TWI575125B - Green energy-saving fiber, its preparation method and the fabric made of the fiber - Google Patents
Green energy-saving fiber, its preparation method and the fabric made of the fiber Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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本發明係有關一種綠能環控纖維、其製法及以該纖維製成之織品，應用於有機環境控制農作產業如農業植物綠能環控溫室及植物綠能環控工廠等，或應用於生活中環境控制設備如健康照護綠能環控織品、室內空氣品質綠能環控織品、油煙綠能環控織品、地工植生綠能環控織品、除霧綠能環控織品、空氣清淨綠能環控織品、環境污染防治綠能環控織品等。運用環境中綠色能源，如太陽光能、太陽熱能、風力能、水力能、地熱能等再生能源，纖維材料接收環境中各式綠能輻射波產生自由電子效應，藉由纖維內部組成有光電材料、熱電材料及壓電材料對綠能輻射波自然能量產生增輻作用進而作用於織品纖維中各類觸媒材料，有效提升觸媒材料之各類機能，使觸媒纖維及製品藉由綠能產生對植物生長有利之生長光線、水氧負離子、遠紅外線生長波、防治病蟲害及對生長環境污染物去除沉降分解及潔淨。 The invention relates to a green energy environmental control fiber, a preparation method thereof and a fabric made of the fiber, and is applied to an organic environment control agricultural industry such as an agricultural plant green energy environmental control greenhouse and a plant green energy environmental control factory, or the like. Environmental control equipment in life such as health care green energy environmental control fabric, indoor air quality green energy environmental control fabric, fume green energy environmental control fabric, geotextile green energy environmental control fabric, defogging green energy control fabric, air clear green It can control environmentally-friendly fabrics and environmental pollution control green energy control fabrics. The use of green energy in the environment, such as solar energy, solar thermal energy, wind energy, hydropower, geothermal energy and other renewable energy sources, the various types of green energy radiation waves in the fiber material receiving environment produce free electron effects, and the interior of the fiber is composed of photoelectric materials. The thermoelectric material and the piezoelectric material have an effect on the natural energy of the green energy radiation wave and act on various kinds of catalyst materials in the fabric fiber, thereby effectively improving various functions of the catalyst material, so that the catalyst fiber and the product are green energy. It produces growth light, water and oxygen anion, far-infrared growth wave, prevention of pests and diseases, and sedimentation decomposition and cleansing of growth environment pollutants.
因應人口增加所產生的糧食需求大增及糧食危機，人類想盡各種農作方法如基因改質、使用化學農藥、化學肥料及生長激素、微生物肥料等來增加糧食產量。為了解決糧食需求大增及糧食危機的問題，目前所採用前述的農作方法也伴隨著大量農藥使用，以致環境污染日趨嚴重，惡劣的污染環境直接對人體健康造成傷害，而日後隨著氣候 變遷及新的病蟲害增加，反而更使農作物產量減少，土壤酸化惡性循環之下，糧食危機問題始終無法從根本解除。產量增加及有機栽種之需求，產生了農業環境及農作物之質與量，亟待解決及克服的課題。良好的自然環境資源有限，為了農業永續發展，根本上解決人類糧食缺乏的問題及提升食的安全與健康，人類應該學習大自然環境生生不息的自然循環原理。善加利用永續不斷的綠色能源，將轉換綠色能源發揮最大效益，運用材料特性及與綠色能源自然交互作用原理，以自然方式創造出合適有機環境控制之農業生產，才有機會根本解決前述現今農作方法所造成的惡性循環問題，以滿足糧食需求及提供農作物食用上的安全。 In response to the increase in food demand and the food crisis caused by the increase in population, humans have tried various farming methods such as genetic modification, chemical pesticides, chemical fertilizers, growth hormones, and microbial fertilizers to increase food production. In order to solve the problem of increasing food demand and the food crisis, the current farming methods are also accompanied by the use of a large number of pesticides, resulting in increasingly serious environmental pollution, and the harsh environment directly causes harm to human health, and in the future, with the climate Changes and new pests and diseases have increased, but crop yields have decreased. Under the vicious cycle of soil acidification, the food crisis has never been lifted. The increase in production and the demand for organic planting have created problems in the agricultural environment and the quality and quantity of crops that need to be solved and overcome. Good natural environment and resources are limited. In order to solve the problem of human food shortage and improve the safety and health of food for the sustainable development of agriculture, human beings should learn the natural circulation principle of the natural environment. We will continue to use the sustainable green energy to maximize the benefits of converting green energy, using material characteristics and natural interaction with green energy, and creating agricultural products with suitable organic environment control in a natural way. The vicious circle caused by farming methods to meet food demand and provide safe food for consumption.
雖然習知技術中，有在織物上添加觸媒等機能性材料，藉觸媒材料的作用而產生除臭及抗菌的功能。然而，習知技術一種方式是在織物表面塗覆機能性材料，不僅機能性材料在未能有效增輻下，而無法發揮其效能，而且經一段時間使用便會脫落，此種技術的經濟效益並不高。其他技術則，例如美國第4,784,909號專利案，是在纖維內添加銅而有抗菌除臭的功能。例如美國第6,540,807號專利案，在織品中添加熱塑性塑膠樹脂及抗菌劑而具有抗菌功能。例如美國第5,690,922號專利案，係纖維添加金屬磷酸鹽及金屬氫氧化物而具除臭功能。然而，前述的那些習知技術，纖維中的機能性材料在未能有效增輻下只能在有效空間內達到效益。再者，雖然有業者開發以LED燈來發射出有利於藍光及紅光植物生長的光線以供種植蔬果之用，惟使用LED燈因為需電力，且器具貴，相對地成本較高，不僅產生耗能問題，而且並無法防治病蟲害，仍必須依賴農藥或生物防治或需另外加裝利用網目隔離蟲害護網或採用密 閉式塑膠棚、玻璃溫室等方式，但仍無法有效做到環境控制的功效。 In the prior art, a functional material such as a catalyst is added to the fabric to produce a deodorizing and antibacterial function by the action of the catalyst material. However, one of the conventional techniques is to apply a functional material on the surface of the fabric. Not only does the functional material fail to effectively increase its efficiency, but it does not exert its performance, and it will fall off after a period of use. The economic benefit of this technology. Not high. Other techniques, for example, in U.S. Patent No. 4,784,909, are to add copper to the fiber to have an antibacterial and deodorizing function. For example, in U.S. Patent No. 6,540,807, a thermoplastic plastic resin and an antibacterial agent are added to the fabric to have an antibacterial function. For example, in U.S. Patent No. 5,690,922, the fiber is added with a metal phosphate and a metal hydroxide to have a deodorizing function. However, in the prior art, the functional materials in the fiber can only achieve benefits in an effective space without effective stimulation. Furthermore, although some manufacturers have developed LED lights to emit light that is beneficial to the growth of blue light and red light plants for planting fruits and vegetables, the use of LED lights requires electricity and is expensive, and relatively high cost, not only produces Energy consumption problems, and the inability to control pests and diseases, must still rely on pesticides or biological control or additional installation of mesh isolation pests or nets Closed plastic sheds, glass greenhouses, etc., but still can not effectively achieve the effect of environmental control.
因此為達有效的環控農業生產及節能控制，本發明人等認為必須善用自然界存在且源源不絕的綠色能源，將綠色能源轉換而創造出合適的農作物生長環境。例如採用綠色能源，善用綠色能源中的陽光，將陽光轉換或增輻成植物生長所需要的光波，來增加有機網室農作物的產量；藉由纖維材料中晶體能帶效應，在纖維材料接收綠色能源後增輻纖維材料中的觸媒材料之效能，不僅將陽光轉換及增加所需的光線、將空氣濕度細小化，有利於植物生長而且能防治植物病害及去除環境中汙染物。再者，更可配合運用天然植物精油對蟲害產生趨避功效，進而達到有機大量栽培之目的。以上乃是本發明的概念及研發動機，也是值得積極投入研發的農業綠能環控材料，及可達到真正有機農業栽種生產及環境污染控制的技術，對於目前有機農業環境控制材料及糧食生產能源消耗等缺失與問題實能加以改善。 Therefore, in order to achieve effective environmentally-controlled agricultural production and energy-saving control, the inventors believe that it is necessary to make good use of green energy that exists in nature and is endless, and to convert green energy into a suitable crop growing environment. For example, using green energy, making good use of the sunlight in green energy, converting or increasing the sunlight into the light waves needed for plant growth, increasing the yield of organic net crops; receiving the fiber material through the crystal band effect in the fiber material. The effectiveness of the catalytic material in the fiber material after green energy energy not only converts the sunlight and increases the required light, but also reduces the humidity of the air, which is beneficial to plant growth and can prevent plant diseases and remove environmental pollutants. In addition, it can be combined with the use of natural plant essential oils to avoid the insect pests, and thus achieve the purpose of organic cultivation. The above is the concept and research engine of the present invention, and is also an agricultural green energy environmental control material that is worthy of active research and development, and a technology that can achieve true organic agricultural planting production and environmental pollution control, for current organic agricultural environmental control materials and food production energy. Loss and problems such as consumption can be improved.
