US2061686A - Method of treating cotton fabric and product - Google Patents

Method of treating cotton fabric and product Download PDF

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Publication number
US2061686A
US2061686A US689433A US68943333A US2061686A US 2061686 A US2061686 A US 2061686A US 689433 A US689433 A US 689433A US 68943333 A US68943333 A US 68943333A US 2061686 A US2061686 A US 2061686A
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United States
Prior art keywords
product
cotton fabric
cellulose
treating cotton
fabric
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US689433A
Inventor
Clarence B White
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wm E Hooper & Sons Co
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Wm E Hooper & Sons Co
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Publication date
Application filed by Wm E Hooper & Sons Co filed Critical Wm E Hooper & Sons Co
Priority to US689433A priority Critical patent/US2061686A/en
Application granted granted Critical
Publication of US2061686A publication Critical patent/US2061686A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/52Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with selenium, tellurium, polonium or their compounds; with sulfur, dithionites or compounds containing sulfur and halogens, with or without oxygen; by sulfohalogenation with chlorosulfonic acid; by sulfohalogenation with a mixture of sulfur dioxide and free halogens
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/62Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines

Definitions

  • the invention relates to a method of treating cotton fabric to form a film of cellulose covering and lying in the surface of part or all of the strands or fibers and to the fabric including this film of cellulose.
  • cuprammonium solution the accepted symbol of which is Clll'NHsH has been well known and quite extensively practiced for many years. form in and near the surface of the cloth or surrounding the exposed strands or fibers, a filament which is the result of the combination of the cuprammonium with the cellulose at and near the surface of the exposed fibers.
  • the object of the invention is to remove the copper without removing or degrading the quality of the cellulose film.
  • the fabric treated with cuprammonium as described has in the past been treated with acid to remove the copper, but this has the effect of changing the cellulose film Which is left, to hydro-cellulose which is lusterless and further not desirable because it is weak and easily destroyed and almost lacking in tenacity.
  • the copper is removed by the treatment of the fabric, which has been first treated with cuprammonium, with a solution of sodium hyposulphitethe symbol of which is Nazszos plus 51 120.
  • This solution is neutral so that it has no efiect on the fiber or cellulose film, but accomplishes a total and complete removal of the
  • This treatment is understood to' copper which enters into the solution and disappears, being, if desired, washed off or otherwise removed.
  • the exposed fibers of the cotton fabric retain after this treatment a film of transparent colorless cellulose which, in the absence of dye or other coloring matter, leaves the fabric white, or nearly so, and. of pleasing appearance closely resembling linen; and it is of particular importance that the fabric thus treated is nearly or quite waterproof, depending on the texture, also it sheds water and does not absorb it.
  • the method of treating cotton fiber to form a cellulose coating thereon which consists in first treating it with a solution of cuprammonium, dissolving a portion of the fiber and thus forming a film thereon containing cellulose and a copper compound and then removing the copper compound by treating the fiber with hyposulphite of soda solution.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Patented Nov. 24, 1936 PATENT OFFICE. I
METHOD OF TREATING COTTON FABRIC AND PRODUCT Clarence E. White, Montclair, N. J., assignor to Wm. E. Hooper & Sons Company, Baltimore, Md, a corporation of Maryland No Drawing. Application September 14, 1933, Serial No. 689,433
1 Claim. (01. 8-20) The invention relates to a method of treating cotton fabric to form a film of cellulose covering and lying in the surface of part or all of the strands or fibers and to the fabric including this film of cellulose.
The method of water proofing cotton cloth by treating it with cuprammonium solution, the accepted symbol of which is Clll'NHsH has been well known and quite extensively practiced for many years. form in and near the surface of the cloth or surrounding the exposed strands or fibers, a filament which is the result of the combination of the cuprammonium with the cellulose at and near the surface of the exposed fibers.
The object of the invention is to remove the copper without removing or degrading the quality of the cellulose film. The fabric treated with cuprammonium as described has in the past been treated with acid to remove the copper, but this has the effect of changing the cellulose film Which is left, to hydro-cellulose which is lusterless and further not desirable because it is weak and easily destroyed and almost lacking in tenacity.
In accordance with the practice of the invention, the copper is removed by the treatment of the fabric, which has been first treated with cuprammonium, with a solution of sodium hyposulphitethe symbol of which is Nazszos plus 51 120. This solution is neutral so that it has no efiect on the fiber or cellulose film, but accomplishes a total and complete removal of the This treatment is understood to' copper which enters into the solution and disappears, being, if desired, washed off or otherwise removed.
The exposed fibers of the cotton fabric retain after this treatment a film of transparent colorless cellulose which, in the absence of dye or other coloring matter, leaves the fabric white, or nearly so, and. of pleasing appearance closely resembling linen; and it is of particular importance that the fabric thus treated is nearly or quite waterproof, depending on the texture, also it sheds water and does not absorb it. I have thus described the method and product of my invention, the description being specific and in detail, in order that the method of practicing the invention and the nature of the resulting product may be clearly understood. However, the specific terms herein are used in a descriptive rather than in a limiting sense, the scope of the invention being defined in the claim.
What I claim as new and desire to secure by Letters Patent is: v
The method of treating cotton fiber to form a cellulose coating thereon which consists in first treating it with a solution of cuprammonium, dissolving a portion of the fiber and thus forming a film thereon containing cellulose and a copper compound and then removing the copper compound by treating the fiber with hyposulphite of soda solution.
CLARENCE B. WHITE.
US689433A 1933-09-14 1933-09-14 Method of treating cotton fabric and product Expired - Lifetime US2061686A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US689433A US2061686A (en) 1933-09-14 1933-09-14 Method of treating cotton fabric and product

Applications Claiming Priority (1)

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US689433A US2061686A (en) 1933-09-14 1933-09-14 Method of treating cotton fabric and product

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US2061686A true US2061686A (en) 1936-11-24

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5743050A (en) * 1995-12-01 1998-04-28 Shibata; Tsutomu Training room serving also as bed room

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5743050A (en) * 1995-12-01 1998-04-28 Shibata; Tsutomu Training room serving also as bed room

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