US20220228804A1 - Method and system for low-temperature air separation - Google Patents
Method and system for low-temperature air separation Download PDFInfo
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- US20220228804A1 US20220228804A1 US17/615,411 US202017615411A US2022228804A1 US 20220228804 A1 US20220228804 A1 US 20220228804A1 US 202017615411 A US202017615411 A US 202017615411A US 2022228804 A1 US2022228804 A1 US 2022228804A1
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- 238000000926 separation method Methods 0.000 title claims abstract description 85
- 238000000034 method Methods 0.000 title claims abstract description 47
- 239000007788 liquid Substances 0.000 claims abstract description 150
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 118
- 229910052786 argon Inorganic materials 0.000 claims abstract description 66
- 239000012530 fluid Substances 0.000 claims abstract description 57
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000001301 oxygen Substances 0.000 claims abstract description 40
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 40
- 239000007789 gas Substances 0.000 claims description 130
- 238000001704 evaporation Methods 0.000 claims description 72
- 230000008020 evaporation Effects 0.000 claims description 65
- 238000001816 cooling Methods 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 25
- 230000008929 regeneration Effects 0.000 claims description 23
- 238000011069 regeneration method Methods 0.000 claims description 23
- 238000010992 reflux Methods 0.000 claims description 20
- 238000009833 condensation Methods 0.000 claims description 10
- 230000005494 condensation Effects 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 58
- 239000000463 material Substances 0.000 description 52
- 239000003570 air Substances 0.000 description 37
- 229910052757 nitrogen Inorganic materials 0.000 description 29
- 238000004519 manufacturing process Methods 0.000 description 12
- 230000008901 benefit Effects 0.000 description 9
- 238000001228 spectrum Methods 0.000 description 9
- 238000005057 refrigeration Methods 0.000 description 8
- 230000006835 compression Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000004781 supercooling Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012809 cooling fluid Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- DOTMOQHOJINYBL-UHFFFAOYSA-N molecular nitrogen;molecular oxygen Chemical compound N#N.O=O DOTMOQHOJINYBL-UHFFFAOYSA-N 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 238000009931 pascalization Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000005514 two-phase flow Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
- F25J3/04872—Vertical layout of cold equipments within in the cold box, e.g. columns, heat exchangers etc.
- F25J3/04878—Side by side arrangement of multiple vessels in a main column system, wherein the vessels are normally mounted one upon the other or forming different sections of the same column
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/08—Processes or apparatus using separation by rectification in a triple pressure main column system
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/10—Processes or apparatus using separation by rectification in a quadruple, or more, column or pressure system
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/90—Details relating to column internals, e.g. structured packing, gas or liquid distribution
- F25J2200/94—Details relating to the withdrawal point
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
- F25J2205/66—Regenerating the adsorption vessel, e.g. kind of reactivation gas
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/50—Oxygen
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/50—Oxygen or special cases, e.g. isotope-mixtures or low purity O2
- F25J2215/52—Oxygen production with multiple purity O2
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/50—Oxygen or special cases, e.g. isotope-mixtures or low purity O2
- F25J2215/56—Ultra high purity oxygen, i.e. generally more than 99,9% O2
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/52—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being oxygen enriched compared to air, e.g. "crude oxygen"
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/42—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being nitrogen
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
- F25J2240/28—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream the fluid being argon or crude argon
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
- F25J2240/44—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval the fluid being nitrogen
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/50—Processes or apparatus involving steps for recycling of process streams the recycled stream being oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2250/00—Details related to the use of reboiler-condensers
- F25J2250/02—Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2250/00—Details related to the use of reboiler-condensers
- F25J2250/20—Boiler-condenser with multiple exchanger cores in parallel or with multiple re-boiling or condensing streams
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/02—Internal refrigeration with liquid vaporising loop
Definitions
- the present invention relates to a method and a system for low-temperature air separation according to the preambles of the independent claims.
- Air-separation systems have rectification column systems, which, conventionally, can be designed, for example, as two-column systems—in particular, as traditional Linde double-column systems—but also as three-column or multi-column systems.
- rectification columns for extracting nitrogen and/or oxygen in the liquid and/or gaseous state i.e., the rectification columns for nitrogen-oxygen separation
- rectification columns for extracting further air components in particular, the noble gases krypton, xenon, and/or argon—can be provided.
- the terms, “rectification” and “distillation” as well as “column” and “tower” or terms composed therefrom are used synonymously.
- the rectification columns of the mentioned rectification column systems are operated at different pressure levels.
- Known double-column systems have what is known as a high-pressure column (also referred to as a pressure column, medium-pressure column, or lower column) and what is known as a low-pressure column (also referred to as an upper column).
- the high-pressure column is typically operated at a pressure level of 4 to 7 bar—in particular, ca. 5.3 bar.
- the low-pressure column is operated at a pressure level of typically 1 to 2 bar—in particular, ca. 1.4 bar. In certain cases, higher pressure levels can also be used in both rectification columns.
- the pressures indicated here and below are absolute pressures at the head of the respective columns indicated.
- liquid argon can be delivered and evaporated on-site, or gaseous argon can be extracted on-site.
- the delivery of liquid argon entails not only economic disadvantages (transport costs, transfer losses, cold losses during evaporation against ambient air), but also places high demands on the reliability of the logistics chain.
- ppb or ppm refer to the mole fraction.
- the aim of the present invention is therefore to specify a method and an air-separation system by means of which, in addition to relatively large quantities of high-purity, gaseous nitrogen at a pressure level significantly above atmospheric pressure, argon can also, advantageously, be provided.
- the present invention proposes a method and a system for low-temperature air separation, having the features of the independent claims.
- Preferred embodiments form the subject matter of the dependent claims and the following description.
- Liquids and gases can, in the terminology used herein, be rich or poor in one or more components, wherein “rich” can refer to a content of at least 75%, 90%, 95%, 99%, 99.5%, 99.9%, or 99.99%, and “poor” can refer to a content of at most 25%, 10%, 5%, 1%, 0.1%, or 0.01% on a molar, weight, or volume basis.
- the term, “predominantly,” may correspond to the definition of “rich.”
- Liquids and gases may also be enriched in or depleted of one or more components, wherein these terms refer to a content in a starting liquid or a starting gas from which the liquid or gas has been extracted.
