US3874913A - Method for making a nonwoven fabric - Google Patents
Method for making a nonwoven fabric Download PDFInfo
- Publication number
- US3874913A US3874913A US359399A US35939973A US3874913A US 3874913 A US3874913 A US 3874913A US 359399 A US359399 A US 359399A US 35939973 A US35939973 A US 35939973A US 3874913 A US3874913 A US 3874913A
- Authority
- US
- United States
- Prior art keywords
- bonded web
- fibers
- nonwoven fabric
- zinc stearate
- web
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000002245 particle Substances 0.000 claims abstract description 39
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 39
- 239000000835 fiber Substances 0.000 claims abstract description 34
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 19
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 6
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 19
- 239000011230 binding agent Substances 0.000 claims description 13
- 239000000725 suspension Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 6
- 229920000297 Rayon Polymers 0.000 claims description 5
- 238000010022 rotary screen printing Methods 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000002964 rayon Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 description 18
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 230000033458 reproduction Effects 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical compound ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/005—Materials for treating the recording members, e.g. for cleaning, reactivating, polishing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
- Y10T442/2869—Coated or impregnated regenerated cellulose fiber fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/69—Autogenously bonded nonwoven fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/699—Including particulate material other than strand or fiber material
Definitions
- a method for making such a xero- 1 17H40 A graphic wipe comprising the steps of treating the non- [5 Int. Cl. woven fabric an aqueous uspension of inc tea- 1 Field of Search 117/76 FB, 90, 140 A, 140 R, rate particles and drying the thus treated web at a 1 17/161 F, 167 temperature below the melting point of the zinc stearate particles.
- a wipe hereinafter referred to as a xerographic wipe
- the wipe usually takes the form of a roll of rearranged (or *bundled) nonwoven fabric from which lengths of fabric are advanced as required to wipe against the photo-conductive surface and thereby clean it.
- a xerographic copying machine incorporating a wipe of this kind is described in U.S. Specification No. 3,186,838.
- the present invention provides a nonwoven fabric, preferably a plain unrearranged nonwoven fabric, comprising a bonded web of fibers, which fabric or fibers has/have been treated with an aqueous suspension of zinc stearate particles to provide a nonwoven fabric having zinc stearate particles attached to the surfaces thereof.
- Such a nonwoven fabric when made into a xerographic wipe, improves the quality of the reproductions obtained from the xerographic copying machine.
- the clarity of the individual characters is sharper and the background is whiter than with a conventional wipe as referred to above.
- the aqueous suspension contains a watersoluble viscosity modifier (which increases viscosity), even more preferably a film-forming viscosity modifier which has bonding properties, such as a modified cellulose thickener or a polyacrylate thickener.
- a watersoluble viscosity modifier which increases viscosity
- a film-forming viscosity modifier which has bonding properties, such as a modified cellulose thickener or a polyacrylate thickener.
- the fibers have already been formed into a nonwoven fabric when they are treated with the aqueous suspension of zinc stearate particles, although they may possibly be in the form of a suspension thereof in water as is used to form wet-laid nonwoven fabrics.
- the present invention further provides a xerographic wipe comprising a roll of the nonwoven fabric described above.
- the present invention even further provides a method of making the nonwoven fabric described above, comprising the steps of treating the fabric, or the fibers, with an aqueous suspension of zinc stearate particles, and drying the nonwoven fabric at a temperature below the melting point of the zinc stearate particles.
- One preferred embodiment of the method comprises the step of treating a web of nonwoven fabric, preferably a plain unrearranged nonwoven fabric, with the aqueous suspension of zinc stearate particles referred to above, as by dipping the nonwoven fabric in the suspension.
- zinc stearate particles may be added to an aqueous suspension of the fibers, preferably a thixotropic aqeuous suspension prepared, e.g., as described in U.K. Specification No. 1,129,757, and the fibers are wet-laid to produce the nonwoven fabric.
- the fabric is subsequently dried, at a temperature below the melting point of the zinc stearate particles.
- the present invention still further provides an aqueous suspension of zinc stearate particles containing a water-soluble viscosity modifier, preferably a filmforming viscosity modifier, as described above.
