US20100215910A1 - Profiled plastic piece that can be decorated, and method for the production thereof - Google Patents

Profiled plastic piece that can be decorated, and method for the production thereof Download PDF

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Publication number
US20100215910A1
US20100215910A1 US12/524,598 US52459808A US2010215910A1 US 20100215910 A1 US20100215910 A1 US 20100215910A1 US 52459808 A US52459808 A US 52459808A US 2010215910 A1 US2010215910 A1 US 2010215910A1
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US
United States
Prior art keywords
functional layer
substrate
plastic profile
primer
decorative coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US12/524,598
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English (en)
Inventor
Sven Kühnberger
Oliver Hagen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rehau Automotive SE and Co KG
Original Assignee
Individual
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Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39345536&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20100215910(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Assigned to REHAU AG + CO. reassignment REHAU AG + CO. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KUEHNBERGER, SVEN, MR, HAGEN, OLIVER, MR
Publication of US20100215910A1 publication Critical patent/US20100215910A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24612—Composite web or sheet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]

Definitions

  • the invention relates to a plastic profile which can be decorated, comprising a profiled substrate as the main body of the plastic profile.
  • surface properties such as surface structure, surface smoothness/roughness, porosity, penetration capability, gloss, color tone, surface tension, electrical conductivity, etc may vary due to variations in the raw materials used and their preparation and due to variation of the processing parameters during longer production times and/or between various manufacturing batches.
  • the cited influences make the reproducibility of a decorative coating more difficult with increasing time interval from the manufacturing of the substrate.
  • the invention is based on the object of providing a plastic profile which can be decorated, which allows reliable reproducibility over a run of the decorative coating even in the event of a longer time interval between the substrate manufacturing and a decorative coating.
  • the invention provides the plastic profile which can be decorated according to claim 1 , comprising: a profiled substrate as the main body of the plastic profile, and a functional layer which at least sectionally covers the substrate, which subsequently has a decorative coating applied, and a color absorption capability and/or color adhesiveness of the functional layer being set by a proportion of fillers and/or additives contained in the functional layer.
  • the functional layer is not itself subject to the cited disadvantageous influences on the ability to decorate plastic surfaces, so that the decorative coating is reliably reproducible over a run in spite of a time interval from the substrate manufacturing.
  • the pre-coated plastic profile may be stored or sent to a processor until the following decoration process.
  • the proportion of the fillers and/or additives influence is the wetting ability and/or absorbency of the functional layer, so that an optimum coating is ensured depending on the embodiment of the selected decoration.
  • the decorative coating can adhere on the functional layer and/or is at least partially absorbable in the functional layer.
  • the functional layer forms an adhesive base for the decorative coating and/or a type of “sponge” for absorbing color pigments or other decorative particles of the decorative coating.
  • the functional layer thus ensures an optimum color application and/or an optimum color intercalation, without complex pretreatment measures being necessary for the subsequent decorative coating.
  • the functional layer comprises:
  • the adhesion of the layered construction is influenced by the binder used.
  • the wetting and the absorbency of the functional layer are set via fillers and additives.
  • a coloration of the functional layer is performed via the colorant, preferably pigments and dyes, and is used for reproducibly providing a constant basic color tone for the subsequent decoration.
  • the cited composition ratio has proven to be particularly favorable.
  • the functional layer also comprises:
  • composition ratio has proven to be particularly advantageous in the event of a subsequent decorative coating in the inkjet method.
