 1/3 light cycle oil.
• the API gravity is 21.6°
• the weight percent Sulfur is 1.8%
• the Total Nitrogen content is 880 ppm.
• Standard run conditions are:
• the reactor pressure, hydrogen flow rate and liquid feed rate are established at ambient temperature.
• the reactor temperature was increased at a rate of 24° F./hour to 650° F.
• the heat was cut off and the temperature was reduced to 475° F.
• the diesel oil was drained from the feed tank and the standard 1.8 wt. % Sulfur feedstock was charged. Standard run conditions, heating rate, etc. followed.
• the reactor was heated at a rate of 50° F./hr until a temperature of 625° F. was reached. During this heat up period, liquid feed was introduced when the reactor temperature reached 550° F. at a feed rate of 65 gms/hr.
• the standard method presulfided catalysts have difficulties. With the slow diesel start-up, excessive sulfur is displaced from the catalyst resulting in less activity. With the hydrogen to 550° F. start-up, the standard method presulfided catalysts yield poor results because of the exposure to hydrogen at high temperature without a hydrocarbon present.
• the modified procedures of the simultaneous and sequential prewet methods with and without heat overcome these difficulties by producing a catalyst that can tolerate a wide range of conceivable start-up procedures.

Landscapes

• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Organic Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Catalysts (AREA)
• Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Priority Applications (6)

Applications Claiming Priority (1)

Related Child Applications (1)

Publications (1)

Family

ID=22919720

Family Applications (1)

Country Status (5)

Cited By (48)

Families Citing this family (5)

Citations (17)

Family Cites Families (3)

• 1988
  • 1988-09-13 US US07/243,687 patent/US4943547A/en not_active Expired - Lifetime
• 1989
  • 1989-05-10 EP EP89304719A patent/EP0359356B1/de not_active Expired
  • 1989-05-10 DE DE8989304719T patent/DE68902375T2/de not_active Expired - Lifetime
  • 1989-05-25 CA CA000600446A patent/CA1334586C/en not_active Expired - Lifetime
  • 1989-09-13 JP JP1238326A patent/JPH0829257B2/ja not_active Expired - Lifetime

Patent Citations (19)

Non-Patent Citations (2)

Also Published As

Similar Documents

Legal Events