US4797434A - Process for the manufacture of particulate bituminized plastics material - Google Patents

Process for the manufacture of particulate bituminized plastics material Download PDF

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Publication number
US4797434A
US4797434A US07/002,697 US269787A US4797434A US 4797434 A US4797434 A US 4797434A US 269787 A US269787 A US 269787A US 4797434 A US4797434 A US 4797434A
Authority
US
United States
Prior art keywords
water
plastics material
bitumen
emulsion
particulate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US07/002,697
Other languages
English (en)
Inventor
Frederick D. Lovatt-Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denehunt Ltd
Original Assignee
Denehunt Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denehunt Ltd filed Critical Denehunt Ltd
Application granted granted Critical
Publication of US4797434A publication Critical patent/US4797434A/en
Assigned to DENEHUNT LIMITED, A BRITISH COMPANY reassignment DENEHUNT LIMITED, A BRITISH COMPANY ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: LOVATT-SMITH, FREDERICK D.
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/005Processes for mixing polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • Y10T428/2998Coated including synthetic resin or polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31815Of bituminous or tarry residue

Definitions

  • This specification relates to a process for the manufacture of particulate material and is particularly, but not exclusively, concerned with the manufacture of material for use as a horse riding surface.
  • Riding surfaces made from this material have certain drawbacks. Firstly, the material does not compact very well and tends to slide away from under a horse's hooves. Secondly, the material is not very dense and, for example, can blow away in a breeze. Thirdly, the material tends to have a significant dust content, which is undesirable.
  • bitumenized material manufactured from raw granulated plastics material which has been bitumenized.
  • This material is denser and compacts in a better manner than the raw material. Furthermore, dust is substantially eliminated.
  • the bitumen used is relatively cheap, weather resistant and non-toxic. An important feature is that the bitumen remains adhered to the plastics granules but does not adhere to a horse's hooves.
  • a process for manufacturing the material includes the steps of mixing the raw granulated plastics material with bitumen emulsion and water in such a way that the granules are coated whilst significant agglomeration is avoided. To have the granules agglomerate into substantial lumps would be unacceptable.
  • a mixing drum is filled with the raw plastics material, and there are added--generally simultaneously--the required quantity of bitumen, a relatively large quantity of water at low pressure, and a relatively small quantity of water at high pressure. This high pressure water agitates the mixture and promotes coating without agglomeration.
  • Other mixing means--such as stirrers--could be used.
  • bitumen and water could be added by completely separate nozzles, for example, or by three nozzles feeding into one outlet.
  • a large rotatable mixing drum is used, of a type normally employed for mixing concrete.
  • the drum has a capacity of 6 cubic meters.
  • About 41/2 tons of raw granulated PVC is fed into the drum by a conveyor which receives the PVC from a hoper. The drum is then rotated.
  • Water and bitumen emulsion are then added.
  • the preferred emulsion is cationic 40%, for example in accordance with British Standard 434, Part II, Class K1-40. Such an emulsion is available from Kelbit Limited. Other cationic bitumen emulsions might be usable, such as 60% or 55% but the 40% emulsion has been found to give particularly good results. Anionic emulsion will generally not adhere properly to the PVC.
  • the emulsion is added in a quantity in the range of about 40-50 liters per ton of PVC.
  • the preferred quantity, which gives especially good results, is 44 liters per ton, which gives about 200 liters for the 41/2 ton PVC load in this example. In practice, for simplicity, a 200 kg drum could be added.
  • the quantity of water added for the full load of PVC and emulsion is about 230 gallons, i.e. 1046 liters. This is a ratio in the range of about 200 to 250 liters per tone of PVC, and in this case is about 230 liters per ton.
  • the major part of the water is added at a relatively low pressure whilst the smaller part is added at a high pressure.
  • the ratio is 20:3, i.e. 200 gallons of low pressure to 30 gallons of high pressure for the full load. Ratios in the range of 5:1 to 10:1 might be acceptable.
  • the high pressure water can be distributed over the load by an operative, to ensure proper mixing and even bitumenizing without agglomeration, e.g. by moving a hose around.
  • a riding surface comprises a drainage membrane, a 100 mm layer of clean limestone, a 40 mm layer of open textured macadam, an optional layer of sharp washed sand, and a 95 mm top layer of the bitumenized material.
  • a surface has particularly good properties and can be used as a riding surface for indoor and all-weather riding arenas as well as for e.g. training gallops.
  • the material may have uses in other contexts.
  • starting material this tends to include certain impurities in addition to PVC, and particularly rubber, and cotton or other dust.
  • the material is therefore firstly screened to extract any large foreign bodies, and then cleaned. This can comprise washing over a separating table (where vestiges of copper can be removed) and/or passing over extractor fans to remove dust. Rubber granules will tend to remain in the material but will not significantly alter its properties if in small quantities. It has been found that rubber tends to deteriorate, whilst PVC has an extremely long life.
  • composition and grade (i.e. granule size) of the starting material tends to vary in view of the nature of its source. Specific grades could be selected for particular purposes, or mixtures used.
  • the nature of the starting material may depend on the type of process used for extraction of copper. Thus, in a wet process there is likely to be a mixture of grades produced. On the other hand, a dry process may provide separated grades which can then be blended in required proportions to produce preferred mixtures.
  • the plastic may be other than PV--for example being polyethylene where telephone cables are used as the starting material--or may be a mixture.
  • the sand In use as a riding surface where installation involves an underlying layer of sand, the sand will mix with the bitumenized material after a while. It may be possible to add the sand during the manufacturing process instead or additionally, although this will increase costs of e.g. transport; sand is usually available locally.
  • bitumen As regards the bitumen, it will be appreciated that the invention extends to substitute materials which will have similar properties.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Working-Up Tar And Pitch (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
US07/002,697 1985-04-23 1986-04-23 Process for the manufacture of particulate bituminized plastics material Expired - Fee Related US4797434A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8510317 1985-04-23
GB858510317A GB8510317D0 (en) 1985-04-23 1985-04-23 Manufacture of particulate material

