TWI569724B - Granular pesticidal composition - Google Patents
Granular pesticidal composition Download PDFInfo
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- TWI569724B TWI569724B TW100123615A TW100123615A TWI569724B TW I569724 B TWI569724 B TW I569724B TW 100123615 A TW100123615 A TW 100123615A TW 100123615 A TW100123615 A TW 100123615A TW I569724 B TWI569724 B TW I569724B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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Description
本發明是關於一種顆粒狀農藥組成物。This invention relates to a particulate pesticide composition.
以往，在農作物的栽培上，有許多有害生物防治活性化合物、植物病害防治活性化合物、除草活性化合物等的農藥活性成分，以種種的形態被適用。In the past, there are many pesticidal active ingredients such as a pest control active compound, a plant disease control active compound, and a herbicidal active compound, which are applied in various forms.
例如，在水稻的栽培上，在育苗箱預先施用農藥製劑，則在該育苗箱生育的幼苗在水田移植同時，前述農藥製劑所含的農藥活性成分也會被施用到水田中。移植後前述農藥活性成分有可能產生效力時，這個方法就可成為在水稻栽培上的對有害生物、植物病害、雜草等有效率的防治方法。因此，為了能適用於該防治方法而有多種的農藥製劑的開發。For example, in the cultivation of rice, the pesticide preparation is pre-applied in the nursery box, and the seedlings which are grown in the nursery box are transplanted in the paddy field, and the pesticide active ingredient contained in the above-mentioned pesticide preparation is also applied to the paddy field. When the above-mentioned pesticide active ingredient is likely to have an effect after transplantation, this method can be an effective method for controlling pests, plant diseases, weeds, etc. in rice cultivation. Therefore, in order to be applicable to this control method, there are various types of pesticide preparation development.
在前述防治方法中，有要求農藥活性成分能長期發揮防治效力，並有要求大量的農藥活性成分的施用。但是，在水稻幼苗等的生育初期的植物體施用過量的農藥活性成分時，也有引起植物體的生育不良等情況，有其改善的要求。In the aforementioned control method, it is required that the active ingredient of the pesticide can exert the control effect for a long period of time, and a large amount of the active ingredient of the pesticide is required to be applied. However, when an excessive amount of agrochemical active ingredient is applied to a plant body at the early stage of growth, such as rice seedlings, there is a case where the plant body is poorly grown, and there is a demand for improvement.
農藥活性成分而言，做為有害生物防治活性化合物而為人所知有剋安勃(Chlorantraniliprole)(一般名，式(I)表示的化合物)(例如，參照專利文獻1)：In the case of a pesticidal active ingredient, Chlorantraniliprole (general name, a compound represented by the formula (I)) is known as a pest control active compound (for example, refer to Patent Document 1):
又，噻醯菌胺(tiadinil)、異噻菌胺(isotianil)、撲殺熱(probenazole)及甲噻活素(Acibenzolar-S-methyl)都是為人所知的作用於水稻的植物體，而表現對稻熱病等的對植物病害的抵抗性誘導的活性物質(例如，參照專利文獻2及非專利文獻1)。Further, tiadinil, isotianil, probenazole, and Acibenzolar-S-methyl are well-known plants acting on rice, and An active substance that exhibits resistance to plant diseases such as rice fever (see, for example, Patent Document 2 and Non-Patent Document 1).
[專利文獻1] 特表2004-538328號公報[Patent Document 1] Japanese Patent Publication No. 2004-538328
[專利文獻2] 國際公開2008/007778號小冊[Patent Document 2] International Publication No. 2008/007778
[非專利文獻1]植物防疫，第61卷第10號(2007)，第531頁-第536頁(社團法人日本植物防疫協會發行)[Non-Patent Document 1] Plant Epidemic Prevention, Vol. 61, No. 10 (2007), p. 531 - p. 536 (issued by the Japan Plant Epidemic Prevention Association)
本發明是提供含有前述式(I)表示的化合物，並有優異性能的農藥製劑為課題。The present invention provides a pesticide preparation containing the compound represented by the above formula (I) and having excellent properties.
本發明者等，為了要找出含有前述式(I)表示的化合物，並有優異的性能的農藥製劑起見精心檢討的結果，發現含有前述式(I)表示的化合物，與由噻醯菌胺(tiadinil)、異噻菌胺(isotianil)、撲殺熱(probenazole)及甲噻活素(Acibenzolar-S-methyl)所成的群中所選的1種以上的植物病害防治活性化合物，含有膨潤石(smectite)礦物的增量劑，與水溶性結合劑的農藥顆粒狀組成物，有優異的性能而達成本發明。 The inventors of the present invention have found that the compound represented by the above formula (I) and the compound represented by the above formula (I) are found to contain the compound represented by the above formula (I) and have excellent performance. One or more plant disease control active compounds selected from the group consisting of tiadinil, isotianil, probenazole, and Acibenzolar-S-methyl, containing swelling The present invention is achieved by an extender of smectite minerals and a pesticide granular composition of a water-soluble binder having excellent properties.
即，本發明如下之[1]至[11]。 That is, the present invention is as follows [1] to [11].
