US3234018A - Method for developing copies using electrophotographic layers - Google Patents

Method for developing copies using electrophotographic layers Download PDF

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Publication number
US3234018A
US3234018A US109767A US10976761A US3234018A US 3234018 A US3234018 A US 3234018A US 109767 A US109767 A US 109767A US 10976761 A US10976761 A US 10976761A US 3234018 A US3234018 A US 3234018A
Authority
US
United States
Prior art keywords
layer
electrophotographic
latent image
developer
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US109767A
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English (en)
Inventor
Wendt Rudolf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lumoprint Zindler KG and Co GmbH
Original Assignee
Lumoprint Zindler KG and Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lumoprint Zindler KG and Co GmbH filed Critical Lumoprint Zindler KG and Co GmbH
Application granted granted Critical
Publication of US3234018A publication Critical patent/US3234018A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/48Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03DAPPARATUS FOR PROCESSING EXPOSED PHOTOGRAPHIC MATERIALS; ACCESSORIES THEREFOR
    • G03D13/00Processing apparatus or accessories therefor, not covered by groups G11B3/00 - G11B11/00
    • G03D13/002Heat development apparatus, e.g. Kalvar
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G13/00Electrographic processes using a charge pattern
    • G03G13/06Developing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/06Apparatus for electrographic processes using a charge pattern for developing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/22Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups G03G13/02 - G03G13/20
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/22Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups G03G13/02 - G03G13/20
    • G03G15/28Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups G03G13/02 - G03G13/20 in which projection is obtained by line scanning
    • G03G15/30Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups G03G13/02 - G03G13/20 in which projection is obtained by line scanning in which projection is formed on a drum
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/09Colouring agents for toner particles
    • G03G9/0926Colouring agents for toner particles characterised by physical or chemical properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S101/00Printing
    • Y10S101/37Printing employing electrostatic force