- the liquid or the gas is “enriched” if it contains at least 1.1 times, 1.5 times, 2 times, 5 times, 10 times, 100 times, or 1,000 times the content, and “depleted” if it contains at most 0.9 times, 0.5 times, 0.1 times, 0.01 times, or 0.001 times the content of a corresponding component, relative to the starting liquid or the starting gas.
- oxygen oxygen
- nitrogen nitrogen
- argon this is also understood to mean a liquid or a gas which is rich in oxygen, nitrogen, or argon, but need not necessarily consist exclusively of it.
- pressure range and “temperature range,” to characterize pressures and temperatures, which means that corresponding pressures and temperatures in a corresponding system do not have to be used in the form of exact pressure or temperature values in order to realize the inventive concept.
- pressures and temperatures typically fall within certain ranges, which are, for example, ⁇ 1%, 5%, 10%, or 20% around an average.
- corresponding pressure ranges and temperature ranges can be in disjoint ranges or in ranges which overlap one another.
- pressure ranges include, for example, unavoidable or expected pressure losses.
- the values indicated here in bar relating to the pressure ranges are absolute pressures.
- expansion machines refer to typically known turboexpanders. These expansion machines can, in particular, also be coupled to compressors. These compressors can, in particular, be turbocompressors.
- turbocompressors A corresponding combination of turboexpander and turbocompressor is typically also referred to as a “turbine booster.”
- turbine booster the turboexpander and the turbocompressor are mechanically coupled, and the coupling can take place at the same rotational speed (for example, via a common shaft) or at different rotational speeds (for example, via a suitably geared transmission).
- compressor is used herein.
- a “cold compressor” refers to a compressor to which a fluid flow is supplied in a temperature range significantly below 0° C.—in particular, below ⁇ 50, ⁇ 75, or ⁇ 100° C., and as far as ⁇ 150 or ⁇ 200° C. A corresponding fluid flow is cooled, in particular, by means of a main heat exchanger (see below) to a temperature in this temperature range.
- a “main air compressor” is characterized in that it compresses all of the air supplied to the air-separation system and separated there. In contrast, only a portion of this air already previously compressed in the main air compressor is further compressed in one or more optionally-provided, further compressors—for example, post-compressors. Accordingly, the “main heat exchanger” of an air-separation system represents the heat exchanger in which at least the predominant portion of the air supplied to the air-separation system and separated there is cooled. This takes place at least in part in counterflow to material flows which are discharged from the air-separation system. In the language used herein, such “discharged” material flows or “products” are fluids which no longer participate in circuits within the system, but are permanently removed therefrom.
- a “heat exchanger” for use in the context of the present invention can be designed in a customary manner. It is used to transfer heat indirectly between at least two fluid flows conducted, for example, in counterflow to each other, e.g., a warm, compressed air flow and one or more cold fluid flows, or a cryogenic liquid air product and one or more warm or warmer, but optionally also cryogenic, fluid flows.
- a heat exchanger can be formed from one or more heat exchanger sections connected in parallel and/or serially, e.g., from one or more plate heat exchanger blocks. This is, for example, a plate fin heat exchanger.
- Such a heat exchanger has “passages” which are designed as fluid channels, separated from one another, with heat exchange surfaces and are combined in parallel and separated by other passages to form “passage groups.”
- the characteristic of a heat exchanger is that heat is exchanged in it between two mobile media at one point in time, viz., at least one fluid flow to be cooled and at least one fluid flow to be heated.
- a “condenser evaporator” refers to a heat exchanger in which a first, condensing fluid flow enters into indirect heat exchange with a second, evaporating fluid flow.
- Each condenser evaporator has a liquefaction chamber and an evaporation chamber.
- the liquefaction and evaporation chambers have liquefaction or evaporation passages. Condensation (liquefaction) of the first fluid flow is carried out in the liquefaction chamber, and evaporation of the second fluid flow in the evaporation chamber.
- the evaporation and liquefaction chambers are formed by groups of passages, which are in a heat-exchanging relationship with one another.
- a liquid flow or a two-phase flow is forced through the evaporation chamber by its own pressure and is partially or completely evaporated there.
- This pressure can be generated, for example, by a liquid column in the feed line to the evaporation chamber.
- the height of this liquid column here corresponds to the pressure loss in the evaporation chamber.
- the gas-liquid mixture emerging from the evaporation chamber, separated by phases is forwarded directly to the next method step or to a downstream device, and, in particular, is not introduced into a liquid bath of the condenser evaporator, from which the portion remaining liquid would be sucked in again.
- the relative spatial terms, “upper,” “lower,” “over,” “under,” “above,” “below,” “adjacent to,” “next to,” “vertical,” “horizontal,” etc., here refer to the spatial orientation of the rectification columns of an air-separation system or other components during normal operation.
- An arrangement of two components “one above the other” is understood here to mean that the upper end of the lower of the two components is located at a lower geodetic height than or the same geodetic height as the lower end of the upper of the two components, and the projections of the two apparatus parts overlap in a horizontal plane.
- the two components are arranged exactly one above the other, i.e., the axes of the two components run on the same vertical straight line.
- the axes of the two components need not lie exactly vertically one above the other, but can also be offset from one another—in particular if one of the two components, e.g., a rectification column or a column part of smaller diameter, is to have the same distance from the sheet-metal jacket of a cold box as another one of larger diameter.
- the present invention proposes a method for low-temperature air separation in which an air-separation system having a column system is used that has a first column, a second column, a third column, and a fourth column.
- the first to third columns emerge in particular from the addition of an additional column, operated at a higher pressure than the conventionally-present high-pressure column, to a traditional double-column system known from the prior art.
- the first column can in particular be provided to be structurally separate from the second and third columns, wherein the second and the third columns can in particular be part of a double column and can be in heat-exchanging connection with one another by means of a corresponding condenser evaporator—the so-called main condenser.
- the second and the third columns can in particular be part of a double column and can be in heat-exchanging connection with one another by means of a corresponding condenser evaporator—the so-called main condenser.
- main condenser the condenser evaporator
- an additional column can also be added to the second and third columns, which are designed as part of a double column, in a corresponding multiple-column system, or the second and third columns can be provided as separate columns.
- the aforementioned main condenser can be provided as an internal or external main condenser, as is known in principle from the prior art. When an internal main condenser is used, it is at least partially immersed in a sump liquid in the sump of the third column, and an overhead gas to be condensed from the second column is conducted through a condensation chamber of the main condenser.
