TWI325869B - - Google Patents

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Publication number: TWI325869B
Authority: TW; Taiwan
Prior art keywords: polyurethane; weight; prepolymer; parts; preparation
Prior art date: 2006-01-25

Application number

TW95102809A

Other languages

English (en)

Chinese (zh)

Other versions

TW200728335A (en

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-01-25

Filing date

2006-01-25

Publication date

2010-06-11

2006-01-25 Application filed filed Critical

2006-01-25 Priority to TW095102809A priority Critical patent/TW200728335A/zh

2007-08-01 Publication of TW200728335A publication Critical patent/TW200728335A/zh

2010-06-11 Application granted granted Critical

2010-06-11 Publication of TWI325869B publication Critical patent/TWI325869B/zh

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229920002635 polyurethane Polymers 0.000 claims description 72
239000004814 polyurethane Substances 0.000 claims description 72
238000002360 preparation method Methods 0.000 claims description 64
229920001971 elastomer Polymers 0.000 claims description 40
239000005060 rubber Substances 0.000 claims description 40
150000002009 diols Chemical class 0.000 claims description 37
229910052901 montmorillonite Inorganic materials 0.000 claims description 33
239000004970 Chain extender Substances 0.000 claims description 26
238000004381 surface treatment Methods 0.000 claims description 26
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 25
229920005862 polyol Polymers 0.000 claims description 25
150000003077 polyols Chemical class 0.000 claims description 25
229920001730 Moisture cure polyurethane Polymers 0.000 claims description 24
239000012948 isocyanate Substances 0.000 claims description 23
150000002513 isocyanates Chemical class 0.000 claims description 23
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 22
238000006243 chemical reaction Methods 0.000 claims description 22
238000007796 conventional method Methods 0.000 claims description 20
239000002131 composite material Substances 0.000 claims description 19
229920003225 polyurethane elastomer Polymers 0.000 claims description 19
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
238000000034 method Methods 0.000 claims description 15
239000004632 polycaprolactone Substances 0.000 claims description 14
238000005266 casting Methods 0.000 claims description 13
229920001610 polycaprolactone Polymers 0.000 claims description 13
229920000642 polymer Polymers 0.000 claims description 13
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 12
229920000909 polytetrahydrofuran Polymers 0.000 claims description 12
238000003756 stirring Methods 0.000 claims description 12
238000005406 washing Methods 0.000 claims description 12
238000001035 drying Methods 0.000 claims description 11
239000000853 adhesive Substances 0.000 claims description 10
230000001070 adhesive effect Effects 0.000 claims description 10
239000000843 powder Substances 0.000 claims description 10
239000012756 surface treatment agent Substances 0.000 claims description 10
-1 14-octadecyltrimethylammonium hydride Chemical compound 0.000 claims description 9
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 9
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
229920000768 polyamine Polymers 0.000 claims description 9
229920001228 polyisocyanate Polymers 0.000 claims description 9
239000005056 polyisocyanate Substances 0.000 claims description 9
239000003795 chemical substances by application Substances 0.000 claims description 8
229910052757 nitrogen Inorganic materials 0.000 claims description 8
238000006116 polymerization reaction Methods 0.000 claims description 8
238000011049 filling Methods 0.000 claims description 7
239000000052 vinegar Substances 0.000 claims description 7
235000021419 vinegar Nutrition 0.000 claims description 7
KMBMQZQZBOLJHN-UHFFFAOYSA-N 2-methyloxirane;oxolane Chemical compound CC1CO1.C1CCOC1 KMBMQZQZBOLJHN-UHFFFAOYSA-N 0.000 claims description 6
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
239000000463 material Substances 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
239000005062 Polybutadiene Substances 0.000 claims description 5
238000001816 cooling Methods 0.000 claims description 5
