TWI253222B - A method of making hydrophilic surface - Google Patents

A method of making hydrophilic surface Download PDF

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Publication number
TWI253222B
TWI253222B TW93111385A TW93111385A TWI253222B TW I253222 B TWI253222 B TW I253222B TW 93111385 A TW93111385 A TW 93111385A TW 93111385 A TW93111385 A TW 93111385A TW I253222 B TWI253222 B TW I253222B
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laser
hydrophilizing
nanostructure
laser source
processing
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TW93111385A
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Chinese (zh)
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TW200536222A (en
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Ga-Lane Chen
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Hon Hai Prec Ind Co Ltd
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Abstract

A method of making a hydrophilic surface includes the steps of: (a) providing an object having a surface needs to be processing; (b) providing a laser source; (c) irradiating the surface employing a laser produced by the laser source; and (d) forming a hydrophilic surface nanostructure by the laser irradiating.

Description

12532221253222

【發明所屬之技術領域】 本發明係關於一種物μ L ^ 歧表面力口工方';> ,士、& 體表面親水化之加工方法。 ^ /ir 尤指一種使物 【先前技術】 表面親水化加 有親水性之一種表面加工 ;::义面加工而使其表面具 法,包括:親水高分子塗有表面親水化加工之方 ^ 表面活性劑塗佈耸 親水高分子塗佈係形& 一層#有 古二 塗佈於基體材料表面,使其具有親水性。%刀子涛膜 表面活性劑塗佈係通過使親水基於基 =使附著之水聚集,使水膜均勻地平面化,=親 然,親水高分子塗佈方法簡單,但所形成之薄膜長時 間使用後容易脫落。而採用塗佈表面活性劑之方法,、^面 活性劑容易在水中流失,亦存在不能長時間使用之問題。 有鑑於此,提供一種能長時間保持物體表面親水性之 加工方法實為必要。 【發明内容】 為解決先前技術之問題,本發明之目的在於提供一種 能長時間保持物體表面親水性之加工方法。 為解決本發明之目的,本發明提供一種使物體表面親 水化之加工方法,包括以下步驟··提供一待加工基體;提 供一雷射源;照射該雷射源產生之雷射光束於該基體表 面,使得一具有親水性之奈米結構形成於其表面。 1253222 五、發明說明(2) 相較於先前技術,本發明所提供之通過雷射加工物體 表面使其具有親水性之方法具有以下優點:首先,其採用 目前習知之雷射加工或雷射雕刻技術,方法簡單,且工藝 比較成熟;其次,通過雷射加工物體表面所得之奈米表面 結構僅在奈米級,宏觀上不易分辨,不受物體形狀之限, 且不會改變物體整體形狀,即不會影響物體原有之外觀; 再次,採用雷射加工物體表面使其具有親水性之方法能長 時間保持物體表面親水性。 【實施方式】 下面將結合附圖對本發明作進一步之詳細說明。 請參閱第一圖,本發明提供一種使物體表面親水化之 加工方法,包括以下步驟:首先提供一欲使其表面具有親 水性之待加工基體’該基體材料包括·玻璃、金屬或合 金;提供一雷射源,根據基體材料之不同,可分別使用二 氧化碳雷射器加工玻璃表面,或摻鈥釔鋁石榴石(Nd-YAG) 雷射器加工金屬輿合金之表面;照射該雷射源產生之雷射 光束於該基體表面,使得一具有親水性之奈米結構形成於 其表面。其中,該種用雷射源加工之方法可參照目前習知 之雷射加工或雷射雕刻技術,即控制使雷射源輸出之高強 度雷射光聚焦至待加工之物體上,通過計算機控制使該待 加工物體表面形成預定形狀。由於雷射光焦點處之功率密 度高達107〜1012瓦/平方厘米,溫度高達1萬攝氏度以上, 任何材料都會瞬時炼化、氣化。 請參閱第二圖,本發明用雷射方法加工物體表面使其BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for processing a surface of a body, a surface of a body, and a surface of a body. ^ /ir Especially refers to a kind of surface treatment [previous technique] surface hydrophilization plus hydrophilic surface treatment;:: surface processing by prosthetic surface, including: hydrophilic polymer coated surface hydrophilization processing ^ The surfactant is coated with a hydrophilic polymer coating system & a layer of #古古2 coated on the surface of the base material to make it hydrophilic. %Knife Koh Tao surfactant coating system makes the water film evenly planarized by making the hydrophilic base based on the aggregation of the adhered water. = Intimately, the hydrophilic polymer coating method is simple, but the formed film is used for a long time. It is easy to fall off. However, by the method of applying a surfactant, the surfactant is easily lost in water, and there is also a problem that it cannot be used for a long time. In view of this, it is necessary to provide a processing method capable of maintaining the hydrophilicity of the surface of an object for a long period of time. SUMMARY OF THE INVENTION In order to solve the problems of the prior art, it is an object of the present invention to provide a processing method capable of maintaining the hydrophilicity of an object surface for a long period of time. In order to solve the object of the present invention, the present invention provides a processing method for hydrophilizing a surface of an object, comprising the steps of: providing a substrate to be processed; providing a laser source; and irradiating the laser beam generated by the laser source to the substrate The surface is such that a hydrophilic nanostructure is formed on the surface thereof. 1253222 V. INSTRUCTION DESCRIPTION (2) Compared with the prior art, the method of the present invention for processing the surface of an object by laser to have hydrophilicity has the following advantages: First, it adopts the conventional laser processing or laser engraving. The technology, the method is simple, and the process is relatively mature; secondly, the surface structure of the nanometer obtained by laser processing the surface of the object is only in the nanometer level, is not easy to distinguish on the macroscopic, is not limited by the shape of the object, and does not change the overall shape of the object. That is, it does not affect the original appearance of the object; again, the method of processing the surface of the object by laser to make it hydrophilic is able to maintain the hydrophilicity of the surface of the object for a long time. [Embodiment] Hereinafter, the present invention will be further described in detail with reference to the accompanying drawings. Referring to the first figure, the present invention provides a processing method for hydrophilizing a surface of an object, comprising the steps of: first providing a substrate to be processed whose surface is hydrophilic; the substrate material comprises: glass, metal or alloy; a laser source, according to the difference of the base material, the glass surface may be processed by using a carbon dioxide laser, or the surface of the metal tantalum alloy is processed by a yttrium aluminum garnet (Nd-YAG) laser; the laser source is irradiated The laser beam is on the surface of the substrate such that a hydrophilic nanostructure is formed on the surface thereof. Among them, the method of processing with a laser source can refer to the conventional laser processing or laser engraving technology, that is, controlling the high-intensity laser light output from the laser source to be focused on the object to be processed, and the computer is controlled to The surface of the object to be processed forms a predetermined shape. Since the power density at the focal point of the laser light is as high as 107 to 1012 watts/cm 2 and the temperature is as high as 10,000 degrees Celsius or more, any material is instantaneously refining and gasifying. Referring to the second figure, the present invention uses a laser method to process the surface of an object.