[1]一種顆粒狀農藥組成物，係含有以式(I)表示的化合物，
由噻醯菌胺(tiadinil)、異噻菌胺(isotianil)、撲殺熱(probenazole)、甲噻活素(Acibenzolar-S-methyl)所成之群中所選的1種以上的植物病害防治活性化合物，含有膨潤石礦物的增量劑，與水溶性結合劑。 One or more plant disease control activities selected from the group consisting of tiadinil, isotianil, probenazole, and Acibenzolar-S-methyl A compound comprising a bulking agent of a bentonite mineral and a water soluble binder.
[2]如[1]所述的顆粒狀農藥組成物，對式(I)表示之化合物100重量份，植物病害防治活性化合物是100至5000重量份的含有比率。 [2] The particulate pesticide composition according to [1], wherein the plant disease controlling active compound is contained in an amount of 100 to 5000 parts by weight based on 100 parts by weight of the compound represented by the formula (I).
[3]如[1]或[2]所述的顆粒狀農藥組成物，該顆粒狀農藥組成物的式(I)表示之化合物與植物病害防治活性化合物的合計含有比率在1至30重量%。 [3] The particulate pesticide composition according to [1] or [2], wherein the total content of the compound represented by the formula (I) and the plant disease controlling active compound is from 1 to 30% by weight. .
[4]如[1]至[3]所述的任1種顆粒狀農藥組成物，該顆粒狀農藥組成物中的含有膨潤石礦物的增量劑含有比率在40至98重量%。[4] The particulate pesticide composition according to any one of [1] to [3], wherein the extender-containing content of the bentonite mineral in the particulate pesticide composition is from 40 to 98% by weight.
[5] 如[1]至[4]所述的任1種顆粒狀農藥組成物，該顆粒狀農藥組成物中的水溶性結合劑的含有比率在1至10重量%。[5] The particulate pesticide composition according to any one of [1] to [4], wherein the content ratio of the water-soluble binder in the particulate pesticide composition is from 1 to 10% by weight.
[6] 如[1]至[5]所述的任1種顆粒狀農藥組成物，該顆粒狀農藥組成物中的植物病害防治活性化合物為異噻菌胺(isotianil)。[6] The particulate disease-controlling active compound according to any one of [1] to [5], wherein the plant disease controlling active compound in the particulate pesticide composition is isotianil.
[7] 如[1]至[6]所述的任1種顆粒狀農藥組成物，再含有新類尼古丁(Neonicotinoid)化合物。[7] The particulate pesticide composition according to any one of [1] to [6], further comprising a novel neonicotinoid compound.
[8] 如[7]所述的顆粒狀農藥組成物，該新類尼古丁是可尼丁(Clothianidin)。[8] The granular pesticide composition according to [7], wherein the new nicotine is Clothianidin.
[9] 如[1]至[8]所述的任1種顆粒狀農藥組成物，其所含的含有膨潤石礦物的增量劑是含有膨潤石礦物及碳酸鈣。[9] The particulate pesticide composition according to any one of [1] to [8], wherein the extender containing the bentonite mineral contains a bentonite mineral and calcium carbonate.
[10]如[1]至[9]所述的任1種顆粒狀農藥組成物，該膨潤石礦物是皂土(bentonite)，[10] The granulated pesticide composition according to any one of [1] to [9], wherein the bentonite mineral is bentonite.
[11]如[1]至[10]所述的任1種顆粒狀農藥組成物，該水溶性化合物是預糊化澱粉(alphatized starch)。[11] The granulated pesticide composition according to any one of [1] to [10], wherein the water-soluble compound is alphatized starch.
由本發明可提供有優異性能的農藥製劑。A pesticide preparation having excellent properties can be provided by the present invention.
本發明的農藥顆粒狀組成物，含有式(I)表示的化合物：
前述式(I)的化合物是一般名為人所知的剋安勃(Chlorantraniliprole)的醯胺化合物。式(I)的化合物，例如日本專利特表2004-538328公報的實施例6所述，可使用該文獻所述之方法製造。 The compound of the above formula (I) is a guanamine compound generally known as Chlorantraniliprole. The compound of the formula (I), for example, as described in Example 6 of JP-A-2004-538328, can be produced by the method described in the literature.
本發明的農藥顆粒狀組成物中的式(I)的化合物的含有量通常是約0.1至5重量%。理想是約0.5至2重量%。 The content of the compound of the formula (I) in the pesticidal particulate composition of the present invention is usually from about 0.1 to 5% by weight. It is desirably about 0.5 to 2% by weight.
本植物病害防治活性化合物噻醯菌胺(tiadinil)是下式(II)表示的化合物：
撲殺熱(probenazole)是下述式(IV)表示的化合物：The probenazole is a compound represented by the following formula (IV):
甲噻活素(Acibenzolar-S-methyl)是下述式(V)表示的化合物：Acibenzolar-S-methyl is a compound represented by the following formula (V):
都可使用市售的化合物。Commercially available compounds can be used.
本發明的農藥顆粒組成物中，含有本植物病害防治活性化合物之1種或2種以上，但其含有量通常是約1至25重量%，理想是1至5重量%。The pesticide particle composition of the present invention contains one or more of the plant disease-controlling active compounds, but the content thereof is usually from about 1 to 25% by weight, preferably from 1 to 5% by weight.
