TWI332405B - Cosmetic composition - Google Patents

Description

1332405 A7 B7 五、發明説明（ 發明說明 技術領域 本發明係關一種化粧組合物適用授予亮麗天然肉色而產 生透明感。 背景技術 作為化粧組合物之色料，以往曾用無機顏料如氧化鐵顏 色，普魯士藍，群青藍及氧化鉻，與有機顏料如紅色2〇1 號，黃色401號藍色1號及綠色3號。此等習用色料任一種 摻進化粧品，尤其色料摻入大量作肉色著色用時所得化粧 組合物產生陰暗塗飾由於色料的光散射而無透明感。 因此為實現明亮潤飾曾進行摻混一種有珍珠光澤之珠光 顏料，經低折射率物質以高折射率物質塗覆而得，諸如鈥 酸雲母。當有珍珠光澤的珠光顏料已摻入一含著色顏料之 化粧組合物時若所摻珠光顏料量少則無法獲得充分效應， 由於珠光顏料的折射干涉光被色料吸收或散射。另一方 面’當珠光顏料量增加至能實際感覺其對潤飾上具賦予亮 度效果之程度時觀察折射干涉光的角度與觀察無折射干涉 光之角度間亮度差異有時會變大而結果不自然的潤飾產生 閃耀感。 因此，曾經建議著色的鈦酸雲母以色料直接塗覆鈦酸雲 母防止光被色料吸收或散射（日本公開專利申請案 81334/1996與16918/2000號）。日本公開專利申請案 81334/1996號揭示對掩蔽紅色膚色有補色之著色鈦酸雲 母’而曰本公開專利申請案16918/2000透露用較少量丨_ j 5 本紙張尺度適用中國國家標準(CNS) A4規格(2l〇X297公爱) 1332405 A7 B7 五、發明説明 “直徑粒子的磨細雲母色料替代—藍色顏料以掩蔽膚 色用此項著色（鈦酸雲母作化粒品著色劑將所製化粒組 合物塗敷於全面的廣範圍時—正對觀察者部分與另一部分 間的色度不同，因為色料之顏色與由欽酸雲母衍生的折射 干涉光色互異，以致化粧易變不自•然塗飾。為製備化粒組 ，物的色彩利用有色鈇酸雲料肉色，必須額外充分撐合 氧化鐵顏料’二氧化鈇，或鈦酸雲母之類。因此不足以達 到產生透明感的亮麗天然潤飾。 本發明I目的在製備一種化粧組合物，能授予亮麗天然 的潤飾產生透明感。 發明之表現 本發明人已發現當化粧組合物摻併黃紅二色的片狀色料 由塗覆片狀粉末作底質以各不相同折射率之粉末塗覆並另 以一種著色劑復蓋已塗的片狀粉末獲得者塗敷於皮膚時達 成產生透明感之亮麗天然潤飾。 本發明提供一種化粧組合物，含二片狀色料，得自有折 射率低於2.0的片狀粉末表面塗覆有至少折射率2 〇之粉， 並再以一著色劑塗覆此已塗覆的片狀粉末，其中片狀色料 之一的表面（可見）色料在Munsell編號系統内有色調自1 0P 至5YR以下’而其他外表色則有5yr至i〇GY之色調。 完成本發明的最佳模式 根據本發明化粧組合物中所用片狀色料之一係一紅色顏 料其表面色彩有色調自1 〇P至5 YR以下，較佳自2.5RP至 2.5YR，特佳在Munsell編號系統内自10RP至1 〇R。另一 -5- 本纸張尺度適用中國國家標竿(CNS) A4規格(210 X 297公釐)1332405 A7 B7 V. INSTRUCTION DESCRIPTION OF THE INVENTION (Technical Field of the Invention) The present invention relates to a cosmetic composition which is suitable for imparting a translucent natural flesh color to produce a translucent feeling. BACKGROUND ART As a coloring material for a cosmetic composition, an inorganic pigment such as an iron oxide color has been used in the past. Prussian blue, ultramarine blue and chrome oxide, and organic pigments such as red 2〇1, yellow 401 blue 1 and green 3. Any of these conventional colors are incorporated into cosmetics, especially the color is mixed with a large amount of flesh The cosmetic composition obtained by coloring produces a dark finish which is not transparent due to light scattering of the colorant. Therefore, in order to achieve bright retouching, a pearlescent pearlescent pigment is blended, and a low refractive index material is coated with a high refractive index substance. However, such as citric acid mica. When a pearlescent pearlescent pigment has been incorporated into a cosmetic composition containing a coloring pigment, a sufficient effect cannot be obtained if the amount of the pearlescent pigment incorporated is small, since the refractive interference of the pearlescent pigment is colored by the coloring material. Absorbing or scattering. On the other hand 'when the amount of pearlescent pigment is increased to the extent that it can actually feel the effect of giving brightness to the finish Observing the angle of the refracted interference light and observing the angle of the non-refracting interference light, the difference in brightness sometimes becomes large and the result is unnaturally retouched to produce a sparkle. Therefore, it has been suggested that the pigmented titanate mica is directly coated with titanic acid mica. The light is prevented from being absorbed or scattered by the coloring material (Japanese Laid-Open Patent Application No. 81-334/1996 and No. 169/2000). Japanese Laid-Open Patent Application No. 81-334/1996 discloses a colored titanic mica which is complementary to the red skin color. Patent application 16918/2000 reveals a smaller amount of 丨_ j 5 This paper scale applies to China National Standard (CNS) A4 specification (2l〇X297 public) 1332405 A7 B7 V. Invention Description “Diamond particles of fine mica pigment Instead of blue pigment to mask the skin color with this coloring (titanic acid mica granule colorant to apply the granulated composition to a wide range - the chromaticity between the viewer part and the other part) Different, because the color of the color material is different from the refractive interference light color derived from the mastic acid mica, so that the makeup is not easily decorated. For the preparation of the chemical group, the color of the object utilizes the colored tannin cloud. It is required to additionally support the iron oxide pigment 'cerium oxide, or titanic acid mica, etc.. Therefore, it is not enough to achieve a bright natural retouching which produces a transparent feeling. The object of the present invention is to prepare a cosmetic composition which can be given a bright natural The retouching of the invention produces a feeling of transparency. The present inventors have found that when the cosmetic composition is blended with a yellow-red two-color flake color, the coated flake powder is used as a substrate to coat the powders of different refractive indices and The present invention provides a cosmetic composition comprising a two-component coloring material having a refractive index lower than that obtained by applying a coloring agent to the coated sheet-like powder to obtain a transparent feeling when applied to the skin. The surface of the flaky powder of 2.0 is coated with a powder having a refractive index of at least 2 Å, and the coated flaky powder is coated with a colorant, wherein the surface (visible) color of one of the flaky pigments is in Munsell The numbering system has a hue from 10P to below 5YR, while other exterior colors have a color range of 5yr to i〇GY. BEST MODE FOR CARRYING OUT THE INVENTION One of the flakes used in the cosmetic composition according to the present invention is a red pigment having a surface color having a hue of from below 1 〇P to less than 5 YR, preferably from 2.5 RP to 2.5 YR. From 10RP to 1 〇R in the Munsell numbering system. Another -5- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm)

