US2133238A - Glass fabric - Google Patents
Glass fabric Download PDFInfo
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- US2133238A US2133238A US149672A US14967237A US2133238A US 2133238 A US2133238 A US 2133238A US 149672 A US149672 A US 149672A US 14967237 A US14967237 A US 14967237A US 2133238 A US2133238 A US 2133238A
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- Prior art keywords
- fibers
- yarns
- glass
- yarn
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
- D02G3/182—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S118/00—Coating apparatus
- Y10S118/19—Wire and cord immersion
Definitions
- the present invention relates to glass textile fabrics, and more. particularly to improved knitted, woven, and braided fabrics, or the like, which are extremely strong, flexible, and may be folded and flexed a great many times without materially injuring the same.
- the present invention relates to a textile material composed of fine glass fibers having improved properties and qualities, rendering them extremely useful in the 10 arts.
- a textile material which may be wholly composed of glass fibers; such material to have strength, flexibility, foldability, and substantial freedom from brashiness or irritation so that it will find commercial uses in many of the arts.
- the fabrics heretofore and cables composed, if desired, wholly of glass fibers, these yarns and threads being of suilicient strength, elasticity, and yieldability that they may be processed through the ordinary and conventional textile machine into interwoven, 5 knitted, braided or other types of textile fabrics as desired.
- An important phase of the present invention is the provision of fibers having a fineness below a critical diameter which we have found to be in 10 the neighborhood of about .0004 inch in diameter,
- the fibers are above this critical diameter, the fibers are too brittle and coarse to permit them to be intertwisted into yarns, without resorting 15 to special and highly expensive means such as a high degree of sizing, and special machinery which would seriously limit the commercial and practical value of the yarns. Even when such expedients are resorted to, the fibers cannot be 20 intertwisted to a sufllciently high degree to render them thoroughly practical in the art. The fibers break and project out of the yarn and the resulting fabric in a bristly manner so that handling thereof causes a serious irritation to the skin. 25
- the fiber diameter is extremely important from another point of view, that is, the increased flexibility produced by using a very fine fiber diameter.
- Fabrics, properly made up may be extremely flexible, even limp 30 and soft, if the diameter of the individual fibers is below the critical range.
- the fiber diameter is important from another point of view, and that is brashiness. Fibers which are above the diameter of about .0002 inch generally feel coarse and brash and the fabrics thereof are irritating to the skin. However, when the fiber diameter is reduced below this figure, all brashiness is eliminated and the fabrics are smooth and have a soft feeling to the skin. 40
- This ratio of yarn diameter tofiber diameter has a definite bearing upon the degree of bending to .which the 45 individual fibers will be subjected when the fabric is folded or creased. This ratio should beat least as high as about 10 to 1, depending upon the fiber diameter itself.
- the radius of curvature to which each fiber is 5 subjected when the fabric is folded is the radius of curvature of the yarns themselves, since the yarns are folded over each other, or, at least, the yarns extending in the transverse direction.
- the thinner the yarns the smaller will be the 55 radius of curvature and the more likelihood of fracturing the yarns when the fabrics are folded.
- the number of fibers, therefore, composing each yarn also has a bearing on the above ratio.
- the number of fibers in each yarnwhich is to be woven or interlaced with other yarns into a textile fabric should have at least about 70 and preferably more than about 100 fibers. Of course, when plying the yarns, it is the total number of fibers in the final yarn which is important.
- the sizing or coating material may be of any suitable type such as wax, oil varnish, shellac, cellulose products or derivatives, resins, plastics, gelatins, agar agar, starch, casein, paraflin, rubber, latex, acetate, aryl phosphate, tricresyl phosphate, halogenated hydrocarbons of both the allphatic or aromatic types, or the like.
- the sizing or coating material may be removed after the fabrication, and other types of coating materials may be substituted in their place if desired. These latter are generally such substances as lubricants, as for example, light oil or the like.
- the glass fibers may also be dyed with any suitable substances to provide the proper color hues, shades or designs.
- Fig. 1 is an elevational diagrammatic view shown partly in section of an apparatus adapted to produce fine glass fibers by means of a gaseous blast, and form them into a sliver or yarn;
- Fig. 2 is a fragmentary plan view of a portion of the device illustrated in Fig. 1 showing the fiber collecting means used for forming the sliver;
- Fig. 3 is a diagrammatic elevational View illustrating another apparatus which may be used for producing long, fine fibers, particularly of the continuous fiber type, and forming them into a thread or yarn;
- Fig. 4 is a diagrammatic elevational view of an 7 apparatus which may be used to coat the yarn with a suitable sizing or coating material;
- Fig. 5 is a diagrammatic elevational view of a winding or spinning device adapted to twist the strands or slivers into twisted yarns or cables;
- Fig. 6 is a diagrammatic perspective view of a loom adapted to interweavethe glass fibers into woven fabrics
- Fig. '7 is a more or less diagrammatic perspective view of a cable yarn composed of yarns twisted in one direction, and which have themselves been intertwisted together in the opposite direction to produce a balanced cable yarn
- Fig. 8 is a diagrammatic view of a braided tubular fabric composed of braided glass yarns; and Fig. 9 is a diagrammatic plan view of a knitted Iabric composed of glass yarns.
- the formula heretofore generally used in mechanics for deflection on central loading of a beam is:
- the size of the loop is also a function of the tensile strength which increases markedly as the fiber becomes smaller so as to permit a still smaller loop to be drawn. It also happens that E increases slowly as the fiber is drawn smaller, thus making a further correction in the proper direction.
- the size of the loop that may be drawn decreases with a decrease in the square of the fiber diameter, as a quadratic function of the diameter because of the increased tensile strength, andas some other less important function of the modulus of elasticity.
- Ts is the tensile strength in thousands of pounds per square inch and d is the diameter expressed in units of ten-thousandths inch.
- the tensile strength of glass fibers is equal to the bulk strength of glass where fiaws are'numerous, plus the increase in strength due to the reduction of fiaws at the surface of the glass fiber, plus the increase in strength due to the decrease of fiaws in the body of the glass.
- the fiber diameter should be maintained below the critical range if it is desired to produce yarns having a sufilcient number of individual fibers therein, that is, at least about '70 or preferably more than 100, and
- the fabric is also relatively thin in spite of the large number of fibers composing the yarns.
- a conventional glass furnace has been illustrated, having an electrically heated bushing 22, preferably composed of a platinum alloy or platinum metal, forming an outlet feeder having a plurality of individual orifices 23 arranged at the' lower end thereof for the emission of a plurality of glass streams. If it is desired, and it has been found practical to do so, the glass may be melted from cullet or batch material directly in the electrically heated bushing '22, thus dispensing with the furnace 20.
- blower 25 Spaced beneath the outlet orifices 23 is a blower 25 which is formed in two parts, separated by a slot 26through which the glass streams flow and are attenuated by gaseous blasts emanating from. a series of jets 21.