- a water-soluble viscosity modifier preferably a filmforming viscosity modifier, as described above.
- Such a suspension once rendered homogeneous, retains its homogeneity for an extended period of time since the viscosity modifier reduces the tendency of the zinc stearate particles to sediment out.
- a more uniform suspension is applied to the nonwoven fabric during sustained processing than would be applied in the absence of the viscosity modifier.
- the viscosity modifier assists in bonding the zinc stearate particles to the fabric, especially when the viscosity modifier is one capable of forming a coherent film.
- the binder used in the nonwoven fabric should be such that it is not unduly water-sensitive and does not give rise to harshness and rigidity in the fabric so that damage to the photo-conductive surface does not occur.
- Suitable binders include crosslinked acrylates, crosslinked vinyl acetate/acrylic ester copolymers, plasticised crosslinked polyvinyl acetate, crosslinked styrene-butadiene copolymers, and other homopolymers or copolymers containing any of, acrylates, vinyl acetate, ethylene, vinyl chloride, and vinylidene dichloride, etc. These binders each have substantial wet strength.
- the amount of binder is generally from 1.5 to 25 percent by weight of the fabric, and preferably from 2 to 10 percent by weight of the fabric.
- the binder is preferably distributed uniformly throughout the fabric, e.g., continuously or in spaced areas.
- the binder may be applied to the unbonded web by, for example, a rotogravure print roller. Reference is also made to FIG. 5 of Specification No. 742,089 for suitable apparatus for carrying out the bonding step.
- the web is then dried, treated with an aqueous suspension of zinc stearate particles (if the web has not already been wet-laid from an aqueous suspension containing the fibers and the zinc stearate particles), wound up into a jumbo roll, slit into webs of a size suitable for use as xerographic wipes, and re-rolled.
- the unbonded web of fibers constituting the precursor web of the bonded nonwoven fabric may be wetlaid, but preferably it is dry-laid.
- the web is a carded web, although it may, for example, be air-laid using, eg a Rando-Webber random air-laying machine (produced by the Curlator Corporation).
- Natural and/or man-made fibers may be employed in the web which may comprise one or more plies.
- the web comprises cellulosic fibers, most preferably viscose rayon fibers and/or cotton fibers.
- a suitable manmade fiber in addition to viscose rayon is polyvinyl alcohol fiber, e.g., Kuralon" from the Marubeni Corporation, Japan. Fibers having a length of 20 to 50 mm. and a denier of 1.5 to 3.0 are preferably used.
- EXAMPLE A plain tenuous three-ply fibrous web comprising 13 g/m of 37 mm staple length, 1.5 denier viscose rayon fibers was produced from carding engines, and was then printed upon by means of a rotogravure roller with a self crosslinking plasticised vinyl acetate/butyl acrylate copolymer binder, the amount of binder (dry weight) being 3.1 g/m of the dry nonwoven fabric.
- the rotogravure roller employed was engraved with a pattern of wavy or saw-tooth" lines, there being four lines per inch disposed circumferentially on the roller.
- the wet printbonded web was dried over steam-heated cans, although ovens may alternatively be employed.
- the web was then passed through a homogeneous aqueous suspension containing 15 percent by weight of zinc stearate particles and 0.25 percent by weight of a modified cellulose viscosity modifier.
- the fabric was then mangled to remove excess liquor, the pressure of the mangle being adjusted to leave 3.1 g/m of zinc stearate on the fabric, and dried over smooth releasecoated steam-heated drying cans, the temperature of which was below the melting point of the zinc stearate particles to avoid fusion of the particles.
- Commercial grades of zinc stearate melt at about 1 16 to 120C (the true melting point is 124C) and we prefer to dry the fabric at about l 10C.
- the web was rolled up for slitting into individual webs of a size suitable for use as xerographic wipes. The wipe was found to be more effective than conventional xerographic wipes as evidenced by the improvement in the quality of photocopies obtained using it over a sustained period.
