US20190078172A1 - High-strength thin steel sheet and manufacturing method therefor - Google Patents
High-strength thin steel sheet and manufacturing method therefor Download PDFInfo
- Publication number
- US20190078172A1 US20190078172A1 US16/083,725 US201716083725A US2019078172A1 US 20190078172 A1 US20190078172 A1 US 20190078172A1 US 201716083725 A US201716083725 A US 201716083725A US 2019078172 A1 US2019078172 A1 US 2019078172A1
- Authority
- US
- United States
- Prior art keywords
- steel sheet
- less
- thin steel
- strength thin
- hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 139
- 239000010959 steel Substances 0.000 title claims abstract description 139
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 37
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 41
- 229910001563 bainite Inorganic materials 0.000 claims abstract description 35
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 7
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 71
- 238000000137 annealing Methods 0.000 claims description 41
- 238000002791 soaking Methods 0.000 claims description 24
- 238000000576 coating method Methods 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 19
- 238000005246 galvanizing Methods 0.000 claims description 18
- 238000005097 cold rolling Methods 0.000 claims description 17
- 238000005244 galvannealing Methods 0.000 claims description 17
- 238000005098 hot rolling Methods 0.000 claims description 17
- 238000003618 dip coating Methods 0.000 claims description 16
- 238000005554 pickling Methods 0.000 claims description 16
- 238000009713 electroplating Methods 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 229910052758 niobium Inorganic materials 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 229910052715 tantalum Inorganic materials 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 description 37
- 238000010583 slow cooling Methods 0.000 description 33
- 238000005096 rolling process Methods 0.000 description 23
- 230000001965 increasing effect Effects 0.000 description 22
- 239000013078 crystal Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 17
- 230000003247 decreasing effect Effects 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- 230000009466 transformation Effects 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 10
- 238000003303 reheating Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000010960 cold rolled steel Substances 0.000 description 7
- 239000011701 zinc Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 238000005275 alloying Methods 0.000 description 4
- 238000005266 casting Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229910000734 martensite Inorganic materials 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910001335 Galvanized steel Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000008397 galvanized steel Substances 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000005255 carburizing Methods 0.000 description 2
- 229910001567 cementite Inorganic materials 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 241000219307 Atriplex rosea Species 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910000655 Killed steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000001887 electron backscatter diffraction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 231100000272 reduced body weight Toxicity 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention relates to a high-strength thin steel sheet that has a high yield ratio and excellent formability and that is best suited for, for example, body parts, such as an automobile pillar, side sill, and member; reinforcing parts therefor; and structural parts used for a door impact beam, a vending machine, a desk, electric appliances, office automation equipment, and construction materials, and to a manufacturing method therefor.
- body parts such as an automobile pillar, side sill, and member
- reinforcing parts therefor and structural parts used for a door impact beam, a vending machine, a desk, electric appliances, office automation equipment, and construction materials, and to a manufacturing method therefor.
- Patent Literature 1 discloses a hot-dip galvanized steel sheet manufactured by hot-rolling steel containing, in mass %, C: 0.07 to 0.25%, Mn: 1.5 to 2.5%, Nb: 0.10% or less, Ti: 0.3% or less, Si: 0.1% or less, Cr: 0.1% or less, P: 0.05% or less, sol.
- Al 0.010 to 0.100%, S: 0.01% or less, and N: 0.01% or less; pickling; cold-rolling; then annealing in a continuous hot-dip galvanizing line; and subsequently hot-dip galvanizing; where annealing in a temperature range of 750° C. or higher and 880° C. or lower is performed for 30 s or more and 90 s or less, and subsequently second annealing of holding in a temperature range of 515° C. to 600° C. for 15 s or more is performed either before or after, or both before and after the hot-dip galvanizing.
- Patent Literature 1 also discloses a high-strength high-yield-ratio hot-dip galvanized steel sheet, which is manufactured as described above so as to include a hot-dip galvanized coating or a galvannealed coating, having a tensile strength of 45 kg/mm 2 or higher and a yield ratio of 80% or higher.
- Patent Literature 2 discloses a technique of manufacturing a high-yield-ratio high-tensile-strength cold-rolled steel sheet with excellent formability including: heating to 1,150° C. or higher a steel slab containing, in mass %, C ⁇ 0.02%, Si ⁇ 0.3%, Mn: 0.5 to 2.0%, P ⁇ 0.06%, S ⁇ 0.005%, Al ⁇ 0.06%, N ⁇ 0.006%, and Ti: 0.15 to 0.40%; then hot-rolling at a finishing temperature of 880° C. or higher; coiling at a coiling temperature of 400° C. to 700° C.; pickling; cold-rolling; and subsequently annealing at 600° C. to 720° C. in a carburizing atmosphere.
- a component composition containing, in mass %, C: 0.02 to 0.10%, Si: 1.5% or less, Mn
- Patent Literature 4 discloses a technique of manufacturing a high-yield-ratio high-strength cold-rolled steel sheet having a yield ratio of higher than 0.70 and lower than 0.83 and a tensile strength of 780 MPa or higher and lower than 900 MPa and containing, in area fraction, 20 to 80% of any of crystal grains with an aspect ratio of 3 or higher oriented in a rolling direction, crystal grains with a grain size of less than 3 ⁇ m, and crystal grains with a grain size of less than 3 ⁇ m and an aspect ratio of 3 or higher oriented in the rolling direction.
- the steel sheet is manufactured by heating, to 1,130° C.
- a cast slab having a steel component containing, in mass %, C: more than 0.028 and less than 0.044%, Si: less than 0.8%, Mn: 1.9 to 2.3%, P: 0.001 to 0.035%, S 0.0001% to 0.013%, Al: 0.1% or less, N: 0.0001% to 0.008%, Ti: 0.012 to 0.029%, Nb: 0.029 to 0.042%, Mo: 0.05 to 0.25%, and B: 0.0008 to 0.0038%; then hot-rolling at a temperature equal to or higher than the Ar 3 transformation temperature; subsequently removing at a temperature of 750° C. or lower; then cold-rolling at a reduction of 35 to 85%; and subsequently continuously annealing at a maximum heating temperature in a temperature range of 740° C. or higher and 950° C. or lower.
- Patent Literature 1 requires an annealing temperature substantially exceeding 800° C.
- an annealing temperature needs to be elevated to 850° C. in order to manufacture a high-yield-ratio steel sheet with a yield ratio exceeding 0.90. Accordingly, there is a problem in which such a technique involves operational difficulties, such as increasing heating costs.
- Patent Literature 2 requires annealing at 600° C. to 720° C. in a carburizing atmosphere and further annealing at 840° C. or higher. Accordingly, there is a problem in which manufacturing costs are increased.
- Patent Literature 3 requires annealing at 840° C. or higher and thus involves a problem in which manufacturing costs are increased.
- Patent Literature 4 substantially requires an annealing temperature of 800° C. or higher, and the yield ratio is low at less than 0.83.
- an object according to aspects of the present invention is to provide a high-strength thin steel sheet having a high yield ratio and excellent formability and to provide a manufacturing method therefor.
- Dislocation tangling refers to a state in which a plurality of dislocations are concentrated in one location and such dislocations become difficult to move due to their interactions.
- a high-strength thin steel sheet having a component composition containing, in mass %, C: 0.04 to 0.25%, Si: 0.5 to 2.0%, Mn: 0.1 to 2.0%, P: 0.05% or less, S: 0.030% or less, Al: 0.10% or less, and N: 0.010% or less, with the balance being iron and incidental impurities; and having a microstructure containing, in area fraction, 90% or more of ferrite and bainite in total, where ferrite and bainite each have an aspect ratio of 3.0 or higher.
- a method of manufacturing a high-strength thin steel sheet comprising: hot-rolling a steel slab having the component composition according to any one of [1] to [7] at a finishing temperature of 800° C. or higher and at a coiling temperature of 400° C. or higher; pickling; then cold-rolling at a cold reduction of 30 to 80%; and subsequently annealing at a soaking temperature of 650° C. to 800° C. for a soaking time of 600 s or less.
- a method of manufacturing a high-strength thin steel sheet comprising: hot-rolling including finish rolling of a steel slab having the component composition according to any one of [1] to [7] at a finishing temperature of 800° C. or higher, followed by slow cooling at a start temperature of 550° C. to 750° C. and at an average cooling rate of less than 10° C./s for a slow cooling time of 1 to 10 s, and subsequent coiling; pickling; then cold-rolling at a cold reduction of 30 to 80%; and subsequently annealing at a soaking temperature of 650° C. to 800° C. for a soaking time of 600 s or less.
- a method of manufacturing a high-strength thin steel sheet comprising a coating process for the high-strength thin steel sheet according to any one of [1] to [7].
- a high-strength thin steel sheet refers to a steel sheet having a tensile strength (TS) of 440 MPa or higher.
- steel sheets include a cold-rolled steel sheet and a steel sheet prepared from a cold-rolled steel sheet through surface treatment, such as a hot-dip coating process, a hot-dip coating process followed by an alloying process, or an electroplating process. Further, such examples also include steel sheets having a coating formed, for example, by chemical conversion treatment of a cold-rolled steel sheet and a surface-treated steel sheet.
- a high yield ratio refers to a yield ratio (YP/TS) ⁇ 0.90. Further, good formability refers to TS ⁇ El ⁇ 10,000 MPa.
- a high-strength thin steel sheet having a high yield ratio and excellent formability is obtained.
- a high-strength thin steel sheet according to aspects of the present invention having a tensile strength of 440 MPa or higher can enhance ductility while maintaining a high yield ratio of the steel sheet. Accordingly, the high-strength thin steel sheet can suitably be used for applications, such as automobile structural parts, thereby providing industrially beneficial effects.
- FIG. 1 is a graph showing a relationship between yield ratio and total area fraction of ferrite and bainite.
- FIG. 2 is a graph showing a relationship between aspect ratio and yield ratio.
- FIG. 3 is a graph showing a relationship between Si content and formability (TS ⁇ El).
- % means mass % unless otherwise indicated.
- C contributes to increased strength of a steel sheet by dissolving in steel. C also contributes to increased strength of a steel sheet through formation of fine carbides and grain refinement of the microstructure. In order to obtain these effects, C content is set to 0.04% or more and preferably 0.07% or more. Meanwhile, a large amount of C promotes formation of martensite, thereby suppressing formation of ferrite and bainite and decreasing the yield ratio. Further, toughness and weldability are impaired. Accordingly, C content is set to 0.25% or less and preferably 0.20% or less.