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線 1332405 A7 - ______B7 五、發明説明（3 ) 片狀色料為黃色顏料其表面色彩在Munseu編號系統中有色 調至5YR至10GY ’較佳自7.5YK至10YR，特佳自i〇YR 至 7.5Y » 作片狀色料基的片狀粉末之折射率低於2 〇，較小於 1.8。此項片狀粉末例包括雲母、絹雲母、滑石、片鋁氧 粉、片矽石、片硫酸鋇等，以雲母為特佳，因其透明度高 且不散射反射的干涉光。 用以塗覆此項片狀粉末之粉（後文指&quot;塗粉&quot;）的折射率至 少為2.0，較佳至少2.2。此等塗粉可單獨或混合使用。其 實例包括二氧化鈦、氧化鋅、黃色氧化鐵、紅色氧化鐵、 黑色氧化鐵及氧化鉻等。最少宜含二氧化鈦，因能提高塗 粉之折射率而無損於所得片狀著色顏料。 構成片狀色料基底的片狀粉末可用一種金屬氧化物如氧 化鐵、氧化鋁或氧化錫，一種金屬氫氧化物如氫氧化鐵或 氫氧化鋁，一種金屬如金、銀或鋁，或一種鹽如無機鹽或 有機鹽以控制由塗粉形成的塗層之光學層厚及/或結晶 式。 塗覆的片狀粉末表面進一步以一著色劑塗覆，例如在 &quot;Saishin Keshohin Kagaku(.最新化粧科學）〈修訂擴增版 2&gt;”（日本化粧品工程學會編Yakuju Nipp〇sha出版）33〇_387 頁内說明，諸如黃色氧化鐵、紅色氧化鐵、黑色氧化鐵、 普魯士藍、氧化鉻、焦油顏料或天然顏料。 特別宜用無機著色劑如氧化鐵、氧化鉻或普魯士藍，因 所得化粧組合物對溶解於水、油等類抗性優越且甚少褪 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公楚:) 1332405Line 1332405 A7 - ______B7 V. Description of invention (3) The flake color is a yellow pigment whose surface color has a hue in the Munseu numbering system to 5YR to 10GY 'better from 7.5YK to 10YR, especially from i〇YR to 7.5 Y » The flake-like powder of the flake-like color base has a refractive index of less than 2 〇 and less than 1.8. Examples of the flake powder include mica, sericite, talc, aluminous powder, celite, and barium sulphate. Mica is particularly preferred because of its high transparency and non-scattering reflected interference light. The powder for coating the flake powder (hereinafter referred to as &quot;coating powder&quot;) has a refractive index of at least 2.0, preferably at least 2.2. These powders can be used singly or in combination. Examples thereof include titanium oxide, zinc oxide, yellow iron oxide, red iron oxide, black iron oxide, and chromium oxide. At least titanium dioxide is preferably contained because it can increase the refractive index of the powder without impairing the obtained flake coloring pigment. The flake powder constituting the sheet-like coloring material base may be a metal oxide such as iron oxide, aluminum oxide or tin oxide, a metal hydroxide such as iron hydroxide or aluminum hydroxide, a metal such as gold, silver or aluminum, or a kind Salts such as inorganic or organic salts are used to control the optical layer thickness and/or crystalline form of the coating formed from the powder coating. The surface of the coated flake powder is further coated with a coloring agent, for example, in &quot;Saishin Keshohin Kagaku (. Latest Cosmetic Science) <Revised Amplified Edition 2&gt; (published by Yakuju Nipp〇sha, Japan Cosmetic Engineering Society) 33〇 Page _387, such as yellow iron oxide, red iron oxide, black iron oxide, Prussian blue, chromium oxide, tar pigment or natural pigment. Inorganic colorants such as iron oxide, chromium oxide or Prussian blue are especially suitable. The composition is excellent in resistance to water, oil and the like and is rarely used in the paper. The Chinese National Standard (CNS) A4 specification (210 X 297 public Chu:) 1332405

色。 舉例’在Munsell編號系統中有色調自j 〇p至5 YR以下之 紅色片狀色料的著色劑較佳含—無機紅色顏料，特別紅色 氧化鐵，因能製得天然肉色。另一方面，在Μ_編號系 ，·先中有色調自5 YR至1 〇 GY之黃色片狀色料的著色劑宜含 一無機黃色顏料，特別黃色氧化鐵。 塗層片狀粉末以此等著色劑塗覆方法的實例包括經化學 反應附加法與用機械衝擊力物理連接法。 著色劑塗覆量此片狀色料重量基計宜為i至2 〇 %，因達 到充分著色能力，反射的干涉光並未減弱。 本發明所用以二片狀色顏料中至少其一項内當片狀色料 在黑白二色人造皮革上以〇5 g/m2塗層重量塗覆對黑日人 造皮革間宜有色度差(C、k，‘眞.(咖)=c、k_c、h)， 二表面在45。入射光角度與_45°接受光角度經比色測定為 -10.0至10.0’特別_5.0至5.0，當片狀色料在白色人造皮上 以0.5 g/m2塗層重量塗覆時白色人造皮之色度（c*〇w)，及其 表面於45°入射光角度與〇〇接受光角度經比色測定為至少 10.0特別至少15.0。 當色度差（Bk-wt〇低落到-10.0至10_0範圍内時靠所塗介 質可見光反射的塗色變化漸小。另一方面當色度為至 少10.0時則展現更充分塗覆效應。因此宜用此種片狀色 料。 色度差（Bk-Wh)係根據以下方法測定。 在黑白一人造皮上均勻塗覆一有色的鈥酸鹽化雲母試樣 -7- 本纸張尺度適用中國國家標準(CNS) A4规格(210X297公釐)color. For example, in the Munsell numbering system, the coloring agent having a red flake color tone ranging from j 〇p to 5 YR or less preferably contains an inorganic red pigment, particularly red iron oxide, since a natural flesh color can be obtained. On the other hand, in the Μ_numbering system, the coloring agent having a yellow flake coloring material having a hue from 5 YR to 1 〇 GY preferably contains an inorganic yellow pigment, particularly yellow iron oxide. Examples of the coated sheet-like powder coating method by such a coloring agent include a chemical reaction addition method and a physical connection method by mechanical impact. The amount of the colorant applied is preferably from i to 2% by weight based on the weight of the flakes, and the reflected interference light is not weakened by the sufficient coloring ability. In at least one of the two-piece color pigments used in the present invention, when the sheet-like color material is coated on the black-and-white two-color artificial leather with a coating weight of 〇5 g/m2, it is preferable to have a color difference between the black artificial leathers (C). , k, '眞. (咖) = c, k_c, h), the two surfaces are at 45. The incident light angle and the _45° acceptance light angle were determined by colorimetric measurement to be -10.0 to 10.0', especially _5.0 to 5.0, when the flake color material was coated on a white artificial leather with a coating weight of 0.5 g/m2, white artificial leather. The chromaticity (c*〇w), and its surface at 45° incident light angle and 〇〇 received light angle are determined by colorimetric determination to be at least 10.0, especially at least 15.0. When the chromaticity is poor (Bk-wt〇 is lowered to the range of -10.0 to 10_0, the color change of the visible light reflected by the applied medium is gradually reduced. On the other hand, when the chromaticity is at least 10.0, a more sufficient coating effect is exhibited. This kind of flake coloring material should be used. The chromaticity difference (Bk-Wh) is determined according to the following method: Uniform coating of a colored bismuth mica sample on black and white artificial leather - 7 - This paper size is applicable China National Standard (CNS) A4 specification (210X297 mm)