- the nonwoven fabric had particles of zinc stearate firmly attached to both surfaces thereof. Whilst we do not wish to be bound by theory we believe that the Zinc stearate particles are bonded'in more than one way to the nonwoven fabric, namely by physical entrapment of the particles, by actual bonding of the particles by the viscosity modifier, and by sinteringof the particles to the nonwoven fabric.
- the Zinc stearate particles are more firmly attached to the nonwoven fabric when the aqueous suspension contains a viscosity modifier.
- the zinc stearate particles thus do not dust off so copiously so that there is reduced health hazard from dust and substantially all of the zinc stearate particles are retained by the nonwoven fabric for effective use.
- the zinc stearate particles may be applied to the nonwoven fabric using a rotary screen printing unit.
- a paste of zinc stearate, viscosity modifier and water is made up and deposited by the rotary screen printing unit on at least one surface of the fabric, e.g., in a pat tern of multitudinous dots, to give overall coverage of the fabric.
- the fabric is then dried below the melting point of zinc stearate as before.
- a method for making a nonwoven fabric comprising:
- aqueous suspension contains a water soluble viscosity modifier- 3.
- said viscosity modifier is film forming.
- said viscosity modifier is a modified cellulosic thickener.
- a method according to claim 1 wherein the fibers comprising said bonded web have a length of from about 20 mm. to about 50 mm. and a denier of from about 1 /2 to about 3.0.
- binder for said bonded web is uniformly distributed throughout said bonded web.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Decoration Of Textiles (AREA)
- Photoreceptors In Electrophotography (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Nonwoven Fabrics (AREA)
Abstract
A xerographic wipe comprising a bonded web of fibers which has been treated with an aqueous suspension of zinc stearate particles to provide a nonwoven fabric having zinc stearate particles attached to at least one surface thereof. A method for making such a xerographic wipe comprising the steps of treating the nonwoven fabric with an aqueous suspension of zinc stearate particles and drying the thus treated web at a temperature below the melting point of the zinc stearate particles.
Description
United States Patent Lofts et a1. Apr. 1, 1975 [5 METHOD FOR MAKING A NONWOVEN 3,185,582 5/1965 Alegre 117/140 X FABRIC 3,186,838 6/1965 Graff 6t :11. 3,706 595 12/19'72 Drelich et [76] Inventors: Peter Frederick Lofts, 30 Winston 3,752,733 8/1973 Graham et al Ave, Cross Hills, near Keighley, 3,788,878 1/1974 Wheelock 117/140 X Yorkshire; John Elves, 45 Priory Gardens, Usk, Monmouthshire; P t B 7. S d i h Cl Primary E.raminer-Mayer Weinblatt Cl t B df d Y k hi Assistant Examiner-Edith L. Rollins BD146EB, all of England [22] Filed: May 11, 1973 21 Appl. No.: 359,399 1 ABSTRACT A xero raphic wi e com risin a bonded web of fibers [30] Forelgn Apphcauon Pnomy Data which l ias been tr eated \Bith ar i aqueous suspension of May 12. 1972 Great Britain inc stearate particles to provide a nonwoven fabric having zinc stearate particles attached to at least one 1 177/140 117/76 117/90, surface thereof. A method for making such a xero- 1 17H40 A graphic wipe comprising the steps of treating the non- [5 Int. Cl. woven fabric an aqueous uspension of inc tea- 1 Field of Search 117/76 FB, 90, 140 A, 140 R, rate particles and drying the thus treated web at a 1 17/161 F, 167 temperature below the melting point of the zinc stearate particles. [56] References Cited UNITED STATES PATENTS 17 Chims, N0 Drawings 3 l20.449 2/1964 Griswold 117/140 X METHOD FOR MAKING A NONWOVEN FABRIC This invention relates to a nonwoven fabric for use as a wipe in xerographic copying machines.
The quality of the reproductions obtained from a xerographic copying machine is determined, to a significant extent, by the cleanliness of the photoconductive surface used therein. Accordingly a wipe, hereinafter referred to as a xerographic wipe," is incorporated in the machine to clean unused electroscopic powder from the photo-conductive surface after a copy has been taken from an exposure. The wipe usually takes the form of a roll of rearranged (or *bundled) nonwoven fabric from which lengths of fabric are advanced as required to wipe against the photo-conductive surface and thereby clean it. A xerographic copying machine incorporating a wipe of this kind is described in U.S. Specification No. 3,186,838.