- a first sump liquid is formed in the first column
- a second sump liquid is formed in the second column
- a third sump liquid is formed in the third column
- a fourth sump liquid is formed in the fourth column.
- the fourth column is used in the context of the present invention in particular for argon production or argon discharge from a gas mixture removed from the third column.
- the fourth column can in particular be a conventional crude-argon column of a known arrangement with crude- and pure-argon columns, but it can also be a modified-argon column from which argon in a pure state is removed below the head, without the use of an additional pure-argon column. Other variants are also possible within the scope of the present invention.
- the first column is operated in a first pressure range
- the second column is operated in a second pressure range below the first pressure range
- the third column is operated in a third pressure range below the second (and thus also the first) pressure range.
- the fourth column can in particular be operated in the third pressure range or in a pressure range slightly below it, which can in particular result from pressure losses over the lines connecting the third and fourth columns.
- the second sump liquid is formed with a higher oxygen content and a higher argon content than the first sump liquid
- the third sump liquid is formed with a higher oxygen content and a lower argon content than the second sump liquid.
- the higher argon content of the second sump liquid compared to that of the first sump liquid results from the different operating conditions—in particular, the different pressures used for operating the first and second columns—and from different compositions of material flows fed into the first and second columns.
- the lower argon content in the third column results in particular from the fact that an argon-enriched gas is removed from this third column, as explained below.
- the first oxygen content can be 28 to 40%, and in particular ca. 34%
- the second oxygen content can be ca. 45 to 65%, and in particular ca. 55%
- the third oxygen content can be ca. 99.0 to 99.9%, and in particular ca. 99.5%.
- the respective percentages relate to the molar content of oxygen in a corresponding component mixture.
- the third column is therefore used as a pure-oxygen column, and a corresponding pure-oxygen product can be withdrawn from said column.
- the first and the second sump liquids are typically not used as product, but are further prepared in the system.
- fluid is generally fed from the first column at least into the second column.
- the fluid fed from the first column into the second column can in particular comprise sump liquid of the first column, which is evaporated, expanded, and introduced into the second column.
- fluid can be fed from the first column into the second column and into the third column. Fluid from the second column is fed at least into the third column, fluid from the third column is fed at least into the fourth column, and fluid from the fourth column is fed at least into the third column.
- the transfer of corresponding fluid can also initially comprise the feeding into a condenser evaporator or its evaporation chamber, from which liquid and/or gaseous fractions are then transferred into the other column. Conducting fluid in this way thus also falls within the transfer of a fluid from one column into the other. The same also applies if a corresponding fluid is only partially transferred, e.g., if it is enriched with or depleted of specific components, and/or divided into partial flows.
- the transferred fluids can comprise overhead gases, sump liquids, and/or side flows of corresponding columns.
- a “side flow” means a material flow which is withdrawn from a corresponding column between different separating trays or separating sections, whereas the overhead gas designates a gas mixture which is withdrawn from the column above the uppermost separating tray or separating region, and a sump liquid designates the liquid which is withdrawn from a corresponding column below the lowermost separating tray or separating region.
- a sump liquid is discharged in particular in the form of a liquid material flow, and an overhead gas is discharged in particular in the form of a gaseous material flow.
- liquid or gaseous material flows can also be withdrawn, for example, directly above the sump, but still below the lowermost separating section or the lowest separating tray.
- a side flow can be present in the liquid or gaseous state.
- a liquid side flow can be taken, for example, from a liquid retaining device or from an accumulation tray.
- the fluid fed from the third column into the fourth column comprises at least a portion of a side flow, which is withdrawn from the third column and has a lower oxygen content and a higher argon content than the third sump liquid.
- the side flow is withdrawn from the third column in particular in the region of the argon transition already explained above, but it can also be removed below the argon transition.
- a corresponding side flow is in particular a gas mixture which has a higher argon content than the sump liquid and a lower argon content than the overhead gas.
- An essential aspect of the present invention is that a reflux liquid is formed by condensing overhead gas of the first column, and that this reflux liquid is fed back to the first column in liquid form.
- the formation of the reflux liquid “using” the overhead gas can comprise, in particular, withdrawing overhead gas in gaseous form from the first column, at least partially liquefying it in a condenser evaporator, which is also explained in detail below, and feeding back a liquid fraction at least partially to the first column.
- a liquid cooling flow is evaporated or partially evaporated in indirect heat exchange with the overhead gas.
- Gas formed during the evaporation or partial evaporation of the cooling flow (any remaining liquid can be separated out in advance) is further, according to the invention, expanded, so as to perform work, to a pressure in the second pressure range, i.e., the operating pressure of the second column, and fed into the second column.
- the correspondingly expanded gas can be a portion of the gas formed during evaporation or partial evaporation, or even only a portion thereof.
- the liquid cooling flow can in particular be provided at a pressure in the first pressure range and expanded to a slightly lower pressure, e.g., in a region between the first pressure range and the second pressure range, before evaporation or partial evaporation - for example, by means of a valve.
- a further expansion after evaporation to a pressure in the second pressure range before feeding into the second column then takes place downstream of the evaporation in the aforementioned work-performing form.
- the present invention provides a method with lower energy consumption than previously developed methods. This applies in particular in comparison with known, so-called SPECTRA methods and variants thereof. However, the present invention can also be used in conjunction with such a SPECTRA method or a variant thereof, as explained in connection with FIG. 4 , for example.
- a SPECTRA method is known, for example, from EP 2 789 958 A1 and the patent literature cited therein. In the simplest form, this is a single-column method. However, a SPECTRA method can also be extended to oxygen and argon recovery, by providing further columns. SPECTRA methods enable a relatively high nitrogen yield.
- cryogenic liquid enriched in oxygen compared with atmospheric air
- the condenser evaporator which is used for cooling and condensing at least a fraction of the overhead gas of the same column.
- condensed overhead gas is at least partially fed back to the column from which it was previously withdrawn.
- the fluid to be evaporated can be conducted through the condenser evaporator in the form of only one material flow or in the form of two or more, separate, first material flows.
- Part of the correspondingly evaporated fluid is cold-compressed, i.e., compressed at a temperature level significantly below 0° C.—in particular, at a temperature level of ⁇ 50° C. or less—using one or more compressors and is then fed back into the column from which it was previously withdrawn.