  • the binder may also be advantageously selected from polyacrylates, polymethacrylates, polyvinyl butyral, polyurethanes, polyesters, polyvinyl acetate, and mixtures and/or copolymers of the cited binder classes.
  • the plastic profile has priming between the substrate and the functional layer.
  • suitable adhesive promoters preferably based on solvents or water and/or UV-curing are applied to the plastic substrate, preferably in the rolling method or by spray application.
  • the priming improves the adhesion of the functional layer on the substrate and is selected as a function of the plastic of the substrate.
  • the priming is a water-based or radiation-curable priming.
  • the priming comprises:
  • the priming also comprises:
  • the substrate is physically treated, preferably on a surface covered by the functional layer. This improves the adhesion of adjoining layers on the substrate.
  • the functional layer is physically treated. This improves the adhesion of the decorative coating on the functional layer and/or its absorption in the functional layer.
  • the functional layer has a surface energy of 40 to 55 mN/m, preferably 47 to 52 mN/m. This promotes the quality of the wetting and adhesion of the decorative coating on the functional layer and the achievement of a good ink application flow with high surface coverage and color saturation.
  • the activation of the functional layer using physical pretreatment is preferably performed surely before the subsequent decoration.
  • the plastic profile is implemented as an edge strip or as an angled profile.
  • Edge strips and/or angled profiles are typically tailored to matching furniture body parts in regard to the decoration, so that the invention having the effect of the subsequent decorative coating of plastic profiles which is reliable over a run is particularly suitable for this purpose.
  • a further aspect of the invention relates to a method for producing a plastic profile which can be decorated, comprising the following steps:
  • step a) comprises the extrusion of the profiled substrate.
  • the extrusion method allows a particularly cost-effective production of the profiled substrate.
  • step b) comprises a corona treatment, preferably using low-frequency/high-frequency corona, flaming, plasma treatment, fluorination, silicating, preferably flame pyrolysis of silanes, or a combination thereof.
  • the surface energy of the substrate may easily be increased to greater than 40 mN/m using the cited measures.
  • step c) comprises: the application of the priming by spraying, roller application, pouring, flooding, preferably using an application weight of 5 to 20 g/m 2 wet film thickness. This measure encourages the adhesion of adjoining layers on the substrate surface.
  • step d) comprises: the application of the functional layer by spraying, roller application, pouring, or flooding, preferably using an application weight of the functional layer as a function of the requirements between 1 and 100 g/m 2 wet film thickness, preferably by multiple coats at low application weight.
  • the method also comprises:
  • step e) comprises a corona treatment, preferably using low-frequency/high-frequency corona, flaming, plasma treatment, fluorination, silicating, preferably flame pyrolysis of silanes, or a combination thereof.
  • the surface energy of the substrate may easily be increased to greater than 47 mN/m using the cited measures.
  • a further preferred aspect of the invention relates to a decorated edge strip, comprising: a profiled substrate as the main body, a functional layer which at least sectionally covers the substrate, the functional layer subsequently having a decorative coating applied.
  • FIG. 1 schematically shows a method and/or a device for producing a plastic profile which can be decorated according to the invention.
  • FIG. 2 shows a section II-II of a profiled substrate from FIG. 1 .
  • FIG. 3 shows a section III-III of a physically pretreated, profiled substrate from FIG. 1 .
  • FIG. 4 shows a section IV-IV of a physically pretreated substrate, which is provided with priming, from FIG. 1 .
  • FIG. 5 shows a section V-V of a physically pretreated substrate, which is provided with the functional layer and the priming, from FIG. 1 .
  • FIG. 6 schematically shows a method and/or a device for the subsequent decorative coating of the plastic profile which can be decorated according to the invention.
  • FIG. 7 shows a section VII-VII of the plastic profile according to the invention from FIG. 6 .
  • FIG. 8 shows a section VIII-VIII of the plastic profile according to the invention having physically treated functional layer from FIG. 6 .
  • FIG. 9 shows a section VIIII-VIIII of the plastic profile, which subsequently has a decorative coating applied, having physically treated functional layer from FIG. 6 .