- Si content is set to 0.5% or more, preferably 0.7% or more, and more preferably 1.0% or more.
- Si content is set to 2.0% or less and preferably 1.5% or less.
- Mn can contribute to increased strength of a steel sheet by solid solution strengthening and/or grain refining effects. Further, Mn can suppress the effect of S, which is an impurity element, by fixing S as MnS. In order to obtain such effects, Mn content is set to 0.1% or more, and preferably 0.3% or more. Meanwhile, a large amount of Mn hinders a coating process and promotes formation of martensite, thereby decreasing the yield ratio. Accordingly, Mn content is set to 2.0% or less, preferably 1.5% or less, and more preferably 1.0% or less.
- P segregates in grain boundaries, thereby impairing ductility and toughness. Further, weldability is also impaired by P. Accordingly, P content is set to 0.05% or less, preferably 0.03% or less, and more preferably 0.01% or less.
- S significantly decreases ductility of a steel sheet in hot rolling and thus induces hot cracking, thereby degrading surface quality considerably.
- S scarcely contributes to increased strength and rather decreases ductility and stretch flangeability through, as an impurity element, formation of coarse sulfides.
- weldability is also impaired by S. Since these problems become noticeable when S content exceeds 0.030%, S content is preferably decreased as much as possible. Accordingly, S content is set to 0.030% or less, preferably 0.010% or less, more preferably 0.003% or less, and further preferably 0.0.01% or less.
- Al content is set to 0.10% or less and preferably 0.06% or less. Although the lower limit is not particularly specified, no problem arises if 0.01% or more of Al is contained as Al-killed steel.
- N content is set to 0.010% or less, preferably 0.005% or less, more preferably 0.003% or less, and further preferably 0.002% or less.
- the balance is iron and incidental impurities.
- incidental impurities include Sn, Mg, Co, As, Pb, Zn, Ce, and O, and their total content of 0.5% or less is allowable.
- a steel sheet according to aspects of the present invention can realize intended characteristics by including the above-described essential alloying elements.
- the following elements may be added as appropriate in order to enhance strength, yield ratio, and formability.
- Ti, Nb, and V Each 0.01 to 1.0%
- Ti, Nb, and V each form fine carbides with C and contribute to increased strength of a steel sheet and an enhanced yield ratio of a steel sheet.
- the content of each of Ti, Nb, and V, if contained, is set to 0.01% or more, preferably 0.05% or more, and more preferably 0.10% or more.
- Mo, Ta, and W can contribute to increased strength of a steel sheet and/or an enhanced yield ratio of a steel sheet through formation of fine precipitates.
- the content of each of Mo, Ta, and W, if contained, is set to 0.005% or more and preferably 0.10% or more. Meanwhile, even if Mo, Ta, and/or W are contained in a large amount, not only do the effects level off, but also, costs are increased. Accordingly, each of Mo, Ta, and W, if contained, is set to 1.0% or less and preferably 0.5% or less.
- each of Cr, Ni, and Cu can contribute to increased strength and an enhanced yield ratio of a steel sheet through grain refinement of the microstructure.
- the content of each of Cr, Ni, and Cu, if contained, is set to 0.01% or more, preferably 0.1% or more, and more preferably 0.3% or more. Meanwhile, even if Cr, Ni, and/or Cu are contained in a large amount, not only do the effects level off, but also, costs are increased. Accordingly, each of Cr, Ni, and Cu, if contained, is set to 1.0% or less and preferably 0.5% or less.
- B contributes to increased strength of a steel sheet and an enhanced yield ratio of a steel sheet by promoting grain refinement of the microstructure and/or bainite transformation.
- B if contained, is set to 0.0002% or more, preferably 0.0005% or more, and more preferably 0.0010% or more. Meanwhile, a large amount of B not only complicates rolling due to increased deformation resistance of a steel sheet during hot rolling, but also causes decreased ductility. Accordingly, B, if contained, is set to 0.0050% or less, preferably 0.0030% or less, and more preferably 0.0020% or less.
- Ca and REM can enhance ductility and/or stretch flangeability by controlling the morphology of sulfides.
- the content of each of Ca and REM, if contained is set to be 0.0005% or more. Meanwhile, even if Ca and/or REM are contained in a large amount, not only do the effects level off, but also, costs are increased. Accordingly, each of Ca and REM, if contained, is set to be 0.01% or less.
- Sb segregates on a slab surface during heating of a slab, nitriding of the slab can be prevented. Consequently, ductility of a steel sheet can be enhanced through suppressed formation of coarse nitrides.
- Sb, if contained, is set to 0.005% or more. Meanwhile, addition of Sb in a large amount leads to increased costs. Accordingly, Sb, if contained, is set to 0.050% or less.
- Ferrite and bainite are the important microstructure for achieving high ductility. Accordingly, an area fraction of ferrite and bainite in total is set to 90% or more, preferably 95% or more, more preferably 98% or more, and further preferably 100%. Individual fractions of ferrite and bainite are not specified. It is preferable, however, that the fraction of ferrite is larger. The fraction of ferrite in the entire microstructure is, in area fraction, preferably 90% or more and more preferably 100%. As the microstructure other than ferrite and bainite, pearlite, martensite, retained austenite, and/or cementite, for example, may be contained in each 5% or less and 10% or less in total, if contained.
- the total area fraction of ferrite and bainite can be measured according to a method described in the Examples section hereinafter.
- C amount, Mn amount, and/or manufacturing conditions, especially a coiling temperature 90% or more of an area fraction of ferrite and bainite in total can be achieved.
- the aspect ratio for crystal grains of ferrite and bainite By raising the aspect ratio for crystal grains of ferrite and bainite, the strength of a steel sheet and a yield ratio of a steel sheet can be increased. Accordingly, the aspect ratio is set to 3.0 or higher, preferably 4.0 or higher, and more preferably 5.0 or higher. Although the upper limit is not particularly specified, an excessively high aspect ratio results in decreased ductility in some cases. Accordingly, the aspect ratio for crystal grains of ferrite and bainite is preferably 10 or lower.
- the aspect ratio herein refers to, when an observation surface is set to be a cross-section parallel to the rolling direction, a ratio of an average grain size in the rolling direction to an average grain size in the thickness direction for crystal grains of ferrite and bainite.
- the average grain size is obtained as an average grain size for both ferrite and bainite phases without distinguishing ferrite and bainite.
- the aspect ratio of ferrite and bainite can be measured according to a method described in the Examples section hereinafter.
- the aspect ratio of ferrite and bainite can be controlled, for example, by controlling manufacturing conditions, especially a cold reduction, a soaking temperature, and/or a soaking time.
- a high-strength thin steel sheet according to aspects of the present invention can be manufactured by hot-rolling a steel slab having the above-described component composition at a finishing temperature of 800° C. or higher and at a coiling temperature of 400° C. or higher; pickling; then cold-rolling at a cold reduction of 30 to 80%; and subsequently annealing at a soaking temperature of 650° C. to 800° C. for a soaking time of 600 s or less.
- the above method may further comprise, after the finish rolling, slow cooling at a start temperature of 550° C. to 750° C.
- a coiling temperature is not particularly limited, and may be lower than 400° C.
- a hot-dip coating process or an electroplating process may be performed after the annealing. After the hot-dip coating process, an allowing process at an alloying temperature of 460° C. to 600° C. for a holding time of 1 s or more may be performed.
- the thus-obtained high-strength thin steel sheet may be processed at a thickness reduction of 0.1 to 3.0%.
- a refining method of steel is not particularly limited, and may employ a commonly known refining method in a converter or an electric furnace, for example.
- secondary refining may be performed in a vacuum degasser.
- a slab is formed by continuous casting in view of productivity and/or quality.
- a slab may also be formed by commonly known casting method, such as ingot casting-slabbing or thin slab continuous casting.
- a slab after casting may undergo direct rolling, or reheating of a hot or cold slab to 1,200° C. or higher and the subsequent hot rolling.
- a heating temperature in the reheating is not particularly limited, and is preferably 1,150° C. or higher.
- a carbide-forming element such as Ti, Nb, or V
- a carbide can also be dissolved by heating to 1,200° C. or higher and finely precipitated in the subsequent hot rolling and/or annealing processes.
- the holding time is not particularly limited, but is preferably 10 minutes or more and more preferably 30 minutes or more. In view of an operational load, the upper limit is preferably 180 minutes or less.
- the finishing temperature is set to 800° C. or higher and preferably 830° C. or higher.
- the upper limit of the finishing temperature is not particularly limited, crystal grains become large at a high temperature, and thus toughness of a steel sheet is decreased. Accordingly, the upper limit is preferably set to 950° C. or lower, more preferably 900° C. or lower, and further preferably 880° C. or lower.
- the coiling temperature becomes important in order to obtain desired characteristics of the steel sheet.
- a low coiling temperature results in martensite transformation, thereby decreasing a yield ratio of the steel sheet.
- the coiling temperature is set to 400° C. or higher.
- the upper limit of the coiling temperature is not particularly limited, crystal grains become large at an excessively high temperature. Accordingly, the upper limit is preferably 650° C. or lower, more preferably 600° C. or lower, and further preferably 550° C. or lower.
- a cooling rate from the end of finish rolling until coiling is not particularly limited.
- an average cooling rate of 10° C./s or more is sufficient for grain refinement. Meanwhile, excessively rapid cooling requires a special cooling apparatus and thus increases manufacturing costs. Accordingly, an average cooling rate is preferably 10° C./s or more and 100° C./s or less.
- Slow cooling slow cooling at a start temperature of 550° C. to 750° C. and at an average cooling rate of less than 10° C./s for a slow cooling time of 1 to 10 s
- Ferrite transformation or bainite transformation can be promoted by performing slow cooling after finish rolling.
- the upper limit of the start temperature is set to 750° C., preferably 700° C. or lower, and more preferably 650° C. or lower.
- the lower limit of the start temperature is set to 550° C. and preferably 600° C. or higher.
- an average cooling rate is set to less than 10° C./s and preferably less than 6° C./s.
- the lower limit of the average cooling rate is not particularly specified, it is preferably 3° C./s or more since crystal grains become large at an extremely slow average cooling rate. Because ferrite transformation or bainite transformation cannot be promoted in a short slow cooling time, a slow cooling time needs to be 1 s or more. Meanwhile, crystal grains become large in a long slow cooling time. Accordingly, the slow cooling time is set to 10 s or less and preferably 5 s or less. When further formability is required, slow cooling is preferably performed. When slow cooling is performed, a coiling temperature during coiling, which is the subsequent step to the slow cooling, is not particularly limited and may be lower than 400° C. or higher than 400° C. without any problem.