It is a main object of the present invention to provide a nonwoven fabric having improved wiping properties.
The present invention provides a nonwoven fabric, preferably a plain unrearranged nonwoven fabric, comprising a bonded web of fibers, which fabric or fibers has/have been treated with an aqueous suspension of zinc stearate particles to provide a nonwoven fabric having zinc stearate particles attached to the surfaces thereof.
Such a nonwoven fabric, when made into a xerographic wipe, improves the quality of the reproductions obtained from the xerographic copying machine. The clarity of the individual characters is sharper and the background is whiter than with a conventional wipe as referred to above.
Preferably the aqueous suspension contains a watersoluble viscosity modifier (which increases viscosity), even more preferably a film-forming viscosity modifier which has bonding properties, such as a modified cellulose thickener or a polyacrylate thickener.
Preferably, the fibers have already been formed into a nonwoven fabric when they are treated with the aqueous suspension of zinc stearate particles, although they may possibly be in the form of a suspension thereof in water as is used to form wet-laid nonwoven fabrics.
The present invention further provides a xerographic wipe comprising a roll of the nonwoven fabric described above. I
The present invention even further provides a method of making the nonwoven fabric described above, comprising the steps of treating the fabric, or the fibers, with an aqueous suspension of zinc stearate particles, and drying the nonwoven fabric at a temperature below the melting point of the zinc stearate particles. One preferred embodiment of the method comprises the step of treating a web of nonwoven fabric, preferably a plain unrearranged nonwoven fabric, with the aqueous suspension of zinc stearate particles referred to above, as by dipping the nonwoven fabric in the suspension. In another embodiment of the method, zinc stearate particles may be added to an aqueous suspension of the fibers, preferably a thixotropic aqeuous suspension prepared, e.g., as described in U.K. Specification No. 1,129,757, and the fibers are wet-laid to produce the nonwoven fabric. In both embodiments, the fabric is subsequently dried, at a temperature below the melting point of the zinc stearate particles.
The present invention still further provides an aqueous suspension of zinc stearate particles containing a water-soluble viscosity modifier, preferably a filmforming viscosity modifier, as described above. Such a suspension, once rendered homogeneous, retains its homogeneity for an extended period of time since the viscosity modifier reduces the tendency of the zinc stearate particles to sediment out. Thus a more uniform suspension is applied to the nonwoven fabric during sustained processing than would be applied in the absence of the viscosity modifier. Furthermore the viscosity modifier assists in bonding the zinc stearate particles to the fabric, especially when the viscosity modifier is one capable of forming a coherent film.
The binder used in the nonwoven fabric should be such that it is not unduly water-sensitive and does not give rise to harshness and rigidity in the fabric so that damage to the photo-conductive surface does not occur. Suitable binders include crosslinked acrylates, crosslinked vinyl acetate/acrylic ester copolymers, plasticised crosslinked polyvinyl acetate, crosslinked styrene-butadiene copolymers, and other homopolymers or copolymers containing any of, acrylates, vinyl acetate, ethylene, vinyl chloride, and vinylidene dichloride, etc. These binders each have substantial wet strength.
The amount of binder is generally from 1.5 to 25 percent by weight of the fabric, and preferably from 2 to 10 percent by weight of the fabric. The binder is preferably distributed uniformly throughout the fabric, e.g., continuously or in spaced areas. The binder may be applied to the unbonded web by, for example, a rotogravure print roller. Reference is also made to FIG. 5 of Specification No. 742,089 for suitable apparatus for carrying out the bonding step. The web is then dried, treated with an aqueous suspension of zinc stearate particles (if the web has not already been wet-laid from an aqueous suspension containing the fibers and the zinc stearate particles), wound up into a jumbo roll, slit into webs of a size suitable for use as xerographic wipes, and re-rolled.