又，本發明的農藥顆粒狀組成物中所含的式(I)的化合物與本植物病害防治活性化合物的含量比率是，對式(I)的化合物100重量份為約100至5000重量份，理想是約100至600重量份。Further, the content ratio of the compound of the formula (I) and the plant disease controlling active compound contained in the pesticidal particulate composition of the present invention is about 100 to 5000 parts by weight based on 100 parts by weight of the compound of the formula (I). It is desirably about 100 to 600 parts by weight.
在本發明的農藥顆粒狀組成物中的式(I)的化合物與本植物病害防治活性化合物的合計含有量通常是約1至30重量%，理想是約1.5至7重量%，更理想是約1.5至5重量%。The total content of the compound of the formula (I) and the plant disease controlling active compound in the pesticidal granular composition of the present invention is usually from about 1 to 30% by weight, preferably from about 1.5 to 7% by weight, more preferably about 1.5 to 5% by weight.
本發明的農藥顆粒狀組成物，除了式(I)的化合物及本植物病害防治活性化合物之外，再可含有其他的農藥活性化合物。這種其他的農藥活性化合物而言，例如可舉：殺蟲活性化合物、殺菌活性化合物、昆蟲成長調控活性化合物、除草活性化合物及植物成長調控活性成分。The pesticide granular composition of the present invention may contain other pesticidal active compounds in addition to the compound of the formula (I) and the plant disease controlling active compound. Examples of such other pesticidal active compounds include insecticidal active compounds, bactericidal active compounds, insect growth regulating active compounds, herbicidal active compounds, and plant growth regulating active ingredients.
本發明的農藥顆粒狀組成物中含有其他的農藥活性化合物時，這種其他的農藥活性化合物在本發明的農藥顆粒狀組成物中的含有量通常是約0.5至40重量%，理想是1至10重量%。When the pesticidal particulate composition of the present invention contains other pesticidal active compounds, the content of such other pesticidal active compound in the pesticidal particulate composition of the present invention is usually from about 0.5 to 40% by weight, preferably from 1 to 10% by weight.
在本發明的農藥顆粒狀組成物中含有的含有膨潤石礦物的增量劑可以是膨潤石礦物本身，或膨潤石礦物與膨潤石礦物以外的物質的混合物也可以。The extender containing the bentonite mineral contained in the pesticidal particulate composition of the present invention may be a bentonite mineral itself or a mixture of a bentonite mineral and a substance other than the bentonite mineral.
膨潤石礦物而言，詳細而言可舉：皂石(saponite)、水輝石(hectorite)、鋅蒙脫石(Sauconite)、斯蒂文石(Stevensite)、鐵膨潤石(nontronite)、蒙脫石(montmorillonite)及鐵鋁膨潤石(beidellite)，合適的是可舉蒙脫石。做為蒙脫石具體而言，可舉蒙脫石富士、蒙脫石穗高、蒙脫石赤城、蒙脫石妙義、超黏土(均為商品名，豐順(Hojun)公司製)、KunigelV1、KunigelV2、KunigelVA、Kunibond(均為註冊商標，Kunimine工業公司製)、關西蒙脫石(商品名，Kanesan工業公司製)等的蒙脫石。For the bentonite mineral, in detail, saponite, hectorite, sulconite, Stevensite, nontronite, montmorillonite (montmorillonite) and iron-aluminum bentonite (beidellite), suitable for montmorillonite. Specifically, as montmorillonite, montmorillonite Fuji, montmorillonite spike height, montmorillonite Chicheng, montmorillonite Miaoyi, super clay (all trade names, manufactured by Hojun Co., Ltd.), Kunigel V1 Kunigel V2, Kunigel VA, Kunibond (both registered trademarks, manufactured by Kunimine Industries, Inc.), and Kansai montmorillonite (trade name, manufactured by Kanesan Industries Co., Ltd.).
增量劑是膨潤石礦物與膨潤石礦物以外的物質的混合物時，做為膨潤石以外的礦物而言，例如可舉：高嶺石、的狄克石(dickite)、珍珠石(nacrite)、禾樂石(halloysite)等高嶺石類礦物，溫石綿(chrysotile)、蜥蛇紋石(lizardite)、葉蛇紋石(antigorite)、鎂鋁蛇紋石(amesite)等蛇紋石，葉蠟石(pyrophyllite)、滑石(talc)、蠟石、白雲母、多矽白雲母(phengite)、絹雲母(sericite)、伊來石(illite)等雲母，方矽石(cristobalite)、石英(quartz)等氧化矽，厄帖浦石(attapulgite)、海泡石(sepiolite)等含水矽酸鎂，石膏等硫酸鹽礦物，白雲石(dolomite)、石膏(gypsum)、沸石(zeolite)、沸石、凝灰石、蛭石(vermiculite)、合成鋰皂石(laponite)、浮石、矽藻土、碳酸鈣等礦物質承載物；玉米穗軸粉、胡桃殼粉、稻殼粉、小麥粉、木粉、糠、麩糠、大豆粉等的植物系承載物；尿素、乳糖、蔗糖、食鹽、芒硝等的水溶性固體承載物。When the extender is a mixture of a bentonite mineral and a substance other than the bentonite mineral, examples of the mineral other than the bentonite include kaolinite, dickite, nacrite, and Halloyite and other kaolinite minerals, chrysotile, lizardite, antigorite, amesite serpentine, pyrophyllite, talc (talc), wax stone, muscovite, phengite, sericite, illite, mica, cristobalite, quartz, etc. Aqueducts such as attapulgite and sepiolite, sulfate minerals such as gypsum, dolomite, gypsum, zeolite, zeolite, tuff, vermiculite ), minerals such as laponite, pumice, diatomaceous earth, calcium carbonate, etc.; corn cob powder, walnut shell powder, rice husk powder, wheat flour, wood flour, alfalfa, bran, soy flour Plant-based carrier; water solubility of urea, lactose, sucrose, salt, thenardite, etc. Carrying body thereof.