Publications (1)

Publication Number Publication Date
US4797434A true US4797434A (en) 1989-01-10

Family

ID=10578062

Family Applications (1)

Application Number Title Priority Date Filing Date
US07/002,697 Expired - Fee Related US4797434A (en) 1985-04-23 1986-04-23 Process for the manufacture of particulate bituminized plastics material

Country Status (6)

Country Link
US (1) US4797434A (de)
EP (1) EP0218670B1 (de)
AU (1) AU585018B2 (de)
DE (1) DE3672440D1 (de)
GB (1) GB8510317D0 (de)
WO (1) WO1986006391A1 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5252641A (en) * 1990-02-21 1993-10-12 Institut Francais Du Petrole Process for production of bituminous compositions containing polymeric residues
US5308898A (en) * 1990-02-21 1994-05-03 Institut Francais Du Petrole Bituminous compositions including residues of thermoplastic polymers with polyurethane foams and thermoset resin, etc.
US5702199A (en) * 1995-11-09 1997-12-30 Plasphalt Project Ltd. Co. Plastic asphalt paving material and method of making same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU625755B2 (en) * 1988-02-09 1992-07-16 Ayton Asphalte Limited Exercise areas
EP0403498A1 (de) * 1988-02-09 1990-12-27 Noonaweena Limited Gelände für übungen
GB2215731B (en) * 1988-02-09 1992-04-08 Collins Martin Enterprises Exercise areas
GB2584486A (en) * 2019-06-07 2020-12-09 Equestrian Direct Ltd An artificial surface and a method for making an artificial surface