The unbonded web of fibers constituting the precursor web of the bonded nonwoven fabric may be wetlaid, but preferably it is dry-laid. Preferably the web. is a carded web, although it may, for example, be air-laid using, eg a Rando-Webber random air-laying machine (produced by the Curlator Corporation). Natural and/or man-made fibers may be employed in the web which may comprise one or more plies. Preferably the web comprises cellulosic fibers, most preferably viscose rayon fibers and/or cotton fibers. A suitable manmade fiber in addition to viscose rayon is polyvinyl alcohol fiber, e.g., Kuralon" from the Marubeni Corporation, Japan. Fibers having a length of 20 to 50 mm. and a denier of 1.5 to 3.0 are preferably used.
The range of strengths, weights per unit area, drape, handle, wettability and permeability of the nonwoven fabrics for use as xerographic wipes will be familiar to those skilled in the art. Preferred nonwoven fabrics of the present invention have a weight in the range 15 to 20 g/m A preferred embodiment of a nonwoven fabric in accordance with the present invention will now be described by way of example.
EXAMPLE A plain tenuous three-ply fibrous web comprising 13 g/m of 37 mm staple length, 1.5 denier viscose rayon fibers was produced from carding engines, and was then printed upon by means of a rotogravure roller with a self crosslinking plasticised vinyl acetate/butyl acrylate copolymer binder, the amount of binder (dry weight) being 3.1 g/m of the dry nonwoven fabric. The rotogravure roller employed was engraved with a pattern of wavy or saw-tooth" lines, there being four lines per inch disposed circumferentially on the roller. The wet printbonded web was dried over steam-heated cans, although ovens may alternatively be employed.
The web was then passed through a homogeneous aqueous suspension containing 15 percent by weight of zinc stearate particles and 0.25 percent by weight of a modified cellulose viscosity modifier. The fabric was then mangled to remove excess liquor, the pressure of the mangle being adjusted to leave 3.1 g/m of zinc stearate on the fabric, and dried over smooth releasecoated steam-heated drying cans, the temperature of which was below the melting point of the zinc stearate particles to avoid fusion of the particles. Commercial grades of zinc stearate melt at about 1 16 to 120C (the true melting point is 124C) and we prefer to dry the fabric at about l 10C. The particles soften at this temperature which may assist in bonding them to the fabric, as the fibers are partially impressed into the stearate particles as the fabric is dried over the cans. The web was rolled up for slitting into individual webs of a size suitable for use as xerographic wipes. The wipe was found to be more effective than conventional xerographic wipes as evidenced by the improvement in the quality of photocopies obtained using it over a sustained period.
The nonwoven fabric had particles of zinc stearate firmly attached to both surfaces thereof. Whilst we do not wish to be bound by theory we believe that the Zinc stearate particles are bonded'in more than one way to the nonwoven fabric, namely by physical entrapment of the particles, by actual bonding of the particles by the viscosity modifier, and by sinteringof the particles to the nonwoven fabric.
We have found that the Zinc stearate particles are more firmly attached to the nonwoven fabric when the aqueous suspension contains a viscosity modifier. The zinc stearate particles thus do not dust off so copiously so that there is reduced health hazard from dust and substantially all of the zinc stearate particles are retained by the nonwoven fabric for effective use.
The zinc stearate particles may be applied to the nonwoven fabric using a rotary screen printing unit. A paste of zinc stearate, viscosity modifier and water is made up and deposited by the rotary screen printing unit on at least one surface of the fabric, e.g., in a pat tern of multitudinous dots, to give overall coverage of the fabric. The fabric is then dried below the melting point of zinc stearate as before.
What is claimed is:
1. A method for making a nonwoven fabric comprising:
a. providing a bonded web of fibers, said bonded web of fibers having substantial wet strength;
b. dispersing zinc stearate particles in water to form an aqueous zinc stearate suspension;
c. treating said bonded web by applying said aqueous suspension thereto; and
d. drying the treated bonded Web at a temperature below the melting point of the zinc stearate whereby there is formed a nonwoven fabric having zinc stearate particles attached to a surface.
thereof. 2. The method of claim 1 wherein said aqueous suspension contains a water soluble viscosity modifier- 3. The method of claim 2 wherein said viscosity modifier is film forming.
