US2842837A - Method of working wire and a lubricant therefor - Google Patents

Method of working wire and a lubricant therefor Download PDF

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US2842837A
US2842837A US578561A US57856156A US2842837A US 2842837 A US2842837 A US 2842837A US 578561 A US578561 A US 578561A US 57856156 A US57856156 A US 57856156A US 2842837 A US2842837 A US 2842837A
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wire
lubricant
inorganic
compound
coating
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US578561A
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Raymond J Huet
Gordon T Spare
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United States Steel Corp
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United States Steel Corp
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/061Carbides; Hydrides; Nitrides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
    • C10M2201/066Molybdenum sulfide
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/081Inorganic acids or salts thereof containing halogen
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/084Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/16Carbon dioxide
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18Ammonia
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
    • C10M2215/082Amides containing hydroxyl groups; Alkoxylated derivatives
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/241Manufacturing joint-less pipes
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/242Hot working
    • CCHEMISTRY; METALLURGY
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/245Soft metals, e.g. aluminum
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/246Iron or steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08Solids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2918Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
    • Y10T428/292In coating or impregnation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/294Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/2958Metal or metal compound in coating

Definitions

  • This invention relates to a method of working wire and a lubricant therefor and particularly to the processing of steel wire which is to be hot worked after being drawn.
  • This invention was necessary to remove the wire drawing lubricant from the wire and apply hot forming lubricants to the wire for subsequent operation such as upsetting and extruding. This was necessary because the conventional wire drawing lubricants became gummy or viscous upon being heated to the hot working temperature and would thus clog the dies of the hot working machine. Also, some wire drawing lubricants char at these temperatures and lose their lubricating characteristics.
  • the wire drawing lubricant of our invention includes a mixture of an organic compound and an inorganic compound.
  • the organic compounds are of the group having the formula (C H CONH) CH where x is any number from 7 to 17. Examples of such compounds are as follows:
  • the wire In drawing the wire it may be first coated by dipping in a water solution containing a well known wire drawing aid such as borax, copperas, lime, phosphates and silicates. It is then passed through a die box containing a dry mixture of our lubricating mixture and the wire drawn through a series of wire drawing dies. The drawn wire with the coating thereon is then heated to a temperature of between 500 and 1000 F. and upset or extruded while hot. During the hot forming operation the organic compound is volatilized, thus leaving the wig? 99 l $iwiththe inorganic lubricant alone so that clogging of the work dies is eliminated. It often occurs that the drawn wire is sold to others who perform the hot working operation thereon. Since the organic compound is not water soluble it protects the wire against corrosion during shipping and storage.
  • a well known wire drawing aid such as borax, copperas, lime, phosphates and silicates.
  • a lubricant suitable for cold and hot working consisting essentially of a mixture containing between and 50% by weigh tof methylene bis-octadecanamide and between 5 and 50% by weight of an inorganic non-volatile lubricant of the class consisting of graphite, molybdenum, disulfide, cadmium sulfide, cadmium iodide and boron nitride.
  • a lubricant suitable for cold and hot working consisting essentially of a mixture containing between 95 and 50% by weight of a compound of the group having the formula (C H CONHhCH where x is any number from 7 to 17, and between 5 and 50% by weight of an inorganic lubricant of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride.
  • the method of wire drawing comprising coating the wire with a mixture consisting essentially of between 95 and 50% by weight of methylene bis-octadecanamide and between 5 and 50% by weight of an inorganic nonvolatile lubricant, drawing the coated wire, and then hot working the drawn wire at a temperature of between 500 and 1000 F.
  • the method of working wire comprising coating the wire with a light coating consisting essentially of a compound of the group consisting of lime, borax, copperas, phosphates and silicates, then applying over said coated wire a coating of a mixture consisting essentially of between 95 and 50% by weight of a compound of the group having the formula (C H CONHhCI-I where x is any number from 7 to 17 and between 5 and 50% by weight of an inorganic lubricant of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride, then drawing the wire, and then hot working the drawn wire at a temperature of between 500 and 1000 F.
  • a light coating consisting essentially of a compound of the group consisting of lime, borax, copperas, phosphates and silicates
  • An article comprising a drawn wire having a coating thereon consisting essentially of a compound of the group having the formula (C,H CONH) CH where x is any number from 7 to 17, and an inorganic non volatile lubricant of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Metal Extraction Processes (AREA)
  • Lubricants (AREA)