- an endless foraminous surface 3 which may be in the form of a screen, mounted upon the rotating drum 3
- the glass streams emerge from the bushing 22, they are attenuated into long, fine fibers'35 having the desired characteristics, and then are conveyed by the gaseous blast upon the foraminous surface 30 where they are arrested and collected into the form of a web 36.
- Baffles 31 may be adjustably placed on each side of the region of the surface 30 upon which the fibers collect, these bafiles 31 serving to conduct all of the fibers 35 to the proper region upon the surface 30 where they may be compactly collected into the form of the web 36.
- a suction box 40 Underneath the surface 30 is a suction box 40, which communicates with a suitable suction blower or other suitable exhausting means 4 the suction box serving to withdraw the vehicular blast and facilitating the retention of the web 36 upon the surface 30 as it is being collected and drawn off into the form of a sliver or yarn 44.
- is driven by any suitable means such as a motor which is mechanically connected to the drum 3
- the fibers After the fibers have been collected in the form of the web 36, they are drawn off in the general direction of travel of the screen or surface 30, although at a higher speed than the peripheral speed of the surface 30; and then drawn through a compacting device or trumpet 49 then through suitable folding devices such as the diablo-shaped rolls 50, which serve to compact the web and to fold in the loose edges and loose fibers which may otherwise project outwardly from the sliver M; then through the guide 5
- the spool 53 is mounted upon a suitable drum or shaft 55 which is driven by the motor 56.
- the mechanical drive connection silver in which the individual fibers lie predominantly in a longitudinal direction parallel to the sliver, although incompletely parallel and being mutually intermatted with one another to form a coherent strong sliver which may be processed as desired, as, for example, by twisting, winding,
- the glass may be melted in a suitable glass furnace having a suitable bushing 6
- the glass streams are mechanically attenuated by means of a rotating spool over which the thread 66 formed by the grouping of the individual fibers together, is wound.
- a suitable blower 61 Spaced beneath the bushing 6
- the blower 61 serves to direct a blast of cooling gas such as air, or the like, through the jets 69 onto the individual fibers, chilling them within a short distance of the outlet orifices 63.
- the blasts emanating from the jets 69 also serve to induce a draft of cool atmosphericair over the top of the blower and down through the slots, whereby it tends to cool the glass as it emerges from the outlet orifices.
- the individual fibers '62 may be grouped by means of a suitable device such as that formed by a V-shaped slot 13 having a pad 74 in the groove thereof, over which the fibers may be drawn into the thread 66.
- a Lubricant reservoir 75 adapted to be filled with a suitable lubricant or sizing or coating material supply body 16. If the supply body 16 is composed of a thermoplastic substance, such as wax, asphalt, or the like, it may be heated by any suitable means such as the burner 11.
- the cooling blasts from the jets 88 serve to chill the glass and permit it to be sufiiciently viscous that it may be drawn down into an extremely fine fiber within an unusually small range below the orifices 63.-
- the glass instead of producing a viscous fiber which is gradually attenuated into a finer fiber, draws down directly from the molten glass into a fine fiber form where it is suddenly chilled into that form while it is still within about an inch or so from the outlet orifice.
- the degree of attenuation to which these fibers may be subjected is extremely high, and it is possible to produce fibers having diameters of about .0002 inch more or less without difficulty.
- the diameters of the orifices 63 are also relatively small, and may be about .030 to about .060 inch in diameter, more or less, as desired.
- the fibers produced by the methods illustrated in Figs. 1 and 2 and by the apparatus illustrated in Fig. 3, are not only extremely fine, but are also extremely long, and have strengths ranging in the order of magnitude of about 300,000 pounds per square inch as an. ordinary matter, and in certain instances, much higher and in the order of magnitude of about one million to three million pounds per square inch. These fibers are also extremely flexible and are substantially free from brash .or skin irritation.
- the threads formed by these methods of production may be processed through any of the usual textile machines to produce twisted yarns, ply yarns, cables, balanced yarns, and fabrics of any desired type such as knitted, interwoven, or braided fabrics, as brought out more fully hereinafter.
- slivers 40 If it is desired to weave the slivers 40 directly into yarns without twisting the same, it has been found preferable to coat the same with a suitabe sizing, and for this purpose the apparatus illustrated in Fig. 4 may be used.
- the sliver 44 is drawn from the spool 53 over the guide rolls and then into the bath 8i of the sizing material within a tank or reservoir 82.
- gelatin or other sizes mentioned hereinabove are satisfactory.
- a roll 83 may be submerged in the bath 8
- coacting rolls 84 may be arranged over the container 82, these rolls serving as a wringer.
- the thread or sliver 44 may then be dried in a suitable heating chamber 85 which may be provided with burners or other suitable heating, means 86. From here the thread or silver 44 may be again wound upon a spool 81, with the assistance of the traverse 88.
- a conventional apparatus for this type of twisting has been shown in Fig. 5, in which one or more spools I00 may feed in the required number of threads IOI through an eye I02, around the rolls I03 forming a bite for the yarn, then through the eye I04, through .the drag I05, and then around the rotating spool I01.
- the drag I00 is mounted upon a traversing means I00 which serves to distribute and wind the thread I M uniformly over the spool I0I,to form a neat package.
- the spool I0I is rotated by any suitable means such as the belt I09.
- the degree of twist induced by this apparatus may be relatively high if desired, as, for example 6 to 12 or more turns per inch; the degree of twist, of course, being dependent upon the diameters of thefibers and the number of fibers composing the individual threads which are being twisted.
- any stresses or vibrations caused by the loom cause the entire load to be borne by the tightest end; these loads being frequently sufficient to break an individual yarn or end, before the load can be distributed to the other ends in the warp.
- the tightest end breaks, the load is transferred to the next tightest end which also does not have sufi'icient strength to carry the entire load, and it also breaks in turn before the load can be distributed among the several ends.
- the yarns formed from the sliver's produced by the apparatus shown in Figs. 1 and-2 have an especially high degree of elongation and stretchability, owing to their particular structure.
- the fibers of these yarns are intermatted and interlaced with one another and are not in substantially complete parallelism and alignment as are the continuous filament yarns formed by the apparatus shown in Fig. 3. Owing to their inherent intermatted nature, these yarnsseem to possess a higher degree of yieldability, and when they are twisted into the form of a twisted yarn, the intermatted fibers of the yarn appear to yield and distribute the stresses and loads induced in the yarn throughout the yarn as a whole, thus angle.
- the twisted yarns produced by the winding apparatus shown in Fig. 5, may be intertwisted with one another to form balanced yarns, an example of which is illustrated in Fig. '7.
