TWI545187B - Liquid detergent compositions for food processing equipment and / or conditioning equipment - Google Patents
Liquid detergent compositions for food processing equipment and / or conditioning equipment Download PDFInfo
- Publication number
- TWI545187B TWI545187B TW100142444A TW100142444A TWI545187B TW I545187 B TWI545187 B TW I545187B TW 100142444 A TW100142444 A TW 100142444A TW 100142444 A TW100142444 A TW 100142444A TW I545187 B TWI545187 B TW I545187B
- Authority
- TW
- Taiwan
- Prior art keywords
- component
- food processing
- mass
- content
- liquid detergent
- Prior art date
Links
- 235000013305 food Nutrition 0.000 title claims description 132
- 230000003750 conditioning effect Effects 0.000 title claims description 129
- 239000000203 mixture Substances 0.000 title claims description 119
- 239000007788 liquid Substances 0.000 title claims description 105
- 239000003599 detergent Substances 0.000 title claims description 97
- 239000006260 foam Substances 0.000 claims description 109
- 238000004140 cleaning Methods 0.000 claims description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
- 239000004094 surface-active agent Substances 0.000 claims description 45
- 125000004432 carbon atom Chemical group C* 0.000 claims description 41
- 150000001412 amines Chemical class 0.000 claims description 38
- -1 halogen acids Chemical class 0.000 claims description 33
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 32
- 239000000194 fatty acid Substances 0.000 claims description 32
- 229930195729 fatty acid Natural products 0.000 claims description 32
- 150000003839 salts Chemical class 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 29
- 230000001590 oxidative effect Effects 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 27
- 150000004665 fatty acids Chemical class 0.000 claims description 25
- 238000010790 dilution Methods 0.000 claims description 23
- 239000012895 dilution Substances 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 22
- 229910052736 halogen Inorganic materials 0.000 claims description 21
- 239000012459 cleaning agent Substances 0.000 claims description 15
- 150000002367 halogens Chemical class 0.000 claims description 15
- 238000005507 spraying Methods 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 14
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000007865 diluting Methods 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000005639 Lauric acid Substances 0.000 claims description 6
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 4
- RSVIRMFSJVHWJV-UHFFFAOYSA-N n,n-dimethyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)(C)[O-] RSVIRMFSJVHWJV-UHFFFAOYSA-N 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 5
- 238000005187 foaming Methods 0.000 description 50
- 239000000243 solution Substances 0.000 description 28
- 150000002430 hydrocarbons Chemical group 0.000 description 24
- 238000012360 testing method Methods 0.000 description 24
- 125000000217 alkyl group Chemical group 0.000 description 22
- 229910052783 alkali metal Inorganic materials 0.000 description 21
- 238000011010 flushing procedure Methods 0.000 description 21
- 125000003342 alkenyl group Chemical group 0.000 description 12
- 159000000000 sodium salts Chemical group 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 8
- 150000004820 halides Chemical class 0.000 description 7
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 239000005708 Sodium hypochlorite Substances 0.000 description 5
- 229940077239 chlorous acid Drugs 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical compound BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 239000001509 sodium citrate Substances 0.000 description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000001508 potassium citrate Substances 0.000 description 3
- 229960002635 potassium citrate Drugs 0.000 description 3
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 3
- 235000011082 potassium citrates Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 2
- 229960002218 sodium chlorite Drugs 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- ZRKZFNZPJKEWPC-UHFFFAOYSA-N decylamine-N,N-dimethyl-N-oxide Chemical group CCCCCCCCCC[N+](C)(C)[O-] ZRKZFNZPJKEWPC-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 1
- 229950010007 dimantine Drugs 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 description 1
- UTTVXKGNTWZECK-UHFFFAOYSA-N n,n-dimethyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)[O-] UTTVXKGNTWZECK-UHFFFAOYSA-N 0.000 description 1
- UQKAOOAFEFCDGT-UHFFFAOYSA-N n,n-dimethyloctan-1-amine Chemical compound CCCCCCCCN(C)C UQKAOOAFEFCDGT-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229940099373 sudan iii Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Description
本發明係關於一種食品加工設備及/或調理設備用液體清潔劑組合物。The present invention relates to a liquid detergent composition for food processing equipment and/or conditioning equipment.
食品加工工廠中會於生產計劃中斷時定期地對加工及/或調理食品所使用之機器及設備進行清潔，而確保衛生狀態。成為清潔對象之機器例如可列舉網帶輸送機或冷凍機、切片機、精米機等，設備例如可列舉地板、牆壁、作業台等。由於該等清潔對象之規模較大，或零件相互交錯而較為複雜，故而作為高效率地清潔該等之方法，通常係採用使清潔劑發泡而成為泡沫狀後應用於清潔對象之發泡清潔。In the food processing plant, the machines and equipment used for processing and/or conditioning the food are regularly cleaned during the interruption of the production plan to ensure hygiene. Examples of the apparatus to be cleaned include a mesh belt conveyor, a refrigerator, a slicer, and a rice mill. Examples of the equipment include a floor, a wall, a work table, and the like. Since the size of the cleaning objects is large, or the parts are interlaced and complicated, the method of cleaning the cleaning materials is usually a foam cleaning method in which the cleaning agent is foamed and then applied to the cleaning object. .
發泡清潔可列舉以下情形：將用水使清潔劑組合物稀釋2~200倍而成之稀釋液投入至噴射裝置中，使利用水壓力或空氣壓力而起泡之泡沫噴射、附著至作為清潔對象之機器或設備上，保持一定時間後，使用刷子或海綿摩擦，或不摩擦而用水沖洗，藉此進行清潔、殺菌之情形；或將清潔劑組合物直接以原液投入至噴射裝置中，利用水壓力而與水混合、起泡後噴射、附著至清潔對象上之情形。於如此之發泡清潔中，藉由以泡沫狀塗佈清潔劑，清潔劑於清潔對象上之滯留時間變長，清潔、殺菌效果提昇。又，在利用泡沫之接觸清潔中，由於可藉由目視確認清潔劑之散佈狀況，故而具有可容易地辨別處理部位，可抑制清潔劑不必要之飛散之優點。The foaming cleaning can be exemplified by the fact that a diluent obtained by diluting the detergent composition by water 2 to 200 times with water is put into the spraying device, and the foam which is foamed by water pressure or air pressure is sprayed and adhered to the object to be cleaned. On the machine or equipment, after a certain period of time, rubbing with a brush or sponge, or rinsing with water without rubbing, thereby cleaning or sterilizing; or putting the detergent composition directly into the spraying device with the original liquid, using water The condition of mixing with water, spraying after foaming, and adhering to a clean object. In such foaming cleaning, by applying the cleaning agent in a foam form, the residence time of the cleaning agent on the cleaning object becomes long, and the cleaning and sterilization effect is improved. Further, in the contact cleaning using the foam, since the dispersion state of the cleaning agent can be visually confirmed, the treatment portion can be easily distinguished, and the advantage that the cleaning agent is unnecessary to be scattered can be suppressed.
作為藉由發泡清潔而清潔加工及/或調理食品所使用之機器及設備(即，食品加工設備及/或調理設備)時之清潔劑組合物，於日本專利特開2007-002014中揭示有含有矽酸鹼金屬鹽、有機膦酸鹽及高發泡性界面活性劑之水性液體清潔劑組合物。A detergent composition as a machine and a device (ie, a food processing device and/or a conditioning device) used for cleaning and/or conditioning a food by foam cleaning, disclosed in Japanese Patent Laid-Open No. 2007-002014 An aqueous liquid detergent composition comprising an alkali metal citrate, an organic phosphonate, and a high foaming surfactant.
又，作為呈現清潔、殺菌效果之清潔劑，於日本專利特開2010-150319、日本專利特表平9-502747、日本專利特表平9-500680、日本專利特開2008-214545、日本專利特表2008-539301中揭示有含有次氯酸鹽之清潔劑。Further, as a cleaning agent which exhibits a cleaning and sterilizing effect, Japanese Patent Laid-Open No. 2010-150319, Japanese Patent Laid-Open No. Hei 9-502747, Japanese Patent Laid-Open No. Hei 9-500680, Japanese Patent Laid-Open No. 2008-214545, Japanese Patent No. A detergent containing hypochlorite is disclosed in Table 2008-539301.
又，於日本專利特表2008-530320(WO-A 2006/087099)中揭示有含有次氯酸鹽、四級銨鹽、氧化胺界面活性劑及脂肪酸之組合物。Further, a composition containing hypochlorite, a quaternary ammonium salt, an amine oxide surfactant, and a fatty acid is disclosed in Japanese Patent Laid-Open Publication No. 2008-530320 (WO-A 2006/087099).
本發明係關於一種食品加工設備及/或調理設備用液體清潔劑組合物，其含有：The present invention relates to a liquid detergent composition for food processing equipment and/or conditioning equipment comprising:
(a) 選自氧化性鹵酸及其等之鹽中之一種以上之化合物[以下稱為(a)成分]0.5~10質量%(其中，含有氧化性鹵酸鹽之情形時係指作為氧化性鹵酸之換算量)、(a) 0.5 to 10% by mass of a compound selected from the group consisting of oxidizing halogen acids and salts thereof (hereinafter referred to as component (a)) (wherein, in the case of containing an oxidizing halide, it means oxidation) Conversion amount of halogen acid),
(b) 具有1個碳數為8~14之烴基之氧化胺型界面活性劑[以下稱為(b)成分]0.5~18質量%、(b) an amine oxide type surfactant having a hydrocarbon group of 8 to 14 carbon atoms (hereinafter referred to as component (b)) is 0.5 to 18% by mass,
(c) 選自碳數為12~16之脂肪酸及其等之鹽中之一種以上之化合物[以下稱為(c)成分]0.5~10質量%(其中，含有脂肪酸鹽之情形時係指作為脂肪酸之換算量)、及(c) a compound selected from one or more of the above-mentioned fatty acids having a carbon number of 12 to 16 and a salt thereof (hereinafter referred to as component (c)) is 0.5 to 10% by mass (wherein, in the case where a fatty acid salt is contained, it means The amount of fatty acid converted), and
(d) 水[以下稱為(d)成分]；並且(d) water [hereinafter referred to as component (d)]; and
(b) 成分/(c)成分之質量比為1/10~10/1，且(b) The mass ratio of the component / (c) component is 1/10 to 10/1, and
(b) 成分與(c)成分之合計含量為4~20質量%。The total content of the component (b) and the component (c) is 4 to 20% by mass.
本發明係關於一種食品加工設備及/或調理設備之清潔方法，其係使用上述本發明之食品加工設備及/或調理設備用液體清潔劑組合物，包含下述步驟1~3。The present invention relates to a method of cleaning a food processing device and/or a conditioning device, which comprises the above-described food processing device and/or liquid detergent composition for conditioning device of the present invention, comprising the following steps 1 to 3.
步驟1：將食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍之稀釋倍率預先稀釋，及/或一面稀釋，一面以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟；Step 1: The liquid detergent composition for food processing equipment and/or conditioning equipment is pre-diluted by water at a dilution ratio of 2 to 200 times, and/or diluted while being sprayed in a foam form to adhere to food processing. Steps on the device and/or conditioning device;
步驟2：將泡沫保持一定時間之步驟；Step 2: The step of keeping the foam for a certain period of time;
步驟3：用水沖洗食品加工設備及/或調理設備之步驟。Step 3: The steps of rinsing the food processing equipment and/or conditioning equipment with water.
又，本發明係關於一種食品加工設備及/或調理設備之清潔方法，其於將清潔液以泡沫狀噴射，使其附著於食品加工設備及/或調理設備上之步驟後，具有用水沖洗之步驟，上述清潔液含有(a)成分0.0025~2質量%、(b)成分0.0025~3.6質量%、(c)成分0.0025~2質量%及(d)成分，並且(b)成分/(c)成分之質量比為1/10~10/1，(b)成分與(c)成分之合計含量為0.02~4質量%，且(a)成分/[(b)成分+(c)成分]的質量比為1/10~2.5/1。Moreover, the present invention relates to a method of cleaning a food processing device and/or a conditioning device, which has a step of spraying the cleaning solution in a foam form to adhere to the food processing device and/or the conditioning device, and then rinsing with water. In the step, the cleaning liquid contains (a) a component of 0.0025 to 2 mass%, (b) a component of 0.0025 to 3.6 mass%, (c) a component of 0.0025 to 2 mass%, and a component (d), and (b) a component/(c). The mass ratio of the components is 1/10 to 10/1, and the total content of the component (b) and the component (c) is 0.02 to 4 mass%, and the component (a)/[(b) component + (c) component] The mass ratio is 1/10~2.5/1.
