US3313633A - High temperature flame spray powder - Google Patents

High temperature flame spray powder Download PDF

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Publication number
US3313633A
US3313633A US297198A US29719863A US3313633A US 3313633 A US3313633 A US 3313633A US 297198 A US297198 A US 297198A US 29719863 A US29719863 A US 29719863A US 3313633 A US3313633 A US 3313633A
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United States
Prior art keywords
powder
self
fluxing
mixture
flame
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Expired - Lifetime
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US297198A
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English (en)
Inventor
Longo Frank Nicholas
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Metco Inc
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Metco Inc
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Filing date
Publication date
Application filed by Metco Inc filed Critical Metco Inc
Priority to US297198A priority Critical patent/US3313633A/en
Priority to GB20409/64A priority patent/GB1042708A/en
Priority to DEM61819A priority patent/DE1300412B/de
Priority to US606480A priority patent/US3378392A/en
Application granted granted Critical
Publication of US3313633A publication Critical patent/US3313633A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0073Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only borides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/067Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/937Sprayed metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12937Co- or Ni-base component next to Fe-base component

Definitions

  • the invention more particularly relates to a flame spray powder mixture containing a self-fluxing alloy powder and a powder of a metal which melts at a high temperature, such as tungsten, rhenium, tantalum, molybdenum, columbium, or alloys thereof, and to a process for flame spraying such powder mixtures at high temperatures to produce dense, coherent coatings which show excellent wear and load-resistant characteristics.
  • a high temperature such as tungsten, rhenium, tantalum, molybdenum, columbium, or alloys thereof
  • the spray welding process involves the steps of first spraying the powder onto the surface to be coated, using the conventional flame-spray process, and thereafter fusing the coating in place.
  • the fusing may be done, for example, in a furnace, by means of induction heating or the like, but is often done by directly heating the coated surface with a heating torch.
  • the flame spraying is the sprayweld process is simply a mode of positioning the alloy powder on the surface to be coated in order to allow the fused coating to be formed by the subsequent fusing operation.
  • the coating thus sprayed prior to the fusing operation is porous, is not firmly bonded in place, and is not useful in the same manner as subsequent fused coatings, i.e. is not a hard, dense, wear-resistant surface.
  • the particles of a groundfinished, as-sprayed coating will for example pull out when pressure-sensitive tape, such as Scotch tape, is applied and then stripped off.
  • a further object of this invention is a process for producing dense, wearand load-resistant coatings, utilizing a flame spray powder mixture containing a self-fluxing alloy powder.
  • the meal powder which is admixed with the self-fluxing alloy powder preferably should have a melting point above 4000 F., as for example between 4600 and 6200 F.
  • the percents by weight of the higher melting point powder, as given herein, refer to the percents by weight based on the mixture of this powder with the self-fluxing alloy powder.
  • the high melting powder component which makes up the 5 to by weight of the mixture thereof with the self-fluxing alloy powder need not be a single metal powder but may be a mixture of one or more separate metal powders and/ or alloys as specified, as for example a mix ture of any of tungsten, rhenium, tantalum, molybdenum, columbium and/or their alloys.
  • the self-fluxing alloy powder used in accordance with the invention may be any known or conventional selffluxing alloy powder, as for example any of the powders described in United States Patent Nos. 2,875,043 and 2,936,229. These powders are often referred to as selffluxing sprayweld or spray-weldable powders but the term self-fluxing alloy powders will be generically used herein and in the claims to designate these materials.
  • the self-fluxing alloy powders are preferably of the nickel or cobalt type containing boron, and most preferably boron and silicon as the self-fluxing element.
  • the most preferable self-fiuxing alloy powders are of the nickel or nickelchromium alloy type containing boron and silicon.
  • the powder may be formed of additional alloy components, as for example up to 20% chromium, to impart corrosion and oxidation resistance, carbon in an amount of not more than a few percent, iron in an amount not exceeding about 10%, and preferably not exceeding about 5% in weight of the total alloy.
  • additional alloy components as for example up to 20% chromium, to impart corrosion and oxidation resistance, carbon in an amount of not more than a few percent, iron in an amount not exceeding about 10%, and preferably not exceeding about 5% in weight of the total alloy.