- a coiling temperature is preferably 650° C. or lower, or equal to or lower than the end temperature of slow cooling. Meanwhile, since an excessively low coiling temperature worsens a coil shape, the lower limit of the coiling temperature is 300° C. or higher.
- An average cooling rate after the end of rolling until the start of slow cooling, as well as an average cooling rate after the end of slow cooling until coiling are not particularly limited. Such an average cooling rate of 10° C./s or more is sufficient for grain refinement. Meanwhile, excessively rapid cooling requires a special cooling apparatus and increases manufacturing costs. Accordingly, the average cooling rate is preferably 10° C./s or more and 100° C./s or less.
- the start of slow cooling herein refers to the moment when a cooling rate is switched to less than 10° C./s at an optional temperature in the start temperature range of slow cooling (750° C. to 550° C.).
- the reheating temperature after casting described herein refers to a temperature in the central part of a slab.
- the finishing temperature, the coiling temperature, the start temperature of slow cooling are each a surface temperature of a steel sheet.
- the average cooling rate during slow cooling is defined as a surface temperature of a steel sheet.
- Pickling may be performed for the thus-obtained steel sheet.
- a method of pickling is not particularly limited, and may be hydrochloric acid pickling or sulfuric acid pickling.
- scale on a steel sheet surface is removed, thereby improving chemical conversion treatment performance and/or coating adhesion.
- coating adhesion is enhanced when the subsequent hot-dip coating process or electroplating process is performed.
- a steel sheet after hot rolling and pickling can raise an aspect ratio for crystal grains of ferrite and bainite by cold rolling, and increase the strength of a steel sheet and a yield ratio of a steel sheet by introducing dislocations.
- a cold reduction is set to 30% or more, preferably 40% or more, and more preferably 50% or more. Meanwhile, a large cold reduction results in an increased rolling load. Accordingly, a cold reduction is set to 80% or less, preferably 70% or less, and more preferably 60% or less.
- the cold reduction refers to a ratio of a thickness of a steel sheet after cold rolling to a thickness of the steel sheet after pickling.
- Soaking Temperature 650° C. to 800° C.
- the microstructure In a steel sheet after completing cold rolling, the microstructure is recovered through annealing.
- the lower limit of the soaking temperature is set to 650° C. and preferably 700° C. or higher. Meanwhile, recrystallization progresses at a high soaking temperature, thereby significantly decreasing the strength of a steel sheet and a yield ratio of a steel sheet.
- the upper limit of the soaking temperature is 800° C. and preferably 780° C.
- a soaking time is set to 600 s or less, preferably 300 s or less, and more preferably 100 s or less.
- the lower limit is not particularly set, but is preferably 1 s or more.
- an average heating rate to the soaking temperature during annealing is not particularly limited, 1° C./s or more is preferable in view of productivity. Since rapid heating requires special equipment, the upper limit of the heating rate is preferably 100° C./s or less. Although an average cooling rate from the soaking temperature is not particularly limited, 1° C./s or more is preferable in view of productivity. Since rapid cooling requires special equipment, the upper limit of the cooling rate is 100° C./s or less if cooling is performed by a common gas cooling, for example. Meanwhile, when cooling is performed after the end of annealing, cementite may be precipitated by holding at 200° C. to 450° C. for 30 to 600 s during the cooling.
- a coating process or the composition of a coating bath can be performed as a coating process.
- a steel sheet is immersed in a coating bath during cooling after annealing.
- a galvanizing bath is preferably at 420° C. to 500° C. Zinc does not melt in a galvanizing bath at lower than 420° C. Meanwhile, galvannealing progresses excessively in a galvanizing bath at higher than 500° C.
- Galvannealing process at a galvannealing temperature of 460° C. to 600° C. for a holding time of 1 s or more after a hot-dip galvanizing process (preferable condition)
- a galvannealed steel sheet can be formed by reheating to 460° C. to 600° C. after the hot-dip galvanizing process and holding at the reheating temperature for 1 s or more.
- a reheating temperature of lower than 460° C. results in unsatisfactory galvannealing.
- galvannealing progresses excessively at a reheating temperature exceeding 600° C., and thus a coating becomes brittle.
- the reheating temperature is preferably 570° C. or lower.
- a holding time of less than 1 s results in unsatisfactory galvannealing.
- the upper limit of the holding time is not particularly set, it is preferably 10 s or less since long-time holding results in coarsened precipitates.
- a zinc coating, a composite coating of zinc and Al, a composite coating of zinc and Ni, an Al coating, a composite coating of Al and Si can be formed on a steel sheet surface by an electroplating process.
- a yield ratio of a steel sheet can be enhanced through general processing of a high-strength thin steel sheet obtained as described above.
- general processing is performed at a thickness reduction of 0.1% or more. More preferably, a thickness reduction is 0.3% or more. Meanwhile, a large thickness reduction results in decreased ductility of a steel sheet. Accordingly, when general processing is performed, a thickness reduction is preferably set to 3.0% or less, more preferably 2.0% or less, and further preferably 1.0% or less.
- General processing herein may be applying of reduction to a steel sheet by a rolling roller or imparting of tension to a steel sheet by pulling. Further, general processing may be combined processing of rolling and pulling.
- a high-strength thin steel sheet according to aspects of the present invention is manufactured as described above.
- the finishing temperature and the coiling temperature are each set to be a temperature on a steel sheet surface.
- the average cooling rate when slow cooling is performed is defined on the basis of a temperature on a steel sheet surface.
- the reheating temperature is set to be a temperature on a steel sheet surface.
- strength of the steel sheet is not decreased even upon reheating to 800° C. or lower. Accordingly, the steel sheet may be reheated to 800° C. or lower and then hot-pressed for stamping of components.
- the thickness is not particularly limited, aspects of the present invention achieve advantageous effects particularly in the manufacture of thin sheets. Accordingly, the thickness is preferably 2.0 mm or less, more preferably 1.6 mm or less, further preferably 1.2 mm or less, and most preferably 1.0 mm or less.
- Molten steel having the component composition shown in Table 1 was refined and continuously cast by a typical and commonly known technique to manufacture steel slabs. Under manufacturing conditions shown in Table 2, these slabs were hot-rolled, and then the resulting hot-rolled steel sheets were cold-rolled and annealed to yield cold-rolled steel sheets.
- the slabs were soaked at 1,250° C. for 30 minutes, and then hot-rolled.
- a cooling rate after hot rolling was 30° C./s in average when slow cooling was not performed, and 30° C./s before and after slow cooling when slow cooling was performed.
- Pickling was performed at a hydrochloric acid concentration of 10% in mass % and at a temperature of 80° C. Cooling was performed at 10° C./s in average after cold rolling and annealing.
- a coating process was performed for some slabs.
- Sample Nos. 3 to 7, 9, 10, 13, 14, and 17 were held at 350° C. for 180 s during cooling after annealing and then cooled with air.
- Sample No. 12 was immersed in a galvanizing bath at 470° C. during cooling after annealing and then cooled with air.
- Sample Nos. 1, 2, 8, 11, 15, and 16 were immersed in a galvanizing bath at 470° C. during cooling after annealing, then reheated at 550° C. for 1 s (galvannealing process), and cooled with air.
- Sample No. 10 was electrogalvanized after annealing.
- Test pieces each taken from the thus-obtained high-strength thin steel sheets were tested as described below and evaluated.
- steel sheets after the respective coating processes were tested and evaluated.
- a surface parallel to the thickness direction and the rolling direction as an observation surface was embedded, polished, and etched with Nital.
- a 100 ⁇ 100 ⁇ m region centered on a 1 ⁇ 4 thickness portion was imaged by a scanning electron microscope (SEM) at a magnification of 1000 ⁇ . Three images for such a region were taken for one specimen. A total area fraction was obtained through image processing of such SEM images. A total area fraction is an average value of area fractions obtained from three images.
- SEM scanning electron microscope
- a specimen was taken by cutting such that a cross-section parallel to the rolling direction became an observation surface, embedded, polished, etched with Nital, and then electron backscatter diffraction (EBSD) pattern measurement was performed at a measurement step of 0.1 ⁇ m for a 1 ⁇ 4 thickness portion of the specimen. Misorientation of 15° or more was set to be a grain boundary. Three 100 ⁇ 100 ⁇ m regions were measured for one specimen and output. Nineteen straight lines parallel to each of the thickness direction and the rolling direction were drawn at regular intervals for each output region, and an each average grain size in the thickness direction and in the rolling direction was obtained by an intercept method. Three data was averaged as an average grain size for a specimen. A ratio of an average grain size in the rolling direction to an average grain size in the thickness direction was set to be an aspect ratio.
- EBSD electron backscatter diffraction
- the steel sheets were each cut to a JIS No. 5 test piece with a direction orthogonal to the rolling direction as a longitudinal direction, and tensile tests were performed according to JIS Z 2241 to obtain yield strength YP (MPa), tensile strength TS (MPa), and total elongation El (%).
- Upper yield point was set to be yield strength for a specimen with yield point elongation, whereas 0.2% proof strength was set to be yield strength for a specimen without yield point elongation.
- a yield ratio was calculated as YP/TS. Tests were performed for two specimens and their average values were regarded as mechanical characteristic values of a steel sheet. In the case of YP/TS ⁇ 0.90, yield ratio is evaluated to be high, and in the case of TS ⁇ El ⁇ 10,000 (MPa ⁇ %), formability is evaluated to be good.
- Table 3 The results obtained as described above are shown in Table 3.
- FIG. 1 shows a relationship between yield ratio and total area fraction of ferrite and bainite.
- FIG. 2 shows a relationship between yield ratio and aspect ratio.
- FIG. 3 shows a relationship between Si content and formability (TS ⁇ El).
- FIG. 1 reveals that a yield ratio of 0.90 or higher can be achieved by setting a total area fraction of ferrite and bainite to 90% or more.
- FIG. 2 reveals that a yield ratio of 0.90 or higher can be achieved by setting an aspect ratio to 3.0 or higher.