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1332405 年7月2?日修(東)正替換頁 第091113361號專利申請案 中文說明書替換頁(99年7月' 五、發明説明（ 至達0.5 g/rn2塗層重量於入射光角度及接受光角度各別為 ’、45時藉一比色計（例如Murakami Shikisai化學研究 所製測角分光光度計（GCMS-3)測定CIE 1976 L*a*b*色距 内之色度座輮L a b*。隨後根據公式c* = (a*2 + b*2)1/2算 出每一色度。此時假如用黑色人造皮的色度為c*(Bk)及用白 k 皮之色度為 C (Wh)，其差 c (Bk)-(2 (Wh)即 AC (&amp;k_Wh)。 此處所用黑白色人造皮等其黑色人造皮内當於45。入射角 光及0。接受角光進行比色測定時其中厂為“至以，，係 -5至5 ’而b為·5至5，其白色人造皮内l*為90至95，a* 係-5至5，而b *係〇至1 〇。 每一片狀色料内又宜△(:·…至2〇 〇為 佳，色度C%5B係由以片狀色料均勻塗覆一黑色人造皮測 定’使其於入射角45。與接受光·45〇角的比色測定及色度 c 〇Β係於接受光0 °角測定’色度差以〇至丨5 〇為特佳。此一 色差AC (“—ο)較佳乃因表面反射光靠塗層上角度之色度變 化較小。 作為片狀色料宜用一種將以有光學層厚14〇至240 nm的二 氧化鈦層塗覆之鈦酸鹽化雲母表面以黃色氧化鐵塗覆所得的 顏料’將以有光學層厚220至320 nm之二氧化鈦層塗覆的鈦 酸鹽化雲母表面以紅色氧化鐵塗覆所得之顏料及將以有光學 層厚290至390 nm的二氧化鈦層塗覆之鈦酸鹽化雲母.表面以 普魯士藍塗覆所得的顏料’因為當每一片狀色料在黑色二種 人造皮上以塗層重量0.5 g/m2塗覆時於4 5。入射光角度與-45° 接受光角度測得之色度（c\k，c*Wh)差（△c'mhfC.Bk· 79085-990727.doc 本紙張尺度適用中國國家標準(CNS) A4規格(210X 297公着) 1332405 第091113361號專利申請案 f；；—---------1 中文說明書替換頁(99年7月) gf年*7月4日修(¾正替換頁 五、發明説明（6 ) C wh)變小。 構成此等有色欽酸鹽化雲母基礎的欽酸鹽化雲母能根據 眾所咸知之多種方法製備。舉例，能根據一種方法製備， 其中一無機鈦鹽如硫酸氧鈦或四氣化鈦於雲母存在下經中 和法或水解法分解析出無水氮氧化欽或二氧化欽，殿積物 隨後於500至l〇〇(TC，較佳7〇〇至9〇(rc在空氣中烺燒（曰本 專利25644/1968號公佈）。 此處所用雲母實例包括白雲母、黑雲母、金雲母與合成 雲母等。 、。 供製作有色鈦酸鹽化雲母的色料之始材料可用一無機與 有機鐵化合物如氯化鐵（11)、氣化鐵（ΠΙ)、硫酸鐵（ιι)、 硫酸鐵（in)、硝酸鐵（u)、硝酸鐵（ΙΠ)、草酸鐵、草 酸銨鐵（III)、硫酸銨鐵（ΙΠ)、磷酸鐵（ΙΠ)、擰檬酸鐵 (ΠΙ)、乳酸鐵（II )或富馬酸鐵的水溶液。添加欽酸鹽化雲 母於此無機或有機鐵化合物之水溶液，加熱此混合物使澱 積鐵化合物的水解產物後水洗澱積並乾燥之遂得有色的鈦 酸鹽化雲母。無機或有機鐵化合物的水液内添加鐵酸鹽化 雲母之前或後亦可加鹼如氫氧化鈉、氫氧化鉀、氨或胺或 其鹼的水溶液以控制水解程.度。 舉例，為製備黃色氧化鐵塗覆之鈦酸鹽化雲母，可將一 有光學層厚度140至240 nm的二氧化鈦層塗覆之欽酸鹽雲 母加入此無機或有機鐵化合物的水溶液，加熱混合物至5〇 至100°C，較佳80 °C以上水解此鐵化合物，黃色氧化鐵於 疋殿積在欽酸鹽化雲母表面上’水洗此殿積物，溏過後於 79085-990727.doc _ 9 _ I纸法尺度適财目g家料(CNS) A4規格(21GX297公釐) 1332405 A7 B7 五、發明説明（7 ) 1 5 0 t以下乾燥即得。 有此光學層厚之二氧化鈦層能藉控制鈦鹽濃度、鈦睡的 水解溫度、鈦鹽之水解時間、塗覆二氧化鈦的雲母之表面 處理等以眾所週知的鈦酸鹽化雲母製法形成。 紅色氧化鐵塗覆之鈦酸鹽化雲母能用有光學層厚至 320 nm二氧化鈦層塗覆的鈦酸鹽化雲母根據上述方法澱積 氧化鐵製備。水洗澱積物，乾燥後於15〇它以上烺燒，較 佳400 °C以上。 λ 普魯士藍塗覆之鈦酸鹽化雲母能用亞鐵氰化鈉與硫酸鐵 (Π)的水溶液供鈦酸鹽化雲母塗覆以有光學層厚29〇至 nm&lt;二氧化鈦層。鈦酸鹽化雲母加進亞鐵氰化鈉與硫酸鐵 (11)的水溶液後加硫酸銨，所得混合物在酸性條件以硫酸 熟化並以氯酸鈉氧化，逐澱積普魯士藍於鈦酸鹽化雲母之 表面上。水洗此產物，過濾後乾燥，逐製成普魯士藍塗覆 的鈥酸鹽化雲石。 .著色劑之塗覆率以所塗鈦酸鹽化雲母的重量基計較佳為 1至2 0 %。塗覆率在此範圍内時反射之干涉光並未減弱， 而得充分著色力。反射干涉光的強度宜能使著色之鈦酸鹽 化雲母均勻塗覆在黑色人造皮上用比色計以4 5 〇入射光角 度與- 45。接受光角度測得CIE 1976 l/，b·色距内著色度 座&amp; L致得塗覆重量〇·5 g/m2者至少為30.0。當片狀色料 於白色人造皮上塗覆至塗料重0·5 g/m2時以45。入射光角與 〇°接受光角所測色度（C*0w)係至少1〇.〇之著色力為佳。 本發明内所用片狀色料亦可進一步接受一種疏水性授予 -10- 本紙張尺度適用中國國家標準(CNS) A4規格(21〇χ 297公釐） 1332405 第091113361號專利申請案 中文說明書替換頁(99年7月） ί Γ年7月巧日修(走)正替換頁 五、發明説明（8 ) 處理。所用疏水性授予劑的實例包括秒酮油、脂肪酸之金 屬鹽類、填酸烧醋、磷酸燒酉旨的驗金屬鹽或胺鹽類、N-單 長鏈(Cs_22)脂族醯化鹼性胺基酸類及有—全氟烷基之氟化 合物。 每一片狀色料的平均粒子直徑宜為，特別2· 3—觀點在防止可見光免被散射由於事實上色彩變陰 暗而減弱透明感，且因大量表面反射光而使用者無閃耀 感。平均粒子直徑係用H()ribaLtd製雷射散射粒子大小分 佈分析計LA-920及乙醇作分散介質測得。 片狀色料摻人化粧組合物之量為色.調自iGp至5yr以下 及色調自5YRM〇GY的二種片狀色料之總重為5_5〇重量 %，較佳為10-30重量％。二種片狀色料間摻混比率並無 強迫特別限制。不過摻混方式宜使所得化链組合物之色調 在Munsen編號系統自2.5尺至1〇丫範圍内，其亮度至少為 3.0以便獲得明亮肉色。 … 根據本發明的化粧組合物内正統化粧組合物中可適當摻 併作其他組份，通用組份舉例如界面活化劑、聚合物二油 類、其他粉類、潤濕劑、防腐劑、具藥效之組份、紫外線 吸收劑、抗氧劑、無機或有機鹽類、香料基、螯合劑、pH 調整劑及水等。 根據本發明化粧組合物的實例包括粉底、面粉、隱蔽 劑、胭脂、眼影與眉毛。作為一種化粧組合物易於發^對 整谷效應產生透明感並有明亮肉色、粉底、面粉與隱蔽劑 為佳’以粉底為特別可取。 79085-990727.doc 本紙浪尺度適用巾@ g家料(CNS) Μ規格(21QX297公$ 11 - 1332405 五、發明説明（9 實例 本發明内外觀色彩之測量係藉比色計（曰本Denshoku K.K.製SQ-300H)用一試樣裝滿一金屬盤，在一能受壓模的 測試物質内’或填裝試樣於一不能加壓模塑之試驗物質或 一液態試驗物質内液體/分末用小管中進行。 色度係藉一測角光度分光儀GCMS-3 (Murakami Shikisai 化學研究所製造）。 平均粒子直徑係藉一雷射散射粒子大小分佈分析計La-920 (Horiba Ltd, 製造） 藉試 驗物質 分散在 乙醇内 測得。 製備實例1 : (1 )加雲母（重量比7 5份）於經離子交換之水（500份重 量）’攪拌混合物成均勻分散液。將3 0 %重量比濃度的硫 酸氧鈥水溶液（重量比250份）加進分散液。加熱並携拌所 得混合物煮沸4小時。任反應混合物冷却後濾過，水洗， 於950 °C烺燒得雲母（鈦酸鹽化雲母；二氧化鈦光學層厚 度：190 nm ;重量比1〇〇份），塗覆有二氧化鈦。 (2)分別溶解硫酸鐵（ΠΙ)η_水合物（重量比6〇份）於 2000份重量之離子交換水中，以〇1 m〇1/L氫氧化鈉水液 調整至pH 2,8’將等（1)步所製的鈥酸鹽化雲母（重量 比1 0 0份）加入此水液，充分攪拌混合物使水液均勻分 散鈦酸鹽化雲母。 (3 )攪拌中加熱鈦酸鹽化雲母分散液，煮沸6小時。 任分散液冷却後過濾水洗’得以黃色氧化鐵塗覆之黃 色鈦酸鹽化雲母（A-1)(重量比1〇3份）。黃色鈦酸鹽化= -12- 本纸張尺度適用中國國家標準(CNS&gt; A4規格(210X 297公釐)July 2, 2, 405, 405 (National) Replacement Page No. 091113361 Patent Application Replacement Page (July 99, '5, Invention Description (up to 0.5 g/rn2 coating weight at incident light angle and acceptance) The light angles are ', 45, and a colorimeter is used (for example, the Murakami Shikisai Institute of Chemistry Institute of Angle Spectrophotometer (GCMS-3) determines the CIE 1976 L*a*b* color chromaticity coordinates 輮L Ab*. Then calculate each chromaticity according to the formula c* = (a*2 + b*2) 1/2. If the chromaticity of the black artificial leather is c*(Bk) and the chromaticity of the white k skin For C (Wh), the difference c (Bk) - (2 (Wh) is AC (&amp; k_Wh). The black and white artificial leather used here is in black artificial leather, which is 45. Incident angle light and 0. Accept When the angle light is colorimetric, the factory is "to, to, -5 to 5' and b is ·5 to 5, and its white artificial leather has l* of 90 to 95, a* is -5 to 5, and b * 〇 to 1 〇. It is better to use △ (: · ... to 2 每一 in each flaky color, and the chromaticity C% 5B is determined by uniformly coating a black artificial leather with a sheet-like coloring material' Make it at an incident angle of 45. Colorimetric and chromaticity c with the angle of acceptance of light·45〇 It is particularly preferable to measure the chromaticity difference from 接受 to 丨5 接受 at a light angle of 0 °. This color difference AC ("- ο) is preferred because the surface reflection light has a small change in the chromaticity of the angle on the coating. As the flake coloring material, it is preferable to use a titanated mica surface coated with a titanium oxide layer having an optical layer thickness of 14 to 240 nm to coat the pigment with yellow iron oxide, which will have an optical layer thickness of 220 to 320. The surface of the titanate-coated mica coated with nm is coated with red iron oxide and the titanated mica coated with a layer of titanium dioxide having an optical layer thickness of 290 to 390 nm. The surface is coated with Prussian blue. The resulting pigment 'because when each flake color is coated on the black two kinds of artificial leather at a coating weight of 0.5 g/m 2 at 45. The angle of incident light and the chromaticity measured at -45° receiving light angle (c\k, c*Wh) difference (△c'mhfC.Bk. 79085-990727.doc This paper scale applies to China National Standard (CNS) A4 specification (210X 297 public) 1332405 Patent No. 091113361; ;----------1 Chinese manual replacement page (July 99) gf year * July 4th repair (3⁄4 is replacing page five, invention said (6) C wh) becomes smaller. The acidified mica constituting the base of these colored dibasic mica can be prepared according to various methods known to the public. For example, it can be prepared according to a method in which an inorganic titanium salt such as sulfuric acid is used. Oxygen-titanium or tetra-titanized titanium is analyzed by neutralization or hydrolysis in the presence of mica to separate anhydrous nitrogen oxides or dioxins, and the temples are then subjected to 500 to 1 〇〇 (TC, preferably 7 to 9). 