- Fig. 7 two original yarns IIO are intertwisted to the right for a suflicient number of turns as, for example, 6 to 12 turns an inch to produce the twisted ply yarns I I I, and then two of these twisted yarns I II are intertwisted to the left for the required number of turns, generally slightly more than half of the original degree of twist to form a balanced cable yarn II2.
- Balanced yarns or cables of other various types may be formed, such as two, three, or four-ply or various other types of ply yarns or cables, or the like.
- a loom which may be used to weave threads or yarns composed of glass fibers.
- any desired construction such as plain weave, twill, or manifold others, and in doing so, it is possible to produce cloths having any degree of hardness which is desired.
- the resulting cloth will have excellent properties of flexibility, strength, foldability, and general resistance to wear.
- Fig. 6 we have shown the warp II4 wound upon the warping beam I I 5. From here the warp is trained over the whip roll I I6 which is preferably arranged in such a position that the indi-' vidual ends of the warp II4 make contact over a relatively wide are on the surface of the whip roll and are turned through a relatively wide We have found that this arrangement materially reduces the number of breaks in the. ends by permitting the whip roll to relieve the individual yarns of unusual stresses and enables the individual yarns to be held at a constant tension.
- the remaining portions of the loom may be of the conventional type, and thus, may comprise the heddles II'l, operating to produce the shed into which a shuttle II8 travels, and cloth beam over which the woven fabric is wound.
- the whip roll H6 and the resilient cover therefor I2 I yield and take up a large portion of these vibrations. Any unusual stresses in the individual ends may also be relieved by the resilient cover I20 on the warping beam II5.
- Various other types of textile fabrics may also be made from our novel yarn or threads, another example of which is illustrated in Fig. 8 showing a braided article I25.
- This braided article is in tubular form although, of course, any other type or construction of braid may be used. When in tubular form, it has particular application as a wire covering or other covering means.
- the braiding operations may be performed by any conventional textile machine now in use.
- FIG. 9 Another example of a textile fabric which we may make using our novel glass yarns, is illustrated in Fig. 9 showing a knitted fabric I26.
- the knitting may be done on any conventional machine, and may be made with any desired con struction.
- the knitted articles may be knitted with a tight construction, if desired, and we have found that such fabrics possess an extremely high flexibility, resilience and stretchability; although when pulled out of shape, they will return to their normal position after the stresses are relieved.
- a textile yarn composed of at least forty fine glass fibers having average diameters not more than about .0004 inch, the fibers of said yarn being twisted in order to produce a yarn of substantial flexibility, mass integrity, strength and stretchability to permit knotting without rupturing said yarn.
- a glass textile fabric comprising. interlaced textile yarns as called for in claim 1.
- a textile yarn composed of at least forty fine glass fibers having diameters not more than about .0003 inch, the fibers of said yarn being intertwisted in order to produce a yarn of substantial flexibility, mass integrity, strength and stretchability to permit said yarn to be folded over itself without rupturing said yarn.
- a textile yarn composed of a multiplicity of fine glass fibers lying predominately parallel to the longitudinal direction of said yarn and being intermatted with one another in said yarn, the
- fibers of said yarn having diameters not more than about .0004 inch, and said yarn being twisted able 0! being folded and creased without fracture, which comprises interwoven yarns each composed of va multiplicity of intertwisted fine glass of at least seventy fine glass fibers having diam- V eters not more than about .0002 inch, the fibers of said yarn being intertwisted to produce a yarn of substantial flexibility, mass integrity, strength and stretchability to permit said yarn to be folded over and wrapped around itseltwithout rupturing 5 said yarn.
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Description
e. SLAYTER El AL GLAS S FABRIC Filed June .22, 1957 2 Sheets-Sheet l INVENTOR Fame: Slag/fer Jain H Thomas.
A TTORNEYS.
GLASS FABRIC Filed June 22, 1937 2 Sheets-Sheet 2 5522755 5125/2 51", Jmimfi 1 15517755 IN VEN TORA',
A TTORNEYS.
Patented Oct. 11, 1938 GLASS FABRIC I Games Slayter and John H; Thomas, Newark,
Ohio, assignors to Owens-Illinois Glass Company, a corporation of Ohio I Application June 22," 1937, Serial No. 149,672
7- Claims. (Cl. ll'L-SZ) The present invention relates to glass textile fabrics, and more. particularly to improved knitted, woven, and braided fabrics, or the like, which are extremely strong, flexible, and may be folded and flexed a great many times without materially injuring the same. Thus the present invention relates to a textile material composed of fine glass fibers having improved properties and qualities, rendering them extremely useful in the 10 arts.
Heretofore it has been attempted to produce interwoven fabrics using glass filaments, but these fabrics were extremely limited in their usefulness and in their properties.
formed were, relatively stiff and resisted fiexure.
If the fabrics were folded or creased, they would break apart at the fold, and if they were flexed back and forth for a relatively small number of times, they would break apart. It has even been attempted to produce a garment using a fabric composed of glass filaments, but in order to piece the material together, it was necessary to secure it to a backing cloth of organic fibrous material. Another serious disadvantage oi the prior fab- :5 rics composed of glass fibers, was that they were brash and irritated the skin to an unbearable degree. We aim to overcome these objections and to largely, if not entirely eliminate brashiness and irritation from our fabrics.
Another defect of the prior art, was the fact that the textile materials composed of glass fibers heretofore in use could not be processed through the ordinary and conventional textile machines such as winding and spinning machines and .3 through the conventional loom. In order to fabricate glass fabrics in a practical commercial manner, it is necessary to process them through a conventional machine loom, and the present invention provides a glass textile which may be processed through the conventional textile machine operations, to produce a fine, high quality piece of merchandise.
One of the serious objections heretofore found in attempting to weave yarns composed of glass fibers in a conventional loom, was the difficulty caused by the relative non-elongation of glass fibers or their lack of elasticity.
It is an object of the invention to provide a textile material which may be wholly composed of glass fibers; such material to have strength, flexibility, foldability, and substantial freedom from brashiness or irritation so that it will find commercial uses in many of the arts. In thus fabricating the textile materials, we also aim to produce yarns, threads, ply yarns, intertwisted yarns,
The fabrics heretofore and cables composed, if desired, wholly of glass fibers, these yarns and threads being of suilicient strength, elasticity, and yieldability that they may be processed through the ordinary and conventional textile machine into interwoven, 5 knitted, braided or other types of textile fabrics as desired.
An important phase of the present invention is the provision of fibers having a fineness below a critical diameter which we have found to be in 10 the neighborhood of about .0004 inch in diameter,
and preferably below about .0002 inch in diameter. If the fibers are above this critical diameter, the fibers are too brittle and coarse to permit them to be intertwisted into yarns, without resorting 15 to special and highly expensive means such as a high degree of sizing, and special machinery which would seriously limit the commercial and practical value of the yarns. Even when such expedients are resorted to, the fibers cannot be 20 intertwisted to a sufllciently high degree to render them thoroughly practical in the art. The fibers break and project out of the yarn and the resulting fabric in a bristly manner so that handling thereof causes a serious irritation to the skin. 25
We have also found that the fiber diameter is extremely important from another point of view, that is, the increased flexibility produced by using a very fine fiber diameter. Fabrics, properly made up, may be extremely flexible, even limp 30 and soft, if the diameter of the individual fibers is below the critical range.