4. The method according to claim 3 wherein said viscosity modifier is a modified cellulosic thickener.
5. The method according to claim 3 wherein said viscosity modifier is a polyacrylate thickener.
6. The method according to claim 1 wherein the fibers comprising said bonded web are unrearranged.
7. The method according to claim 1 wherein the treated bonded web is dried at a temperature of about 1 l6-l20C.
8. The method according to claim 1 wherein the treated bonded web is dried at a temperature of about 1 10C.
9. A method according to claim 1 wherein the fibers comprising said bonded web have a length of from about 20 mm. to about 50 mm. and a denier of from about 1 /2 to about 3.0.
10. The method according to claim 9 wherein the fibers comprising said bonded web are rayon fibers.
11. The method according to claim 9 wherein the fibers comprising said bonded web are polyvinyl alcohol percent to about 10 percent by weight of said bonded web.
15. The method according to claim 1 wherein the I,
binder for said bonded web is uniformly distributed throughout said bonded web. i
16. The method according to claim 1 wherein said suspension is applied to said nonwoven fabric using a rotary screen printing unit.
17. The method according to claim 1 wherein said suspension is applied to said nonwoven fabric by passing said nonwoven fabric through said aqueous'suspen 14. The method according to claim 1 wherein the. binder for said bonded web comprises from about 2
Claims (17)
1. A METHOD FOR MAKING A NONWOVEN FABRIC COMPRISING: A. PROVIDING A BONDED WEB OF FIBERS, SAID BONDED WEB OF FIBERS HAVING SUBSTANTIAL WET STRENGTH; B. DISPERSING ZINC STEARATE PARTICLES IN WATER TO FORM AN AQUEOUS ZINC STEARATE SUSPENSION; C. TREATING SAID BONDED WEB BY APPLYING SAID AQUEOUS SUSPENSION THERETO; AND D. DRYING THE TREATED BONDED WEB AT A TEMPERATURE BELOW THE MELTING POINT OF THE ZINC STEARATE WHEREBY THERE IS FORMED A NONWOVEN FABRIC HAVING ZINC STEARATE PARTICLES ATTACHED TO A SURFACE THEREOF.
2. The method of claim 1 wherein said aqueous suspension contains a water soluble viscosity modifier.
3. The method of claim 2 wherein said viscosity modifier is film forming.
4. The method according to claim 3 wherein said viscosity modifier is a modified cellulosic thickener.
5. The method according to claim 3 wherein said viscosity modifier is a polyacrylate thickener.
6. The method according to claim 1 wherein the fibers Comprising said bonded web are unrearranged.
7. The method according to claim 1 wherein the treated bonded web is dried at a temperature of about 116*-120*C.
8. The method according to claim 1 wherein the treated bonded web is dried at a temperature of about 110*C.
9. A method according to claim 1 wherein the fibers comprising said bonded web have a length of from about 20 mm. to about 50 mm. and a denier of from about 1 1/2 to about 3.0.
10. The method according to claim 9 wherein the fibers comprising said bonded web are rayon fibers.
11. The method according to claim 9 wherein the fibers comprising said bonded web are polyvinyl alcohol fibers.
12. The method according to claim 9 wherein the fibers comprising said bonded web are cotton fibers.
13. The method according to claim 1 wherein the binder for said bonded web comprises from about 1.5 percent to about 25 percent by weight of said bonded web.
14. The method according to claim 1 wherein the binder for said bonded web comprises from about 2 percent to about 10 percent by weight of said bonded web.
15. The method according to claim 1 wherein the binder for said bonded web is uniformly distributed throughout said bonded web.
16. The method according to claim 1 wherein said suspension is applied to said nonwoven fabric using a rotary screen printing unit.