在本發明的農藥顆粒狀組成物中，含有膨潤石礦物的增量劑，對本發明的農藥顆粒狀組成物全體通常含有約40至98%重量%，理想是約60至95重量%。In the pesticidal particulate composition of the present invention, the extender containing the bentonite mineral usually contains about 40 to 98% by weight, preferably about 60 to 95% by weight, based on the total of the agricultural chemical particulate composition of the present invention.
在本發明的農藥顆粒狀組成物中的增量劑是膨潤石礦物與膨潤石礦物以外的物質的混合物時，對本發明的農藥顆粒狀組成物的膨潤石礦物的含有量而言，例如可舉：5至40重量%，理想是5至20重量%。When the extender in the pesticidal particulate composition of the present invention is a mixture of a bentonite mineral and a substance other than the bentonite mineral, the content of the bentonite mineral of the agricultural chemical particulate composition of the present invention may be, for example, : 5 to 40% by weight, desirably 5 to 20% by weight.
在本發明的農藥顆粒狀組成物中，含有水溶性結合劑。這種結合劑而言，例如可舉：羧甲基纖維素鈉、羥丙基甲基纖維素、甲基纖維素、甲基乙基纖維素、羥丙基纖維素、聚丙烯酸鈉、黃著膠、聚乙烯吡咯酮、聚乙烯醇、預糊化澱粉、糊精、海藻酸及海藻酸鈉。The pesticide granular composition of the present invention contains a water-soluble binder. Such a binder may, for example, be sodium carboxymethylcellulose, hydroxypropylmethylcellulose, methylcellulose, methylethylcellulose, hydroxypropylcellulose, sodium polyacrylate, yellow Gum, polyvinylpyrrolidone, polyvinyl alcohol, pregelatinized starch, dextrin, alginic acid and sodium alginate.
在本發明的農藥顆粒狀組成物中，水溶性結合劑通常含有約1至10重量%，理想是約1至5重量%。In the pesticidal particulate composition of the present invention, the water-soluble binder usually contains from about 1 to 10% by weight, desirably from about 1 to 5% by weight.
本發明的農藥顆粒狀組成物，除了式(I)的化合物、本植物病害防治活性化合物、含有膨潤石礦物的增量劑及水溶性結合劑、再加任意含有的其他農藥活性化合物之外，也可含有界面活性劑、溶劑、安定劑、防腐劑、著色劑、香料等。The pesticide granular composition of the present invention, in addition to the compound of the formula (I), the plant disease controlling active compound, the extender containing a bentonite mineral, and a water-soluble binder, together with any other pesticidal active compound optionally contained, It may also contain a surfactant, a solvent, a stabilizer, a preservative, a colorant, a fragrance, and the like.
本發明的農藥顆粒狀組成物，例如以擠出造粒法、含浸法、或覆蓋法而製成顆粒狀製劑。The granular material composition of the present invention is prepared into a granular preparation by, for example, extrusion granulation, impregnation, or coating.
本發明的農藥顆粒狀組成物，在含有式(I)的化合物、本植物病害防治活性化合物、含有膨潤石礦物的增量劑及水溶性結合劑、再視需要如何而加任意含有的其他農藥活性化合物、界面活性劑、溶劑、安定劑、防腐劑、著色劑、香料等的混合物中，加水而混練，將所得混練物造粒，將所得造粒物乾燥，視需要而進行破碎、篩選、整粒等而製造。The pesticide granular composition of the present invention contains the compound of the formula (I), the plant disease control active compound, the extender containing a bentonite mineral, and a water-soluble binder, and optionally contains other pesticides as needed. a mixture of an active compound, a surfactant, a solvent, a stabilizer, a preservative, a coloring agent, a fragrance, and the like, and kneading with water, granulating the obtained kneaded product, drying the obtained granulated product, and crushing and screening as necessary. Manufactured by whole grain, etc.
前述混練中，可使用摻合機。摻合機而言，可舉捏合機(kneader)、諾塔混合機(nauta mixer)、羅迪格混合機(Loedige mixer)等。In the aforementioned kneading, a blending machine can be used. The blender may be a kneader, a nauta mixer, a Loedige mixer or the like.
混練時所用的水量，對前述混合物100重量份通常是3至50重量份的比率。The amount of water used in the kneading is usually a ratio of 3 to 50 parts by weight based on 100 parts by weight of the aforementioned mixture.
將前述混練物擠出造粒時，通常是使用0.5至2.0mmφ，理想是0.7至1.5mmφ的篩網而實施。When the kneaded product is extruded and granulated, it is usually carried out using a sieve of 0.5 to 2.0 mmφ, preferably 0.7 to 1.5 mmφ.