第5頁 1253222Page 5 1253222

2有親水性所得之奈米表面結構為一連續齒形結構1 l,該 不米結構之節距P為丨〇〜5 0 0奈米,深度R為1 〇〜丨〇 〇奈米,表 面袓糙度為1〜1 〇奈米。 、 本發明用雷射方法加工所得之上述奈米表面結構於水 高附著方、其上日$,4基體表面之接觸角(C〇ntact Angie)明 顯減t。由於接觸角係顯示固體表面濕度之尺度,低接觸 角表不濕度高(親水性能好),表面自由能低,故加工後所 得之基體表面具有良好之親水性◦而且,由於本發明雷射 方法加工所得之奈米表面結構僅在奈米級,宏觀上不易分 辨,不會改變物體整體形狀,即不會影響物體原有之外 觀。 另,本發明用雷射方法加工物體表面使其具有親水性 所得之奈米表面結構可進一步包括其他形狀結構如連續梯 形結構、連繽矩形結構或連續駝峰形結構,只需保證該夺 米結構之節距?為1〇〜5 0 0奈米,深度1^為1〇〜1〇〇奈米,表面 粗糙度為卜1 〇奈米即可。 綜上所述’本發明符合發明專利之要件,爰依法 專利申請。惟,以上所述去 ^ 凡熟悉本案技藝之人士,於明之較佳實施例’舉 修飾或變化,皆應包含於以二依本案發明精神所作之等效 卜之申請專利範圍内。2 The surface structure of the nanometer having hydrophilicity is a continuous tooth structure 1 l, the pitch P of the non-meter structure is 丨〇~500 nm, and the depth R is 1 〇~丨〇〇N, surface The roughness is 1~1 〇 nanometer. The above-mentioned nano surface structure obtained by the laser processing of the present invention is significantly reduced by a contact angle (C〇ntact Angie) on the surface of the upper surface of the water, and the surface of the substrate is substantially reduced by t. Since the contact angle shows the scale of the solid surface humidity, the low contact angle table has high humidity (good hydrophilic property) and the surface free energy is low, so the surface of the substrate obtained after processing has good hydrophilicity and, due to the laser method of the present invention. The surface structure of the processed nanometer is only in the nanometer level, and it is difficult to distinguish on the macroscopic scale, and does not change the overall shape of the object, that is, it does not affect the original appearance of the object. In addition, the present invention uses the laser method to process the surface of the object to make it hydrophilic. The nano surface structure can further include other shape structures such as a continuous trapezoidal structure, a continuous rectangular structure or a continuous hump-shaped structure, and only the rice structure is required to be ensured. The pitch? It is 1〇~5 0 0 nm, the depth 1^ is 1〇~1〇〇N, and the surface roughness is 1 〇 nanometer. In summary, the invention conforms to the requirements of the invention patent, and is patented according to law. However, the above description of the preferred embodiments of the present invention is intended to be included within the scope of the patent application of the present invention.