  • An example of a typical self-fluxing alloy powder of the boron-nickel type consists of 0.7l% carbon, 3.5- 45% silicon, 2.75 to 3.75% boron, 35% iron, up to 18% chromium, as for instance 16-18% chromium with nickel making up the balance.
  • An example of a typical sprayweld alloy of the cobalt base type may, for example, contain 1 /2 to 3% boron, 04.5% silicon, 03% carbon, 0'20-% chromium, 030% nickel, 020% molybdenum, 020% tungsten, and the balance cobalt.
  • the self-fluxing alloy powder should generally have a particle size below mesh US. Standard screen size.
  • the particles should be of a size between 100 mesh and +8 microns and preferably between 230' mesh and +15 microns.
  • the high melting point metal powder used in admixture with the self-fluxing alloy powder must be a metal powder having a melting point above 3500 and preferably albove 99.42% molybdenum-5% titaniurn.08% zirconium 90% tantalum-10% tungsten 85% tantalum-10% hafnium-5% tungsten 50% rhenium-50% molybdenum 80% columbiuml% molybdenum-10% titanium Any mixture of these metal powders or alloy powders may also be used.
  • the most preferable metal powders are powders of tungsten, tantalum, or molybdenum, or alloys thereof having a melting point between 4600" F. and 6200" F.
  • the high melting point metal powder must be a metal per se and cannot be in the form of a refractory oxide, carbide, or the like. Furthermore, the high melting point metal powder must be independent of the self-fluxing alloy powder and may not be alloyed therewith or the like.
  • the particle size of the high melting point metal powder should be similar to that of the self-fluxing alloy powder and should generally be between 100 mesh and +8 microns, and preferably between 270 mesh and +8 microns, the mesh sizes being US. Standard screen sizes.
  • the high melting point metal powder must be present in an amount of about to 95% by weight and preferably 15 to 30%, or alternatively 70 to 90%, by weight based on the total weight of the mixture thereof with the selffluxing alloy powder.
  • the powder mixture in accordance with the invention is preferably sprayed per se but may be sprayed in admixture or in conjunction with other spray materials, as for example, aluminum; or refractory carbides, such as carbides of tungsten, tantalum, titanium, etc., with or without a cobalt or nickel matrix; refractory oxides, such as aluminum oxide or zirconium oxide, molybdenum disilicide, etc.
  • the powder mixture in accordance with the invention may, for example, be sprayed in amounts of 595%, or preferably 90%, by weight of the other spray material, said percentage being based on the total mixture.
  • the powder mixture is preferably sprayed in a powder type flame spray gun but must be sprayed under conditions of temperature which will cause melting of the high melting point metal powder component.
  • the temperature in the heating zone should exceed 4000 F. and should preferably exceed 7000 F.
  • the spraying in accordance with the invention is preferably effected with a plasma flame spray gun, as for example of the type which produces a plasma flame by constricting an electric arc in a nozzle with a plasma-forming gas, for instance nitrogen or argon alone, or in mixture with hydrogen.
  • a plasma-forming gas for instance nitrogen or argon alone, or in mixture with hydrogen.
  • Guns which produce a plasma flame in this manner are, for example, described in US. Patent 2,960,- 594.
  • the spraying is effected in the wellknown and conventional manner for flame spraying, particularly for flame spraying with a plasma flame spray gun.
  • the coatings may be formed on conventional surfaces, as for example iron and steel alloyed surfaces for any purposes which require a wearand/ or load-resistant surface. Coatings of a depth of between .002 and 0.125"
  • the coatings in accordance with the invention may also be used for forming polished rod liners, pump plungers, medium-to-high temperature-resistant steel roller bearings, furnace rolls, engine valve trim, glass molds, engine piston tops and annealing rolls or the like.
  • the surface which is sprayed in accordance with the invention should be prepared in the well known and conventional manner for flame spraying, for example with steel grit propelled with air at a pressure of 100 lbs. per square inch, or surface rolled in any other conventional manner, as for example rough-threading, coating, or the like.
  • copper, brass, aluminum, titanium, molybdenum, or any other material whose surface is suitable for flame spraying by conventional methods may be coated with the powder and by the process in accordance with the invention.
  • the coatings produced in accordance with the invention may be substituted in their as sprayed condition for the fused coatings produced by the sprayweld process, they are not identical to these fused coatings, and in certain respects are superior thereto.