〇 (rc is burnt in the air (promulgated by this patent 25644/1968). Examples of mica used herein include muscovite, biotite, phlogopite and synthetic mica. ,. The starting material for the coloring titanated mica can be an inorganic and organic iron compound such as ferric chloride (11), iron (iron), iron sulfate (I), iron (in), iron nitrate (u), ferric nitrate (iron), iron oxalate, ammonium oxalate (III), ammonium iron sulfate (strontium), iron phosphate (strontium), iron citrate (iron), iron (II) lactate or fumaric acid An aqueous solution of iron. The acidified mica is added to the aqueous solution of the inorganic or organic iron compound, and the mixture is heated to deposit a hydrolyzate of the iron compound, followed by water-washing and drying to obtain colored titanated mica. The addition of ferrite to the aqueous solution of the inorganic or organic iron compound may also be followed by an aqueous solution of a base such as sodium hydroxide, potassium hydroxide, ammonia or an amine or a base thereof to control the degree of hydrolysis. For example, to prepare yellow iron oxide coated titanated mica, a titanium dioxide layer coated with a thickness of 140 to 240 nm of optical layer may be added to the aqueous solution of the inorganic or organic iron compound, and the mixture is heated to 5〇至100°C, preferably 80 °C or more hydrolyzed the iron compound, and yellow iron oxide is deposited on the surface of the dilated mica as a water-washing of the temple. After the smashing, it is at 79085-990727.doc _ 9 _ I paper method scales for financial purposes g (materials) A4 specifications (21GX297 mm) 1332405 A7 B7 V, invention description (7) 1 5 0 t or less is dry. The titanium dioxide layer having such an optical layer thickness can be formed by a well-known titanated mica method by controlling the titanium salt concentration, the hydrolysis temperature of titanium sleep, the hydrolysis time of the titanium salt, and the surface treatment of the titania-coated mica. The red iron oxide coated titanated mica can be prepared by depositing iron oxide according to the above method using titanated mica coated with an optical layer thickness of 320 nm. The deposit is washed with water, dried and then calcined above 15 Torr, preferably above 400 °C. λ Prussian blue coated titanated mica can be coated with titanated mica with an aqueous solution of sodium ferrocyanide and iron sulphate (Π) to have an optical layer thickness of 29 Å to nm &lt; The titanated mica is added with an aqueous solution of sodium ferrocyanide and iron sulfate (11), and then ammonium sulfate is added. The resulting mixture is aged under acidic conditions with sulfuric acid and oxidized with sodium chlorate to precipitate Prussian blue for titanation. On the surface of the mica. The product was washed with water, filtered and dried to give a Prussian blue coated silicate. The coating rate of the colorant is preferably from 1 to 20% by weight based on the weight of the titanated mica coated. When the coating ratio is within this range, the reflected interference light is not weakened, and sufficient coloring power is obtained. The intensity of the reflected interference light is such that the colored titanated mica is uniformly coated on the black artificial leather with a colorimeter at an incident angle of 45 与 and -45. The acceptance of the light angle of CIE 1976 l /, b · color distance within the color of the seat &amp; L to achieve a coating weight of 5 · 5 g / m2 is at least 30.0. When the flake color was applied to the white artificial leather to a coating weight of 0.5 g/m2, it was 45. The incident light angle and the chromaticity measured by the acceptance angle of the light angle (C*0w) are at least 1 〇. The flake coloring material used in the present invention can further accept a hydrophobicity grant - 10 paper scale applicable Chinese National Standard (CNS) A4 specification (21〇χ 297 mm) 1332405 No. 091113361 Patent application Chinese manual replacement page (in July, 1999) ί The following is the replacement of page 5, invention description (8). Examples of the hydrophobicity-improving agent to be used include a second ketone oil, a metal salt of a fatty acid, a sulphuric acid-filled vinegar, a metal salt or an amine salt for a phosphate burn, and an N-single long chain (Cs_22) aliphatic bismuth. Amino acids and fluorine compounds having a perfluoroalkyl group. The average particle diameter of each of the flakes is preferably, in particular, the viewpoint of preventing visible light from being scattered due to the fact that the color becomes dark and dark, and the transparency is weakened, and the user does not have a sleek feeling due to a large amount of surface reflected light. The average particle diameter was measured by a laser scattering particle size distribution analyzer LA-920 manufactured by H. riba Ltd and ethanol as a dispersion medium. The amount of the flake-form color-incorporating cosmetic composition is color. The total weight of the two flakes of coloring from iGp to 5 yr and the color tone from 5YRM〇GY is 5-5 wt%, preferably 10-30 wt%. . The blending ratio between the two flakes is not particularly limited. However, the blending means is such that the resulting chain composition has a hue of from 2.5 ft to 1 Torr in the Munsen numbering system and a brightness of at least 3.0 in order to obtain a bright flesh color. The ortho-cosmic composition in the cosmetic composition according to the present invention may be appropriately blended into other components, such as an interface activator, a polymer di-oil, other powders, a wetting agent, a preservative, and the like. A pharmaceutical ingredient, an ultraviolet absorber, an antioxidant, an inorganic or organic salt, a perfume base, a chelating agent, a pH adjuster, and water. Examples of cosmetic compositions according to the present invention include foundations, flours, concealers, blushers, eye shadows and eyebrows. As a cosmetic composition, it is easy to produce a transparent feeling to the whole grain effect and has a bright flesh color, a foundation, a flour and a concealing agent. It is particularly preferable to use a foundation. 79085-990727.doc This paper wave scale applies towel@g家料(CNS) ΜSpecifications (21QX297 public $11 - 1332405 V. Invention description (9 Example The measurement of the appearance color in the invention is by colorimeter (曰本Denshoku KK SQ-300H) Fill a metal plate with a sample, in a test material capable of being pressed, or fill the sample in a test substance that cannot be pressure molded or a liquid test substance. The chromaticity is carried out by a goniophotometer GCMS-3 (manufactured by Murakami Shikisai Chemical Research Institute). The average particle diameter is manufactured by a laser scattering particle size distribution analyzer La-920 (Horiba Ltd, manufactured). Measured by dispersing the test substance in ethanol. Preparation Example 1: (1) Add mica (weight ratio of 75 parts) in ion-exchanged water (500 parts by weight) 'stir the mixture into a uniform dispersion. 30% An aqueous solution of bismuth sulfate (weight ratio of 250 parts) was added to the dispersion, and the mixture was heated and boiled for 4 hours. The reaction mixture was cooled, filtered, washed with water, and calcined at 950 ° C to obtain mica (titanate). Mica; titanium dioxide light The thickness of the layer is 190 nm; the weight ratio is 1 part), coated with titanium dioxide. (2) Dissolving ferric sulfate (ΠΙ) η_hydrate (weight ratio of 6 parts) in 2000 parts by weight of ion-exchanged water, Add 鈥1 m〇1/L sodium hydroxide solution to pH 2, 8', add the citrate mica (weight ratio 100 parts) prepared in step (1) to the water, and stir the mixture thoroughly. The water liquid is uniformly dispersed in the titanated mica. (3) The titanated mica dispersion is heated while stirring, and boiled for 6 hours. The dispersion is cooled and then filtered and washed to obtain a yellow titanated mica coated with yellow iron oxide. (A-1) (weight ratio: 1〇3 parts). Yellow titanate = -12- This paper scale applies to Chinese national standards (CNS> A4 size (210X 297 mm)