  • the invention described hereafter with reference to FIGS. 1 through 9 relates to a plastic profile 1 , which can be decorated, comprising a profiled substrate as the main body of the plastic profile I and a functional layer 5 , which at least sectionally covers the substrate 2 and which may subsequently have a decorative coating 6 applied.
  • a plastic profile 1 is shown on the basis of the sectional illustration V-V of FIG. 5 .
  • the physical pretreatment of the substrate 2 and the application of a priming 4 are not absolutely necessary. These measures may be selected in order to achieve a better bonding of the substrate 2 to the functional layer 5 for specific plastics of the substrate 2 .
  • the decorative coating 6 (e.g., color pigments, decorative particles, etc.) can adhere on the functional layer 5 and/or can be at least sectionally absorbed in the functional layer 5 .
  • the functional layer 5 preferably has a physically pretreated surface 5 ′.
  • the intercalation of fillers and/or additives in the functional layer 5 influences the wetting ability and/or absorbency of the functional layer 5 .
  • a color print and/or a color lacquering are preferably provided as the decorative coating 6 .
  • the color print is preferably applied via printing rollers or applied without contact, for example, in the event of inkjet printing.
  • the functional layer 5 preferably has the following composition:
  • the plastic profile 1 may have a primer 4 between the substrate 2 and the functional layer 5 .
  • the primer 4 preferably has the following composition:
  • a water-based primer cross-linkable polyurethane dispersion
  • a radiation-curing primer e.g., radically and/or cationically curing UV primer
  • the profiled substrate 2 may be physically treated, preferably on a surface 3 covered by the functional layer 5 .
  • the surface energy of the substrate is increased to greater than 40 mN/m by the physical treatment.
  • the functional layer 5 may be physically treated.
  • the physically treated functional layer preferably has a surface energy of 40 to 55 mN/m, more preferably 47 to 52 mN/m.
  • the plastic profile 1 is implemented as an edge strip or as an angled profile.
  • the method according to the invention for producing the plastic profile 1 which can be decorated comprises the following steps:
  • FIG. 1 schematically shows a device and/or a method for producing the plastic profile 1 which can be decorated according to the invention.
  • Step a) comprises the provision of a profiled substrate using a provision apparatus 12 .
  • An extruder is preferably provided as the provision apparatus 11 , the profiled substrate 2 being extruded.
  • the cross-section of the substrate 2 after the execution of step a) is schematically shown in section II-II of FIG. 2 .
  • Other cross-sectional profiles of the substrate 2 may also be executed in addition to the rectangular cross-sectional profile.
  • Step b) comprises a physical pretreatment of the substrate 2 , which is necessary in particular for low-energy surfaces such as polyolefins.
  • the functional layer 5 may also be applied directly to the substrate 2 without physical pretreatment of the substrate 2 .
  • the surface treatment which is recommended for specific low-energy surfaces for reasons of adhesion, may be performed via a corona treatment, preferably using low-frequency/high-frequency corona, flaming, plasma treatment, fluorination, silicating, preferably flame pyrolysis of silanes, or a combination thereof.
  • the goal of step b) is to increase the surface energy of the substrate to greater than 40 mN/m.
  • Step b) is performed in an apparatus 12 for the physical pretreatment of the substrate 2 .
  • a surface 3 of the substrate which is to be covered using the functional layer 5 is processed in the scope of the cited measures.
  • the cross-section of the substrate 2 having physically pretreated substrate surface 3 ′, after execution of step b), is shown in section III-III of FIG. 3 .
  • Step c) comprises the priming of the physically pretreated substrate surface 3 ′.
  • step c) is not absolutely necessary to produce the plastic profile 1 which can be decorated according to the invention.
  • the priming of the substrate surface 3 ′ is only required for low-energy surfaces such as polyolefins.
  • the substrate may also be equipped with a printing primer, such as an adhesion promoter or a pre-coat.
  • the application of the priming and/or the primer 4 is performed in a suitable apparatus 13 (symbolically shown in FIG. 1 ) by spraying, roller application, pouring, flooding, etc.
  • the primer 4 preferably has the above-mentioned composition.