Definitions

  • the invention is based on the problem of providing a method and material which, using latent charge images in a dry process, enable development and if required fixing without the disadvantages of the known processes.
  • This problem is solved in that the electrophotographic layer is exposed to a source of heat radiation and that a heat distribution corresponding to the latent image is produced in this layer and in that this layer is exposed to said heat radiation when in engagement with heat-reactive developing material, i.e. material which reacts or dissolves at a fixed temperature, whereby the material melts in accordance with the latent image and forms a visible image.
  • heat-reactive developing material i.e. material which reacts or dissolves at a fixed temperature
  • One feature of the invention lies in that the latent charge image of an electrophotographic layer has, in particular for heat rays of long wavelengths such as infrared rays, a (heat) conductivity different from that of the layer outside the image or without image representation.
  • electrophotographic layer relates to materials which can ordinarily be used in electrophotographic processes.
  • the coated backings which have been employed previously in electrophotographic processes can be used as the electrophotographic layer.
  • developer materials in combination with a heatreactive material are provided on the electrophotographic sheet with the electrostatic latent image and are exposed to heat rays.
  • the developer substances are arranged on a separate backing, which is first brought into contact with the electrophotographic layer after the production of the electrostatic image and then has the heat ray applied thereto.
  • This contact is advantageously effected under pressure, the layer and the backing with the developer substances for example being pressed together in frame-like supports.
  • the invention includes the provision of developer materials which, at a fixed temperature, carry out chemical and/or physical reactions in accordance with the dimensions of the electrostatic latent image.
  • a known developer powder comprising pigment materials is uniformly distributed on the backing by means of a fusible means such as a wax or a low melting resin which may have a colophony base.
  • a fusible means such as a wax or a low melting resin which may have a colophony base.
  • the backing is exposed to a heat ray when the developer substance on the special backing has been brought in contact with the electrophotographic sheet in which the electrostatic latent image is located, the developer layer side of the special backing lying against the electrophotographic sheet.
  • the heat ray is applied from the side of the electrophotographic sheet which latter in this manner acts as a selective heat filter.
  • This process has the advantage that the fixing is carried out in the same step as the developing since the pigment particles of the developer which are set free in the region of the electrostatic latent image by liquification of the fusible substance are fused to the electrophotographic sheet.
  • a visible image has been formed on the backing. This visible image corresponds to the latent image in the electrophotographic layer.
  • the electrophotographic layer is separated from the backing which carries said visible image.
  • An infra-red source is advantageously used for producing the heat ray. It is pointed out, however, that the rays from the heat source may have wavelengths between from the end of the visible light to and including the infrared region.
  • the invention includes the use of developer substances on a special backing, whereby the developer substances are released by a heating effect at a fixed temperature, are transferred to the electrophotographic layer in accordance with the dimensions of the electrostatic latent image therein and are fixed on this layer.
  • developer substances are used which under the effect of heat rays of a fixed temperature carry out a col-our change on the special backing for the developer substances and/or with materials on the electrophotographic layer.
  • the developer material for carrying out this process contains, in one embodiment, pigment materials in uniform distribution in a fusible substance on a backing.
  • fusible substances are used waxes, for example paraffin wax or ceresin wax, which are particularly stable and have, for example, a melting point between 60 and C.
  • the invention includes as fusible substance resins having low melting points, for example of colophony basis.
  • carbon black is advantageously used in the above embodiment.
  • developer materials with accurately defined melting points and which have been previously used in electrophotographic processes, advantageously those powders being used which have the lowest possible melting point.
  • the developer material may comprise a combination of substantially 15% carbon black and substantially 85% of so-called highest wax type S with a melting point of about 80 C. This developer material is applied to a paper, for example of low quality.
  • the developer layer applied to the second backing has the composition quoted below.
  • a backing which after exposureof the; photoconductive layer or the photoconductive layer backing, if this layer is arranged on a special backing, is exposed to heat rays while being pressed against the photoconductive layer or photoconductive layer backing.
  • Special black dye IV is a product of Degussa containing 89% C, 1.1% H, .7% N, .3% S, and 8.9% 0.
  • the wax type S is produced by a chrom acid oxidation of raw montan wax and is composed of- 80% by weight of wax acid and 15 to by weight of the original wax ester.
  • the Emnlsifier 2106 is an organic substance emulsifiable in water and composed of a mixture of different polyglycol-ether as disclosed in the German patent specification No. 1,020,426.
  • Special black dye IV is generally used for printing and copying inks, dye bands, carbon papers and lacquers, and
  • the photoconductive layer is' advantageously sheet-shaped, being arranged on a special carrier or being self-supporting.
  • second layer 'contains developi-ng materials which on being heated by infra-red rays carry out reactions according to the latent image and produce the'visible image in thesecond layer.
  • the 1 second layer contains developer substances which on being heated by infra-red rays carry out reactions according to the latent image and produce the visible image in thesecond lay-en said second layer containing substances, which carry out a color change, at a fixed temperature and (react in dependence with the degree of heat transfer caused by the heat. conduction of the: electrophotographic layer.
  • rays consists of rays 'in the region at the end of the visible light, including infra-red rays.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Fixing For Electrophotography (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
  • Electrophotography Using Other Than Carlson'S Method (AREA)
US109767A 1960-03-18 1961-03-08 Method for developing copies using electrophotographic layers Expired - Lifetime US3234018A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEL35669A DE1186331B (de) 1960-03-18 1960-03-18 Verfahren zur Entwicklung eines Waermeleitfaehigkeitsbildes

Publications (1)

Publication Number Publication Date
US3234018A true US3234018A (en) 1966-02-08

Family

ID=7267176

Family Applications (1)

Application Number Title Priority Date Filing Date
US109767A Expired - Lifetime US3234018A (en) 1960-03-18 1961-03-08 Method for developing copies using electrophotographic layers

Country Status (6)