The fiber diameter is important from another point of view, and that is brashiness. Fibers which are above the diameter of about .0002 inch generally feel coarse and brash and the fabrics thereof are irritating to the skin. However, when the fiber diameter is reduced below this figure, all brashiness is eliminated and the fabrics are smooth and have a soft feeling to the skin. 40
Another important feature of the invention which is tied in with fiber diameter, is the ratio of fiber diameter to yarn diameter. This ratio of yarn diameter tofiber diameter has a definite bearing upon the degree of bending to .which the 45 individual fibers will be subjected when the fabric is folded or creased. This ratio should beat least as high as about 10 to 1, depending upon the fiber diameter itself.
The radius of curvature to which each fiber is 5 subjected when the fabric is folded is the radius of curvature of the yarns themselves, since the yarns are folded over each other, or, at least, the yarns extending in the transverse direction. Thus the thinner the yarns, the smaller will be the 55 radius of curvature and the more likelihood of fracturing the yarns when the fabrics are folded. The number of fibers, therefore, composing each yarn also has a bearing on the above ratio. 5 That is to say, if a large number of fibers go to make up the individual yarns, there will be less likelihood of fracture due to creasing or folding the fabrics, and conversely, the smaller the number of fibers in the yarns, the greater will be the tendency of fracture owing to bending or creasing of the fabrics.
Thus, in order to produce a usable, thin, flexible cloth, it is necessary to build up the individual yarns with a multiplicity of individual fibers having diameters below the diameter indicated.
The number of fibers in each yarnwhich is to be woven or interlaced with other yarns into a textile fabric should have at least about 70 and preferably more than about 100 fibers. Of course, when plying the yarns, it is the total number of fibers in the final yarn which is important.
In fabricating these yarns composed of a multiplicity of glass fibers, we may use an adhesive or lubricant or sizing which increases the mass integrity of the group of fibers, and inhibits mutual scratching of the fibers and facilitates the handling, winding and unwinding of the yarn upon spools, and various other steps of the process. The sizing or coating material may be of any suitable type such as wax, oil varnish, shellac, cellulose products or derivatives, resins, plastics, gelatins, agar agar, starch, casein, paraflin, rubber, latex, acetate, aryl phosphate, tricresyl phosphate, halogenated hydrocarbons of both the allphatic or aromatic types, or the like.
If desired, the sizing or coating material may be removed after the fabrication, and other types of coating materials may be substituted in their place if desired. These latter are generally such substances as lubricants, as for example, light oil or the like. The glass fibers may also be dyed with any suitable substances to provide the proper color hues, shades or designs.
The present application is a continuation in part of our co-pending applications, Serial Number 704,028, filed December 26, 1933; Serial Number 82,293, filed May 28, 1936; and Serial Number 105,405, filed October 13, 1936, these applications illustrating and describing more fully the methods and apparatus which we may use in order to produce the fine fibers called for in the present application.
Other objects and advantages of the present invention will become apparent from the following description taken in conjunction with the drawings, in which:
Fig. 1 is an elevational diagrammatic view shown partly in section of an apparatus adapted to produce fine glass fibers by means of a gaseous blast, and form them into a sliver or yarn;
Fig. 2 is a fragmentary plan view of a portion of the device illustrated in Fig. 1 showing the fiber collecting means used for forming the sliver;
Fig. 3 is a diagrammatic elevational View illustrating another apparatus which may be used for producing long, fine fibers, particularly of the continuous fiber type, and forming them into a thread or yarn;
Fig. 4 is a diagrammatic elevational view of an 7 apparatus which may be used to coat the yarn with a suitable sizing or coating material;
Fig. 5 is a diagrammatic elevational view of a winding or spinning device adapted to twist the strands or slivers into twisted yarns or cables;
Fig. 6 is a diagrammatic perspective view of a loom adapted to interweavethe glass fibers into woven fabrics; Fig. '7 is a more or less diagrammatic perspective view of a cable yarn composed of yarns twisted in one direction, and which have themselves been intertwisted together in the opposite direction to produce a balanced cable yarn; I
Fig. 8 is a diagrammatic view of a braided tubular fabric composed of braided glass yarns; and Fig. 9 is a diagrammatic plan view of a knitted Iabric composed of glass yarns. The formula heretofore generally used in mechanics for deflection on central loading of a beam is:
deflectronwhere P is the load, 1 the length of span, E the modulus of elasticity and I the inertia, which for a rod section is 0.05d whered is the rod diameter. As this equation is applied I to a. glass fiber by bending it into a loop. and pulling the loop down to the point just before which it will break, the deflection is' equal to 1/". Substituting now in the above equation and combining constants, we have i which means that the circumference of the loop at breaking is proportional to the square of the fiber diameten. That means that the loopthat can be made from a fiber 1 unit in diameter will be A; as large as the loop that can be made from a fiber 2 units in diameter. These values, however, do not tell the complete story for the size of the loop is also a function of the tensile strength which increases markedly as the fiber becomes smaller so as to permit a still smaller loop to be drawn. It also happens that E increases slowly as the fiber is drawn smaller, thus making a further correction in the proper direction. Thus, we have found that the size of the loop that may be drawn, decreases with a decrease in the square of the fiber diameter, as a quadratic function of the diameter because of the increased tensile strength, andas some other less important function of the modulus of elasticity.
Another significant observation is that the open area of the loop decreases in turn as the square of the diameter of the loop. Since the area of the loop determines the yarn diameter over which the fibers of thetransverse yarns are bent, the area of this loop is extremely important in determining creasability of fabrics and knotability'of yarns.
We have also noted a marked acceleration in the tensile strength increase as the fibers are drawn below .0004 and particularly at or below .0002 inch. An equation which we submit for the relation between tensile strength and diameter is:
where Ts is the tensile strength in thousands of pounds per square inch and d is the diameter expressed in units of ten-thousandths inch.
The presence of this last term has not been known or appreciated heretofore.
The significance of the above equation may be stated in words as, the tensile strength of glass fibers is equal to the bulk strength of glass where fiaws are'numerous, plus the increase in strength due to the reduction of fiaws at the surface of the glass fiber, plus the increase in strength due to the decrease of fiaws in the body of the glass.
We also believe that the surface tension in the fibers at this extremely low diameter has an effect of maintaining the surface more perfect and more resistant to stresses.