本發明之第一目的，在於提供一種運用綠能以增加有機農業植物生長的環境控制纖維及其織品，藉由該環境控制纖維的特殊材料性能來增加植物生長所需光波及轉移有害光波或增加照射光波時間、將空氣中濕氣分解使水分子細小化(水氧負離子)而能更有效吸收水份、產生遠紅外線以提供植物生長光波及去除環境中汙染物，藉以促進環境中陽光、水、空氣及土壤對有機植物生產的質與量的提升。其技術手段係纖維以聚烯類材料為基材，而於內部混含包括有能產生電磁輻射波之光電效應的光電材料(蓄光長餘暉螢光磷光材料)具有光轉換蓄光機能、 能致使應力場與電場產生耦合之壓電效應的壓電材料、能接收到外在熱輻射而產生遠紅外線的熱電材料及能加快化學反應速率的觸媒材料。當纖維接收外界的綠色能量如太陽光電能，則藉由光電材料(如蓄光長餘暉螢光磷光材料)的作用而產生植物生長所需光譜(400-700nm波長光線)，將對植物有害紫外線光轉換為植物生長所需之400-700nm波長光線，並且蓄光能源供植物夜間生長，以促進植物生長。當纖維接收外界的綠色能量如太陽光熱能或地熱能，則藉由熱電材料的作用而於環境中產生促進植物生長波長為4~14um的紅外線能量波輻。當纖維接收外界的綠色能量如風力能，則藉由壓電材料於環境中產生壓電性，分解空氣中濕度之水力能以產生水氧負離子，使環境中產生雨林生態，提供植物更有效的水份吸收。觸媒材料藉由光電效應、熱電效應及壓電效應產生共振而將能量增輻以活化自由電子之活躍性，激發材料中電子電洞能階活動之催化作用的增加，而使觸媒材料更為有效地產生作用以去除環境汙染物材料。 The first object of the present invention is to provide an environmental control fiber and a fabric thereof which use green energy to increase the growth of organic agricultural plants, and the special material properties of the fiber are controlled by the environment to increase the light wave required for plant growth and to transfer harmful light waves or increase Irradiating the light wave time, decomposing the moisture in the air to make the water molecules fine (water oxygen and anion), can absorb water more effectively, generate far infrared rays to provide plant growth light waves and remove environmental pollutants, thereby promoting sunlight and water in the environment. , air and soil increase the quality and quantity of organic plant production. The technical means is that the fiber is made of a polyolefin-based material, and the photoelectric material (light-storing long-lasting fluorescent phosphorescent material) including a photoelectric effect capable of generating electromagnetic radiation waves is internally mixed, and has a light conversion and light-storing function. A piezoelectric material capable of causing a piezoelectric effect in which a stress field and an electric field are coupled, a thermoelectric material capable of receiving external thermal radiation to generate far infrared rays, and a catalytic material capable of accelerating a chemical reaction rate. When the fiber receives the external green energy such as solar photovoltaic energy, the spectrum required for plant growth (400-700 nm wavelength light) is generated by the action of the photoelectric material (such as the long-lasting fluorescent phosphorescent material), which will be harmful to the plant. It is converted into 400-700 nm wavelength light required for plant growth, and the light storage energy source is used for plant growth at night to promote plant growth. When the fiber receives external green energy such as solar thermal energy or geothermal energy, an infrared energy wave having a growth wavelength of 4 to 14 um is generated in the environment by the action of the thermoelectric material. When the fiber receives the external green energy such as wind energy, the piezoelectric material generates piezoelectricity in the environment, and the hydrodynamic energy of the humidity in the air is decomposed to generate water and oxygen negative ions, so that the rain forest ecology is generated in the environment, and the plant is provided more effectively. Water absorption. The catalytic material generates resonance by photoelectric effect, thermoelectric effect and piezoelectric effect to amplify energy to activate the activity of free electrons, and stimulate the increase of the catalytic activity of the electron hole energy level activity in the material, thereby making the catalytic material more To effectively act to remove environmental contaminant materials.
本發明之第二目的，在於提供一種具去除生物性汙染物功能的綠能環控纖維及其織品。其技術手段係上述第一目的之綠能環控纖維內部混含能去除環境中生物性汙染物之觸媒材料。藉由該種觸媒材料的設置而使綠能環控纖維及其織品具有抑制環境中生物性汙染源等機能，進而達到抑制環境中生物性汙染源，如真菌類、細菌類及病毒類等汙染源的功效與目的。 A second object of the present invention is to provide a green energy ring control fiber and a fabric thereof having the function of removing biological contaminants. The technical means is that the green energy-controlled fiber inside the first object contains a catalytic material capable of removing biological pollutants in the environment. By the arrangement of the catalyst material, the green energy-controlled fiber and the fabric thereof have the functions of inhibiting biological pollution sources in the environment, thereby suppressing environmental pollution sources such as fungi, bacteria and viruses. Efficacy and purpose.
本發明之第三目的，在於提供一種具去除環境中化學性汙染物功能的綠能環控纖維及其織品。其技術手段係上述第一目的之綠 能環控纖維內部混含具有去除化學性汙染物機能的觸媒材料，具有去除環境中甲醛HCHO、總揮發性有機化合物TVOCs、一氧化碳CO、二氧化碳CO2、臭氧O3、醋酸、乙醛、氨氣、正負離子(F-、Cl-、NO3-、PO43-、SO42-、NH4+)等化學性汙染物機能。 A third object of the present invention is to provide a green energy loop control fiber and a fabric thereof having the function of removing chemical pollutants from the environment. The technical means is that the green energy-controlled fiber inside the first object contains a catalytic material having the function of removing chemical pollutants, and has the environment of removing formaldehyde HCHO, total volatile organic compounds TVOCs, carbon monoxide CO, carbon dioxide CO 2 , Oxygen O 3 , acetic acid, acetaldehyde, ammonia, positive and negative ions (F - , Cl - , NO3 - , PO4 3- , SO4 2- , NH4 + ) and other chemical pollutants.
本發明之第四目的，在於提供一種具去除環境中物理性汙染物功能的綠能環控纖維。其技術手段係上述第一目的中之纖維內部混含具有沉降環境中物理性汙染源的觸媒材料，具有沉降環境中空氣物理性汙染源至地上，如花粉、PM2.5、PM10等懸浮微粒機能。 A fourth object of the present invention is to provide a green energy loop control fiber having a function of removing physical pollutants from the environment. The technical means is that the fiber inside the first object contains a catalytic material having a physical pollution source in a sedimentation environment, and has a physical activity source of air in a sedimentation environment to the ground, such as pollen, PM 2.5 , PM 10 and the like.
本發明之第五目的，在於提供一種具有芬多精防蟲的綠能環控纖維。其技術手段係上述前四項目的之纖維內部混含具有趨避蟲類功效的天然植物精油，材料中含有趨避蟲類功效而達到防治蟲類功效，並能產生植物芬多精，以利植物生長。 A fifth object of the present invention is to provide a green energy ring-controlled fiber having fentanyl insect-repellent. The technical means is that the fiber of the first four items mentioned above contains a natural plant essential oil with anti-insect effect, and the material contains the effect of avoiding insects to achieve the effect of controlling insects, and can produce fentanyl for plant growth. .
本發明之第六目的，在於提供一種具耐燃及導電抗靜電功能的安全綠能環控纖維。其技術手段係上述五項目的中之纖維增加混含防火材料及導電抗靜電導電功能的材料，而使纖維具有安全功能。 A sixth object of the present invention is to provide a safe green energy ring-controlled fiber having a flame-resistant and conductive antistatic function. The technical means is that the fibers in the above five items increase the material containing the fireproof material and the conductive antistatic conductive function, so that the fiber has a safety function.
10‧‧‧纖維 10‧‧‧Fiber
11‧‧‧凸條 11‧‧ ‧ ribs
12‧‧‧凹陷 12‧‧‧ dent
20‧‧‧織品 20‧‧‧ fabric
30‧‧‧光電材料 30‧‧‧Photoelectric materials
31‧‧‧壓電材料 31‧‧‧Piezoelectric materials
32‧‧‧熱電材料 32‧‧‧ thermoelectric materials
33‧‧‧觸媒材料 33‧‧‧catalyst materials
圖1係本發明製程之第一種實施例示意圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic illustration of a first embodiment of the process of the present invention.