17. The method according to claim 1 wherein said suspension is applied to said nonwoven fabric by passing said nonwoven fabric through said aqueous suspension.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2237272A GB1430065A (en) | 1972-05-12 | 1972-05-12 | Nonwoven fabric |
Publications (1)
Publication Number | Publication Date |
---|---|
US3874913A true US3874913A (en) | 1975-04-01 |
Family
ID=10178311
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US359399A Expired - Lifetime US3874913A (en) | 1972-05-12 | 1973-05-11 | Method for making a nonwoven fabric |
Country Status (7)
Country | Link |
---|---|
US (1) | US3874913A (en) |
JP (1) | JPS4955162A (en) |
BR (1) | BR7303448D0 (en) |
CA (1) | CA1001502A (en) |
GB (1) | GB1430065A (en) |
NL (1) | NL7306415A (en) |
ZA (1) | ZA733203B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040176264A1 (en) * | 2002-12-30 | 2004-09-09 | The Procter & Gamble Company | Rinse aid composition containing water-soluble metal salt for use in automatic dishwashing for glassware corrosion protection |
US20040176269A1 (en) * | 2002-12-30 | 2004-09-09 | The Procter & Gamble Company | Process of preparing in-situ water-soluble zinc salt for use in automatic dishwashing compositions |
US20040180807A1 (en) * | 2002-12-30 | 2004-09-16 | The Procter & Gamble Company | Rinse aid composition containing water-soluble metal salt for use in automatic dishwashing for metal corrosion and rust formation protection |
US20050039781A1 (en) * | 2002-11-01 | 2005-02-24 | The Procter & Gamble Company | Dispensing device for liquid detergent compositions |
US20090233218A1 (en) * | 2008-03-17 | 2009-09-17 | Satoshi Ogawa | Method for preparing toner |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3011591A1 (en) * | 1980-03-26 | 1981-10-01 | Ibm Deutschland Gmbh, 7000 Stuttgart | METHOD FOR REDUCING GRINDING OR SCRATCH TRACKS ON THE SURFACE OF A RECORDING CARRIER |
JPH01178223A (en) * | 1988-01-08 | 1989-07-14 | Kanai Hiroyuki | Floor pad with dry finishing coat |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3120449A (en) * | 1961-04-05 | 1964-02-04 | Johnson & Johnson | Fibrous materials and methods of making the same |
US3185582A (en) * | 1953-12-17 | 1965-05-25 | Alegre Antonio Albareda | Process for making and finishing artificial hides or leathers |
US3186838A (en) * | 1960-12-27 | 1965-06-01 | Xerox Corp | Xerographic plate cleaning method utilizing the relative movement of a cleaning web |
US3706595A (en) * | 1971-01-22 | 1972-12-19 | Johnson & Johnson | Method of applying a resin binder to a substrate |
US3752733A (en) * | 1969-10-29 | 1973-08-14 | Monsanto Co | Bonded nonwoven fibrous product |
US3788878A (en) * | 1972-07-14 | 1974-01-29 | Goodrich Co B F | Impregnating nonwovens with an alkyl acrylate polymer-carboxylic polymer latex |
-
1972
- 1972-05-12 GB GB2237272A patent/GB1430065A/en not_active Expired
-
1973
- 1973-05-08 NL NL7306415A patent/NL7306415A/xx not_active Application Discontinuation
- 1973-05-11 JP JP48053027A patent/JPS4955162A/ja active Pending
- 1973-05-11 BR BR3448/73A patent/BR7303448D0/en unknown
- 1973-05-11 CA CA171,326A patent/CA1001502A/en not_active Expired
- 1973-05-11 US US359399A patent/US3874913A/en not_active Expired - Lifetime
- 1973-05-11 ZA ZA00733203A patent/ZA733203B/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3185582A (en) * | 1953-12-17 | 1965-05-25 | Alegre Antonio Albareda | Process for making and finishing artificial hides or leathers |
US3186838A (en) * | 1960-12-27 | 1965-06-01 | Xerox Corp | Xerographic plate cleaning method utilizing the relative movement of a cleaning web |
US3120449A (en) * | 1961-04-05 | 1964-02-04 | Johnson & Johnson | Fibrous materials and methods of making the same |