As a result of the above considerations, we have discovered a critical value infiber diameters for producing successful weavable yarns. Moreover, when the fiber diameter is maintained below .0004 inch and preferably not more than about .0002 inch, the fibers may readily be twisted, flexed, and compounded into yarns comprising a multiplicity of fibers which are free from brashiness or skin irritation. Moreover, the fiber diameter should be maintained below the critical range if it is desired to produce yarns having a sufilcient number of individual fibers therein, that is, at least about '70 or preferably more than 100, and
yet produce a yarn which is not bulky but which is notably thin, flexible, pliable, and workable. The fabric is also relatively thin in spite of the large number of fibers composing the yarns.
Referring now more particularly to Figs. 1 and 2, a conventional glass furnace has been illustrated, having an electrically heated bushing 22, preferably composed of a platinum alloy or platinum metal, forming an outlet feeder having a plurality of individual orifices 23 arranged at the' lower end thereof for the emission of a plurality of glass streams. If it is desired, and it has been found practical to do so, the glass may be melted from cullet or batch material directly in the electrically heated bushing '22, thus dispensing with the furnace 20.
Spaced beneath the outlet orifices 23 is a blower 25 which is formed in two parts, separated by a slot 26through which the glass streams flow and are attenuated by gaseous blasts emanating from. a series of jets 21.
Below this blower a convenient distance is an endless foraminous surface 3 which may be in the form of a screen, mounted upon the rotating drum 3|, supported by spokes 32 and rotating upon the shaft 33. As the glass streams emerge from the bushing 22, they are attenuated into long, fine fibers'35 having the desired characteristics, and then are conveyed by the gaseous blast upon the foraminous surface 30 where they are arrested and collected into the form of a web 36. Baffles 31 may be adjustably placed on each side of the region of the surface 30 upon which the fibers collect, these bafiles 31 serving to conduct all of the fibers 35 to the proper region upon the surface 30 where they may be compactly collected into the form of the web 36. Underneath the surface 30 is a suction box 40, which communicates with a suitable suction blower or other suitable exhausting means 4 the suction box serving to withdraw the vehicular blast and facilitating the retention of the web 36 upon the surface 30 as it is being collected and drawn off into the form of a sliver or yarn 44.
The drum 3| is driven byany suitable means such as a motor which is mechanically connected to the drum 3| through the pulleys 46, the adjustable speed change box 41, and the belt 48.
After the fibers have been collected in the form of the web 36, they are drawn off in the general direction of travel of the screen or surface 30, although at a higher speed than the peripheral speed of the surface 30; and then drawn through a compacting device or trumpet 49 then through suitable folding devices such as the diablo-shaped rolls 50, which serve to compact the web and to fold in the loose edges and loose fibers which may otherwise project outwardly from the sliver M; then through the guide 5|; through the traverse 52 and then over the spool 53 into the form of a-package 54. The spool 53 is mounted upon a suitable drum or shaft 55 which is driven by the motor 56. The mechanical drive connection silver in which the individual fibers lie predominantly in a longitudinal direction parallel to the sliver, although incompletely parallel and being mutually intermatted with one another to form a coherent strong sliver which may be processed as desired, as, for example, by twisting, winding,
spinning, weaving, or the. like. These yarns or slivers may also be drafted into fine attenuated threads which may then be compounded into ply yarns, balanced yarns, and fine textile fabrics.
Referring now more particularly to Fig. 3, we
have diagrammatically illustrated an apparatus capable of producing a yarn or thread composed of a multiplici y of continuous glass filaments. The glass may be melted in a suitable glass furnace having a suitable bushing 6| at the lower end thereof to feed a multiplicity of glass streams through a series of outlet orifices 63. The glass streams are mechanically attenuated by means of a rotating spool over which the thread 66 formed by the grouping of the individual fibers together, is wound.
Spaced beneath the bushing 6| is a suitable blower 61, which also may be formed into two parts having a slot 68 therebetween through which the individual fibers '62 are drawn. The blower 61 serves to direct a blast of cooling gas such as air, or the like, through the jets 69 onto the individual fibers, chilling them within a short distance of the outlet orifices 63. The blasts emanating from the jets 69 also serve to induce a draft of cool atmosphericair over the top of the blower and down through the slots, whereby it tends to cool the glass as it emerges from the outlet orifices.
The individual fibers '62 may be grouped by means of a suitable device such as that formed by a V-shaped slot 13 having a pad 74 in the groove thereof, over which the fibers may be drawn into the thread 66. Arranged in conjunction with the pad 14 is a Lubricant reservoir 75 adapted to be filled with a suitable lubricant or sizing or coating material supply body 16. If the supply body 16 is composed of a thermoplastic substance, such as wax, asphalt, or the like, it may be heated by any suitable means such as the burner 11. I
When using a thermoplastic substance or one which requires evaporation in order to harden it over the thread, it may be desirable to expose the thread 66 over a relatively long distance applying heat or drying air to the same before winding upon the spool 65. Assisting in the'formation of a neat package which may be readily unwound from the spool 65, is a traverse I8. When winding the thread, however, at extremely high speed, such as 5 to 10 or even 20,000 feet per minute, the traverse may be dispensed with and the thread would directly upon the spool 65.
In producing fine long fibers by means of such an apparatus, we have found it important to maintain the temperature of the molten glass within the bushing 6| in a relatively high range. Temperatures ranging from about 2100 F. to about 2500 F. have been found suitable, depending, of course, upon the particular type of glass which is being melted and the degree of attenuation which is desired. From this relatively high temperature, which is generally in the neighborhood of about 2200 F. to 2400 F., the glass as it is drawn out of the outlet orifices and is attenuated, attains a relatively high speed, at least about several hundred feet per minute, and preferably more than about 1000 feet per minute, and for most economical results, more than about 5000 feet per minute.
The cooling blasts from the jets 88 serve to chill the glass and permit it to be sufiiciently viscous that it may be drawn down into an extremely fine fiber within an unusually small range below the orifices 63.- The glass instead of producing a viscous fiber which is gradually attenuated into a finer fiber, draws down directly from the molten glass into a fine fiber form where it is suddenly chilled into that form while it is still within about an inch or so from the outlet orifice.
The degree of attenuation to which these fibers may be subjected is extremely high, and it is possible to produce fibers having diameters of about .0002 inch more or less without difficulty. The diameters of the orifices 63 are also relatively small, and may be about .030 to about .060 inch in diameter, more or less, as desired.
The fibers produced by the methods illustrated in Figs. 1 and 2 and by the apparatus illustrated in Fig. 3, are not only extremely fine, but are also extremely long, and have strengths ranging in the order of magnitude of about 300,000 pounds per square inch as an. ordinary matter, and in certain instances, much higher and in the order of magnitude of about one million to three million pounds per square inch. These fibers are also extremely flexible and are substantially free from brash .or skin irritation.