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1332405 A7 B7 五、發明説明（1332405 A7 B7 V. Description of invention (

母（A - 1)内黃色氧化物的塗覆率為重量比6 67〇/〇，其平均 粒子直徑係8.2 y m。其外觀色在Munsell編號系統中為 4.8Y，其色彩亮度為5.5。 «色鈇酸鹽化雲母（A-1)與商品可得黃色氧化鐵塗覆之 欽酸鹽化雲母（B-l ; DUOCROME DYR 442C ， ENGELHARD CO.產品；分類入平均粒子直徑32 〇 a m ;The coating ratio of the yellow oxide in the mother (A-1) was 6 67 Å/〇, and the average particle diameter was 8.2 μm. Its appearance color is 4.8Y in the Munsell numbering system, and its color brightness is 5.5. «Citrate mica (A-1) and commercially available yellow iron oxide coated masticated mica (B-l; DUOCROME DYR 442C, ENGELHARD CO. product; classified into average particle diameter 32 〇 a m;

二氧化鈇光學層厚：270 nm)的色度值對照如表1所示β (測量方法） 裝 在一塗覆固體粉底之商品可得的特殊海綿中採樣，以〇 5 g/m2之塗料重量塗覆於一黑色人造皮（1/=22 6，」， 1/=0.1)與一白色人造皮（1/ = 91.3，&amp;*=-2，1&gt;*=6_1)上進行比 色測定。 表1 試樣 A-l B-l Δ C (Bk-Wh) -2.5 -7.0 C 〇w 19.2 6.1 △ c (45-0) 10.5 4.6 製備實例2 :The chromaticity value of the erbium dioxide optical layer thickness: 270 nm) is compared with the β (measuring method) shown in Table 1 in a special sponge available for coating a solid foundation, and the coating is 〇5 g/m2. The weight is applied to a black artificial leather (1/=22 6,", 1/=0.1) and a white artificial leather (1/= 91.3, &*=-2,1&gt;*=6_1) Determination. Table 1 Sample A-l B-l Δ C (Bk-Wh) -2.5 -7.0 C 〇w 19.2 6.1 △ c (45-0) 10.5 4.6 Preparation Example 2:

溶解硫酸鐵（III) η -水合物重量比6 〇份於離子交換水（重 量比2000份）内’用0.1 mol/L氫氧化鈉水液調整比水溶液 至pH 2.8 ’加鈦酸鹽化雲母（FLAMENCO SATIN RED 460M，ENGELHARD CO.之產品；平均粒子直徑：6.8 -13- 本紙張尺度適用中國國家標準(CMS) A4規格(210X 297公釐) 1332405 A7 B7_ 五、發明説明（„ ) ;二氧化鈦之光學層厚：260 nm ;重量比100份）於此水溶 液，並藉由充分揽伴該混合液使鈥酸鹽化雲母均勻分散。 充分攪拌加熱此鈦酸鹽化雲母分散液並煮沸6小時。任分 散液冷後濾過，水洗，及在800°C烺燒2小時而得塗覆紅色 氧化鐵之紅色鈦酸鹽化雲母（A - 2)(重量比102份）》 紅色鈦酸鹽化雲母（A - 2)中紅色氧化鐵的塗覆率為重量 比6.2 5 %，其平均粒子直徑為7.3 m。其外觀色彩在 Munsell編號系統中係6.5R，其亮度為5.3。 如同實例1，紅色鈦酸鹽化雲母（A - 2 )與商品可得之紅色 氧化鐵塗覆的鈦酸鹽化雲母（B-2 ; COLORONA RED BROWN, MERCK Co.產品；平均粒子直徑：40.5 ;二 氧化鈇之光學層厚：8 0 n m )對照的色度值表現於表2。 表2 試樣 A-2 B-2 △ c (Bk-Wh) 1.1 -13.7 C 〇w 21.5 25.3 △ C (45-0) 9.6 4.5 製備實例3 (1)溶解亞鐵氰化鈉（重量2.5份）與硫酸鐵（II)(重量1 ·2份） 在離子交換的水（重量10 0 0份）内，所得水溶液中加飲酸化 雲母（FLAMENCO SATIN BLUE 660Μ，ENGELHARD CO. 之產品；平均粒子直徑：7.5以m ;二氧化鈦光學層厚340 -14- 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐） 1332405 A7 B7Dissolved iron(III) sulfate η-hydrate weight ratio 6 parts in ion-exchanged water (weight ratio 2000 parts) 'Adjust the specific aqueous solution to pH 2.8' with 0.1 mol/L sodium hydroxide solution plus titanated mica (FLAMENCO SATIN RED 460M, product of ENGELHARD CO.; average particle diameter: 6.8 -13- This paper scale applies to Chinese National Standard (CMS) A4 specification (210X 297 mm) 1332405 A7 B7_ V. Invention description („ ); Titanium dioxide The optical layer thickness: 260 nm; weight ratio of 100 parts) of the aqueous solution, and the cerium-acidized mica is uniformly dispersed by fully mixing the mixture. The titanated mica dispersion is heated and stirred for 6 hours. The dispersion was cooled, filtered, washed with water, and calcined at 800 ° C for 2 hours to obtain red titanated mica (A - 2) coated with red iron oxide (weight ratio 102 parts). Red titanation The coating ratio of red iron oxide in mica (A-2) is 6.25% by weight, and its average particle diameter is 7.3 m. Its appearance color is 6.5R in the Munsell numbering system, and its brightness is 5.3. As in Example 1, Red titanated mica (A - 2 ) and commercially available red Color iron oxide coated titanated mica (B-2; COLORONA RED BROWN, MERCK Co. product; average particle diameter: 40.5; optical layer thickness of cerium oxide: 80 nm) Table 2. Table 2 Sample A-2 B-2 △ c (Bk-Wh) 1.1 -13.7 C 〇w 21.5 25.3 △ C (45-0) 9.6 4.5 Preparation Example 3 (1) Dissolving sodium ferrocyanide ( Weight 2.5 parts) and iron (II) sulfate (1 · 2 parts by weight) In the ion-exchanged water (weight 100 parts), the obtained aqueous solution is added with acidified mica (FLAMENCO SATIN BLUE 660Μ, ENGELHARD CO.; Average particle diameter: 7.5 in m; TiO 2 optical layer thickness 340 -14- This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) 1332405 A7 B7