  • the structure is different, in that individual high melting point metal particles can useually be individually identified in metallographically prepared sections.
  • the coatings in accordance with the invention do not require a subsequent fusing operation and are generally utilized without fusing, the same may be fused or heat-treated in many cases, forming a desirable, high-melting alloyed coating.
  • EXAMPLE 1 Percent B 3.5 Si 4 Fe 4 Cr 17 C 1.0 Nickel Balance
  • the powder mixture is flame-sprayed on a mild steel plate which was degreased and then blasted with Gl8 steel grit, propelled with air at a pressure of 100 p.s.i.g.
  • the spraying is effected at a distance of 4-6 from the plate, using the plasma flame spray gun Type 2M, as sold by Metco, Inc., of Westbury, N.Y., operated at 500 amps, -85 volts, to produce a plasma temperature of l0,000 F.
  • the spraying is effected at a rate of 6 to 7 lbs. of powder per hour, using nitrogen at a pressure of 50 p.s.i.g. and a flow rate of CFH, and hydrogen at a pressure of 50 p.s.i.g. and a flow rate of 15 CFH.
  • the spray coating produced on the base is a dense coating which is built up to a layer thickness of 0.030".
  • the preliminary grind-finish of the sprayed coating was 7 micro inches as compared to the ordinary 30-40 micro inch finish for conventional sprayed coatings.
  • Example 1 is repeated on the bearing surfaces of a crank shaft for an internal combustion engine having an outer diameter of 2" for the main bearings and 1 /2" for the connecting rod bearings.
  • the bearing surfaces, as formed, are excellent, wear-resistant bearing surfaces, which are able to withstand the extremely high loading forces of modern engines.
  • Example 1 is repeated using, however, a self-fluxing alloy of the following composition: Fe 2.5%, Cr C .l5%, Si 2.5%, B 2.5%, Ni balance, and tungsten powder of a size between 325 mesh and +8 microns, in a mixture ratio of 75% of the self-fluxing alloy powder and 25% of the tungsten powder.
  • a self-fluxing alloy of the following composition: Fe 2.5%, Cr C .l5%, Si 2.5%, B 2.5%, Ni balance, and tungsten powder of a size between 325 mesh and +8 microns, in a mixture ratio of 75% of the self-fluxing alloy powder and 25% of the tungsten powder.
  • the coating produced had the appearance of wrought metal when ground-finished, and a surface finished of 5 micro inches was obtained.
  • any of the powders set forth in US. Patents 2,875,043 and 2,936,229 or any other conventional self-fiuxing alloy powder may be used.
  • the percentages of the higher melting point powder as set fort-h in the claims are indicated as based on the self-fiuxing alloy powder and this specifically design-ates that the percentages given are the percentages of the sum of the high melting powder and the self-fluxing alloy powder.
  • 5% by weight of the higher melting powder based on the self-fluxing alloy powder designates that of the combined weight of the higher melting powder and the self-fluxing powder 5% is attributable to the higher melting powder and to the selffluxing alloy powder.
  • 95% by weight of the higher melting powder based on the self-fiuxing alloy powder designates that of the sum of the weight of the higher melting powder and self-fluxing alloy powder 95 is attributable to the higher melting powder and 5% to the self-fiuxing alloy powder.
  • a flame spray powder comprising a mixture of a boron containing nickel or cobalt base self-fluxing alloy powder and about 595% by weight, based on the total thereof with said self-fluxing alloy powder, of a powder of at least one metal selected from the group consisting of tungsten, rhenium, tantalum, molybdenum, columbium, and alloys thereof having a melting point about 3500 P. which powder is characterized by forming in its as flamesprayed condition an adherent coating on a substrate.
  • a flame spray powder according to claim 1 in which said powder of said group member is present in amount of about l530%.
  • a flame spray powder according to claim 1 having a particle size between l00 mesh and +8 microns.
  • a flame spray powder according to claim 1 having a particle size between 230 mesh and 8 microns.
  • a flame spray powder comprising a mixture of a boron containing nickel or cobalt base self-fluxing alloy powder and about 595% by weight, based on the total thereof with said self-fluxing alloy powder, of a powder of at least one refractory metal having a melting point above 3500 P. which powder is characterized by forming in its as flame-sprayed condition an adherent coating on a substrate.