圖2係本發明製程之第二種實施例示意圖。 Figure 2 is a schematic illustration of a second embodiment of the process of the present invention.
圖3係本發明製程之第三種實施例示意圖。 Figure 3 is a schematic illustration of a third embodiment of the process of the present invention.
圖4係本發明所製成纖維之一種斷面結構示意圖。 Fig. 4 is a schematic sectional view showing the structure of the fiber produced by the present invention.
圖5係本發明所製成纖維織成農業用網暨其使用示意圖。 Fig. 5 is a schematic view showing the fiber woven into an agricultural net made by the present invention and its use.
本發明所研發的綠能環控纖維，當纖維接收外界的綠色能量時，纖維產生能量傳導能力，藉由光電材料產生光電性、壓電材料產生壓電性及熱電材料(遠紅外線材料)產生波輻共振將能量增輻活化激發觸媒材料，產生電子電洞能階活動催化作用增加，可以有效提升激發觸媒催化環境中汙染物效能，並且產生400-700nm波長的光線(如波長4~14μm的遠紅外線)及分解空氣中水份(濕度)產生水氧負離子。因此，本發明纖維織成之織品20具有共振摩擦增輻效果而能產生環境控制功能效果，其織品20可作為用以輔助培植植物的有機農業綠能環控織品或植物光柵綠能環控織品，請配合參看圖5所示。本發明纖維製成之織品更可應用於健康照護綠能環控織品、室內空氣品質綠能環控織品(如空調綠能環控網)、油煙設備綠能環控織品(如去除油煙綠能環控網)、地工植生綠能環控織品(如舖於泥土下方而於泥土上種植植物的地工植生網)、除霧綠能環控織品(如洗滌塔除霧綠能環控網)、空氣清淨綠能環控織品(如空氣清淨機綠能環控網)、紗窗綠能環控織品(如紗窗換氣綠能環控網)及環境污染防治綠能環控織品(如水洗設備去除TVOCS、正負離子等工業設備)。其基本特徵的技術，係本發明的纖維由聚烯類材料(Polyolefine)(如聚丙烯及聚乙烯等，選擇碳氫化合物減少對環境汙染材料)、光電材料、壓電材料、熱電材料及觸媒材料，經雙螺桿風冷式造粒熔融混練製成加工材料，再將該加工材料經融熔抽絲加工技術製成纖維。使纖維所織成之織品，接收外界陽光照射、空氣流動、熱能、纖維震動摩擦、空氣濕度等自然能量，藉由光電材料產生光電性、壓電材料之壓電效應及熱電材料之熱電效應(遠紅外線)。藉由熱電效應、壓電效應、光催化效應、氧 化還原效應、自由電子效應、觸媒效應及緩釋效應以對自然能量增輻而作用於觸媒材料，使觸媒材料充份發揮其效能，各材料的重量配比可依使用者的需求而調整，本發明主要概念是整合光電材料、壓電材料、熱電材料及觸媒材料應用於纖維，使纖維接收自然能源時，其內的觸媒材料能產生增輻功效。首先使環境中產生波長範圍4~14um之遠紅外線及分解空氣中水份(濕度)，產生水氧負離子。其次達到光效應增加植物生長及限制陽光波長在400-700nm波長光線並且增加長餘暉夜間亮度。第三達到抑制生物汙染源如空氣中總細菌及黴菌等減少植物病害。第四達到去除空氣中化學汙染源(如空氣中汽狀污染物HCHO、TVOCs、O3、CO、CO2、SOX、NOX、CXHY、HCL、CS2、CFCS、CmHnXx等)以減少化學汙染，或達到沉降物理性汙染如空氣中粒狀污染物花粉、PM2.5、PM10等懸浮微粒的機能。第五達到趨避蟲類功效使植物免於蟲害危害及傳染病菌。第六達到具有耐燃及抗靜電、導電功能的安全綠能環控纖維。本發明綠能環控纖維綠能環控纖維具有效果極佳的機能性，可供織造成織品以應用於農業綠能環控溫室網室、植物光柵綠能環控織品等並且可應用於各類環境綠能環控織品設備如健康照護綠能環控織品、室內空氣品質綠能環控織品、油煙綠能環控織品、除霧綠能環控織品、地工植生綠能環控織品、空氣清淨綠能環控織品、紗窗綠能環控織品及環境污染防治綠能環控織品等，供農、工、漁、牧產業及民生廣泛使用。 The green energy ring-controlled fiber developed by the invention generates energy conduction capability when the fiber receives external green energy, generates photoelectricity by photoelectric material, generates piezoelectricity by piezoelectric material and generates thermoelectric material (far infrared material). The wave-wave resonance activates the excitation material by the energy-increasing excitation, which increases the energy catalysis of the electron-cavity energy level, can effectively improve the pollutant efficiency in the catalytic catalyst environment, and generate light of 400-700 nm wavelength (such as wavelength 4~) The 14 μm far infrared ray and the decomposition of moisture (humidity) in the air produce water oxygen anions. Therefore, the fiber-woven fabric 20 of the present invention has a resonance friction-increasing effect and can produce an environmental control function, and the fabric 20 can be used as an organic agricultural green energy-controlled fabric or a plant grating green energy-controlled fabric to assist in cultivating plants. Please refer to Figure 5 for cooperation. The fabric made of the fiber of the invention can be further applied to the health care green energy environment control fabric, the indoor air quality green energy environment control fabric (such as the air conditioner green energy ring control network), the soot equipment green energy environment control fabric (such as removing the oil smoke green energy) Environmental control network), geophysical green-green environmental control fabrics (such as geophysical planting nets planted under the soil and planted on the soil), defogging green energy-controlled fabrics (such as washing tower defogging green energy ring control network) ), air clean green energy ring control fabric (such as air cleaner green energy ring control network), screen window green energy ring control fabric (such as screen window ventilation green energy ring control network) and environmental pollution control green energy environmental control fabric (such as washing The equipment removes industrial equipment such as TVOCS, positive and negative ions). The basic feature of the technology is that the fibers of the present invention are made of a polyolefine (such as polypropylene and polyethylene, and hydrocarbons are selected to reduce environmentally harmful materials), photovoltaic materials, piezoelectric materials, thermoelectric materials, and touches. The medium material is processed into a processing material by twin-screw air-cooling granulation, melt-kneading, and the processed material is made into a fiber by a melt-spinning processing technique. The fabric woven into the fiber receives natural energy such as external sunlight, air flow, heat energy, fiber vibration friction, air humidity, etc., and photoelectricity of the photoelectric material, piezoelectric effect of the piezoelectric material, and thermoelectric effect of the thermoelectric material ( Far infrared ray). The thermoelectric effect, the piezoelectric effect, the photocatalytic effect, the redox effect, the free electron effect, the catalytic effect and the slow release effect act on the catalytic material to increase the natural energy, so that the catalytic material can fully exert its performance. The weight ratio of each material can be adjusted according to the needs of the user. The main concept of the invention is to integrate the photoelectric material, the piezoelectric material, the thermoelectric material and the catalytic material into the fiber, so that the fiber touches the natural energy. The media material can produce radiation-increasing effects. First, the environment generates infrared rays with a wavelength range of 4 to 14 um and decomposes moisture (humidity) in the air to generate water and oxygen anions. Secondly, the light effect is increased to increase plant growth and limit the wavelength of sunlight at wavelengths of 400-700 nm and increase the nighttime brightness of long afterglow. The third is to reduce the plant diseases caused by the suppression of biological pollution sources such as total bacteria and mold in the air. Fourth achieve the removal of chemicals in the air pollution (e.g. air vaporous contaminants HCHO, TVOCs, O 3, CO , CO 2, SO X, NO X, C X H Y, HCL, CS 2, CFC S, C m H n X x , etc.) to reduce chemical pollution, or to achieve the function of sedimentation physical pollution such as airborne particulate pollen, PM 2.5 , PM 10 and other suspended particles. The fifth achieves the effect of avoiding insects and protects plants from pest damage and infectious diseases. Sixth, it achieves safe green energy-controlled fiber with flameproof, antistatic and conductive functions. The green energy environmental control fiber green energy ring control fiber of the invention has excellent effect, and can be used for weaving the fabric to be applied to the agricultural green energy environmental control greenhouse room, the plant grating green energy ring control fabric, etc. and can be applied to All kinds of environmental green energy environmental control fabric equipment such as health care green energy environmental control fabric, indoor air quality green energy environmental control fabric, fume green energy control fabric, defogging green energy control fabric, geotextile green energy environmental control fabric Air clean green energy-controlled fabrics, screens green energy-controlled fabrics and environmental pollution control green energy environmental control fabrics, etc., for agricultural, industrial, fishing, animal husbandry and the people's livelihood.