US3752733A (en) * | 1969-10-29 | 1973-08-14 | Monsanto Co | Bonded nonwoven fibrous product |
US3706595A (en) * | 1971-01-22 | 1972-12-19 | Johnson & Johnson | Method of applying a resin binder to a substrate |
US3788878A (en) * | 1972-07-14 | 1974-01-29 | Goodrich Co B F | Impregnating nonwovens with an alkyl acrylate polymer-carboxylic polymer latex |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050039781A1 (en) * | 2002-11-01 | 2005-02-24 | The Procter & Gamble Company | Dispensing device for liquid detergent compositions |
US20040176264A1 (en) * | 2002-12-30 | 2004-09-09 | The Procter & Gamble Company | Rinse aid composition containing water-soluble metal salt for use in automatic dishwashing for glassware corrosion protection |
US20040176269A1 (en) * | 2002-12-30 | 2004-09-09 | The Procter & Gamble Company | Process of preparing in-situ water-soluble zinc salt for use in automatic dishwashing compositions |
US20040180807A1 (en) * | 2002-12-30 | 2004-09-16 | The Procter & Gamble Company | Rinse aid composition containing water-soluble metal salt for use in automatic dishwashing for metal corrosion and rust formation protection |
US6992052B2 (en) | 2002-12-30 | 2006-01-31 | The Procter & Gamble Company | Process of preparing in-situ water-soluble zinc salt for use in automatic dishwashing compositions |
US20060100118A1 (en) * | 2002-12-30 | 2006-05-11 | Song Brian X | Process of preparing in-situ water-soluble zinc salt for use in automatic dishwashing compositions |
US20090233218A1 (en) * | 2008-03-17 | 2009-09-17 | Satoshi Ogawa | Method for preparing toner |
Also Published As
Publication number | Publication date |
---|---|
ZA733203B (en) | 1975-01-29 |
AU5554373A (en) | 1974-11-14 |
CA1001502A (en) | 1976-12-14 |
BR7303448D0 (en) | 1974-07-25 |
NL7306415A (en) | 1973-11-14 |
GB1430065A (en) | 1976-03-31 |
JPS4955162A (en) | 1974-05-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4600620A (en) | Article suitable for wiping surfaces | |
GB885006A (en) | Nonwoven fabrics and methods of manufacturing the same | |
US4451315A (en) | Process for producing a non-woven fabric | |
US6675429B2 (en) | Imaged nonwoven fabric for imparting an improved aesthetic texture to surfaces | |
US4324827A (en) | Water-proof, fuse-bonding fabric | |
US3874913A (en) | Method for making a nonwoven fabric | |
GB1294794A (en) | Fibrous sheet material and method and apparatus for forming same | |
US4128679A (en) | Soft, non-woven fabrics and process for their manufacture | |
DE3145138A1 (en) | "FIXING INSERT WITH IMPROVED BACK RETAINING SECURITY AND METHOD FOR THE PRODUCTION THEREOF" | |
US3908058A (en) | Spot-bonded nonwoven fabrics and methods of making the same | |
DE2351405C3 (en) | Process for the production of a one-sided heat-sealable fleece | |
WO1989010543A1 (en) | A flexible porous web having a permanent humidity sensor for indicating release of material therefrom | |
JP2854776B2 (en) | Printing method using transfer paper | |
GB1311256A (en) | Terpolymers of ethylene vinyl chloride and a substituted acrylamide and their use | |
US4308306A (en) | Fabric conditioning products | |
JPH0351835B2 (en) | ||
JPH05163603A (en) | Adhesive interlining | |
JP3047930B2 (en) | Non-woven polyolefin sheet for food packaging | |
JPS6245355B2 (en) | ||
CA1067765A (en) | Absorbent textile article with coating of foamed rubber in a three dimensional pattern | |
JPS6364549B2 (en) | ||
JP2808748B2 (en) | Method for producing nubuck-like artificial leather | |
US2863715A (en) | Wiping cloth and the manufacture thereof | |
JP2000034659A (en) | Trap sheet | |
KR840001483B1 (en) | Process and apparatus for the continuous simultaneous application of pastes onto opposite faces of a sheet structure |