使用的擠出造粒機而言，可列舉螺桿型(screw type)擠出造粒機、滾筒型(roller type)擠出造粒機、圓盤製粒型(disk pelletor type)擠出造粒機、製粒型擠出造粒機(pellet mill type)、籃型(basket type)擠出造粒機、格子(plaid type)型擠出造粒機、振盪擠出造粒機(oscillating type)、齒輪型(gear type)擠出造粒機、圓環模子型(ring type)擠出造粒機等。具體而言，可使用不二(Fuji) Paudal公司製的雙半球形型造粒機(twin dome granulator)、單半球形型造粒機(single dome granulator)等。Examples of the extrusion granulator to be used include a screw type extrusion granulator, a roller type extrusion granulator, and a disk pelletor type extrusion granulation. Machine, granule extrusion granulator, basket type extrusion granulator, plaid type extrusion granulator, oscillating type oscillating type A gear type extrusion granulator, a ring type extrusion granulator, and the like. Specifically, a twin dome granulator manufactured by Fuji Paudal Co., Ltd., a single dome granulator, or the like can be used.
所得造粒物通常是在30至90℃，理想是在30至80℃乾燥。The resulting granules are usually dried at 30 to 90 ° C, desirably at 30 to 80 ° C.
乾燥後，所得本發明的農藥顆粒狀組成物的粒長通常是0.5至6.0mm，理想是0.7至4.0mm。又，在本發明的粒長就是，指顆粒可以有的最大長度而言。After drying, the obtained granular particle composition of the present invention has a particle length of usually 0.5 to 6.0 mm, preferably 0.7 to 4.0 mm. Further, the grain length in the present invention means, in terms of the maximum length that the particles can have.
本發明的農藥顆粒狀組成物，可在對水稻的育苗箱的播種時或發芽後到移植於水田前的水稻育苗時施用於育苗箱。其施用量，依式(I)的化合物及本植物病害防治活性化合物的含有量及水稻育苗箱的大小而可變動，但例如：30cm×60cm大小的水稻育苗箱每1箱，式(I)的化合物及本植物病害防治活性化合物的合計量約為0.05至4.0g。The pesticide granular composition of the present invention can be applied to a nursery box at the time of seeding of the rice seedling box or after germination to the rice seedling transplanted before the paddy field. The application amount thereof may vary depending on the content of the compound of the formula (I) and the plant disease control active compound and the size of the rice seedling box, but for example, a rice seedling box of 30 cm×60 cm size per case, formula (I) The total amount of the compound and the plant disease control active compound is about 0.05 to 4.0 g.
其次，將本發明以參考製造例、比較例及試驗例更詳細說明，但本發明不受其任何限定。Next, the present invention will be described in more detail with reference to Production Examples, Comparative Examples and Test Examples, but the present invention is not limited thereto.
70.0重量份的2’-氰基-3,4-二氯異噻唑-5-羧基苯胺化物(一般名：異噻菌胺(isotianil))及30.0重量份的蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)混合均勻，以離心粉碎機全量粉碎，得容積中值粒徑為4.12μm(以MALVERN製MASTERSIZER2000測定)的含有2’-氰基-3,4-二氯異噻唑-5-羧基苯胺化物的粉狀農藥組成物(以下簡稱為粉狀農藥組成物1)。70.0 parts by weight of 2'-cyano-3,4-dichloroisothiazol-5-carboxyaniline (general name: isotianil) and 30.0 parts by weight of wax stone (trade name: Shengguangshan clay) S, Shengguangshan Mining Co., Ltd.) is uniformly mixed and pulverized by a centrifugal pulverizer to obtain 2'-cyano-3,4-dichloroisothiazole having a volume median diameter of 4.12 μm (measured by MALVERN MASTERSIZER2000). A powdery pesticide composition of -5-carboxyaniline (hereinafter referred to as powdered pesticide composition 1).
70.0重量份的式(I)的化合物及30.0重量份的蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)混合均勻，以離心粉碎機全量粉碎，得容積中值粒徑為3.92μm(以MALVERN製MASTERSIZER2000測定)的含有式(I)的化合物的粉狀農藥組成物(以下簡稱為粉狀農藥組成物2)。70.0 parts by weight of the compound of the formula (I) and 30.0 parts by weight of the wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) were uniformly mixed, and pulverized by a centrifugal pulverizer to obtain a volume median diameter of 3.92. A powdery agrochemical composition containing a compound of the formula (I) (hereinafter referred to as a powdery agrochemical composition 2) of μm (measured by MASTERSIZER 2000 manufactured by MALVERN).
70.0重量份的(E)-1-(2-氯-1,3-噻唑-5-基甲基)-3-甲基-2-硝基胍(一般名：可尼丁(CLOTHIANIDIN))及30.0重量份的蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)混合均勻，以離心粉碎機全量粉碎，得容積中值粒徑為8.20μm(以MALVERN製MASTERSIZER2000測定)的含有(E)-1-(2-氯-1,3-噻唑-5-基甲基)-3-甲基-2-硝基胍的粉狀農藥組成物(以下簡稱為粉狀農藥組成物3)。70.0 parts by weight of (E)-1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroindole (general name: CLOTHIANIDIN) and 30.0 parts by weight of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) was uniformly mixed and pulverized by a centrifugal pulverizer to obtain a volume median diameter of 8.20 μm (measured by MALVERN MASTERSIZER 2000). E) Powdered pesticide composition of 1-(2-chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroindole (hereinafter referred to as powdered pesticide composition 3) .