清潔食品加工設備及/或調理設備所使用之清潔劑組合物除清潔、殺菌之性能以外，就對上述發泡清潔之適應性而言，要求其起泡性(起泡容易度)、或接觸之泡沫之穩定性優異。先前之食品加工設備及/或調理設備用液體清潔劑組合物係主要著眼於起泡性或泡沫穩定性而進行開發，以日本專利特開2007-002014所記載之技術為代表，以往之食品加工設備及/或調理設備用液體清潔劑組合物大多實現了充分之起泡性或泡沫穩定性。另一方面，該等先前之食品加工設備及/或調理設備用液體清潔劑組合物於沖洗時泡沫難以沖洗乾淨而必需使用大量之沖洗水進行沖洗，於經濟性方面不利，並且作業負荷變大(耗費作業時間)，且於環境負荷方面亦不利。然而，清潔時之起泡性/泡沫穩定性與沖洗時之泡沫沖淨性存在取捨關係，要同時滿足兩性能非常困難。The cleaning agent composition used in the cleaning food processing equipment and/or conditioning equipment requires, in addition to the cleaning and sterilizing properties, the foaming property (foaming ease) or contact for the above foaming cleaning suitability. The foam has excellent stability. The previous liquid detergent composition for food processing equipment and/or conditioning equipment was developed mainly focusing on foaming property or foam stability, and represented by the technology described in Japanese Patent Laid-Open No. 2007-002014, and the prior food processing. Most of the liquid detergent compositions for equipment and/or conditioning equipment achieve sufficient foaming or foam stability. On the other hand, the prior liquid processing compositions for food processing equipment and/or conditioning equipment are difficult to rinse when flushing, and it is necessary to use a large amount of flushing water for rinsing, which is economically disadvantageous and the working load is increased. (It takes time) and is also unfavorable in terms of environmental load. However, there is a trade-off between foaming/foam stability during cleaning and foam flushing during rinsing, and it is very difficult to satisfy both properties at the same time.
另一方面，作為呈現清潔、殺菌效果之清潔劑，於日本專利特開2010-150319、日本專利特表平9-502747、日本專利特表平9-500680中，揭示有併用次氯酸鹼金屬鹽、氧化胺型界面活性劑及脂肪酸鹼金屬鹽之技術，但日本專利特開2010-150319為排水管用液體清潔劑之技術，日本專利特表平9-502747為次氯酸鹽基底之濃縮水性漂白清潔劑之技術，另外，日本專利特表平9-500680為含有短鏈界面活性劑之濃縮水性漂白清潔劑之技術，任一者均未提示食品加工設備及/或調理設備用清潔劑中之課題及其解決方法。況且，根據該等日本專利特開2010-150319、日本專利特表平9-502747、日本專利特表平9-500680之記載內容，並不能想到藉由以特定之比率/特定之含量使用氧化胺型界面活性劑與脂肪酸鹼金屬鹽，可實現能夠同時滿足發泡清潔時之起泡性/泡沫穩定性與沖洗時之泡沫沖淨性兩性能的食品加工設備及/或調理設備用清潔劑。On the other hand, as a cleaning agent which exhibits a cleaning and sterilizing effect, an alkali metal hypochlorite is disclosed in Japanese Patent Laid-Open No. 2010-150319, Japanese Patent Laid-Open No. Hei 9-502747, and Japanese Patent Laid-Open No. Hei 9-500680. Salt, amine oxide type surfactant and fatty acid alkali metal salt technology, but Japanese Patent Laid-Open No. 2010-150319 is a liquid cleaning agent for drain pipes, and Japanese Patent Special Publication No. 9-502747 is a concentration of hypochlorite substrate. Aqueous bleach cleaner technology, in addition, Japanese Patent Special Table 9-500680 is a concentrated aqueous bleach cleaner containing short-chain surfactant, neither of which suggests food processing equipment and / or conditioning equipment cleaner The topic and its solution. In addition, according to the contents described in Japanese Patent Laid-Open No. 2010-150319, Japanese Patent Laid-Open No. Hei 9-502747, and Japanese Patent Laid-Open No. Hei 9-500680, it is not conceivable to use an amine oxide at a specific ratio/specific content. The type of surfactant and the alkali metal salt of the fatty acid can realize the food processing equipment and/or the cleaning agent for the conditioning equipment capable of satisfying both the foaming/foam stability during foam cleaning and the foam flushing property during washing. .
如上所述，就對發泡清潔之適應性而言，清潔食品加工設備及/或調理設備所使用之清潔劑組合物要求使起泡性/泡沫穩定性與沖洗時之泡沫沖淨性並存。因此，較佳為預先於調配組合物中以對於滿足起泡性/泡沫穩定性而言充分之濃度調配界面活性劑，並且必需調配沖洗性較高之界面活性劑作為界面活性劑。作為沖洗性較高之界面活性劑，已知有肥皂，但肥皂之烷基鏈之鏈長之選擇非常重要，若烷基鏈較短，則稀釋使用時沖洗性降低，又，若烷基鏈較長，則調配液之黏度變高，甚至於低溫下固化，或即便常溫下亦固化，導致調配變得困難。因此，高濃度地調配界面活性劑且於低溫下亦可維持溶液穩定性，並且將稀釋使用時之起泡性/泡沫穩定性、進而沖洗性全部滿足之調配非常難以實現。As noted above, in terms of adaptability to foam cleaning, detergent compositions used in cleaning food processing equipment and/or conditioning equipment require foaming/foam stability to coexist with foam flushing upon rinsing. Therefore, it is preferred to prepare the surfactant in a concentration sufficient for satisfying the foaming/foam stability in advance in the compounding composition, and it is necessary to formulate a surfactant having a high rinsing property as a surfactant. As a surfactant having a high rinsing property, soap is known, but the choice of the chain length of the alkyl chain of the soap is very important. If the alkyl chain is short, the rinsing property is lowered when diluted, and if the alkyl chain is When the length is longer, the viscosity of the formulation liquid becomes higher, even at a low temperature, or even at a normal temperature, which makes the formulation difficult. Therefore, it is very difficult to achieve a high concentration of the surfactant and maintain the stability of the solution at a low temperature, and the formulation of the foaming/foam stability and the rinsing property at the time of dilution use is extremely difficult to achieve.
日本專利特開2008-214545中揭示有含有次氯酸鈉/肥皂/氧化胺之液體清潔劑組合物，但液體組合物中之肥皂或氧化胺之調配濃度較低，若將該液體組合物直接以原液使用於產品中，則必需大量使用，運輸成本變得過大。就該方面而言，亦要求於清潔食品加工設備及/或調理設備所使用之清潔劑組合物中高濃度地調配界面活性劑。A liquid detergent composition containing sodium hypochlorite/soap/amine oxide is disclosed in Japanese Patent Laid-Open No. 2008-214545, but the concentration of soap or amine oxide in the liquid composition is low, and if the liquid composition is directly used as a stock solution, In the product, it must be used in large quantities, and the transportation cost becomes too large. In this regard, it is also desirable to formulate the surfactant at a high concentration in the detergent composition used in the cleaning food processing equipment and/or conditioning equipment.
日本專利特表2008-539301中揭示有含有氧化化合物、鹼金屬皂、三烷基氧化胺、緩衝液及電解質之組合物，但其係關於容易注入且流過全自動型洗衣機之分送器(dispenser)之濃漂白劑，並不能想到可實現食品加工設備及/或調理設備用清潔劑。又，日本專利特表2008-539301之組合物即便稀釋欲使其發泡，起泡狀況亦較差，不適合用於發泡清潔。A composition containing an oxidizing compound, an alkali metal soap, a trialkylamine oxide, a buffer, and an electrolyte is disclosed in Japanese Patent Laid-Open Publication No. 2008-539301, but it is related to a dispenser which is easy to inject and flows through a fully automatic washing machine ( The concentrated bleach of dispensers, and it is not conceivable that detergents for food processing equipment and/or conditioning equipment can be realized. Further, the composition of Japanese Patent Laid-Open Publication No. 2008-539301 is inferior in foaming condition even if it is intended to be foamed, and is not suitable for use in foam cleaning.
本發明提供一種於稀釋而用於發泡清潔時呈現優異之起泡性/泡沫穩定性，並且於沖洗時呈現優異之泡沫沖淨性的界面活性劑濃度較高之食品加工設備及/或調理設備用液體清潔劑組合物。The present invention provides a food processing apparatus and/or conditioning having a high concentration of a surfactant which exhibits excellent foaming/foam stability when used for foam cleaning and exhibits excellent foam flushing upon rinsing. Liquid detergent composition for equipment.
又，本發明提供一種於低溫下溶液穩定性亦優異，且於稀釋而用於發泡清潔時呈現優異之起泡性/泡沫穩定性，並且於沖洗時呈現優異之泡沫沖淨性的界面活性劑濃度較高之食品加工設備及/或調理設備用液體清潔劑組合物。Further, the present invention provides an interface activity which is excellent in stability at a low temperature, exhibits excellent foaming/foam stability upon use in foaming cleaning, and exhibits excellent foam flushing upon rinsing. A liquid detergent composition for food processing equipment and/or conditioning equipment having a high concentration of the agent.
本案申請人對上述課題進行努力研究，結果發現，藉由於含有氧化性鹵酸(或其鹽)之系統中，以特定之比率/特定之含量使用氧化胺型界面活性劑與脂肪酸(或其鹽)，可實現同時滿足稀釋而用於發泡清潔時之起泡性/泡沫穩定性與沖洗時之泡沫沖淨性兩性能的食品加工設備及/或調理設備用清潔劑，從而完成本發明。The applicant of the present invention conducted an effort to study the above-mentioned subject, and as a result, found that an amine oxide type surfactant and a fatty acid (or a salt thereof) are used in a specific ratio/specific content in a system containing an oxidizing halogen acid (or a salt thereof). The present invention can be accomplished by a food processing apparatus and/or a cleaning agent for conditioning equipment which simultaneously satisfy the foaming/foam stability at the time of foaming cleaning and the foaming property at the time of rinsing.
根據本發明，可提供一種於稀釋而用於發泡清潔時呈現優異之起泡性/泡沫穩定性，並且於沖洗時呈現優異之泡沫沖淨性的界面活性劑濃度較高之食品加工設備及/或調理設備用液體清潔劑組合物。According to the present invention, it is possible to provide a food processing apparatus having a high concentration of a surfactant which exhibits excellent foaming/foam stability when used for foaming cleaning and which exhibits excellent foam flushing upon rinsing and / or liquid detergent composition for conditioning equipment.
又，根據本發明，可提供一種於低溫下溶液穩定性亦優異，且於稀釋而用於發泡清潔時呈現優異之起泡性/泡沫穩定性，並且於沖洗時呈現優異之泡沫沖淨性的界面活性劑濃度較高之食品加工設備及/或調理設備用液體清潔劑組合物。本發明之組合物之黏度較低。Further, according to the present invention, it is possible to provide an excellent solution stability at a low temperature and excellent foaming/foam stability when used for foam cleaning after dilution, and excellent foam flushing property upon rinsing. A liquid detergent composition for food processing equipment and/or conditioning equipment having a high concentration of surfactant. The composition of the invention has a low viscosity.
對本發明之構成進行詳細說明之前，請注意以下用語之含義。即，於本發明中，用語「食品加工設備及/或調理設備」意指食品加工工廠中對食品進行加工時及/或調理時所使用之機器及設備。作為該機器，例如可列舉網帶輸送機或冷凍機、切片機、精米機等。又，作為該設備，例如可列舉地板、牆壁、作業台等。Before describing the configuration of the present invention in detail, please pay attention to the meaning of the following terms. That is, in the present invention, the term "food processing equipment and/or conditioning equipment" means the machine and equipment used in the processing of food and/or conditioning in a food processing factory. As such a machine, a mesh belt conveyor, a refrigerator, a slicer, a rice mill, etc. are mentioned, for example. Moreover, examples of the device include a floor, a wall, a work table, and the like.
於本發明中，用語「食品加工設備及/或調理設備用液體清潔劑組合物」意指用於清潔上述「食品加工設備及/或調理設備」之液體清潔劑組合物，更詳細而言，意指用以藉由發泡清潔而清潔上述「食品加工設備及/或調理設備」之液體清潔劑組合物。此處，請注意本發明之「食品加工設備及/或調理設備用液體清潔劑組合物」並不包括排水管用清潔劑組合物。其原因在於，由於本發明之「食品加工設備及/或調理設備用液體清潔劑組合物」藉由發泡而泡沫滯留於配管內，會對沖洗時產生影響，故而不適於排水管用清潔劑組合物(發泡清潔用清潔劑組合物不適於作為排水管用清潔劑之事項亦可參照上述特開2010-150319之段落0004)。In the present invention, the phrase "liquid detergent composition for food processing equipment and/or conditioning equipment" means a liquid detergent composition for cleaning the above-mentioned "food processing equipment and/or conditioning equipment", and more specifically, It means a liquid detergent composition for cleaning the above-mentioned "food processing equipment and/or conditioning equipment" by foam cleaning. Here, please note that the "liquid detergent composition for food processing equipment and/or conditioning equipment" of the present invention does not include a detergent composition for a drain pipe. The reason for this is that the "liquid detergent composition for food processing equipment and/or conditioning equipment" of the present invention is retained in the piping by foaming, which has an effect on the rinsing, and is therefore not suitable for a cleaning agent combination for a drain pipe. The matter (the foam cleaning detergent composition is not suitable as a drain cleaner) can also be referred to paragraph 0004 of the above-mentioned JP-A-2010-150319.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物含有下述(a)成分~(d)成分。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention contains the following components (a) to (d).