- the one or more compressors can be coupled to one or more expansion machines—in particular, to one of two expansion machines arranged in parallel—and can at least partially be driven using the same. In the expansion machine or machines, a further portion of the evaporated fluid is expanded and discharged from the air-separation system.
- the present invention is based upon the finding that the potential of a generic method is not fully exploited without the measures proposed according to the invention.
- An indicator of this is or was a still relatively high temperature difference present in such generic methods in a condenser which condenses overhead gas of the first rectification column operating at the highest pressure.
- this condenser was designed, due to the requirements for the nitrogen product pressure and thus the first pressure level (for example, 11 bar; the feed air is correspondingly highly-compressed), as a bath condenser with a relatively high hydrostatic pressure loss of ca. 150-200 mbar and an average temperature difference of 2.5 K (or more).
- a relatively large amount of exergy is “lost” in a corresponding process, which is not the case within the scope of the present invention.
- a further issue (seen as a disadvantage) of alternative concepts not according to the invention, which are based upon a process topology differing from SPECTRA methods and having multiple rectification columns, is the injection, intended to generate refrigeration capacity, of air (ca. 10-15% of the quantity of feed air) into the second rectification column operating at medium pressure.
- the present invention proposes that a feed air flow into the second rectification column not (or at least not exclusively) be used to generate the process refrigeration capacity, but rather a flow evaporating in a condenser evaporator (overhead condenser) of the first rectification column, viz., the material flow referred to herein as the “cooling flow.”
- An essential aspect of the present invention consists, inter alia, in the exploitation of the differential pressure between the operating pressure of the second rectification column (i.e., the one corresponding to the second pressure range) and the evaporation pressure in the condenser used for condensing the overhead gas in order to generate the cold and to reduce the air “injection quantity” into the second rectification column.
- the condenser is therefore advantageously designed not as a bath condenser, but in particular as a forced-flow condenser with the lowest possible minimal temperature difference.
- the aforementioned cooling flow (which is expanded instead of air for refrigeration capacity) is, advantageously, thus formed using at least a fraction of the first sump liquid, and/or a forced-flow condenser evaporator is, advantageously, thus used for condensing the overhead gas of the first column and for evaporating the cooling flow.
- forced-flow condenser evaporator reference is expressly made to the above explanations.
- a further liquid cooling flow is, furthermore, evaporated or partially evaporated in indirect heat exchange with the overhead gas in order to condense the overhead gas of the first column, wherein the further cooling flow is withdrawn above the sump from the first column and is at least partially compressed after evaporation or partial evaporation and fed back to the first column.
- the compression of the evaporated, further cooling flow or a portion thereof takes place in particular in one or more compressors, which are mechanically coupled to one or more expansion machines and, in particular, are additionally braked.
- Compression takes place in particular at a temperature level below 0° C., and in particular below ⁇ 50° C., e.g., at ⁇ 100 to ⁇ 150° C.
- the one or more expansion machines compress, in particular, a remainder of the cooling flow formed from sump liquid of the first column, which is not compressed and fed back to the second column. This compressed remainder is compressed, in particular, to a pressure in the first pressure range and fed back to the first column.
- the aforementioned first pressure range is in particular 9 to 12 bar
- the second pressure range is in particular 4 to 6.5 bar
- the third pressure range is in particular 1 to 2 bar.
- the third pressure range can also be lowered further, and in particular by 50 to 200 mbar, for example, relative to the pressure value of 1.4 bar mentioned at the outset with respect to conventional air-separation systems.
- the second pressure range can also be lowered by 120 to 500 mbar—for example, relative to the aforementioned value of 5.3 bar.
- a corresponding decrease in pressure is possible, in particular, if, as explained below, gas from an evaporation chamber of a condenser evaporator, which condenses overhead gas of the fourth column, is used as regeneration gas.
- the driving temperature difference in this condenser evaporator is also reduced.
- the refrigeration capacity can be correspondingly increased by increasing the pressure difference between the first pressure range and the second pressure range or by decreasing the outlet pressure during expansion.
- the pressure data here each denote absolute pressures at the head of the columns.
- the first pressure range is thus above a pressure which is conventionally used for a high-pressure column in an air-separation system.
- the second column can in particular be operated at a lower pressure range than the high-pressure column conventionally used in an air-separation system. However, it can in principle also be the same pressure.
- the turbine output (process refrigeration capacity) achieved with the measures according to the invention is in particular sufficient for “gas” systems with a relatively small liquid production, e.g., in the case of a required nitrogen product pressure of 11 bar (which then also corresponds to the pressure in the first pressure range).
- a required nitrogen product pressure of 11 bar which then also corresponds to the pressure in the first pressure range.
- no further turbine is required.
- no injection of air into the second column or no bypass of the first column is required in this constellation.
- an additional turbine can nevertheless be used in an operating case with relatively high liquid production.
- a nitrogen-rich gas is in particular withdrawn as a product from the first rectification column, heated, and discharged from the system at a pressure in the first pressure range.
- a nitrogen product can be provided in a corresponding pressure range without further compression.
- an energy advantage of 5-6%, relative to the output of the main air compressor can be achieved, in comparison with the mentioned, likewise possible, expansion of feed air instead of the evaporated cooling flow, by increasing the yield of nitrogen product and the recovery of turbine output.
- This can correspond to a reduced energy consumption of, for example, ca. 500 kW and thus to a reduction in the TCO (Total Cost of Ownership) of more than 1 million EUR.
- TCO Total Cost of Ownership
- Due to the measures proposed according to the invention a smaller air feed quantity is required overall, which leads to a smaller “warm” system part.
- a smaller main heat exchanger (the kF value is ca. 6% lower with the same MTD value) can thus also be used. If a forced-flow condenser evaporator is used, combustible hydrocarbons are not enriched, due to the relatively high evaporation pressure (typically more than 7 bar).
- the present invention can provide different possibilities for controlling or not controlling the temperature of the cooling flow, each of which can offer certain advantages in terms of energy.
- the gas which is formed during the evaporation or partial evaporation of the cooling flow and expanded to perform work and fed into the second column, can be heated before expansion.
- the main heat exchanger of the air-separation system can be used for this purpose. In this way, feed flows can be cooled by means of corresponding refrigeration, and the heat exchanger profile can be adapted accordingly.