The threads formed by these methods of production, may be processed through any of the usual textile machines to produce twisted yarns, ply yarns, cables, balanced yarns, and fabrics of any desired type such as knitted, interwoven, or braided fabrics, as brought out more fully hereinafter.
If it is desired to weave the slivers 40 directly into yarns without twisting the same, it has been found preferable to coat the same with a suitabe sizing, and for this purpose the apparatus illustrated in Fig. 4 may be used. The sliver 44 is drawn from the spool 53 over the guide rolls and then into the bath 8i of the sizing material within a tank or reservoir 82. For this purpose we have found that gelatin or other sizes mentioned hereinabove are satisfactory.
A roll 83 may be submerged in the bath 8| around which the sliver 44 is drawn. In order I to remove excess sizing or coating substance, coacting rolls 84 may be arranged over the container 82, these rolls serving as a wringer. If desired, the thread or sliver 44 may then be dried in a suitable heating chamber 85 which may be provided with burners or other suitable heating, means 86. From here the thread or silver 44 may be again wound upon a spool 81, with the assistance of the traverse 88.
The yarns formed by the mechanism shownin Fig. 3 or Figs. 1 and 2, or the sized yarns or threads produced by the apparatus in Fig. 4,
may be twisted, either singly or in groups, to
form twisted yarns. a conventional apparatus for this type of twisting has been shown in Fig. 5, in which one or more spools I00 may feed in the required number of threads IOI through an eye I02, around the rolls I03 forming a bite for the yarn, then through the eye I04, through .the drag I05, and then around the rotating spool I01. The drag I00 is mounted upon a traversing means I00 which serves to distribute and wind the thread I M uniformly over the spool I0I,to form a neat package. The spool I0I is rotated by any suitable means such as the belt I09.
The degree of twist induced by this apparatus may be relatively high if desired, as, for example 6 to 12 or more turns per inch; the degree of twist, of course, being dependent upon the diameters of thefibers and the number of fibers composing the individual threads which are being twisted. We have found'it possible to twist, on conventional twisting apparatus, strands composed of only a few fibers such as only 5 to 10 fibers or even less, these fibers having, however, diameters less than .0004 inch, and for best results, less than .0002 inch. V
By intertwisting the fibers into a twisted yarn form, with a suflicientiy high degree of twist, it is possible to overcome the inherent objection to glass fibers caused by their non-stretchability, or tendency not to elongate. Ordinarily the degree of stretch which any individual fiber may pos sess before breaking, is extremely small, and even for fine fibers, is seldom more than one or two, or at the most about 3 per cent. Owing to the inherent non-stretchability of the fibers, it has been found substantially impossible to weave them in a conventional loom. As such a warp of yarns composed of glass fibers is being fed into the warp of the loom, any stresses or vibrations caused by the loom cause the entire load to be borne by the tightest end; these loads being frequently sufficient to break an individual yarn or end, before the load can be distributed to the other ends in the warp. When the tightest end breaks, the load is transferred to the next tightest end which also does not have sufi'icient strength to carry the entire load, and it also breaks in turn before the load can be distributed among the several ends. However, we have discovered that by providing yarn having sufliciently fine fibers, which may be intertwisted a sufiiciently high degree, the yarns themselves may possess .a relatively high degree of elongation, in the order of magnitude of about 10 to 30 per cent before breakage. The degree of stretch, of course, in the twisted yarns is also dependent upon the sizes of the yarns compared to the fiber diameter; the smaller the yarns, the les being the elongation before breakage.
In this connection, it is to be noted that the yarns formed from the sliver's produced by the apparatus shown in Figs. 1 and-2, have an especially high degree of elongation and stretchability, owing to their particular structure. The fibers of these yarns are intermatted and interlaced with one another and are not in substantially complete parallelism and alignment as are the continuous filament yarns formed by the apparatus shown in Fig. 3. Owing to their inherent intermatted nature, these yarnsseem to possess a higher degree of yieldability, and when they are twisted into the form of a twisted yarn, the intermatted fibers of the yarn appear to yield and distribute the stresses and loads induced in the yarn throughout the yarn as a whole, thus angle.
substantially increasing the total strength and resistance of the yarn.
The twisted yarns produced by the winding apparatus shown in Fig. 5, may be intertwisted with one another to form balanced yarns, an example of which is illustrated in Fig. '7.
In Fig. 7 two original yarns IIO are intertwisted to the right for a suflicient number of turns as, for example, 6 to 12 turns an inch to produce the twisted ply yarns I I I, and then two of these twisted yarns I II are intertwisted to the left for the required number of turns, generally slightly more than half of the original degree of twist to form a balanced cable yarn II2. Balanced yarns or cables of other various types may be formed, such as two, three, or four-ply or various other types of ply yarns or cables, or the like.
Referring now more particularly to Fig. 6, we have diagrammatically illustrated a loom which may be used to weave threads or yarns composed of glass fibers. In weaving glass cloths, it is possible to use any desired construction 'such as plain weave, twill, or manifold others, and in doing so, it is possible to produce cloths having any degree of hardness which is desired. In other words, we are not limited in weaving glass cloths having the individual yarns of the warp or filler spaced apart from one another in order to provide suificient flexibility and pliability to the materials. On the contrary, it is possible to place the ends of the warp extremely close together, and to pack the filler yarns tightly into place. The resulting cloth will have excellent properties of flexibility, strength, foldability, and general resistance to wear.
In Fig. 6 we have shown the warp II4 wound upon the warping beam I I 5. From here the warp is trained over the whip roll I I6 which is preferably arranged in such a position that the indi-' vidual ends of the warp II4 make contact over a relatively wide are on the surface of the whip roll and are turned through a relatively wide We have found that this arrangement materially reduces the number of breaks in the. ends by permitting the whip roll to relieve the individual yarns of unusual stresses and enables the individual yarns to be held at a constant tension.
The remaining portions of the loom may be of the conventional type, and thus, may comprise the heddles II'l, operating to produce the shed into which a shuttle II8 travels, and cloth beam over which the woven fabric is wound.
In weaving glass cloths, we have discovered that the difliculty caused by the non-elongation of the individual glass yarns may be overcome by provid ing resilient coverings I20, composed of rubber or other suitable yielding material over the warp ing beam II5. A resilient cover I2I may also be provided over the whip roll IIS. By the use of this resilient material over the warping beam and the whip roll, and of the arrangement of the whip roll in relation to the warping beam whereby the warp is caused to turn through a substantial angle, it is possible to maintain an even tension on the individual yarns or ends between the heddles of the loom and the warping beam. Thus, as m'brations or pulsations are induced into the ends by the reciprocatory movements of the.
heddles, the whip roll H6 and the resilient cover therefor I2 I yield and take up a large portion of these vibrations. Any unusual stresses in the individual ends may also be relieved by the resilient cover I20 on the warping beam II5.