  • a mixture of a self-fluxing metal powder essentially consisting of at least one base metal selected from the group consisting of nickel and cobalt and containing boron 'as a self-fiuxing element with about 5- 95% by weight of a tungsten powder, the powder mixture having a particle size between and +8 microns which powder is characterized by forming in its as flame-sprayed condition an adherent coating on a substrate.
  • a mixture of a self-fluxing met-a1 powder essentially consisting of at least one base metal selected from the group consisting of nickel and cobalt and containing boron as a self-fluxing element with about 5'95% by weight of a tantalum powder, the powder mixture having a particle size between l00 mesh and +8 microns which powder is characterized by forming in its as flame-sprayed condition an adherent coating on a substrate.
  • a mixture of a self-fiuxing metal powder essentially consisting of at least one base metal selected from the group consisting of nickel and cobalt and containing boron as a self-fluxing element with about 595% by weight of a molybdenum powder, the powder mixture having a particle size between l0-0 and +8 microns which powder is characterized by forming in its as flamesprayed condition an adherent coating on a substrate.
  • a mixture of a self-fiuxing metal powder essentially consisting of at least one base metal selected from the group consisting of nickel and cobalt and containing boron as a self-fluxing element with about 595% by weight of a columbium powder, the powder mixture having a particle size between 1()0 mesh and +8 microns which powder is characterized by forming in its as flamesprayed condition an adherent coating on a substrate.
  • a mixture of a self-fiuxing metal powder essentially consisting of at least one base metal selected from the group consisting of nickel and cobalt and containing boron as a self-fluxing element with about 5-95% by weight of a rhenium powder, the powder mixture having a particle size between l00 mesh and +8 microns which 8 powder is characterized by forming it its as flame-sprayed condition an adherent coating on a substrate.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating By Spraying Or Casting (AREA)
US297198A 1963-07-24 1963-07-24 High temperature flame spray powder Expired - Lifetime US3313633A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US297198A US3313633A (en) 1963-07-24 1963-07-24 High temperature flame spray powder
GB20409/64A GB1042708A (en) 1963-07-24 1964-05-15 High temperature flame spray powder and process
DEM61819A DE1300412B (de) 1963-07-24 1964-07-21 Flammspritzpulver auf der Basis einer selbstfliessenden Legierung und Flammspritzverfahren
US606480A US3378392A (en) 1963-07-24 1966-10-21 High temperature flame spray powder and process

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DE (1) DE1300412B (de)
GB (1) GB1042708A (de)

Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3436512A (en) * 1966-04-13 1969-04-01 Coast Metals Inc Method of spray coating gas seals of gas turbines and the like
US3496682A (en) * 1964-05-05 1970-02-24 Eutectic Welding Alloys Composition for producing cutting and/or wearing surfaces
US3725017A (en) * 1970-01-07 1973-04-03 Ramsey Corp Coated nervous substrate
JPS4846721A (de) * 1971-10-18 1973-07-03
US3819384A (en) * 1973-01-18 1974-06-25 Metco Inc Flame spraying with powder blend of ferromolybdenum alloy and self-fluxing alloys
US3947269A (en) * 1970-01-07 1976-03-30 Trw Inc. Boron-hardened tungsten facing alloy
US3975891A (en) * 1974-02-22 1976-08-24 Roland Eric Gunther Mower blades
US4076883A (en) * 1975-07-30 1978-02-28 Metco, Inc. Flame-sprayable flexible wires
US4136230A (en) * 1976-07-29 1979-01-23 Eutectic Corporation Wear resistant alloy coating containing tungsten carbide
US4189317A (en) * 1978-06-15 1980-02-19 Eutectic Corporation Flame spray powder mix
US4190442A (en) * 1978-06-15 1980-02-26 Eutectic Corporation Flame spray powder mix
US4190443A (en) * 1978-06-15 1980-02-26 Eutectic Corporation Flame spray powder mix
US4191565A (en) * 1978-06-15 1980-03-04 Eutectic Corporation Flame spray powder mix