將46.3重量份的SumiphenTM(註冊商標，Sumitomo Bayer Urethane公司製，支鏈型聚醚聚醇)，52.2重量份的Sumiphen 1600U(註冊商標，Sumitomo Bayer Urethane公司製，直鏈型聚醚聚醇)，及1.5重量份的2,4,6-三(二甲基胺基甲基)酚(KAYAKU AKZO製造)混合均勻，而得聚醇與觸媒的液狀混合物(以下簡稱為聚醇前混合物1)。聚醇前混合物1的黏度是322m‧Pa(以B型黏度計，25℃，12回轉，1號轉子(rotor)測定)。46.3 parts by weight of the Sumiphen TM (registered trademark, Sumitomo Bayer Urethane Co., Ltd., a branched polyether polyol), 52.2 parts by weight of Sumiphen 1600U (registered trademark, Sumitomo Bayer Urethane Co., straight-chain polyether polyol) And 1.5 parts by weight of 2,4,6-tris(dimethylaminomethyl)phenol (manufactured by KAYAKU AKZO) are uniformly mixed to obtain a liquid mixture of a polyalcohol and a catalyst (hereinafter referred to as a pre-polyol mixture). 1). The viscosity of the pre-polyol mixture 1 was 322 m·Pa (measured by a B-type viscosity meter, 25 ° C, 12 turns, and a rotor 1).
在高速混合機裝置(深江Powteck公司製FS-GS-25型；有貫穿圓盤形的容器部的底面中心的垂直線為回轉軸的攪拌片及貫穿圓盤型的容器部的側面的水平線為回轉軸的切碎片的裝置)的容器內，裝入100重量份的粉狀農藥組成物3，轉動該裝置的攪拌片(回轉數：382rpm)及切碎片(回轉數：3500rpm)。其次，將混合容器加溫，在保持粉狀農藥組成物3的品溫於85±5℃，費2分鐘添加1.93重量份的聚醇前混合物1。可觀察到該聚醇前混合物1受到粉狀農藥組成物3所濕潤的狀況。在3分鐘後，將品溫保持在85±5℃，費2分鐘添加1.07重量份的Sumijul 44V10(註冊商標，Sumitomo Bayer Urethane公司製，聚亞甲基聚苯基聚異氰酸酯，黏度130m‧Pa(25℃))。添加後立即可確認增黏現象，之後，黏度降低，觀察到聚胺酯樹脂的硬化(對100重量份的粉狀農藥組成物3，相當於3.0重量份的聚胺酯樹脂)。在6分鐘後，將品溫保持在85±5℃，將下述的胺甲酸乙酯(urethane)的添加操作重複34次。In the high-speed mixer device (Model FS-GS-25 manufactured by Deepwater Powteck Co., Ltd.; the horizontal line of the side of the bottom surface of the bottom portion of the container portion that penetrates the disk-shaped container portion is the rotating shaft and the horizontal line of the side portion of the container portion that penetrates the disk-shaped portion is In a container of the device for cutting chips of the rotary shaft, 100 parts by weight of the powdery agrochemical composition 3 was placed, and the stirring piece (rotation number: 382 rpm) of the apparatus and the chips (revolution number: 3500 rpm) were rotated. Next, the mixing container was heated, and 1.93 parts by weight of the pre-polyol mixture 1 was added for 2 minutes while maintaining the temperature of the powdery pesticide composition 3 at 85 ± 5 °C. It was observed that the pre-polyol mixture 1 was wetted by the powdery pesticide composition 3. After 3 minutes, the product temperature was maintained at 85 ± 5 ° C, and 1.07 parts by weight of Sumijul 44V10 (registered trademark, manufactured by Sumitomo Bayer Urethane Co., Ltd., polymethylene polyphenyl polyisocyanate, viscosity 130 m‧Pa (added) was added for 2 minutes. 25 ° C)). Immediately after the addition, the viscosity-increasing phenomenon was confirmed, and thereafter, the viscosity was lowered, and curing of the polyurethane resin was observed (for 100 parts by weight of the powdery agrochemical composition 3, which corresponds to 3.0 parts by weight of the polyurethane resin). After 6 minutes, the product temperature was maintained at 85 ± 5 ° C, and the following urethane addition operation was repeated 34 times.
將1.93重量份的聚醇前混合物1費2分鐘添加→等待3分鐘→將1.07重量份的Sumijul 44V10費2分鐘添加→等待6分鐘。1.93 parts by weight of the pre-polyol mixture 1 was added for 2 minutes → wait for 3 minutes → 1.07 parts by weight of Sumijul 44V10 was added for 2 minutes → wait for 6 minutes.
在上述的胺甲酸乙酯的添加操作中，高速混合機裝置繼續同條件下有剪斷力的攪拌混合。In the above-described addition operation of the urethane ethyl ester, the high-speed mixer apparatus continues stirring mixing with shearing force under the same conditions.