Description

United States Patent METHOD OF WORKING WliRE AND A LUBRICANT THEREFOR Raymond J. Huet, Chagrin Falls, and Gordon T. Spare, Chardon, Ohio, assignors to United States Steel Corporation, a corporation of New Jersey No Drawing. Application April 17, 1956 Serial No. 578,561
Claims. (Cl. 29193) This invention relates to a method of working wire and a lubricant therefor and particularly to the processing of steel wire which is to be hot worked after being drawn. Prior to the development of our invention it was necessary to remove the wire drawing lubricant from the wire and apply hot forming lubricants to the wire for subsequent operation such as upsetting and extruding. This was necessary because the conventional wire drawing lubricants became gummy or viscous upon being heated to the hot working temperature and would thus clog the dies of the hot working machine. Also, some wire drawing lubricants char at these temperatures and lose their lubricating characteristics.
It is therefore an object of our invention to provide a method of working wire in which the coating used for wire drawing can also be used for subsequent hot working operations.
Another object is to provide a wire drawing lubricant which is suitable for both hot and cold working operations.
Still another object is to provide a drawn wire hav-' ing a coating thereon for use in further hot working operations.
These and other objects will be more apparent after referring to the following specification.
The wire drawing lubricant of our invention includes a mixture of an organic compound and an inorganic compound. The organic compounds are of the group having the formula (C H CONH) CH where x is any number from 7 to 17. Examples of such compounds are as follows:
Methylene bis-octanamide [CH (CH CONH] CH Methylene bis-decanamide [CH (CH CONH] CH Methylene bis-dodecanamide [CH (CH C0NH] CH Methylene bis-tetradecanamide [CH (CH CONH] CH Methylene bis-hexadecanamide [CH CH CONH] CH Methylene bis-octadecanamide [CH CH CONH] CH The compound methylene bis-octadecanamide is preferred. These compounds volatilize at a temperature of about 500 F. and are not water soluble. The inorganic compound includes non-volatile lubricants of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride. The preferred mixture contains between 20 and 50% by weight of the inorganic lubricant with the remainder being the organic lubricant. However, the inorganic lubricant may be as little as 5% by weight of the entire mixture with the remainder being the organic lubricant. A mixture of 70% methylene bis-octadecanarnide and 30% molybdenum disulfide is satisfactory.
In drawing the wire it may be first coated by dipping in a water solution containing a well known wire drawing aid such as borax, copperas, lime, phosphates and silicates. It is then passed through a die box containing a dry mixture of our lubricating mixture and the wire drawn through a series of wire drawing dies. The drawn wire with the coating thereon is then heated to a temperature of between 500 and 1000 F. and upset or extruded while hot. During the hot forming operation the organic compound is volatilized, thus leaving the wig? 99 l $iwiththe inorganic lubricant alone so that clogging of the work dies is eliminated. It often occurs that the drawn wire is sold to others who perform the hot working operation thereon. Since the organic compound is not water soluble it protects the wire against corrosion during shipping and storage.
While several embodiments of our invention have been shown and described it will be apparent that other adaptations and modifications may be made without departing from the scope of the following claims.
We claim: 1
1. A lubricant suitable for cold and hot working consisting essentially of a mixture containing between and 50% by weigh tof methylene bis-octadecanamide and between 5 and 50% by weight of an inorganic non-volatile lubricant of the class consisting of graphite, molybdenum, disulfide, cadmium sulfide, cadmium iodide and boron nitride.
2. A lubricant suitable for cold and hot working consisting essentially of a mixture containing between 95 and 50% by weight of a compound of the group having the formula (C H CONHhCH where x is any number from 7 to 17, and between 5 and 50% by weight of an inorganic lubricant of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride.
3. The method of wire drawing comprising coating the wire with a mixture consisting essentially of between 95 and 50% by weight of methylene bis-octadecanamide and between 5 and 50% by weight of an inorganic nonvolatile lubricant, drawing the coated wire, and then hot working the drawn wire at a temperature of between 500 and 1000 F.
4. The method of working wire comprising coating the wire with a light coating consisting essentially of a compound of the group consisting of lime, borax, copperas, phosphates and silicates, then applying over said coated wire a coating of a mixture consisting essentially of between 95 and 50% by weight of a compound of the group having the formula (C H CONHhCI-I where x is any number from 7 to 17 and between 5 and 50% by weight of an inorganic lubricant of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride, then drawing the wire, and then hot working the drawn wire at a temperature of between 500 and 1000 F.
5. An article comprising a drawn wire having a coating thereon consisting essentially of a compound of the group having the formula (C,H CONH) CH where x is any number from 7 to 17, and an inorganic non volatile lubricant of the class consisting of graphite, molybdenum disulfide, cadmium sulfide, cadmium iodide and boron nitride.
References Cited in the file of this patent UNITED STATES PATENTS 1,712,348 Howe May 7, 1929 2,139,679 Hardy Dec. 13, 1938 2,340,881 Kelley et a1. Feb. 8, 1944 2,425,392 Robinson Aug. 12, 1947 2,460,632 Folda Feb. 1, 1949 2,703,768 Hall Mar. 8, 1955 2,736,700 Graham et al. Feb. 28, 1956 2,743,509 Friedman May 1, 1956