US4230747A (en) * 1979-08-15 1980-10-28 Eutectic Corporation Flame spray powder mix
US4230749A (en) * 1979-08-15 1980-10-28 Eutectic Corporation Flame spray powder mix
US4230748A (en) * 1979-08-15 1980-10-28 Eutectic Corporation Flame spray powder mix
US4263353A (en) * 1978-06-15 1981-04-21 Eutectic Corporation Flame spray powder mix
US4400212A (en) * 1982-01-18 1983-08-23 Marko Materials, Inc. Cobalt-chromium alloys which contain carbon and have been processed by rapid solidification process and method
EP0114232A1 (de) * 1982-12-20 1984-08-01 Goetze Ag Spritzpulver für die Herstellung verschleissfester Beschichtungen
US4473402A (en) * 1982-01-18 1984-09-25 Ranjan Ray Fine grained cobalt-chromium alloys containing carbides made by consolidation of amorphous powders
DE3718778A1 (de) * 1987-06-04 1988-12-15 Krauss Maffei Ag Legierung und deren verwendung
DE3744491C1 (en) * 1987-12-30 1989-03-02 Winkelstroeter Dentaurum Use of an iron- and nickel-free alloy
US4854980A (en) * 1987-12-17 1989-08-08 Gte Laboratories Incorporated Refractory transition metal glassy alloys containing molybdenum
US4868069A (en) * 1988-08-11 1989-09-19 The Dexter Corporation Abrasion-resistant coating
US4996114A (en) * 1988-08-11 1991-02-26 The Dexter Corporation Abrasion-resistant coating
FR2686873A1 (fr) * 1992-02-05 1993-08-06 Toyo Kohan Co Ltd Alliage dur fritte resistant a la chaleur.
US5358547A (en) * 1993-02-18 1994-10-25 Holko Kenneth H Cobalt-phosphorous-base wear resistant coating for metallic surfaces
EP0701005A1 (de) 1994-09-09 1996-03-13 Osram Sylvania Inc. Thermisches Sprühpulver
US5641580A (en) * 1995-10-03 1997-06-24 Osram Sylvania Inc. Advanced Mo-based composite powders for thermal spray applications
US5660934A (en) * 1994-12-29 1997-08-26 Spray-Tech, Inc. Clad plastic particles suitable for thermal spraying
US20040194662A1 (en) * 2003-03-31 2004-10-07 Tsuyoshi Itsukaichi Thermal spraying powder and method of forming a thermal sprayed coating using the same
WO2004097061A1 (en) 2003-04-28 2004-11-11 Coppe/Ufrg - Coordenacão Dos Programas De Pós Graduacão De Engenharia Da Universida Federal Do Rio De Janeiro Use of thermal spraying with niobium oxides and niobium alloys during the production process of rolled steel plates
US20110067796A1 (en) * 2008-05-28 2011-03-24 Deloro Stellite Holdings Corporation Slurry-based manufacture of thin wall metal components
US20120276411A1 (en) * 2009-06-30 2012-11-01 Hunprenco Precision Engineers Limited Coating Composition
US20130221261A1 (en) * 2010-11-09 2013-08-29 Nittan Valve Co., Ltd. Wear-resistant cobalt-based alloy and engine valve coated with same
US9249889B1 (en) 2012-03-09 2016-02-02 Mogas Industries, Inc. High pressure ball valve
US9500285B2 (en) 2012-03-09 2016-11-22 Mogas Industries, Inc. High pressure ball valve and packing
US10428406B2 (en) * 2016-02-12 2019-10-01 Kennametal Inc. Wear resistant and corrosion resistant cobalt-based alloy powders and applications thereof
CN113684438A (zh) * 2021-08-31 2021-11-23 安徽工业大学 一种高强度高硬度表面防护用喷涂粉末及其应用方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3690686A (en) * 1969-08-11 1972-09-12 Ramsey Corp Piston with seal having high strength molybdenum alloy facing
US3841901A (en) * 1973-07-06 1974-10-15 Metco Inc Aluminum-and molybdenum-coated nickel, copper or iron core flame spray materials
DE2841552C2 (de) * 1978-09-23 1982-12-23 Goetze Ag, 5093 Burscheid Spritzpulver für die Herstellung verschleißfester Beschichtungen auf den Laufflächen gleitender Reibung ausgesetzter Maschinenteile
DE3447784A1 (de) * 1984-12-20 1986-06-26 Gebrüder Sulzer AG, Winterthur Kolbenbrennkraftmaschine
DE102007054665B4 (de) 2007-11-14 2018-03-29 H.C. Starck Hermsdorf Gmbh Metallpulver und Verfahren zur Herstellung des Metallpulvers

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2936229A (en) * 1957-11-25 1960-05-10 Metallizing Engineering Co Inc Spray-weld alloys
US2964420A (en) * 1955-06-14 1960-12-13 Union Carbide Corp Refractory coated body

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH224135A (de) * 1941-09-23 1942-10-31 Dr Schoop M U Verfahren zur Herstellung von Metallüberzügen.