對於100重量份的粉狀農藥組成物3，添加合計105重量份的聚胺酯樹脂原料。上述操作完成後，添加4.76重量份的碳酸鈣NS#2300(日東粉化公司製)，混合3分鐘。混合後，冷卻該混合物，而得粉狀農藥組成物3被聚胺酯樹脂固定，覆蓋而成的硬化性樹脂微粉末(以下稱為含有農藥之熱硬化性樹脂微粉末1；容積中值粒徑：44μm，容積重(bulk density,apparent density)：0.42g/ml)。To 100 parts by weight of the powdery agrochemical composition 3, a total of 105 parts by weight of a polyurethane resin raw material was added. After the above operation was completed, 4.76 parts by weight of calcium carbonate NS#2300 (manufactured by Nitto Powder Chemical Co., Ltd.) was added and mixed for 3 minutes. After mixing, the mixture is cooled to obtain a curable resin fine powder in which the powdery agrochemical composition 3 is fixed by a polyurethane resin (hereinafter referred to as a thermosetting resin fine powder 1 containing a pesticide; volume median diameter: 44 μm, bulk density, apparent density: 0.42 g/ml).
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石穗高，豐順公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的65.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物1。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight of montmorillonite (trade name: montmorillonite spike, manufactured by Fengshun Co., Ltd.), and 10.0 parts by weight of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylidene styrylphenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added. Mixed. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 1.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石穗高，豐順公司製)的7.5重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的68.1重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物2。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, 7.5 parts by weight of montmorillonite (trade name: montmorillonite spike, manufactured by Fengshun Co., Ltd.), and 68.1 parts of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylidene styrylphenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added. Mixed. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 2.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石妙義，豐順公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的65.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物3。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, 10.0 parts by weight of montmorillonite (trade name: montmorillonite Miaoyi, manufactured by Fengshun Co., Ltd.), and 65.6 parts by weight of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To the mixture, about 10 parts by weight of water containing 1.0% by weight of a surfactant (polyoxy-triethylstilbene phenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added, and kneading was carried out. . About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 3.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：Kunigel VA(註冊商標)，Kunimine工業公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的65.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物4。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight of montmorillonite (trade name: Kunigel VA (registered trademark), manufactured by Kunimine Industries Co., Ltd.), and wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of 65.6 parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylene striphenylstyrene ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Co., Ltd.), And mixing. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 4.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：Kunigel V2(註冊商標)，Kunimine工業公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的65.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物5。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight of montmorillonite (trade name: Kunigerel V2 (registered trademark), manufactured by Kunimine Industries Co., Ltd.), and wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of 65.6 parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylene striphenylstyrene ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Co., Ltd.), And mixing. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 5.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名Kunibond，Kunimi工業公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的65.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物6。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, 10.0 parts by weight of montmorillonite (trade name: Kunibond, manufactured by Kunimi Industrial Co., Ltd.), and 65.6 parts by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) Then, about 20 parts by weight of water containing a surfactant (polyoxy-extended ethyltritriphenylphenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Co., Ltd.) was added and kneaded. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 6.
對粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石穗高，豐順公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的70.0重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物7。2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the pesticidal active compound), 1.1 parts by weight of the powdered agrochemical composition 2 (0.75 parts by weight of the agrochemical active compound), pregelatinized starch (trade name: amylox No.) 5.0 parts by weight of 1A, manufactured by Japan Corn Starch Co., Ltd., 10.0 parts by weight of heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Industry Co., Ltd.), montmorillonite (trade name: montmorillonite spike, Fengshun Company) 10.0 parts by weight, and 70.0 parts by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.), containing a surfactant (polyoxyethylidene styrenephenyl) Ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Co., Ltd.), about 10 parts by weight of water, and kneaded. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 7.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石穗高，豐順公司製)的20.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的55.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物8。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, 20.0 parts by weight of montmorillonite (trade name: montmorillonite spike, manufactured by Fengshun Co., Ltd.), and 55.6 parts of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylidene styrylphenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added. Mixed. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 8.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的0.7重量份(農藥活性化合物0.50重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石穗高，豐順公司製)的20.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的56.0重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物9。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 0.7 parts by weight (0.50 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, 20.0 parts by weight of montmorillonite (trade name: montmorillonite spike, manufactured by Fengshun Co., Ltd.), and 56.0 parts of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylidene styrylphenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added. Mixed. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a pesticide granule. Composition 9.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的0.7重量份(農藥活性化合物0.50重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，蒙脫石(商品名：蒙脫石穗高，豐順公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的66.0重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得農藥顆粒狀組成物10。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 0.7 parts by weight (0.50 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, 10.0 parts by weight of montmorillonite (trade name: montmorillonite spike, manufactured by Fengshun Co., Ltd.), and 66.0 parts of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.) To a mixture of parts by weight, about 10 parts by weight of water containing 1.0 part by weight of a surfactant (polyoxyethylidene styrylphenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added. Mixed. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain a granular composition of the pesticide. Matter 10.