(a) 成分為選自氧化性鹵酸及其等之鹽中之一種以上之化合物。作為氧化性鹵酸，可列舉次氯酸、次溴酸、亞氯酸，就殺菌性之觀點而言，較佳為次氯酸。又，作為氧化性鹵酸之鹽，可列舉次氯酸、次溴酸、亞氯酸之鹼金屬鹽。更佳為鈉鹽。就殺菌性及通用性之方面而言，較佳為次氯酸之鹼金屬鹽，其中較佳為次氯酸鈉。(a) The component is one or more compounds selected from the group consisting of oxidizing halogen acids and salts thereof. Examples of the oxidizing halogen acid include hypochlorous acid, hypobromous acid, and chlorous acid. From the viewpoint of bactericidal properties, hypochlorous acid is preferred. Further, examples of the salt of the oxidizing halogen acid include alkali metal salts of hypochlorous acid, hypobromous acid, and chlorous acid. More preferably, it is a sodium salt. In terms of bactericidal properties and versatility, an alkali metal salt of hypochlorous acid is preferred, and among them, sodium hypochlorite is preferred.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物中的(a)成分之含量若為0.5質量%以上，則可獲得充分之殺菌效果，又，就使用感之觀點而言，較佳為10質量%以下。就獲得充分之殺菌效果與良好之使用感之觀點而言，(a)成分之含量為0.5~10質量%，較佳為1.5~8質量%，更佳為2~5質量%。此處，於(a)成分中含有氧化性鹵酸鹽之情形時，上述含量係使用作為氧化性鹵酸之換算量的值。When the content of the component (a) in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is 0.5% by mass or more, a sufficient bactericidal effect can be obtained, and from the viewpoint of the feeling of use, It is preferably 10% by mass or less. The content of the component (a) is from 0.5 to 10% by mass, preferably from 1.5 to 8% by mass, and more preferably from 2 to 5% by mass, from the viewpoint of obtaining a sufficient bactericidal effect and a good feeling of use. Here, in the case where the oxidizing halide is contained in the component (a), the above content is a value which is a converted amount of the oxidizing halogen acid.
(b) 成分為具有1個碳數為8~14之烴基之氧化胺型界面活性劑。作為分子中所含之碳數為8~14之烴基，可列舉烷基或烯基，其等可為直鏈，亦可為支鏈，但為有助於調配溶液之低溫穩定性及沖洗時之泡沫沖淨性，較佳為碳數為8~12之烷基。(b) The component is an amine oxide type surfactant having one hydrocarbon group having 8 to 14 carbon atoms. Examples of the hydrocarbon group having 8 to 14 carbon atoms contained in the molecule include an alkyl group or an alkenyl group, and the like may be a straight chain or a branched chain, but may contribute to low-temperature stability of the solution and rinse time. The foam flushing property is preferably an alkyl group having a carbon number of 8 to 12.
(b) 成分例如為具有1個碳數為8~14之烴基、及2個碳數為1~6之烷基或碳數為1~3之羥基烷基的氧化胺型界面活性劑。作為氧化胺型界面活性劑，較佳為下述通式(1)所表示之化合物。The component (b) is, for example, an amine oxide type surfactant having one hydrocarbon group having 8 to 14 carbon atoms and two alkyl groups having 1 to 6 carbon atoms or hydroxyalkyl groups having 1 to 3 carbon atoms. The amine oxide type surfactant is preferably a compound represented by the following formula (1).
[化1][Chemical 1]
(式中，R1為碳數為8~14之烴基，R2為碳數為1~3之伸烷基，R3、R4獨立地為碳數為1~3之烷基或羥基烷基，X為選自-COO-、-OCO-、-NHCO-、-CONH-、-O-中之基，m為0或1之數)(wherein R 1 is a hydrocarbon group having a carbon number of 8 to 14, R 2 is an alkylene group having a carbon number of 1 to 3, and R 3 and R 4 are independently an alkyl group having 1 to 3 carbon atoms or a hydroxyalkane. Base, X is a group selected from -COO-, -OCO-, -NHCO-, -CONH-, -O-, m is 0 or 1)
於上述通式(1)中，R1較佳為碳數為8~14之烷基或烯基，就有助於沖洗時之泡沫沖淨性之觀點而言，更佳為碳數為8~12之烷基或烯基。R1亦可為來源於天然油脂之烷基結構，就使用天然原料之觀點而言，較佳為直鏈。作為較佳之化合物之具體例，可列舉於通式(1)中R1為選自由辛基、壬基、癸基、十一烷基、及十二烷基所組成之群中之1個基，R3、R4均為甲基，m為0之化合物，其中，就有助於沖洗時之泡沫沖淨性之觀點而言，更佳為R1為十二烷基，R3、R4均為甲基，m為0之化合物(即十二烷基二甲基氧化胺)。In the above formula (1), R 1 is preferably an alkyl group or an alkenyl group having a carbon number of 8 to 14 and more preferably has a carbon number of 8 from the viewpoint of foaming cleanability at the time of rinsing. ~12 alkyl or alkenyl. R 1 may also be an alkyl structure derived from natural fats and oils, and is preferably a linear chain from the viewpoint of using a natural raw material. Specific examples of preferred compounds include R 1 in the formula (1), which is a group selected from the group consisting of an octyl group, a decyl group, a decyl group, an undecyl group, and a dodecyl group. , R 3 and R 4 are each a methyl group, and m is a compound of 0. Among them, R 1 is a dodecyl group, and R 3 and R are preferable from the viewpoint of foaming cleanability at the time of rinsing. 4 is a methyl group, and m is a compound of 0 (ie, dodecyldimethylamine oxide).
(b) 成分可單獨使用一種，或適當組合兩種以上而使用。其中，就調配溶液之溶液穩定性以及沖洗時之泡沫沖淨性之觀點而言，較佳為將分子中具有1個碳數為8~12之烷基之氧化胺型界面活性劑單獨使用，或將分子中具有1個碳數為8~12之烷基之氧化胺型界面活性劑組合兩種以上而使用。更佳為將十二烷基二甲基氧化胺與辛基二甲基氧化胺組合而使用。(b) The components may be used singly or in combination of two or more. Among them, from the viewpoint of the stability of the solution of the solution and the foaming property at the time of rinsing, it is preferred to use an amine oxide type surfactant having one alkyl group having 8 to 12 carbon atoms in the molecule. Alternatively, an amine oxide type surfactant having one alkyl group having 8 to 12 carbon atoms in the molecule may be used in combination of two or more. More preferably, it is used in combination with dodecyldimethylamine oxide and octyldimethylamine oxide.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物中的(b)成分之含量若為0.5質量%以上，則可不受污漬之負荷量之影響而獲得充分之起泡性及泡沫穩定性，又，就調配性之觀點而言，較佳為18質量%以下。就實現發泡清潔時之充分之起泡性及泡沫穩定性與良好之調配性的觀點而言，(b)成分之含量為0.5~18質量%，較佳為0.5~15質量%，更佳為2~15質量%，進而較佳為3~10質量%。When the content of the component (b) in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is 0.5% by mass or more, sufficient foaming property and foam can be obtained without being affected by the load of the stain. The stability is preferably 18% by mass or less from the viewpoint of blending properties. The content of the component (b) is from 0.5 to 18% by mass, preferably from 0.5 to 15% by mass, more preferably from the viewpoint of achieving sufficient foaming property and foam stability at the time of foam cleaning and good blending property. It is 2 to 15% by mass, and more preferably 3 to 10% by mass.
就調配溶液(本發明之食品加工設備及/或調理設備用液體清潔劑組合物亦稱為調配溶液。以下相同)之溶液穩定性以及沖洗時之泡沫沖淨性之觀點而言，本發明之食品加工設備及/或調理設備用液體清潔劑組合物較佳為含有：具有1個碳數為8~10之烴基之氧化胺型界面活性劑[以下稱為(b1)成分]、及具有1個碳數為12之烴基之氧化胺型界面活性劑[以下稱為(b2)成分]。於該情形時，(b1)成分之含量相對於(b2)成分之含量的質量比[(b1)成分之含量/(b2)成分之含量的質量比]較佳為0.1~0.95，進而較佳為0.2~0.5。(b1)成分較佳為具有1個碳數為8之烴基之氧化胺型界面活性劑，如上所述，作為(b)成分，較佳為將相當於(b1)成分之辛基二甲基氧化胺與相當於(b2)成分之十二烷基二甲基氧化胺組合使用。The present invention is in view of the solution stability of the solution preparation (the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, also referred to as the formulation solution, the same applies hereinafter) and the foam flushing property upon rinsing The liquid detergent composition for food processing equipment and/or conditioning equipment preferably contains an amine oxide type surfactant (hereinafter referred to as (b1) component) having one hydrocarbon group having 8 to 10 carbon atoms, and has 1 An amine oxide type surfactant (hereinafter referred to as a component (b2)) having a hydrocarbon group of 12 carbon atoms. In this case, the mass ratio of the content of the component (b1) to the content of the component (b2) [mass ratio of the content of the (b1) component to the content of the (b2) component is preferably from 0.1 to 0.95, and further preferably. It is 0.2~0.5. The component (b1) is preferably an amine oxide type surfactant having one hydrocarbon group having 8 carbon atoms. As described above, as the component (b), an octyldimethyl group corresponding to the component (b1) is preferred. The amine oxide is used in combination with dodecyldimethylamine oxide equivalent to the component (b2).
又，就低溫穩定性之觀點而言，較佳為具有1個碳數為14之烴基之氧化胺型界面活性劑之含量為0~0.01質量%。Further, from the viewpoint of low-temperature stability, the content of the amine oxide-type surfactant having one hydrocarbon group having 14 carbon atoms is preferably from 0 to 0.01% by mass.
(c) 成分為選自碳數為12~16之脂肪酸及其等之鹽中之一種以上之化合物。作為較佳之(c)成分之例，可列舉月桂酸、肉豆蔻酸、十五烷酸、棕櫚酸及其等之鹽，其中，為有助於調配溶液之溶液穩定性以及沖洗時之泡沫沖淨性，較佳為月桂酸、肉豆蔻酸及其等之鹽。此處，作為鹽，可列舉鹼金屬鹽，其中較佳為鈉鹽、鉀鹽。(c) The component is one or more compounds selected from the group consisting of a fatty acid having 12 to 16 carbon atoms and salts thereof. Examples of the preferred component (c) include lauric acid, myristic acid, pentadecanoic acid, palmitic acid, and the like, wherein the solution is stable in solution and foaming during rinsing. The net nature is preferably a salt of lauric acid, myristic acid and the like. Here, examples of the salt include an alkali metal salt, and among them, a sodium salt or a potassium salt is preferred.
藉由將本發明之食品加工設備及/或調理設備用液體清潔劑組合物中的(c)成分之含量設為0.5質量%以上，可實現沖洗時之良好之泡沫沖淨性，又，就發泡清潔時之泡沫穩定性之觀點而言，較佳為10質量%以下。就實現發泡清潔時之充分之泡沫穩定性與沖洗時之良好之泡沫沖淨性之方面而言，(c)成分之含量為0.5~10質量%，較佳為1~10質量%，更佳為2.5~8質量%，進而較佳為3~5質量%。此處，於(c)成分中含有脂肪酸鹽之情形時，上述含量係使用作為脂肪酸之換算量的值。By setting the content of the component (c) in the liquid detergent composition of the food processing device and/or the conditioning device of the present invention to 0.5% by mass or more, good foaming property at the time of rinsing can be achieved, and From the viewpoint of foam stability at the time of foam cleaning, it is preferably 10% by mass or less. The content of the component (c) is from 0.5 to 10% by mass, preferably from 1 to 10% by mass, in terms of sufficient foam stability at the time of foaming cleaning and good foaming property at the time of rinsing. Preferably, it is 2.5 to 8 mass%, and more preferably 3 to 5 mass%. Here, in the case where the fatty acid salt is contained in the component (c), the above content is a value which is a converted amount of the fatty acid.
就低溫穩定性之觀點而言，本發明之食品加工設備及/或調理設備用液體清潔劑組合物較佳為含有(b2)成分作為(b)成分，且作為(c)成分之選自碳數為14之脂肪酸及其等之鹽中之一種以上之化合物[以下稱為(c1)成分]之含量相對於(b2)成分之含量的質量比[以下記載為(c1)成分之含量/(b2)成分之含量的質量比]為0~2.5。(c1)成分之含量/(b2)成分之含量的質量比更佳為0~2，進而較佳為0~1.7。The liquid detergent composition for food processing equipment and/or conditioning apparatus of the present invention preferably contains the component (b2) as the component (b) and the component (c) selected from the viewpoint of low-temperature stability. The mass ratio of the content of one or more compounds (hereinafter referred to as (c1) component) of the fatty acid having 14 or more, to the content of the component (b2) (hereinafter referred to as the content of the component (c1) / ( The mass ratio of the content of the component b2) is 0 to 2.5. The mass ratio of the content of the component (c1) / the content of the component (b2) is more preferably 0 to 2, still more preferably 0 to 1.7.
就低溫穩定性之觀點而言，於本發明之食品加工設備及/或調理設備用液體清潔劑組合物中，(b1)成分之含量相對於(b1)成分與(c1)成分之合計含量[(b1)成分之含量+(c1)成分之含量]的質量比[以下記載為(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比]較佳為0.3~1。(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比更佳為0.4~1，進而較佳為0.5~1。From the viewpoint of low-temperature stability, in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, the content of the component (b1) relative to the total content of the components (b1) and (c1) [ The mass ratio of the content of the component (b1) + the content of the component (c1)] (hereinafter referred to as the content of the component (b1) / the mass ratio of the component (the content of the component (b1) + the content of the component (c1)] is preferably 0.3~1. The mass ratio of the component (b1)/the content of the ((b1) component + the content of the component (c1)] is more preferably 0.4 to 1, more preferably 0.5 to 1.
欲發揮本發明所期望之效果時，重要的是將(b)成分與(c)成分之含量比率及其等之合計含量設於特定之範圍內。In order to exert the desired effect of the present invention, it is important to set the content ratio of the component (b) to the component (c) and the total content thereof in a specific range.