FR1172214A (fr) * 1956-04-06 1959-02-06 Metallizing Engineering Co Perfectionnements concernant les produits pour la métallisation par pulvérisation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964420A (en) * 1955-06-14 1960-12-13 Union Carbide Corp Refractory coated body
US2936229A (en) * 1957-11-25 1960-05-10 Metallizing Engineering Co Inc Spray-weld alloys

Cited By (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496682A (en) * 1964-05-05 1970-02-24 Eutectic Welding Alloys Composition for producing cutting and/or wearing surfaces
US3436512A (en) * 1966-04-13 1969-04-01 Coast Metals Inc Method of spray coating gas seals of gas turbines and the like
US3725017A (en) * 1970-01-07 1973-04-03 Ramsey Corp Coated nervous substrate
US3947269A (en) * 1970-01-07 1976-03-30 Trw Inc. Boron-hardened tungsten facing alloy
JPS4846721A (de) * 1971-10-18 1973-07-03
JPS5138006B2 (de) * 1971-10-18 1976-10-19
US3819384A (en) * 1973-01-18 1974-06-25 Metco Inc Flame spraying with powder blend of ferromolybdenum alloy and self-fluxing alloys
US3975891A (en) * 1974-02-22 1976-08-24 Roland Eric Gunther Mower blades
US4076883A (en) * 1975-07-30 1978-02-28 Metco, Inc. Flame-sprayable flexible wires
US4136230A (en) * 1976-07-29 1979-01-23 Eutectic Corporation Wear resistant alloy coating containing tungsten carbide
US4190443A (en) * 1978-06-15 1980-02-26 Eutectic Corporation Flame spray powder mix
US4190442A (en) * 1978-06-15 1980-02-26 Eutectic Corporation Flame spray powder mix
US4189317A (en) * 1978-06-15 1980-02-19 Eutectic Corporation Flame spray powder mix
US4191565A (en) * 1978-06-15 1980-03-04 Eutectic Corporation Flame spray powder mix
US4263353A (en) * 1978-06-15 1981-04-21 Eutectic Corporation Flame spray powder mix
US4230748A (en) * 1979-08-15 1980-10-28 Eutectic Corporation Flame spray powder mix
US4230749A (en) * 1979-08-15 1980-10-28 Eutectic Corporation Flame spray powder mix
US4230747A (en) * 1979-08-15 1980-10-28 Eutectic Corporation Flame spray powder mix
US4400212A (en) * 1982-01-18 1983-08-23 Marko Materials, Inc. Cobalt-chromium alloys which contain carbon and have been processed by rapid solidification process and method
US4473402A (en) * 1982-01-18 1984-09-25 Ranjan Ray Fine grained cobalt-chromium alloys containing carbides made by consolidation of amorphous powders
EP0114232A1 (de) * 1982-12-20 1984-08-01 Goetze Ag Spritzpulver für die Herstellung verschleissfester Beschichtungen
DE3718778A1 (de) * 1987-06-04 1988-12-15 Krauss Maffei Ag Legierung und deren verwendung
US4854980A (en) * 1987-12-17 1989-08-08 Gte Laboratories Incorporated Refractory transition metal glassy alloys containing molybdenum
DE3744491C1 (en) * 1987-12-30 1989-03-02 Winkelstroeter Dentaurum Use of an iron- and nickel-free alloy
US4868069A (en) * 1988-08-11 1989-09-19 The Dexter Corporation Abrasion-resistant coating
US4996114A (en) * 1988-08-11 1991-02-26 The Dexter Corporation Abrasion-resistant coating
FR2686873A1 (fr) * 1992-02-05 1993-08-06 Toyo Kohan Co Ltd Alliage dur fritte resistant a la chaleur.