對含有農藥之熱硬化性樹脂微粉末1的4.4重量份(農藥活性化合物1.5重量份)，粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的75.6重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得對照農藥顆粒狀組成物1。4.4 parts by weight of the thermosetting resin fine powder 1 containing a pesticide (1.5 parts by weight of the agrochemical compound), 2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the agrochemical compound), and the powdered pesticide composition 2 1.1 parts by weight (0.75 parts by weight of agrochemical active compound), 5.0 parts by weight of pregelatinized starch (trade name: amylox No. 1A, manufactured by Japan Corn Starch Co., Ltd.), heavy calcium carbonate (SS#80, Nitto Powder Chemical Industry Co., Ltd.) 10.0 parts by weight, and 75.6 parts by weight of a mixture of wax stone (trade name: Shengguangshan clay S, manufactured by Shengguangshan Mining Co., Ltd.), containing a surfactant (polyoxyethylidene styrenephenyl) Ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Co., Ltd.), about 10 parts by weight of water, and kneaded. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain comparative pesticide granules. Composition 1.
對粉狀農藥組成物1的2.9重量份(農藥活性化合物2.0重量份)，粉狀農藥組成物2的1.1重量份(農藥活性化合物0.75重量份)，預糊化澱粉(商品名：amylox No. 1A，日本玉米澱粉公司製)的5.0重量份，重質碳酸鈣(SS#80，日東粉化工業公司製)的10.0重量份，及蠟石(商品名：勝光山黏土S，勝光山鑛業公司製)的80.0重量份的混合物中，加入含有界面活性劑(聚氧伸乙基三苯乙烯基苯基醚，Sorpol T-20(註冊商標)，東邦化學工業製)1.0重量份的水約20重量份，而混練。所得混練物的約1.5kg投入於附有0.9mmφ篩網的籃型擠出造粒機(HU-G型畑式造粒機，畑製作所製)，先將該造粒機運轉10秒鐘。除掉在10秒鐘內得到的造粒物後，再開動該造粒機，收取在30秒鐘內所得的造粒物，將該造粒物在70℃乾燥30分鐘，而得對照農藥顆粒狀組成物2。2.9 parts by weight of the powdered agrochemical composition 1 (2.0 parts by weight of the pesticidal active compound), 1.1 parts by weight of the powdered agrochemical composition 2 (0.75 parts by weight of the agrochemical active compound), pregelatinized starch (trade name: amylox No.) 5.0 parts by weight of 1A, manufactured by Japan Corn Starch Co., Ltd., 10.0 parts by weight of heavy calcium carbonate (SS#80, manufactured by Nitto Powder Chemical Industry Co., Ltd.), and wax stone (trade name: Shengguangshan clay S, Shengguangshan Mining Company) To a mixture of 80.0 parts by weight of a solution, 1.0 part by weight of water containing a surfactant (polyoxy-extended ethyltriphenylstyrene phenyl ether, Sorpol T-20 (registered trademark), manufactured by Toho Chemical Industry Co., Ltd.) was added to about 20 parts by weight. Parts by weight, while mixing. About 1.5 kg of the obtained kneaded material was placed in a basket type extrusion granulator (HU-G type granulator, manufactured by Konica Minolta Co., Ltd.) equipped with a 0.9 mmφ sieve, and the granulator was operated for 10 seconds. After removing the granules obtained in 10 seconds, the granulator was started, and the granules obtained in 30 seconds were collected, and the granules were dried at 70 ° C for 30 minutes to obtain comparative pesticide granules. Composition 2.
在水稻育苗箱(30cm×60cm)的播種前覆土前將供試顆粒狀組成物以100g/育苗箱的比率處理，將濕稻穀(品種：日光)播種160g。在育苗器(全日30℃)發芽3日後，移動於屋外而育苗，在播種1週後測量水稱(處理區)的草高。另一方面，測定除了不以顆粒狀組成物處理外，與前述同樣方式進行播種及育曲的水稻(無處理區)的草高(二重複)。將處理區與無處理區的草高以下述式(A)做對比而算出生育率(%)，以下述判定基準評估生育狀況。將其結果示於第1表。The test granular composition was treated at a ratio of 100 g/the seedling box before the soiling of the rice seedling box (30 cm × 60 cm), and the wet rice (variety: daylight) was sown 160 g. After germination for 3 days in the seedling apparatus (30 ° C throughout the day), the plants were moved outside the house to raise seedlings, and the grass height of the water scale (treatment area) was measured 1 week after sowing. On the other hand, the grass height (two repetitions) of rice (no treatment zone) which was sown and sown in the same manner as described above was measured except that it was not treated with the particulate composition. The fertility rate (%) was calculated by comparing the grass height of the treatment zone and the non-treatment zone with the following formula (A), and the growth condition was evaluated by the following criteria. The results are shown in the first table.
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|---|---|---|---|---|
| JP2007001960A (en) * | 2005-06-27 | 2007-01-11 | Sumitomo Chemical Takeda Agro Co Ltd | Insecticide composition |
| WO2009074236A1 (en) * | 2007-12-11 | 2009-06-18 | Bayer Cropscience Ag | Active compound combinations |
| TW201008488A (en) * | 2008-05-16 | 2010-03-01 | Sumitomo Chemical Co | Granulated agrichemical |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201208566A (en) | 2012-03-01 |
| KR20120004334A (en) | 2012-01-12 |
| JP2012017271A (en) | 2012-01-26 |
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