即，關於(b)成分與(c)成分之含量比率[記載為(b)成分/(c)成分之質量比，或(b)成分之含量/(c)成分之含量的質量比]，就調配溶液之溶液穩定性以及發泡清潔時之泡沫穩定性之觀點而言，較佳為1/10以上，就沖洗時之泡沫沖淨性之觀點而言，較佳為10/1以下。就可以較高水準實現調配溶液之溶液穩定性、發泡清潔時之泡沫穩定性與沖洗時之泡沫沖淨性之觀點而言，(b)成分/(c)成分之質量比合適的是為1/10~10/1，更佳為1/8~6/1，進而較佳為1/5~5/1。In other words, the content ratio of the component (b) to the component (c) is described as the mass ratio of the component (b) component/(c) component or the mass ratio of the component (b) component to the component (c) component, From the viewpoint of the stability of the solution of the preparation solution and the stability of the foam at the time of foaming and cleaning, it is preferably 1/10 or more, and from the viewpoint of foam flushing at the time of washing, it is preferably 10/1 or less. The mass ratio of the component (b) component/(c) is preferably from the viewpoint of achieving a higher level of solution stability of the formulation solution, foam stability at the time of foam cleaning, and foam flushing at the time of rinsing. 1/10 to 10/1, more preferably 1/8 to 6/1, and further preferably 1/5 to 5/1.
關於(b)成分與(c)成分之合計含量，就本發明之食品加工設備及/或調理設備用液體清潔劑組合物之運輸成本、及於發泡清潔時獲得充分之起泡性之觀點而言，較佳為4質量%以上，就使用時之操作性、及沖洗時之泡沫沖淨性之觀點而言，較佳為20質量%以下。就可以較高水準使發泡清潔時之起泡性與沖洗時之泡沫沖淨性並存之觀點而言，(b)成分與(c)成分之合計含量合適的是為4~20質量%，較佳為5~20質量%，進而較佳為6~15質量%，更佳為7~10質量%。Regarding the total content of the component (b) and the component (c), the transportation cost of the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, and the viewpoint of obtaining sufficient foaming property during foam cleaning The content is preferably 4% by mass or more, and is preferably 20% by mass or less from the viewpoint of workability at the time of use and foaming property at the time of rinsing. The total content of the component (b) and the component (c) is suitably 4 to 20% by mass in view of the fact that the foaming property at the time of foaming cleaning and the foaming property at the time of rinsing can be coexisted at a higher level. It is preferably 5 to 20% by mass, more preferably 6 to 15% by mass, still more preferably 7 to 10% by mass.
(a)成分之含量相對於(b)成分與(c)成分之合計含量[記載為(b)成分+(c)成分，或(b)成分之含量+(c)成分之含量]的比率(即，記載為(a)成分/[(b)成分+(c)成分]的質量比，或(a)成分之含量/[(b)成分之含量+(c)成分之含量]的質量比)會對稀釋溶液之發泡性或泡沫穩定性造成影響因此重要。就將本發明之食品加工設備及/或調理設備用液體清潔劑組合物藉由水(尤其是含有硬度成分之水)以2~200倍(較佳為5~200倍)之倍率稀釋而成之稀釋溶液的起泡性及泡沫穩定性之觀點而言，(a)成分/[(b)成分+(c)成分]的質量比較佳為1/10~2.5/1，進而較佳為1/7~2/1，更佳為1/5~1/1，進而更佳為1/5~7/10。又，就本發明之食品加工設備及/或調理設備用液體清潔劑組合物之低溫穩定性之觀點而言，(a)成分/[(b)成分+(c)成分]的質量比較佳為1/10~1/1，進而較佳為1/7~1/1，更佳為1/5~1/1，進而更適宜為1/5~7/10。Ratio of the content of the component (a) to the total content of the component (b) and the component (c) (described as the component (b) component + (c) component, or the component (b) component + (c) component content] (That is, the mass ratio of (a) component / [(b) component + (c) component], or the mass of (a) component / [(b) component + (c) component] It is important to influence the foaming property or foam stability of the diluted solution. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is diluted by water (especially water containing a hardness component) by a ratio of 2 to 200 times (preferably 5 to 200 times). The mass of the component (a) / [(b) component + (c)] is preferably from 1/10 to 2.5/1, more preferably 1 in terms of foaming property and foam stability of the diluted solution. /7~2/1, more preferably 1/5~1/1, and even more preferably 1/5~7/10. Further, in terms of low-temperature stability of the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, the quality of (a) component / [(b) component + (c) component] is preferably 1/10 to 1/1, further preferably 1/7 to 1/1, more preferably 1/5 to 1/1, and still more preferably 1/5 to 7/10.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物中，就稀釋而用於發泡清潔時呈現優異之起泡性/泡沫穩定性，並且於沖洗時具有優異之泡沫沖淨性，且低溫穩定性亦優異之觀點而言，較佳為(b)成分含有具有1個碳數為8~10之烴基之氧化胺型界面活性劑((b1)成分)、及具有1個碳數為12之烴基之氧化胺型界面活性劑((b2)成分)，作為(b)成分之具有1個碳數為14之烴基之氧化胺型界面活性劑的含量為0~0.01質量%，作為(c)成分之選自碳數為14之脂肪酸及其等之鹽中之一種以上之化合物((c1)成分)之含量、(b1)成分之含量及(b2)成分之含量滿足如下條件(i)及(ii)，且(a)成分/[(b)成分+(c)成分]的質量比為1/10~1/1。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention exhibits excellent foaming/foam stability when used for foam cleaning, and has excellent foam flushing property upon rinsing. In view of the fact that the low-temperature stability is also excellent, the component (b) preferably contains an amine oxide type surfactant (component (b1)) having one hydrocarbon group having 8 to 10 carbon atoms, and has one carbon. The content of the amine oxide type surfactant (the component (b2)) having a hydrocarbon group of 12, and the content of the amine oxide type surfactant having one hydrocarbon group having 14 carbon atoms as the component (b) is 0 to 0.01% by mass. The content of the compound ((c1) component), the content of the (b1) component, and the component (b2) of the component (c) selected from the group consisting of the fatty acid having 14 carbon atoms and the like, and the content of the component (b2) satisfy the following conditions (i) and (ii), and the mass ratio of (a) component / [(b) component + (c) component] is 1/10 to 1/1.
條件(i)：(c1)成分之含量/(b2)成分之含量的質量比為0~2.5。Condition (i): The mass ratio of the content of the (c1) component to the content of the (b2) component is 0 to 2.5.
條件(ii)：(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比為0.3~1。Condition (ii): The mass ratio of the component (b1)/the content of the (b1) component to the component (c1) component is 0.3 to 1.
於本發明之食品加工設備及/或調理設備用液體清潔劑組合物中，可將上述(a)成分~(c)成分以外之剩餘部分設為水[即(d)成分]。水較佳可使用不含硬度成分之離子交換水。In the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, the remainder other than the components (a) to (c) above may be referred to as water [i.e., component (d)]. As the water, ion-exchanged water containing no hardness component can be preferably used.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物就清潔性之觀點而言，較佳為強鹼性，較佳為調配鹼劑。作為鹼劑，可列舉鹼金屬之氫氧化物、或鹼金屬之矽酸鹽。作為鹼金屬之氫氧化物，可列舉氫氧化鈉或氫氧化鉀等，作為鹼金屬之矽酸鹽，可列舉矽酸鈉、矽酸鉀，具體而言可列舉偏矽酸鈉、原矽酸鈉、1號矽酸鈉、2號矽酸鈉、3號矽酸鈉、4號矽酸鈉、1K矽酸鉀、2K矽酸鉀。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is preferably strongly alkaline from the viewpoint of cleanability, and is preferably formulated as an alkali agent. The alkali agent may, for example, be an alkali metal hydroxide or an alkali metal citrate. Examples of the hydroxide of the alkali metal include sodium hydroxide or potassium hydroxide. Examples of the alkali metal citrate include sodium citrate and potassium citrate. Specific examples thereof include sodium metasilicate and protoporic acid. Sodium, sodium citrate No. 1, sodium citrate No. 2, sodium citrate No. 3, sodium citrate No. 4, potassium citrate 1K, potassium citrate 2K.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物較佳為用水稀釋20倍而成之5質量%水溶液於20℃下之pH值為11.5以上。此處，該pH值係使用pH METER F-21(堀場製作所股份有限公司製造)而測定之值。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is preferably a 5% by mass aqueous solution diluted 20 times with water and having a pH of 11.5 or more at 20 °C. Here, the pH value is a value measured using pH METER F-21 (manufactured by Horiba, Ltd.).
本發明之食品加工設備及/或調理設備用液體清潔劑組合物就發泡清潔時之泡沫穩定性之觀點而言，亦可含有1-羥基乙烷-1,1-二膦酸鹽等有機膦酸鹽。然而，若有機膦酸鹽之調配量較多，則存在對沖洗時之泡沫沖淨性產生影響之情形，故而重要的是以不損害泡沫沖淨性之量調配。具體而言，本發明之食品加工設備及/或調理設備用液體清潔劑組合物中之有機膦酸鹽之含量較佳為0質量%以上且未達0.5質量%，就沖洗時之泡沫沖淨性之觀點而言，更佳為不含該有機膦酸鹽。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention may also contain organic substances such as 1-hydroxyethane-1,1-diphosphonate from the viewpoint of foam stability during foam cleaning. Phosphonate. However, if the amount of the organic phosphonate is large, there is a case where the foaming property at the time of rinsing is affected, and therefore it is important to adjust the amount so as not to impair the foam repellency. Specifically, the content of the organic phosphonate in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is preferably 0% by mass or more and less than 0.5% by mass, and the foam is washed out during rinsing. From the standpoint of sex, it is more preferred to be free of the organic phosphonate.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物亦可於不阻礙本申請案所期望之效果之範圍內含有食品加工設備及/或調理設備用液體清潔劑組合物中通常使用之其他界面活性劑、螯合劑、增泡劑、增水溶劑、著色劑、香料、助洗劑、防銹劑、黏度調整劑等任意成分。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention may also be generally used in liquid detergent compositions for food processing equipment and/or conditioning equipment within a range that does not inhibit the desired effects of the present application. Any other surfactant, chelating agent, foaming agent, water-increasing solvent, coloring agent, perfume, builder, rust inhibitor, viscosity modifier and the like.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物於10℃~60℃之溫度範圍內為液體。詳細而言，較佳為於10℃~60℃之範圍內具有黏度3000 mPa‧s以下之流動性者，更佳為2000 mPa‧s以下，進而更適宜為800 mPa‧s以下。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is a liquid at a temperature ranging from 10 ° C to 60 ° C. Specifically, it is preferably a fluid having a viscosity of 3,000 mPa·s or less in a range of from 10 ° C to 60 ° C, more preferably 2,000 mPa ‧ s or less, and still more preferably 800 mPa ‧ s or less.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物較佳為即便於10℃以下亦不損傷溶液穩定性，進而較佳為即便於0℃以下，甚至-5℃之環境下亦維持透明性而不結凍。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention preferably does not impair the stability of the solution even below 10 ° C, and is preferably even in an environment of below 0 ° C or even -5 ° C. Maintain transparency without freezing.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物之製備方法並無特別限制，例如可藉由下述方法製備：將除氧化性鹵酸鹽以外之原料(氧化胺、脂肪酸、水等)於40~80℃之溫度下混合，獲得均勻透明之混合液後，進行緩冷卻，確認變成40℃以下後，調配氧化性鹵酸鹽。The preparation method of the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is not particularly limited, and can be prepared, for example, by the following method: a raw material other than an oxidizing halogen acid salt (amine oxide, fatty acid, Water, etc.) are mixed at a temperature of 40 to 80 ° C to obtain a homogeneous and transparent mixture, and then slowly cooled, and after confirming that it is 40 ° C or less, an oxidizing halide is prepared.
本發明之食品加工設備及/或調理設備用液體清潔劑組合物適宜用於包含下述步驟1~3之清潔方法。The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is suitably used in a cleaning method comprising the following steps 1 to 3.
步驟1：將食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍(較佳為5~200倍)之稀釋倍率預先稀釋，及/或一面稀釋，一面以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟；Step 1: Pre-diluting the liquid detergent composition for food processing equipment and/or conditioning equipment by water at a dilution ratio of 2 to 200 times (preferably 5 to 200 times), and/or diluting one side with foam a step of spraying to attach to a food processing device and/or conditioning device;
步驟2：將泡沫保持一定時間之步驟；及Step 2: the step of maintaining the foam for a certain period of time; and
步驟3：用水沖洗食品加工設備及/或調理設備之步驟；Step 3: The steps of rinsing the food processing equipment and/or conditioning equipment with water;
於步驟1中，將本發明之食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍(較佳為5~200倍)之稀釋倍率預先稀釋後，以泡沫狀噴射。或者將食品加工設備及/或調理設備用液體清潔劑組合物裝入至專用容器中，利用軟管等與自來水管直接連結等，藉此一面稀釋一面混合而以泡沫狀噴射。亦可將上述預先稀釋與同時稀釋組合而以泡沫狀噴射食品加工設備及/或調理設備用液體清潔劑組合物之稀釋溶液。步驟1中之稀釋倍率為2~200倍，較佳為5~200倍，更佳為20~100倍。In the step 1, the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is pre-diluted by water at a dilution ratio of 2 to 200 times (preferably 5 to 200 times), and is foamed. injection. Alternatively, the liquid detergent composition for food processing equipment and/or conditioning equipment is placed in a dedicated container, and directly connected to a water pipe by a hose or the like, and mixed while being diluted and sprayed in a foam form. The above-mentioned pre-dilution and simultaneous dilution may also be combined to spray a diluted solution of the liquid detergent composition for food processing equipment and/or conditioning equipment in a foam form. The dilution ratio in the step 1 is 2 to 200 times, preferably 5 to 200 times, more preferably 20 to 100 times.