US5358547A (en) * 1993-02-18 1994-10-25 Holko Kenneth H Cobalt-phosphorous-base wear resistant coating for metallic surfaces
EP0701005A1 (de) 1994-09-09 1996-03-13 Osram Sylvania Inc. Thermisches Sprühpulver
US5603076A (en) * 1994-09-09 1997-02-11 Osram Sylvania Inc. Coating containing dimolybdenum carbide precipitates and a self-fluxing NiCrFeBSi alloy
US5690716A (en) * 1994-09-09 1997-11-25 Osram Sylvania Inc. Thermal spray powder
US5660934A (en) * 1994-12-29 1997-08-26 Spray-Tech, Inc. Clad plastic particles suitable for thermal spraying
US5718970A (en) * 1994-12-29 1998-02-17 Longo; Frank N. Thermal sprayed coating containing plastic
US5885663A (en) * 1994-12-29 1999-03-23 Spray-Tech, Inc. Method for depositing a coating containing plastic on a surface
US5641580A (en) * 1995-10-03 1997-06-24 Osram Sylvania Inc. Advanced Mo-based composite powders for thermal spray applications
US6376103B1 (en) 1995-10-03 2002-04-23 Osram Sylvania Inc. Advanced Mo-based composite powders for thermal spray applications
US6984255B2 (en) * 2003-03-31 2006-01-10 Fujimi Incorporated Thermal spraying powder and method of forming a thermal sprayed coating using the same
US20040194662A1 (en) * 2003-03-31 2004-10-07 Tsuyoshi Itsukaichi Thermal spraying powder and method of forming a thermal sprayed coating using the same
EP1618224A1 (de) * 2003-04-28 2006-01-25 Coppe/Ufrj - Coordenacao Dos Programas De Pos Graduacao De Engenharia Da Universidade Federal Do Rio De Janeiro Verwendung von thermischem spritzen mit nioboxiden und nioblegierungen während der herstellung von gewalzten stahlblechen
US20060280874A1 (en) * 2003-04-28 2006-12-14 Coppe/Ufrj Coordenacao Dos Programas De Pos Graduacao De Engenharia Da Universidade Use of thermal spraying with niobium oxides and niobium alloys during the production process of rolled steel plates
WO2004097061A1 (en) 2003-04-28 2004-11-11 Coppe/Ufrg - Coordenacão Dos Programas De Pós Graduacão De Engenharia Da Universida Federal Do Rio De Janeiro Use of thermal spraying with niobium oxides and niobium alloys during the production process of rolled steel plates
US8551395B2 (en) * 2008-05-28 2013-10-08 Kennametal Inc. Slurry-based manufacture of thin wall metal components
US20110067796A1 (en) * 2008-05-28 2011-03-24 Deloro Stellite Holdings Corporation Slurry-based manufacture of thin wall metal components
US20120276411A1 (en) * 2009-06-30 2012-11-01 Hunprenco Precision Engineers Limited Coating Composition
JP2012532202A (ja) * 2009-06-30 2012-12-13 ハンプレンコ プレシジョン エンジニアズ リミテッド コーティング組成物
US20130221261A1 (en) * 2010-11-09 2013-08-29 Nittan Valve Co., Ltd. Wear-resistant cobalt-based alloy and engine valve coated with same
US9206319B2 (en) * 2010-11-09 2015-12-08 Fukuda Metal Foil & Powder Co., Ltd. Wear-resistant cobalt-based alloy and engine valve coated with same
CN105734345A (zh) * 2010-11-09 2016-07-06 福田金属箔粉工业株式会社 填满了耐磨损性钴基合金的发动机阀门
US9249889B1 (en) 2012-03-09 2016-02-02 Mogas Industries, Inc. High pressure ball valve
US9366345B2 (en) 2012-03-09 2016-06-14 Mogas Industries, Inc. High pressure ball valve and seat
US9500285B2 (en) 2012-03-09 2016-11-22 Mogas Industries, Inc. High pressure ball valve and packing
US10428406B2 (en) * 2016-02-12 2019-10-01 Kennametal Inc. Wear resistant and corrosion resistant cobalt-based alloy powders and applications thereof
DE102017101919B4 (de) 2016-02-12 2023-01-19 Kennametal Inc. Verfahren zum Aufbringen einer Beschichtung auf ein Substrat
CN113684438A (zh) * 2021-08-31 2021-11-23 安徽工业大学 一种高强度高硬度表面防护用喷涂粉末及其应用方法

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GB1042708A (en) 1966-09-14

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