- the gas which is formed during the evaporation or partial evaporation of the cooling flow and expanded to perform work and fed into the second column, can also be supplied to the expansion at a temperature at which it is present after evaporation or partial evaporation; thus, no further temperature control takes place in this embodiment.
- the gas which is formed during evaporation or partial evaporation of the cooling flow and expanded to perform work and fed into the second column, can be fed into the second column at a temperature at which it is withdrawn from an expansion machine used for expansion. Alternatively, heating can also take place after expansion.
- overhead gas of the fourth column is condensed at least partially in a condensation chamber of a condenser evaporator, from the evaporation chamber of which a gas mixture is withdrawn.
- part of this gas mixture and/or also at least part of the residual gas from the upper region of the third column i.e., at least part of a gas mixture which is withdrawn from the third column
- a gas mixture which is withdrawn from the third column can be used to form a reflux flow and, in the process, heated, compressed, cooled, and fed into the second column.
- the main heat exchanger of the air-separation system in particular, can be used for heating and cooling the aforementioned reflux flow.
- a (further) portion of the gas mixture from the evaporation chamber of the condenser evaporator can also be used as regeneration gas for an adsorber in which feed air supplied to the column system is prepared. This can be done in particular at a corresponding evaporation pressure.
- the adsorber mentioned is operated in particular without the use of regeneration gas, which is withdrawn from the third column and fed to the adsorber in the same composition as there.
- gas from the upper region of the third column and gas from the lower region of this column can, for example, be combined and heated in the main heat exchanger as a common flow and used as regeneration gas.
- At least a portion of the gas mixture withdrawn from the evaporation chamber of the condenser evaporator is used as a first regeneration gas fraction
- at least a portion of the gas or of the mentioned gas mixture withdrawn from the third column is used as a second regeneration gas fraction.
- the second regeneration gas fraction in particular, is provided at a lower pressure than the first regeneration gas fraction, compressed, and combined with the first regeneration gas fraction before it is fed to the adsorber. Residual gas from the third column and gas from an overhead condenser of the argon column are thus combined.
- the embodiment just explained has, in particular, advantages when no refrigeration machine is used in pre-cooling, and the regeneration gas requirement is therefore comparatively high.
- the quantity of gas from the condenser evaporator can be insufficient as a regeneration gas quantity.
- a partial flow of the residual gas from the low-pressure column i.e., the third column
- the pressure difference is ca. 50 to 200 mbar
- the air inlet temperature in the molecular sieve i.e., the adsorber
- the hydrogen removal on the special layer with catalyst provided for this purpose in the adsorber
- the quantity of gas from the condenser evaporator may not suffice as the quantity of regeneration gas.
- a fraction of the first sump liquid is supplied to the evaporation chamber of the condenser evaporator, in the condensation chamber of which the overhead gas of the fourth column is at least partially condensed, and subjected to partial evaporation, wherein, with this partial evaporation, the aforementioned gas mixture is formed.
- an overhead condenser of a crude-argon column or of the single-argon column is therefore cooled using sump liquid of the first column. If a pure-argon column is present as a fifth column, its overhead condenser can also be cooled using corresponding sump liquid, as explained below.
- evaporated and unevaporated fractions of the sump liquid from the first column which were used in the condenser evaporator(s) of the fourth, or fourth and fifth, column(s) can then also be transferred at least partially into the third column (optionally, minus the fraction used in the adsorber), and in fact at a position corresponding to the oxygen content and argon content of these fluids.
- the evaporated and unevaporated fractions can therefore be fed into the third column at essentially the same point.
- Said material flows can be combined or transferred separately from one another into the third column.
- the fluid transferred from the first column into the third column thus comprises corresponding liquid, i.e., at least part of the first sump liquid which was used to cool the overhead condenser(s) of the fourth, or fourth and fifth, column(s).
- feeding evaporated fractions from the overhead condenser(s) can also be omitted, and these evaporated fractions are discharged from the method without feeding into the third column, as mentioned in the case of the reflux flow and the fraction used in the adsorber. With the unevaporated liquid, however, a portion of the first sump liquid is fed into the third column in this case as well.
- the fluid fed from the second column into the third column can comprise at least a portion of the second sump liquid, which is transferred from the second column into the third column without the use of a pump.
- corresponding sump liquid it is possible for corresponding sump liquid to be transferred to the third column solely owing to the pressure difference between the second and third columns.
- it can also be supercooled, beforehand or during transfer, against further flows, using a supercooling, counterflow heat exchanger.
- Overhead gas can be withdrawn from the first column at a defined withdrawal position and discharged from the air-separation system as a compressed nitrogen product in a corresponding pressure range.
- the present invention can be used in combination with a pure-argon column, i.e., a fifth column, into which fluid from the fourth column is transferred, wherein the fluid transferred from the fourth column has an argon content which is higher than in the gas mixture withdrawn from the third column and transferred at least in part into the fourth column.
- the fifth column is thus used to obtain a corresponding argon product, as is known in principle from the field of air-separation technology.
- overhead gas of the fifth column is condensed by means of a further condenser evaporator, in which a further fraction of the second sump liquid is subjected to partial evaporation.
- the side flow formed, in the context of the present invention, with a lower oxygen content and a higher argon content than the third sump liquid and withdrawn from the third column, can be subjected to preparation in a further column—in particular, to obtain an oxygen-depleted gas mixture and an oxygen-rich liquid—wherein the oxygen-depleted gas mixture can be fed from the further column at least in part into the fourth column. In this way, part of the side flow reaches the fourth column via the deviation of the further column.
- the further column is in particular formed in two parts and comprises two parts arranged one above the other, which are separated by a fluid-tight separating tray, wherein the oxygen-depleted gas mixture is withdrawn at least at the head of the upper part, but, optionally, also at the head of the lower part, and the oxygen-rich liquid is withdrawn from the sump of the lower part.
- the side flow from the third column is fed—in particular, in gaseous form—into a lower region of the upper part.
- liquid is withdrawn from the sump of the upper part and fed back to the third column.
- Sump liquid of the fourth column is, in particular, delivered as a reflux at the head of the upper part, but can also be delivered in part as a reflux to the lower part.
- the lower part fulfills the function of a (high-purity) oxygen column.
