US1681335A - Stable suspension and paste of coal - Google Patents
Stable suspension and paste of coal Download PDFInfo
- Publication number
- US1681335A US1681335A US177832A US17783227A US1681335A US 1681335 A US1681335 A US 1681335A US 177832 A US177832 A US 177832A US 17783227 A US17783227 A US 17783227A US 1681335 A US1681335 A US 1681335A
- Authority
- US
- United States
- Prior art keywords
- coal
- paste
- stable suspension
- parts
- stable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
Definitions
- alcohols such as methanol and may be obtained by stabilising said alcohols, for example, alkali metals or ammonia, pyridine, aniline and the like.
- coal may already contain example crude coal-tar oils.
- the parts are by weight.
- the stability of the suspension or paste of be further improved by an addition of mineral oils, more especially those which finely divided carbon, as for etroleum or certain brownhe resulting suspensions or pastes are highly suitable for example as heating oils or as original materials for as the destructive ground brown-coal (ligor several hours in a ball mill or disintegrator with 25 parts of crude isobutyl alcohol (products of high boiling point of the synthesis of methanol from oxide of carbon) containing 1 part of sodium hydroxid in solution until the mixture no longer separates into its components and a stable, oleaginous and viscous suspension of brown coal has been formed.
- mineral oils more especially those which finely divided carbon
Description
Patented Aiig. 21, 1928.
ROBERT GBIESSBACH AND JULIUS EISELE, OF LUDWIGSHAIEN-ON-THE-RHINE, GER.-
Mm, ASSIGNORS TO I. o. roar-on-rnn-unn, GERMANY,
FARBENINDUSTRIE AKTIENGESELLSCHAFT, OF FRANK- .A CORPORATION OF GERMANY.
.STABLE SUSPENSION 'AIl'D IASTE OF COAL.
Ho Drawing. Application filed March 23, 1927, Serial No. 177,832, and in Germany March 24, 1926.
A variety of of coal in which agents.
many purposes, ma the aforementione dispersion of coal, by alcohols, such as methanol and may be obtained by stabilising said alcohols, for example, alkali metals or ammonia, pyridine, aniline and the like.
By suitably coal may already contain example crude coal-tar oils.
chemical purposes such hydrogenation of coal.
The following examples will further illustrate the nature of the said invention but the invention is not limited to these examples.
The parts are by weight.
Example I.
10 parts of fine] nite) are treated rocesses are already known for the production of suspensions or pastes processes viscous hydrocarbons or oils are employed as dispersing proportioning the amount of coal, it is possible to obtain stable, oleaginous suspensions or pastes of coal possessing from low to maximum viscosity. In many cases the stability of the suspension or paste of be further improved by an addition of mineral oils, more especially those which finely divided carbon, as for etroleum or certain brownhe resulting suspensions or pastes are highly suitable for example as heating oils or as original materials for as the destructive ground brown-coal (ligor several hours in a ball mill or disintegrator with 25 parts of crude isobutyl alcohol (products of high boiling point of the synthesis of methanol from oxide of carbon) containing 1 part of sodium hydroxid in solution until the mixture no longer separates into its components and a stable, oleaginous and viscous suspension of brown coal has been formed.
Ewample 2.
1 part of finely ground brown-coal is treated with 5 parts of crude isobutyl alcohol ner described in Example 1, a stable suspension of brown coal, possessing lower viscosity than that described in the foregoing example, being produced.
Ewample 3.
40 parts of brown. coal are treated with 90 parts of crude isobutyl alcohol, 1 part of sodium hydroxid and 5 parts of brown-coal tar oil, as in Example 1, a highly viscous mass, specially adapted to form the original material for the destructive hydrogenation of coal, being obtained. y
Other varieties of coal or bitumens, for. example pit coaland thelike, can also betreated in the same manner as hereinbefore described. 5
Whatwe claim is:
1. The process of producing stable suspensions of coal which consists in mechanically dispersing the coal in a liquid alcohol with an addition ofa base soluble therein.
2. The process ofproducing stable suspensions of coal which consists in mechanically dispersing the coal in crude synthetic isobutyl alcohol.
In testimony whereof we have hereunto set our hands.
ROBERT GRIESSBACH. JULIUS EISELE.
methylamine,
and 1 part of pyridine or aniline, in the man'- V
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1681335X | 1926-03-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1681335A true US1681335A (en) | 1928-08-21 |
Family
ID=7739223
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US177832A Expired - Lifetime US1681335A (en) | 1926-03-24 | 1927-03-23 | Stable suspension and paste of coal |
Country Status (1)
Country | Link |
---|---|
US (1) | US1681335A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3850477A (en) * | 1972-02-18 | 1974-11-26 | Univ Syracuse Res Corp | Chemical comminution and mining of coal |
US4045092A (en) * | 1975-09-22 | 1977-08-30 | The Keller Corporation | Fuel composition and method of manufacture |
US4177039A (en) * | 1977-11-29 | 1979-12-04 | Lion Yushi Kabushiki Kaisha | Dispersant for coal into oils |
US4425135A (en) | 1980-07-07 | 1984-01-10 | Rodman Jenkins | Motor fuel containing refined carbonaceous material |
US4546925A (en) * | 1983-09-09 | 1985-10-15 | General Electric Company | Supermicronized process for coal comminution |
US4711643A (en) * | 1981-12-14 | 1987-12-08 | Ashland Oil, Inc. | Stabilized coal oil mixtures |
US4802891A (en) * | 1986-04-15 | 1989-02-07 | Mitsui Mining Company, Limited | Coal-methanol slurry and its production process |
-
1927
- 1927-03-23 US US177832A patent/US1681335A/en not_active Expired - Lifetime
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3850477A (en) * | 1972-02-18 | 1974-11-26 | Univ Syracuse Res Corp | Chemical comminution and mining of coal |
US4045092A (en) * | 1975-09-22 | 1977-08-30 | The Keller Corporation | Fuel composition and method of manufacture |
US4177039A (en) * | 1977-11-29 | 1979-12-04 | Lion Yushi Kabushiki Kaisha | Dispersant for coal into oils |
US4425135A (en) | 1980-07-07 | 1984-01-10 | Rodman Jenkins | Motor fuel containing refined carbonaceous material |
US4711643A (en) * | 1981-12-14 | 1987-12-08 | Ashland Oil, Inc. | Stabilized coal oil mixtures |
US4546925A (en) * | 1983-09-09 | 1985-10-15 | General Electric Company | Supermicronized process for coal comminution |
US4802891A (en) * | 1986-04-15 | 1989-02-07 | Mitsui Mining Company, Limited | Coal-methanol slurry and its production process |
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