  • the cross-section of the substrate 2 having the primer 4 applied on the physically pretreated surface 3 ′ is shown in section IV-IV of FIG. 4 .
  • Step d) comprises the application of the functional layer 5 on the substrate 2 and/or on the primer 4 .
  • the functional layer 5 forms the adhesive base for the later decorative coating 6 and preferably has the above-mentioned composition.
  • the adhesion of the layered construction is influenced by the binder used.
  • the wetting and the absorbency of the functional layer 5 are set via fillers and additives. Coloration of the functional layer 5 occurs via typical colorants, such as pigments and other dyes, and is used for reproducibly providing a constant basic color tone for the subsequent decoration.
  • the application of the functional layer 5 may be performed by spraying, roller application, pouring, flooding, etc.
  • the application weight of the functional layer 5 is between 1 and 100 g/m 2 wet film thickness as a function of the requirements.
  • Step d) is performed in a suitable apparatus for applying the functional layer 5 .
  • the state of the substrate 2 having physically pretreated surface 3 ′, applied primer 4 , and applied functional layer 5 after completed step d) is illustrated in section V-V of FIG. 5 .
  • the plastic profile 1 which can be decorated is finished and is prepared for storage or transport.
  • the plastic profile 1 which can be decorated is preferably stored onto a storage apparatus, e.g., rolled onto a storage spool 15 .
  • FIG. 6 schematically shows a device and/or a method for the subsequent decorative coating of the plastic profile 1 which can be decorated according to the invention.
  • the plastic profile 1 which can be decorated according to the invention is provided by a provision apparatus 16 .
  • the plastic profile 1 is unwound from a storage coil 16 and supplied to the following method steps and/or devices.
  • the cross-section of the plastic profile 1 comprising the substrate 2 having physically treated surface 3 ′, the primer 4 , and the functional layer 5 , after execution of step d) and before execution of step e), is illustrated in section VII-VII of FIG. 7 .
  • steps b) and c) are not absolutely necessary for producing the plastic profile 1 according to the invention.
  • the plastic profile 1 according to the invention does not necessarily comprise a physically treated surface 3 ′ or a primer 4 , as shown in FIG. 5 . In such a case, the functional layer 5 is bonded directly to the substrate 2 .
  • Step e) comprises the physical treatment of the functional layer 5 before the subsequent decoration of the plastic profile 1 in an apparatus 17 suitable for this purpose.
  • an activation of the functional layer 5 using physical pretreatment in a suitable apparatus 17 is performed shortly before the subsequent decoration of the plastic profile 1 .
  • the activation of the functional layer 5 is preferably performed by corona treatment, preferably using low-frequency/high-frequency corona, flaming, plasma treatment, fluorination, silicating, preferably flame pyrolysis of silanes, or a combination thereof.
  • step e an increase of the surface energy of the functional layer from an average of 41 to 43 mN/m before the activation to 47 to 52 mN/m after the activation and/or treatment is achieved.
  • the surface energy of the functional layer 5 is determined via contact angle measurements.
  • the cross-section of the plastic profile 1 after execution of step e) is illustrated in section VIII-VIII of FIG. 2 .
  • the functional layer 5 After execution of step e), the functional layer 5 has a roughened and/or activated surface 5 ′.
  • Step f) comprises the application of the decorative coating 6 to the functional layer 5 in a suitable apparatus 18 for applying the decorative coating 6 on the functional layer 5 .
  • the application of the decorative coating 6 is preferably performed by roller application or without contact in the inkjet method.
  • the state of the decoratively-coated plastic profile 1 after execution of step f) is illustrated in section VIIII-VIIII of FIG. 9 .
  • the plastic profile 1 according to the invention is preferably used as an angled profile or edge strip for the decoration of furniture parts or the like.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Laminated Bodies (AREA)
US12/524,598 2007-01-27 2008-01-23 Profiled plastic piece that can be decorated, and method for the production thereof Abandoned US20100215910A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102007004229A DE102007004229A1 (de) 2007-01-27 2007-01-27 Dekorierbares Kunststoffprofil und Verfahren zu dessen Herstellung
DE102007004229.0 2007-01-27
PCT/EP2008/000492 WO2008089967A1 (de) 2007-01-27 2008-01-23 Dekorierbares kunststoffprofil und verfahren zu dessen herstellung