- FIG. 3 reveals that TS ⁇ El of 10,000 (MPa ⁇ %) or more can be achieved by setting a Si content to 0.5 to 2.0%.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
- Coating With Molten Metal (AREA)
Abstract
Description
- This is the U.S. National Phase application of PCT/JP2017/008291, filed Mar. 2, 2017, which claims priority to Japanese Patent Application No. 2016-047815, filed Mar. 11, 2016, the disclosures of each of these applications being incorporated herein by reference in their entireties for all purposes.
- The present invention relates to a high-strength thin steel sheet that has a high yield ratio and excellent formability and that is best suited for, for example, body parts, such as an automobile pillar, side sill, and member; reinforcing parts therefor; and structural parts used for a door impact beam, a vending machine, a desk, electric appliances, office automation equipment, and construction materials, and to a manufacturing method therefor.
- In recent years, growing attention to the global environment has increased demands for reduced CO2 emission. In the automotive field, for example, there is a mounting need for improved fuel efficiency through reduced body weight, as well as for reduced emission. Collision safety is also highly needed. Thinning of structural parts is most effective for reducing automobile weight. In other words, enhanced energy absorption in a collision through increased tensile strength and yield strength of steel sheets that form structural parts is effective for reducing automobile weight while maintaining strength.
- As a conventional steel sheet having a high yield ratio, which is a ratio of yield strength to tensile strength, Patent Literature 1 discloses a hot-dip galvanized steel sheet manufactured by hot-rolling steel containing, in mass %, C: 0.07 to 0.25%, Mn: 1.5 to 2.5%, Nb: 0.10% or less, Ti: 0.3% or less, Si: 0.1% or less, Cr: 0.1% or less, P: 0.05% or less, sol. Al: 0.010 to 0.100%, S: 0.01% or less, and N: 0.01% or less; pickling; cold-rolling; then annealing in a continuous hot-dip galvanizing line; and subsequently hot-dip galvanizing; where annealing in a temperature range of 750° C. or higher and 880° C. or lower is performed for 30 s or more and 90 s or less, and subsequently second annealing of holding in a temperature range of 515° C. to 600° C. for 15 s or more is performed either before or after, or both before and after the hot-dip galvanizing. Patent Literature 1 also discloses a high-strength high-yield-ratio hot-dip galvanized steel sheet, which is manufactured as described above so as to include a hot-dip galvanized coating or a galvannealed coating, having a tensile strength of 45 kg/mm2 or higher and a yield ratio of 80% or higher.
- Patent Literature 2 discloses a technique of manufacturing a high-yield-ratio high-tensile-strength cold-rolled steel sheet with excellent formability including: heating to 1,150° C. or higher a steel slab containing, in mass %, C≤0.02%, Si≤0.3%, Mn: 0.5 to 2.0%, P≤0.06%, S≤0.005%, Al≤0.06%, N≤0.006%, and Ti: 0.15 to 0.40%; then hot-rolling at a finishing temperature of 880° C. or higher; coiling at a coiling temperature of 400° C. to 700° C.; pickling; cold-rolling; and subsequently annealing at 600° C. to 720° C. in a carburizing atmosphere.
- Patent Literature 3 discloses a technique of manufacturing a high-yield-ratio high-strength cold-rolled steel sheet having a component composition containing, in mass %, C: 0.02 to 0.10%, Si: 1.5% or less, Mn: 1.0 to 2.0%, P: 0.005 to 0.1%, S 0.01% or less, Al: 0.005 to 0.1%, N: 0.01% or less, and Ti: 0.05 to 0.40% and satisfying (Ti/48)/(C/12)=0.1 to 0.9; and having a microstructure containing ferrite, where the ferrite contains, in area fraction relative to the entire microstructure, 80% or more of crystal grains with an aspect ratio of lower than 3; and 1.0×104/mm2 or more of a carbide containing Ti (Ti carbide) with a grain size of 20 nm or less is precipitated in the ferrite.
- Patent Literature 4 discloses a technique of manufacturing a high-yield-ratio high-strength cold-rolled steel sheet having a yield ratio of higher than 0.70 and lower than 0.83 and a tensile strength of 780 MPa or higher and lower than 900 MPa and containing, in area fraction, 20 to 80% of any of crystal grains with an aspect ratio of 3 or higher oriented in a rolling direction, crystal grains with a grain size of less than 3 μm, and crystal grains with a grain size of less than 3 μm and an aspect ratio of 3 or higher oriented in the rolling direction. The steel sheet is manufactured by heating, to 1,130° C. or higher directly or after single-time cooling, a cast slab having a steel component containing, in mass %, C: more than 0.028 and less than 0.044%, Si: less than 0.8%, Mn: 1.9 to 2.3%, P: 0.001 to 0.035%, S 0.0001% to 0.013%, Al: 0.1% or less, N: 0.0001% to 0.008%, Ti: 0.012 to 0.029%, Nb: 0.029 to 0.042%, Mo: 0.05 to 0.25%, and B: 0.0008 to 0.0038%; then hot-rolling at a temperature equal to or higher than the Ar3 transformation temperature; subsequently removing at a temperature of 750° C. or lower; then cold-rolling at a reduction of 35 to 85%; and subsequently continuously annealing at a maximum heating temperature in a temperature range of 740° C. or higher and 950° C. or lower.
- The technique described in Patent Literature 1, however, requires an annealing temperature substantially exceeding 800° C. In addition, an annealing temperature needs to be elevated to 850° C. in order to manufacture a high-yield-ratio steel sheet with a yield ratio exceeding 0.90. Accordingly, there is a problem in which such a technique involves operational difficulties, such as increasing heating costs.
- The technique described in Patent Literature 2 requires annealing at 600° C. to 720° C. in a carburizing atmosphere and further annealing at 840° C. or higher. Accordingly, there is a problem in which manufacturing costs are increased.
- The technique described in Patent Literature 3 requires annealing at 840° C. or higher and thus involves a problem in which manufacturing costs are increased.
- There is a problem in which the technique described in Patent Literature 4 substantially requires an annealing temperature of 800° C. or higher, and the yield ratio is low at less than 0.83.
- PTL 1: Japanese Unexamined Patent Application Publication No. 10-273754
- PTL 2: Japanese Unexamined Patent Application Publication No. 2007-9253
- PTL 3: Japanese Unexamined Patent Application Publication No. 2009-235440
- PTL 4: Japanese Patent No. 4436275
- In view of the above, an object according to aspects of the present invention is to provide a high-strength thin steel sheet having a high yield ratio and excellent formability and to provide a manufacturing method therefor.
- To achieve the above object, extensive research has been conducted. As a result, the following findings were obtained. First, ferrite and bainite that exhibit excellent ductility are set to be the primary phase. Further, by cold-rolling a hot-rolled steel sheet having a small stacking fault energy by addition of Si, cross slip of dislocations to be introduced by cold rolling is suppressed. Consequently, dislocation tangling can be suppressed. During annealing, the microstructure is allowed to be recovered while an aspect ratio of the microstructure, which has been enlarged by cold rolling, is maintained, thereby promoting disappearance of dislocations that have become easily movable without tangling and significantly enhancing ductility while a high yield ratio is maintained. Dislocation tangling herein refers to a state in which a plurality of dislocations are concentrated in one location and such dislocations become difficult to move due to their interactions.
- Aspects of the present invention have been completed on the basis of the above findings and are summarized as follows.
- [1] A high-strength thin steel sheet having a component composition containing, in mass %, C: 0.04 to 0.25%, Si: 0.5 to 2.0%, Mn: 0.1 to 2.0%, P: 0.05% or less, S: 0.030% or less, Al: 0.10% or less, and N: 0.010% or less, with the balance being iron and incidental impurities; and having a microstructure containing, in area fraction, 90% or more of ferrite and bainite in total, where ferrite and bainite each have an aspect ratio of 3.0 or higher.
- [2] The high-strength thin steel sheet according to [1], where the component composition further contains, in massa, 0.01 to 1.0% of each of one or two or more of Ti, Nb, and V.
- [3] The high-strength thin steel sheet according to [1] or [2], where the component composition further contains, in mass %, 0.005 to 1.0% of each of one or two or more of Mo, Ta, and W.
- [4] The high-strength thin steel sheet according to any one of [1] to [3], where the component composition further contains, in mass %, 0.01 to 1.0% of each of one or two or more of Cr, Ni, and Cu.
- [5] The high-strength thin steel sheet according to any one of [1] to [4], where the component composition further contains, in mass %, 0.0002 to 0.0050% of B.
- [6] The high-strength thin steel sheet according to any one of [1] to [5], where the component composition further contains, in mass %, 0.0005 to 0.01% of each of one or two of Ca and REM.
- [7] The high-strength thin steel sheet according to any one of [1] to [6], where the component composition further contains, in mass %, 0.005 to 0.050% of Sb.
- [8] The high-strength thin steel sheet according to any one of [1] to [7], having a coated layer on a steel sheet surface.
- [9] A method of manufacturing a high-strength thin steel sheet, comprising: hot-rolling a steel slab having the component composition according to any one of [1] to [7] at a finishing temperature of 800° C. or higher and at a coiling temperature of 400° C. or higher; pickling; then cold-rolling at a cold reduction of 30 to 80%; and subsequently annealing at a soaking temperature of 650° C. to 800° C. for a soaking time of 600 s or less.
- [10] A method of manufacturing a high-strength thin steel sheet, comprising: hot-rolling including finish rolling of a steel slab having the component composition according to any one of [1] to [7] at a finishing temperature of 800° C. or higher, followed by slow cooling at a start temperature of 550° C. to 750° C. and at an average cooling rate of less than 10° C./s for a slow cooling time of 1 to 10 s, and subsequent coiling; pickling; then cold-rolling at a cold reduction of 30 to 80%; and subsequently annealing at a soaking temperature of 650° C. to 800° C. for a soaking time of 600 s or less.
- [11] The method of manufacturing a high-strength thin steel sheet according to [9] or [10], further including a hot-dip coating process after the annealing.
- [12] The method of manufacturing a high-strength thin steel sheet according to [11], where the hot-dip coating process is a hot-dip galvanizing process, the method further including a galvannealing process at a galvannealing temperature of 460° C. to 600° C. for a holding time of 1 s or more after the hot-dip galvanizing process.
- [13] The method of manufacturing a high-strength thin steel sheet according to [9] or [10], further including an electroplating process after the annealing.
- [14] The method of manufacturing a high-strength thin steel sheet according to any one of [9] to [13], including processing at a thickness reduction of 0.1 to 3.0% after any of the coiling, the annealing, the hot-dip coating process, the galvannealing process, and the electroplating process.