Claims (1)

  1. 5. AN ARTICLE COMPRISING A DRAWN WIRE HAVING A COATING THEREON CONSISTING ESSENTIALLY OF A COMPOUND OF THE GROUP HAVING THE FORMULA (CHXH2X+1CONH)2CH2 WHERE X IS ANY NUMBER FROM 7 TO 17, AND AN INORGANIC NONVOLATILE LUBRICANT OF THE CLASS CONISISTING OF GRAPHITE, MOLYBDENUM DISULFIDE, CADIMIUM SLIFDE, CADMIUM IODIDE AND BORON NITRIDE.
US578561A 1956-04-17 1956-04-17 Method of working wire and a lubricant therefor Expired - Lifetime US2842837A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2926108A (en) * 1957-08-30 1960-02-23 Gen Mills Inc Process for inhibiting corrosion of metals
US3059769A (en) * 1959-04-14 1962-10-23 Cefilac Extrusion lubrication
US3188791A (en) * 1963-04-22 1965-06-15 United States Steel Corp Locked coil cable and method of making same
US3213024A (en) * 1962-07-17 1965-10-19 Socony Mobil Oil Co Inc High temperature lubricant
US3392116A (en) * 1963-02-28 1968-07-09 Cegedur Gp Process of metal working and lubricant therefor
US3506463A (en) * 1967-01-04 1970-04-14 Mobil Oil Corp Mold release agent
US3765205A (en) * 1966-05-24 1973-10-16 G Schaumburg Method for protecting hot metal surface
US3916075A (en) * 1972-07-22 1975-10-28 Philips Corp Chemically highly resistant material
US3928214A (en) * 1972-04-25 1975-12-23 Hitachi Ltd Grease composition
US4308182A (en) * 1978-06-06 1981-12-29 Pennwalt Corporation Dry wire drawing lubricants based on Poly (3,5-dithio-1,2,4-thiadiazole) and Poly (2,5-dithio-1,3,4-thiadiazole)
US4371446A (en) * 1979-11-15 1983-02-01 Hirotsugu Kinoshita Lubricant
US5213644A (en) * 1991-03-20 1993-05-25 Southwire Company Method of and apparatus for producing moisture block stranded conductor
US6461730B1 (en) * 1991-09-20 2002-10-08 Danfoss A/S Lubricant for wire used for forming the stator windings of an electrical refrigerating compressor
US11069459B2 (en) * 2017-07-14 2021-07-20 Autonetworks Technologies, Ltd. Covered electrical wire and terminal-equipped electrical wire