We have discovered that when suflicient yarn is wound upon the warping beam to weave an entire bolt of cloth, that is, when there are about eighty yards of yarn per end, the warp on the beam is of considerable diameter and consequent 1y possesses a suflicient resilience and yieldability of its own which may be called upon to relieve any unusual stresses in the individual ends. However, when the beam has run through nearly the entire weaving operation, and there is little warp left upon the beam, the resilient cover I20 is adapted to relieve any unusual stresses in the individual ends. Thus, by means of this novel construction of loom, it is possible toweave an entire bolt of cloth several yards in width, if desired, with substantially no breaks throughout the entire weaving operation.
Various other types of textile fabrics may also be made from our novel yarn or threads, another example of which is illustrated in Fig. 8 showing a braided article I25. This braided article is in tubular form although, of course, any other type or construction of braid may be used. When in tubular form, it has particular application as a wire covering or other covering means. The braiding operations may be performed by any conventional textile machine now in use.
Another example of a textile fabric which we may make using our novel glass yarns, is illustrated in Fig. 9 showing a knitted fabric I26. The knitting may be done on any conventional machine, and may be made with any desired con struction. We have found it possible to weave directly from glass yarns, various articles such as socks, gloves, sweaters or the like. The knitted articles may be knitted with a tight construction, if desired, and we have found that such fabrics possess an extremely high flexibility, resilience and stretchability; although when pulled out of shape, they will return to their normal position after the stresses are relieved.
Modifications and variations may be resorted to without departing from the spirit and scope of the present invention as defined in the appended claims.
We claim:
1. A textile yarn composed of at least forty fine glass fibers having average diameters not more than about .0004 inch, the fibers of said yarn being twisted in order to produce a yarn of substantial flexibility, mass integrity, strength and stretchability to permit knotting without rupturing said yarn.
2. A glass textile fabric comprising. interlaced textile yarns as called for in claim 1.
3. A textile yarn composed of at least forty fine glass fibers having diameters not more than about .0003 inch, the fibers of said yarn being intertwisted in order to produce a yarn of substantial flexibility, mass integrity, strength and stretchability to permit said yarn to be folded over itself without rupturing said yarn.
I 4. A flexible, closely woven textile fabric capable of being folded and creased without fracture, which comprises interwoven yarns as claimed in claim 3. v
5. A textile yarn composed of a multiplicity of fine glass fibers lying predominately parallel to the longitudinal direction of said yarn and being intermatted with one another in said yarn, the
fibers of said yarn having diameters not more than about .0004 inch, and said yarn being twisted able 0! being folded and creased without fracture, which comprises interwoven yarns each composed of va multiplicity of intertwisted fine glass of at least seventy fine glass fibers having diam- V eters not more than about .0002 inch, the fibers of said yarn being intertwisted to produce a yarn of substantial flexibility, mass integrity, strength and stretchability to permit said yarn to be folded over and wrapped around itseltwithout rupturing 5 said yarn.
GAMES SLAYI'ER. JOHN H. THOMAS.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US149672A US2133238A (en) | 1937-06-22 | 1937-06-22 | Glass fabric |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US149672A US2133238A (en) | 1937-06-22 | 1937-06-22 | Glass fabric |
Publications (1)
Publication Number | Publication Date |
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US2133238A true US2133238A (en) | 1938-10-11 |
Family
ID=22531318
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US149672A Expired - Lifetime US2133238A (en) | 1937-06-22 | 1937-06-22 | Glass fabric |
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US (1) | US2133238A (en) |
Cited By (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2415683A (en) * | 1939-08-31 | 1947-02-11 | Folco Angelo Vincenzo | Treatment of glass-covered electric conductros |
US2428325A (en) * | 1942-10-30 | 1947-09-30 | Owens Corning Fiberglass Corp | Reinforced plywood |
US2428302A (en) * | 1943-04-09 | 1947-09-30 | Owens Corning Fiberglass Corp | Colored glass fiber product |
US2428591A (en) * | 1943-12-08 | 1947-10-07 | Owens Corning Fiberglass Corp | Insulating fabric |
US2439645A (en) * | 1944-09-12 | 1948-04-13 | Jr Wright Bolton | Preparation of multiend yarn packages |
US2457775A (en) * | 1943-10-27 | 1948-12-28 | Owens Corning Fiberglass Corp | Manufacture of glass fibers |
US2460899A (en) * | 1944-08-30 | 1949-02-08 | Johns Manville | Method of mat formation |
US2477407A (en) * | 1943-04-22 | 1949-07-26 | Owens Corning Fiberglass Corp | Reinforced plastics of increased strength |
US2489243A (en) * | 1944-04-27 | 1949-11-22 | Owens Corning Fiberglass Corp | Method and apparatus for making fine glass fibers |
US2531571A (en) * | 1945-04-21 | 1950-11-28 | Owens Corning Fiberglass Corp | Manufacture of glass yarn |
US2545869A (en) * | 1948-02-17 | 1951-03-20 | Plax Corp | Multiple fiber strand |
US2582919A (en) * | 1946-08-28 | 1952-01-15 | Owens Corning Fiberglass Corp | Coloring glass fibers |
US2607167A (en) * | 1948-04-01 | 1952-08-19 | Owens Corning Fiberglass Corp | Method and apparatus for making glass fiber textile slivers |
US2623549A (en) * | 1949-04-21 | 1952-12-30 | Research Corp | Radiant-energy-opaque fabric |
US2706377A (en) * | 1951-04-28 | 1955-04-19 | Owens Corning Fiberglass Corp | Twine and method of manufacture thereof |
US2743572A (en) * | 1951-09-11 | 1956-05-01 | Textile Machinery Corp | Textile yarn producing apparatus |
US2747335A (en) * | 1951-04-18 | 1956-05-29 | Int Harvester Co | Glass fiber drawing mechanism |
US2753677A (en) * | 1950-05-31 | 1956-07-10 | Owens Corning Fiberglass Corp | Method and apparatus for making cordage and twine |
US2773297A (en) * | 1951-08-30 | 1956-12-11 | Louis M Cotchett | Process and apparatus for making yarn and fabric |