- [15] A method of manufacturing a high-strength thin steel sheet comprising a coating process for the high-strength thin steel sheet according to any one of [1] to [7].
- In accordance with aspects of the present invention, a high-strength thin steel sheet refers to a steel sheet having a tensile strength (TS) of 440 MPa or higher. Examples of such steel sheets include a cold-rolled steel sheet and a steel sheet prepared from a cold-rolled steel sheet through surface treatment, such as a hot-dip coating process, a hot-dip coating process followed by an alloying process, or an electroplating process. Further, such examples also include steel sheets having a coating formed, for example, by chemical conversion treatment of a cold-rolled steel sheet and a surface-treated steel sheet. In accordance with aspects of the present invention, a high yield ratio refers to a yield ratio (YP/TS)≥0.90. Further, good formability refers to TS×El≥10,000 MPa.
- According to aspects of the present invention, a high-strength thin steel sheet having a high yield ratio and excellent formability is obtained. A high-strength thin steel sheet according to aspects of the present invention having a tensile strength of 440 MPa or higher can enhance ductility while maintaining a high yield ratio of the steel sheet. Accordingly, the high-strength thin steel sheet can suitably be used for applications, such as automobile structural parts, thereby providing industrially beneficial effects.
-
FIG. 1 is a graph showing a relationship between yield ratio and total area fraction of ferrite and bainite. -
FIG. 2 is a graph showing a relationship between aspect ratio and yield ratio. -
FIG. 3 is a graph showing a relationship between Si content and formability (TS×El). - Following, aspects of the present invention will be described in detail with reference to the following embodiments. Hereinafter, % means mass % unless otherwise indicated.
- First, the reasons for limiting the component composition of a high-strength thin steel sheet according to aspects of the present invention will be described.
- C: 0.04 to 0.25%
- C contributes to increased strength of a steel sheet by dissolving in steel. C also contributes to increased strength of a steel sheet through formation of fine carbides and grain refinement of the microstructure. In order to obtain these effects, C content is set to 0.04% or more and preferably 0.07% or more. Meanwhile, a large amount of C promotes formation of martensite, thereby suppressing formation of ferrite and bainite and decreasing the yield ratio. Further, toughness and weldability are impaired. Accordingly, C content is set to 0.25% or less and preferably 0.20% or less.
- Si: 0.5 to 2.0%
- The presence of a proper amount of Si in steel can decrease stacking fault energy of steel and suppress cross slip of dislocations, thereby suppressing dislocation tangling during cold rolling. Consequently, ductility can be enhanced while a high yield ratio is maintained. In order to obtain such effects, Si content is set to 0.5% or more, preferably 0.7% or more, and more preferably 1.0% or more. Meanwhile, a large amount of Si induces surface defects, called red scale, during hot rolling, and surface Si oxide severely hinders chemical conversion treatment and the coating process. Accordingly, Si content is set to 2.0% or less and preferably 1.5% or less.
- Mn: 0.1 to 2.0%
- Mn can contribute to increased strength of a steel sheet by solid solution strengthening and/or grain refining effects. Further, Mn can suppress the effect of S, which is an impurity element, by fixing S as MnS. In order to obtain such effects, Mn content is set to 0.1% or more, and preferably 0.3% or more. Meanwhile, a large amount of Mn hinders a coating process and promotes formation of martensite, thereby decreasing the yield ratio. Accordingly, Mn content is set to 2.0% or less, preferably 1.5% or less, and more preferably 1.0% or less.
- P: 0.05% or Less
- P segregates in grain boundaries, thereby impairing ductility and toughness. Further, weldability is also impaired by P. Accordingly, P content is set to 0.05% or less, preferably 0.03% or less, and more preferably 0.01% or less.
- S: 0.030% or Less
- S significantly decreases ductility of a steel sheet in hot rolling and thus induces hot cracking, thereby degrading surface quality considerably. In addition, S scarcely contributes to increased strength and rather decreases ductility and stretch flangeability through, as an impurity element, formation of coarse sulfides. Further, weldability is also impaired by S. Since these problems become noticeable when S content exceeds 0.030%, S content is preferably decreased as much as possible. Accordingly, S content is set to 0.030% or less, preferably 0.010% or less, more preferably 0.003% or less, and further preferably 0.0.01% or less.
- Al: 0.10% or Less
- A large amount of Al results in increased aluminum oxide in steel and thus decreases ductility of a steel sheet. Accordingly, Al content is set to 0.10% or less and preferably 0.06% or less. Although the lower limit is not particularly specified, no problem arises if 0.01% or more of Al is contained as Al-killed steel.
- N: 0.010% or Less
- If N is contained in a large amount, slab cracking is likely to occur during hot rolling, thereby causing surface defects. Accordingly, N content is set to 0.010% or less, preferably 0.005% or less, more preferably 0.003% or less, and further preferably 0.002% or less.
- The balance is iron and incidental impurities. Examples of incidental impurities include Sn, Mg, Co, As, Pb, Zn, Ce, and O, and their total content of 0.5% or less is allowable.
- A steel sheet according to aspects of the present invention can realize intended characteristics by including the above-described essential alloying elements. In addition to the above essential alloying elements, however, the following elements may be added as appropriate in order to enhance strength, yield ratio, and formability.
- One or Two or More of Ti, Nb, and V: Each 0.01 to 1.0%
- Ti, Nb, and V each form fine carbides with C and contribute to increased strength of a steel sheet and an enhanced yield ratio of a steel sheet. In order to obtain such effects, the content of each of Ti, Nb, and V, if contained, is set to 0.01% or more, preferably 0.05% or more, and more preferably 0.10% or more. Meanwhile, Ti, Nb, and/or V, even if contained in a large amount, do not contribute much to increased strength and/or an enhanced yield ratio, but rather significantly increase costs. Accordingly, each of Ti, Nb, and V, if contained, is set to 1.0% or less, preferably 0.8% or less, and more preferably 0.6% or less.
- One or Two or More of Mo, Ta, and W: Each 0.005 to 1.0%
- Mo, Ta, and W can contribute to increased strength of a steel sheet and/or an enhanced yield ratio of a steel sheet through formation of fine precipitates. In order to obtain such effects, the content of each of Mo, Ta, and W, if contained, is set to 0.005% or more and preferably 0.10% or more. Meanwhile, even if Mo, Ta, and/or W are contained in a large amount, not only do the effects level off, but also, costs are increased. Accordingly, each of Mo, Ta, and W, if contained, is set to 1.0% or less and preferably 0.5% or less.
- One or Two or More of Cr, Ni, and Cu: Each 0.01 to 1.0%
- Cr, Ni, and Cu can contribute to increased strength and an enhanced yield ratio of a steel sheet through grain refinement of the microstructure. In order to obtain such effects, the content of each of Cr, Ni, and Cu, if contained, is set to 0.01% or more, preferably 0.1% or more, and more preferably 0.3% or more. Meanwhile, even if Cr, Ni, and/or Cu are contained in a large amount, not only do the effects level off, but also, costs are increased. Accordingly, each of Cr, Ni, and Cu, if contained, is set to 1.0% or less and preferably 0.5% or less.
- B: 0.0002 to 0.0050%
- B contributes to increased strength of a steel sheet and an enhanced yield ratio of a steel sheet by promoting grain refinement of the microstructure and/or bainite transformation. In order to obtain such effects, B, if contained, is set to 0.0002% or more, preferably 0.0005% or more, and more preferably 0.0010% or more. Meanwhile, a large amount of B not only complicates rolling due to increased deformation resistance of a steel sheet during hot rolling, but also causes decreased ductility. Accordingly, B, if contained, is set to 0.0050% or less, preferably 0.0030% or less, and more preferably 0.0020% or less.
- One or Two of Ca and REM: Each 0.0005 to 0.01%
- Ca and REM can enhance ductility and/or stretch flangeability by controlling the morphology of sulfides. In order to obtain such effects, the content of each of Ca and REM, if contained, is set to be 0.0005% or more. Meanwhile, even if Ca and/or REM are contained in a large amount, not only do the effects level off, but also, costs are increased. Accordingly, each of Ca and REM, if contained, is set to be 0.01% or less.
- Sb: 0.005 to 0.050%
- Since Sb segregates on a slab surface during heating of a slab, nitriding of the slab can be prevented. Consequently, ductility of a steel sheet can be enhanced through suppressed formation of coarse nitrides. In order to obtain such effects, Sb, if contained, is set to 0.005% or more. Meanwhile, addition of Sb in a large amount leads to increased costs. Accordingly, Sb, if contained, is set to 0.050% or less.
- Next, the microstructure and the like, which are important requirements for a steel sheet according to aspects of the present invention, will be described.
- Total Area Fraction of Ferrite and Bainite: 90% or More
- Ferrite and bainite (tempered ones included) are the important microstructure for achieving high ductility. Accordingly, an area fraction of ferrite and bainite in total is set to 90% or more, preferably 95% or more, more preferably 98% or more, and further preferably 100%. Individual fractions of ferrite and bainite are not specified. It is preferable, however, that the fraction of ferrite is larger. The fraction of ferrite in the entire microstructure is, in area fraction, preferably 90% or more and more preferably 100%. As the microstructure other than ferrite and bainite, pearlite, martensite, retained austenite, and/or cementite, for example, may be contained in each 5% or less and 10% or less in total, if contained. The total area fraction of ferrite and bainite can be measured according to a method described in the Examples section hereinafter. By controlling C amount, Mn amount, and/or manufacturing conditions, especially a coiling temperature, 90% or more of an area fraction of ferrite and bainite in total can be achieved.
- Aspect Ratio of Ferrite and Bainite: 3.0 or Higher
- By raising the aspect ratio for crystal grains of ferrite and bainite, the strength of a steel sheet and a yield ratio of a steel sheet can be increased. Accordingly, the aspect ratio is set to 3.0 or higher, preferably 4.0 or higher, and more preferably 5.0 or higher. Although the upper limit is not particularly specified, an excessively high aspect ratio results in decreased ductility in some cases. Accordingly, the aspect ratio for crystal grains of ferrite and bainite is preferably 10 or lower. The aspect ratio herein refers to, when an observation surface is set to be a cross-section parallel to the rolling direction, a ratio of an average grain size in the rolling direction to an average grain size in the thickness direction for crystal grains of ferrite and bainite. The average grain size is obtained as an average grain size for both ferrite and bainite phases without distinguishing ferrite and bainite. The aspect ratio of ferrite and bainite can be measured according to a method described in the Examples section hereinafter. The aspect ratio of ferrite and bainite can be controlled, for example, by controlling manufacturing conditions, especially a cold reduction, a soaking temperature, and/or a soaking time.