1253222 圖式簡單說明 【圖式簡單說明】 第一圖係本發明使物體表面親水化之加工方法之流程 圖; 第二圖係本發明使物體表面親水化之加工方法所得之 奈米表面結構之示意圖; 【元件符號說明】 齒形結構 111253222 BRIEF DESCRIPTION OF THE DRAWINGS [Simplified illustration of the drawings] The first drawing is a flow chart of a processing method for hydrophilizing the surface of the object of the present invention; the second drawing is a nano surface structure obtained by the method for hydrophilizing the surface of the object of the present invention. Schematic; [Component Symbol Description] Toothed Structure 11

第7頁Page 7

Claims (1)

1253222 六、申請專利範圍 1. 一種使物體表面親水化之加工方法,包括以下步驟: 提供一待加工基體; 提供一雷射源; 照射該雷射源產生之雷射光束於該基體表面,使得 一具有親水性之奈米結構形成於其表面。 2. 如申請專利範圍第1項所述之使物體表面親水化之加工 方法,其中該奈米結構之深度為1 0〜1 0 0奈米,節距為 10〜500奈米,表面粗糙度為1〜10奈米。 3. 如申請專利範圍第2項所述之使物體表面親水化之加工 方法,其中該奈米結構之形狀為一連續齒形。 4. 如申請專利範圍第2項所述之使物體表面親水化之加工 方法,其中該奈米結構之形狀為一連續矩形。 5. 如申請專利範圍第2項所述之使物體表面親水化之加工 方法,其中該奈米結構之形狀為一連續駝峰形。 6. 如申請專利範圍第1項所述之使物體表面親水化之加工 方法,其中該基體材料包括:玻璃、金屬或合金。 7. 如申請專利範圍第1項所述之使物體表面親水化之加工 方法,其中該雷射源包括二氧化碳雷射器或摻鈥釔鋁 石榴石(Nd-YAG) 雷射器。1253222 VI. Patent application scope 1. A processing method for hydrophilizing a surface of an object, comprising the steps of: providing a substrate to be processed; providing a laser source; irradiating the laser beam generated by the laser source on the surface of the substrate, A hydrophilic nanostructure is formed on the surface thereof. 2. The processing method for hydrophilizing the surface of the object as described in claim 1, wherein the nanostructure has a depth of 10 to 100 nm, a pitch of 10 to 500 nm, and surface roughness. For 1 to 10 nm. 3. A method of hydrophilizing an object surface as described in claim 2, wherein the nanostructure has a continuous tooth shape. 4. A method of hydrophilizing an object surface as described in claim 2, wherein the nanostructure has a continuous rectangular shape. 5. A method of hydrophilizing an object surface as described in claim 2, wherein the shape of the nanostructure is a continuous hump shape. 6. A method of hydrophilizing an object surface as described in claim 1 wherein the matrix material comprises: glass, metal or alloy. 7. A method of hydrophilizing an object surface as described in claim 1 wherein the laser source comprises a carbon dioxide laser or a yttrium aluminum garnet (Nd-YAG) laser.
TW93111385A 2004-04-23 2004-04-23 A method of making hydrophilic surface TWI253222B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI403816B (en) * 2006-06-30 2013-08-01 Hon Hai Prec Ind Co Ltd Method for assembling an ir-cut filter into a lens barrel
US8883289B2 (en) 2010-11-26 2014-11-11 National Central University Fluid philicity/ phobicity adjustable surface structure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI403816B (en) * 2006-06-30 2013-08-01 Hon Hai Prec Ind Co Ltd Method for assembling an ir-cut filter into a lens barrel
US8883289B2 (en) 2010-11-26 2014-11-11 National Central University Fluid philicity/ phobicity adjustable surface structure

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