本發明製造綠能環控纖維，所採用的光電材料之光電效應是電磁輻射波(如紫外線光)照射到材料，而產生光子吸收激發自由電子效應，主要為蓄光長餘暉螢光磷光材料產生光電性具有光轉換蓄光機能材料；基本上有Zn2SiO4、CaSiO3、SiO2、TiO2、(SrBaMg)3Si2O7、CaWO4、 MgWO4、LiAl5O8：Mn4+、CaAl2O4：Eu2+,Dy3+、CaAl12O19：Mn4+、SrAl2O4：Eu2+,Dy3+、Sr4Al14O25：Eu2+,Dy3+、SrAl12O19：Eu2+,Dy3+、BaMg2Al16O27、CeMgAl11O19、MgAl2O4、GdAlO3、Y2O3、YVO4、SrB4O7F、MgGa2O4、MgGa2O4、BeO、MgO、Al2O3、MgAl2O4、GeO2SnO2ZnO、Sc2O3、La2O3、Sm2O3、Gd2O3、Dy2O3、ZrO2、CdS及WO3等。 The invention produces a green energy ring-controlled fiber, and the photoelectric effect of the photoelectric material used is that electromagnetic radiation wave (such as ultraviolet light) is irradiated to the material, and photon absorption excites the free electron effect, mainly for accumulating long-lasting fluorescent phosphorescent material to generate photoelectric The material has a light conversion light storage function; basically Zn 2 SiO 4 , CaSiO 3 , SiO 2 , TiO 2 , (SrBaMg) 3 Si 2 O 7 , CaWO 4 , MgWO 4 , LiAl 5 O 8 : Mn 4+ , CaAl 2 O 4 :Eu 2+ , Dy 3+ , CaAl 12 O 19 :Mn 4+ , SrAl 2 O 4 :Eu 2+ , Dy 3+ , Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ , SrAl 12 O 19 :Eu 2+ , Dy 3+ , BaMg 2 Al 16 O 27 , CeMgAl 11 O 19 , MgAl 2 O 4 , GdAlO 3 , Y 2 O 3 , YVO 4 , SrB 4 O 7 F, MgGa 2 O 4 , MgGa 2 O 4 , BeO, MgO, Al 2 O 3 , MgAl 2 O 4 , GeO 2 SnO 2 ZnO, Sc 2 O 3 , La 2 O 3 , Sm 2 O 3 , Gd 2 O 3 , Dy 2 O 3 , ZrO 2 , CdS and WO 3, etc.
本發明製造綠能環控纖維，所採用的壓電材料之壓電效應是因晶格內原子間特殊排列方式，而有應力場與電場的耦合效應。壓電材料基本上有石英、硫化鎘、氧化鋅、氮化鋁、鐵電晶體、鈦酸鋇晶體、鈮酸鋰、鈮酸鉭、鈮酸鍶鋇晶體、磷酸二氫鉀、磷酸二氫銨、磷酸氫鉛、磷酸氘鉛晶體、鈦酸鉍晶體、鈦酸鋇陶瓷、鋯鈦酸鉛PZT等。 The invention produces a green energy ring-controlled fiber, and the piezoelectric effect of the piezoelectric material used is due to a special arrangement between atoms in the crystal lattice, and a coupling effect between the stress field and the electric field. Piezoelectric materials are basically quartz, cadmium sulfide, zinc oxide, aluminum nitride, ferroelectric crystal, barium titanate crystal, lithium niobate, barium strontium citrate, barium strontium silicate crystal, potassium dihydrogen phosphate, ammonium dihydrogen phosphate , lead hydrogen phosphate, lead strontium phosphate crystal, barium titanate crystal, barium titanate ceramic, lead zirconate titanate PZT and the like.
本發明製造綠能環控纖維，所採用的熱電材料為遠紅外線材料接收到外在熱輻射可產生光譜上4-14μm波長的遠紅外線，波長大於可見光之波長，是一種具有強熱作用的「熱感應」能。熱電材料成分基本上為Al2O3、ZrO2、MgO、TiO2、SiO2、ZrC、SiC、B4C、TaC、TiB2、ZrB2、CrB2、TiSi2、MoSi2、WSi2、Si3N4、TiN、Fe2O、高溫竹炭、備長炭、麥飯石、桂陽石、火山岩、玉石。 The invention produces a green energy ring-controlled fiber, and the thermoelectric material used is a far-infrared material that receives external thermal radiation to generate far-infrared rays having a wavelength of 4-14 μm on the spectrum, and the wavelength is greater than the wavelength of visible light, and is a kind of strong heat effect. Thermal induction" can. The thermoelectric material composition is substantially Al 2 O 3 , ZrO 2 , MgO, TiO 2 , SiO 2 , ZrC, SiC, B 4 C, TaC, TiB 2 , ZrB 2 , CrB 2 , TiSi 2 , MoSi 2 , WSi 2 , Si 3 N 4 , TiN, Fe 2 O, high temperature bamboo charcoal, preparation of charcoal, medical stone, Guiyang stone, volcanic rock, jade.
本發明製造綠能環控纖維，所採用的觸媒材料為催化劑，是能透過提供另一活化能較低的反應途徑，而加快化學反應速率，而本身的質量、組成和化學性質在參加化學反應前後保持不變的物質。觸媒材料成分主要為觸媒金屬如金、鉑、鈀、銠、銀、鐵、銅、鈦、鎳、鎢、鋅、錳、鍺、鉍、釕、鋨、銥、鉬、鉻、鑭、鈰、鐠、釹、鉕、奈米碳管等及氧化金屬觸媒如氧化鍺、氧化鋅、氧化矽、氧化鈦、氧化鋁、氧化鐵、氧化鈀、氧化鎂、氧化鋯、氧化鎳、氧化錫、氧化錳、氧化鉻、氧化鈰、氧化釹、氧化釔等。 The invention produces a green energy ring-controlled fiber, and the catalyst material used is a catalyst, which can accelerate the chemical reaction rate by providing another reaction energy with lower activation energy, and the quality, composition and chemical properties of itself participate in the chemical A substance that remains unchanged before and after the reaction. The catalytic material components are mainly catalytic metals such as gold, platinum, palladium, rhodium, silver, iron, copper, titanium, nickel, tungsten, zinc, manganese, lanthanum, cerium, lanthanum, cerium, lanthanum, molybdenum, chromium, cerium,铈, 鐠, 钕, 鉕, carbon nanotubes, etc. and oxidizing metal catalysts such as cerium oxide, zinc oxide, cerium oxide, titanium oxide, aluminum oxide, iron oxide, palladium oxide, magnesium oxide, zirconium oxide, nickel oxide, oxidation Tin, manganese oxide, chromium oxide, cerium oxide, cerium oxide, cerium oxide, and the like.
本發明製造綠能環控纖維，所採用的天然植物精油有茶樹油、苦煉油、檸檬油、冬青油、樟樹油、丁香油、薄荷油、桉葉油、香茅油、山雞椒油、鼠尾草油、尤加利油、玫瑰油、茉莉油、天竺葵油、玫瑰天竺葵油、依蘭油、乳香油、廣霍香油、迷迭香油、永久花油、百里香油、松樹油、雪松油、杜松油、檀香油、蘿勒油、萊姆油、桔油、甜橙油、苦橙油、苦橙葉油、橙花油、洋柑橘油、山雞椒油、沒葯油、牛膝草油、白千層油、薑油等。 The invention produces green energy ring control fiber, and the natural plant essential oil used is tea tree oil, bitter oil, lemon oil, wintergreen oil, eucalyptus oil, clove oil, peppermint oil, eucalyptus oil, citronella oil, pheasant pepper oil, Sage oil, eucalyptus oil, rose oil, jasmine oil, geranium oil, rose geranium oil, ylang-ylang oil, mastic oil, hoarfrost oil, rosemary oil, permanent flower oil, thyme oil, pine oil, cedar oil , Juniper oil, sandalwood oil, basil oil, lime oil, orange oil, orange oil, bitter orange oil, bitter orange leaf oil, neroli oil, foreign citrus oil, pheasant pepper oil, myrrh oil, cattle Knee grass oil, white layer oil, ginger oil, etc.
本發明製造綠能環控纖維，所採用的阻燃防火材料有三氧化二銻、氫氧化鎂、紅磷、鉬化合物、硼酸鋅、錫酸鋅、十溴二苯醚、八溴醚、有機矽、炭黑等。 The invention discloses a green energy ring-controlling fiber, and the fire-retardant fireproofing materials used are antimony trioxide, magnesium hydroxide, red phosphorus, molybdenum compound, zinc borate, zinc stannate, decabromodiphenyl ether, octabromoether, organic antimony. , carbon black and so on.