Country Link
US (1) US3234018A (fr)
BE (1) BE601484A (fr)
DE (1) DE1186331B (fr)
FR (2) FR1284291A (fr)
GB (1) GB978811A (fr)
NL (1) NL262411A (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3379526A (en) * 1962-03-09 1968-04-23 Lumoprint Zindler Kg Method of producing images by using electrophotographic material
US3411932A (en) * 1964-09-23 1968-11-19 Xerox Corp Quality xerographic reproductions
US3512882A (en) * 1965-12-17 1970-05-19 Slaughter Byers Icenhour & Jac Electro photography system
US3652315A (en) * 1967-11-13 1972-03-28 Takehiko Matsuo A developing method in electrophotography using toner particles coated with a non-volatile liquid
US5695904A (en) * 1992-08-19 1997-12-09 Xerox Corporation Semi-dry developers and processes thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6941739B2 (ja) * 2018-07-30 2021-09-29 住友理工株式会社 電子写真機器用導電性ロール

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2297691A (en) * 1939-04-04 1942-10-06 Chester F Carlson Electrophotography
US2503758A (en) * 1947-08-16 1950-04-11 Eastman Kodak Co Fusion photothermography
US2629671A (en) * 1947-08-16 1953-02-24 Eastman Kodak Co Photothermography, printing sheet and printing ink therefor
US2692178A (en) * 1948-04-30 1954-10-19 Onera (Off Nat Aerospatiale) Method and material for graphical registering or direct recording
US2764693A (en) * 1951-05-25 1956-09-25 Gen Electric Process and apparatus for image production and recordation
US2798959A (en) * 1953-10-01 1957-07-09 Rca Corp Photoconductive thermography
US2798960A (en) * 1953-10-01 1957-07-09 Rca Corp Photoconductive thermography
US2916622A (en) * 1956-12-28 1959-12-08 Kalvar Corp Methods and apparatus for copying
US3010883A (en) * 1956-03-30 1961-11-28 Minnesota Mining & Mfg Electrolytic electrophotography
US3055006A (en) * 1961-01-24 1962-09-18 Ibm High density, erasable optical image recorder
US3083117A (en) * 1957-06-14 1963-03-26 Schmiedel Ulrich Process of developing electrostatic images

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE589707A (fr) * 1959-04-15

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2297691A (en) * 1939-04-04 1942-10-06 Chester F Carlson Electrophotography
US2503758A (en) * 1947-08-16 1950-04-11 Eastman Kodak Co Fusion photothermography
US2629671A (en) * 1947-08-16 1953-02-24 Eastman Kodak Co Photothermography, printing sheet and printing ink therefor
US2692178A (en) * 1948-04-30 1954-10-19 Onera (Off Nat Aerospatiale) Method and material for graphical registering or direct recording
US2764693A (en) * 1951-05-25 1956-09-25 Gen Electric Process and apparatus for image production and recordation
US2798959A (en) * 1953-10-01 1957-07-09 Rca Corp Photoconductive thermography
US2798960A (en) * 1953-10-01 1957-07-09 Rca Corp Photoconductive thermography
US3010883A (en) * 1956-03-30 1961-11-28 Minnesota Mining & Mfg Electrolytic electrophotography
US2916622A (en) * 1956-12-28 1959-12-08 Kalvar Corp Methods and apparatus for copying
US3083117A (en) * 1957-06-14 1963-03-26 Schmiedel Ulrich Process of developing electrostatic images
US3055006A (en) * 1961-01-24 1962-09-18 Ibm High density, erasable optical image recorder

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3379526A (en) * 1962-03-09 1968-04-23 Lumoprint Zindler Kg Method of producing images by using electrophotographic material
US3411932A (en) * 1964-09-23 1968-11-19 Xerox Corp Quality xerographic reproductions
US3512882A (en) * 1965-12-17 1970-05-19 Slaughter Byers Icenhour & Jac Electro photography system
US3652315A (en) * 1967-11-13 1972-03-28 Takehiko Matsuo A developing method in electrophotography using toner particles coated with a non-volatile liquid
US5695904A (en) * 1992-08-19 1997-12-09 Xerox Corporation Semi-dry developers and processes thereof

Also Published As

Publication number Publication date
BE601484A (fr) 1961-07-17
FR1299550A (fr) 1962-07-27
FR1284291A (fr) 1962-02-09
GB978811A (en) 1964-12-23
NL262411A (fr)
DE1186331B (de) 1965-01-28

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