此處，作為稀釋所使用之水，一般而言假定為如自來水般含有硬度成分之水。對於稀釋所使用之水之硬度，就發泡清潔時之泡沫穩定性之觀點而言，較佳為在0.1~30°dH之範圍內，更佳為在0.1~20°dH之範圍內，進而較佳為在0.1~15°dH之範圍內，進而較佳為在0.1~12°dH之範圍內，進而較佳為在0.1~8°dH之範圍內，進而較佳為在0.1~4°dH之範圍內。Here, the water used for the dilution is generally assumed to be water containing a hardness component like tap water. The hardness of the water used for the dilution is preferably in the range of 0.1 to 30 ° dH, more preferably in the range of 0.1 to 20 ° dH, from the viewpoint of foam stability during foam cleaning. It is preferably in the range of 0.1 to 15 ° dH, more preferably in the range of 0.1 to 12 ° dH, further preferably in the range of 0.1 to 8 ° dH, and more preferably in the range of 0.1 to 4 °. Within the range of dH.
作為使本發明之食品加工設備及/或調理設備用液體清潔劑組合物之稀釋溶液以泡沫狀噴射之態樣，可較佳地列舉下述態樣：將用水稀釋特定倍率而成之稀釋溶液適量填充至專用之泡沫清潔機中，混合來自外部之空氣/壓縮空氣而以泡沫狀噴射。稀釋溶液(清潔液)中的本發明之組合物之(b)成分與(c)成分(含有脂肪酸鹽之情形時係指脂肪酸換算量)之合計含量較佳為0.02~4質量%，更佳為0.02~1質量%。於食品加工工廠內之生產線等處理面積較大之情形時，可較佳使用泡沫清潔機(例如「SCU-HF」，Spraying公司製造；「KF-100」、「KF-200」，花王股份有限公司製造)。於砧板等調理器具等處理面積較小之情形時，可較佳使用觸發式噴霧器(trigger sprayer)或起泡式噴霧器(foamer sprayer)等可間歇地產生泡沫之手動噴霧器。As a method of spraying the diluted solution of the liquid detergent composition for a food processing apparatus and/or a conditioning apparatus of the present invention in a foam form, a dilute solution obtained by diluting a specific ratio with water can be preferably exemplified. Fill the foam into a special foam cleaner and mix the air/compressed air from the outside to spray it in a foam. The total content of the component (b) of the composition of the present invention and the component (c) (in the case of containing a fatty acid salt, the amount of the fatty acid) in the diluted solution (cleaning solution) is preferably 0.02 to 4% by mass, more preferably It is 0.02 to 1% by mass. When the processing line in the food processing plant has a large processing area, it is better to use a foam cleaner (such as "SCU-HF", manufactured by Spraying; "KF-100", "KF-200", Kao shares limited Made by the company). In the case where the treatment area such as the cutting board is small, a manual sprayer which intermittently generates a foam such as a trigger sprayer or a foamer sprayer can be preferably used.
於步驟1中，較佳為不間歇地以泡沫狀噴射。此處，所謂「不間歇地」噴射，表示使用泡沫清潔機，於藉由控制桿(lever)或開關等開啟期間連續地(例如5秒以上)將清潔劑以泡沫狀持續噴射，其有別於「間歇」噴射，例如使用觸發式噴霧器或起泡式噴霧器等手動噴霧器，於拉動控制桿時噴射，並瞬時停止噴射般之噴射態樣。In the step 1, it is preferred to spray in a foam form without intermittently. Here, the "non-intermittent" injection means that the cleaning agent is continuously sprayed in a foam form continuously (for example, 5 seconds or more) during the opening period by a lever or a switch, etc., using a foam cleaner. For "intermittent" injection, for example, a manual sprayer such as a trigger sprayer or a bubbler sprayer is used to spray when the control lever is pulled, and the spray-like spray pattern is instantaneously stopped.
使用泡沫清潔機不間歇地以泡沫狀噴射之態樣於作為清潔對象之食品加工設備及/或調理設備之面積或規模較大之情形時更有效。It is more effective to use a foam cleaner which is not intermittently sprayed in a foamed state in the case where the area or scale of the food processing equipment and/or conditioning equipment to be cleaned is large.
於使用泡沫清潔機之情形時，發泡倍率(泡沫之體積(mL)/泡沫之重量(g)之比)合適的是較佳為3~50倍，進而較佳為5~40倍，更佳為10~40倍。又，噴射時之壓力(錶壓)合適的是較佳為設為0.1~1 MPa，進而較佳為設為0.2~0.8 MPa，更佳為設為0.2~0.5 MPa。於使用觸發式噴霧器或起泡式噴霧器等手動噴霧器之情形時，發泡倍率較佳為2~30倍，進而較佳為2~20倍，更佳為3~10倍。In the case of using a foam cleaner, the expansion ratio (the ratio of the volume of the foam (mL) / the weight of the foam (g)) is preferably from 3 to 50 times, more preferably from 5 to 40 times, more preferably. Good for 10 to 40 times. Further, the pressure (gauge pressure) at the time of spraying is preferably 0.1 to 1 MPa, more preferably 0.2 to 0.8 MPa, still more preferably 0.2 to 0.5 MPa. In the case of using a hand sprayer such as a trigger sprayer or a bubbler sprayer, the expansion ratio is preferably 2 to 30 times, more preferably 2 to 20 times, still more preferably 3 to 10 times.
於步驟1中將本發明之食品加工設備及/或調理設備用液體清潔劑組合物之稀釋溶液以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上後，將泡沫保持一定時間(步驟2)。對於步驟2中保持泡沫之時間，就各裝置之機構及作業性之觀點而言，合適的是較佳為1~60分鐘，更佳為1分鐘~45分鐘。進而較佳為1~30分鐘，更佳為1~20分鐘，更佳為1~15分鐘，更佳為1~10分鐘，進而更佳為1~5分鐘。又，就清潔性之觀點而言，步驟2中保持泡沫之時間較佳為10~60分鐘，更佳為15~45分鐘，進而較佳為20~30分鐘。In step 1, the diluted solution of the liquid detergent composition of the food processing device and/or the conditioning device of the present invention is sprayed in a foam form to adhere to the food processing device and/or the conditioning device, and the foam is kept for a certain period of time. (Step 2). The time for holding the foam in the step 2 is preferably from 1 to 60 minutes, more preferably from 1 minute to 45 minutes, from the viewpoint of the mechanism and workability of each device. Further preferably, it is 1 to 30 minutes, more preferably 1 to 20 minutes, still more preferably 1 to 15 minutes, more preferably 1 to 10 minutes, and still more preferably 1 to 5 minutes. Further, from the viewpoint of cleanability, the time for holding the foam in the step 2 is preferably from 10 to 60 minutes, more preferably from 15 to 45 minutes, further preferably from 20 to 30 minutes.
步驟2中保持泡沫之時間根據稀釋溶液之稀釋倍率或使用場合而不同，並無特別限制，例如於2~50倍(較佳為5~50倍)之稀釋倍率下，保持泡沫之時間較佳為1~60分鐘，又，於50~200倍之稀釋倍率下，較佳為將泡沫穩定地保持1~10分鐘。The time for holding the foam in the step 2 is different depending on the dilution ratio of the diluted solution or the use occasion, and is not particularly limited. For example, at a dilution ratio of 2 to 50 times (preferably 5 to 50 times), the time for maintaining the foam is preferably. For 1 to 60 minutes, and further, at a dilution ratio of 50 to 200 times, it is preferred to keep the foam stably for 1 to 10 minutes.
於步驟2中保持泡沫期間，較佳為放置不動，亦可添加少許之水等。During the holding of the foam in the step 2, it is preferred to leave it still, and a little water or the like may be added.
將泡沫保持一定時間後，於步驟3中，用水沖洗食品加工設備及/或調理設備。沖洗水之溫度合適的是較佳為10~70℃，更佳為20~70℃。作為沖洗水，可使用自來水，為調整為上述較佳之水溫，亦可加熱後使用。通常係利用軟管等由人手進行沖洗作業。本發明之食品加工設備及/或調理設備用液體清潔劑組合物於該沖洗時之泡沫沖淨性優異，與先前之清潔劑組合物相比所需之沖洗水較少，於經濟性方面有利，並且亦顯著有助於減輕作業負荷(作業時間或作業人員數量)或環境負荷。After the foam has been held for a certain period of time, in step 3, the food processing equipment and/or conditioning equipment is rinsed with water. The temperature of the rinse water is suitably from 10 to 70 ° C, more preferably from 20 to 70 ° C. As the rinse water, tap water may be used, and it may be adjusted to the above preferred water temperature, and may be used after heating. It is usually performed by a hand using a hose or the like. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is excellent in foam flushing property at the time of rinsing, and requires less flushing water than the previous detergent composition, and is economically advantageous. And also significantly contribute to reducing the workload (working time or number of workers) or environmental load.
以下，表示本發明之態樣。Hereinafter, the aspect of the invention is shown.
一種食品加工設備及/或調理設備之清潔方法，其係使用如下食品加工設備及/或調理設備用液體清潔劑組合物，該液體清潔劑組合物含有：A method of cleaning food processing equipment and/or conditioning equipment using a liquid cleaning composition for food processing equipment and/or conditioning equipment, the liquid detergent composition comprising:
(a) 選自氧化性鹵酸(較佳為次氯酸、次溴酸、亞氯酸，更佳為次氯酸)及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽)中之一種以上之化合物((a)成分)0.5~10質量%(較佳為1.5~8質量%，進而較佳為2~5質量%)(其中，含有氧化性鹵酸鹽之情形時係指作為氧化性鹵酸之換算量)、(a) a salt selected from the group consisting of oxidizing halogen acids (preferably hypochlorous acid, hypobromous acid, chlorous acid, more preferably hypochlorous acid) and the like (preferably an alkali metal salt, more preferably a sodium salt) One or more of the compounds (component (a)) is 0.5 to 10% by mass (preferably 1.5 to 8% by mass, and more preferably 2 to 5% by mass) (wherein the case of containing an oxidizing halide) Means the conversion amount of oxidizing halogen acid)
(b) 具有1個碳數為8~14之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b)成分)0.5~18質量%(較佳為2~15質量%，進而較佳為3~10質量%)、(b) an amine oxide type surfactant having a hydrocarbon group of 8 to 14 carbon atoms (preferably a linear or branched alkyl group or a linear or branched alkenyl group) (component (b)) 0.5 to 18% by mass (preferably 2 to 15% by mass, further preferably 3 to 10% by mass),
(c) 選自碳數為12~16之脂肪酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物((c)成分)0.5~10質量%(較佳為1~10質量%，進而較佳為2.5~8質量%，更佳為3~5質量%)(其中，含有脂肪酸鹽之情形時係指作為脂肪酸之換算量)、及(c) a compound selected from the group consisting of a fatty acid having 12 to 16 carbon atoms and a salt thereof (preferably an alkali metal salt, more preferably a sodium salt or a potassium salt) ((c) component) 0.5 to 10 % by mass (preferably 1 to 10% by mass, further preferably 2.5 to 8% by mass, more preferably 3 to 5% by mass) (wherein, in the case of a fatty acid salt, it is referred to as a conversion amount of a fatty acid), and
(d) 水((d)成分)；(d) water (component (d));
(b) 成分之含量/(c)成分之含量的質量比為1/10~10/1(較佳為1/8~6/1，進而較佳為1/5~5/1)，且(b) The mass ratio of the content of the component / the content of the component (c) is 1/10 to 10/1 (preferably 1/8 to 6/1, more preferably 1/5 to 5/1), and
(b) 成分與(c)成分之合計含量為4~20質量%(較佳為5~20質量%，進而較佳為6~15質量%，更佳為7~10質量%)；並且該清潔方法包含下述步驟1~3：The total content of the component (b) and the component (c) is 4 to 20% by mass (preferably 5 to 20% by mass, more preferably 6 to 15% by mass, still more preferably 7 to 10% by mass); The cleaning method includes the following steps 1~3:
步驟1：將食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍(較佳為5~200倍，更佳為20~100倍)之稀釋倍率預先稀釋，及/或一面稀釋，一面以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟；Step 1: pre-diluting the liquid detergent composition for food processing equipment and/or conditioning equipment by a dilution ratio of 2 to 200 times (preferably 5 to 200 times, more preferably 20 to 100 times) of water, and / or a step of spraying on one side and spraying it on the food processing equipment and/or conditioning equipment;
步驟2：將泡沫保持一定時間(就各裝置之機構及作業性之觀點而言，合適的是較佳為1~60分鐘，更佳為1分鐘~45分鐘；進而較佳為1~30分鐘，更佳為1~20分鐘，更佳為1~15分鐘，更佳為1~10分鐘，進而更佳為1~5分鐘；又，就清潔性之觀點而言，較佳為10~60分鐘，更佳為15~45分鐘，進而較佳為20~30分鐘)之步驟；Step 2: The foam is kept for a certain period of time (it is preferably from 1 to 60 minutes, more preferably from 1 minute to 45 minutes, and more preferably from 1 to 30 minutes) from the viewpoint of the mechanism and workability of each device. More preferably, it is 1 to 20 minutes, more preferably 1 to 15 minutes, more preferably 1 to 10 minutes, and even more preferably 1 to 5 minutes; and, in terms of cleanliness, preferably 10 to 60. a minute, more preferably 15 to 45 minutes, and more preferably 20 to 30 minutes);
步驟3：用水沖洗食品加工設備及/或調理設備之步驟。Step 3: The steps of rinsing the food processing equipment and/or conditioning equipment with water.