本發明製造綠能環控纖維，所採用的導電抗靜電材料有聚醚類、季銨鹽類、磺酸鹽、甜菜鹼類、導電炭黑、碳纖維、金屬纖維、鍍鎳金屬碳纖維、奈米碳管。 The invention produces green energy ring control fibers, and the conductive antistatic materials used are polyethers, quaternary ammonium salts, sulfonates, betaines, conductive carbon black, carbon fibers, metal fibers, nickel-plated metal carbon fibers, and nanometers. Carbon tube.
本發明綠能環控纖維綠能環控纖維的基本特徵：採用聚烯類(Polyolefine)、光電材料、壓電材料、熱電材料及觸媒材料，並視各材料比例多寡及結構強度需求決定是否添加橡膠彈性材料(如三元乙丙膠(Ethylene-Propylene-Diene Monomer，EPDM))，將該等材料一起熔融混練製成聚烯類功能性材料後，再將顆粒狀的聚烯類功能性材料，熔融抽絲製成丹尼數為50~50000den的纖維。其中，第一聚烯類可以是聚丙烯(其熔融流率(Melt flow rate,MFR)範圍為0.1~50g/10min，或是第一聚烯類可以是聚乙烯(其熔融流率(Melt flow rate,MFR)範圍為0.1~50g/10min。光電材料之特性為蓄光性(3000-0.32mcd/m2)粒徑分佈：10~0.1μm；壓電材料之特性為：壓電係數(10-12C/N)0.1~1000，粒徑 分佈：10~0.1μm。熱電材料之特性為：波長範圍4~14um之遠紅外線的放射率0.85~0.99%，粒徑分佈：10~0.1μm、三元乙丙膠(EPDM)(其門尼黏度(ML1+4,125℃)20~70)。如圖4所示，一種較佳實施例中，該纖維10表面一體成形有至少二凸條11，該凸條11長度沿著該纖維之軸向延伸，且由該纖維橫斷面觀察，該凸條11頂部呈曲線延伸，圖4示例中二凸條11之間有一具曲度的凹陷12，當纖維接收外界日光，纖維中的光電材料30、壓電材料31、熱電材料32及觸媒材料33的交互作用而將日光轉換為植物生長所需之顏色光線，經由凸條11的曲度而散射出來而照射至植物，以促進植物生長。 The basic characteristics of the green energy ring-control fiber green energy ring-controlled fiber of the invention: using polyolefine (Polyolefine), photoelectric material, piezoelectric material, thermoelectric material and catalytic material, depending on the ratio of each material and the structural strength requirement A rubber elastic material (such as Ethylene-Propylene-Diene Monomer (EPDM)) is added, and the materials are melted and kneaded together to form a polyolefin functional material, and then the granular polyene functionality is added. The material is melt-spun and made into fibers having a Danny number of 50 to 50000 den. Wherein, the first polyolefin may be polypropylene (melt flow rate (MFR) ranging from 0.1 to 50 g/10 min, or the first polyolefin may be polyethylene (melt flow rate (Melt flow) The rate, MFR) ranges from 0.1 to 50 g/10 min. The characteristics of the photoelectric material are light storage (3000-0.32 mcd/m 2 ) particle size distribution: 10 to 0.1 μm; the characteristics of the piezoelectric material are: piezoelectric coefficient (10 - 12 C/N) 0.1~1000, particle size distribution: 10~0.1μm. The characteristics of thermoelectric materials are: the emissivity of far infrared rays in the wavelength range of 4~14um is 0.85~0.99%, the particle size distribution is 10~0.1μm, three Ethylene propylene acrylate (EPDM) (with Mooney viscosity (ML1+4, 125 ° C) 20-70). As shown in FIG. 4, in a preferred embodiment, at least two ribs 11 are integrally formed on the surface of the fiber 10. The length of the rib 11 extends along the axial direction of the fiber, and the top of the rib 11 extends in a curve when viewed from a cross section of the fiber. In the example of FIG. 4, there is a concave 12 between the two ribs 11 when The fiber receives external sunlight, and the interaction of the photovoltaic material 30, the piezoelectric material 31, the thermoelectric material 32, and the catalytic material 33 in the fiber converts sunlight into color light required for plant growth, via The curvature of the ridges 11 is scattered and irradiated to the plants to promote plant growth.
請配合參看圖1所示，本發明製造綠能環控纖維達到前述第一至第四目的之方法的基本特徵，主要是準備70%~95%重量百分比作為基材的聚稀類材料如聚丙烯碎片或聚乙烯碎片(熔融流率(Melt flow rate,MFR)範圍為0.1~50g/10min)(本發明以下各對應的實驗例，係以熔融流率為5g/10min且佔70%或80%重量百分比的聚丙烯為例做說明)、1%~10%重量百分比的光電材料(本發明以下各項實驗例係以光電材料10%重量百分比，粒徑分佈：0.3μm，為例做說明)、1%~5%重量百分比的壓電材料(本發明以下各項實驗例係以壓電材料2%重量百分比，粒徑分佈：1μm，為例做說明)、1%~5%重量百分比的熱電材料(本發明以下各項實驗例係以熱電材料2%重量百分比，粒徑分佈：1μm，為例做說明)及1%~5%重量百分比的觸媒材料(本發明以下各項實驗例係以觸媒材料佔3%重量百分比，粒徑分佈：0.3μm，為例做說明)，並視纖維延展性、強度及硬度需要選擇是否添加橡膠彈性材料(如三元乙丙橡膠(Ethylene-Propylene-Diene Monomer，EPDM)1%~5%重量百分比(本發明以下各項實驗例係以EPDM佔3%重量百分比(門尼黏度60)為例做說明)。將前述的材料混合以風冷式雙螺桿混練造粒，其 中聚丙烯為基材時，其製粒溫度160℃~250℃增溫；聚乙烯為基材時，其製粒溫度260℃~350℃。進而製成複數個顆粒狀母材(該顆粒狀母材之平均粒徑小於2-10mm)，將該複數個顆粒狀母材透過單螺桿押出機使該加工材料經抽絲、冷卻、熱延伸、加熱定型製成纖維。其中，聚丙烯為基材時，其抽絲溫度160℃~250℃增溫；聚乙烯為基材時，其抽絲溫度為260℃~350℃。其後冷卻溫度為-20~50℃，牽伸倍率為3~8倍，熱水延伸溫度為80~120℃，捲取速度為40~180rpm。本發明具體操作之實施例中以聚丙烯為基材，其製粒加工溫度180℃/200℃/210℃/220℃/230℃/240℃，其纖維抽絲溫度200℃/210℃/220℃/230℃/240℃/250℃，冷卻溫度25℃，熱水延伸溫度100℃，牽伸倍率為6倍，捲取速度120rpm。前述熔融抽絲是將該加工材料加熱熔融，熔融從噴絲孔擠出進入冷卻水中，在冷卻水中冷卻的同時，以一定速度捲取，再進行熱水熱拉伸數倍速度捲取，在該階段加工材料熔體細化的同時凝固即形成纖維，將纖維捲繞。熔融抽絲工程，是將在聚合工序製得的具有可紡性的聚合物在其熔點以上的溫度從噴絲板細孔擠出，冷卻細化成絲狀固體，同時進行捲繞。 Referring to FIG. 1 together, the basic feature of the method for producing the green energy-controlled fiber of the present invention to achieve the above first to fourth objects is mainly to prepare 70% to 95% by weight of the poly-thick material such as poly. Propylene fragments or polyethylene chips (Melt flow rate (MFR) ranging from 0.1 to 50 g/10 min) (the following corresponding experimental examples of the present invention have a melt flow rate of 5 g/10 min and account for 70% or 80%) % by weight of polypropylene as an example), 1% to 10% by weight of optoelectronic material (the following experimental examples of the present invention are 10% by weight of photoelectric material, particle size distribution: 0.3 μm, for example ), 1% to 5% by weight of piezoelectric material (the following experimental examples of the present invention are 2% by weight of piezoelectric material, particle size distribution: 1 μm, for example), 1% to 5% by weight The thermoelectric material (the following experimental examples of the present invention are 2% by weight of the thermoelectric material, the particle size distribution: 1 μm, for example) and 1% to 5% by weight of the catalyst material (the following experiments of the present invention) For example, the catalyst material accounts for 3% by weight, and the particle size distribution: 0.3 μm, for example, Depending on fiber ductility, strength and hardness, it is necessary to choose whether to add rubber elastic material (such as Ethylene-Propylene-Diene Monomer (EPDM) 1% to 5% by weight (the following experimental examples of the present invention are EPDM) Taking 3% by weight (Mooney viscosity 60) as an example). The above materials are mixed and granulated by air-cooled twin-screw mixing. When the medium polypropylene is used as the substrate, the granulation temperature is increased from 160 ° C to 250 ° C; when the polyethylene is used as the substrate, the granulation temperature is 260 ° C to 350 ° C. Further, a plurality of granular base materials (the average particle diameter of the granular base material is less than 2-10 mm) are prepared, and the plurality of granular base materials are passed through a single screw extruder to spin, cool, and thermally extend the processed material. Heated and shaped into fibers. Among them, when polypropylene is used as the substrate, the spinning temperature is increased from 160 ° C to 250 ° C; when polyethylene is used as the substrate, the spinning temperature is 260 ° C to 350 ° C. The subsequent cooling temperature is -20 to 50 ° C, the draw ratio is 3 to 8 times, the hot water extension temperature is 80 to 120 ° C, and the take-up speed is 40 to 180 rpm. In the specific operation example of the present invention, polypropylene is used as a substrate, and the granulation processing temperature is 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C, and the fiber spinning temperature is 200 ° C / 210 ° C / 220 °C/230°C/240°C/250°C, cooling temperature 25°C, hot water extension temperature 100°C, draw ratio 6 times, coiling speed 120 rpm. The melt-spinning is to heat and melt the processed material, and the molten material is extruded from the spinning hole into the cooling water, cooled in the cooling water, and taken up at a constant speed, and then hot-rolled at a multiple speed of hot water to take up the coil. At this stage, the melted material of the processed material is solidified to form fibers, and the fibers are wound. In the melt spinning process, the spinnable polymer obtained in the polymerization step is extruded from the pores of the spinneret at a temperature higher than the melting point, cooled and refined into a filamentous solid, and simultaneously wound.