- Different embodiments are illustrated in the figures.
- the present invention also extends to an air-separation system, for the features of which reference is expressly made to the corresponding independent claim.
- an air-separation system is designed for carrying out a method as explained above in different embodiments, and in each case has means designed for this purpose.
- FIGS. 1 through 4 show air-separation systems, which correspond to embodiments of the present invention where they fall within the scope of protection of the patent claims, and otherwise relate to the technical background and/or embodiments not according to the invention.
- the air-separation systems according to FIGS. 1 through 4 are respectively designated as a whole by reference signs 100 through 400 .
- the air-separation system 500 illustrated in FIG. 5 is shown as a variant of the air-separation system 100 illustrated in FIG. 1 .
- the aspects illustrated here can nevertheless also be implemented by other systems—in particular, by systems 200 through 400 .
- the following explanations—in particular, regarding the system 100 according to FIG. 1 relate to the system 500 in the same way, even if this reference is not specifically made.
- All the air-separation systems 100 through 400 shown in FIGS. 1 through 4 are equipped with a column system which, irrespective of the different design and, optionally, different number of columns, is in each case designated overall by 10 .
- the column systems 10 each have a first column 11 , a second column 12 , a third column 13 , and a fourth column 14 .
- the second column 12 and the third column 13 are each designed as parts of a double column of a type known in principle. Reference is expressly made in this context to the technical literature cited at the outset regarding air-separation systems—in particular, to the explanations relating to FIG. 23A in Häring (see above), in which a corresponding double column is shown.
- the first column 11 is formed separately from the second column 12 and from the third column 13 .
- the first column 11 is equipped with a condenser evaporator 111 , which is used for condensing overhead gas of the first column 11 and is designed as a traditional overhead condenser in the embodiments according to FIGS. 1 through 3 .
- sump liquid which is conveyed without the use of a pump, is fed from the first column 11 into the condenser evaporator 111 , which is in each case designed as a forced-flow condenser evaporator in the examples shown.
- An essential aspect of the embodiments of the invention illustrated here is in each case that a reflux liquid is formed by condensing overhead gas of the first column 11 and that the reflux liquid is fed back to the first column 11 .
- a liquid cooling flow which is formed using the mentioned sump liquid from the first column 11 , is evaporated or partially evaporated with the overhead gas of the first column 11 .
- Gas formed during the evaporation or partial evaporation of the cooling flow is expanded, so as to perform work, by means of an expansion machine 5 to a pressure in the second pressure range and fed into the second column 12 .
- the second column 12 and the third column 13 are connected to each other, so as to exchange heat, via an internal condenser evaporator 121 —the so-called main condenser.
- the main condenser 121 is used, on the one hand, for condensing an overhead gas of the second column 12 and, on the other, for evaporating a sump liquid of the third column 13 .
- the second column 12 and the third column 13 can also be separate.
- the main condenser 121 can, alternatively, also be designed to be on the outside. Different types of condenser evaporators can be used as main condensers 121 .
- the fourth column 14 is used for argon production in all the air-separation systems 100 through 400 according to FIGS. 1 through 4 .
- no crude-argon column is present, but, rather, the systems 100 through 400 are each designed for withdrawal of an argon product from the fourth column 14 .
- the systems 100 through 400 are each designed for withdrawal of an argon product from the fourth column 14 .
- the fourth column is equipped with a condenser evaporator (overhead condenser) 141 which condenses overhead gas.
- a condenser evaporator (overhead condenser) 141 which condenses overhead gas.
- this is cooled with a portion of sump liquid from the first column 11
- sump liquid from the second column 12 is used for this purpose in the embodiment according to FIG. 4 .
- the sump liquid used in each case is previously supercooled by a supercooling, counterflow heat exchanger 18 .
- a fraction unevaporated in the overhead condenser 141 is at least partially fed into the third column 13 in the examples illustrated here.
- an evaporated fraction is used to regenerate an adsorber and, in the case of the air-separation system 300 according to FIG. 3 , to form a reflux flow, as explained below.
- a further column 15 is provided, in which a material exchange is carried out between a fraction of a sump flow from the fourth column 14 and a side flow from the third column 13 , and a fraction of the sump flow from the fourth column 14 is depleted of highly-volatile components.
- the further column 15 has an upper and a lower region, which are, functionally, completely separated from one another. Further details are explained in each case below.
- the further column 15 is designed with a condenser evaporator 152 which is heated with overhead gas from the second column 12 .
- a pump 19 is present in all the air-separation systems 100 through 300 according to FIGS. 1 through 3 and conveys the sump liquid back from the fourth column 14 into the further column 15 .
- a sump liquid is formed in the first column 11 and is referred to here as first sump liquid. Accordingly, a second sump liquid is formed in the second column 12 , a third sump liquid is formed in the third column 13 , and a fourth sump liquid is formed in the fourth column 14 .
- the first column 11 is operated in a first pressure range
- the second column 12 is operated in a second pressure range below the first pressure range
- the third column 13 is operated in a third pressure range below the second pressure range.
- the second sump liquid is formed with a higher oxygen content and a higher argon content than the first sump liquid
- the third sump liquid is formed with a higher oxygen content and a lower argon content than the second sump liquid.
- fluid is fed from the first column 11 into the second column 12 (and also into the third column 13 in the air-separation systems 100 through 300 according to FIGS. 1 through 3 ). Furthermore, fluid is fed from the second column 12 into the third column 13 , and fluid is fed from the fourth column 14 into the third column 13 .
- the fluid fed into the fourth column 14 from the third column 13 comprises at least a portion of a side flow which is withdrawn from the third column 13 and has a lower oxygen content and a higher argon content than the second sump liquid.
- the other fluids mentioned each comprise at least portions of the respective sump liquids. In all cases, direct feeding or feeding via an intermediate overhead condenser or the like and corresponding partial feeding can take place.
- FIG. 1 the air-separation system 100 according to FIG. 1 is first explained in more detail below.
- the explanations relating to the air-separation systems 200 , 300 , and 400 according to FIGS. 2 through 4 each relate only to the features deviating therefrom.
- identical features are also provided with corresponding reference symbols only in some cases.
- a feed air flow a from the atmosphere which is generally designated A here, is introduced by means of a main air compressor 1 via a filter, which is indicated by crosshatching and without a separate designation, cooled in an aftercooler, which likewise has no separate designation, and supplied to a direct-contact cooler 2 , which is operated with cooling water W.