US2775860A (en) * | 1951-03-28 | 1957-01-01 | Owens Corning Fiberglass Corp | Twine |
US2780909A (en) * | 1953-03-24 | 1957-02-12 | Owens Corning Fiberglass Corp | Method of forming yarns from staple glass fibers |
US2849333A (en) * | 1954-01-08 | 1958-08-26 | Owens Corning Fiberglass Corp | Method of dyeing tightly wound glass fibers sized with a water swellable material |
US2867891A (en) * | 1954-03-11 | 1959-01-13 | Owens Corning Fiberglass Corp | Process for manufacture of coated filamentary material |
US2881732A (en) * | 1954-05-19 | 1959-04-14 | Pittsburgh Plate Glass Co | Apparatus for coating glass fiber strand |
US2885257A (en) * | 1951-04-18 | 1959-05-05 | Filament drawing mechanism | |
US2961821A (en) * | 1956-12-07 | 1960-11-29 | Owens Corning Fiberglass Corp | Apparatus for manufacturing bonded fibrous glass slivers |
US3029589A (en) * | 1958-12-30 | 1962-04-17 | Owens Corning Fiberglass Corp | Extensible fibrous glass textile strand and method of producing same |
US3348368A (en) * | 1964-07-23 | 1967-10-24 | Leesona Corp | Method and apparatus for processing glass yarn |
US3900302A (en) * | 1972-08-10 | 1975-08-19 | Owens Corning Fiberglass Corp | Method for producing glass fiber bulk product |
US3999971A (en) * | 1974-11-07 | 1976-12-28 | Ppg Industries, Inc. | Apparatus for producing crimped fiber glass strand |
US4029623A (en) * | 1974-10-07 | 1977-06-14 | Ppg Industries, Inc. | Glass fiber sizing compositions for the reinforcement of resin matrices |
US4038243A (en) * | 1975-08-20 | 1977-07-26 | Ppg Industries, Inc. | Glass fiber sizing compositions for the reinforcement of resin matrices |
US4237685A (en) * | 1979-03-29 | 1980-12-09 | Owens-Corning Fiberglas Corporation | Apparatus for producing a yarn |
US5405895A (en) * | 1992-07-30 | 1995-04-11 | Industrial Technology Research Institute | Surface treating compositions and methods of preparation and use in treating long glass fibers |
-
1937
- 1937-06-22 US US149672A patent/US2133238A/en not_active Expired - Lifetime
Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2415683A (en) * | 1939-08-31 | 1947-02-11 | Folco Angelo Vincenzo | Treatment of glass-covered electric conductros |
US2428325A (en) * | 1942-10-30 | 1947-09-30 | Owens Corning Fiberglass Corp | Reinforced plywood |
US2428302A (en) * | 1943-04-09 | 1947-09-30 | Owens Corning Fiberglass Corp | Colored glass fiber product |
US2477407A (en) * | 1943-04-22 | 1949-07-26 | Owens Corning Fiberglass Corp | Reinforced plastics of increased strength |
US2457775A (en) * | 1943-10-27 | 1948-12-28 | Owens Corning Fiberglass Corp | Manufacture of glass fibers |
US2428591A (en) * | 1943-12-08 | 1947-10-07 | Owens Corning Fiberglass Corp | Insulating fabric |
US2489243A (en) * | 1944-04-27 | 1949-11-22 | Owens Corning Fiberglass Corp | Method and apparatus for making fine glass fibers |
US2460899A (en) * | 1944-08-30 | 1949-02-08 | Johns Manville | Method of mat formation |
US2439645A (en) * | 1944-09-12 | 1948-04-13 | Jr Wright Bolton | Preparation of multiend yarn packages |
US2531571A (en) * | 1945-04-21 | 1950-11-28 | Owens Corning Fiberglass Corp | Manufacture of glass yarn |
US2582919A (en) * | 1946-08-28 | 1952-01-15 | Owens Corning Fiberglass Corp | Coloring glass fibers |
US2545869A (en) * | 1948-02-17 | 1951-03-20 | Plax Corp | Multiple fiber strand |
US2607167A (en) * | 1948-04-01 | 1952-08-19 | Owens Corning Fiberglass Corp | Method and apparatus for making glass fiber textile slivers |
US2623549A (en) * | 1949-04-21 | 1952-12-30 | Research Corp | Radiant-energy-opaque fabric |
US2753677A (en) * | 1950-05-31 | 1956-07-10 | Owens Corning Fiberglass Corp | Method and apparatus for making cordage and twine |
US2775860A (en) * | 1951-03-28 | 1957-01-01 | Owens Corning Fiberglass Corp | Twine |
US2885257A (en) * | 1951-04-18 | 1959-05-05 | Filament drawing mechanism | |
US2747335A (en) * | 1951-04-18 | 1956-05-29 | Int Harvester Co | Glass fiber drawing mechanism |
US2706377A (en) * | 1951-04-28 | 1955-04-19 | Owens Corning Fiberglass Corp | Twine and method of manufacture thereof |
US2773297A (en) * | 1951-08-30 | 1956-12-11 | Louis M Cotchett | Process and apparatus for making yarn and fabric |
US2743573A (en) * | 1951-09-11 | 1956-05-01 | Textile Machinery Corp | Methods of production of textile yarns |
US2743572A (en) * | 1951-09-11 | 1956-05-01 | Textile Machinery Corp | Textile yarn producing apparatus |
US2780909A (en) * | 1953-03-24 | 1957-02-12 | Owens Corning Fiberglass Corp | Method of forming yarns from staple glass fibers |
US2849333A (en) * | 1954-01-08 | 1958-08-26 | Owens Corning Fiberglass Corp | Method of dyeing tightly wound glass fibers sized with a water swellable material |
US2867891A (en) * | 1954-03-11 | 1959-01-13 | Owens Corning Fiberglass Corp | Process for manufacture of coated filamentary material |
US2881732A (en) * | 1954-05-19 | 1959-04-14 | Pittsburgh Plate Glass Co | Apparatus for coating glass fiber strand |
US2961821A (en) * | 1956-12-07 | 1960-11-29 | Owens Corning Fiberglass Corp | Apparatus for manufacturing bonded fibrous glass slivers |
US3029589A (en) * | 1958-12-30 | 1962-04-17 | Owens Corning Fiberglass Corp | Extensible fibrous glass textile strand and method of producing same |
US3029590A (en) * | 1958-12-30 | 1962-04-17 | Owens Corning Fiberglass Corp | Extensible fibrous glass textile strand structure and method of making same |
US3348368A (en) * | 1964-07-23 | 1967-10-24 | Leesona Corp | Method and apparatus for processing glass yarn |
US3900302A (en) * | 1972-08-10 | 1975-08-19 | Owens Corning Fiberglass Corp | Method for producing glass fiber bulk product |
US4029623A (en) * | 1974-10-07 | 1977-06-14 | Ppg Industries, Inc. | Glass fiber sizing compositions for the reinforcement of resin matrices |
US3999971A (en) * | 1974-11-07 | 1976-12-28 | Ppg Industries, Inc. | Apparatus for producing crimped fiber glass strand |
US4038243A (en) * | 1975-08-20 | 1977-07-26 | Ppg Industries, Inc. | Glass fiber sizing compositions for the reinforcement of resin matrices |
US4237685A (en) * | 1979-03-29 | 1980-12-09 | Owens-Corning Fiberglas Corporation | Apparatus for producing a yarn |
US5405895A (en) * | 1992-07-30 | 1995-04-11 | Industrial Technology Research Institute | Surface treating compositions and methods of preparation and use in treating long glass fibers |
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