239000012153 distilled water Substances 0.000 claims description 5
238000002347 injection Methods 0.000 claims description 5
239000007924 injection Substances 0.000 claims description 5
150000002500 ions Chemical class 0.000 claims description 5
229920002857 polybutadiene Polymers 0.000 claims description 5
239000000725 suspension Substances 0.000 claims description 5
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 4
239000004593 Epoxy Substances 0.000 claims description 4
238000000227 grinding Methods 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 4
238000010298 pulverizing process Methods 0.000 claims description 4
238000000967 suction filtration Methods 0.000 claims description 4
229920002121 Hydroxyl-terminated polybutadiene Polymers 0.000 claims description 3
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
239000013078 crystal Substances 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
239000002689 soil Substances 0.000 claims description 3
239000000243 solution Substances 0.000 claims description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
229920002292 Nylon 6 Polymers 0.000 claims description 2
229920005830 Polyurethane Foam Polymers 0.000 claims description 2
208000027418 Wounds and injury Diseases 0.000 claims description 2
238000007334 copolymerization reaction Methods 0.000 claims description 2
230000006378 damage Effects 0.000 claims description 2
239000003292 glue Substances 0.000 claims description 2
208000014674 injury Diseases 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
239000002808 molecular sieve Substances 0.000 claims description 2
239000011496 polyurethane foam Substances 0.000 claims description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
238000012546 transfer Methods 0.000 claims description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 6
125000005442 diisocyanate group Chemical group 0.000 claims 4
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
238000012986 modification Methods 0.000 claims 2
230000004048 modification Effects 0.000 claims 2
IAXFZZHBFXRZMT-UHFFFAOYSA-N 2-[3-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=CC(OCCO)=C1 IAXFZZHBFXRZMT-UHFFFAOYSA-N 0.000 claims 1
OAOABCKPVCUNKO-UHFFFAOYSA-M 8-methylnonanoate Chemical compound CC(C)CCCCCCC([O-])=O OAOABCKPVCUNKO-UHFFFAOYSA-M 0.000 claims 1
DGPHMWKZJDYZSN-UHFFFAOYSA-N CCCCCCCCCC(C1=CC=CC=C1)C1=CC=CC=C1.N=C=O.N=C=O Chemical compound CCCCCCCCCC(C1=CC=CC=C1)C1=CC=CC=C1.N=C=O.N=C=O DGPHMWKZJDYZSN-UHFFFAOYSA-N 0.000 claims 1
241000244206 Nematoda Species 0.000 claims 1
239000002253 acid Substances 0.000 claims 1
230000004913 activation Effects 0.000 claims 1
VEFXTGTZJOWDOF-UHFFFAOYSA-N benzene;hydrate Chemical compound O.C1=CC=CC=C1 VEFXTGTZJOWDOF-UHFFFAOYSA-N 0.000 claims 1
239000001273 butane Substances 0.000 claims 1
238000005660 chlorination reaction Methods 0.000 claims 1
238000004140 cleaning Methods 0.000 claims 1
150000001875 compounds Chemical class 0.000 claims 1
150000001993 dienes Chemical class 0.000 claims 1
CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims 1
238000005553 drilling Methods 0.000 claims 1
239000000796 flavoring agent Substances 0.000 claims 1
230000002496 gastric effect Effects 0.000 claims 1
ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 claims 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
LBTOSGHVABTIRX-UHFFFAOYSA-N oxolane-2,3-diol Chemical compound OC1CCOC1O LBTOSGHVABTIRX-UHFFFAOYSA-N 0.000 claims 1
229920001083 polybutene Polymers 0.000 claims 1
229920000573 polyethylene Polymers 0.000 claims 1
239000001294 propane Substances 0.000 claims 1
238000012216 screening Methods 0.000 claims 1
238000004804 winding Methods 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
229910000831 Steel Inorganic materials 0.000 description 5
230000001680 brushing effect Effects 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
239000010959 steel Substances 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
238000004364 calculation method Methods 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
238000005507 spraying Methods 0.000 description 4
239000007789 gas Substances 0.000 description 3
238000000465 moulding Methods 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