五、發明説明（ nm ;重量比100份），充分攪拌混合物使其中鈦酸鹽化雲母 均勾分散。 (2)溶解硫酸銨（重量1.0份）於離子交換之水（重量50份） 與濃硫酸（重量〇.5份）的水溶液於第（丨）步所製鈦酸鹽化雲 母分散液攪拌中加入，使混合物熟化。熟化混合内添加一 氣酸納（重量0.1 5份）溶於離子交換水（重量5 0份）之水液 中’水洗所得混合物，濾後乾燥得有普魯士藍塗覆的藍色 鈇酸鹽化雲母（A-3)(重量1〇1份）。 藍色欽酸鹽化雲母（A-3)中普魯士藍之塗覆率為重量 1.95%。其平均粒子直徑為7 。其外觀色彩在Munsell編 號系統内為6.8PB，其亮度為4.7。 實例1 : 製備實例1至3所得片狀色料分別用於製品壓製粉底，根 據本質上技術已知的一種方法，有表3所示相當成份。 如此獲得之每一粉底由2 〇位化粧品專家評審小組用以根 據以下評價標準作有關&quot;產生透明感的潤飾&quot;，，，明亮修整，， ’天然肉色&quot;及甚少閃耀感π方面評估。其結果之平均值 集體顯示於表3。 (評估標準） 5點 :很好； 4點 :好； 3點 :相當好； 2點 •稍差；及 1點 :差。 -15- 本紙張尺度適用中國國家標準(CNS) Α4規格(210X297公着) 1332405 A7 B7 五、發明説明（13 表3 Component (% by 本發明產物 比較的產物 Weight) 1 2 3 2 3 4 5 6 7 滑石 20 20 20 20 20 20 20 20 20 20 絹雲母 差額 差額 差額 差额 差額 差額 差額 差額 差额 差額 球狀耐綸 5 5 5 ' 5 5 5 5 5 5 5 硬脂酸鋅 3 3 3 3 3 3 3 3 3 3 黃色鈦酸鹽化雲母 (A-1) 15 10 10 15 紅色鈦酸鹽化雲母 (Α·2) 10 5 5 10 藍色鈦酸鹽化雲母 (Α-3) 2 黃色鈦酸鹽化雲母 (Β-1) 25 25 紅色鈦酸鹽化雲母 (Β-2) 10 10 鈦酸鹽化雲母” 5 5 5 25 5 5 &lt; 二氧化鈦 3 3 10 10 10 10 3 5 黃色氧化鐵 2 2 7 7 2 7 紅色氧化鐵 0.5 2 2 2 .黑色氧化鐵 0.3 1 1 1 0,5 n c 對羥苯甲酸酯 0.5 0.5 0.5 0.5 0.5 0.5 〇 &lt; U. j 复 0.5 0.5 0.5 二甲基聚矽氧烷 5 5 5 5 5 5 5 液體石蠟 5 5 5 5 5 5 5 5 5 5 5 5 成品得透明感 4.7 4.5 4.8 - 1.8 1.6 2.2 2 1 3.5 2.9 明亮潤飾 4.8 4,5 4.7 1.5 4.5 3.6 及 .18 〜4.2 3.7 4.6 自然肉色 4.5 4.8 4.8 3.3 2.0 1.7 2.5 3 1 2.2 微感閃耀 4.3 4,7 4.6 4.9 1.2 1.9 2.1 4.6 4.7 1.5 *1 : TIMIRON MP-1005, MERCK Co·產品 本發明產品的固體粉底得到明亮天然肉声&amp; j巴凋鈽產生透明 -16-5. Description of the invention (nm; weight ratio: 100 parts), the mixture is thoroughly stirred to disperse the titanated mica. (2) Dissolving ammonium sulfate (1.0 part by weight) in an ion exchange water (50 parts by weight) and concentrated sulfuric acid (wt. 5 parts) in an aqueous solution of the titanated mica dispersion prepared in the step (丨) Add to ripen the mixture. Adding sodium sulphate (0.15 parts by weight) to the aqueous solution of ion-exchanged water (50 parts by weight) in the ripening mixture, the mixture is washed with water, and dried by filtration to obtain Prussian blue-coated blue citrate mica. (A-3) (weight 1 〇 1 part). The coating rate of Prussian blue in blue-picdated mica (A-3) was 1.95% by weight. Its average particle diameter is 7. Its exterior color is 6.8PB in the Munsell numbering system and its brightness is 4.7. Example 1: The flakes obtained in the preparation of Examples 1 to 3 were respectively used for the pressed base of the article, and according to a method known in the art, there were equivalent components shown in Table 3. Each foundation thus obtained was used by the 2 化妆品 Cosmetics Expert Review Panel to make a &quot;transparent retouching&quot;, bright finish, 'natural flesh color&quot; and very little sparkling π according to the following evaluation criteria Evaluation. The average of the results is collectively shown in Table 3. (Evaluation Criteria) 5 points: Very good; 4 points: Good; 3 points: Pretty good; 2 points • Slightly worse; and 1 point: Poor. -15- This paper scale applies to Chinese National Standard (CNS) Α4 specification (210X297 public) 1332405 A7 B7 V. Description of invention (13 Table 3 Component (% by product comparison product weight) 1 2 3 2 3 4 5 6 7 Talc 20 20 20 20 20 20 20 20 20 20 Sericite difference difference difference difference difference difference difference difference spherical nylon 5 5 5 ' 5 5 5 5 5 5 5 zinc stearate 3 3 3 3 3 3 3 3 3 3 Yellow titanated mica (A-1) 15 10 10 15 Red titanated mica (Α·2) 10 5 5 10 Blue titanated mica (Α-3) 2 Yellow titanic acid Salified mica (Β-1) 25 25 red titanated mica (Β-2) 10 10 titanated mica" 5 5 5 25 5 5 &lt; titanium dioxide 3 3 10 10 10 10 3 5 yellow iron oxide 2 2 7 7 2 7 Red iron oxide 0.5 2 2 2 . Black iron oxide 0.3 1 1 1 0,5 nc p-hydroxybenzoate 0.5 0.5 0.5 0.5 0.5 0.5 〇&lt; U. j complex 0.5 0.5 0.5 dimethyl group Oxane 5 5 5 5 5 5 5 Liquid paraffin 5 5 5 5 5 5 5 5 5 5 5 5 Finished transparency 4.7 4.5 4.8 - 1.8 1.6 2.2 2 1 3.5 2.9 Bright retouching 4.8 4,5 4.7 1.5 4.5 3.6 and .18 ～4.2 3.7 4.6 Natural flesh color 4.5 4.8 4.8 3.3 2.0 1.7 2.5 3 1 2.2 Slight sensation 4.3 4,7 4.6 4.9 1.2 1.9 2.1 4.6 4.7 1.5 * 1 : TIMIRON MP-1005, MERCK Co·Products The solid foundation of the product of the invention is obtained by bright natural meat sound &amp; j