如<第1項>之食品加工設備及/或調理設備之清潔方法，其中步驟1係將食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍(較佳為5~200倍，更佳為20~100倍)之稀釋倍率預先稀釋，及/或一面稀釋，一面不間歇地以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上的步驟。The cleaning method of the food processing equipment and/or the conditioning equipment of the item <1>, wherein the step 1 is to use the liquid cleaning composition for the food processing equipment and/or the conditioning equipment by water 2 to 200 times (preferably 5 to 200 times, more preferably 20 to 100 times, the dilution ratio is pre-diluted, and/or diluted on one side, and sprayed on the side without intermittently to adhere to the food processing equipment and/or the conditioning equipment.
如<第1項>或<第2項>之食品加工設備及/或調理設備之清潔方法，其係使用(a)成分之含量/[(b)成分之含量+(c)成分之含量]的質量比為1/10~2.5/1(較佳為1/10~1/1，更佳為1/7~1/1，進而較佳為1/5~1/1，進而更佳為1/5~7/10)之食品加工設備及/或調理設備用液體清潔劑組合物。For the cleaning method of food processing equipment and/or conditioning equipment of <1st item> or <2nd item>, the content of (a) component/[(b) component content + (c) component content] The mass ratio is 1/10 to 2.5/1 (preferably 1/10 to 1/1, more preferably 1/7 to 1/1, further preferably 1/5 to 1/1, and further preferably 1/5~7/10) liquid cleaning agent composition for food processing equipment and/or conditioning equipment.
如<第1項>至<第3項>中任一項之食品加工設備及/或調理設備之清潔方法，其係使用(c)成分為選自肉豆蔻酸、月桂酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物的食品加工設備及/或調理設備用液體清潔劑組合物。The method for cleaning food processing equipment and/or conditioning equipment according to any one of the items 1 to 3, wherein the component (c) is a salt selected from the group consisting of myristic acid, lauric acid, and the like. A liquid detergent composition for food processing equipment and/or conditioning equipment of a compound of one or more of (preferably an alkali metal salt, more preferably a sodium salt or a potassium salt).
如<第1項>至<第4項>中任一項之食品加工設備及/或調理設備之清潔方法，其中(b)成分含有具有1個碳數為8~10之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b1)成分)、及具有1個碳數為12之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b2)成分)，且作為(b)成分之具有1個碳數為14之烴基之氧化胺型界面活性劑的含量為0~0.01質量%。The method for cleaning food processing equipment and/or conditioning equipment according to any one of the items 1 to 4, wherein the component (b) contains a hydrocarbon group having 8 to 10 carbon atoms (preferably a linear or branched alkyl group, or a linear or branched alkenyl group, an amine oxide type surfactant ((b1) component), and a hydrocarbon group having 12 carbon atoms (preferably linear or An amine oxide type surfactant (a component of the (b2)) of a branched alkyl group or a linear or branched alkenyl group, and an amine oxide type having one hydrocarbon group of 14 carbon atoms as the component (b) The content of the surfactant is from 0 to 0.01% by mass.
如<第5項>之食品加工設備及/或調理設備之清潔方法，其中作為(c)成分之選自碳數為14之脂肪酸及其等之鹽中之一種以上之化合物((c1)成分)之含量、(b1)成分之含量、及(b2)成分之含量滿足如下條件(i)及(ii)：條件(i)：(c1)成分之含量/(b2)成分之含量的質量比為0~2.5；條件(ii)：(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比為0.3~1。A cleaning method of a food processing device and/or a conditioning device according to the item 5, wherein the compound (c1) is one or more selected from the group consisting of a fatty acid having 14 carbon atoms and a salt thereof (c) The content of the component, the content of the component (b1), and the content of the component (b2) satisfy the following conditions (i) and (ii): the mass ratio of the component (i): the content of the component (c1) / the component of the component (b2) It is 0 to 2.5; the condition (ii): the mass ratio of the component (b1) / the content of the (b1) component + the content of the component (c1) is 0.3 to 1.
如<第1項>至<第6項>中任一項之食品加工設備及/或調理設備之清潔方法，其係使用(a)成分為選自次氯酸及其鹽中之一種以上之化合物之食品加工設備及/或調理設備用液體清潔劑組合物。The method for cleaning food processing equipment and/or conditioning equipment according to any one of the items of the present invention, wherein the component (a) is one or more selected from the group consisting of hypochlorous acid and a salt thereof. A liquid detergent composition for a food processing device and/or conditioning device for a compound.
一種食品加工設備及/或調理設備用液體清潔劑組合物，其含有：A liquid detergent composition for food processing equipment and/or conditioning equipment, comprising:
(a)選自氧化性鹵酸(較佳為次氯酸、次溴酸、亞氯酸，更佳為次氯酸)及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽)中之一種以上之化合物((a)成分)0.5~10質量%(較佳為1.5~8質量%，進而較佳為2~5質量%)(其中，含有氧化性鹵酸鹽之情形時係指作為氧化性鹵酸之換算量)、(a) a salt selected from the group consisting of oxidizing halogen acids (preferably hypochlorous acid, hypobromous acid, chlorous acid, more preferably hypochlorous acid) and the like (preferably an alkali metal salt, more preferably a sodium salt) One or more of the compounds (component (a)) is 0.5 to 10% by mass (preferably 1.5 to 8% by mass, and more preferably 2 to 5% by mass) (wherein the case of containing an oxidizing halide) Means the conversion amount of oxidizing halogen acid)
(b) 具有1個碳數為8~14之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b)成分)0.5~18質量%(較佳為2~15質量%，進而較佳為3~10質量%)、(b) an amine oxide type surfactant having a hydrocarbon group of 8 to 14 carbon atoms (preferably a linear or branched alkyl group or a linear or branched alkenyl group) (component (b)) 0.5 to 18% by mass (preferably 2 to 15% by mass, further preferably 3 to 10% by mass),
(c) 選自碳數為12~16之脂肪酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物((c)成分)0.5~10質量%(較佳為1.0~10質量%，進而較佳為2.5~8質量%，更佳為3~5質量%)(其中，含有脂肪酸鹽之情形時係指作為脂肪酸之換算量)、及(c) a compound selected from the group consisting of a fatty acid having 12 to 16 carbon atoms and a salt thereof (preferably an alkali metal salt, more preferably a sodium salt or a potassium salt) ((c) component) 0.5 to 10 % by mass (preferably 1.0 to 10% by mass, further preferably 2.5 to 8% by mass, more preferably 3 to 5% by mass) (wherein, in the case of a fatty acid salt, it is referred to as a conversion amount of a fatty acid), and
(d) 水((d)成分)；並且(d) water (component (d)); and
(b) 成分之含量/(c)成分之含量的質量比為1/10~10/1(較佳為1/8~6/1，進而較佳為1/5~5/1)，且(b) The mass ratio of the content of the component / the content of the component (c) is 1/10 to 10/1 (preferably 1/8 to 6/1, more preferably 1/5 to 5/1), and
(b) 成分與(c)成分之合計含量為4~20質量%(較佳為5~20質量%，進而較佳為6~15質量%，更佳為7~10質量%)。The total content of the component (b) and the component (c) is 4 to 20% by mass (preferably 5 to 20% by mass, more preferably 6 to 15% by mass, still more preferably 7 to 10% by mass).
如<第8項>之食品加工設備及/或調理設備用液體清潔劑組合物，其中(a)成分之含量/[(b)成分之含量+(c)成分之含量]的質量比為1/10~2.5/1(較佳為1/10~1/1，更佳為1/7~1/1，進而較佳為1/5~1/1，進而更佳為1/5~7/10)。A liquid detergent composition for food processing equipment and/or conditioning equipment according to <8>, wherein the mass ratio of the component (a)/the content of the (b) component to the component (c) component is 1 /10~2.5/1 (preferably 1/10~1/1, more preferably 1/7~1/1, further preferably 1/5~1/1, and even more preferably 1/5~7) /10).
如<第8項>或<第9項>之食品加工設備及/或調理設備用液體清潔劑組合物，其中(c)成分為選自肉豆蔻酸、月桂酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物。A liquid detergent composition for food processing equipment and/or conditioning equipment according to <8> or <9>, wherein the component (c) is a salt selected from the group consisting of myristic acid, lauric acid and the like (preferably) It is a compound of one or more of an alkali metal salt, more preferably a sodium salt or a potassium salt.
如<第8項>至<第10項>中任一項之食品加工設備及/或調理設備用液體清潔劑組合物，其中(b)成分含有具有1個碳數為8~10之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b1)成分)、及具有1個碳數為12之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b2)成分)，且作為(b)成分之具有1個碳數為14之烴基之氧化胺型界面活性劑的含量為0~0.01質量%。The liquid detergent composition for food processing equipment and/or conditioning equipment according to any one of the items of the present invention, wherein the component (b) contains a hydrocarbon group having 8 to 10 carbon atoms ( An amine oxide type surfactant ((b1) component) preferably having a linear or branched alkyl group or a linear or branched alkenyl group, and a hydrocarbon group having 12 carbon atoms (preferably a linear or branched alkyl group, or a linear or branched alkenyl group, an amine oxide type surfactant (component (b2)), and as a component (b) having one hydrocarbon group having 14 carbon atoms The content of the amine oxide type surfactant is 0 to 0.01% by mass.
如<第11項>之食品加工設備及/或調理設備用液體清潔劑組合物，其中作為(c)成分之選自碳數為14之脂肪酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物((c1)成分)之含量、(b1)成分之含量、及(b2)成分之含量滿足如下條件(i)及(ii)：A liquid detergent composition for food processing equipment and/or conditioning equipment according to <11>, wherein the component (c) is selected from the group consisting of a fatty acid having 14 carbon atoms and a salt thereof (preferably an alkali metal salt, More preferably, the content of the compound (the component (c1)), the component (b1), and the component (b2) of the sodium salt or the potassium salt satisfy the following conditions (i) and (ii):
條件(i)：(c1)成分之含量/(b2)成分之含量的質量比為0~2.5；Condition (i): the mass ratio of the content of the component (c1) / the content of the component (b2) is 0 to 2.5;
條件(ii)：(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比為0.3~1。Condition (ii): The mass ratio of the component (b1)/the content of the (b1) component to the component (c1) component is 0.3 to 1.
如<第8項>至<第12項>中任一項之食品加工設備及/或調理設備用液體清潔劑組合物，其中(a)成分為選自次氯酸及其鹽中之一種以上之化合物。The liquid detergent composition for food processing equipment and/or conditioning equipment of any one of the above-mentioned item, wherein the component (a) is one or more selected from the group consisting of hypochlorous acid and a salt thereof. Compound.
如<第8項>至<第13項>中任一項之食品加工設備及/或調理設備用液體清潔劑組合物，其係用於包含下述步驟1~3之清潔方法：The liquid detergent composition for food processing equipment and/or conditioning equipment according to any one of <8> to <13>, which is used for the cleaning method comprising the following steps 1 to 3:
步驟1：將食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍(較佳為5~200倍，更佳為20~100倍)之稀釋倍率預先稀釋，及/或一面稀釋，一面以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟；Step 1: pre-diluting the liquid detergent composition for food processing equipment and/or conditioning equipment by a dilution ratio of 2 to 200 times (preferably 5 to 200 times, more preferably 20 to 100 times) of water, and / or a step of spraying on one side and spraying it on the food processing equipment and/or conditioning equipment;
步驟2：將泡沫保持一定時間(就各裝置之機構及作業性之觀點而言，合適的是較佳為1~60分鐘，更佳為1分鐘~45分鐘；進而較佳為1~30分鐘，更佳為1~20分鐘，更佳為1~15分鐘，更佳為1~10分鐘，進而更佳為1~5分鐘；又，就清潔性之觀點而言，較佳為10~60分鐘，更佳為15~45分鐘，進而較佳為20~30分鐘)之步驟；Step 2: The foam is kept for a certain period of time (it is preferably from 1 to 60 minutes, more preferably from 1 minute to 45 minutes, and more preferably from 1 to 30 minutes) from the viewpoint of the mechanism and workability of each device. More preferably, it is 1 to 20 minutes, more preferably 1 to 15 minutes, more preferably 1 to 10 minutes, and even more preferably 1 to 5 minutes; and, in terms of cleanliness, preferably 10 to 60. a minute, more preferably 15 to 45 minutes, and more preferably 20 to 30 minutes);
步驟3：用水沖洗食品加工設備及/或調理設備之步驟。Step 3: The steps of rinsing the food processing equipment and/or conditioning equipment with water.
如<第14項>之食品加工設備及/或調理設備用液體清潔劑組合物，其中步驟1係將食品加工設備及/或調理設備用液體清潔劑組合物藉由水以2~200倍(較佳為5~200倍，更佳為20~100倍)之稀釋倍率預先稀釋，及/或一面稀釋，一面不間歇地以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上的步驟。A liquid detergent composition for food processing equipment and/or conditioning equipment according to <14>, wherein step 1 is to use a liquid detergent composition for food processing equipment and/or conditioning equipment by water 2 to 200 times ( Preferably, the dilution ratio is 5 to 200 times, more preferably 20 to 100 times, the dilution ratio is pre-diluted, and/or diluted on one side, and sprayed on the side without intermittently, so that it adheres to the food processing equipment and/or the conditioning equipment. A step of.