請配合參看圖2所示，本發明製造綠能環控纖維達成前述第五項目的(含有趨避蟲類功效的綠能環控纖維)之方法的基本特徵，主要是準備65%~94%重量百分比的聚烯類材料(本發明以下各項對應的實驗例係以熔融流率為5g/10min，且佔80%重量百分比的聚丙烯為例做說明)，其次準備光電材料1~5%重量百分比、壓電材料1~5%重量百分比、熱電材料1~5%重量百分比、觸媒材料1~5%重量百分比及視纖維延展性、強度及硬度需要選擇是否添加橡膠彈性材料1~5%重量百分比共佔5%~25%重量百分比(本發明實驗例中係以光電材料佔2%重量百分比，粒徑分佈： 0.3μm；壓電材料佔2%重量百分比，粒徑分佈：1μm；熱電材料佔2%重量百分比，粒徑分佈：1μm；觸媒材料佔3%重量百分比，粒徑分佈：0.3μm，橡膠彈性材料(如三元乙丙橡膠(Ethylene-Propylene-Diene Monomer，EPDM)佔3%重量百分比(其門尼黏度60)。即光電材料、壓電材料、熱電材料、觸媒材料及EPDM共佔12%重量百分比，為具例做說明)，天然植物精油1~10%(本發明以下各項試驗係以天然植物精油8%重量百分比為例做說明)。 Please refer to FIG. 2, the basic characteristics of the method for producing the green energy ring control fiber of the present invention to achieve the green energy control fiber containing the insect-repellent effect of the fifth item, mainly preparing 65% to 94% by weight. Percentage of polyene-based materials (the experimental examples corresponding to the following examples of the present invention are based on a melt flow rate of 5 g/10 min and accounting for 80% by weight of polypropylene), and secondly, a photovoltaic material is prepared in an amount of 1 to 5% by weight. Percentage, piezoelectric material 1~5% weight percentage, thermoelectric material 1~5% weight percentage, catalyst material 1~5% weight percentage and apparent fiber ductility, strength and hardness need to choose whether to add rubber elastic material 1~5% The weight percentage accounts for 5% to 25% by weight (in the experimental example of the present invention, the photoelectric material accounts for 2% by weight, and the particle size distribution: 0.3μm; piezoelectric material accounts for 2% by weight, particle size distribution: 1μm; thermoelectric material accounts for 2% by weight, particle size distribution: 1μm; catalytic material accounts for 3% by weight, particle size distribution: 0.3μm, rubber elasticity Materials (such as Ethylene-Propylene-Diene Monomer (EPDM) accounted for 3% by weight (the Mooney viscosity of 60). Photoelectric materials, piezoelectric materials, thermoelectric materials, catalytic materials and EPDM accounted for 12 % by weight, for the purpose of illustration), natural plant essential oil 1~10% (the following tests in the present invention are based on 8% by weight of natural plant essential oils as an example).
請配合參看圖3所示，本發明製造安全綠能環控纖維以達成前述第六目的(具耐燃及導電抗靜電功能的安全綠能環控纖維)之方法的基本特徵，主要是準備55%~92%重量百分比的聚烯類材料(本發明以下各項對應的實驗例係以熔融流率為5g/10min，且佔70%重量百分比的聚丙烯為例做說明)。其次準備光電材料1~5%重量百分比、壓電材料1~5%重量百分比、熱電材料1~5%重量百分比、觸媒材料1~5%重量百分比及，並視纖維延展性、強度及硬度需要選擇是否添加橡膠彈性材料1~5%重量百分比共佔5%~25%重量百分比(本發明實驗例中，係以光電材料2%重量百分比，粒徑分佈：0.3μm；壓電材料2%重量百分比，粒徑分佈：1μm；熱電材料2%重量百分比，粒徑分佈：1μm；觸媒材料佔3%重量百分比，粒徑分佈：0.3μm，橡膠彈性材料(如三元乙丙橡膠(Ethylene-Propylene-Diene Monomer，EPDM)佔3%重量百分比(其門尼黏度60)。即光電材料、壓電材料、熱電材料、觸媒材料及橡膠彈性材料(EPDM)共佔12%重量百分比為例做說明)。並準備天然植物精油1~5%重量百分比(本發明以下各項試驗係以天然植物精油3%重量百分比為例做說明)。準備防火材料1~10%重量百分比，粒徑分佈：10~0.1μm(本發明以下各項對應的實驗例係以防 火材料10%重量百分比為例做說明)。準備導電抗靜電材料1~5%重量百分比，其粒徑分佈：10~0.1μm(本發明以下各項對應的實驗例係以導電抗靜電材料佔5%重量百分比為例做說明)。 Please refer to FIG. 3, the basic characteristics of the method for manufacturing the safe green energy ring control fiber to achieve the foregoing sixth object (safe green energy ring control fiber with flameproof and conductive antistatic function), mainly preparing 55%. ~92% by weight of the polyolefin material (the experimental examples corresponding to the following examples of the present invention are based on a melt flow rate of 5 g/10 min and 70% by weight of polypropylene). Secondly, prepare 1~5% by weight of photoelectric material, 1~5% by weight of piezoelectric material, 1~5% by weight of thermoelectric material, 1~5% by weight of catalyst material, and consider fiber ductility, strength and hardness. It is necessary to select whether to add rubber elastic material 1 to 5% by weight of 5% to 25% by weight (in the experimental example of the present invention, 2% by weight of the photoelectric material, particle size distribution: 0.3 μm; piezoelectric material 2%) Weight percentage, particle size distribution: 1 μm; thermoelectric material 2% by weight, particle size distribution: 1 μm; catalytic material accounted for 3% by weight, particle size distribution: 0.3 μm, rubber elastic material (such as ethylene propylene diene monomer (Ethylene) -Propylene-Diene Monomer, EPDM) accounts for 3% by weight (its Mooney viscosity is 60). Photoelectric materials, piezoelectric materials, thermoelectric materials, catalytic materials and rubber elastic materials (EPDM) account for 12% by weight. Make a description) and prepare natural plant essential oils 1 to 5% by weight (the following test in the present invention is based on 3% by weight of natural plant essential oils as an example). Prepare fireproof materials 1 to 10% by weight, particle size distribution :10~0.1μm (below the present invention) The corresponding experimental examples are in case 10% by weight of the fire material is used as an example). The conductive antistatic material is prepared in an amount of 1 to 5% by weight, and the particle size distribution thereof is 10 to 0.1 μm (the experimental examples corresponding to the following items of the present invention are exemplified by a conductive antistatic material of 5% by weight).