238000007667 floating Methods 0.000 description 2
238000002309 gasification Methods 0.000 description 2
230000020169 heat generation Effects 0.000 description 2
238000005259 measurement Methods 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
238000001291 vacuum drying Methods 0.000 description 2
ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
SVUOLADPCWQTTE-UHFFFAOYSA-N 1h-1,2-benzodiazepine Chemical compound N1N=CC=CC2=CC=CC=C12 SVUOLADPCWQTTE-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
241000283070 Equus zebra Species 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
HPYHZQBAFOWIIL-UHFFFAOYSA-N N=C=O.N=C=O.C(C=C1)=CC=C1SC1=CC=CC=C1.C(C=C1)=CC=C1SC1=CC=CC=C1 Chemical compound N=C=O.N=C=O.C(C=C1)=CC=C1SC1=CC=CC=C1.C(C=C1)=CC=C1SC1=CC=CC=C1 HPYHZQBAFOWIIL-UHFFFAOYSA-N 0.000 description 1
KCHAGAIDSBZELO-UHFFFAOYSA-N N=C=O.N=C=O.OC(N(C1=CC=CC=C1)C1=CC=CC=C1)=O Chemical compound N=C=O.N=C=O.OC(N(C1=CC=CC=C1)C1=CC=CC=C1)=O KCHAGAIDSBZELO-UHFFFAOYSA-N 0.000 description 1
241000283973 Oryctolagus cuniculus Species 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
206010036790 Productive cough Diseases 0.000 description 1
BWLKKFSDKDJGDZ-UHFFFAOYSA-N [isocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)C1=CC=CC=C1 BWLKKFSDKDJGDZ-UHFFFAOYSA-N 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
DFWZIKINBHKJOB-UHFFFAOYSA-N benzene-1,3-diol;2-(2-hydroxyethoxy)ethanol Chemical compound OCCOCCO.OC1=CC=CC(O)=C1 DFWZIKINBHKJOB-UHFFFAOYSA-N 0.000 description 1
229940049706 benzodiazepine Drugs 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
210000000941 bile Anatomy 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
229960005286 carbaryl Drugs 0.000 description 1
238000009750 centrifugal casting Methods 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
238000007872 degassing Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000002019 doping agent Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
229930195712 glutamate Natural products 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
238000007689 inspection Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
210000004072 lung Anatomy 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000002105 nanoparticle Substances 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
230000006675 polyamination Effects 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
238000004321 preservation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000007921 spray Substances 0.000 description 1
210000003802 sputum Anatomy 0.000 description 1
208000024794 sputum Diseases 0.000 description 1
238000010025 steaming Methods 0.000 description 1
239000004575 stone Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
UMWTXGYCEUTPBW-UHFFFAOYSA-N sulfuric acid Chemical compound OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O.OS(O)(=O)=O UMWTXGYCEUTPBW-UHFFFAOYSA-N 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
238000005891 transamination reaction Methods 0.000 description 1
238000005303 weighing Methods 0.000 description 1
210000000707 wrist Anatomy 0.000 description 1

Landscapes

Polyurethanes Or Polyureas (AREA)

TW095102809A 2006-01-25 2006-01-25 Method of manufacture polyurethane-rubber composite tires TW200728335A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
TW095102809A TW200728335A (en)	2006-01-25	2006-01-25	Method of manufacture polyurethane-rubber composite tires

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
TW095102809A TW200728335A (en)	2006-01-25	2006-01-25	Method of manufacture polyurethane-rubber composite tires

Publications (2)

Publication Number	Publication Date
TW200728335A TW200728335A (en)	2007-08-01
TWI325869B true TWI325869B (ja)	2010-06-11

Family

ID=45074286

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW095102809A TW200728335A (en)	2006-01-25	2006-01-25	Method of manufacture polyurethane-rubber composite tires

Country Status (1)

Country	Link
TW (1)	TW200728335A (ja)

2006
- 2006-01-25 TW TW095102809A patent/TW200728335A/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
TW200728335A (en)	2007-08-01

Legal Events

Date	Code	Title	Description
2024-03-11	MM4A	Annulment or lapse of patent due to non-payment of fees

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