- the feed air flow still designated a is freed of water and carbon dioxide in an adsorption device 3 in a manner described multiple times in the literature.
- the adsorption device 3 also generally referred to as an “adsorber” above, can be regenerated by means of a regeneration gas flow z. The formation of the regeneration gas flow z is explained below.
- the feed air flow which is still denoted by a, correspondingly treated, and thus purified, is fed to the warm side of a main heat exchanger 4 .
- the feed air flow a is withdrawn from the main heat exchanger 4 on the cold side or near its cold end and fed into the first column 11 .
- the sump liquid of the first column 11 is withdrawn therefrom and divided into two partial flows d and e in the air-separation systems 100 through 300 according to FIGS. 1 through 3 .
- the partial flow d is here fed into the condenser evaporator 111 and evaporated.
- the evaporated partial flow d is then partially heated in the main heat exchanger 4 and then expanded to the operating pressure of the second column 12 in an expansion machine 5 , which is coupled to a generator G, and fed into this second column 12 in a lower region.
- the treatment of the sump liquid in the air-separation system 400 according to FIG. 4 differs therefrom. Reference is made to the specific explanations below.
- the partial flow e is conducted through the supercooling, counterflow heat exchanger 18 and then through the condenser evaporator 141 .
- a portion can also be fed into the second column 12 .
- Gas formed in the overhead condenser 141 can be used as the aforementioned regeneration gas flow z.
- it is first heated in the supercooling, counterflow heat exchanger 18 and then in the main heat exchanger 4 .
- a fraction which remains liquid is fed into the third column 13 .
- no corresponding partial flow e or f is formed. Reference is also expressly made here to the specific explanations below.
- the overhead gas of the first column 11 is partially conducted through the condensation chamber of the overhead condenser 111 in the form of a material flow h and fed back to the first column 11 as a liquid reflux.
- a further fraction is heated in the form of a material flow i in the main heat exchanger 4 and, as a gaseous, compressed nitrogen product, discharged from the air-separation system 100 or used otherwise.
- the sump liquid of the second column 12 is withdrawn therefrom in the form of a material flow j, conducted through the supercooling, counterflow heat exchanger 18 , and fed into the third column 13 .
- the material flow j is conducted through the condenser evaporator 141 for cooling, as an alternative to the material flow e (see above).
- Gas formed in the overhead condenser 141 of the air-separation system 400 can also be used here as a regeneration gas flow, which is likewise designated z for the sake of simplicity.
- a regeneration gas flow which is likewise designated z for the sake of simplicity.
- gas is, furthermore, fed from the overhead condenser 141 or its evaporation chamber into the third column 13 .
- a fraction which remains liquid is fed into the third column 13 .
- the overhead gas of the second column 12 is partially conducted in the form of a material flow k through the condensation chamber of the main condenser 121 , liquefied there, and again fed back in part to the second column 12 as a liquid reflux.
- a further fraction is liquefied in the form of a material flow I in the condensation chamber of the condenser evaporator 152 .
- this further fraction is combined with the fraction liquefied in the condensation chamber of the main condenser 121 , as illustrated in the form of the linkage I.
- Corresponding liquid can also be delivered by means of a pump 6 as reflux to the first column 11 .
- the pump 6 conveys a liquid, nitrogen-rich flow b, which is withdrawn from the second column 12 in an upper region.
- a further fraction of overhead gas from the second column 12 is discharged from the system in the form of a material flow c.
- the liquefied fraction of the material flow k and of the material flow I are not combined. Rather, in this case, fractions of the material flow k are delivered separately from one another to the second column 12 and the third column 13 after liquefaction. The material flow I is fed separately into the third column 13 .
- the sump liquid of the third column 13 is withdrawn from it in the form of a material flow o, pressurized in liquid form by means of an internal compression pump 7 , converted into the gaseous or critical state in the main heat exchanger 4 by heating, and discharged from the air-separation system 100 as a gaseous, compressed oxygen product or used otherwise.
- gas withdrawn above the sump from the third column 13 in the form of a material flow p is combined with residual gas from the third column 13 (see below) to form a collective flow q, which is subsequently heated in the main heat exchanger 4 and discharged from the air-separation system 100 or used otherwise.
- the overhead gas of the third column 13 is conducted through the supercooling, counterflow heat exchanger 18 in the form of a material flow r and, in the air-separation systems 100 through 300 according to FIGS. 1 through 3 , combined with the material flow o to form the collective flow q, as mentioned.
- a separate discharge takes place in the air-separation system 400 according to FIG. 4 .
- a side flow t is withdrawn in gaseous form from the third column 13 and first fed into an upper part of the further column 15 .
- a material flow u is fed back in liquid form from the upper part of the further column 15 into the third column 13 .
- a mass transfer with sump liquid from the fourth column 14 is carried out, which, in the air-separation systems 100 through 300 according to FIGS. 1 through 3 , is delivered in liquid form in the form of a material flow v into the upper and lower parts of the further column 15 .
- the material flow v is fed only into the upper part of the further column 15 .
- the further column 15 can, for example, also be arranged above the overhead condenser 111 of the first column 11 .
- Sump liquid from the lower part of the further column 15 is withdrawn in the form of a material flow x and, in the example shown, fed into a tank system T. If necessary, a material flow, also designated x for the sake of clarity, is withdrawn from the tank system T, evaporated in the main heat exchanger 4 , and discharged as a high-purity, gaseous oxygen product.
- Argon-rich liquid is withdrawn from the fourth column 14 in the form of a material flow y by means of a further internal compression pump 8 , pressurized in liquid form, converted to the gaseous or critical state in the main heat exchanger 4 by heating, and discharged from the air-separation system 100 as a gaseous, compressed argon product or used otherwise.
- a corresponding tank system T′ is also illustrated in this context.
- Liquid nitrogen, liquid oxygen (optionally, also having different purities), and liquid argon can be provided as further products of the system 100 , as is known in principle and shown, for example, in the form of a partial flow of the liquefied overhead gas h of the first column 11 .
- a liquid nitrogen feed into the condenser evaporator 111 is also shown using a material flow h′.
