US1005629A - Forming compound bodies of different metals. - Google Patents

Forming compound bodies of different metals. Download PDF

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Publication number
US1005629A
US1005629A US50251609A US1909502516A US1005629A US 1005629 A US1005629 A US 1005629A US 50251609 A US50251609 A US 50251609A US 1909502516 A US1909502516 A US 1909502516A US 1005629 A US1005629 A US 1005629A
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United States
Prior art keywords
copper
metal
electro
different metals
forming compound
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US50251609A
Inventor
Henry W Fisher
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STANDARD UNDERGROUND CABLE Co
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STANDARD UNDERGROUND CABLE Co
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Priority to US50251609A priority Critical patent/US1005629A/en
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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/288Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition
    • H01L21/2885Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition using an external electrical current, i.e. electro-deposition

Definitions

  • My invention relates to improvements in methods of forming compound bodies of metal and the object of my improvement is to produce such articles of compound character which shall be more intimately united,
  • a copper solution may conven iently be a solution of cupric chlorid in borax, or it may be cupric chlorid or fluorid in boraX or in an alkaline chlorid such as chlorid of sodium or chlorid of potassium.
  • the operation is to provide a cell of suitable refractory material and place within .it the flux and the copper salt and bring them to the melting point of copper; which is about 1913 F., at which temperature the flux will contain the copper salt in solutionr I then introduce into such electrolyte the body of iron to be electro-plated, as .the cathode, and I preferably introduce, as
  • the anode a stick of'graphite, or I may make the inner wall-of the cell itself the anode, making the proper connections, and
  • the wall of the cell will preferably be faced with graphite. Electrolysis then progresses at this high temperature and the plated coating being laid down .at a temperature at which the copper is molten, instead of being porous and spongy and imperfectly adhering to the surface of the iron, is compact, and adheres closely to the iron surface.
  • the operation is stopped, and thereafter, according to my present invention, the already plated blank is provided with a further layer of metal, which ma be either copper or some other metal WhlCh will readily unite with copper, deposited upon the previously electroplated surface by electro-plating in the manner in which that operation is'usually practiced; that is,'at substantially normal atmospheric temperature.
  • a further layer of metal which ma be either copper or some other metal WhlCh will readily unite with copper, deposited upon the previously electroplated surface by electro-plating in the manner in which that operation is'usually practiced; that is,'at substantially normal atmospheric temperature.
  • This supplemental body of deposited metal will of course be less compact than theinitial layer of plating, but it' will be compacted by furt her treatment to which such blanks are ordinarily subjected in reducing them to sheets, wires, and other forms; but, being either of identical material with the initial electroplated layer, or of a metal which readily I unites with that initial layer, the adhesion of the whole will be more perfect
  • 'my invention is not limited in its application to the use of copper and iron, but may be generally employed in the formation of articles in layers of metals of different kinds.
  • the herein described method of coating iron with copper which consists in electro-plating a body of iron with copper at a temperature as great as the melting-point of copper, and then electro-plating a further deposit of copper upon such coppercoated body at substantially atmospheric temperature.