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1712348A (en) * 1926-12-10 1929-05-07 American Steel & Wire Co Method of manufacturing wire
US2139679A (en) * 1937-07-02 1938-12-13 Du Pont Diamides of unsaturated carboxylic acids and process of making the same
US2340881A (en) * 1939-08-22 1944-02-08 Nat Oil Prod Co Composition for lubricating and softening textile fibers
US2425392A (en) * 1939-05-20 1947-08-12 Nopco Chem Co Diamide textile lubricants
US2460632A (en) * 1946-04-08 1949-02-01 Socony Vacuum Oil Co Inc Spark plug thread lubricant
US2703768A (en) * 1950-04-26 1955-03-08 Electrofilm Inc Dry lubrication process and product
US2736700A (en) * 1954-03-16 1956-02-28 Jr Charles D Graham Lubricant for cold drawing of thorium wire
US2743509A (en) * 1952-12-30 1956-05-01 Nat Machinery Co Method of making compressor blades

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1712348A (en) * 1926-12-10 1929-05-07 American Steel & Wire Co Method of manufacturing wire
US2139679A (en) * 1937-07-02 1938-12-13 Du Pont Diamides of unsaturated carboxylic acids and process of making the same
US2425392A (en) * 1939-05-20 1947-08-12 Nopco Chem Co Diamide textile lubricants
US2340881A (en) * 1939-08-22 1944-02-08 Nat Oil Prod Co Composition for lubricating and softening textile fibers
US2460632A (en) * 1946-04-08 1949-02-01 Socony Vacuum Oil Co Inc Spark plug thread lubricant
US2703768A (en) * 1950-04-26 1955-03-08 Electrofilm Inc Dry lubrication process and product
US2743509A (en) * 1952-12-30 1956-05-01 Nat Machinery Co Method of making compressor blades
US2736700A (en) * 1954-03-16 1956-02-28 Jr Charles D Graham Lubricant for cold drawing of thorium wire

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2926108A (en) * 1957-08-30 1960-02-23 Gen Mills Inc Process for inhibiting corrosion of metals
US3059769A (en) * 1959-04-14 1962-10-23 Cefilac Extrusion lubrication
US3213024A (en) * 1962-07-17 1965-10-19 Socony Mobil Oil Co Inc High temperature lubricant
US3392116A (en) * 1963-02-28 1968-07-09 Cegedur Gp Process of metal working and lubricant therefor
US3188791A (en) * 1963-04-22 1965-06-15 United States Steel Corp Locked coil cable and method of making same
US3765205A (en) * 1966-05-24 1973-10-16 G Schaumburg Method for protecting hot metal surface
US3506463A (en) * 1967-01-04 1970-04-14 Mobil Oil Corp Mold release agent
US3928214A (en) * 1972-04-25 1975-12-23 Hitachi Ltd Grease composition
US3916075A (en) * 1972-07-22 1975-10-28 Philips Corp Chemically highly resistant material
US4308182A (en) * 1978-06-06 1981-12-29 Pennwalt Corporation Dry wire drawing lubricants based on Poly (3,5-dithio-1,2,4-thiadiazole) and Poly (2,5-dithio-1,3,4-thiadiazole)
US4371446A (en) * 1979-11-15 1983-02-01 Hirotsugu Kinoshita Lubricant
US5213644A (en) * 1991-03-20 1993-05-25 Southwire Company Method of and apparatus for producing moisture block stranded conductor
US6461730B1 (en) * 1991-09-20 2002-10-08 Danfoss A/S Lubricant for wire used for forming the stator windings of an electrical refrigerating compressor
US6562767B1 (en) * 1991-09-30 2003-05-13 Danfoss Compressors Gmbh Process for producing a lubricant coated laquered wire used for forming the stator winding of an electrical refrigerating compressor
US11069459B2 (en) * 2017-07-14 2021-07-20 Autonetworks Technologies, Ltd. Covered electrical wire and terminal-equipped electrical wire

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