- the air-separation system 200 illustrated in FIG. 2 and designed according to an embodiment of the invention differs from the air-separation system shown in FIG. 1 essentially in that the material flow d is not heated in the expansion machine 8 prior to its expansion.
- the air-separation system 300 illustrated in FIG. 3 differs from the air-separation system 200 shown in FIG. 2 essentially in that a division of the material flow z is carried out on the warm side of the main heat exchanger 4 , wherein a partial flow z′ of the material flow z is compressed by means of a compressor 9 , cooled in the main heat exchanger 4 , and fed into the second column 12 .
- the air-separation system 300 can otherwise also be the same as the air-separation system 100 illustrated in FIG. 1 .
- the air-separation system 400 shown in FIG. 4 illustrates the measures proposed according to the invention in connection with a SPECTRA process known per se.
- a further material flow d′ is withdrawn above the sump from the first column 11 and, like the material flow d, cooled again in the main heat exchanger 4 . Evaporation then takes place in the condenser evaporator 111 .
- the material flow d is, in the expansion machine 5 , which is coupled to a generator G, expanded in part and, as mentioned, fed into the second column 12 (see linkage D).
- the remainder of the material flow d is partially heated in the main heat exchanger 4 and then expanded in a further expansion machine 401 , which is coupled to a compressor 402 and a brake 403 . Discharge from the air-separation system 400 then takes place.
- a portion of the liquefied material flow h is discharged in liquid form and, optionally, supercooled against a portion of the same material flow in a supercooler 404 .
- the fraction used for supercooling can be combined with the expanded remainder of the material flow d.
- the material flow d′ is at least partially subjected to compression in the compressor 402 , cooled again in the main heat exchanger 4 , and fed back to the first column 11 .
- the air-separation system 500 shown in FIG. 5 is illustrated as a variant of the air-separation system 100 according to FIG. 4 . It is characterized in particular by the use of a blower 501 , by means of which a portion of the material flow q, here denoted by q′, is brought to the pressure of the material flow z and fed to the latter.
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US17/615,411 Pending US20220228804A1 (en) | 2019-06-04 | 2020-05-06 | Method and system for low-temperature air separation |
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US (1) | US20220228804A1 (de) |
EP (1) | EP3980705A1 (de) |
KR (1) | KR20220015406A (de) |
CN (1) | CN113874669A (de) |
TW (1) | TW202108222A (de) |
WO (1) | WO2020244801A1 (de) |
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US20240035743A1 (en) | 2022-08-01 | 2024-02-01 | Air Products And Chemicals, Inc. | Process and apparatus for recovery of at least nitrogen and argon |
US20240125550A1 (en) | 2022-10-18 | 2024-04-18 | Air Products And Chemicals, Inc. | Process and Apparatus for Improved Recovery of Argon |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20170234614A1 (en) * | 2014-07-31 | 2017-08-17 | Linde Aktiengesellschaft | Method for the cryogenic separation of air and air separation plant |
US20180017322A1 (en) * | 2016-07-12 | 2018-01-18 | Dimitri Golubev | Method and apparatus for producing compressed nitrogen and liquid nitrogen by cryogenic separation of air |
US20180023890A1 (en) * | 2015-02-19 | 2018-01-25 | Linde Aktiengesellschaft | Method And Apparatus For Obtaining A Compressed Nitrogen Product |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR610024A (fr) * | 1924-11-18 | 1926-08-28 | Procédé de liquéfaction et de séparation des mélanges gazeux, particulièrementde l'air | |
GB688550A (en) * | 1950-03-29 | 1953-03-11 | British Oxygen Co Ltd | Improvements in or relating to the low temperature separation of gas mixtures by rectification |
FR1496217A (fr) * | 1966-08-19 | 1967-09-29 | Air Liquide | Procédé de séparation et de purification d'un mélange gazeux riche en éthylène |
US4533375A (en) * | 1983-08-12 | 1985-08-06 | Erickson Donald C | Cryogenic air separation with cold argon recycle |
US4769055A (en) * | 1987-02-03 | 1988-09-06 | Erickson Donald C | Companded total condensation reboil cryogenic air separation |
US5098456A (en) * | 1990-06-27 | 1992-03-24 | Union Carbide Industrial Gases Technology Corporation | Cryogenic air separation system with dual feed air side condensers |
GB9414939D0 (en) * | 1994-07-25 | 1994-09-14 | Boc Group Plc | Air separation |
GB9513765D0 (en) * | 1995-07-06 | 1995-09-06 | Boc Group Plc | Production of argon |
GB9619687D0 (en) * | 1996-09-20 | 1996-11-06 | Boc Group Plc | Air separation |
US5966967A (en) * | 1998-01-22 | 1999-10-19 | Air Products And Chemicals, Inc. | Efficient process to produce oxygen |
EP2789958A1 (de) | 2013-04-10 | 2014-10-15 | Linde Aktiengesellschaft | Verfahren zur Tieftemperaturzerlegung von Luft und Luftzerlegungsanlage |
-
2020
- 2020-05-06 US US17/615,411 patent/US20220228804A1/en active Pending
- 2020-05-06 KR KR1020217039883A patent/KR20220015406A/ko unknown
- 2020-05-06 EP EP20727147.9A patent/EP3980705A1/de not_active Withdrawn
- 2020-05-06 CN CN202080038291.7A patent/CN113874669A/zh active Pending
- 2020-05-06 WO PCT/EP2020/025207 patent/WO2020244801A1/de unknown
- 2020-06-02 TW TW109118427A patent/TW202108222A/zh unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20170234614A1 (en) * | 2014-07-31 | 2017-08-17 | Linde Aktiengesellschaft | Method for the cryogenic separation of air and air separation plant |
US20180023890A1 (en) * | 2015-02-19 | 2018-01-25 | Linde Aktiengesellschaft | Method And Apparatus For Obtaining A Compressed Nitrogen Product |
US20180017322A1 (en) * | 2016-07-12 | 2018-01-18 | Dimitri Golubev | Method and apparatus for producing compressed nitrogen and liquid nitrogen by cryogenic separation of air |
Also Published As
Publication number | Publication date |
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EP3980705A1 (de) | 2022-04-13 |
WO2020244801A1 (de) | 2020-12-10 |
KR20220015406A (ko) | 2022-02-08 |
TW202108222A (zh) | 2021-03-01 |
CN113874669A (zh) | 2021-12-31 |
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