- Next, a manufacturing method for a high-strength thin steel sheet according to aspects of the present invention will be described. A high-strength thin steel sheet according to aspects of the present invention can be manufactured by hot-rolling a steel slab having the above-described component composition at a finishing temperature of 800° C. or higher and at a coiling temperature of 400° C. or higher; pickling; then cold-rolling at a cold reduction of 30 to 80%; and subsequently annealing at a soaking temperature of 650° C. to 800° C. for a soaking time of 600 s or less. The above method may further comprise, after the finish rolling, slow cooling at a start temperature of 550° C. to 750° C. and at an average cooling rate of less than 10° C./s for a slow cooling time of 1 to 10 s, and subsequent coiling. In this case, a coiling temperature is not particularly limited, and may be lower than 400° C. Further, a hot-dip coating process or an electroplating process may be performed after the annealing. After the hot-dip coating process, an allowing process at an alloying temperature of 460° C. to 600° C. for a holding time of 1 s or more may be performed. The thus-obtained high-strength thin steel sheet may be processed at a thickness reduction of 0.1 to 3.0%.
- Hereinafter, the details will be described.
- In accordance with aspects of the present invention, a refining method of steel is not particularly limited, and may employ a commonly known refining method in a converter or an electric furnace, for example. In addition, secondary refining may be performed in a vacuum degasser. Subsequently, a slab (steel) is formed by continuous casting in view of productivity and/or quality. A slab may also be formed by commonly known casting method, such as ingot casting-slabbing or thin slab continuous casting.
- Slab After Casting
- A slab after casting may undergo direct rolling, or reheating of a hot or cold slab to 1,200° C. or higher and the subsequent hot rolling. A heating temperature in the reheating is not particularly limited, and is preferably 1,150° C. or higher. When a carbide-forming element, such as Ti, Nb, or V is contained, a carbide can also be dissolved by heating to 1,200° C. or higher and finely precipitated in the subsequent hot rolling and/or annealing processes. The holding time is not particularly limited, but is preferably 10 minutes or more and more preferably 30 minutes or more. In view of an operational load, the upper limit is preferably 180 minutes or less.
- Finishing Temperature: 800° C. or Higher
- When a finishing temperature is low, rolling progresses in the ferrite region and thus tensile strength is decreased by coarsened crystal grains. Since toughness is also decreased significantly, formability of a steel sheet is unsatisfactory. When the non-recrystallized ferrite microstructure is formed, many dislocations remain even after cold rolling and/or annealing and thus formability is decreased greatly. Accordingly, the finishing temperature is set to 800° C. or higher and preferably 830° C. or higher. Although the upper limit of the finishing temperature is not particularly limited, crystal grains become large at a high temperature, and thus toughness of a steel sheet is decreased. Accordingly, the upper limit is preferably set to 950° C. or lower, more preferably 900° C. or lower, and further preferably 880° C. or lower.
- Coiling Temperature: 400° C. or Higher
- When slow cooling described hereinafter is not performed in the cooling process of a steel sheet in the period from the end of finish rolling until coiling, a coiling temperature becomes important in order to obtain desired characteristics of the steel sheet. A low coiling temperature results in martensite transformation, thereby decreasing a yield ratio of the steel sheet. Accordingly, when slow cooling is not performed, the coiling temperature is set to 400° C. or higher. Although the upper limit of the coiling temperature is not particularly limited, crystal grains become large at an excessively high temperature. Accordingly, the upper limit is preferably 650° C. or lower, more preferably 600° C. or lower, and further preferably 550° C. or lower. A cooling rate from the end of finish rolling until coiling is not particularly limited. An average cooling rate of 10° C./s or more is sufficient for grain refinement. Meanwhile, excessively rapid cooling requires a special cooling apparatus and thus increases manufacturing costs. Accordingly, an average cooling rate is preferably 10° C./s or more and 100° C./s or less.
- Slow cooling: slow cooling at a start temperature of 550° C. to 750° C. and at an average cooling rate of less than 10° C./s for a slow cooling time of 1 to 10 s
- Ferrite transformation or bainite transformation can be promoted by performing slow cooling after finish rolling. In this case, when a start temperature of slow cooling is high, crystal grains become large. Accordingly, the upper limit of the start temperature is set to 750° C., preferably 700° C. or lower, and more preferably 650° C. or lower. Meanwhile, when a start temperature of slow cooling is low, ferrite transformation or bainite transformation cannot be promoted. Accordingly, the lower limit of the start temperature is set to 550° C. and preferably 600° C. or higher. When a cooling rate during slow cooling is fast, ferrite transformation or bainite transformation cannot be promoted. Accordingly, an average cooling rate is set to less than 10° C./s and preferably less than 6° C./s. Although the lower limit of the average cooling rate is not particularly specified, it is preferably 3° C./s or more since crystal grains become large at an extremely slow average cooling rate. Because ferrite transformation or bainite transformation cannot be promoted in a short slow cooling time, a slow cooling time needs to be 1 s or more. Meanwhile, crystal grains become large in a long slow cooling time. Accordingly, the slow cooling time is set to 10 s or less and preferably 5 s or less. When further formability is required, slow cooling is preferably performed. When slow cooling is performed, a coiling temperature during coiling, which is the subsequent step to the slow cooling, is not particularly limited and may be lower than 400° C. or higher than 400° C. without any problem. Since an excessively high coiling temperature results in large crystal grains, a coiling temperature is preferably 650° C. or lower, or equal to or lower than the end temperature of slow cooling. Meanwhile, since an excessively low coiling temperature worsens a coil shape, the lower limit of the coiling temperature is 300° C. or higher. An average cooling rate after the end of rolling until the start of slow cooling, as well as an average cooling rate after the end of slow cooling until coiling are not particularly limited. Such an average cooling rate of 10° C./s or more is sufficient for grain refinement. Meanwhile, excessively rapid cooling requires a special cooling apparatus and increases manufacturing costs. Accordingly, the average cooling rate is preferably 10° C./s or more and 100° C./s or less. The start of slow cooling herein refers to the moment when a cooling rate is switched to less than 10° C./s at an optional temperature in the start temperature range of slow cooling (750° C. to 550° C.).
- The reheating temperature after casting described herein refers to a temperature in the central part of a slab. In addition, the finishing temperature, the coiling temperature, the start temperature of slow cooling are each a surface temperature of a steel sheet. Further, the average cooling rate during slow cooling is defined as a surface temperature of a steel sheet.
- Pickling
- Pickling may be performed for the thus-obtained steel sheet. A method of pickling is not particularly limited, and may be hydrochloric acid pickling or sulfuric acid pickling. By performing pickling, scale on a steel sheet surface is removed, thereby improving chemical conversion treatment performance and/or coating adhesion. In addition, coating adhesion is enhanced when the subsequent hot-dip coating process or electroplating process is performed.
- Cold Reduction: 30 to 80%
- A steel sheet after hot rolling and pickling can raise an aspect ratio for crystal grains of ferrite and bainite by cold rolling, and increase the strength of a steel sheet and a yield ratio of a steel sheet by introducing dislocations. In order to obtain such effects, a cold reduction is set to 30% or more, preferably 40% or more, and more preferably 50% or more. Meanwhile, a large cold reduction results in an increased rolling load. Accordingly, a cold reduction is set to 80% or less, preferably 70% or less, and more preferably 60% or less. The cold reduction refers to a ratio of a thickness of a steel sheet after cold rolling to a thickness of the steel sheet after pickling.
- Soaking Temperature: 650° C. to 800° C.
- In a steel sheet after completing cold rolling, the microstructure is recovered through annealing. When a soaking temperature is low during annealing, the microstructure cannot be recovered and thus ductility of a steel sheet is decreased. Accordingly, the lower limit of the soaking temperature is set to 650° C. and preferably 700° C. or higher. Meanwhile, recrystallization progresses at a high soaking temperature, thereby significantly decreasing the strength of a steel sheet and a yield ratio of a steel sheet. Accordingly, the upper limit of the soaking temperature is 800° C. and preferably 780° C.
- Soaking Time: 600 s or Less
- When a soaking time during annealing is long, recrystallization progresses, and thus an aspect ratio of crystal grains becomes low. Further, strength of a steel sheet and a yield ratio of a steel sheet are decreased. Accordingly, a soaking time is set to 600 s or less, preferably 300 s or less, and more preferably 100 s or less. The lower limit is not particularly set, but is preferably 1 s or more.
- Although an average heating rate to the soaking temperature during annealing is not particularly limited, 1° C./s or more is preferable in view of productivity. Since rapid heating requires special equipment, the upper limit of the heating rate is preferably 100° C./s or less. Although an average cooling rate from the soaking temperature is not particularly limited, 1° C./s or more is preferable in view of productivity. Since rapid cooling requires special equipment, the upper limit of the cooling rate is 100° C./s or less if cooling is performed by a common gas cooling, for example. Meanwhile, when cooling is performed after the end of annealing, cementite may be precipitated by holding at 200° C. to 450° C. for 30 to 600 s during the cooling.
- Since the material properties of a high-strength thin steel sheet according to aspects of the present invention are not affected by a coating process or the composition of a coating bath, a hot-dip galvanizing process, a galvannealing process, or an electroplating process, for example, can be performed as a coating process.
- Hot-Dip Coating Process (Preferable Condition)
- When a hot-dip coating process is performed, a steel sheet is immersed in a coating bath during cooling after annealing. For example, in a case of a hot-dip galvanizing process, a galvanizing bath is preferably at 420° C. to 500° C. Zinc does not melt in a galvanizing bath at lower than 420° C. Meanwhile, galvannealing progresses excessively in a galvanizing bath at higher than 500° C.
- Galvannealing process at a galvannealing temperature of 460° C. to 600° C. for a holding time of 1 s or more after a hot-dip galvanizing process (preferable condition)
- A galvannealed steel sheet can be formed by reheating to 460° C. to 600° C. after the hot-dip galvanizing process and holding at the reheating temperature for 1 s or more. A reheating temperature of lower than 460° C. results in unsatisfactory galvannealing. Meanwhile, galvannealing progresses excessively at a reheating temperature exceeding 600° C., and thus a coating becomes brittle. Accordingly, the reheating temperature is preferably 570° C. or lower. Meanwhile, a holding time of less than 1 s results in unsatisfactory galvannealing. Although the upper limit of the holding time is not particularly set, it is preferably 10 s or less since long-time holding results in coarsened precipitates.