1332405 A7 B7 五、發明説明（14 感而極少閃耀感。 另一方面’對照產品1之粉底並無閃耀感，但產生塗飾 使印象陰沉憂修缺乏透明感，由於色料散射可見光。 含鈦酸鹽化雲母的對照產品2獲得明亮潤飾，但因產生 不自然光澤感之閃耀塗飾而使皮膚紋理大發光芒。 對照產物3與4含一種商品可得的有色鈦酸鹽化雲母者甚 少閃耀度，但與發明製品丨至3比較則缺乏”產生透明感之 潤飾明亮修整，，及&quot;天然肉色&quot;，乃因可見光為色料散 對照產物5與6僅含一 母者在肉色上不自然， 干涉光之色彩。 種根據製備實例的有色鈦酸鹽化雲 由於有色鈦酸鹽化雲母中固有反射 對照產物用二種商品可得的有色妖酸鹽化雲 捧併大量有色鈦酸鹽化之雲母以製備肉色獲得”明亮潤飾 ’但與發明製品I至3相比則因非天然閃耀度以致 生透明感的潤飾”及，，天然肉色”。 實例2 :(乳脂狀粉底） (配方） (重量％) 5.5 2.5 1.0 3.0 7.0 8.01332405 A7 B7 V. Invention description (14 feelings rarely shine. On the other hand, 'the foundation of the control product 1 has no sparkle, but the finish is made to make the impression gloomy and lack of transparency, because the color material scatters visible light. The control product 2 of the salted mica obtained a bright finish, but the skin texture was greatly radiant due to the shine of the unnatural luster. The control products 3 and 4 contained a commercially available colored titanated mica with little brilliance. However, compared with the invented product 丨3, there is a lack of “transparent retouching, and &quot;natural flesh color&quot;, because visible light is a color shift control product 5 and 6 containing only one mother in the flesh color. Naturally, the color of the interference light. The colored titanated cloud according to the preparation example, due to the intrinsic reflection control product in the colored titanated mica, is obtained by two kinds of commercially available colored deuterated cloud and a large amount of colored titanate The mica is made into a "bright finish" for the preparation of flesh color, but it is a natural flesh-colored finish due to the non-natural brilliance compared with the inventive articles I to 3." 2 : (creamy foundation) (formulation) (% by weight) 5.5 2.5 1.0 3.0 7.0 8.0

硬脂酸 親脂性甘油基單硬脂酸酯 鯨蠟硬脂醇 單月桂基丙二醇 三十碳五埽 橄欖油 -17- 本紙張尺度適用中g國家標準(CNS) Α4規格⑽父撕公宠） 1332405 A7 __ B7 五、發明説明（15 ) 對羥苯甲酸酯 〇2 三乙醇胺 1&gt;2Stearic acid lipophilic glyceryl monostearate cetearyl alcohol monolauryl propylene glycol thirty carbon five quinone olive oil -17- This paper scale applies to the national standard (CNS) Α 4 specifications (10) father tears the public pet) 1332405 A7 __ B7 V. INSTRUCTIONS (15) Paraben 〇2 Triethanolamine 1&gt;2

Sorbit 3.0 一乳化鈥2經授予疏水性處理 10 〇 滑石 5.0 黃色飲酸鹽化雲母（A · 1 )·2經授予疏水性處理 5 〇 紅色鈦酸鹽化雲母（A - 2 )·2經授予疏水性處理 2.0 藍色鈥酸鹽化雲母（A - 3 )*2經授予疏水性處理 〇.5 氧化鐵類（紅、黃與黑色）·2經授予疏水性處理 2.0 香料基 足量 純淨水 差額 總計 1 〇〇. *2 :以重量5份二乙醇胺全氟烷基麟酸乙酯（AG 5 30，旭 硝子公司產品）塗覆1 〇〇份重量的粉。 實例3 :(液態粉底） (配方） （重量％ ) 二氧化鈦·3經授予疏水性處理 1.0 乳化鐵類（紅黃與藍）* 3經授予疏水性處理 1.0 聚甲基梦倍半氧娱;粉 4.0 黃色鈦酸鹽化雲母（A -*3經授予疏水性處理 5.0 紅色鈦酸鹽化雲母（A_2)*3經授予疏水性處理 2.0 八甲基環四矽氧烷 20.0 二甲基聚矽氧烷 1〇.〇 二甲基聚矽氧烷.聚氧埽共聚物 10 -18 - 本紙張尺度賴巾目財科(CNS) A4«(21GX2^7_公釐)-- 1332405 A7 B7 五、發明説明（16 ) 甘油 2.0 純淨水 差額 總計 100. * 3 ··以3份重量之二甲基氫聚矽氧烷處理1 〇〇份重量粉。 實例4 :(粉狀疏鬆粉底） (配方） (重量％) 滑石 20.0 雲母 差額 球粒PMMA 15.0 黃色鈦酸鹽化雲母（A-1) 10.0 紅色鈦酸鹽化雲母（A-2). 4.0 鈦酸鹽化雲母（平均粉子直徑：5.5 m， 5.0 白色干涉色系） 二氧化鈦 3.0 黃色氧化鐵 2.0 紅色氧化鐵 0.5 黑色氧化鐵 0.3 二甲基聚矽氧烷 5.0 總計 100. 實例5 :(面粉） (配方） (重量％) 絹雲母 差額 Ne -十二烷醯-L -賴胺酸粉 15.0 球粒聚苯乙醯 10.0 -19- 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) 1332405 A7 _________5Z__ 五、發明説明（17 ) 一 片狀硫酸鋇 硬脂酸鎂 2〇.〇 二氧化鈦 10.0 w色欽酸鹽化雲母（Α· 1 )·4經授予疏水性處理 1.0 4.0 紅色鈦酸鹽化雲母(Α_2)·'經授予疏水性處理 2.0 普魯士藍經授予疏水性處理 0.02 總計 100. 4 ·以5份重量的Ν、十二烷醯_ L _賴胺酸處理1 〇〇份重量 粉。 實例6 ··(壓製粉末） (配方） (重量％) 雲母 差額 滑石 15.0 黃色鈦酸鹽化雲母（A-1) 5 .0 紅色鈇酸鹽化雲母（八_2) 2.0 欽酸鹽化雲母（平均粉子直徑：45.0/zm， 5.0 白色干涉色系） 氧化鋅 5.0 二氧化鈦 3 .0 群青 2.0 液態石蠟 8.0 蜂蠟 2.0 對經苯甲酸酯 0.2 香料基 足量 -20- 本f张尺度通用中關家標準_(—) A4規格(21GX 297公楚)—Sorbit 3.0-Emulsified 鈥2 was granted hydrophobic treatment 10 〇 talc 5.0 Yellow yoghurt mica (A · 1 )·2 was given hydrophobic treatment 5 〇 Red titanated mica (A - 2 ) · 2 was awarded Hydrophobic treatment 2.0 Blue citrate mica (A - 3 )*2 granted hydrophobic treatment 〇.5 Iron oxide (red, yellow and black) · 2 granted hydrophobic treatment 2.0 Perfume-based pure water The difference is 1 〇〇. *2: 1 part by weight of powder is coated with 5 parts by weight of diethanolamine perfluoroalkyl linoleic acid ester (AG 5 30, product of Asahi Glass Co., Ltd.). Example 3: (liquid foundation) (formulation) (% by weight) Titanium dioxide · 3 was given hydrophobic treatment 1.0 Emulsified iron (red yellow and blue) * 3 granted hydrophobic treatment 1.0 Polymethyl dream sesquioxide; powder 4.0 Yellow titanated mica (A-*3 granted hydrophobic treatment 5.0 Red titanated mica (A_2)*3 granted hydrophobic treatment 2.0 Octamethylcyclotetraoxane 20.0 Dimethylpolyoxyl Alkene 1 〇. dimethyl dimethyl oxane. Polyoxy Hydrazine Copolymer 10 -18 - This paper scale 赖 目 目 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( DESCRIPTION OF THE INVENTION (16) Glycerin 2.0 Pure water difference is 100. * 3 ··1 part by weight of 3 parts by weight of dimethylhydrogenpolysiloxane. Example 4: (powdered loose foundation) (formulation) (% by weight) Talc 20.0 Mica difference pellet PMMA 15.0 Yellow titanated mica (A-1) 10.0 Red titanated mica (A-2). 4.0 Titanated mica (average powder diameter: 5.5 m , 5.0 white interference color system) titanium dioxide 3.0 yellow iron oxide 2.0 red iron oxide 0.5 black iron oxide 0.3 dimethyl poly Alkane 5.0 Total 100. Example 5: (flour) (formulation) (% by weight) sericite balance Ne-dodecane-L-lysine powder 15.0 spherule polystyrene 10.0 -19- paper scale Applicable to China National Standard (CNS) A4 Specification (210X297 mm) 1332405 A7 _________5Z__ V. Description of Invention (17) Piece of Barium Sulfate Barium Stearate 2〇.〇TiO2 10.0 w Color Acidated Mica (Α·1 4) Granted hydrophobic treatment 1.0 4.0 Red titanated mica (Α_2)·' was granted hydrophobic treatment 2.0 Prussian blue was given hydrophobic treatment 0.02 Total 100. 4 · 5 parts by weight of hydrazine, dodecane醯 _ L _ lysine treatment 1 重量 weight powder. Example 6 · · (press powder) (recipe) (% by weight) Mica difference talc 15.0 yellow titanated mica (A-1) 5 .0 red 鈇Acidated mica (eight-2) 2.0 acidated mica (average powder diameter: 45.0/zm, 5.0 white interference color) zinc oxide 5.0 titanium dioxide 3.9 ultramarine 2.0 liquid paraffin 8.0 beeswax 2.0 pairs of benzoic acid Ester 0.2 Fragrance based on sufficient amount -20- Use the Zhongguan standard _ (-) A4 specifications (21GX 297 public Chu) -