一種食品加工設備及/或調理設備之清潔方法，其於將清潔液以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟後，具有用水沖洗之步驟，上述清潔液含有：A cleaning method for a food processing device and/or a conditioning device, which has a step of rinsing with water after the step of spraying the cleaning solution in a foam form to adhere to the food processing device and/or the conditioning device, the cleaning solution containing :
(a) 選自氧化性鹵酸(較佳為次氯酸、次溴酸、亞氯酸，更佳為次氯酸)及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽)中之一種以上之化合物0.0025~2質量%、(a) a salt selected from the group consisting of oxidizing halogen acids (preferably hypochlorous acid, hypobromous acid, chlorous acid, more preferably hypochlorous acid) and the like (preferably an alkali metal salt, more preferably a sodium salt) a compound of one or more of 0.0025 to 2% by mass,
(b) 具有1個碳數為8~14之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)的氧化胺型界面活性劑0.0025~3.6質量%、(b) an amine oxide type surfactant having one hydrocarbon group having 8 to 14 carbon atoms (preferably a linear or branched alkyl group or a linear or branched alkenyl group) of 0.0025 to 3.6% by mass,
(c) 選自碳數為12~16之脂肪酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物0.0025~2質量%、及(c) 0.0025 to 2% by mass of a compound selected from the group consisting of a fatty acid having 12 to 16 carbon atoms and a salt thereof (preferably an alkali metal salt, more preferably a sodium salt or a potassium salt), and
(d) 水；且(d) water; and
(b) 成分之含量/(c)成分之含量的質量比為1/10~10/1；(b) the content of the component / the content of the component (c) is 1/10 to 10/1;
(b) 成分與(c)成分之合計含量為0.02~4質量%。The total content of the component (b) and the component (c) is 0.02 to 4% by mass.
如<第16項>之食品加工設備及/或調理設備之清潔方法，其中將清潔液以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟為將清潔液不間歇地以泡沫狀噴射，使其附著至食品加工設備及/或調理設備上之步驟。The cleaning method of the food processing device and/or the conditioning device according to the item [16], wherein the cleaning liquid is sprayed in a foam form to adhere to the food processing device and/or the conditioning device, wherein the cleaning liquid is intermittently The step of spraying in a foam to attach it to a food processing device and/or conditioning device.
如<第16項>或<第17項>之食品加工設備及/或調理設備之清潔方法，其中清潔液中之(a)成分之含量/[(b)成分之含量+(c)成分之含量]的質量比為1/10~2.5/1。The cleaning method of the food processing equipment and/or the conditioning equipment of the <16th item> or <17th item>, wherein the content of the component (a) in the cleaning liquid / the content of the component (b) + the component (c) The mass ratio of the content is 1/10 to 2.5/1.
如<第16項>至<第18項>中任一項之食品加工設備及/或調理設備之清潔方法，其中A method of cleaning food processing equipment and/or conditioning equipment according to any one of <16> to <18>, wherein
(b)成分含有具有1個碳數為8~10之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b1)成分)、及具有1個碳數為12之烴基(較佳為直鏈或支鏈之烷基，或者直鏈或支鏈之烯基)之氧化胺型界面活性劑((b2)成分)，且作為(b)成分之具有1個碳數為14之烴基之氧化胺型界面活性劑的含量為0~0.01質量%；The component (b) contains an amine oxide type surfactant having one hydrocarbon group having 8 to 10 carbon atoms (preferably a linear or branched alkyl group or a linear or branched alkenyl group) ((b1) a component), and an amine oxide type surfactant ((b2) component) having one hydrocarbon group having 12 carbon atoms (preferably a linear or branched alkyl group or a linear or branched alkenyl group), And the content of the amine oxide type surfactant having one hydrocarbon group having 14 carbon atoms as the component (b) is 0 to 0.01% by mass;
作為(c)成分之選自具有碳數為14之脂肪酸及其等之鹽(較佳為鹼金屬鹽，更佳為鈉鹽或鉀鹽)中之一種以上之化合物((c1)成分)之含量、(b1)成分之含量、及(b2)成分之含量滿足如下條件(i)及(ii)：a compound ((c1)) selected from the group consisting of a fatty acid having 14 carbon atoms and a salt thereof (preferably an alkali metal salt, more preferably a sodium salt or a potassium salt) as the component (c) The content, the content of the (b1) component, and the content of the (b2) component satisfy the following conditions (i) and (ii):
條件(i)：(c1)成分之含量/(b2)成分之含量的質量比為0~2.5；Condition (i): the mass ratio of the content of the component (c1) / the content of the component (b2) is 0 to 2.5;
條件(ii)：(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比為0.3~1。Condition (ii): The mass ratio of the component (b1)/the content of the (b1) component to the component (c1) component is 0.3 to 1.
以下之實施例係對本發明之實施進行說明。實施例係對本發明之示例進行說明者，並非用以限定本發明。The following examples are illustrative of the practice of the invention. The examples are illustrative of the invention and are not intended to limit the invention.
製備表1、2所示之食品加工設備及/或調理設備用液體清潔劑組合物，進行以下之試驗。將結果一併示於表1、2。The liquid detergent composition for food processing equipment and/or conditioning equipment shown in Tables 1 and 2 was prepared, and the following test was performed. The results are shown together in Tables 1 and 2.
再者，於表1、2中，質量比一欄中附有記號「-」者表示無法得出比例。又，於表1、2中，試驗結果一欄中附有「-」者表示由於食品加工設備及/或調理設備用液體清潔劑組合物固化或凝膠化，故而未進行試驗。記載為難以評價者表示雖嘗試評價，但無法評價。Furthermore, in Tables 1 and 2, the symbol "-" attached to the column of the mass ratio indicates that the ratio cannot be obtained. Further, in Tables 1 and 2, "-" in the column of the test results indicates that the liquid detergent composition for food processing equipment and/or conditioning equipment was cured or gelled, and thus the test was not carried out. It is described that the person who is difficult to evaluate indicates that although the evaluation is attempted, it cannot be evaluated.
實施例2、3、5、7、10~13、21、22、24~26係上述態樣<第6項>、<第12項>之發明之實施例。Examples 2, 3, 5, 7, 10 to 13, 21, 22, and 24 to 26 are examples of the invention of the above-described aspects <6th item> and <12th item>.
其中，表1、2所示之(a)成分之含量係根據氧化性鹵酸鹽之投入量，藉由下述式而求出之作為氧化性鹵酸之換算量(以有效數字為兩位數之方式四捨五入而算出)。In addition, the content of the component (a) shown in Tables 1 and 2 is obtained by the following formula as the conversion amount of the oxidizing halogen acid (the effective number is two digits) based on the amount of the oxidizing halide. The method of counting is rounded off and calculated).
(作為氧化性鹵酸之換算量)=(氧化性鹵酸鹽之調配質量[g])×[(氧化性鹵酸之莫耳質量[g/mol])/(氧化性鹵酸鹽之莫耳質量[g/mol])](as a converted amount of oxidizing halogen acid) = (mixed mass of oxidizing halogen acid [g]) × [(mole mass of oxidizing halogen acid [g/mol]) / (molytical halogenate Ear mass [g/mol])]
此處，計算所使用之莫耳質量[g/mol]如下所示。Here, the molar mass [g/mol] used for the calculation is as follows.
次氯酸：52.46Hypochlorous acid: 52.46
次氯酸鈉：74.44Sodium hypochlorite: 74.44
亞氯酸：68.46Chlorite: 68.46
亞氯酸鈉：90.44Sodium chlorite: 90.44
又，關於表1、2中之椰子油脂肪酸，係將碳數為12~16之脂肪酸之比例設為89質量%而計算，且將小數點以下第3位四捨五入而記載。In addition, the coconut oil fatty acids in Tables 1 and 2 are calculated by setting the ratio of the fatty acids having 12 to 16 carbon atoms to 89% by mass, and the third decimal place is rounded off.
將表1、2記載之食品加工設備及/或調理設備用液體清潔劑組合物(表中記載為「液體清潔劑組合物」，以下稱為液體清潔劑組合物)利用硬度為4°dH之水稀釋20倍，製成5質量%水溶液，投入100 mL至泵式起泡容器(B 523，吉野工業所股份有限公司製造)中。向300 mL之拋棄式杯(上端直徑為9 cm，下端直徑為7 cm，高度為10 cm)推壓一次起泡頭形成泡沫(推壓一次所花費之時間為1秒，每推壓一次產生1 g之泡沫；發泡倍率為20倍)，目視判定至完全消泡為止之時間，測定該時間(分鐘)。於該試驗中，將60分鐘以上設為合格。The liquid detergent composition for food processing equipment and/or conditioning equipment described in Tables 1 and 2 (hereinafter referred to as "liquid detergent composition", hereinafter referred to as liquid detergent composition) has a hardness of 4 ° dH. The water was diluted 20 times to prepare a 5 mass% aqueous solution, and 100 mL was placed in a pump type foaming container (B 523, manufactured by Yoshino Industrial Co., Ltd.). Push the bubbling head into a 300 mL disposable cup (9 cm in diameter at the top end, 7 cm in diameter at the lower end, and 10 cm in height) to form a foam. The time it takes to push it once is 1 second. 1 g of foam; expansion ratio of 20 times), the time until the complete defoaming was visually determined, and the time (minutes) was measured. In this test, 60 minutes or more was set as pass.
再者，比較例7、比較例11及比較例12由於未充分地起泡，故而未能實施泡沫穩定性試驗及沖洗性之試驗(下述(2)及(3))。Further, in Comparative Example 7, Comparative Example 11, and Comparative Example 12, since the foaming was not sufficiently performed, the foam stability test and the rinsing property test (the following (2) and (3)) were not performed.
將表1、2記載之液體清潔劑組合物利用硬度為4°dH之水稀釋20倍，製成5質量%水溶液，投入100 mL至泵式起泡容器(B 523，吉野工業所股份有限公司製造)中。向300 mL之拋棄式杯推壓一次起泡頭形成泡沫(每推壓一次產生1 g之泡沫；發泡倍率為20倍)。1分鐘後，向該泡沫投入硬度為4°dH之水(25℃)100 mL，目視判定至完全消泡為止之時間。測定該時間(秒)。於該試驗中，將未達20秒設為合格。The liquid detergent composition described in Tables 1 and 2 was diluted 20 times with water having a hardness of 4° dH to prepare a 5 mass% aqueous solution, and 100 mL was supplied to a pump-type foaming container (B 523, Yoshino Industrial Co., Ltd. Made). A foaming head was pressed against a 300 mL disposable cup to form a foam (1 g of foam per press; the expansion ratio was 20 times). After 1 minute, 100 mL of water (25 ° C) having a hardness of 4 ° dH was placed in the foam, and the time until complete defoaming was visually determined. This time (seconds) was measured. In this test, less than 20 seconds was set as pass.
將利用自來水(硬度為3.9°dH)使液體清潔劑組合物稀釋20倍而成之5質量%水溶液混合投入至泡沫清潔機中(KF-200，花王股份有限公司製造)，對塑膠容器用清潔機(DW-2000R/L，三洋電機股份有限公司製造)(兩清潔機相距50 cm，自KF-200噴射口向DW-2000R/L中噴射)，以0.4 MPa(錶壓)之壓力噴射15秒鐘(泡沫之總噴射量為500 g；發泡倍率為20倍)。30分鐘後，使用自來水以10 L/min之水量(水溫為25℃，硬度為2.5°dH)沖洗，測定直至泡沫完全消失為止之時間(秒)。於該試驗中，將150秒以下設為合格。A 5 mass% aqueous solution obtained by diluting a liquid detergent composition by 20 times with tap water (hardness of 3.9 ° dH) is mixed and put into a foam cleaner (KF-200, manufactured by Kao Co., Ltd.), and the plastic container is cleaned. Machine (DW-2000R/L, manufactured by Sanyo Electric Co., Ltd.) (two cleaning machines are separated by 50 cm from the KF-200 injection port to DW-2000R/L), and sprayed at a pressure of 0.4 MPa (gauge pressure). Seconds (the total spray volume of the foam is 500 g; the expansion ratio is 20 times). After 30 minutes, the tap water was rinsed with a water amount of 10 L/min (water temperature of 25 ° C, hardness of 2.5 ° dH), and the time (seconds) until the foam completely disappeared was measured. In this test, 150 seconds or less was set as pass.
再者，關於沖洗性現場試驗之沖洗時間(秒)，表1、2之附有括弧之數值係藉由下述推算方法所獲得之推算值。Further, regarding the rinsing time (seconds) of the rinsing field test, the values of the parentheses in Tables 1 and 2 are estimated values obtained by the following estimation methods.
推算值之算出方法係使用表1之實施例1~13之「(2)沖洗性模型試驗」之值與「(3)沖洗性現場試驗」之值，藉由下述一階近似式(相關函數)而算出。The calculation method of the estimated value is the value of "(2) flushing model test" and "(3) flushing field test" of Examples 1 to 13 of Table 1, by the following first-order approximation (correlation) Calculated by function).