本發明之實驗例一，係取80%重量百分比的聚丙烯(熔融流率5g/10min)、10%重量百分比的光電材料(Sr4Al14O25：Eu2+,Dy3+)粉末(粒徑0.3μm)、2%重量百分比的壓電材料(鈦酸鋇陶瓷)粉末(粒徑1μm)、2%重量百分比的熱電材料(含有氧化鋁Al2O3 35.92%、氧化鎂MgO 33.86%、氧化鐵Fe2O 16.10%、二氧化鈦TiO2 12.26%及二氧化矽SiO2 2.86%等氧化物)粉末(粒徑1μm)、3%重量百分比的觸媒材料(金30%/氧化鈦30%/氧化鋅40%)粉末(粒徑0.3μm)，及EPDM佔3%重量百分比(其門尼黏度60)。將前述材料以雙螺桿混練風冷卻造粒(造粒溫度為180℃/200℃/210℃/220℃/230℃/240℃)而製成複數個顆粒狀母材做為混練加工材料(平均粒徑約5mm)，再將顆粒狀母材的加工材料以單螺桿混練溫度為200℃/210℃/220℃/230℃/240℃/250℃，再將熔融加工材料經抽絲、冷卻25℃、熱延伸100℃、捲繞120rpm製成纖維。本發明之試驗結果如下。 In the first experimental example of the present invention, 80% by weight of polypropylene (melt flow rate 5 g/10 min) and 10% by weight of photovoltaic material (Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ ) powder are taken ( 2 μg of piezoelectric material (barium titanate ceramic) powder (particle size 1 μm), 2% by weight of thermoelectric material (containing alumina Al 2 O 3 35.92%, magnesium oxide MgO 33.86%) Iron oxide Fe 2 O 16.10%, titanium dioxide TiO 2 12.26% and cerium oxide SiO2 2.86% oxide) powder (particle size 1 μm), 3% by weight of catalyst material (gold 30% / titanium oxide 30% / Zinc oxide 40%) powder (particle size 0.3 μm), and EPDM accounted for 3% by weight (its Mooney viscosity 60). The above materials were granulated by twin-screw air-cooling granulation (granulation temperature: 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to make a plurality of granular base materials as a kneading material (average The particle size is about 5mm), and the processing material of the granular base material is 200°C/210°C/220°C/230°C/240°C/250°C at a single screw mixing temperature, and then the melt processed material is subjected to spinning and cooling. The fibers were formed by ° C, hot stretching at 100 ° C, and winding at 120 rpm. The test results of the present invention are as follows.
實驗例一之抗拉強度及撕裂強度試驗結果，請參看表1所示：隨著光電材料、壓電材料、熱電材料、觸媒材料及EPDM含量越多，其抗拉強度將逐漸下降，但仍保有要求的強度，因而本發明所添加的光電材料、壓電材料、熱電材料、觸媒材料及EPDM佔整體重量的20-30%為較佳(表1實例共添加20%做說明)。蓄光效果(Sr4Al14O25：Eu2+,Dy3+藍綠光488nm)有956分鐘效益。400~520nm波長有增加植物根、莖部位發展，對葉綠素與類胡蘿蔔素吸收最大，對光合作用影響最大。610~720nm波長促進對光合作用與植物生長速度(CaAl12O19：Mn4+紅光656nm)。 For the tensile strength and tear strength test results of Experimental Example 1, please refer to Table 1: As the photoelectric material, piezoelectric material, thermoelectric material, catalytic material and EPDM content are more, the tensile strength will gradually decrease. However, the required strength is still maintained. Therefore, the photoelectric material, the piezoelectric material, the thermoelectric material, the catalytic material and the EPDM added by the present invention account for 20-30% of the total weight (the example of Table 1 adds 20% for explanation) . The light storage effect (Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ blue-green light 488 nm) has a benefit of 956 minutes. The wavelength of 400~520nm increased the development of plant roots and stems, and absorbed the most chlorophyll and carotenoids, and had the greatest impact on photosynthesis. The 610-720 nm wavelength promotes photosynthesis and plant growth rate (CaAl 12 O 19 : Mn 4 + red light 656 nm).
實驗例一之遠紅外線放射率試驗結果，請參看表2所示：遠紅外線放射率試驗中，在50℃遠紅外線3-15μm的平均放射率為0.968。在5℃環境下其遠紅外線3-15μm平均放射率為0.918。 For the far-infrared emissivity test results of Experimental Example 1, please refer to Table 2: In the far-infrared emissivity test, the average emissivity of the far-infrared rays at 50 °C of 3-15 μm is 0.968. The average emissivity of far-infrared rays of 3-15 μm is 0.918 at 5 °C.
實驗例一之遠紅外線實驗結果，請參看表3所示；係以本發明所製纖維織成織品之遠紅外線人體生理實驗；使用在健康照護織品上具有30分鐘後升溫2.9℃。 The results of the far infrared ray experiment of Experimental Example 1 are shown in Table 3; the far-infrared human physiological experiment of the fiber woven fabric of the present invention; the temperature was raised by 2.9 ° C after 30 minutes on the health care fabric.
實驗例一之負離子實驗結果，請參看表4所示：係以本發明所製纖維織成織品進行試驗；動態摩擦下可增加空氣中2858負離子(個/cc)。 The results of the negative ion experiment of Experimental Example 1 are shown in Table 4: the fiber woven fabric of the present invention was tested; under dynamic friction, 2858 negative ions (pieces/cc) in the air were added.
實驗例一之水洗牢度試驗結果，請參看表5所示：水洗牢度試驗，測試前後仍維持良好的堅牢度，負離子的產生量並未因水洗而減 少。 For the test results of the washing fastness test in the first example, please refer to Table 5: Washing fastness test, the good fastness is maintained before and after the test, and the amount of negative ions is not reduced by washing. less.
實驗例一之空氣中總揮發有機物去除測試結果，請參看表6所示。 For the test results of the total volatile organic matter removal in the air in Experimental Example 1, please refer to Table 6.
實驗例一之室內空氣品質(汙染物去除測試)結果，請參看表7所示。測試儀器請參看表7-1所示。 See Table 7 for the results of Indoor Air Quality (Contaminant Removal Test) in Experimental Example 1. See Table 7-1 for test instruments.
實驗例一之空氣中正負離子汙染物去除測試效率結果，請參看表8所示。 For the test efficiency results of positive and negative ion contaminant removal in the air in Experimental Example 1, please refer to Table 8.
實驗例一之抗菌測試結果99.9%抑菌率(R%)，請參看表9所示。 The antibacterial test results of Experimental Example 1 were 99.9% inhibition rate (R%), as shown in Table 9.
實驗例一之防黴測試結果(0：沒有滋生黴菌)，請參看表10所示。 The anti-mildew test results of Experimental Example 1 (0: no mold), please refer to Table 10.
本發明之實驗例二，係取80%重量百分比的聚丙烯(熔融流率5g/10min)、2%重量百分比的光電材料(Sr4Al14O25：Eu2+,Dy3+)粉末(平均粒徑0.3μm)、2%重量百分比的壓電材料(鈦酸鋇陶瓷)粉末(平均粒徑1μm)、2%重量百分比的熱電材料(含有氧化鋁Al2O3 35.92%、氧化鎂MgO 33.86%、氧化鐵Fe2O 16.10%、二氧化鈦TiO2 12.26%及二氧化矽SiO2 2.86%重量百分比等氧化物)粉末(平均粒徑1μm)、3%重量百分比的觸媒材料(金30%/氧化鈦30%/氧化鋅40%重量百分比)粉末(平均粒徑0.3μm)、EPDM佔3%重量百分比(門尼黏度60)及8%重量百分比的植物精油材料(尤加利20%、檸檬30%及茶樹精油50%)，將前述全部材料以雙螺桿混練風冷卻造粒(造粒溫度為180℃/200℃/210℃/220℃/230℃/240℃)而製成複數個顆粒狀母材(平均粒徑約5mm)做為加工材料。再將加工材料以單螺桿混練(混練溫度為200℃/210℃/220℃/230℃/240℃/250℃)而形成熔融加工材料，再將熔融加工材料經抽絲、25℃冷卻、100℃熱延伸及以120rpm轉速捲繞而製成纖維。 In the second experimental example of the present invention, 80% by weight of polypropylene (melt flow rate: 5 g/10 min) and 2% by weight of photovoltaic material (Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ ) powder are taken ( 2 μg of piezoelectric material (barium titanate ceramic) powder (average particle size 1 μm), 2% by weight of thermoelectric material (containing alumina Al 2 O 3 35.92%, magnesium oxide MgO) 33.86%, iron oxide Fe 2 O 16.10%, titanium dioxide TiO 2 12.26% and cerium oxide SiO 2 2.86% by weight oxides) powder (average particle size 1 μm), 3% by weight of catalyst material (gold 30%) / titanium oxide 30% / zinc oxide 40% by weight) powder (average particle size 0.3 μm), EPDM accounted for 3% by weight (Mooney viscosity 60) and 8% by weight of plant essential oil material (eucalyptus 20%, 30% of lemon and 50% of tea tree oil), all of the above materials are cooled and granulated by twin-screw mixing air (granulation temperature is 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to make a plurality of A particulate base material (having an average particle diameter of about 5 mm) is used as a processing material. The processed material is then melted by single screw (mixing temperature is 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C) to form a melt processed material, and then the melt processed material is subjected to spinning, cooling at 25 ° C, 100 The fiber was thermally expanded and wound at 120 rpm to form a fiber.