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1215899B (de) * 1962-01-18 1966-05-05 Mannesmann Ag Verfahren zum Vermischen von Polyvinylchlorid-Pulver mit elastifizierenden Kunstharzen
DE2146915A1 (en) * 1970-09-21 1972-03-23 Haberl, Paul, Klein Wolkersdorf (Osterreich) Bitumen-polyethylene mixture - for use as road surfacing material
GB1427307A (en) * 1973-05-11 1976-03-10 Siplast Soc Nouvelle Thermoplastic compositions comprising essentially bitumen and and elastomer and method for its production
DE2549794A1 (de) * 1974-11-08 1976-05-13 Screg Routes & Travaux Decken- und belagmasse fuer strassen u.dgl. sowie verfahren zu ihrer herstellung
US4172821A (en) * 1977-04-19 1979-10-30 Imperial Chemical Industries Limited Bitumen emulsions
US4177079A (en) * 1978-04-20 1979-12-04 Mobil Oil Corporation Asphaltic paving compositions and method of preparation from solid organic wastes
US4410646A (en) * 1978-09-11 1983-10-18 Bergwerksverband Gmbh Form masses from thermoplastic synthetic materials and residues of coal hydrogenation
US4544690A (en) * 1983-07-27 1985-10-01 Reichhold Chemicals, Incorporated Aqueous rubberized coal tar emulsion
US4576648A (en) * 1981-11-27 1986-03-18 Elf France Cationic emulsions of bituminous binders of the bitumen type and their process of preparation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8317540D0 (en) * 1983-06-28 1983-08-03 Exxon Research Engineering Co Bituminous compositions

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1215899B (de) * 1962-01-18 1966-05-05 Mannesmann Ag Verfahren zum Vermischen von Polyvinylchlorid-Pulver mit elastifizierenden Kunstharzen
DE2146915A1 (en) * 1970-09-21 1972-03-23 Haberl, Paul, Klein Wolkersdorf (Osterreich) Bitumen-polyethylene mixture - for use as road surfacing material
GB1427307A (en) * 1973-05-11 1976-03-10 Siplast Soc Nouvelle Thermoplastic compositions comprising essentially bitumen and and elastomer and method for its production
DE2549794A1 (de) * 1974-11-08 1976-05-13 Screg Routes & Travaux Decken- und belagmasse fuer strassen u.dgl. sowie verfahren zu ihrer herstellung
US4172821A (en) * 1977-04-19 1979-10-30 Imperial Chemical Industries Limited Bitumen emulsions
US4177079A (en) * 1978-04-20 1979-12-04 Mobil Oil Corporation Asphaltic paving compositions and method of preparation from solid organic wastes
US4410646A (en) * 1978-09-11 1983-10-18 Bergwerksverband Gmbh Form masses from thermoplastic synthetic materials and residues of coal hydrogenation
US4576648A (en) * 1981-11-27 1986-03-18 Elf France Cationic emulsions of bituminous binders of the bitumen type and their process of preparation
US4544690A (en) * 1983-07-27 1985-10-01 Reichhold Chemicals, Incorporated Aqueous rubberized coal tar emulsion

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5252641A (en) * 1990-02-21 1993-10-12 Institut Francais Du Petrole Process for production of bituminous compositions containing polymeric residues
US5308898A (en) * 1990-02-21 1994-05-03 Institut Francais Du Petrole Bituminous compositions including residues of thermoplastic polymers with polyurethane foams and thermoset resin, etc.
US5702199A (en) * 1995-11-09 1997-12-30 Plasphalt Project Ltd. Co. Plastic asphalt paving material and method of making same
US6000877A (en) * 1995-11-09 1999-12-14 Plasphalt Project Ltd. Co. Plastic asphalt paving material and method of making same

Also Published As

Publication number Publication date
AU585018B2 (en) 1989-06-08
DE3672440D1 (de) 1990-08-09
WO1986006391A1 (en) 1986-11-06
AU5776486A (en) 1986-11-18
GB8510317D0 (en) 1985-05-30
EP0218670B1 (de) 1990-07-04
EP0218670A1 (de) 1987-04-22

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Legal Events

Date Code Title Description
AS Assignment

Owner name: DENEHUNT LIMITED, A BRITISH COMPANY, UNITED KINGDO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:LOVATT-SMITH, FREDERICK D.;REEL/FRAME:005032/0005

Effective date: 19881125

LAPS Lapse for failure to pay maintenance fees
FP Lapsed due to failure to pay maintenance fee

Effective date: 19930110

STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362