Y=4.9741‧X+78.357Y=4.9741‧X+78.357
藉由向該近似式之X代入表1中之「(2)沖洗性模型試驗」之沖洗時間(秒)，獲得沖洗性現場試驗之沖洗時間(秒)之推算值Y。推算值係將小數第1位四捨五入而以附有括弧之形式記載於表1中。The estimated value Y of the flushing time (seconds) of the rinsing field test is obtained by substituting the X of the approximate formula into the "(2) flushing model test" rinsing time (second) in Table 1. The estimated value is rounded off to the first decimal place and is shown in Table 1 in the form of brackets.
對表1、2記載之液體清潔劑組合物，使用B型黏度計(TOKIMEC製造)，將組合物之溫度調節至20℃，使用NO.2或NO.3之旋轉器(NO.2係於黏度為1000 mPa以下時使用，NO.3係於黏度為1000~10000 mPa時使用)，於轉速6~60 rpm下測定黏度，讀取旋轉開始60秒後之值。於該試驗中，將3000 mPa‧s以下設為合格。再者，將利用B型黏度難以正常測定，且認為黏度為10000 mPa‧s以上者記載為「凝膠」，進而，對於一部分凝固者，記載為「一部分固化」，對於全部凝固者，記載為「固化」。For the liquid detergent composition described in Tables 1 and 2, a B-type viscometer (manufactured by TOKIMEC) was used, and the temperature of the composition was adjusted to 20 ° C, and a rotator of NO. 2 or NO. 3 was used (NO. 2 was used for The viscosity is 1000 mPa or less, and the NO.3 is used when the viscosity is 1000 to 10000 mPa. The viscosity is measured at a rotation speed of 6 to 60 rpm, and the value after 60 seconds from the start of rotation is read. In this test, 3000 mPa ‧ s or less was set as pass. In addition, the B-type viscosity is difficult to measure normally, and it is considered that the viscosity is 10000 mPa ‧ s or more, and it is described as "gel", and the part of the coagulation is described as "partially solidified". "Curing".
將表1、2記載之液體清潔劑組合物於-5℃環境下保存3天，將於-5℃下為透明之液體設為合格(○)。再者，將利用B型黏度計難以正常測定，且認為黏度為10000 mPa‧s以上者記載為「凝膠」。又，對於產生析出物者，記載為「析出」，對於無生析出物但產生相分離者，記載為「分離」。The liquid detergent composition described in Tables 1 and 2 was stored in an environment of -5 ° C for 3 days, and a liquid which was transparent at -5 ° C was set as a pass (○). In addition, it is difficult to measure normally using a B-type viscometer, and it is considered to be "gel" when it is considered that the viscosity is 10000 mPa‧s or more. In addition, those who produce precipitates are described as "precipitation", and those who have no precipitates but which are separated are described as "separation".
於標準試驗板(SUS304：1.0 mm×30 mm×80 mm，Testpanel股份有限公司製造)上塗佈含0.1%蘇丹III之菜籽油10 μg，將其作為清潔模型試驗板。將液體清潔劑組合物之5質量%水溶液(4°dH硬水)投入100 mL至泵式起泡容器(B 523，吉野工業所股份有限公司製造)中，將推壓一次起泡頭而形成之泡沫(每推壓一次產生1 g之泡沫；發泡倍率為20倍)塗佈於上述清潔模型試驗板上。塗佈後放置30分鐘後，利用自來水沖洗並乾燥，藉由己烷萃取測定殘留油量，藉由下述式算出清潔率(%)。於該試驗中，將70%以上設為合格。10 μg of 0.1% Sudan III rapeseed oil was applied to a standard test plate (SUS304: 1.0 mm × 30 mm × 80 mm, manufactured by Testpanel Co., Ltd.) as a clean model test plate. A 5 mass% aqueous solution (4° dH hard water) of the liquid detergent composition was put into 100 mL to a pump-type foaming container (B 523, manufactured by Yoshino Industrial Co., Ltd.), and a bubbling head was pushed once to form a foaming head. The foam (1 g of foam per press was applied; the expansion ratio was 20 times) was applied to the above clean model test plate. After the coating was allowed to stand for 30 minutes, it was rinsed with tap water and dried, and the amount of residual oil was measured by hexane extraction, and the cleaning rate (%) was calculated by the following formula. In this test, 70% or more was set as pass.
清潔率(%)=100×((塗佈油量)-(殘留油量))/(塗佈油量)Cleaning rate (%) = 100 × ((coating oil amount) - (residual oil amount)) / (coating oil amount)
實施例、比較例(比較例1、5、7、8、11~15除外)之清潔率均為70%~100%，在合格範圍內。The cleaning rates of the examples and comparative examples (except for Comparative Examples 1, 5, 7, 8, and 11 to 15) were all 70% to 100%, which were within the acceptable range.
*1 作為氧化性鹵酸之換算量(表中，括弧內之數值為氧化性鹵酸鹽之投入量)*1 As a conversion amount of oxidizing halogen acid (in the table, the value in parentheses is the input amount of oxidizing halide)
*2 (b)成分之比較成分*2 Comparative component of component (b)
*3 (c)成分之比較成分*3 (c) comparison component
*4 烷基組成[質量%]：碳數為10以下：5%；碳數為12：57%；碳數為14：22%；碳數為16：10%；碳數為18以上：4%(表中，括弧內之數值為碳數為12~16之脂肪酸之含量)*4 Alkyl composition [% by mass]: carbon number is 10 or less: 5%; carbon number is 12:57%; carbon number is 14:22%; carbon number is 16:10%; carbon number is 18 or more: 4 % (in the table, the value in parentheses is the content of fatty acids with a carbon number of 12 to 16)
*5 將液體清潔劑組合物利用水稀釋20倍而成之5質量%水溶液之pH(20℃)值*5 pH (20 ° C) value of a 5 mass % aqueous solution obtained by diluting a liquid detergent composition 20 times with water
(註1) 表中之成分為以下者。(Note 1) The components in the table are as follows.
‧次氯酸鈉：中鹽次氯酸鈉，南海化學股份有限公司製造‧ sodium hypochlorite: medium salt sodium hypochlorite, manufactured by Nanhai Chemical Co., Ltd.
‧亞氯酸鈉：Silbrite 25，Japan Carlit股份有限公司製造‧ Sodium chlorite: Silbrite 25, manufactured by Japan Carlit Co., Ltd.
‧十二烷基二甲基氧化胺：Amphitol 20N，花王股份有限公司製造，有效成分為35質量%※2 ‧ Dodecyl dimethyl amine oxide: Amphitol 20N, manufactured by Kao Co., Ltd., with an active ingredient of 35 mass% *2
‧辛基二甲基氧化胺：可藉由使二甲基辛胺與過氧化氫溶液於50℃~80℃下反應而獲得※1，有效成分為50質量%※2 ‧ Octyl dimethylamine oxide: It can be obtained by reacting dimethyloctylamine with a hydrogen peroxide solution at 50 ° C to 80 ° C to obtain *1 , and the active ingredient is 50% by mass *2
‧癸基二甲基氧化胺：可藉由使二甲基癸胺與過氧化氫溶液於50℃~80℃下反應而獲得※1，有效成分為40.4質量%※2 ‧ decyl dimethyl amine oxide group: by making available dimethyl decylamine with hydrogen peroxide solution at 50 ℃ ~ 80 ℃ obtained by reacting ※ 1, the active ingredient of 40.4 mass% ※ 2
‧十四烷基二甲基氧化胺：可藉由使二甲基十四烷基胺與過氧化氫溶液於50℃~80℃下反應而獲得※1，有效成分為25質量%※2 ‧ tetradecyl dimethyl amine oxide: available by so-dimethyl tetradecyl amine with hydrogen peroxide solution at 50 ℃ ~ 80 ℃ obtained by reacting ※ 1, the active ingredient is 25 mass% ※ 2
‧十六烷基二甲基氧化胺：可藉由使二甲基十六烷基胺與過氧化氫溶液於50℃~80℃下反應而獲得※1，有效成分為15.5質量%※2 ‧ Cetyl dimethyl amine oxide: It can be obtained by reacting dimethyl hexadecylamine with hydrogen peroxide solution at 50 ° C to 80 ° C to obtain *1 , and the active ingredient is 15.5 mass% *2
‧十八烷基二甲基氧化胺：可藉由使二甲基十八烷基胺與過氧化氫溶液於50℃~80℃下反應而獲得※1，有效成分為6.8質量%※2 ‧ Octadecyl dimethyl amine oxide: It can be obtained by reacting dimethyl octadecylamine with a hydrogen peroxide solution at 50 ° C to 80 ° C to obtain *1 , and the active ingredient is 6.8 mass% *2
‧肉豆蔻酸：Lunac MY-98，花王股份有限公司製造‧Myristic acid: Lunac MY-98, manufactured by Kao Co., Ltd.
‧月桂酸：Lunac L-98，花王股份有限公司製造‧ Lauric acid: Lunac L-98, manufactured by Kao Co., Ltd.
‧椰子油脂肪酸：Lunac L-55，花王股份有限公司製造‧Coconut oil fatty acid: Lunac L-55, manufactured by Kao Co., Ltd.
‧癸酸：Lunac 10-98，花王股份有限公司製造‧Citrate: Lunac 10-98, manufactured by Kao Co., Ltd.
‧烷基苯磺酸鈉：Neopelex G-15，花王股份有限公司製造，有效成分為16質量%※2 ‧Sodium alkylbenzene sulfonate: Neopelex G-15, manufactured by Kao Co., Ltd., with an active ingredient of 16% by mass *2
‧聚氧乙烯醚乙酸鈉：Kao-Akypo RLM-100NV，花王股份有限公司製造，有效成分為23.5質量%※2 ‧Sodium polyoxyethylene ether acetate: Kao-Akypo RLM-100NV, manufactured by Kao Co., Ltd., active ingredient is 23.5% by mass *2
‧氫氧化鉀：液體苛性鉀(48質量%)，Asahi Glass股份有限公司製造‧ Potassium Hydroxide: Liquid Caustic Potassium (48% by mass), manufactured by Asahi Glass Co., Ltd.
‧氫氧化鈉：氫氧化鈉(48質量%)，Tosoh股份有限公司製造※1 藉由日本專利特開昭57-54160記載之製造方法(即，於具有一個以上羥基之多元酸(檸檬酸)或其鹽之存在下進行脂肪族三級胺與過氧化氫水溶液之反應的方法)而製造‧Sodium hydroxide: sodium hydroxide (48% by mass), manufactured by Tosoh Co., Ltd. *1 The manufacturing method described in Japanese Patent Laid-Open Publication No. SHO 57-54160 (i.e., polybasic acid (citric acid) having one or more hydroxyl groups) Manufactured by the method of reacting an aliphatic tertiary amine with an aqueous hydrogen peroxide solution in the presence of a salt thereof
※2 表1、2之調配組成係記載實質濃度*2 The composition of Tables 1 and 2 describes the actual concentration.
‧表中之「(b)成分/(c)成分之質量比」表示(b)成分之含量/(c)成分之含量的質量比。‧ "The mass ratio of component (b) / component (c)" in the table indicates the mass ratio of the content of component (b) / the content of component (c).
‧表中之「(c1)成分/(b2)成分之質量比」表示(c1)成分之含量/(b2)成分之含量的質量比。‧ The "mass ratio of (c1) component / (b2) component" in the table indicates the mass ratio of the content of the component (c1) / the content of the component (b2).
‧表中之「(b1)成分/[(b1)成分+(c1)成分]的質量比」表示(b1)成分之含量/[(b1)成分之含量+(c1)成分之含量]的質量比。‧ The mass ratio of (b1) component / [(b1) component + (c1) component] in the table indicates the mass of the component (b1) / the content of [(b1) component + the content of (c1) component] ratio.
‧表中之「(a)成分/[(b)成分+(c)成分]的質量比」表示(a)成分之含量/[(b)成分之含量+(c)成分之含量]的質量比。‧In the table, "mass ratio of (a) component / [(b) component + (c) component]" indicates the mass of (a) component / [(b) component + (c) component] ratio.
製備表3所示之液體清潔劑組合物，進行以下試驗。將結果一併示於表3。The liquid detergent composition shown in Table 3 was prepared and subjected to the following test. The results are shown together in Table 3.
對於表3記載之液體清潔劑組合物，以與上述(4)黏度特性試驗相同之條件測定20℃下之黏度。With respect to the liquid detergent composition described in Table 3, the viscosity at 20 ° C was measured under the same conditions as in the above (4) viscosity characteristic test.
將表3記載之液體清潔劑組合物於-5℃環境下保存3天，將於-5℃下為透明之液體設為合格(○)。The liquid detergent composition described in Table 3 was stored in an environment of -5 ° C for 3 days, and a liquid which was transparent at -5 ° C was set as a pass (○).
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| CN105861178A (en) * | 2015-12-18 | 2016-08-17 | 内蒙古河西航天科技发展有限公司 | Neutral foam cleaning agent |
| JP2018203853A (en) * | 2017-06-02 | 2018-12-27 | 花王株式会社 | Liquid detergent composition for hard surface |
| JP7064743B2 (en) * | 2017-12-27 | 2022-05-11 | 株式会社ニイタカ | Effervescent detergent composition |
| JP7122921B2 (en) * | 2018-09-25 | 2022-08-22 | 株式会社Adeka | LIQUID ALKALINE DETERGENT COMPOSITION AND CLEANING METHOD |
| JP2019073732A (en) * | 2019-01-23 | 2019-05-16 | 花王株式会社 | Method for cleaning food processing equipment and/or cooking equipment |
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