實驗例二之織品的物理性，請參看表11所示：
實驗例二之塵螨忌避試驗結果忌避率(90.3%)，請參看表12所示：
實驗例二之精油成分-氣相層析質譜儀(GC/MS)檢測結果，請參看表13所示。將受測產品架設於1立方米之密閉測試箱中，並開啟受測產品運轉1小時測試。可得本商品精油成分如表13。測試方法：連接氣相層析質譜儀(GC/MS)檢測之。 The test results of the essential oil component-gas chromatography mass spectrometer (GC/MS) of Experimental Example 2 are shown in Table 13. The tested product is placed in a 1 cubic meter sealed test box, and the tested product is turned on for 1 hour. The essential oil components of this product are shown in Table 13. Test method: connected by gas chromatography mass spectrometry (GC/MS).
實驗例二之空氣中污染物去除量分析結果，請參看表14所示：在1m3密閉空間測試；1m2樣品6.5CMM下污染物每分鐘去除量。 For the results of the analysis of the amount of pollutants removed in the air in Experimental Example 2, please refer to Table 14 for the test in a 1 m 3 closed space; the removal of contaminants per minute in a 1 m 2 sample at 6.5 CMM.
本發明之實驗例三，係取70%重量百分比的聚丙烯(熔融流率5g/10min)、2%重量百分比的光電材料(Sr4Al14O25：Eu2+,Dy3+)粉末(平均粒徑0.3μm)、2%重量百分比的壓電材料(鈦酸鋇陶瓷)粉末(平均粒徑1μm)、2%重量百分比的熱電材料(含有氧化鋁Al2O3 35.92%、氧化鎂MgO 33.86%、氧化鐵Fe2O 16.10%、二氧化鈦TiO2 12.26%及二氧化矽SiO2 2.86%等氧化物)、3%重量百分比的觸媒材料(金30%/氧化鈦30%/氧化鋅40%)粉末(平均粒徑0.3μm)、EPDM佔3%重量百分比(門尼黏度60)、3%重量百分比的植物精油材料(尤加利20%、檸檬30%及茶樹精油50%重量百分比)、10%重量百分比的防火材料(氫氧化鎂90%及三氧化二銻10%重量百分比，粒徑0.5μm)及5%重量百分比的導電抗靜電材料(導電炭黑，粒徑0.2μm)，將前述全部材料以雙螺桿混練風冷卻造粒(造粒溫度為180℃/200℃/210℃/220℃/230℃/240℃)而製成複數個顆粒狀母材(平均粒徑約5mm)做為加工材料。再將加工材料以單螺桿混練(混練溫度為200℃/210℃/220℃/230℃/240℃/250℃)而形成熔融加工材料，再將熔融加工材料經抽絲、25℃冷卻、100℃熱延伸及以120rpm轉速捲繞而製成纖維。 In the third experimental example of the present invention, 70% by weight of polypropylene (melt flow rate: 5 g/10 min) and 2% by weight of photovoltaic material (Sr 4 Al 14 O 25 :Eu 2+ , Dy 3+ ) powder were taken ( 2 μg of piezoelectric material (barium titanate ceramic) powder (average particle size 1 μm), 2% by weight of thermoelectric material (containing alumina Al 2 O 3 35.92%, magnesium oxide MgO) 33.86%, iron oxide Fe 2 O 16.10%, titanium dioxide TiO 2 12.26% and cerium oxide SiO 2 2.86% oxide), 3% by weight of catalyst material (gold 30% / titanium oxide 30% / zinc oxide 40 %) powder (average particle size 0.3 μm), EPDM 3% by weight (Mooney viscosity 60), 3% by weight of plant essential oil material (eucalyptus 20%, lemon 30% and tea tree essential oil 50% by weight) 10% by weight of fireproof material (magnesium hydroxide 90% and antimony trioxide 10% by weight, particle size 0.5 μm) and 5% by weight of conductive antistatic material (conductive carbon black, particle size 0.2 μm), All the above materials are granulated by twin-screw air-cooling granulation (granulation temperature: 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to produce a plurality of granular base materials ( Average particle diameter of about 5mm) as the work material. The processed material is then melted by single screw (mixing temperature is 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C) to form a melt processed material, and then the melt processed material is subjected to spinning, cooling at 25 ° C, 100 The fiber was thermally expanded and wound at 120 rpm to form a fiber.
實驗例三之毒性氣體含量測試結果：符合規定。毒性氣體含量，請參看表15所示：本報告Toxic Gas值，係指燃燒測試4分鐘產生之毒性氣體含量。ABD0031(2005)ISSUE：F之要求：已檢知管(Detection tube)量測HF<100，HCL<150，HCN<150，SO2<100，XO2<100，CO<1000。 Test Example 3 toxic gas content test results: in line with the regulations. For toxic gas content, please refer to Table 15: The Toxic Gas value in this report refers to the toxic gas content produced by the combustion test for 4 minutes. ABD0031 (2005) ISSUE: F requirements: Detection tube measurement HF <100, HCL < 150, HCN < 150, SO 2 <100, XO 2 <100, CO <1000.
實驗例三之水平燃燒測試結果測試結果：符合規定。請參看表16所示。FAR 25.853(b)(Amdt.25-116,2004)&Appendix F Par I(a)(1)(ii)。火焰時間(Flame Time)：≦15Sec；滴灌火焰時間(Drip Flame Time)：≦5Sec；燃燒長度(Burn Length)：≦8in(203.2mm)。 Experimental Example 3 Horizontal Burning Test Results Test Results: Compliance. Please refer to Table 16. FAR 25.853(b) (Amdt. 25-116, 2004) & Appendix F Par I(a)(1)(ii). Flame Time: ≦15Sec; Drip Flame Time: ≦5Sec; Burn Length: ≦8in (203.2mm).
實驗例三之垂直燃燒測試結果測試結果：符合規定。請參看表17所示。FAR 25.853附錄Appendix F Amdt.25-111。te(10)=te(11.5)-te(1.5)。 Experimental Example 3 Vertical Burning Test Results Test Results: Compliance. Please refer to Table 17. FAR 25.853 appendix Appendix F Amdt. 25-111. Te(10)=te(11.5)-te(1.5).
實驗例三之煙濃度測試結果：符合規定。請參看表18所示：Dm為測試樣品在測試時間4分鐘內，所測得煙濃度之最大值。ABD0031(2005)Issue：F規範要求：在有焰或無焰的測試條件下，測試時間4分鐘內的最大煙濃度不應超過表19所列的規範值。 Test sample smoke concentration test results: in accordance with the regulations. Please refer to Table 18: D m is the maximum value of the measured smoke concentration within 4 minutes of the test time of the test sample. ABD0031 (2005) Issue: F specification requires that, under flaming or flameless test conditions, the maximum smoke concentration within 4 minutes of the test time should not exceed the specifications listed in Table 19.
實驗例三之導電抗靜電測試結果：R=5.8x 105Ω，請參看表20所示。 Conductive antistatic test results of Experimental Example 3: R = 5.8 x 10 5 Ω, see Table 20.
以上所述，僅為本發明之一可行實施例，並非用以限定本發明之專利範圍，凡舉依據下列請求項所述之內容、特徵以及其精神而為之其他變化的等效實施，皆應包含於本發明之專利範圍內。 本發明所具體界定於請求項之結構特徵，未見於同類物品，且具實用性與進步性，已符合創作專利要件，爰依法具文提出申請，謹請 鈞局依法核予專利，以維護本申請人合法之權益。 The above is only one of the possible embodiments of the present invention, and is not intended to limit the scope of the patents of the present invention, and the equivalent implementations of other changes according to the contents, features and spirits of the following claims are It should be included in the scope of the patent of the present invention. The invention is specifically defined in the structural features of the request item, is not found in the same kind of articles, and has practicality and progress, has met the requirements for the creation of patents, and has filed an application according to law, and requests the bureau to approve the patent according to law to maintain the present. The legal rights of the applicant.
10‧‧‧纖維 10‧‧‧Fiber
20‧‧‧織品 20‧‧‧ fabric
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