100. (重量％)100. (% by weight)

1332405 五、發明説明（18 ) 總計 實例7 : (0/W型膏） (配方） 蜂蠟 十六燒醇 氫化羊毛脂 三十碳五烯 甘油脂肪酸 3.5 親脂甘油單硬脂酸酯 2.0 聚氧乙婦(20 Ε.Ο.)花楸醇酐單月桂酸酯 1.0 黃色鈇酸鹽化雲母（Α-1) 1.0 紅色欽酸鹽化雲母（A - 2 ) 2.0 對羥苯甲酸酯 0.2 抗氧劑 0.1 丙二醇 10.0 香料基 足量 純淨水 差額 總計 100. 實例2至7内所得全部化粧組合物均無閃耀感 ，且能使明 允潤飾產生透明感。 工業應用性 根據本發明之化粒組合物有足夠著.色力，經歷甚少光散 射，能授予明亮紋理產生透明感，特別於製備肉色時產生 甚少閃耀感。 -21 - 本紙張尺度適;ίΐ中關家標準(CNS) Μ規格(训χ挪公楚) 裝 訂1332405 V. INSTRUCTIONS (18) GENERAL EXAMPLE 7: (0/W type paste) (Formulation) Beeswax hexadecanol hydrogenated lanolin tricarbonate glycerol fatty acid 3.5 lipophilic glyceryl monostearate 2.0 polyoxyethylene Women (20 Ε.Ο.) Resveratrol Monolaurate 1.0 Yellow Citrate Mica (Α-1) 1.0 Red Citrate Mica (A - 2 ) 2.0 Paraben 0.2 Antioxidant Agent 0.1 Propylene glycol 10.0 Perfume-based sufficient amount of pure water difference total 100. All of the cosmetic compositions obtained in Examples 2 to 7 have no brilliance, and can make the Mingyun retouch have a transparent feeling. Industrial Applicability The granule composition according to the present invention has sufficient color strength and undergoes little light scattering, imparting a transparent texture to give a transparent feeling, particularly when preparing a flesh color, which produces little sparkle. -21 - The paper size is suitable; ΐ ΐ Zhongguanjia Standard (CNS) Μ Specifications (Exhibition of the public Chu) Binding

Claims (1)

133240^公告本£ 091113361號專利申請案 ^ 文申請專利範圍替換本(99年7月）g 竹年7月4日修(東)正本 六、申請專利範圍 1. 一種化粧組合物，其包含二種片狀色料，其係以折射率 至少2.0之粉末塗覆於折射率低於2〇的片狀粉末表面， 再以-著色劑塗覆已塗之片狀粉末而得，其中片狀色料 之一的外觀色彩有一 MunseU編號系統中自1〇p至低於 5 YR之色調，且另一片狀色料的外觀色彩有自$ yr至 1 0 G Y的色調； 前述二種片狀色料總量為3 - 5 0重量〇/〇;且 至少一片狀色料内當片狀色料以塗覆重量〇 5 g/m2塗 覆在黑白二種人造皮上時黑白人造皮間色度（c·^，c*wh) 之差（AC (Bk.Wh)=c*Bk-C*Wh) ’與兩表面接受450入射光角 及-45 C接收光角時的比色測定為_1〇〇至1〇〇，又當片 狀色料以塗覆重量〇·5 g/m2塗覆於白色人造皮上時白色 人皮之色度（C 0w)及其表面在45°入射光角與〇〇接收 光角度作比色測定時至少為1〇 〇。 2. 如凊求項1之化粧組合物，其中該著色劑的塗覆率為片 狀色料基重量之1-20%。 3. 如請求項1之化粧組合物’其中該片狀色料係—紅色欽 酸鹽化雲母’由將以有220至320 nm光學層厚的二氧化 欽層塗覆之鈦酸鹽化雲母表面以紅色氧化鐵塗覆而得。 4. 如請求項1之化粧組合物，其中片狀色料係一黃色鈦酸 鹽化雲母’由將以有140至240 nm光學層厚的二氧化欽 層塗覆之鈦酸鹽化雲母表面以黃色氧化鐵塗覆而得。 5_如請求項1至4中任一項之化粧組合物，其係—粉底者。 79085-990727.doc 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐)133240^ Announcement Patent Application No. 091113361 ^Application for Patent Renewal (June 99) g Bamboo Year July 4th (East) Original 6 Scope of Application Patent 1. A cosmetic composition comprising two a flake coloring material which is applied to a surface of a flake powder having a refractive index of less than 2 Å by a powder having a refractive index of at least 2.0, and then coated with a coated flake powder by a coloring agent, wherein the flake color is obtained The appearance color of one of the materials has a hue from 1 〇p to less than 5 YR in the MunseU numbering system, and the appearance color of the other flake color material has a hue from $ yr to 10 GY; the above two kinds of flake colors The total amount of material is 3 - 50 0 〇 / 〇; and at least one piece of color material when the sheet color is coated with a coating weight of g 5 g / m 2 on black and white two kinds of artificial leather, black and white artificial leather color Difference between degrees (c·^, c* wh) (AC (Bk.Wh)=c*Bk-C*Wh) 'The colorimetric measurement when accepting 450 incident light angles and -45 C receiving light angles on both surfaces is _1〇〇 to 1〇〇, when the sheet color is applied to the white artificial leather with a coating weight of 〇·5 g/m2, the color of the white human skin (C 0w) and its surface incident at 45° Light angle and 〇〇 When the angle of the received light for colorimetric assay of at least 1〇 square. 2. The cosmetic composition of claim 1, wherein the colorant is coated at a rate of from 1 to 20% by weight based on the weight of the tablet base. 3. The cosmetic composition of claim 1, wherein the flake color system is red titanated mica, and the titanated mica to be coated with a dichroic layer having an optical layer thickness of 220 to 320 nm The surface is coated with red iron oxide. 4. The cosmetic composition of claim 1, wherein the flake colorant is a yellow titanated mica' consisting of a titanated mica surface to be coated with a dichroic layer having an optical layer thickness of 140 to 240 nm It is obtained by coating with yellow iron oxide. The cosmetic composition according to any one of claims 1 to 4, which is a foundation. 79085-990727.doc This paper size applies to China National Standard (CNS) A4 specification (210x297 mm)