Description

UNITED, STATES PATENT OFFICE,
HENRY W. FISHER, OF PITTSBURGH, PENNSYLVANIA, ASSIGNOR T STANDARD UNDER- GROU'ND CABLE COMPANY, A CORPORATION OF PENNSYLVANIA.
FORMING COMPOUND BODIES OF DIFFERENT METALS,
No Drawing,
Specification of Letters Patent.
Patented Oct. 10, 1911.
Application filed June 16, 1909. Serial No. 502,516.
To alliwhom it may concern:
Be 1t known that I, HENRY FISHER,
v residing at Pittsburgh, in the county of Allegheny and State of Pennsylvania, a citizen of the United States, have invented or discovered certain new and useful Improvements in Methods of Forming Oompound Bodies of Different Metals, of which improvements the following is' a specification.
My invention relates to improvements in methods of forming compound bodies of metal and the object of my improvement is to produce such articles of compound character which shall be more intimately united,
and for that reason more serviceable than articles of that general character as have heretofore ordinarily been made. -Thearticles of this general nature may'be made of metals of different kinds, and the metals may be of different classes and characters, andmy invention is not in its broader aspect limited to any particular metals or to any particular combination of metals, but the invention finds its peculiar application in the preparation of blanks from which operation which is my invention, and which consists in electro-plating an iron core or body with copper, carrying on the process of electroplating at a temperature as great as. themelting-point of copper, and then adding, if so desired, a supplemental body of metal to the iron body so electro-plated. In that earlier specification I have described that this supplemental body of metal, whether of copper or ofsome other material which readily unites with the electroplated coating, *is applied either by elec-.
trolysis at normal temperature. or .by casting in a mold about the previously electr'oe In my present applicaplated iron core.
v tion I lay specific claim to the electrolytic deposit of this supplemental body of metal upon the previously electroplated core, this electrolytic deposit being formed at ordinary temperature.
In the practice of my invention, I employ as an electrolyte for the initial electro-plating a solution of copper which may be maintained in the liquid state at a temperature as high as the melting-point of copper, such a copper solution may conven iently be a solution of cupric chlorid in borax, or it may be cupric chlorid or fluorid in boraX or in an alkaline chlorid such as chlorid of sodium or chlorid of potassium. The operation, as I have described it in my said application, is to provide a cell of suitable refractory material and place within .it the flux and the copper salt and bring them to the melting point of copper; which is about 1913 F., at which temperature the flux will contain the copper salt in solutionr I then introduce into such electrolyte the body of iron to be electro-plated, as .the cathode, and I preferably introduce, as
the anode, a stick of'graphite, or I may make the inner wall-of the cell itself the anode, making the proper connections, and
in that case the wall of the cell will preferably be faced with graphite. Electrolysis then progresses at this high temperature and the plated coating being laid down .at a temperature at which the copper is molten, instead of being porous and spongy and imperfectly adhering to the surface of the iron, is compact, and adheres closely to the iron surface. When this electrolytic operation has progressed sufiiciently to form a plating of desired amount, the operation is stopped, and thereafter, according to my present invention, the already plated blank is provided with a further layer of metal, which ma be either copper or some other metal WhlCh will readily unite with copper, deposited upon the previously electroplated surface by electro-plating in the manner in which that operation is'usually practiced; that is,'at substantially normal atmospheric temperature.- This supplemental body of deposited metal will of course be less compact than theinitial layer of plating, but it' will be compacted by furt her treatment to which such blanks are ordinarily subjected in reducing them to sheets, wires, and other forms; but, being either of identical material with the initial electroplated layer, or of a metal which readily I unites with that initial layer, the adhesion of the whole will be more perfect than is the case where the entire added body is electro-plated upon the iron at normal temperature.
It will be understood that 'my invention is not limited in its application to the use of copper and iron, but may be generally employed in the formation of articles in layers of metals of different kinds.
I claim as my invention: K a
1. The herein described method of'forming articles of different metals which con sists in electro-plating upon the surface of a body of one metal a layer of another metal at a temperature as high as the melting point of such second named metal, and then making electrolytic deposit of a, third body of metal upon the body of metal electro plated as aforesaid.
2. The herein described method of forming articles of diiferent metals which consists in electro-plating upon one body of metal a second body of metal at a temperature as great as the melting-point of the metal of which said second body is composed, and then electrolytically depositing upon such electro-plated body a second deposit or body of metal, said second electrolytic operation being performed at substantially normal atmospheric temperature.
3. The herein described method of coating iron with copper which consists in electro-plating a body of iron with copper at a temperature as great as the melting-point of copper, and then electro-plating a further deposit of copper upon such coppercoated body at substantially atmospheric temperature.
In testimony whereof, I have hereunto set my hand.
HENRY W. FISHER.
Witnesses CHARLES BARNETT, FRIEDA E. WoLrF.
US50251609A 1909-06-16 1909-06-16 Forming compound bodies of different metals. Expired - Lifetime US1005629A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2995814A (en) * 1957-10-11 1961-08-15 Harold A Chamness Method for soldering aluminum
US6656606B1 (en) 2000-08-17 2003-12-02 The Westaim Corporation Electroplated aluminum parts and process of production
US20100313629A1 (en) * 2009-06-10 2010-12-16 International Engine Intellectual Property Company , Llc Preventing Soot Underestimation in Diesel Particulate Filters by Determining the Restriction Sensitivity of Soot
US20110025045A1 (en) * 2009-07-29 2011-02-03 International Engine Intellectual Property Company, Llc Fitting with audible misassembly indicator

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2995814A (en) * 1957-10-11 1961-08-15 Harold A Chamness Method for soldering aluminum
US6656606B1 (en) 2000-08-17 2003-12-02 The Westaim Corporation Electroplated aluminum parts and process of production
US6692630B2 (en) 2000-08-17 2004-02-17 The Westaim Corporation Electroplated aluminum parts and process for production
US20100313629A1 (en) * 2009-06-10 2010-12-16 International Engine Intellectual Property Company , Llc Preventing Soot Underestimation in Diesel Particulate Filters by Determining the Restriction Sensitivity of Soot
US20110025045A1 (en) * 2009-07-29 2011-02-03 International Engine Intellectual Property Company, Llc Fitting with audible misassembly indicator

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