- Electroplating Process
- A zinc coating, a composite coating of zinc and Al, a composite coating of zinc and Ni, an Al coating, a composite coating of Al and Si can be formed on a steel sheet surface by an electroplating process.
- Processing at a Thickness Reduction of 0.1 to 3.0%
- A yield ratio of a steel sheet can be enhanced through general processing of a high-strength thin steel sheet obtained as described above. In order to obtain such an effect, general processing is performed at a thickness reduction of 0.1% or more. More preferably, a thickness reduction is 0.3% or more. Meanwhile, a large thickness reduction results in decreased ductility of a steel sheet. Accordingly, when general processing is performed, a thickness reduction is preferably set to 3.0% or less, more preferably 2.0% or less, and further preferably 1.0% or less. General processing herein may be applying of reduction to a steel sheet by a rolling roller or imparting of tension to a steel sheet by pulling. Further, general processing may be combined processing of rolling and pulling.
- A high-strength thin steel sheet according to aspects of the present invention is manufactured as described above. In the foregoing, the finishing temperature and the coiling temperature are each set to be a temperature on a steel sheet surface. The average cooling rate when slow cooling is performed is defined on the basis of a temperature on a steel sheet surface. The reheating temperature is set to be a temperature on a steel sheet surface. Meanwhile, in a high-strength thin steel sheet according to aspects of the present invention, strength of the steel sheet is not decreased even upon reheating to 800° C. or lower. Accordingly, the steel sheet may be reheated to 800° C. or lower and then hot-pressed for stamping of components. Although the thickness is not particularly limited, aspects of the present invention achieve advantageous effects particularly in the manufacture of thin sheets. Accordingly, the thickness is preferably 2.0 mm or less, more preferably 1.6 mm or less, further preferably 1.2 mm or less, and most preferably 1.0 mm or less.
- Molten steel having the component composition shown in Table 1 was refined and continuously cast by a typical and commonly known technique to manufacture steel slabs. Under manufacturing conditions shown in Table 2, these slabs were hot-rolled, and then the resulting hot-rolled steel sheets were cold-rolled and annealed to yield cold-rolled steel sheets.
- The slabs were soaked at 1,250° C. for 30 minutes, and then hot-rolled. A cooling rate after hot rolling was 30° C./s in average when slow cooling was not performed, and 30° C./s before and after slow cooling when slow cooling was performed. Pickling was performed at a hydrochloric acid concentration of 10% in mass % and at a temperature of 80° C. Cooling was performed at 10° C./s in average after cold rolling and annealing. A coating process was performed for some slabs.
- Sample Nos. 3 to 7, 9, 10, 13, 14, and 17 were held at 350° C. for 180 s during cooling after annealing and then cooled with air. Sample No. 12 was immersed in a galvanizing bath at 470° C. during cooling after annealing and then cooled with air. Sample Nos. 1, 2, 8, 11, 15, and 16 were immersed in a galvanizing bath at 470° C. during cooling after annealing, then reheated at 550° C. for 1 s (galvannealing process), and cooled with air. Sample No. 10 was electrogalvanized after annealing.
- Test pieces each taken from the thus-obtained high-strength thin steel sheets were tested as described below and evaluated. In the case of coated steel sheets, steel sheets after the respective coating processes were tested and evaluated.
- Total Area Fraction of Ferrite and Bainite
- A surface parallel to the thickness direction and the rolling direction as an observation surface was embedded, polished, and etched with Nital. On the observation surface, a 100×100 μm region centered on a ¼ thickness portion was imaged by a scanning electron microscope (SEM) at a magnification of 1000×. Three images for such a region were taken for one specimen. A total area fraction was obtained through image processing of such SEM images. A total area fraction is an average value of area fractions obtained from three images.
- Aspect Ratio for Crystal Grains of Ferrite and Bainite
- A specimen was taken by cutting such that a cross-section parallel to the rolling direction became an observation surface, embedded, polished, etched with Nital, and then electron backscatter diffraction (EBSD) pattern measurement was performed at a measurement step of 0.1 μm for a ¼ thickness portion of the specimen. Misorientation of 15° or more was set to be a grain boundary. Three 100×100 μm regions were measured for one specimen and output. Nineteen straight lines parallel to each of the thickness direction and the rolling direction were drawn at regular intervals for each output region, and an each average grain size in the thickness direction and in the rolling direction was obtained by an intercept method. Three data was averaged as an average grain size for a specimen. A ratio of an average grain size in the rolling direction to an average grain size in the thickness direction was set to be an aspect ratio.
- Mechanical Characteristics
- The steel sheets were each cut to a JIS No. 5 test piece with a direction orthogonal to the rolling direction as a longitudinal direction, and tensile tests were performed according to JIS Z 2241 to obtain yield strength YP (MPa), tensile strength TS (MPa), and total elongation El (%). Upper yield point was set to be yield strength for a specimen with yield point elongation, whereas 0.2% proof strength was set to be yield strength for a specimen without yield point elongation. A yield ratio was calculated as YP/TS. Tests were performed for two specimens and their average values were regarded as mechanical characteristic values of a steel sheet. In the case of YP/TS≥0.90, yield ratio is evaluated to be high, and in the case of TS×El≥10,000 (MPa·%), formability is evaluated to be good. The results obtained as described above are shown in Table 3.
-
TABLE 1 Sample Chemical composition (mass %) No. C Si Mn P S Al N Others 1 0.04 1.2 1.8 0.02 0.002 0.04 0.003 2 0.07 1.8 0.2 0.05 0.005 0.05 0.005 B: 0.0014 3 0.05 0.9 1.9 0.01 0.001 0.07 0.006 Ti: 0.20, B: 0.0014 4 0.20 0.7 0.4 0.03 0.002 0.06 0.006 Mo: 0.2 5 0.26 1.3 1.0 0.01 0.002 0.05 0.003 Ti: 0.05 6 0.16 1.0 0.5 0.01 0.001 0.05 0.004 Ti: 0.07, V: 0.50 7 0.13 0.7 1.5 0.02 0.001 0.05 0.005 Ti: 0.05, V: 0.25, Sb: 0.010 8 0.15 1.0 0.6 0.02 0.001 0.04 0.009 V: 0.20, B: 0.0013, Ca: 0.003 9 0.08 0.6 0.7 0.02 0.028 0.07 0.004 Ti: 0.10, Nb: 0.05, V: 0.05, Mo: 0.08, Ta: 0.02, W: 0.04, Cr: 0.08, Ni: 0.07, Cu: 0.11, B: 0.0020, Sb: 0.009, Ca: 0.005, REM: 0.003 10 0.24 0.9 0.1 0.01 0.001 0.08 0.002 Cr: 0.05, Cu: 0.08, Ni: 0.06 11 0.08 1.2 1.0 0.03 0.004 0.06 0.004 V: 0.25, Cr: 0.31 12 0.07 0.8 1.0 0.01 0.001 0.03 0.005 Ti: 0.05, Nb: 0.05, B: 0.0015 13 0.08 1.2 0.8 0.01 0.005 0.06 0.001 Ti: 0.11, Cr: 0.21 14 0.11 2.0 0.4 0.03 0.008 0.04 0.004 Nb: 0.07, V: 0.41, Ca: 0.004 15 0.15 0.4 0.6 0.02 0.003 0.04 0.005 16 0.15 1.4 0.6 0.01 0.015 0.06 0.005 V: 0.35 17 0.14 1.2 2.1 0.01 0.001 0.05 0.004 Ti: 0.10, V: 0.12 -
TABLE 2 Hot rolling Cold Start rolling Annealing Sam- Finishing temperature Cooling rate in Slow Coiling Cold Soaking Thickness ple temperature of slow cooling slow cooling cooling time temperature reduction temperature Soaking reduction No. (° C.) (° C.) (° C./s) (s) (° C.) (%) (° C.) time (s) Coating*1) (%) 1 880 — — — 400 70 650 550 GA 0.1 2 820 — — — 650 50 680 150 GA — 3 880 — — — 600 40 760 80 — 2.5 4 810 — — — 600 30 710 150 — 0.5 5 830 — — — 600 60 720 150 — 0.1 6 850 — — — 500 50 750 30 — — 7 920 — — — 450 50 740 120 — — 8 860 — — — 600 25 740 80 GA — 9 850 — — — 500 50 780 30 — 1.2 10 930 — — — 550 40 730 120 Electrogalvanized — Zn 11 860 600 4 2 400 60 750 100 GA — 12 830 — — — 450 60 680 300 GI — 13 900 — — — 550 50 810 60 — — 14 900 550 4 3 300 55 740 130 — — 15 860 — — — 550 50 700 50 GA — 16 860 650 5 1 450 60 790 10 GA — 17 850 600 4 3 450 50 750 50 — — *1)GI: hot-dip galvanized steel sheet, GA: Galvannealed steel sheet -
TABLE 3 Microstructure Area fraction of Mechanical characteristic value Sample ferrite and bainite Aspect Thickness YP TS El Yield TS × El No. (%) ratio (mm) (MPa) (MPa) (%) ratio (MPa · %) Note 1 100 12.0 0.8 470 480 21 0.98 10080 Example 2 96 4.6 1.2 580 620 20 0.94 12400 Example 3 100 3.5 2.0 800 820 17 0.98 13940 Example 4 93 3.1 2.2 680 720 15 0.94 10800 Example 5 88 7.3 1.4 530 620 19 0.85 11780 Comparative Example 6 100 5.2 1.4 1230 1250 12 0.98 15000 Example 7 95 4.6 1.6 940 980 14 0.96 13720 Example 8 97 2.8 1.8 790 900 14 0.88 12600 Comparative Example 9 95 4.6 1.6 920 960 14 0.96 13440 Example 10 90 3.5 1.6 500 550 19 0.91 10450 Example 11 98 7.1 1.4 970 1000 14 0.97 14000 Example 12 96 7.3 1.4 650 680 18 0.96 12240 Example 13 98 2.4 1.6 680 830 22 0.82 18260 Comparative Example 14 94 5.6 1.2 970 1050 13 0.92 13650 Example 15 89 4.5 1.2 480 530 17 0.91 9010 Comparative Example 16 92 7.5 1.0 950 1020 13 0.93 13260 Example 17 86 5.0 1.4 780 950 13 0.82 12350 Comparative Example - Table 3 reveals that high-strength thin steel sheets having a high yield ratio and excellent formability were obtained for Examples.