Publications (1)

Publication Number Publication Date
US20100215910A1 true US20100215910A1 (en) 2010-08-26

Family

ID=39345536

Family Applications (1)

Application Number Title Priority Date Filing Date
US12/524,598 Abandoned US20100215910A1 (en) 2007-01-27 2008-01-23 Profiled plastic piece that can be decorated, and method for the production thereof

Country Status (8)

Country Link
US (1) US20100215910A1 (de)
EP (1) EP2111425B1 (de)
CN (1) CN101589095A (de)
AT (1) ATE502977T1 (de)
DE (2) DE102007004229A1 (de)
PL (1) PL2111425T3 (de)
PT (1) PT2111425E (de)
WO (1) WO2008089967A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105946318A (zh) * 2016-05-25 2016-09-21 上海美挚网络科技有限公司 一种塑料制品及其制备方法

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DE102008010738A1 (de) * 2007-12-20 2009-06-25 Rehau Ag + Co. Verfahren zum Herstellen eines dekorierten Profilkörpers
CN102602095B (zh) * 2012-03-08 2015-09-23 江阴市信科塑胶五金有限公司 冰箱彩塑覆膜饰条及其制备方法
DE102012112607A1 (de) 2012-12-19 2014-06-26 W. Döllken & Co. GmbH Kunststoffleiste
DE202014102839U1 (de) * 2014-06-23 2015-09-24 Rehau Ag + Co. Magnetband mit Dekorationselement
DE102018129558A1 (de) * 2018-11-23 2020-05-28 Rehau Ag + Co Verfahren zur Herstellung eines Fenster- oder Tür-Hohlkammerprofiles
EP4357146A1 (de) * 2022-10-21 2024-04-24 Printec GmbH Kantenleiste

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US4382115A (en) * 1980-10-20 1983-05-03 Daicel Chemical Industries, Ltd. Film coated with solution containing a vinylidene chloride copolymer and surface active agent
US6177496B1 (en) * 1998-01-27 2001-01-23 Charles F Luzon Process for making organic materials receptive to coloring agents and adhesives
US20020086940A1 (en) * 2000-09-19 2002-07-04 Seiji Ota Modified polyolefin and resin composition containing the same
US20030104125A1 (en) * 2000-05-09 2003-06-05 Detlef Busch Transparent, biaxially orientated polyolefinic film with improved bonding properties
US20040209085A1 (en) * 2001-09-05 2004-10-21 Amin Erb Gluing plastic extrudates to material surfaces
US20050064182A1 (en) * 2003-09-23 2005-03-24 3M Innovative Properties Company Adhesive articles including a nanoparticle primer and methods for preparing same

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US4382115A (en) * 1980-10-20 1983-05-03 Daicel Chemical Industries, Ltd. Film coated with solution containing a vinylidene chloride copolymer and surface active agent
US6177496B1 (en) * 1998-01-27 2001-01-23 Charles F Luzon Process for making organic materials receptive to coloring agents and adhesives
US20030104125A1 (en) * 2000-05-09 2003-06-05 Detlef Busch Transparent, biaxially orientated polyolefinic film with improved bonding properties
US20020086940A1 (en) * 2000-09-19 2002-07-04 Seiji Ota Modified polyolefin and resin composition containing the same
US20040209085A1 (en) * 2001-09-05 2004-10-21 Amin Erb Gluing plastic extrudates to material surfaces
US20050064182A1 (en) * 2003-09-23 2005-03-24 3M Innovative Properties Company Adhesive articles including a nanoparticle primer and methods for preparing same

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Publication number Priority date Publication date Assignee Title
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Also Published As

Publication number Publication date
PL2111425T3 (pl) 2011-08-31
CN101589095A (zh) 2009-11-25
EP2111425B1 (de) 2011-03-23
DE502008002940D1 (de) 2011-05-05
ATE502977T1 (de) 2011-04-15
DE102007004229A1 (de) 2008-07-31
EP2111425A1 (de) 2009-10-28
WO2008089967A1 (de) 2008-07-31
PT2111425E (pt) 2011-07-01

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