FIG. 1 shows a relationship between yield ratio and total area fraction of ferrite and bainite.FIG. 2 shows a relationship between yield ratio and aspect ratio.FIG. 3 shows a relationship between Si content and formability (TS×El).FIG. 1 reveals that a yield ratio of 0.90 or higher can be achieved by setting a total area fraction of ferrite and bainite to 90% or more.FIG. 2 reveals that a yield ratio of 0.90 or higher can be achieved by setting an aspect ratio to 3.0 or higher.FIG. 3 reveals that TS×El of 10,000 (MPa·%) or more can be achieved by setting a Si content to 0.5 to 2.0%.
Claims (16)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016047815 | 2016-03-11 | ||
JP2016-047815 | 2016-03-11 | ||
PCT/JP2017/008291 WO2017154727A1 (en) | 2016-03-11 | 2017-03-02 | High-strength thin steel sheet and method for manufacturing same |
Publications (1)
Publication Number | Publication Date |
---|---|
US20190078172A1 true US20190078172A1 (en) | 2019-03-14 |
Family
ID=59790448
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/083,725 Abandoned US20190078172A1 (en) | 2016-03-11 | 2017-03-02 | High-strength thin steel sheet and manufacturing method therefor |
Country Status (7)
Country | Link |
---|---|
US (1) | US20190078172A1 (en) |
EP (1) | EP3412787B1 (en) |
JP (2) | JP6458870B2 (en) |
KR (1) | KR102119017B1 (en) |
CN (1) | CN108699657B (en) |
MX (1) | MX2018010932A (en) |
WO (1) | WO2017154727A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20200306812A1 (en) * | 2017-10-02 | 2020-10-01 | Nippon Steel Corporation | Hot stamped product, steel sheet for hot stamp, and manufacturing method thereof |
CN113215485A (en) * | 2021-04-15 | 2021-08-06 | 首钢集团有限公司 | 780 MPa-grade thermal-base coating dual-phase steel and preparation method thereof |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019207636A1 (en) * | 2018-04-24 | 2019-10-31 | 株式会社Sbb66 | Method for manufacturing steel sheet comprising high-tensile-strength steel |
KR102237628B1 (en) * | 2019-08-26 | 2021-04-07 | 현대제철 주식회사 | High-strength steel sheet and method of manufacturing the same |
CN113088816B (en) * | 2021-03-27 | 2021-10-12 | 京泰控股集团有限公司 | Steel material for furniture and preparation method thereof |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3780611B2 (en) | 1997-03-31 | 2006-05-31 | Jfeスチール株式会社 | High strength and high yield ratio hot dip galvanized steel sheet and its manufacturing method |
JP4465490B2 (en) * | 1999-02-26 | 2010-05-19 | 独立行政法人物質・材料研究機構 | Precipitation hardened ferritic heat resistant steel |
JP3480357B2 (en) * | 1999-03-03 | 2003-12-15 | Jfeスチール株式会社 | Method for producing high strength galvanized steel sheet containing Si and high strength galvannealed steel sheet |
EP1577412B2 (en) * | 2002-12-24 | 2014-11-12 | Nippon Steel & Sumitomo Metal Corporation | High strength steel sheet exhibiting good burring workability and excellent resistance to softening in heat-affected zone and method for production thereof |
JP4317384B2 (en) * | 2003-04-28 | 2009-08-19 | 新日本製鐵株式会社 | High-strength galvanized steel sheet with excellent hydrogen embrittlement resistance, weldability and hole expansibility, and its manufacturing method |
JP4436275B2 (en) | 2005-03-30 | 2010-03-24 | 新日本製鐵株式会社 | High yield ratio high strength cold rolled steel sheet, high yield ratio high strength hot dip galvanized steel sheet, high yield ratio high strength alloyed hot dip galvanized steel sheet, and methods for producing them |
JP2007009253A (en) | 2005-06-29 | 2007-01-18 | Jfe Steel Kk | Method for manufacturing cold-rolled steel sheet having high yield ratio, high tensile strength and superior workability |
KR20080110904A (en) * | 2006-05-16 | 2008-12-19 | 제이에프이 스틸 가부시키가이샤 | High-strength hot-rolled steel plate having excellent stretch properties, stretch flanging properties and tension fatigue properties, and method for production thereof |
JP5194930B2 (en) | 2008-03-26 | 2013-05-08 | Jfeスチール株式会社 | High yield ratio high strength cold-rolled steel sheet |
BRPI0924410B1 (en) * | 2009-05-11 | 2018-07-17 | Nippon Steel & Sumitomo Metal Corp | hot rolled steel sheet having excellent drilling work capacity and fatigue properties, hot dip galvanized steel sheet, and production methods thereof |
JP5453973B2 (en) * | 2009-07-15 | 2014-03-26 | Jfeスチール株式会社 | High-strength cold-rolled steel sheet and manufacturing method thereof |
KR101329922B1 (en) * | 2010-09-29 | 2013-11-14 | 주식회사 포스코 | High strength and high bending formability thin cold-rolled sheet and method for manufacturing the cold-rolled sheet |
KR20140099544A (en) * | 2011-12-26 | 2014-08-12 | 제이에프이 스틸 가부시키가이샤 | High-strength steel sheet and method for manufacturing same |
JP5633594B2 (en) * | 2013-04-02 | 2014-12-03 | Jfeスチール株式会社 | Cold-rolled steel sheet excellent in punchability and heat-strain resistance and method for producing the same |
JP6015602B2 (en) * | 2013-09-11 | 2016-10-26 | Jfeスチール株式会社 | High toughness, high ductility, high strength hot-rolled steel sheet and method for producing the same |
JP5967320B2 (en) * | 2014-08-07 | 2016-08-10 | Jfeスチール株式会社 | High strength steel plate and manufacturing method thereof |
-
2017
- 2017-03-02 WO PCT/JP2017/008291 patent/WO2017154727A1/en active Application Filing
- 2017-03-02 CN CN201780015669.XA patent/CN108699657B/en active Active
- 2017-03-02 EP EP17763067.0A patent/EP3412787B1/en active Active
- 2017-03-02 MX MX2018010932A patent/MX2018010932A/en unknown
- 2017-03-02 US US16/083,725 patent/US20190078172A1/en not_active Abandoned
- 2017-03-02 JP JP2017533660A patent/JP6458870B2/en active Active
- 2017-03-02 KR KR1020187025909A patent/KR102119017B1/en active IP Right Grant
-
2018
- 2018-10-31 JP JP2018204774A patent/JP6610749B2/en active Active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20200306812A1 (en) * | 2017-10-02 | 2020-10-01 | Nippon Steel Corporation | Hot stamped product, steel sheet for hot stamp, and manufacturing method thereof |
US11565299B2 (en) * | 2017-10-02 | 2023-01-31 | Nippon Steel Corporation | Hot stamped product, steel sheet for hot stamp, and manufacturing method thereof |
CN113215485A (en) * | 2021-04-15 | 2021-08-06 | 首钢集团有限公司 | 780 MPa-grade thermal-base coating dual-phase steel and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
JPWO2017154727A1 (en) | 2018-03-15 |
WO2017154727A1 (en) | 2017-09-14 |
JP6610749B2 (en) | 2019-11-27 |
JP2019044269A (en) | 2019-03-22 |
EP3412787A1 (en) | 2018-12-12 |
CN108699657A (en) | 2018-10-23 |
JP6458870B2 (en) | 2019-01-30 |
KR20180112817A (en) | 2018-10-12 |
KR102119017B1 (en) | 2020-06-04 |
MX2018010932A (en) | 2018-11-22 |
EP3412787A4 (en) | 2018-12-12 |
EP3412787B1 (en) | 2021-01-06 |
CN108699657B (en) | 2021-02-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5141811B2 (en) | High-strength hot-dip galvanized steel sheet excellent in uniform elongation and plating property and method for producing the same | |
US10934600B2 (en) | High-strength steel sheet and production method therefor | |
US9708684B2 (en) | Hot dip galvanized and galvannealed steel sheet having excellent elongation properties | |
EP3366797A1 (en) | Hot press member and method for producing same | |
US9598755B2 (en) | High strength galvanized steel sheet having excellent deep drawability and stretch flangeability and method for manufacturing the same | |
US11965222B2 (en) | Method for producing hot-rolled steel sheet and method for producing cold-rolled full hard steel sheet | |
US20190078172A1 (en) | High-strength thin steel sheet and manufacturing method therefor | |
US11035019B2 (en) | High-strength steel sheet and production method therefor | |
JP6601253B2 (en) | High strength steel plate | |
US10570476B2 (en) | High-strength steel sheet and production method therefor | |
US20180023161A1 (en) | High-strength steel sheet and production method therefor | |
JPWO2016152135A1 (en) | High strength steel plate and manufacturing method thereof | |
KR102177591B1 (en) | High-strength steel sheet and its manufacturing method | |
JP6690793B1 (en) | High-strength steel sheet and method for manufacturing the same | |
US20190055621A1 (en) | High-strength galvanized steel sheet and method for producing the same | |
US11060157B2 (en) | Steel sheet, coated steel sheet, method for producing hot-rolled steel sheet, method for producing full hard cold-rolled steel sheet, method for producing steel sheet, and method for producing coated steel sheet | |
US20230374622A1 (en) | High-strength cold-rolled steel sheet, high-strength coated or plated steel sheet, method of producing high-strength cold-rolled steel sheet, and method of producing high-strength coated or plated steel sheet | |
JP2018003115A (en) | High strength steel sheet and manufacturing method therefor | |
JP7070812B1 (en) | High-strength cold-rolled steel sheet, high-strength plated steel sheet, high-strength cold-rolled steel sheet manufacturing method, high-strength plated steel sheet manufacturing method, and automobile parts | |
KR102451002B1 (en) | Plated steel sheet having excellent strength, formability and surface property and method for manufacturing the same | |
KR20120135840A (en) | High strength steel sheet for automobile having high compactibility and method of manufacturing the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: JFE STEEL CORPORATION, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:KIZU, TARO;REEL/FRAME:047391/0273 Effective date: 20180417 |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: FINAL REJECTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: ADVISORY ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: NON FINAL ACTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: FINAL REJECTION MAILED |
|
STPP | Information on status: patent application and granting procedure in general |
Free format text: ADVISORY ACTION MAILED |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |