TW583270B - Reinforced thermoplastic composition - Google Patents

Abstract

A reinforced thermoplastic composition includes a poly(arylene ether), a poly(alkenyl aromatic) compound, a polyolefin, a hydrogenated block copolymer with a high alkenyl aromatic content, a polyolefin-graft-cyclic anhydride copolymer, and a reinforcing filler. The composition exhibits high stiffness while maintaining high impact strength.

Description

經濟部智慧財產局員工消費合作社印製 583270 A7 B7 五、發明説明（1 ) 相關申請案的交互參考文獻 此項申請案揭示下列之利益·· U · s _專利申請案編 號〇9/682，92〇，申請曰期爲^ 月1曰， 2 〇 0 1年，來自u . S ·臨時申請案編號〇 6 / 258 ，835 ，申請曰期爲十二月28曰’ 2000年 ，及 U · S ·申請案 No · 09/682，926，申請 曰期爲十一月1日，2001年，來自U· S .臨時申請 案編號06/258 ，84 0 ，申請日期爲十二月28臼 ，2〇〇◦年，及u. S .申請案No . 0 9/ 682 ，928 ，申請曰期爲十一月1曰，2001年’ 來自U . S .臨時申請案編號06/258 ’ 896 ’申 請曰期爲十二月28曰，2000年。 背景 已有記述一類組成物，該組成物中包含聚（芳醚）與 在此技藝中已知的聚烯烴，以及其中進一步包含各種衝擊 改良劑及相容化藥劑的一類組成物 。 美國專利編號4，7 64，5 59，頒予Yamauchi等 人，一般地敘述一項組成物，該組成物中包含（a )具有 低聚合度的聚苯醚，其中帶有或未帶有苯乙烯樹脂，(b )聚烯烴、及（c )苯乙烯化合物/共範雙嫌嵌段共聚物 或其氫化產物。記述使用無機塡料，如玻璃纖維、欽酸辨 晶鬚，滑石粉，及沈澱碳酸鈣。 美國專利編號 4 ，863 ，997^ kPrinted by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 583270 A7 B7 V. Description of the invention (1) Cross-references to related applications This application reveals the following benefits ... U.S. Patent Application No. 09/682, 92.0, application date is ^ month 1 date, 2001, from u.S. Provisional Application No. 06 / 258,835, application date is December 28, 2000, and U.S. S · Application No. 09/682, 926, the application date is November 1, 2001, from the U.S. Provisional Application No. 06/258, 84 0, the application date is December 28, 2000, and u.S. Application No. 0 9 / 682,928, the application date is November 1, 2001, 'from U.S. Provisional Application No. 06/258' 896 ' The application period is December 28, 2000. Background There have been described a class of compositions including poly (arylene ether) and polyolefins known in the art, and a class of compositions that further include various impact modifiers and compatibilizing agents. U.S. Patent No. 4,7 64,5 59, issued to Yamauchi et al., Generally describes a composition containing (a) a polyphenylene ether having a low degree of polymerization with or without benzene Ethylene resins, (b) polyolefins, and (c) styrene compounds / common-spectrum diblock copolymers or hydrogenated products thereof. The use of inorganic materials such as glass fiber, acetic acid whiskers, talc, and Shendian calcium carbonate is described. U.S. Patent No. 4,863,997 ^ k

r Shibuya W A -—-----—_____r 4· - _ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) 〜 - C请先聞讀背面之注意事項存填寫本頁) 訂 583270 A7 B7 五、發明説明（2 ) ’一般地敘述一項組成物，該組成物中包含（a )聚烯烴 樹脂，（b )聚苯醚樹脂，及（〇 )烯基芳香族化合物與 共軛雙烯之氫化嵌段共聚物，而該共軛雙烯含有4 5 _ .8 0重量百分比的重覆單位係源自烯基芳香族化合物。記 述加入塡料’如玻璃纖維、矽礦石、鈦酸鉀晶鬚、雲母、 滑石粉、及碳酸鈣。 美國專利編號4，892 ，904，頒予Ti ng， 一般敘述一類組成物，該組成物中包含（a )聚苯醚，（ b )聚（烯基芳香族）樹脂，（c )聚烯烴樹脂，（d ) 嫌基芳香族共聚物或三聚物、及（e )少量的纖維玻璃。 美國專利編號5，071，912，頒予^1^1^等人 ，一般地敘述一項組成物，該組成物中包含（a )聚苯醚 ，（b)苯乙烯改良的丙烯聚合物，或內含苯乙烯改良丙 烯聚合.物與聚丙烯的組成物，及（c )至少二種橡膠狀物 質而其中一項相容於（a )且另一項不相容於（a )。記 述使用補強劑與無機塡料。 美國專利編威5 ’ 0 8 1 ’ 1 8 7 ’頒予Maruyama等 人’一般地敘述一項組成物，該組成物中包含特定含量的 (a )聚烯烴、（b )聚苯醚、（c )局部氫化的烯基芳 香族化合物-異戊間二烯嵌段共聚物、及（d )烯基芳香 族化合物-共軛雙烯嵌段共聚物。記述使用塡料，如玻璃 纖維、矽礦石、鈦酸鉀、晶鬚、雲母、滑石粉、及碳酸鈣 〇 美國專利編號5，206，28 1，頒予Furuta等人 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 衣-- I 一 (請先閱讀背面之注意事項再填寫本頁)r Shibuya WA -—-----—_____ r 4 ·-_ This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) ~-C, please read the notes on the back first and fill in this page) Order 583270 A7 B7 V. Description of the invention (2) 'Generally describes a composition containing (a) a polyolefin resin, (b) a polyphenylene ether resin, and (0) an alkenyl aromatic compound and a co-polymer A hydrogenated block copolymer of a conjugated diene, and the conjugated diene contains 4 5 — .80 weight percent of a repeating unit derived from an alkenyl aromatic compound. It is described that materials such as glass fiber, silicon ore, potassium titanate whiskers, mica, talc, and calcium carbonate are added. U.S. Patent No. 4,892,904, issued to Ting, generally describes a class of compositions that include (a) polyphenylene ether, (b) poly (alkenyl aromatic) resin, and (c) polyolefin resin. (D) Aromatic aromatic copolymer or terpolymer, and (e) a small amount of fiber glass. U.S. Patent No. 5,071,912, issued to ^ 1 ^ 1 ^ et al., Generally describes a composition comprising (a) polyphenylene ether, (b) a styrene-modified propylene polymer, Or containing styrene to improve the composition of propylene polymer and polypropylene, and (c) at least two rubbery substances, one of which is compatible with (a) and the other is not compatible with (a). Describes the use of reinforcing agents and inorganic materials. U.S. Pat. No. 5 '0 8 1' 1 8 7 'Issued to Maruyama et al.' Generally describes a composition containing a specified amount of (a) polyolefin, (b) polyphenylene ether, ( c) partially hydrogenated alkenyl aromatic compound-isoprene block copolymer, and (d) alkenyl aromatic compound-conjugated diene block copolymer. Describe the use of materials such as glass fiber, silicon ore, potassium titanate, whiskers, mica, talc, and calcium carbonate. US Patent No. 5,206, 28 1, awarded to Furuta et al. This paper applies Chinese national standards (CNS) A4 size (210 X 297 mm) Clothing-I I (Please read the precautions on the back before filling this page)

、1T 經濟部智慧財產局員工消費合作社印製 583270 A7 B7 五、發明説明（3 ) ，一般地敘述一類組成物，該組成物中包含（a )聚苯酸 ’ （b )改良的丙烯聚合物而彼改良係經由單獨接枝以苯 (請先閱讀背面之注意事項再填寫本頁) 乙烯爲主的單體，或接枝以苯乙烯與丙烯聚合物，（c) 橡膠狀物質，及（d)平均粒徑在〇 · 〇5 - 1〇微米的 無機塡料。 美國專利編號5，4 1 8，2 8 7，頒予Tanaka等人 ’一般地敘述一項組成物，該組成物中包含（a )聚苯醚 、（b )結晶聚烯烴樹脂，及（c )接枝共聚物而其中骨 幹爲下列之共聚物：（i)乙烯或至少一種C3 - C12a -燔烴、及（i i )至少一種鏈非共軛雙烯。記述使用補 強劑，如玻璃纖維、雲母、滑石粉、沈澱碳酸鈣、二氧化 矽、矽礦石、及鈦酸鉀晶鬚。 美國專利編號6 ，031 ，049 ，頒予Chino等人 ’一般地敘述一項組成物，該組成物中包含特定含量的（ a )包含對排聚苯乙烯與聚烯烴的成分、（b )嵌段或接 枝的苯乙烯-烯烴共聚物而其中具有苯乙烯含量在4 〇至 8 5 %重量比，及（c )聚苯醚。記述使用無機塡料。 經濟部智慧財產局員工消費合作社印製 歐洲專利申請案N 〇 . 4 1 2，7 8 7 A 2，頒予 Furuta等人，一般地敘述一類組成物，該組成物中包含（ a )聚苯醚、（b )改良的丙烯聚合物而彼改良係經由單 獨接枝以苯乙烯爲主的單體，或經由接枝以苯乙烯爲主的 單體合倂以另一可共聚合的單體，使用或未使用未改良的 丙烯聚合物、及（c )橡膠狀物質而彼具有可與所有或部 分的（a )相混合的鏈A及可與所有或部分的（b )相混 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇χ297公釐） 583270 A7 ___ B7 _ 五、發明説明（4 ) 合的鏈B。 (請先閲讀背面之注意事項再填寫本頁) 上述組成物之商業價値已受限於不足的介於勁度與衝 擊強度之間的平衡，也受限於在各批與各批之間及在同批 反應物之中的各模與各模之間，試樣各種性質之不一致。 有保持一項彼具有改進的性質平衡的聚（伸芳基醚）-聚 烯烴組成物之需求。尤其，有保持一項需求聚（伸芳基醚 )-聚烯烴組成物，而彼可展現改進的在高勁度下的衝擊 強度。也有保持一項聚（伸芳基醚）-聚烯烴組成物之需 求而彼可展現降低各批與各批及各試樣與各試樣在關鍵性 質上之變異性，該關鍵性質包括勁度及衝擊強度。 本發明槪要 經濟部智慧財產局員工消費合作社印製 上述的及其它缺點及相關技藝的不利因素可經由一種 樹脂組成物而減輕，該組成物中含有：一種聚（伸芳基醚 );一種聚（烯基芳香族）樹脂其含量在至少約1 0之重 量百分比，佔聚（伸芳基醚）與聚（烯基芳香族）樹脂之 總量；一種聚烯烴；一種烯基芳香族化合物與共軛雙烯之 氫化嵌段共聚物，其中烯基芳香族含量在約4 0至約9 0 重量百分比；烯基芳香族化合物與共軛雙烯之未氫化嵌段 共聚物；及一種補強塡料。 另一本發明的具體實施例爲熱塑性樹脂組成物，該組 成物中含有：一種聚（伸芳基醚）；一種聚（烯基芳香族 )樹脂；一種聚烯烴；一種嫌基芳香族化合物與共轭雙燒 之氫化嵌段共聚物，其中烯基芳香族含量在約4 0至約 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇Χ：297公釐） 583270 A7 B7 五、發明説明（5 ) (請先閲讀背面之注意事項再填寫本頁} 9 0重量百分比；一種烯基芳香族化合物與共軛雙烯之未 氫化嵌段共聚物；一種聚丙烯-聚苯乙烯接枝共聚物或烯 基芳香族化合物與共軛雙烯之未氫化嵌段共聚物；及〜種 補強塡料。 如下將記述其它具體實施例，包括一類物品而其中包 含上述組成物之反應產物。 本發明較佳具體實施例之詳細敘述 一種熱塑性樹脂組成物而彼具有卓越的勁度與衝擊強 度之平衡，且可降低性質的變異性，包含：一種聚（伸芳 基醚）；一種聚（烯基芳香族）樹脂其含量在至少約3 〇 之重量百分比，佔聚（伸芳基醚）與聚（烯基芳香族）樹 脂之總量；一種聚烯烴；一種烯基芳香族化合物與共軛雙 烯之氫化嵌段共聚物，其中烯基芳香族含量在約4 0至約 9 0重量百分比；烯基芳香族化合物與共軛雙烯之未氫化 嵌段共聚物；及一種補強塡料。 經濟部智慧財產局員工消費合作社印製 本案發明人已出人意外地發現他們的組成物可提供一 種有利的且先前無法獲得的性質平衡。此組成物也提供實 質降低的性質變異性，相較於已知的組成物。如下記述將 其它具體實施例，包括其中包含該組成物的一類物品。 該組成物可包含任何聚（伸芳基醚）。本文之聚（伸 芳基醚）包含聚苯醚（P P E )及聚（伸芳基醚）共聚物 •，接枝共聚物；聚（伸芳基醚）醚離子體；及烯基芳香族 化合物、乙烯基芳香族化合物、及聚（伸芳基醚）、及其 類似者之嵌段共聚物；及其中至少包含一種前述者的組合 ______ -- — 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 五、發明説明（6 ) 物；及其類似者。聚（伸芳基醚）係已知的一類聚合物其 中包含複數的如下式的結構單位1. 1T printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 583270 A7 B7 5. Description of the invention (3), generally describes a type of composition that contains (a) polybenzoic acid '(b) modified propylene polymer However, the modification is based on the grafting of benzene alone (please read the notes on the back before filling this page), the monomer based on ethylene, or the grafting of styrene and propylene polymers, (c) a rubbery substance, and ( d) Inorganic aggregates having an average particle size of from 0.05 to 10 microns. U.S. Patent No. 5,4 1 8, 2 8 7 issued to Tanaka et al. 'Generally describes a composition comprising (a) polyphenylene ether, (b) a crystalline polyolefin resin, and (c Graft copolymers wherein the backbone is a copolymer of (i) ethylene or at least one C3-C12a-fluorene, and (ii) at least one chain non-conjugated diene. Describes the use of reinforcing agents such as glass fiber, mica, talc, precipitated calcium carbonate, silicon dioxide, silicon ore, and potassium titanate whiskers. U.S. Patent No. 6,031,049, issued to Chino et al. 'Generally describes a composition that contains a specific amount of (a) a component that contains polystyrene and polyolefin, and (b) A segmented or grafted styrene-olefin copolymer which has a styrene content of 40 to 85% by weight, and (c) polyphenylene ether. The use of inorganic materials is described. The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed a European patent application No. 0.41 2, 7 8 7 A 2 and was awarded to Furuta et al., Generally describing a class of composition that contains (a) polybenzene Ether, (b) modified propylene polymer, and the modified system is obtained by grafting a monomer mainly composed of styrene alone, or combining another monomer which is copolymerizable by grafting a monomer mainly composed of styrene , With or without the use of unmodified propylene polymers, and (c) rubbery substances which have a chain A that can be mixed with all or part of (a) and a paper that can be mixed with all or part of (b) The scale applies to the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 583270 A7 ___ B7 _ 5. Description of the invention (4) Combined chain B. (Please read the notes on the back before filling out this page) The commercial value of the above composition has been limited by the insufficient balance between stiffness and impact strength, and also between batches and batches and There are inconsistencies in the various properties of the sample between the molds and the molds in the same batch of reactants. There is a need to maintain a poly (arylene ether) -polyolefin composition that has an improved balance of properties. In particular, there is a need to maintain a poly (arylene ether) -polyolefin composition, which can exhibit improved impact strength at high stiffness. There is also a need to maintain a poly (arylene ether) -polyolefin composition that can exhibit reduced variability in batches and batches and samples and samples in key properties including stiffness And impact strength. The present invention requires that the above-mentioned and other disadvantages and related disadvantages of related arts be printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics, which can be alleviated by a resin composition containing: a poly (arylene ether); The content of poly (alkenyl aromatic) resin is at least about 10% by weight, which accounts for the total amount of poly (arylene ether) and poly (alkenyl aromatic) resin; a polyolefin; an alkenyl aromatic compound A hydrogenated block copolymer with a conjugated diene, wherein the alkenyl aromatic content is about 40 to about 90% by weight; an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; and a reinforcement Unexpectedly. Another embodiment of the present invention is a thermoplastic resin composition, which contains: a poly (arylene ether); a poly (alkenyl aromatic) resin; a polyolefin; a aryl aromatic compound and Conjugated double-fired hydrogenated block copolymers, in which the alkenyl aromatic content is about 40 to about this paper size. Applicable to China National Standard (CNS) A4 specifications (21〇 ×: 297 mm) 583270 A7 B7 V. Invention Note (5) (Please read the notes on the back before filling in this page} 9 0 weight percent; an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; a polypropylene-polystyrene graft Copolymers or unhydrogenated block copolymers of alkenyl aromatic compounds and conjugated dienes; and ~ reinforcing materials. Other specific examples will be described below, including a class of articles containing the reaction products of the above composition. A detailed description of a preferred embodiment of the invention describes a thermoplastic resin composition which has an excellent balance of stiffness and impact strength and can reduce the variability of properties. Ether); a poly (alkenyl aromatic) resin with a content of at least about 30% by weight, accounting for the total amount of poly (arylene ether) and poly (alkenyl aromatic) resin; a polyolefin; an olefin Hydrogenated block copolymer of an aromatic aromatic compound and a conjugated diene, wherein the alkenyl aromatic content is from about 40 to about 90 weight percent; unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene And a kind of reinforcing material. The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the inventors who have unexpectedly discovered that their composition can provide a beneficial and previously unavailable balance of properties. This composition also provides a substantial reduction Compared with known compositions, the following describes other specific examples, including a class of articles containing the composition. The composition can include any poly (arylene ether). The poly ( Poly (arylene ether) includes polyphenylene ether (PPE) and poly (polyaryl ether) copolymers, graft copolymers; poly (polyaryl ether) ether ions; and alkenyl aromatic compounds, ethylene Aromatic compounds, and block copolymers of poly (arylene ether), and the like; and combinations containing at least one of the foregoing ______-This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) 583270 A7 B7 V. Description of the invention (6); and the like. Poly (arylene ether) is a known type of polymer which contains a plurality of structural units of the following formula

(請先閲讀背面之注意事項再填寫本頁) 其中針對各個結構單位，各個Q 1係獨立爲鹵素、一級 或二級Cl — C8院基、苯基、Cl 一 C8鹵院基、Cl —(Please read the notes on the back before filling out this page.) For each structural unit, each Q 1 is independently halogen, primary or secondary Cl — C8 courtyard, phenyl, Cl — C8 halogen courtyard, Cl —

Cs氨院基、C 1 一 C8烴氧基、或C2 — C8國素烴氧基而 其中至少二個碳原子分隔鹵素及氧原子；且各個Q 2係獨立 爲氫、鹵素、一級或二級Ci—C8烷基、苯基、Ci — Cs 鹵烷基、Ci — Cs氨烷基、Ci— C8烴氧基、或Ci — C8鹵素烴氧基而其中至少二個碳原子分隔鹵素及氧原子。 較佳者，各個Q 1爲烷基或苯基，特別地爲C i - 4烷基， 且各個Q2係獨立爲氫或甲基。 經濟部智慧財產局員工消費合作社印製 包含均聚物及共聚物聚（伸芳基醚）兩者。較佳的均 聚物爲那些內含2，6 -二甲基伸苯基醚單位者。適合的 共聚物包括雜排共聚物而其中包含例如單位彼合倂2，3 ，6 -三甲基一 1 ，4 -伸苯基醚單位或共聚物而彼係源 自2 ，6 —二甲基酚與2 ，3 ，6 —三甲基酚的共聚合。 亦包含者爲聚（伸芳基醚）內含可經由接枝乙烯基單體而 製備之部分或聚合物如聚苯乙烯，與耦合的聚（伸芳基醚 ---—____ -Q-__ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 583270 經濟部智慧財產局員工消費合作社印製 A7 __B7五、發明説明（7 ) )其中耦合劑如低分子量聚碳酸酯、醌、雜環族化合物及 醛類而彼係在已知的方式中，與二個聚（伸芳基醚）鏈的 經基基團反應而產生較高的分子量聚合物。本發明聚（伸 方基醚）進一步包含上述者任何的組成物。 聚（伸芳基醚）一般具有數目平均分子量在約 3, 000至約40, 000原子量單位（AMU)且重 量平均分子量在約20， 000至約80， 000AMU ，而彼係經由凝膠滲透層析法測定。聚（伸芳基醚）一般 可帶有本性黏度在約0 · 2至約0 . 6分升每克（ d L / g )，如在氯仿中於2 5 °C測量。在此範圍之中， 本性黏度可較佳者至高達約0 . 5 d L / g，更佳者至高 達約0 · 4 7 d L / g。亦在此範圍之中，本性黏度較佳 者可在至少約0 . 3 d L / g。彼亦可能的合倂利用高本 性黏度聚（伸芳基醚）及低本性黏度聚（伸芳基醚）。當 使用二種本性黏度，決定精確的比例，將取決於所使用的 聚（伸芳基醚）之精確的本性黏度與所欲求之最終物理性 質。 聚（伸芳基醚）典型地之製備，可經由氧化耦合至少 一種單羥基芳香族的化合物如2，6 -二甲苯酚或2，3 ，6 -三甲基酚。催化系統爲一般用於該耦合的催化系統 ;彼典型地至少含有一種重金屬化合物如銅、錳或鈷化合 物，通常合倂以各種其它材料。 針對許多目的特別地有用的聚（伸芳基醚），包含那 些分子而彼具有至少具有一個內含氨烷基的末端基團。氨 __-_ - m -_ 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X297公釐） (請先閱讀背面之注意事項再填寫本頁) 583270 A7 B7 五、發明説明（8 ) (請先閱讀背面之注意事項存填寫本頁) 烷基基團典型地位在鄰位位置，相對於羥基基團。內含該 末端基團的產物可得自加入合適的一級或二級單胺如二一 正丁胺或二甲胺作爲該氧化耦合反應混合物的一項組分。 亦頻繁地展現者爲4 -羥基聯苯末端基團，典型地得自反 應混合物其中存在副產物二酚醌，特別地在一銅一鹵化物 -二級或第三-胺系統之中。該聚合物分子的一項基本部 分’典型地構成該聚合物多達約9 0 ( % )以重量計，可 能至少含有內含氨烷基的及4 -羥基聯苯末端基團二者中 之一項。 此組成物可包含聚（伸芳基醚）用量在約1 〇至約 5 5重量百分比，此係基於組成物之總重。在此範圍之中 ，宜使用聚（伸芳基醚）之量至少在約1 5重量百分比， 更佳者在至少約1 8重量百分比。宜使用聚（伸芳基醚） 之量至高達約5 5重量百分比，更佳者至高達約5 0重量 百分比。 經濟部智慧財產局員工消費合作社印製 此組成物進一步的包含聚（烯基芳香族）樹脂。本文 之”聚（烯基芳香族）樹脂”如在此使用者，包含各類聚 合物而其可經由在此技藝中已知的方法製備，包含整體、 懸浮、及乳化聚合，其中至少含有2 5 ( % )以重量計的 結構單位而該結構單位係源自如下式的烯基芳香族單體Cs ammonia, C 1 -C8 hydrocarbyloxy, or C 2 -C8 hydrocarbyl hydrocarbyloxy with at least two carbon atoms separating the halogen and oxygen atoms; and each Q 2 is independently hydrogen, halogen, primary or secondary Ci-C8 alkyl, phenyl, Ci—Cs haloalkyl, Ci—Cs aminoalkyl, Ci—C8 alkoxy, or Ci—C8 haloalkoxy with at least two carbon atoms separating the halogen and oxygen atoms . Preferably, each Q 1 is an alkyl group or a phenyl group, particularly a C i -4 alkyl group, and each Q 2 is independently hydrogen or methyl. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Includes both homopolymers and copolymer poly (arylene ether). Preferred homopolymers are those containing 2,6-dimethylphenylene ether units. Suitable copolymers include heteropolymers which contain, for example, the units 2,3,6-trimethyl-1,4-phenylene ether units or copolymers which are derived from 2,6-dimethyl Copolymerization of methylphenol with 2,3,6-trimethylphenol. Also included are poly (arylene ether) containing a part or polymer that can be prepared by grafting vinyl monomers, such as polystyrene, and coupled poly (arylene ether) -------____ -Q- __ This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 583270 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 __B7 V. Description of the invention (7) Quinones, heterocyclic compounds, and aldehydes, which are in a known manner, react with the radical groups of two poly (arylene ether) chains to produce higher molecular weight polymers. The poly (methylene ether) of the present invention further contains any one of the above. Poly (arylene ether) generally has a number average molecular weight in the range of about 3,000 to about 40,000 atomic weight units (AMU) and a weight average molecular weight in the range of about 20,000 to about 80,000 AMU. Analytical method. Poly (arylene ether) can generally have an intrinsic viscosity of from about 0.2 to about 0.6 deciliters per gram (dL / g), as measured in chloroform at 25 ° C. Within this range, the intrinsic viscosity may be as high as about 0.5 d L / g, and more preferably as high as about 0.47 d L / g. Also within this range, those with better intrinsic viscosity may be at least about 0.3 d L / g. It is also possible to combine poly (arylene ether) with high intrinsic viscosity and poly (arylene ether) with low intrinsic viscosity. When using two intrinsic viscosities, determining the exact ratio will depend on the precise intrinsic viscosity of the poly (arylene ether) used and the desired final physical properties. Poly (arylene ether) is typically prepared by oxidatively coupling at least one monohydroxy aromatic compound such as 2,6-xylenol or 2,3,6-trimethylphenol. The catalytic system is a catalytic system generally used for this coupling; it typically contains at least one heavy metal compound such as copper, manganese, or cobalt compounds, usually combined with various other materials. Poly (arylene ethers) that are particularly useful for many purposes, include those molecules that have at least one terminal group containing an aminoalkyl group. Ammonia __-_-m -_ This paper size applies to Chinese National Standard (CNS) A4 specification (21 × 297 mm) (Please read the notes on the back before filling this page) 583270 A7 B7 V. Description of the invention (8 ) (Please read the notes on the back and fill in this page) The typical position of the alkyl group is in the ortho position, relative to the hydroxyl group. Products containing this terminal group can be obtained by adding a suitable primary or secondary monoamine such as di-n-butylamine or dimethylamine as a component of the oxidative coupling reaction mixture. Also frequently exhibited are 4-hydroxybiphenyl end groups, typically obtained from reaction mixtures in which a byproduct diphenolquinone is present, particularly in a copper monohalide-secondary or tertiary-amine system. An essential part of the polymer molecule 'typically constitutes the polymer up to about 90 (%) by weight, which may contain at least either of the aminoalkyl-containing and 4-hydroxybiphenyl end groups. One item. The composition may include poly (arylene ether) in an amount of about 10 to about 55 weight percent, based on the total weight of the composition. Within this range, the amount of poly (arylene ether) is preferably at least about 15 weight percent, and more preferably at least about 18 weight percent. The amount of poly (arylene ether) is preferably up to about 55 weight percent, more preferably up to about 50 weight percent. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This composition further contains poly (alkenyl aromatic) resin. As used herein, the "poly (alkenyl aromatic) resin" contains various types of polymers which can be prepared by methods known in the art, including bulk, suspension, and emulsion polymerization, which contain at least 2 5 (%) is a structural unit by weight and the structural unit is derived from an alkenyl aromatic monomer of the formula

Ri—Cz=ch2 (Z)p 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇'〆297公釐） -11 - 583270 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（t) 其中R1爲氮’ Ci 一 C8院基、鹵素、或其類似者， Z爲乙烯基、鹵素、c i 一 C 8烷基，或其類似者；且P爲 〇至5。較佳的烯基芳香族單體包括苯乙烯、氯苯乙烯、 及乙烯基甲苯。聚（烯基芳香族）樹脂包括烯基芳香族單 體之均聚物；烯基芳香族單體如苯乙烯與一或更多不同之 單體之雜排共聚物，而該類不同單體如丙烯腈、丁二烯、 α -甲基苯乙烯、乙基乙烯基苯、二乙烯基苯及順丁燃二 酸酐；及橡膠故良的聚（烯基芳香族）樹脂而該樹脂中包 含橡膠改良劑與烯基芳香族單體（如上述者）均聚物之摻 合物及/或接枝，其中該橡膠改良劑可爲至少一種C 4 - i' C ^。非芳香族的雙烯單體的聚合產物，該單體如丁二烯或 異戊間二烯。此橡膠改良的聚（烯基芳香族）樹脂可包含 約9 8至約7 0重量百分比的烯基芳香族單體之均聚物及 約2至約3 0重量百分比的橡膠改良劑。在此類範圍之中 宜使用至少8 8重量百分比的烯基芳香族單體。彼亦可較 佳地使用至高達約9 4重量百分比的烯基芳香族單體。彼 亦可較佳地使用至少6重量百分比的橡膠改良劑。彼亦可 較佳地使用至高達1 2重量百分比的橡膠改良劑。 聚（烯基芳香族）樹脂之立體規構可爲雜排或對排。 高度較佳的聚（烯基芳香族）樹脂包括雜排與對排均聚苯 乙烯。.適合的雜排均聚苯乙烯爲商購上可獲得者，例如 EB3 3 00，產自 Chevron，及 P 1 8 0 0，產自 B A S F。適合的對排均聚苯乙烯爲商購上可獲得者，例 如商品名爲QUESTRA®(例如QUESTRA®WA550)，產自Dow 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I--------·裝-- (請先閲讀背面之注意事項再填寫本頁) 583270 A7 __ B7 五、發明説明（10) (請先閲讀背面之注意事項再填寫本頁)Ri—Cz = ch2 (Z) p This paper size is in accordance with Chinese National Standard (CNS) A4 (21 ° '297 mm) -11-583270 A7 B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (T) wherein R1 is nitrogen, Ci-C8, a halogen, or the like, Z is vinyl, halogen, ci-C8, or the like; and P is 0 to 5. Preferred alkenyl aromatic monomers include styrene, chlorostyrene, and vinyltoluene. Poly (alkenyl aromatic) resins include homopolymers of alkenyl aromatic monomers; heteropolymers of alkenyl aromatic monomers such as styrene and one or more different monomers, and such different monomers Such as acrylonitrile, butadiene, α-methylstyrene, ethylvinylbenzene, divinylbenzene, and maleic anhydride; and poly (alkenyl aromatic) resins that are good rubbers, and the resin contains Blends and / or grafting of homopolymers of rubber modifiers and alkenyl aromatic monomers (such as the above), wherein the rubber modifier may be at least one C 4-i ′ C ^. Polymerization product of a non-aromatic diene monomer such as butadiene or isoprene. The rubber-modified poly (alkenyl aromatic) resin may include a homopolymer of about 98 to about 70 weight percent of an alkenyl aromatic monomer and a rubber modifier of about 2 to about 30 weight percent. Within this range, at least 88 weight percent of the alkenyl aromatic monomer is preferably used. They can also preferably use alkenyl aromatic monomers up to about 94 weight percent. They may also preferably use at least 6 weight percent of a rubber modifier. They can also preferably use rubber modifiers up to 12% by weight. The poly (alkenyl aromatic) resin may have a three-dimensional structure in a row or a row. Highly preferred poly (alkenyl aromatic) resins include hetero- and para-row homopolystyrene. Suitable heterogeneous homopolystyrenes are commercially available, such as EB3 300, manufactured by Chevron, and P 1 800, manufactured by B A S F. Suitable counter-row homopolystyrenes are commercially available, for example under the trade name QUESTRA® (eg QUESTRA® WA550), produced by Dow. This paper is sized to Chinese National Standard (CNS) A4 (210X297 mm) I -------- · Installation-(Please read the precautions on the back before filling this page) 583270 A7 __ B7 V. Description of the invention (10) (Please read the precautions on the back before filling this page)

Chemical Company。高度較佳的聚（烯基芳香族）樹脂進一 步的包含橡膠改良的聚苯乙烯，亦已知爲高衝擊性聚苯乙 烯或Η I P S，其中包含約8 8至約9 4重量百分比的聚 苯乙烯及約6至約1 2重量百分比的聚丁二烯，帶有有效 的凝膠含量在約1 0 ( % )至約3 5 ( % )。此類橡膠改 良的聚苯乙烯爲商購上可獲得者，例如G Ε Η 1897 產自 General Electric Plastics ，及 ΒΑ5 3 5 0 ，產自Chemical Company. The highly preferred poly (alkenyl aromatic) resin further comprises rubber-modified polystyrene, also known as high-impact polystyrene or rhenium IPS, which contains about 88 to about 94 weight percent polystyrene Ethylene and about 6 to about 12 weight percent polybutadiene, with an effective gel content of about 10 (%) to about 35 (%). Such rubber-modified polystyrenes are commercially available, such as G Ε Η 1897 from General Electric Plastics and ΒΑ5 3 50 from

Chevron 〇 該組成物可包含聚（烯基芳香族）樹脂其含量在約1 至約5 0重量百分比，較佳者在約3至約5 0重量百分比 ，此係基於組成物之總重。 經濟部智慧財產局員工消費合作社印製 在一項具體實施例之中，聚（烯基芳香族）樹脂的用 量可表示爲聚（伸芳基醚）與聚（烯基芳香族）樹脂之總 量的分率。此組成物宜包含聚（烯基芳香族）樹脂其含量 在約1 0至約8 0重量百分比，此係基於聚（伸芳基酸） 與聚（烯基芳香族）樹脂之合倂重量。在此範圍之中，宜 使用聚（烯基芳香族）樹脂量至高達約7 0重量百分比， 更佳者至高達約6 5重量百分比。亦在此範圍之中，宜使 聚（烯基芳香族）樹脂的用量至少約2 0重量百分比，更 佳者在至少約3 0重量百分比。當聚（烯基芳香族）樹脂 的用量少於約1 0之重量百分比，佔聚（伸芳基醚）與聚 (烯基芳香族）樹脂之總量，此組成物於模製之後其撓曲 模數可能不足。當聚（烯基芳香族）樹脂的用量大於約 8 0之重量百分比，佔聚（伸芳基醚）與聚（烯基芳香族 __________ 1 q ___ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（11 ) )樹脂之總量，此組成物於模製之後其熱變形溫度可能不 足。可操縱聚（烯基芳香族）樹脂與聚（伸芳基醚）之比 例，以控制內含此二種成分的單一相之玻璃轉移溫度（ τ g )，相對於聚（伸芳基醚）本身的T g，或相對於聚 烯烴本身的熔融溫度（T m )。例如，可選擇聚（燦基芳 香族）樹脂與聚（伸芳基醚）相對的用量，而使聚（伸芳 基醚）與聚（烯基芳香族）樹脂形成單一相而使彼具有玻 璃轉移溫度至少約2 0 °C較高，較佳者在至少約3 〇 °C較 高，相較於聚（烯基芳香族）樹脂本身之玻璃轉移溫度， 彼可例如在約1 0 0 °C至約1 1 〇 °c。同時，可選擇聚（ 烯基芳香族）樹脂與聚（伸芳基醚）的相對用量，而使聚 (伸芳基醚）與聚（烯基芳香族）樹脂呈現單一相而彼具 有玻璃轉移溫度至高達約1 5 °C較高，較佳者至高達約 1 0 °C較高，更佳者至高達約1 t較高，相較於聚烯烴本 身之Tm。可選擇聚（烯基芳香族）樹脂與聚（伸芳基醚 )的相對用量，而使聚（伸芳基醚）與聚（烯基芳香族） 樹脂呈現單一相而彼具有玻璃轉移溫度在約1 3 0 °C至約 18 0。。。 此組成物進一步的包含聚烯烴。該聚烯烴可爲均聚物 或共聚物而其中具有至少約8 0重量百分比之單位係源自 聚合乙烯、丙烯、丁烯、或其混合物。之實施例聚烯烴均 聚物包含聚乙烯、聚丙烯、及聚丁烯。聚烯烴共聚物之實 施例包括乙烯、丙烯、及丁烯相互間之雜排、接枝、及嵌 段共聚物，且其中進一步的包含至高達2 0重量百分比之 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 Β7 五、發明説明（12) (請先閲讀背面之注意事項再填寫本頁) 單位係源自C 5 - C i ϋ α烯烴（排除芳香族α -烯烴）。 此聚烯烴進一步的包含上述均聚物及共聚物之摻合物。較 佳的聚烯烴可帶有撓曲模數在至少約1 0 〇，〇 〇 0磅每 平方英寸（P s i )，於2 3 °C，其測量係依據A S T Μ D 7 9 0。適合的聚烯烴可包括例如線性的低密度聚乙燃 彼可商購自Exxon Mobil而品名爲L L — 6 2 0 1，低密度 聚乙烯彼可商購自Exxon Mobil而品名爲LMA — 027， 高密度聚乙烯彼可商購自Exxon Mobil而品名爲H D — 6605 ，超高分子量聚乙烯以類型1900 之品名而 得自 Montell Polyolefins，且聚丁條（聚丁烯—1 )以 P B 〇 1 1 〇 之品名而得自 Montell Polyolefins。 經濟部智慧財產局員工消費合作社印製 目前較佳的聚烯烴包括丙烯聚合物。此丙烯聚合物可 爲聚丙烯之均聚物。供選擇地，此丙烯聚合物可爲丙烯與 至少一種烯烴的雜排、接枝、或嵌段共聚物，而該烯烴係 選自乙烯與C4 一 C ι〇α -烯烴（排除芳香族α -燃烴） ，其限制條件爲該共聚物至少包含約8 〇重量百分比，較 佳者在至少約9 0重量百分比的重覆單位係源自丙烯。帶 有少量的另一聚合物如聚乙儲之丙儲聚合物摻合物亦包含 在此類丙烯聚合物範圍之中。此類丙燦聚合物可帶有熔融 流動指數在約0 · 1至約5 0 g / 1 〇分鐘，較佳者約1 至約3 0 g / 1 0分鐘，其測量係依據A S T Μ D1238 ，條件在2 · 16公斤與2〇〇。〇之下。上述 的丙烯聚合物可經由各種已知的方法製作。亦可使用商購 之丙烯聚合物。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 583270 A7 _ B7 五、發明説明（13) (請先閱讀背面之注意事項再填寫本頁) 較佳的丙烯聚合物包含均聚丙烯。高度較佳的丙烯聚 合物包含均聚丙烯而彼具有結晶含量在至少約2 0 ( % ) ’較佳者在至少約3 0 ( % )。適合的同排聚丙烯爲商購 上可獲得者’例如P D 4 0 3顆粒’產自B a s e 11 (以前的 M〇ntell Polyolefins of North America) 〇 此組成物可包含聚烯烴其用量在約1 〇至約6 0重量 百分比，此係基於組成物之總重。在此範圍之中，聚烯烴 之含量在至少約1 5重量百分比可爲較佳的。亦在此範圍 之中，聚烯烴量的至高達約5 0重量百分比可爲較佳的， 且至高達約4 0重量百分比的含量可爲更佳的。 經濟部智慧財產局員工消費合作社印製 此組成物包含一種氫化的烯基芳香族化合物/共軛雙 烯的嵌段共聚物而其中烯基芳香族含量在約4 0至約9 0 重量百分比（以下稱爲”氫化嵌段共聚物”）。此氫化嵌 段共聚物爲一種共聚物而其中包含（A)至少一種源自烯 基芳香族化合物的嵌段及（B )至少一種源自共軛雙烯的 嵌段，其中在嵌段（B )中脂肪族不飽和基團之含量將經 由氫化而降低。嵌段（A )與（B )之排列包含線性的結 構、接枝結構、及輻射狀的發射嵌段（teleblock )結構，且 帶有或未帶有枝鏈。 在此類結構之中較佳者爲線性的結構而包含二嵌段（ A — B嵌段）、三嵌段（A - B — A嵌段或B— A - B嵌 段）'四嵌段（A-B - A — B嵌段）、及五嵌段（A-B — A — B - A嵌段或B— A - B— A — B嵌段）結構與 內含A與B嵌段總量在6或更多的線性結構。更佳者爲二 ____________- -_ 本紙張尺度適用中國國家標準（CNS ) A4規格（2ΐ〇χ297公釐） 583270 A7 B7 _ 五、發明説明（14) 嵌段、三嵌段、及四嵌段結構’而以A - B - A三嵌段結 構係特別較佳的。 (請先閲讀背面之注意事項再填寫本頁} 提供嵌段（A )的烯基芳香族化合物係由下式代表Chevron 〇 The composition may include poly (alkenyl aromatic) resin in an amount of about 1 to about 50 weight percent, preferably about 3 to about 50 weight percent, based on the total weight of the composition. Printed in a specific embodiment by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the amount of poly (alkenyl aromatic) resin can be expressed as the total of poly (arylene ether) and poly (alkenyl aromatic) resin. The fraction of the amount. The composition preferably comprises a poly (alkenyl aromatic) resin at a content of about 10 to about 80 weight percent, based on the combined weight of the poly (alkenyl aromatic) and poly (alkenyl aromatic) resin. Within this range, the amount of poly (alkenyl aromatic) resin is preferably up to about 70 weight percent, more preferably up to about 65 weight percent. Also within this range, the amount of poly (alkenyl aromatic) resin is preferably at least about 20 weight percent, and more preferably at least about 30 weight percent. When the amount of poly (alkenyl aromatic) resin is less than about 10% by weight, it accounts for the total amount of poly (arylene ether) and poly (alkenyl aromatic) resin. Deflection modulus may be insufficient. When the amount of poly (alkenyl aromatic) resin is greater than about 80% by weight, it accounts for poly (alkenyl ether) and poly (alkenyl aromatic) __________ 1 q ___ This paper size applies to Chinese National Standard (CNS) A4 Specifications (210X297 mm) 583270 A7 B7 The total amount of resin printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Inventory (11)) The total amount of resin after molding. The thermal deformation temperature of this composition may be insufficient. The ratio of poly (alkenyl aromatic) resin to poly (arylene ether) can be manipulated to control the glass transition temperature (τ g) of a single phase containing these two components, relative to poly (arylene ether) Tg itself, or the melting temperature (Tm) relative to the polyolefin itself. For example, the relative amount of poly (canyl aromatic) resin and poly (arylene ether) can be selected, so that poly (arylene ether) and poly (alkenyl aromatic) resin form a single phase so that they have glass. The transfer temperature is higher at least about 20 ° C, preferably higher at at least about 30 ° C. Compared to the glass transition temperature of the poly (alkenyl aromatic) resin itself, it can be, for example, at about 100 ° C to about 110 ° C. At the same time, the relative amount of poly (alkenyl aromatic) resin and poly (arylene ether) can be selected, so that poly (arylene ether) and poly (alkenyl aromatic) resin present a single phase and each has glass transfer The temperature is as high as about 15 ° C, preferably as high as about 10 ° C, and more preferably as high as about 1 t, compared to the Tm of the polyolefin itself. The relative amount of poly (alkenyl aromatic) resin and poly (arylene ether) can be selected, so that poly (arylene ether) and poly (alkenyl aromatic) resin present a single phase and each has a glass transition temperature between About 1 3 0 ° C to about 18 0. . . This composition further comprises a polyolefin. The polyolefin can be a homopolymer or a copolymer with units having at least about 80 weight percent derived from the polymerized ethylene, propylene, butene, or a mixture thereof. Examples Polyolefin homopolymers include polyethylene, polypropylene, and polybutene. Examples of polyolefin copolymers include miscellaneous row, graft, and block copolymers of ethylene, propylene, and butene, and further include up to 20% by weight (please read the precautions on the back first) (Fill in this page again) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 583270 A7 Β7 V. Description of the invention (12) (Please read the notes on the back before filling this page) The unit is from C 5-C i ϋ α-olefins (excluding aromatic α-olefins). This polyolefin further comprises a blend of the above homopolymers and copolymers. Better polyolefins may have a flexural modulus of at least about 10,000 pounds per square inch (P s i) at 2 3 ° C. The measurement is based on AS T DM D 790. Suitable polyolefins may include, for example, linear low-density polyethylene, commercially available from Exxon Mobil under the name LL-6 2 01, and low-density polyethylene, commercially available from Exxon Mobil under the name LMA-027, high Density polyethylene is commercially available from Exxon Mobil under the trade name HD-6605, ultra high molecular weight polyethylene is available from Montell Polyolefins under the name 1900, and polybutylene (polybutene-1) is PB 〇1 1 〇 The name is derived from Montell Polyolefins. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The currently preferred polyolefins include propylene polymers. This propylene polymer may be a homopolymer of polypropylene. Alternatively, the propylene polymer may be a hetero-row, graft, or block copolymer of propylene and at least one olefin, and the olefin is selected from ethylene and C4-Cio-α-olefin (excluding aromatic α- Hydrocarbon combustion), the limitation is that the copolymer contains at least about 80 weight percent, preferably at least about 90 weight percent of the repeating unit is derived from propylene. Blends of propylene polymers with a small amount of another polymer such as polyethylene are also included in the scope of such propylene polymers. Such acrylic polymers may have a melt flow index of about 0.1 to about 50 g / 10 minutes, preferably about 1 to about 30 g / 10 minutes, and their measurement is based on AST M D1238, Conditions are between 2.16 kg and 200. 〇 Below. The above-mentioned propylene polymer can be produced by various known methods. Commercially available propylene polymers can also be used. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 583270 A7 _ B7 V. Description of the invention (13) (Please read the precautions on the back before filling this page) Better propylene polymer contains homopolymer Acrylic. A highly preferred propylene polymer comprises homopolypropylene and it has a crystalline content of at least about 20 (%) ', preferably at least about 30 (%). A suitable in-row polypropylene is commercially available 'e.g. PD 403 pellets' from Base 11 (formerly Montell Polyolefins of North America). This composition may comprise polyolefins in an amount of about 1 0 to about 60 weight percent, based on the total weight of the composition. Within this range, a polyolefin content of at least about 15 weight percent may be preferred. Also within this range, up to about 50 weight percent of the amount of polyolefin may be preferred, and content up to about 40 weight percent may be more preferred. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This composition contains a hydrogenated alkenyl aromatic compound / conjugated diene block copolymer with an alkenyl aromatic content of about 40 to about 90 weight percent ( Hereinafter referred to as "hydrogenated block copolymer"). The hydrogenated block copolymer is a copolymer containing (A) at least one block derived from an alkenyl aromatic compound and (B) at least one block derived from a conjugated diene, in which the block (B The content of aliphatic unsaturated groups in) will be reduced by hydrogenation. The arrangement of the blocks (A) and (B) includes a linear structure, a graft structure, and a radial teleblock structure, with or without a branch chain. Among such structures, a linear structure is preferred and it includes a diblock (A-B block), a triblock (A-B-A block or B-A-B block) 'tetrablock (AB-A-B block), and pentablock (AB-A-B-A block or B-A-B-A-B block) structure and the total content of A and B blocks is 6 Or more linear structures. The better one is two. ____________- -_ This paper size is applicable to the Chinese National Standard (CNS) A4 specification (2ΐ〇χ297mm) 583270 A7 B7 _ 5. Description of the invention (14) Block, triblock, and tetrablock The segment structure is particularly preferred as the A-B-A triblock structure. (Please read the notes on the back before filling out this page} Alkenyl aromatic compounds that provide blocks (A) are represented by the following formula

其中R2與R3係各自獨立代表氫原子、Ci-Cs烷基 基團、C 2 — C 8烯基基團、或其類似者；R 4與R 8係各自 獨立代表氫原子、C 1 - C8院基基團、氯原子、溴原子、 或其類似者；及R 5 - R 7係各自獨立代表氫原子、C i〜 C8烷基基團、C2— C8烯基基團、或其類似者，或R4與 R5合倂爲中央芳香環以形成萘基基團，或R5與R6合倂 爲中央芳香環以形成萘基基團。 經濟部智慧財產局員工消費合作社印製 烯基芳香族化合物的特定實施例包括苯乙烯、對-甲 基苯乙烯、α —甲基苯乙烯、乙烯基二甲苯、乙烯基甲苯 、乙烯基萘、二乙烯基苯、溴苯乙烯、氯苯乙烯、及其類 似者、及其中至少包含一項前述烯基芳香族化合物的組合 物。在此類之中，苯乙烯、α -甲基苯乙烯、對一甲基苯 乙烯、乙烯基甲苯、及乙烯基二甲苯爲較佳的，而以苯乙 烯爲更佳的。 共軛雙烯之特定實施例包括1 ，3— 了二烯、2 -甲 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 583270 A7 B7 五、發明説明（15) (請先閲讀背面之注意事項再填寫本頁) 基一 1 ，3 — 丁二烯、2 ，3 —二甲基一 1 ，3 — 丁二烯 、1 ，3 -戊二烯.、及其類似者。其中較佳者爲1 ’ 3 一 丁二烯及2 —甲基—1 ，3 - 丁二烯，而以1 ，3 -丁二 烯爲更佳的。 除共軛雙烯之外，氫化嵌段共聚物可含有小比例的較 低的烯烴系烴，例如乙烯、丙烯、1 一丁烯、二環戊二儲 、未共軛的雙烯、或其類似者。 在氫化嵌段共聚物中源自烯基芳香族化合物的重覆單 位之含量可在約4 0至約9 0重量百分比’此係基於氫化 嵌段共聚物之總重，而烯基芳香族化合物含量之下限較佳 者在約5 0重量百分比，更佳者約5 5重量百分比，且烯 基芳香族化合物含量之上限較佳者在至尚達約8 5重量百 分比，更佳者至高達約7 5重量百分比，而更佳者至高達 約7 0重量百分比。 在氫化嵌段共聚物中骨幹中加入共軛雙烯的模式，無 特別的限制。例如，當共軛雙烯爲1 ，3 - 丁二烯，可加 入約1 ( % )至約9 9 ( % ) 1 ，2 -加入，而其餘爲1 經濟部智慧財產局員工消費合作社印製 ，4 -加入。 氫化嵌段共聚物較佳者係氫化至一種程度，在源自共 軛雙烯的脂肪族鏈部分中，有少於5 0 ( % )，更佳者少 於2 0 ( % )，而更佳者少於1 0 ( % )的不飽和鍵結保 持未還原。源自烯基芳香族化合物的芳香族不飽和鍵結可 氫化到至高達約2 5 ( % )之程度。 此氫化嵌段共聚物宜具有數目平均分子量在約 --—----- - 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X297公釐） 583270 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（16) 5， 0 0 0至約5〇0，〇〇 0 A M U，而彼測定係經由 凝膠滲透層析法（G P C )，使用聚苯乙烯標準。在此範 圍之中，此數目平均分子量較佳者可在至少約 10, 000AMU，更佳者在至少約30， 000 AMU，而更佳者在至少約45， 000AMU。亦在此 範圍之中，此數目平均分子量可較佳者至高達約 300， 000AMU，更佳者至高達約 200, 000AMU，而更佳者至高達約 150，000AMU。 由G P C測量的氫化嵌段共聚物之分子量分佈未特別 地限制。此共聚物可帶有任何的重量平均分子量對數目平 均分子量之比例。 某些此類氫化嵌段共聚物帶有具備結晶性的氫化共軛 雙烯聚合物鏈。氫化嵌段共聚物的結晶性可經由使用微差 掃描熱卡計（D S C )而測定，例如D S C - I I模式， 由Perkin-Elmer公司製作，熔融熱之測量可經由例如1 0 °C / m i η的加熱速率，在惰性氣體氣體如氮氣之中。例如 ，可將試樣加熱至預估計熔點溫度以上，經由1 0 °C / m i η之速率降溫冷卻，允許放置約1分鐘，且然後再一 次以1 0 °C /分鐘之速率加熱。 此氫化嵌段共聚物可帶有任何程度之結晶性。基於所 生成的樹脂組成物的機械強度之平衡，較佳者爲那些具有 熔點在約一 4 0 °C至約1 6 0 °C，或不帶有明確熔點（即 彼具有非結晶性）之氫化嵌段共聚物，如係依據上述的技 ________1Q -__ 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X297公釐） (請先聞讀背面之注意事項再填寫本頁) 583270 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（17) 藝測量者。在熔點範圍約一 4 0 °C至約1 6 0 t之中，宜 使用氫化嵌段共聚物彼具有熔點在至少約- 2 0 °C，更佳 者在至少約0 °C，而更佳者在至少約2 0 °C，而更佳者在 至少約4 0 °C。亦在此範圍之中，宜使用熔點至高達約 1 4 0 °C的氫化嵌段共聚物，更佳者至高達約1 1 0 °C， 而更佳者至高達約1 0 0 °C。 此氫化嵌段共聚物可帶有任何玻璃轉移溫度（T g ) ，此係歸因於氫化共軛雙烯聚合物鏈。由生成的樹脂組成 物的低溫衝擊強度之觀點，彼宜具有T g在至高達約-6 0 °C，更佳者至高達約一 1 2 0 °C。共聚物的玻璃轉移 溫度之測量，可經由前述的D S C方法測量，或由對溫度 改變的黏彈性行爲測量，如使用機械光譜儀觀察者。 特別較佳的氫化嵌段共聚物爲苯乙烯-（乙烯-丁烯 )二嵌段與苯乙烯一（乙烯-丁烯）-苯乙烯三嵌段共聚 物，此係分別地得自氫化的苯乙傭-丁 一傭與苯乙矯-丁 二烯-苯乙烯三嵌段共聚物。 此氫化嵌段共聚物之合成可經由嵌段聚合接著作氫化 ，例如記述於美國專利編號4 ，8 6 3 ’ 9 9 7 ，頒予 Shibuya等人。適合的氫化嵌段共聚物包括苯乙燦-（乙燒 -丁烯）二嵌段及苯乙烯-（乙烯一丁烯）一苯乙烯三嵌 段共聚物，例如商購之TUFTEC®H1 043,由 Asahi Chemical 銷售。 此組成物可包含氫化嵌段共聚物其用量在約1至約 2 0重量百分比，較佳者約1至約1 5重量百分比，更佳 ______-?n-____ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 583270R2 and R3 each independently represent a hydrogen atom, a Ci-Cs alkyl group, a C 2 -C 8 alkenyl group, or the like; R 4 and R 8 each independently represent a hydrogen atom, C 1-C8 A radical, a chlorine atom, a bromine atom, or the like; and R 5 to R 7 each independently represent a hydrogen atom, a Ci ~ C8 alkyl group, a C2-C8 alkenyl group, or the like , Or R4 and R5 are combined to form a central aromatic ring to form a naphthyl group, or R5 and R6 are combined to form a central aromatic ring to form a naphthyl group. Specific examples of alkenyl aromatic compounds printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs include styrene, p-methylstyrene, α-methylstyrene, vinylxylene, vinyltoluene, vinylnaphthalene, Divinylbenzene, bromostyrene, chlorostyrene, and the like, and a composition containing at least one of the aforementioned alkenyl aromatic compounds. Among these, styrene,? -Methylstyrene, p-methylstyrene, vinyltoluene, and vinylxylene are preferable, and styrene is more preferable. Specific examples of conjugated diene include 1, 3—diene, 2—a paper size applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 583270 A7 B7 5. Description of the invention (15) (please first Read the notes on the reverse side and fill out this page again.) Benzene-1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, and the like. Of these, 1'3-butadiene and 2-methyl-1,3-butadiene are preferred, and 1,3-butadiene is more preferred. In addition to conjugated diene, the hydrogenated block copolymer may contain a small proportion of lower olefin-based hydrocarbons, such as ethylene, propylene, 1-butene, dicyclopentadiene, unconjugated diene, or their Similar. The content of the repeating unit derived from the alkenyl aromatic compound in the hydrogenated block copolymer may be about 40 to about 90 weight percent. 'This is based on the total weight of the hydrogenated block copolymer, and the alkenyl aromatic compound The lower limit of the content is preferably about 50% by weight, more preferably about 55% by weight, and the upper limit of the content of the alkenyl aromatic compound is preferably up to about 85% by weight, more preferably up to about 50% by weight. 7 5 weight percent, and more preferably up to about 70 weight percent. The mode of adding a conjugated diene to the backbone of the hydrogenated block copolymer is not particularly limited. For example, when the conjugated diene is 1, 3-butadiene, about 1 (%) to about 9 9 (%) 1, 2-join, and the rest is 1 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs , 4-added. The hydrogenated block copolymer is preferably hydrogenated to such an extent that less than 50 (%) of the aliphatic chain portion derived from the conjugated diene, more preferably less than 20 (%), and more Preferably, less than 10 (%) of unsaturated bonds remain unreduced. Aromatic unsaturated bonds derived from alkenyl aromatic compounds can be hydrogenated to the extent of up to about 25 (%). The hydrogenated block copolymer should preferably have a number average molecular weight of about ------------This paper size is applicable to Chinese National Standard (CNS) A4 specifications (21 × 297 mm) 583270 A7 B7 Employees of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Consumer Cooperatives. 5. Description of the invention (16) 5,000 to about 50,000 AMU, and the measurement is by gel permeation chromatography (GPC), using polystyrene standards. Within this range, the number with a better average molecular weight may be at least about 10,000 AMU, more preferably at least about 30,000 AMU, and more preferably at least about 45,000 AMU. Also within this range, the number average molecular weight can be preferably up to about 300,000 AMU, more preferably up to about 200,000 AMU, and even more preferably up to about 150,000 AMU. The molecular weight distribution of the hydrogenated block copolymer measured by G P C is not particularly limited. This copolymer may carry any ratio of weight average molecular weight to number average molecular weight. Some such hydrogenated block copolymers carry a hydrogenated conjugated diene polymer chain having crystallinity. The crystallinity of the hydrogenated block copolymer can be measured by using a differential scanning calorimeter (DSC), such as DSC-II mode, manufactured by Perkin-Elmer. The measurement of the heat of fusion can be measured, for example, by 10 ° C / mi η The heating rate is in an inert gas such as nitrogen. For example, the sample can be heated above the pre-estimated melting point temperature, cooled down at a rate of 10 ° C / m i η, allowed to stand for about 1 minute, and then heated again at a rate of 10 ° C / minute. This hydrogenated block copolymer may carry any degree of crystallinity. Based on the balance of the mechanical strength of the resulting resin composition, those having a melting point in the range of about 40 ° C to about 160 ° C, or having no clear melting point (that is, they have non-crystalline properties) are preferred. If the hydrogenated block copolymer is based on the above-mentioned technology ________1Q -__ This paper size is applicable to China National Standard (CNS) A4 (21 × 297 mm) (Please read the precautions on the back before filling this page) 583270 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (17) Art Surveyor. In the melting point range of about-40 ° C to about 160 ° T, it is preferred to use a hydrogenated block copolymer which has a melting point of at least about -20 ° C, more preferably at least about 0 ° C, and more preferably It is at least about 20 ° C, and more preferably at least about 40 ° C. Also within this range, hydrogenated block copolymers having a melting point of up to about 140 ° C, more preferably up to about 110 ° C, and more preferably up to about 100 ° C. This hydrogenated block copolymer can carry any glass transition temperature (Tg), which is attributed to the hydrogenated conjugated diene polymer chain. From the viewpoint of the low-temperature impact strength of the resulting resin composition, it is preferred that the T g be up to about -60 ° C, and more preferably up to about 120 ° C. The glass transition temperature of the copolymer can be measured by the aforementioned DSC method, or by measuring the viscoelastic behavior with respect to temperature changes, such as using a mechanical spectrometer for an observer. Particularly preferred hydrogenated block copolymers are styrene- (ethylene-butene) diblock and styrene- (ethylene-butene) -styrene triblock copolymers, which are obtained separately from hydrogenated benzene Ethylene-butadiene-acetylene-butadiene-styrene triblock copolymer. The synthesis of this hydrogenated block copolymer can be hydrogenated via block polymerization, for example, described in U.S. Patent No. 4, 8 6 3 '997, and issued to Shibuya et al. Suitable hydrogenated block copolymers include styrene- (ethylene-butene) diblock and styrene- (ethylene-butene) -styrene triblock copolymers, such as the commercially available TUFTEC® H1 043, Sold by Asahi Chemical. This composition may include a hydrogenated block copolymer in an amount of about 1 to about 20 weight percent, more preferably about 1 to about 15 weight percent, and more preferably ______-? N -____ This paper size applies to Chinese national standards (CNS) A4 size (210X297 mm) (Please read the precautions on the back before filling this page) 583270

者約1至約1 0重量百分比，此係基於組成物之總重。 視需要，此方法可包含加入一或更多補強塡料。補強 墳料可包括例如無機及有機材料，如纖維、機織織物及非 機織織物而其材料係採用E 一、N E 一、S 丁一及D 型玻璃及石央，碳纖維’包括聚（丙烯腈）（p a n )纖 維、蒸汽成長碳纖維，且特別爲石墨蒸汽成長碳纖維彼具 有平均直徑在約3至約5 0 〇奈米（例如參見美國專利編 號 4，5 6 Tibbetts 等人 4，6 6 3， ，4，8 1 6 4，8 7 6，5，5 8 9， 5 ，5 9 1 ， — 、 經濟部智慧財產局員工消費合作社印製 5，684 及 5，024，818，頒予 ’4’572’813，頒予 Arakawa ; 23〇及5，165，909，頒予1^111^以 ’ 2 8 9 ’ 頒予 Komatsu 等人， 0 7 8 ’頒予Arakawa等人， 1 5 2 ’頒予Tennent等人，及 3 8 2，頒予Nahass等人）；鈦酸鉀單晶纖 維、碳化矽纖維、碳化硼纖維、石膏纖維、氧化鋁纖維、 石棉、鐵纖維、鎳纖維、銅纖維、矽礦石纖維；及其類似 者。此補強塡料可呈下列形式：玻璃粗紗布、玻璃布、切 玻璃、中空玻璃纖維、玻璃蓆、玻璃面板蓆、及非織布玻 璃織物、陶瓷纖維織物、及金屬的纖維織物。此外，亦可 使用合成的有機補強塡料，包括能形成纖維的有機聚合物 。該補強有機纖維說明性實施例，可使用聚（醚酮）、聚 醯亞胺苯并噚唑、聚（伸苯基硫化物）、聚酯、芳香族聚 醯胺、芳香族聚醯亞胺或聚醚醯亞胺、丙烯酸樹脂、及聚 (乙烯醇）。氟聚合物如聚四氟乙烯。亦包含者爲天然的 -91 -_____ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂 583270 A7 B7 五、發明説明（19) (請先閲讀背面之注意事項再填寫本頁) 有機纖維，此係已知於一位熟悉此技藝的專業人士，包含 棉線布、***布、與毛氈，碳纖維織物、及天然的纖維素 的織物如牛皮紙、棉線紙、及內含玻璃纖維之紙。該補強 塡料可呈單細絲或多細絲纖維的形式且可單獨使用或與另 一類型纖維合倂使用，經由，例如共編織或核鞘、側對側 、橙型或基質與細纖維建構、或已知於一位熟悉纖維生產 技藝的專業人士的其它方法。彼可呈不同形式，例如織布 纖維強化物、非織布纖維強化物、或紙。 較佳的補強塡料包含玻璃纖維。較佳的玻璃纖維其直 徑可在約2至約2 5微米，更佳者約1 〇至約2 0微米， 而更佳者約1 3至約1 8微米。玻璃纖維之長度可在約 0 · 1至約2 0公釐，更佳者約1至約1 〇公釐，而更佳 經濟部智慧財產局員工消費合作社印製 者約2至約8公釐。亦可使用較長的玻璃纖維，例如在所 謂的線上配料，針對長纖維塡充零件，在未使用製粒步驟 的單一步驟方法之中。針對該線上配料之設備係可商購者 ，例如Husky 3 0 0 0 千牛頓（330噸）模製機器， 產自Husky，Ontario，加拿大。使用長纖維複合材料作射出 成形亦敘述於美國專利編號4 ，5 5 9 ，2 6 2 ，頒予 Cogswell 等人及 6 ，258，453 B1，頒予It is about 1 to about 10 weight percent, which is based on the total weight of the composition. If desired, this method may include adding one or more reinforcing materials. Reinforced graves can include, for example, inorganic and organic materials such as fibers, woven fabrics, and non-woven fabrics whose materials are E-, NE-, S-D, and D-type glass and stone central. (Pan) fiber, steam-grown carbon fiber, and especially graphite steam-grown carbon fiber, each having an average diameter of about 3 to about 500 nanometers (see, for example, U.S. Patent No. 4,5 6 Tibbetts et al. 4,6 6 3, ,, 4,8 1 6 4,8 7 6,5,5 8 9 9, 5, 5 9 1 ——, 5.684 and 5,024,818 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, awarded to '4' 572'813, awarded to Arakawa; 23 and 5,165,909, awarded to 1 ^ 111 ^ to '2 8 9' to Komatsu and others, 0 7 'to Arakawa and others, 1 5 2' to To Tennent et al., And 3 to 2, Nahass et al.); Potassium titanate single crystal fiber, silicon carbide fiber, boron carbide fiber, gypsum fiber, alumina fiber, asbestos, iron fiber, nickel fiber, copper fiber, Silicon ore fiber; and the like. This reinforcing material can take the following forms: glass roving cloth, glass cloth, cut glass, hollow glass fiber, glass mat, glass panel mat, and non-woven glass fabric, ceramic fiber fabric, and metal fiber fabric. In addition, synthetic organic reinforcing materials can also be used, including organic polymers that form fibers. This illustrative embodiment of reinforced organic fibers can use poly (ether ketone), polyimide benzoxazole, poly (phenylene sulfide), polyester, aromatic polyimide, aromatic polyimide Or polyetherimide, acrylic resin, and poly (vinyl alcohol). Fluoropolymers such as polytetrafluoroethylene. Also included are natural -91 -_____ This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) Order 583270 A7 B7 V. Description of the invention (19 ) (Please read the notes on the back before filling out this page) Organic fiber, which is known to a professional who is familiar with this technology, including cotton cloth, hemp cloth, and felt, carbon fiber fabric, and natural cellulose Fabrics such as kraft paper, cotton paper, and paper containing fiberglass. The reinforcing material may be in the form of single or multifilament fibers and may be used alone or in combination with another type of fiber, for example, by co-woven or core sheath, side-to-side, orange-type or matrix and fine fibers Other methods of construction, or known to a professional familiar with fiber production techniques. They can take different forms, such as woven fiber reinforcement, non-woven fiber reinforcement, or paper. A preferred reinforcing filler comprises glass fibers. The preferred glass fiber may have a diameter of about 2 to about 25 microns, more preferably about 10 to about 20 microns, and even more preferably about 13 to about 18 microns. The length of glass fiber can be from about 0.1 to about 20 mm, more preferably from about 1 to about 10 mm, and more preferably from about 2 to about 8 mm printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs . It is also possible to use longer glass fibers, for example in so-called in-line batching, for long-fiber filling parts, in a single step method without the use of a granulation step. Equipment for this online batching is commercially available, such as a Husky 300 kilonewton (330 tons) molding machine, manufactured by Husky, Ontario, Canada. The use of long-fiber composites for injection molding is also described in U.S. Patent Nos. 4,559,262, and issued to Cogswell et al. And 6,258,453 B1, awarded to

Montsinger。其中包含用以增加其與聚烯烴或聚（芳醚）相 容性的上漿之玻璃纖維，係特別較佳的。適合的上漿，例 如記述在美國專利編號5，9 9 8，0 2 9，頒予Adzima 等人。適合的玻璃纖維係商購上可獲得者，例如產品編號 147A— 14P (14 微米直徑）及 147A—17P 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（20) (1 7微米直徑），產自Owens Corning。 較佳的補強塡料進一步的包含滑石粉。在滑石粉之物 理特性上沒有特別的限制。較佳的滑石粉可帶有平均粒度 在約0 . 5至約2 5微米。在此範圍之中，宜使用滑石粉 而彼具有平均粒度至高達約1 〇微米，更佳者至高達約5 微米。針對使用一些組成物，宜使用滑石粉彼係符合 F · D . A .(即符合U · S ·食品及藥物管理規定）。 適合的滑石粉包括例如符合F . D . A ·的滑石粉，彼具 有平均粒度在約3 _ 2微米，以CIMPACT®610(C)銷售，產 自 Luzenac ° 補強塡料與聚烯烴之相容性，不僅可用補強塡料表面 上之漿料改進，且可經由在組成物中加入接枝共聚物而改 進，該接枝共聚物中包含聚烯烴骨幹與形成自一或更多環 酐的極性接枝。該材料包含接枝聚烯烴與C 4 - C i 2環酐 之共聚物，例如那些可商購自 Exxon Mobil ?商品名爲 EXXEL0R®，及商購DuPont，商品名爲FUSAB0ND®。適合的 聚烯烴-接枝-環酐共聚物之實施例爲那些聚丙烯-接枝 一聚（順丁烯二酸酐）材料，由E xxon Mobil供給而品名爲 EXXEL〇R®P〇 1020 及產自 DuPont 而品名爲 FUSAB〇ND®M613-05。該材料的適合含量可立即決定且一 般在約0 · 1至約1 0重量百分比，此係基於組成物之總 重。在此範圍之中，聚烯烴-接枝-環酐共聚物的含量至 少約0 . 5重量百分比可爲較佳的。亦在此範圍之中’聚 烯烴-接枝-環酐共聚物的含量在至高達約5重量百分比 _______________ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 583270 A7 B7 ____ 五、發明説明（21) 可爲較佳的。 (請先閲讀背面之注意事項再填寫本頁) 此較佳的補強塡料進一步的包含有機黏土。如在此使 用者，該有機黏土爲層化矽酸鹽黏土，源自層化礦物，其 中有機結構已作化學上加入。此有機結構的說明性實施例 爲三甲基十二碳基銨離子及Ν，Ν’ -雙十二碳基咪唑離 子。因爲在有晶格狀排列的黏土層之表面，，係帶電的， 彼可結合有機離子。考量使用於本發明的層化礦物並無限 制’除了彼能與有機離子進行離子交換。較佳的有機黏土 包含已與有機陽離子及/或鐵化合物進行陽離子交換的層 化礦物。該層化礦物的說明例爲高嶺石類、膠嶺石類、及 可包含氫雲母的依萊石（illite)類、芬矩石（phengite)、布萊 姆石（brammallite)、格魯克石（giauconiite)、青磁石 (celadonite)及其類似者。較佳的層化礦物包含那些經常稱 爲2 : 1層化的矽酸鹽礦物，如白雲母、蛭石、皂石、水 輝石及膠嶺石’其中膠嶺石經常爲較佳的。上述之層化礦 物可合成地製作。然而，通常彼爲天然者及商購者。有機 黏土及其製備，例如記述在美國專利編號 經濟部智慧財產局員工消費合作社印製 4，569，923、4，664，842、 5 ，110，501 、及 5 ，1Θ0 ，454 ，頒予 Knudson, Jr .等人；5，5 3 0，0 5 2 及 5，773，502，頒予丁吐4〇31^等人； 5 ’78 〇’ 376’ 頒予 Gonzales 等人； 6，036，765，頒予 Farrow 等人； 6，228，9〇3 Bl，頒予Beall等人；及 本紙張尺度適用中國國家標準（CNS ) A4^iT7l^x297/i^l---*- 583270 A7 B7 五、發明説明（22) 6，262 ’162 B1，頒予 Lan 等人。 (請先閲讀背面之注意事項再填寫本頁) 該組成物包含補強塡料含量在約1至約5 0重量百分 比，較佳者約5至約5 0重量百分比，此係基於組成物之 總重。當補強塡料爲有機黏土，宜使其含量在至少約5重 量百分比，更佳者在至少約1 0重量百分比。亦當補強塡 料爲有機黏土，宜使彼含量在至高達約4 5重量百分比， 更佳者至高達約5 0重量百分比。 該組成物可視需要而進一步的包含聚丙烯-聚苯乙烯 接枝共聚物。聚丙烯-聚苯乙烯接枝共聚物在此定義爲一 種接枝共聚物，而其中具有丙烯聚合物骨幹與一或更多的 苯乙烯聚合物接枝。 經濟部智慧財產局員工消費合作社印製 可形成聚丙烯-聚苯乙烯接枝共聚物的骨幹或基材之 丙烯聚合物材料爲（a)丙烯之均聚物；（b)丙烯與烯 烴之雜排共聚物，彼係選自由乙烯與C 4 - C i Q烯烴所組 成之類群，其限制條件爲，當此烯烴爲乙烯，聚合的乙烯 含量至高達約1 0重量百分比，較佳者至高達約4重量百 分比，且當烯烴爲C 4 一 C i Q烯烴，此C 4 一 C i。烯烴的 聚合含量爲至高達約2 0重量百分比，較佳者至高達約 1 6重量百分比；（c )丙烯與至少二種烯烴之雜排三聚 物，該二種烯烴係選自由乙烯與C 4 一 C !。^ 一烯烴所組 成的類群，其限制條件爲聚合的C 4 - C i。α -烯烴含量 至高達約2 0重量百分比，較佳者至高達約1 6重量百分 比，而且，當乙烯爲烯烴之一，聚合的乙烯含量至高達約 5重量百分比，較佳者至高達約4重量百分比；或（d ) _______ -95-__ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 Α7 Β7 五、發明説明（23) (請先閱讀背面之注意事項再填寫本頁) 衝擊改良型丙烯之均聚物或雜排共聚物，該衝擊改良型丙 烯係在反應器中與經由物理摻合而使用乙烯一丙烯單體橡 膠作衝擊改良，在改良的聚合物中，乙烯一丙烯單體橡膠 含量在約5至約3 0重量百分比，且在橡膠中乙烯含量約 7至約7 0重量百分比，且較佳者約1 〇至約4 0重量百 分比。此C 4 一 C i Q烯烴包含線性的及分枝的C 4 一 C i 〇 α -烯烴，例如1 一 丁烯、1—戊烯、3 -甲基一 1— 丁 烯、4 一甲基—1 一戊烯、1—己烯、3 ，4 —二甲基— 1 一 丁烯、1—戊烯、1 一辛烯、3 —甲基—己烯、及其 類似者。丙烯均聚物及衝擊改良型丙烯均聚物爲較佳的丙 烯聚合物材料。雖然不是較佳的，亦可用作爲丙烯聚合物 材料者’爲丙烯均聚物及雜排共聚物而其中經使用乙烯一 丙烯-雙烯單體橡膠，該橡膠中的雙烯含量在約2至約8 重量百分比。適合的二烯包括二環戊二烯、1 ，6 -己二 烯、亞乙基原冰片烯，及其類似者。 經濟部智慧財產局員工消費合作社印製 本文之”苯乙烯聚合物”，係指在聚丙烯-聚苯乙烯 接枝共聚物中，展現在丙烯聚合物材料骨幹上的接枝聚合 物’意指（a )苯乙烯或烷基苯乙烯之均聚物，而在該烷 基苯乙烯上帶有至少一種C i - C 4線性的或分枝的烷基環 取代基，特別爲對-烷基苯乙烯；（b)由（a)單體相 互間以所有比例構成之共聚物；及（c )至少一種（a ) 單體與其α -甲基衍生物之共聚物，該衍生物例如有α 一 甲基苯乙烯，其中α -甲基衍生物構成共聚物重量約1至 約 4 0 ( % ) 〇 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） 583270 A7Montsinger. Especially preferred are glass fibers that contain sizing to increase their compatibility with polyolefins or poly (aryl ethers). A suitable sizing is described, for example, in U.S. Patent Nos. 5,9,8,209, and issued to Adzima et al. Suitable glass fiber is commercially available, such as product numbers 147A-14P (14 micron diameter) and 147A-17P. This paper size is applicable to China National Standard (CNS) A4 size (210X297 mm) 583270 A7 B7 Ministry of Economy Wisdom Printed by the Consumer Affairs Cooperative of the Property Bureau V. Invention Description (20) (17 micron diameter), produced by Owens Corning. The preferred reinforcing material further comprises talc. There are no particular restrictions on the physical properties of talc. The preferred talc may have an average particle size of from about 0.5 to about 25 microns. Within this range, talc is preferably used and has an average particle size of up to about 10 microns, more preferably up to about 5 microns. For the use of some components, talc should be used, which is in accordance with F · D · A. (That is, in accordance with U · S · food and drug management regulations). Suitable talc powders include, for example, talc powders that comply with F.D.A., which have an average particle size of about 3-2 microns, are sold as CIMPACT® 610 (C), and are produced from Luzenac ° Reinforced Concrete Compatible with Polyolefins It can be improved not only by the slurry on the surface of the reinforced concrete, but also by adding a graft copolymer to the composition, which contains a polyolefin backbone and a polarity formed from one or more cyclic anhydrides. graft. This material includes copolymers of grafted polyolefins and C 4 -C i 2 cyclic anhydrides, such as those commercially available from Exxon Mobil® under the trade name EXXEL0R® and commercially available DuPont under the trade name FUSABOND®. Examples of suitable polyolefin-grafted-cyclic anhydride copolymers are those polypropylene-grafted monopoly (maleic anhydride) materials supplied by E xxon Mobil under the name EXXELOR® P〇1020 and products From DuPont under the designation FUSABOND® M613-05. The appropriate content of the material can be determined immediately and is generally from about 0.1 to about 10 weight percent, based on the total weight of the composition. Within this range, a content of the polyolefin-graft-cyclic anhydride copolymer of at least about 0.5 weight percent may be preferred. Also within this range, the content of polyolefin-graft-cyclic anhydride copolymers is up to about 5 weight percent. This paper size applies to China National Standard (CNS) A4 (210X297 mm) (please read the back first) (Notes on this page, please fill out this page) 583270 A7 B7 ____ V. Description of the invention (21) may be better. (Please read the notes on the back before filling out this page) This better reinforcing material further contains organic clay. As used herein, the organoclay is a layered silicate clay derived from layered minerals in which the organic structure has been chemically added. Illustrative examples of this organic structure are trimethyldodecylammonium ion and N, N'-bisdodecylimidazole ion. Because on the surface of the clay layer with a lattice arrangement, the charged ones can bind organic ions. It is considered that the layered mineral used in the present invention is not limited except that it can be ion-exchanged with organic ions. Preferred organic clays include layered minerals which have been cation exchanged with organic cations and / or iron compounds. Illustrative examples of this layered mineral are kaolinite, kaolinite, and illite, phengite, brammallite, and gramstone, which can contain hydrogen mica. (Giauconiite), celadonite, and the like. The preferred stratified minerals include those silicate minerals often referred to as 2: 1 stratified minerals, such as muscovite, vermiculite, soapstone, hectorite, and colloidal stone. Of these, colloidal stone is often preferred. The above-mentioned layered minerals can be produced synthetically. However, they are usually natural and commercial. Organoclay and its preparation, for example, described in US Patent No. 4, Intellectual Property Office of the Intellectual Property Office, Employees' Cooperatives printed 4,569,923, 4,664,842, 5, 110,501, and 5,1Θ0,454, awarded to Knudson , Jr. et al .; 5, 5 3 0, 0 5 2 and 5, 773, 502, awarded to Dingtu 4〇31 ^ et al .; 5 '78 〇 '376' to Gonzales et al .; 6, 036, 765, awarded to Farrow et al .; 6,228,903 Bl, awarded to Beall et al .; and this paper size applies Chinese National Standard (CNS) A4 ^ iT7l ^ x297 / i ^ l --- *-583270 A7 B7 V. Description of Invention (22) 6,262 '162 B1, awarded to Lan et al. (Please read the precautions on the back before filling this page) The composition contains a reinforcing material content of about 1 to about 50 weight percent, preferably about 5 to about 50 weight percent, based on the total composition weight. When the reinforced concrete is organic clay, its content should be at least about 5 weight percent, and more preferably at least about 10 weight percent. When the reinforcing material is organic clay, its content should be up to about 45 weight percent, more preferably up to about 50 weight percent. The composition may further include a polypropylene-polystyrene graft copolymer as required. A polypropylene-polystyrene graft copolymer is defined herein as a graft copolymer in which a propylene polymer backbone is grafted with one or more styrene polymers. The propylene polymer material printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to form the backbone or substrate of a polypropylene-polystyrene graft copolymer is (a) a homopolymer of propylene; (b) a mixture of propylene and olefins Row copolymers, which are selected from the group consisting of ethylene and C 4-C i Q olefins. The limiting condition is that when this olefin is ethylene, the polymerized ethylene content is up to about 10% by weight, preferably up to About 4 weight percent, and when the olefin is a C 4 -C i Q olefin, this C 4 -C i. The polymerization content of olefins is up to about 20% by weight, preferably up to about 16% by weight; (c) a heterotrimer of propylene and at least two olefins selected from the group consisting of ethylene and C 4 One C !. ^ The group consisting of an olefin is restricted to polymerized C 4-C i. The α-olefin content is up to about 20 weight percent, preferably up to about 16 weight percent, and when ethylene is one of the olefins, the polymerized ethylene content is up to about 5 weight percent, preferably up to about 4 Weight percentage; or (d) _______ -95 -__ This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 583270 Α7 Β7 5. Invention Description (23) (Please read the precautions on the back before filling in this Page) Impact modified propylene homopolymers or heteropolymers. The impact modified propylene is used in the reactor and physically blended with ethylene-propylene monomer rubber for impact modification. Among the modified polymers, The ethylene-propylene monomer rubber content is about 5 to about 30 weight percent, and the ethylene content in the rubber is about 7 to about 70 weight percent, and preferably about 10 to about 40 weight percent. The C 4 -C i Q olefins include linear and branched C 4 -C i 0α-olefins, such as 1-butene, 1-pentene, 3-methyl- 1-butene, 4-methyl —1-pentene, 1-hexene, 3,4-dimethyl-1—butene, 1-pentene, 1-octene, 3-methyl-hexene, and the like. Propylene homopolymers and impact modified propylene homopolymers are preferred propylene polymer materials. Although it is not preferable, it can also be used as a propylene polymer material, which is a propylene homopolymer and a hetero-copolymer, in which ethylene-propylene-diene monomer rubber is used, and the diene content in the rubber is about 2 to Approximately 8 weight percent. Suitable dienes include dicyclopentadiene, 1,6-hexadiene, ethylidenenorbornene, and the like. The "Styrenic Polymer" printed by the Employee Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs refers to the graft polymer shown on the backbone of propylene polymer materials in polypropylene-polystyrene graft copolymers. (A) homopolymers of styrene or alkylstyrene with at least one Ci-C4 linear or branched alkyl ring substituent on the alkylstyrene, especially p-alkyl Styrene; (b) a copolymer consisting of (a) monomers in all proportions with each other; and (c) a copolymer of at least one (a) monomer and its α-methyl derivative, such as α Monomethylstyrene, in which the α-methyl derivative constitutes the copolymer. The weight of the copolymer is about 1 to about 40 (%). The paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 583270 A7.

經濟部智慧財產局員工消費合作社印製 聚丙烯-聚苯乙烯接枝共聚物將典型地包含約1 〇至 約9 〇重量百分比的丙烯聚合物骨幹及約9 〇至約1 〇重 量百分比的苯乙烯聚合物接枝。在此類範圍之中，丙儀聚 合物骨幹可較佳者佔至少約2 〇重量百分比，的總接枝共 聚物；且丙烯聚合物骨幹可較佳者佔至高達約4 〇之重量 百分比總接枝共聚物。亦在此類範圍之中，苯乙烯聚合物 接枝可較佳者佔至少約5 0重量百分比，更佳者在至少約 6 0重量百分比，佔總接枝共聚物。 製備聚丙烯-聚苯乙烯接枝共聚物，例如記述在美國 專利編號4，990，558頒予DeNicola，h · 等人。 適合的聚丙烯-聚苯乙烯接枝共聚物亦可商購，例如 P1045HI 及 P1085HI ，產自 Basel 卜 當存在’聚丙燦-聚苯乙烯接枝共聚物之含量可在約 0 · 5至約2 0重量百分比，此係基於組成物之總重。在 此範圍之中，宜使用至少約1 · 〇重量百分比的聚丙烯一 聚苯乙烯接枝共聚物。亦在此範圍之中，彼亦可較佳地使 用至高達約1 5重量百分比，更佳者至高達約1 〇重量百 分比，而更佳者至高達約8重量百分比的聚丙烯一聚苯乙 烯接枝共聚物。 s亥組成物可視需要而進一步的包含乙燦/ ^ 一烯烴彈 性體共聚物。此α -烯烴共聚物之成分可至少爲一種c 3 -C !。α -烯烴。較佳的α -烯烴包括丙烯、1 一丁烯、及 1 一辛烯。此彈性體共聚物可爲雜排共聚物，而其中具有 約2 5至約7 5重量百分比的乙烯及約7 5至約2 5重量 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） ^2Ζ — =1 mi m« (請先閱讀背面之注意事項再填寫本頁) -·裝·The polypropylene-polystyrene graft copolymer printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs will typically contain about 10 to about 90 weight percent propylene polymer backbone and about 90 to about 10 weight percent benzene Ethylene polymer is grafted. Within this range, the backbone of the acrylic polymer may preferably account for at least about 20% by weight of the total graft copolymer; and the backbone of the propylene polymer may preferably account for up to about 40% by weight of the total graft copolymer. Graft copolymer. Also within this range, styrene polymer grafting may preferably account for at least about 50 weight percent, and more preferably at least about 60 weight percent for the total graft copolymer. The preparation of polypropylene-polystyrene graft copolymers is described, for example, in U.S. Patent No. 4,990,558 to DeNicola, h. Et al. Suitable polypropylene-polystyrene graft copolymers are also commercially available, such as P1045HI and P1085HI, produced by Basel. The content of 'polypropylene-polystyrene graft copolymers can be in the range of about 0.5 to about 2 0 weight percent, which is based on the total weight of the composition. Within this range, it is preferred to use at least about 1.0 weight percent of a polypropylene-polystyrene graft copolymer. Also within this range, it can be preferably used up to about 15 weight percent, more preferably up to about 10 weight percent, and more preferably up to about 8 weight percent polypropylene-polystyrene. Graft copolymer. The composition may further include an ethylene / ^-olefin elastomer copolymer as required. The α-olefin copolymer may have at least one type of c 3 -C!. α-olefins. Preferred alpha-olefins include propylene, 1-butene, and 1-octene. The elastomer copolymer may be a hetero-copolymer, and it has about 25 to about 75 weight percent of ethylene and about 75 to about 25 weight. The paper size is applicable to China National Standard (CNS) A4 specifications (210X297) ^) ^ 2Z — = 1 mi m «(Please read the notes on the back before filling this page)-· 装 ·

、1T 583270 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明（25) 百分比的α -烯烴。在此類範圍之中，宜使用至少約4 0 重量百分比的乙烯；且宜使用至高達約6 0重量百分比乙 烯。亦在此類範圍之中，宜使用至少約4 0重量百分比的 α -烯烴；且宜使用至高達約6 0重量百分比的α -烯烴 。乙烯/ α -烯烴彈性體共聚物可典型地帶有熔融流動指 數在約0 · 1至約2 0 g / 1 0分鐘，條件在2 . 1 6公 斤與200°C之下，且密度在約0 · 8至約〇 · 9g/毫 升。 特別較佳的乙烯/ α -烯烴彈性體共聚物橡膠包括乙 烯-丙烯橡膠、乙烯-丁烯橡膠、乙烯-辛烯橡膠、及其 混合物。 乙烯/ α -烯烴彈性體共聚物可依據已知的方法製備 ，或在，商購上得到，例如純乙烯-丙烯橡膠 VIS TALON® 878 由 Exxon Mobil Chemical 銷售，及乙烯一丁 烯橡膠如 EXACT®4 0 3 3 由 Exxon Mobil Chemical 銷售。乙烯/α-烯烴彈性體共聚物亦可呈聚烯烴摻合物在商 購上得到，例如乙烯-丙烯橡膠預分散在聚丙烯中，銷售產物 編號爲Profax 7624及Profax 8023,產自Basell，及乙烯-丁烯 橡膠預分散在聚丙烯中，銷售爲Catalloy K021 P，產自Basell 〇 當存在，乙烯/ α -烯烴彈性體共聚物之含量可在約 〇· 5至約2 5重量百分比，此係基於組成物之總重。在 此範圍之中，宜使用至少約1重量百分比，更佳者在至少 約3重量百分比的乙烯/ α -烯烴彈性體共聚物。亦在此 __-9R-___ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 Χ297公釐） (請先閱讀背面之注意事項再填寫本頁) 583270 A7 B7 五、發明説明（26) 範圍之中，宜使用至高達約2 0重量百分比，更佳者至高 達約1 5重量百分比的乙烯/ ^ -烯烴彈性體共聚物。 供選擇地，乙烯/ α -烯烴彈性體共聚物之含量可表 示爲聚烯烴與乙烯/ ^ -烯烴彈性體共聚物之總量的分率 。如此，當乙烯/ α -烯烴彈性體共聚物存在，其含量可 表現以約1至約3 0重量百分比，較佳者約3至約3 0重 量百分比，此係基於聚烯烴與乙烯/ α -烯烴彈性體共聚 物之合倂重量。 此組成物進一步的包含烯基芳香族化合物與共軛雙燦 之未氫化嵌段共聚物（以下稱爲”未氫化嵌段共聚物”) 。此未氫化嵌段共聚物爲一種共聚物而其中包含（Α)至 少一種源自烯基芳香族化合物的嵌段及（Β )至少一嵌段 係源共軛雙烯，其中在嵌段（Β )中脂肪族不飽和基團 之含量尙未經由氫化而降低。烯基芳香族化合物（A )及 共軛雙烯（B )，在以上氫化嵌段共聚物之描述中已詳細 定義。嵌段（A )與（B )之排列包含線性的結構及所謂 的輻射狀的發射嵌段（teleblock )結構而彼帶有枝鏈。 經濟部智慧財產局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁} 此類結構中較佳者爲線性的結構而其中包含二嵌段（ A — B嵌段）、三嵌段（A - Β — A嵌段或B— A — B嵌 段）、四嵌段（A - Β — A - B嵌段）、及五嵌段（A〜 Β — A - B—A嵌段或B— A — B — A — B嵌段）結構與 內含A與B嵌段總量在6或更多的線性結構。更佳者爲二 嵌段、三嵌段、及四嵌段結構，而以A - B - A三嵌段結 構係特別較佳的。 __ - 29 -本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 _ 五、發明説明（27) (請先閲讀背面之注意事項再填寫本頁) 該未氫化嵌段共聚物可包含約1 〇至約9 0重量百分 比的（A )嵌段。在此範圍之中，宜使用至少約2 0重量 百分比的（A )嵌段。亦在此範圍之中，宜使用至高達約 8 0重董白‘分比的（A )嵌段。 特別較佳的未氫化嵌段共聚物包括苯乙烯-丁二烯-苯乙烯三嵌段共聚物。 適合的未氫化嵌段共聚物之製備，可經由已知的方法 或商購上得到，例如 KRATON®D系列聚合物，包含 KRATON®D 11〇 1 及 D 1102，Kraton Polymers(先前爲 Shell Chemical之部門）。此適合進一步包含苯乙烯-丁二烯輻射狀 的發射嵌段（teleblock)共聚物之未氫化嵌段共聚物例如可得 到自 K-RESIN®KR〇1、KR03、KR05、及 KR10,由 Chevron Phillips Chemical 公司銷售。 經濟部智慧財產局員工消費合作社印製 當存在，該未氫化嵌段共聚物可使用約〇 . 5至約 2 0重量百分比，此係基於組成物之總重。在此範圍之中 ，宜使用至少約1重量百分比，更佳者在至少約2重量百 分比的未氫化嵌段共聚物。亦在此範圍之中，宜使用至高 達約1 5重量百分比，較佳者至高達約1 〇重量百分比的 未氫化嵌段共聚物。 此組成物可視需要而進一步的包含烯基芳香族化合物 與共軛雙烯之氫化嵌段共聚物，其中烯基芳香族含量在約 1 0至少於4 0重量百分比。針對此成分，烯基芳香族化 合物及共軛雙烯化合物，係相同於那些以上針對內含烯基 芳香族含量在4 〇至約9 0重量百分比的氫化嵌段共聚物 ________ -30-_ — 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 經濟部智慧財產局員工消費合作社印製 A7 __ B7 _五、發明説明（28) 所定義者。該材料爲商購上可獲得者，例如 KRAT〇N®6 1 650 及 6 1 652 產自 Kraton Polymers。當存在，其 中具有烯基芳香族含量在約1 0至少於4 0重量百分比的 氫化嵌段共聚物，可使用約1重量百分比至約2 0重量百 分比，此係基於組成物之總重。 除上述成分之外，此組成物可包含一或更多在此技藝 中已知的添加劑。該添加劑可包括例如安定劑、模製離型 劑、加工助劑、阻焰劑、滴液阻滯劑、成核劑、U V阻隔 劑、染料、顏料、微粒塡料（即縱橫比少於約3的塡料） 、抗氧化劑、抗靜電劑、發泡劑、及其類似者。該添加劑 係在此技藝中熟知的且可立即決定合適的用量。 在一項具體實施例之中，該組成物包含：約1 0至約 5 5重量百分比的聚（芳醚）；約3至約5 0重量百分比 的聚（烯基芳香族）樹脂；其中聚（烯基芳香族）樹脂的 含量至少約1 0之重量百分比，佔聚（芳醚）與聚（烯基 芳香族）樹脂之總量；約1 0至約6 0重量百分比的聚烯 烴；約1至約2 0重量百分比的烯基芳香族化合物與共軛 雙烯之氫化嵌段共聚物而其中烯基芳香族含量在約4 0至 約9 0重量百分比；約1至約2 0重量百分比的烯基芳香 族化合物與共軛雙烯之未氫化嵌段共聚物；及約1至約 5〇之重量百分比補強塡料；其中所有重量百分比係基於 該組成物之總重。 在另一具體實施例之中，該組成物包含：約1 〇至約 5 5重量百分比的聚（芳醚）·，約1至約5 0重量百分比 _ (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 Α7 Β7 五、發明説明（29) (請先閲讀背面之注意事項再填寫本頁) 的聚（烯基芳香族）樹脂；約1 0至約6 0重量百分比的 聚烯烴；約1至約2 0重量百分比的烯基芳香族化合物與 共軛雙烯之氫化嵌段共聚物而其中烯基芳香族含量在約 4 0至約9 0重量百分比；約1至約50之重量百分比補 強塡料；及約0 · 5至約2 0重量百分比的聚丙烯-聚苯 乙烯接枝共聚物或烯基芳香族化合物與共軛雙烯之未氫化 嵌段共聚物；其中所有重量百分比係基於該組成物之總重 〇 在另一具體實施例之中，該組成物包含：約1 0至約 5 5重量百分比的聚（芳醚）；約1至約5 0重量百分比 的聚（烯基芳香族）樹脂；約1 〇至約6 0重量百分比的 聚烯烴；約1至約2 0重量百分比的烯基芳香族化合物與 共軛雙烯之氫化嵌段共聚物而其中烯基芳香族含量在約 4 〇至約9 0重量百分比；約1至約5 0之重量百分比補 強塡料；約0 · 5至約2 0重量百分比的聚丙烯-聚苯乙 經濟部智慧財產局員工消費合作社印製 烯接枝共聚物或烯基芳香族化合物與共軛雙烯之未氫化嵌 段共聚物；及約〇 · 5至約2 5重量百分比的乙烯/ α -烯烴彈性體共聚物；其中所有重量百分比係基於該組成物 之總重。 在另一具體實施例之中，此熱塑性組成物包含：一種 聚（芳醚）；一種聚（燒基芳香族）樹脂而其含量在至少 約1 0重量百分比’佔聚（芳醚）與聚（；^基芳香族）樹 脂之總量；一種聚烯烴；一種嫌基芳香族化合物與共轭雙 烯之氫化嵌段共聚物’其中儲基芳香族含量在約4 0至約 __________-39 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公楚） 583270 A7 B7____ 五、發明説明（30) 9 0重量百分比；一種聚烯烴-接枝-環酐共聚物；及一 種補強塡料。 在另一具體實施例之中，此熱塑性組成物包含下列之 反應產物：一種聚（芳醚）；一種聚（烯基芳香族）樹脂 而其含量在至少約1 0之重量百分比，佔聚（芳醚）與聚 (烯基芳香族）樹脂之總量；一種聚烯烴；一種烯基芳香 族化合物與共軛雙烯之氫化嵌段共聚物，其中烯基芳香族 含量在約4 0至約9 0重量百分比；一種烯基芳香族化合 物與共軛雙烯之未氫化嵌段共聚物；及一種補強塡料。 當此組成物定義爲內含多重成分，彼將可瞭解各成分 爲化學上明顯的，特別地當一種單一化學化合物可滿足多 於一種成分之定義。 達成本發明組成物之製備，通常可經由僅僅於用以形 成本質摻合物之條件下，將各成分摻合。該條件經常包含 在單螺桿或雙螺桿類型押出機或相似的混合裝置中作混合 ，而在該類裝置中可將剪力施用於各成分。 較佳的摻合方法詳細敘述於共申請案u . S ·編號 09/682，929，申請日期爲十一月1日， 2 ◦ 0 1年，彼全文在此加入。在本發明一項較佳具體實 施例之中，將各成分在一押出機之中摻合，該押出機具有 至少二個加入口，將至少約5 0 %的，較佳者在至少約 7 5 %的，更佳者所有的聚（芳醚）作逆流加入，且將至 少約5 0 %儀，較佳者在至少約7 5 %的，而更佳者在 1 0 0 %的聚烯烴作順流加入，且將至少約5 0 %的，較 _______- __ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) -裝· 訂 經濟部智慧財產局員工消費合作社印製 583270 A7 B7 五、發明説明（31 ) (請先閱讀背面之注意事項再填寫本頁) 佳者在至少約7 5 %的，更佳者所有的玻璃纖維作順流加 入。在另一項本發明較佳具體實施例之中，使用至少二混 合階段將各成分摻合，其中包含逆流混合與順流混合，其 中逆流混合爲高能量混合其特色在於至少二混合元件及/ 或混合區段的長度不少於約1英寸。順流混合可爲如上述 之高能量混合或低能量混合，取決於組成物及所欲求之組 成物性質。 該組成物適用於形成各種物品或物品之零件，使用各 種模製技藝，例如射出成形、吹模成形、押出成形、片押 出成形、膜押出成形、輪廓押出成形、拉擠成形、壓縮模 製、熱成形、壓力成形、水壓成形、真空成形、發泡模製 、及其類似者。當使用吹模成形而自組成物形成物品，可 達成密度降低高達約9 5 %。 該組成物展現改進的性質平衡。尤其，該組成物展現 介於勁度與衝擊強度之間改進的平衡。例如該組成物可展 現撓曲模數，於2 3 °C，其測量係依據A S T Μ D 7 9 Ο ，在至少約3 Ο Ο，較佳者在至少約3 5 Ο，千 經濟部智慧財產局員工消費合作社印製 磅每平方英寸（k p s i )。此組成物可展現於2 3 °C的 懸臂樑凹口衝擊強度，其測量依據A S T M D 2 5 6 ，在至少約1呎一磅每英寸（f t 一 1 b / i η ))，較 佳者在至少約1 . 5 ( f t — 1 b / i η )，更佳者在至 少約2 ( f t - 1 b / i η )。此組成物可展現熱變形溫 度（H D T )，於6 6 P s i之下，其測量係依據 A S T M D 6 4 8，在至少約2 8 Ο ( °F )，較佳者在 —__Γ.34-_ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 ___ B7 五、發明説明（32) (請先閲讀背面之注意事項再填寫本頁) 至少約2 9 0 ( T )，更佳者在至少約3 0 0 ( T )，且 在2 6 4 P s i之下的H D T在至少約2 0 0 ( °F )， 較佳者在至少約2 2 0 ( °F )，更佳者在至少約2 4 0 ( °F )。此組成物可展現斷裂點的抗張伸長，其測量係依據 A S T M D 6 3 8，在至少約4 %，較佳者在至少約5 %，更佳者在至少約6 %。 該組成物可展現低的性質變異性，無論在各批與各批 之間，或於同批內在各試樣與各試樣之間。變異性之計算 可呈百分比形式，將1 〇 〇乘以各性質的標準差再除以該 性質的平均値。此組成物可展現各試樣與各試樣（即在同 批之中式）的2 3 °C撓曲模數之變異性在少於約1 0百分 比，較佳者在小於約5 %，更佳者在小於約3 %。此組成 物可性針對2 3 °C的懸臂樑凹口衝擊強度，其測量依據 A S T M D 2 5 6 ，展現各批與各批之間的變異少於約 1 5 % ’較佳者在少於約1 0 %，更佳者在少於約5 %。 由以下非限制實施例，將進一步的說明本發明。 實施例1 一 4，比較例1 一 1 〇 經濟部智慧財產局員工消費合作社印製 使用於所有實施例配方中之生料總結於表1。 成分1 - 1 1係在一袋子之中徹底作手工混合。除非 另有說明’所有成分含量表示爲重量份。然後此袋子之內 容物經由進料器作進料且進入押出機喉嚨（押出機起始進 入點）°然後將成分1 2 - 1 4以順流送入押出機（進入 點位於於進料喉嚨之後，大約1 〇筒之5的位置）。 在表2中給予特定配方的實施例與比較例。使用3〇 -----^ -__ 本紙張尺度適用中國國家榡準（CNS ) A4規格（210X 297公釐） 583270 A7 __ _ B7 五、發明説明（33) m m共旋轉雙螺桿押出機，將試樣押出。將摻合物作熔融 押出，其條件爲 5 2 0 ( °F ) ，4 5 0 — 5 0 0 r p m， (請先聞讀背面之注意事項再填寫本頁) 及3 0 - 5 5磅每小時。出自押出機的熔融物將壓經3 -孔壓模而生產熔融股。經由將彼通過冷水浴而使此類股快 速冷卻。將此冷卻的股切爲顆粒。將此顆粒在烤箱於 2 0 0 ( °F )乾燥2 — 4小時。 模製A S TM零件，在1 2 0噸模製機器（製造業者 :V a n D o m )上，使用 1 〇 〇 — 1 2 〇（°F )的模 製溫度及4 5 0 - 5 5 0 ( °F )的筒溫。 零件測試係依據A S T Μ方法。撓曲模數測量係依據 A S T M D790。在64與264 P si之下的熱 經濟部智慧財產局員工消費合作社印製 變形溫度（H D T )，其測量係依據A S T M D 6 4 8 。懸臂樑凹口及無凹口衝擊強度之測量係依據A S 丁 Μ D 2 5 6。達諾持（Dynatup )(落鏢）總能量，於最大應 力的能量，及失效能量之測量係依據A S T Μ D376 3。斷裂點的抗張伸長、斷裂抗張強度、及抗張 強度降伏點之測量係依據A S T M D 6 3 8。其中値各 性質的平均及標準差，係代表五支試樣之結果。 結果列於表2。相較於缺少玻璃纖維的試樣，內含玻 璃纖維的試樣展現了高撓曲模數與熱變形溫度，而維持良 好的衝擊強度。 _____ _ Op 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 五、發明説明（34) 經濟部智慧財產局員工消費合作社印製1T 583270 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (25) Percentage of α-olefins. Within such ranges, at least about 40 weight percent ethylene should be used; and up to about 60 weight percent ethylene should be used. Also within this range, it is preferred to use at least about 40 weight percent alpha-olefins; and it is desirable to use up to about 60 weight percent alpha-olefins. The ethylene / α-olefin elastomer copolymer may typically have a melt flow index of from about 0.1 to about 20 g / 1 min, under conditions of 2.16 kg and 200 ° C, and a density of about 0 8 to about 0.9 g / ml. Particularly preferred ethylene /?-Olefin elastomer copolymer rubbers include ethylene-propylene rubber, ethylene-butene rubber, ethylene-octene rubber, and mixtures thereof. Ethylene / α-olefin elastomer copolymers can be prepared according to known methods, or are commercially available, such as pure ethylene-propylene rubber VIS TALON® 878 sold by Exxon Mobil Chemical, and ethylene-butene rubber such as EXACT® 4 0 3 3 is sold by Exxon Mobil Chemical. Ethylene / α-olefin elastomeric copolymers are also commercially available as polyolefin blends, such as ethylene-propylene rubber pre-dispersed in polypropylene, and sold under product numbers Profax 7624 and Profax 8023, produced by Basell, and Ethylene-butene rubber is pre-dispersed in polypropylene and sold as Catalloy K021 P, produced by Basell. When present, the ethylene / α-olefin elastomer copolymer content can range from about 0.5 to about 25 weight percent. Based on the total weight of the composition. Within this range, it is preferred to use at least about 1 weight percent, and more preferably at least about 3 weight percent of the ethylene /?-Olefin elastomer copolymer. Also here __- 9R -___ This paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling out this page) 583270 A7 B7 V. Description of the invention (26) Within the range, it is preferred to use up to about 20 weight percent, more preferably up to about 15 weight percent ethylene / ^-olefin elastomer copolymer. Alternatively, the content of the ethylene / α-olefin elastomer copolymer may be expressed as a fraction of the total amount of the polyolefin and the ethylene / ^-olefin elastomer copolymer. As such, when the ethylene / α-olefin elastomer copolymer is present, its content can be expressed as about 1 to about 30 weight percent, preferably about 3 to about 30 weight percent, based on polyolefin and ethylene / α- Combined weight of olefin elastomer copolymer. This composition further contains an unhydrogenated block copolymer (hereinafter referred to as "unhydrogenated block copolymer") of an alkenyl aromatic compound and a conjugated dican. The unhydrogenated block copolymer is a copolymer containing (A) at least one block derived from an alkenyl aromatic compound and (B) at least one block-based conjugated diene, wherein the block (B ) The content of aliphatic unsaturated groups 尙 is reduced without hydrogenation. The alkenyl aromatic compound (A) and the conjugated diene (B) have been defined in detail in the above description of the hydrogenated block copolymer. The arrangement of the blocks (A) and (B) includes a linear structure and a so-called radial teleblock structure with branched chains. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) The better of this type is a linear structure that contains diblocks (A-B blocks), triblocks Segments (A-B-A block or B-A-B block), tetrablocks (A-B-A-B block), and pentablocks (A ~ B-A-B-A block) Or B—A—B—A—B block) structure and a linear structure containing a total of 6 or more A and B blocks. More preferred are diblock, triblock, and tetrablock structures. A-B-A triblock structure is particularly preferred. __-29-This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) 583270 A7 B7 _ V. Description of the invention (27) (Please read the notes on the back before filling out this page) The unhydrogenated block copolymer may contain about 10 to about 90 weight percent (A) blocks. Within this range, at least about 20 should be used (A) blocks by weight. Also within this range, up to about 80 weight percent (A) blocks are preferred. Particularly preferred unhydrogenated blocks Polymers include styrene-butadiene-styrene triblock copolymers. Suitable unhydrogenated block copolymers can be prepared by known methods or commercially available, such as KRATON® D series polymers, including KRATON® D 1101 and D 1102, Kraton Polymers (previously a division of Shell Chemical). This is suitable for unhydrogenated block copolymers which further comprise a styrene-butadiene radial teleblock copolymer such as Available from K-RESIN® KR〇1, KR03, KR05, and KR10, sold by Chevron Phillips Chemical Company. When printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the unhydrogenated block copolymer can be used for about 0.1%. 5 to about 20 weight percent, which is based on the total weight of the composition. Within this range, it is preferred to use at least about 1 weight percent, and more preferably at least about 2 weight percent of the unhydrogenated block copolymer. Also in Within this range, up to about 15 weight percent, preferably up to about 10 weight percent of the unhydrogenated block copolymer is preferably used. The composition may further include an alkenyl aromatic compound as required. A hydrogenated block copolymer of a family compound and a conjugated diene, wherein the alkenyl aromatic content is about 10 to less than 40 weight percent. For this component, the alkenyl aromatic compound and the conjugated diene compound are the same as Those above are for hydrogenated block copolymers with an alkenyl aromatic content ranging from 40 to about 90% by weight ________ -30-_ — This paper size applies to China National Standard (CNS) A4 (210X297 mm) 583270 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 __ B7 _V. As defined in the invention description (28). This material is commercially available, such as KRATON® 6 1 650 and 6 1 652 from Kraton Polymers. When present, hydrogenated block copolymers having an alkenyl aromatic content of about 10 to less than 40 weight percent can be used from about 1 weight percent to about 20 weight percent, based on the total weight of the composition. In addition to the above ingredients, this composition may contain one or more additives known in the art. The additives may include, for example, stabilizers, mold release agents, processing aids, flame retarders, drip retarders, nucleating agents, UV blockers, dyes, pigments, particulate materials (i.e., aspect ratios of less than about 3)), antioxidants, antistatic agents, foaming agents, and the like. The additive is well known in the art and an appropriate amount can be determined immediately. In a specific embodiment, the composition comprises: about 10 to about 55 weight percent of poly (aryl ether); about 3 to about 50 weight percent of poly (alkenyl aromatic) resin; wherein the poly The content of (alkenyl aromatic) resin is at least about 10% by weight, which accounts for the total amount of poly (aryl ether) and poly (alkenyl aromatic) resin; about 10 to about 60% by weight of polyolefin; about 1 to about 20 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, wherein the alkenyl aromatic content is about 40 to about 90 weight percent; about 1 to about 20 weight percent An unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; and a weight percentage of about 1 to about 50 to reinforce the filler; wherein all weight percentages are based on the total weight of the composition. In another specific embodiment, the composition includes: about 10 to about 55 weight percent of poly (arylene ether) ·, about 1 to about 50 weight percent of _ (Please read the precautions on the back before filling (This page) This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) 583270 Α7 Β7 V. Description of the invention (29) (Please read the precautions on the back before filling this page) Poly (alkenyl aromatic) ) Resin; about 10 to about 60 weight percent polyolefin; about 1 to about 20 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, wherein the alkenyl aromatic content is about 40 to about 90 weight percent; about 1 to about 50 weight percent reinforcing filler; and about 0.5 to about 20 weight percent of a polypropylene-polystyrene graft copolymer or an alkenyl aromatic compound and An unhydrogenated block copolymer of a conjugated diene; wherein all weight percentages are based on the total weight of the composition. In another specific embodiment, the composition includes: about 10 to about 5 5 weight percent polymer (Aryl ether); about 1 to about 50 weight percent (Alkenyl aromatic) resin; about 10 to about 60 weight percent polyolefin; about 1 to about 20 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, wherein the alkenyl group Aromatic content in the range of about 40 to about 90 weight percent; about 1 to about 50 weight percent of reinforcing materials; about 0.5 to about 20 weight percent of polypropylene-polystyrene employees of the Intellectual Property Office of the Ministry of Economic Affairs Consumer cooperatives print olefin graft copolymers or unhydrogenated block copolymers of alkenyl aromatic compounds and conjugated dienes; and about 0.5 to about 25 weight percent ethylene / α-olefin elastomer copolymers; All weight percentages are based on the total weight of the composition. In another specific embodiment, the thermoplastic composition comprises: a poly (aryl ether); a poly (aromatic-based aromatic) resin, and its content is at least about 10% by weight of the poly (aryl ether) and poly The total amount of (; yl-based aromatic) resins; a polyolefin; a hydrogenated block copolymer of a aryl aromatic compound and a conjugated diene, wherein the storage group aromatic content is about 40 to about __________- 39 This paper size applies to Chinese National Standard (CNS) A4 specifications (210 × 297 Gongchu) 583270 A7 B7____ 5. Description of the invention (30) 90% by weight; a polyolefin-grafted-cyclic anhydride copolymer; and a reinforcing filler. In another embodiment, the thermoplastic composition includes the following reaction products: a poly (arylene ether); a poly (alkenyl aromatic) resin, and the content thereof is at least about 10% by weight, which accounts for the poly ( Total amount of aryl ether) and poly (alkenyl aromatic) resin; a polyolefin; a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, wherein the alkenyl aromatic content is about 40 to about 90 weight percent; an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene; and a reinforcing filler. When the composition is defined as having multiple components, he will understand that each component is chemically obvious, especially when a single chemical compound can satisfy the definition of more than one component. In general, the composition of the present invention can be prepared by blending the ingredients only under conditions for forming a cost-effective blend. This condition often involves mixing in a single-screw or twin-screw type extruder or similar mixing device where shear force can be applied to the ingredients. The preferred blending method is described in detail in the co-application U.S. No. 09 / 682,929, with the application date of November 1, 2 ◦ 01, which is hereby incorporated in its entirety. In a preferred embodiment of the present invention, the ingredients are blended in an extruder, which has at least two inlets, at least about 50%, preferably at least about 7 5%, more preferably all poly (aryl ether) is added countercurrently, and at least about 50% of the meter, preferably at least about 75%, and more preferably 100% polyolefin Join downstream, and at least about 50% will be more than _______- __ This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)-Install · Order 583270 A7 B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (31) (Please read the notes on the back before filling out this page) The best is at least 75%, and the better is owned by Glass fibers are added downstream. In another preferred embodiment of the present invention, the ingredients are blended using at least two mixing stages, including counter-current mixing and co-current mixing, where counter-current mixing is a high-energy mixing characterized by at least two mixing elements and / or The length of the mixing section is not less than about 1 inch. Downstream mixing can be high energy mixing or low energy mixing as described above, depending on the composition and the nature of the desired composition. The composition is suitable for forming various articles or parts of articles, using various molding techniques, such as injection molding, blow molding, extrusion molding, sheet extrusion molding, film extrusion molding, contour extrusion molding, pultrusion molding, compression molding, Thermoforming, pressure forming, hydroforming, vacuum forming, foam molding, and the like. When blow molding is used to form articles from the composition, a density reduction of up to about 95% can be achieved. The composition exhibits an improved balance of properties. In particular, the composition exhibits an improved balance between stiffness and impact strength. For example, the composition can exhibit a flexural modulus at 2 3 ° C, and its measurement is based on AST M D 7 9 Ο, at least about 3 Ο, preferably at least about 3 5 〇, the intellectual property of the Ministry of Economic Affairs Bureau employee consumer cooperatives print pounds per square inch (kpsi). This composition can exhibit the notch impact strength of a cantilever beam at 2 3 ° C. It is measured in accordance with ASTMD 2 5 6 at at least about 1 foot one pound per inch (ft-1 b / i η)), preferably at At least about 1.5 (ft — 1 b / i η), and more preferably at least about 2 (ft-1 b / i η). This composition can exhibit a heat distortion temperature (HDT) below 6 6 P si, and its measurement is based on ASTMD 6 4 8 and at least about 2 8 〇 (° F), preferably at __Γ.34-_ This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 583270 A7 ___ B7 V. Description of the invention (32) (Please read the notes on the back before filling this page) At least about 2 0 (T), More preferably, it is at least about 300 (T), and HDT below 26.4 Psi is at least about 200 (° F), more preferably at least about 220 (° F), more The best is at least about 2 40 (° F). This composition can exhibit tensile elongation at break point, which is measured at least about 4%, preferably at least about 5%, and more preferably at least about 6% according to AS T M D 6 38. The composition can exhibit low variability in properties, whether between batches or batches, or between samples and samples within the same batch. The calculation of variability can be in the form of a percentage, multiplying 1000 by the standard deviation of each property, and then dividing by the average 値 of the property. This composition can show that the variability of the flexural modulus at 23 ° C of each sample and each sample (that is, in the same batch) is less than about 10%, preferably less than about 5%, more The best is less than about 3%. This composition can be used for the impact strength of a cantilever notch at 2 3 ° C. Its measurement is based on ASTMD 2 5 6 and shows that the variation between batches is less than about 15%. 10%, more preferably less than about 5%. The invention is further illustrated by the following non-limiting examples. Examples 1 to 4 and Comparative Example 1 to 1 10 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The raw materials used in the formulations of all the examples are summarized in Table 1. Ingredients 1-1 1 are thoroughly mixed by hand in a bag. Unless stated otherwise, all component contents are expressed in parts by weight. Then the contents of this bag are fed through the feeder and enter the extruder throat (the initial entry point of the extruder) ° Then the ingredients 1 2-1 4 are fed into the extruder in a downstream flow (the entry point is behind the feeding throat) , About 5 positions of 10 tube). Examples and comparative examples of specific formulations are given in Table 2. Use 3〇 ----- ^ -__ This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 583270 A7 __ _ B7 V. Description of the invention (33) mm co-rotating twin screw extruder, Extrude the sample. The blend is extruded under the conditions of 5 2 0 (° F), 4 5 0 — 5 0 0 rpm, (please read the precautions on the back before filling this page) and 3 0-5 5 lbs per hour. The melt from the extruder will be pressed through a 3-hole die to produce molten strands. Such strands are quickly cooled by passing them through a cold water bath. This cooled strand was cut into pellets. Dry the granules in an oven at 2000 (° F) for 2-4 hours. Molded AS TM parts on a 120 ton molding machine (manufacturer: Van Dom) using a molding temperature of 100—120 (° F) and a temperature of 4 50-5 5 0 ( ° F). Part testing is based on the AS T M method. The flexural modulus is measured in accordance with AS T M D790. Deformation temperature (H D T) printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs under 64 and 264 P si. The measurement is based on A S T M D 6 4 8. The cantilever beam notch and no-notch impact strength measurements are based on A S 丁 Μ D 2 5 6. The total energy of Dynatup (Dart), the energy at the maximum stress, and the energy of failure are measured according to AS T M D376 3. The measurement of the tensile elongation at break, the tensile strength at break, and the drop point of tensile strength are based on AS T M D 6 38. Among them, the average and standard deviation of each property represent the results of five samples. The results are shown in Table 2. Compared to samples lacking glass fibers, samples containing glass fibers exhibited high flexural modulus and heat distortion temperature while maintaining good impact strength. _____ _ Op This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) 583270 A7 B7 V. Description of invention (34) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

•I愀 來源 Montell olyolefinslnc.，北美洲(目前爲 BASELL) ExxonMobil Chemical Montell Polyolefins公司 Montell Polyolefmslnc.,北美洲（目前 爲 BASELL) General Electric公司 Huntsman Chemical General Electric公司 Shell Chemical company Shell Chemical company Asahi Chemical，由Marubeni America 公司銷售 ExxonMobil Owens Corning Owens Corning Luzenac 形式 顆粒 顆粒 顆粒 1_ 顆粒 粉末 顆粒 顆粒 顆粒 顆粒 顆粒 顆粒 切股纖維 切股纖維 粉末 描述 同排丙烯聚合物，MFI(200 C/2.16kg)二1.5 乙烯-丙烯共聚物，熔融指數爲190 C/21.6k=6.5 lOmins, pa <R 劉 2 a 幽 糍 裝 K) 工;_ • g Wl 亵π κ _ 踩舶 PP而帶有PS聚合物接枝，其中含有約45 pph的總PP-g-PS 聚(2,6-二甲基伸苯基醚） 均聚苯乙烯，MFR(200 C，5kg)=10.5 g/10mins PS 分子量在230,000 g/mol，％ 丁二烯佔總HIPS 的 10.3% 含有約31%PS 含有約 28%PS，Mwt:77,000 g/mol 含有約66%PS 聚丙烯帶有約0.7 wt%聚(順丁烯二酸酐)接枝 玻璃纖維，長絲直徑=14微米，針對PP基質上漿，平均長度 =4mm 玻璃纖維，長絲直徑=17微米，針對PP基質上漿，平均長度 =4mm 姻 粜 g 賴 、擊 οα cn m β < 5? S 等級 PD403 VISTALON®878 Profax 7624 Interloy P1045HI 0.4 IV Chevron EB3300 GEH 1897 KRATON® D1101 KRATON® 61652 TUFTEC® H1043 EXXELOR® P01020 147A-14P 147A-17P CIMPACT® 610(C) 生料 PP顆粒 EPR PP-EP,HECO-30 P-g-PS —…—一 PPE 00 Ph HIPS SBS 低S SEBS 高S SEBS PP-g-MA 玻璃纖維-14 玻璃纖維_17 滑石粉 r—4 csj CO 寸 1/Ί oo as o ! < οα CO (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -37- 583270 B7 五、發明説明（35) 經濟部智慧財產局員工消費合作社印製 表2· 實施例1 實施例2 實施例3 實施例4 組成 PP-G-PS 10.00 10.00 4.33 4.63 高 S SEBS 10.00 5.0 2.60 10.00 低 S SEBS 0.00 0.00 2.60 0.00 PPE 26.40 15.00 18.1 15.00 HIPS 0.00 0.00 0.00 0.00 xPS 6.60 22.50 12.02 3.75 SBS 15.00 6.93 5.60 4.63 PP顆粒 22.00 22.00 33.36 22.00 EPR 0.00 8.57 0.00 0.00 玻璃纖維-14 10.00 10.00 21.36 40.00 性質 撓曲模數（psi)，平均 408,700 401,800 575,800 1,199,000 撓曲模數（psi)，標準差 32,920 4,108 4,056 25,000 撓曲模數，相對標準差 8.1 1.0 0.7 2.1 HDT,66 psi(°F ) 295 289.8 305.2 312.8 HDT,264 psi(°F ) 257.8 219.8 268 286.7 懸臂樑凹口衝擊 (ft-lb/in)，平均 0.3 0.1 0.1 <0.05 懸臂樑凹口衝擊 (ft-lb/in)，標準差 12.0 4.2 4.5 <2.4 抗張破斷伸長％ 7.76 8.53 7.55 5.01 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -38- 583270 A7 B7 五、發明説明（36) 經濟部智慧財產局員工消費合作社印製 i )cxl嗽 比較例10 5.00 0.00 0.00 60.00 15.00 0.00 0.00 22.00 0.00 0.00 335,400 1,999 0.60 324.0 271.3 寸 Ο o O CN 比較例9 0.10 0.00 0.00 10.00 50.00 0.00 0.00 32.00 0.00 0.00 284,900 wn cn 〇〇 0.29 215.3 178.3 o o cn 比較例8 0.00 P 〇 P 〇 30.0 0.00 0.00 0.00 72.00 0.00 0.00 〇 〇 〇\ CN CN 7,107 | 1 3.10 1 | 252.6 | LJ54.7 1 o o cn 比較例7 0.00 0.00 0.00 10.00 35.00 0.00 0.00 57.00 0.00 0.00 〇 CN 2,181 0.95 216.8 | 1 168.3 1 un o o 13.6 比較例6 0.00 0.00 0.00 45.00 35.00 0.00 0.00 22.00 0.00 0.00 317,200 | !" 1 ^ 〇〇 ιη· τ—< | 284.2 | 1 241.0 1 wn o o 比較例5 10.00 0.00 0.00 20.00 50.00 P 0.00 22.00 0.00 0.00 299,600 ί· i CN 0.92 1 | 233.1 | 1 194.2 1 寸 Ο o o MD 比較例4 0.00 0.00 0.00 60.00 0.00 0.00 0.00 36.00 6.00 0.00 | 257,100 | cn CN VO 1 1.80 1 1 303.8 | 1 218.3 1 CO CN 66.7 — 比較例3 0.00 0.00 0.00 45.00 35.0 0.00 0.00 22.00 0.00 0.00 313,100 un 2.08 287.3 1 240.7 1 寸 ο o o CN 比較例2 10.00 0.00 0.00 20.00 50.00 0.00 0.00 22.00 0.00 0.00 〇 un 1 3,501 1 wn τ—< 1 i | 237.5 | 〇\ t—Η CO o o cn 比較例1 0.00 0.00 0.00 60.00 0.00 0.00 0.00 42.00 0.00 0.00 295,000 υη CN CN 0.96 1 329.7 1 1 255.8 1 寸 ο r—H CN 組成 PP-G-PS 高S SEBS 低S SEBS PPE HIPS XPS SBS PP顆粒 EPR 玻璃纖維-14 性質 撓曲模數(psi),平均 |撓曲模數(psi)，標準差 撓曲模數，相對標準差％) HDT,66 psi(°F) HDT,264 psi(°F) 繼 5今 s s ΪΙ mi s今 as 凹口懸臂樑衝擊，相對標準 差(％) 抗張破斷伸長(％) (請先閲讀背面之注意事項再填寫本頁)• I 愀 Source Montell olyolefinslnc., North America (currently BASELL) ExxonMobil Chemical Montell Polyolefins Montell Polyolefmslnc., North America (currently BASELL) Huntsman Chemical General Electric Company Shell Chemical company Shell Chemical company Asahi Chemical, by Marubeni America company sells ExxonMobil Owens Corning Owens Corning Luzenac form granule granule 1_ granule powder granule granule granule granule granule cut strand fiber cut strand fiber powder Description In-row propylene polymer, MFI (200 C / 2.16kg) Di 1.5 ethylene-propylene copolymerization Material, melt index is 190 C / 21.6k = 6.5 lOmins, pa < R Liu 2 a 糍 装 K) worker; _ • g Wl ππ κ _ stepped on PP with PS polymer grafting, which contains Approximately 45 pph of total PP-g-PS poly (2,6-dimethylphenylene ether) homopolystyrene, MFR (200 C, 5kg) = 10.5 g / 10mins PS molecular weight at 230,000 g / mol,% Butadiene accounts for 10.3% of the total HIPS, contains about 31% PS, contains about 28% PS, Mwt: 77,000 g / mol, contains about 66% PS, polypropylene with about 0.7 wt% poly (cis-butyl Diacid anhydride) Grafted glass fiber, filament diameter = 14 microns, average length = 4 mm for PP matrix sizing, glass fiber, filament diameter = 17 microns, average length = 4 mm for PP matrix sizing, Lai, Οα cn m β < 5? S grade PD403 VISTALON®878 Profax 7624 Interloy P1045HI 0.4 IV Chevron EB3300 GEH 1897 KRATON® D1101 KRATON® 61652 TUFTEC® H1043 EXXELOR® P01020 147A-14P 147A-17P CIMPACT® 610 (C) PP granules EPR PP-EP, HECO-30 Pg-PS —...— One PPE 00 Ph HIPS SBS Low S SEBS High S SEBS PP-g-MA Glass fiber-14 Glass fiber_17 Talc powder r-4 csj CO inch 1 / Ί oo as o! ≪ οα CO (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) -37- 583270 B7 V. Invention Explanation (35) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 · Example 1 Example 2 Example 3 Example 4 Composition PP-G-PS 10.00 10.00 4.33 4.63 High S SEBS 10.00 5.0 2.60 10.00 Low S SEBS 0.00 0.00 2.60 0.00 PPE 26.40 15. 00 18.1 15.00 HIPS 0.00 0.00 0.00 0.00 xPS 6.60 22.50 12.02 3.75 SBS 15.00 6.93 5.60 4.63 PP granules 22.00 22.00 33.36 22.00 EPR 0.00 8.57 0.00 0.00 Glass fiber-14 10.00 10.00 21.36 40.00 Nature flexural modulus (psi), average 408,700 401,800 575,800 1,199,000 flexural modulus (psi), standard deviation 32,920 4,108 4,056 25,000 flexural modulus, relative standard deviation 8.1 1.0 0.7 2.1 HDT, 66 psi (° F) 295 289.8 305.2 312.8 HDT, 264 psi (° F) 257.8 219.8 268 286.7 Cantilever beam notch impact (ft-lb / in), average 0.3 0.1 0.1 < 0.05 Cantilever beam notch impact (ft-lb / in), standard deviation 12.0 4.2 4.5 < 2.4 Tensile elongation at break 7.76 8.53 7.55 5.01 (Please read the notes on the back before filling in this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) -38- 583270 A7 B7 V. Description of Invention (36) Intellectual Property Bureau, Ministry of Economic Affairs Printed by the employee consumer cooperative i) cxl comparative example 10 5.00 0.00 0.00 60.00 15.00 0.00 0.00 22.00 0.00 0.00 335,400 1,999 0.60 324.0 271.3 inch 0 o O CN Comparative example 9 0.10 0.00 0.00 10.00 50.00 0.00 0.00 32.00 0.00 0.00 284,900 wn cn 〇〇0.29 215.3 178.3 oo cn Comparative Example 8 0.00 P 〇P 〇30.0 0.00 0.00 0.00 72.00 0.00 0.00 〇〇 \ CN CN 7,107 | 1 3.10 1 | 252.6 | LJ54.7 1 oo cn Comparative Example 7 0.00 0.00 0.00 10.00 35.00 0.00 0.00 57.00 0.00 0.00 〇CN 2,181 0.95 216.8 | 1 168.3 1 un oo 13.6 Comparative Example 6 0.00 0.00 0.00 45.00 35.00 0.00 0.00 22.00 0.00 0.00 317,200 |! &Quot; 1 ^ 〇〇 ιη · τ— &|; 284.2 | 1 241.0 1 wn oo Comparative example 5 10.00 0.00 0.00 20.00 50.00 P 0.00 22.00 0.00 0.00 299,600 i CN 0.92 1 | 233.1 | 1 194.2 1 inch 0 oo MD Comparative example 4 0.00 0.00 0.00 60.00 0.00 0.00 0.00 36.00 6.00 0.00 | 257,100 | en CN VO 1 1.80 1 1 303.8 | 1 218.3 1 CO CN 66.7 — Comparative Example 3 0.00 0.00 0.00 45.00 35.0 0.00 0.00 22.00 0.00 0.00 313,100 un 2.08 287.3 1 240.7 1 inch ο oo CN Comparative Example 2 10.00 0.00 0.00 20.00 50.00 0.00 0.00 22.00 0.00 0.00 〇un 1 3,501 1 wn τ— < 1 i | 237.5 | 〇 \ t—Η CO oo cn Comparative Example 1 0.00 0.00 0.00 60.00 0.00 0.00 0.00 42.00 0.00 0.00 295,000 υη CN CN 0.96 1 329.7 1 1 255.8 1 inch ο r—H CN Composition PP-G-PS High S SEBS Low S SEBS PPE HIPS XPS SBS PP particles EPR glass fiber-14 nature scratch Modulus of Modulus (psi), Average | Deflection Modulus (psi), Standard Deviation of Modulus of Deflection, Relative Standard Deviation%) HDT, 66 psi (° F) HDT, 264 psi (° F) mi s this as notch Izod impact, relative standard deviation (%) tensile elongation at break (%) (Please read the precautions on the back before filling in this page)

本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 五、發明説明（37) 實施例5 - 9 此類實施例可提供額外的說明，由此組成物可提供卓 越的性質平衡。各試樣之製備及測試如記述於以上實施例 1 - 4。各組成物及性質見如下表3。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 40 本紙張尺度適用中國國家標準（CNS ) A4規格（210X：297公釐） 583270This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 583270 A7 B7 V. Description of the invention (37) Examples 5-9 These examples can provide additional explanations, so the composition can provide excellent Balance of nature. The preparation and testing of each sample are described in Examples 1-4 above. The compositions and properties are shown in Table 3 below. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 40 This paper size applies to China National Standard (CNS) A4 (210X: 297 mm) 583270

7 B 五、發明説明（38) 經濟部智慧財產局員工消費合作社印製 表3 實施例5 實施例6 實施例7 組成物 PPE 15.00 15.00 15.00 Xps 3.75 3.75 19.43 SBS 9.25 9.25 15.00 SEBS H1043 10.00 10.00 10.00 PP，PD403 42.50 42.50 20.00 EPR 7.50 7.50 8.57 PP-g-MA 2.00 2.00 2.00 玻璃纖維-14 10.00 10.00 10.00 性質 撓曲模數，23°C，1/8”（psi) 314,800 315,600 321,300 降伏點撓曲強度，23t，1/8” (psi) 10,310 10,270 10,140 HDT，66 psi，l/8” (°F ) 294.1 291.7 258.9 HDT，264 psi，l/8”（Τ ) 224.4 228.1 218.1 凹口懸臂樑，23t： (ft-lb/in) 3.7 3.8 4.1 凹口懸臂樑，-30°C (ft-lb/in) 2.2 2.3 3.1 無凹口懸臂樑，23t (ft-lb/in) 11.5 11.2 11.9 於最大應力的能量，23°C，7.5 mph(ft-lb) 8.50 8.58 8.91 斷裂抗張強度，23°C (psi) 6,162 6,480 6,293 抗張破斷伸長，23°C (%) 11.47 10.53 11.40 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -41 - 583270 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明（39) 表3 (續） 實施例8 實施例9 組成物 PPE 15.00 15.00 xPS 3.75 19.43 SBS 15.00 15.00 SEBS H1043 10.00 10.00 PP，PD403 44.25 20.00 EPR 0.00 8.57 PP-g-MA 2.00 2.00 玻璃纖維-14 10.00 10.00 性質 撓曲模數，23t，1/8”（psi) 323,100 333,900 降伏點撓曲強度，23t，l/8”（psi) 10,510 10,260 HDT，66 psi，l/8”（Τ ) 291.8 25 8.8 HDT，264 psi，l/8” (°F ) 228.6 218.1 凹口懸臂樑，23°C (ft-lb/in) 3.8 4.5 凹口懸臂樑，-3(TC (ft-lb/in) 2.3 2.9 無凹口懸臂樑，23°C (ft-lb/in) 11.7 13.0 於最大應力的能量，23 °C，7·5 mph(ft-lb) 9.05 8.64 斷裂抗張強度，23°C (psi) 6,431 6,213 抗張破斷伸長，23°C 10.38 12.42 (請先閲讀背面之注意事項再填寫本頁) ______-42- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 五、發明説明（40) 實施例1〇一 1 5 ，比較例1 1 — 1 6 此類實施例與比較例將闡明與在組成物中含有未氫化 嵌段共聚物相關的之優點，且進一步的闡明一類內包含非 纖維的補強塡料的組成物。各成分相同於那些於表1所敘 述者，除了聚（芳醚）（PPE)之本性黏度在0.46 d L / g，其係於2 5 °C在氯仿中測量。”添加劑”意指 1 : 1 : 3重量比例的氧化鎂、硫化鋅、及二（十二碳基 )亞磷酸鹽碳基亞磷酸鹽之摻合物。各試樣之製備與測試 同以上實施例1 - 4。各組成物與性質見如下表4。帶有 與未帶有未氫化嵌段共聚物S B S的成對的各試樣之比較 ，顯示S B S之存在一般係相關於較高的在2 3 °C與 - 3 0 t之凹口懸臂樑衝擊強度、於- 3 0 °C下較高的最 大應力下能量、及於- 3 0 °C下較高的之失效能量。成對 的比較實施例1 0與1 1 ，及實施例1 2與1 3 ，顯示存 在乙烯- α烯烴共聚物EBR係相關於在2 3 °C與一 3 0 t下改進的凹口懸臂樑衝擊強度。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 二43- 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇X297公釐） 583270 五、發明説明（41) 經濟部智慧財產局員工消費合作社印製 表4 比較例11 實施例10 比較例12 實施例11 組成 PP，PD403 45.00 40.00 40.00 35.00 EBR 0.00 0.00 5.00 5.00 SBS 0.00 5.00 0.00 5.00 SEBS H1043 8.00 8.00 8.00 8.00 XPS 12.00 12.00 12.00 12.00 PP-g-MA 2.00 2.00 2.00 2.00 玻璃纖維-14 15.00 15,00 15.00 15.00 滑石粉 0.00 0.00 0.00 0.00 PPE 0.46 IV 18.00 18.00 18.00 18.00 添加劑 0.25 0.25 0.25 0.25 性質 撓曲模數，23°C，l/8”（psi) 500,900 470,000 435,600 449,700 標準差 41,690 7,236 6,499 6,493 降伏點撓曲強度，23°C，l/8”（psD 15,410 14,670 13,930 13,930 標準差 607 103 141 123 HDT,264psi,l/8>，(°F) 252.2 251.1 239.3 249.9 標準差 4.2 2.0 3.5 0.8 HDT’66 psU/8”（。F) 300.0 299.4 295.7 295.4 標準差 4.2 1.2 1.0 0.4 凹口懸臂樑，23°C(ft-lb/in) 2.1 2.3 2.7 2.9 標準差 0.1 0.1 0.1 0.1 凹口懸臂樑，-3(TC(ft-lb/m) 1.2 1.4 1.4 1.8 標準差 0,1 0,0 0.1 0 於最大應力的能量，23°C，7.5mph(ft-lb) 3.03 3.30 3.08 2.96 標準差 1.03 1.66 0.91 0.27 失效能量，23°C，7.5 mph(ft-lb) 8.77 9.66 10.29 9.96 標準差 2.79 0,53 0.54 0.39 於最大應力的能量，-30°C，7.5mph(fWb) 4.49 4.65 5.69 5.40 標準差 2.78 2.04 2.44 1.38 失效能量，-30°C，7.5 mph(ft-lb) 7.82 8.79 10.71 12.76 標準差 3.94 3.45 2.09 0.68 於最大應力的能量，-30°C，5mph(ft-lb) 0.52 0.71 0.71 1.12 標準差 0.08 0.41 0.27 0.43 失效能量，_30°C，5 mph(ft-lb) 0.57 0.85 0.83 2.14 標準差 0.08 0.50 0.30 0.57 降伏點抗張強度,23't(psi) 10,051 9,959 9,564 9,482 標準差 42.6 51.7 40.3 49.6 斷裂抗張強度，23°C(psi) 10,036 9,942 9,527 9,465 標準差 39 58 48 46 抗張破斷伸長,23°C(%) 9.35 9.08 10.36 9.57 標準差 0.16 0.14 0.25 0.13 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） -44- 583270 A7 B7 五、發明説明（42) 表4(續） 經濟部智慧財產局員工消費合作社印製 比較例13 實施例12 比較例14 實施例13 組成物 PP，PD403 30.00 30.00 25.5 25.5 EBR 0.00 0.00 4.50 4.50 SBS 0.00 4.50 0.00 4.50 SEBS H1043 6.00 6.00 6.00 6.00 xPS 16.00 11.50 16.00 11.50 PP-g-MA 2.00 2.00 2.00 2.00 玻璃纖維-14 30.00 30.00 30.00 30.00 滑石粉 0.00 0.00 0.00 0.00 PPE 0.46 IV 16.00 16.00 16.00 16.00 添加劑 0.25 0.25 0.25 0.25 性質 撓曲模數，23°C，l/8”（psi) 776,200 866,900 766,100 756,600 標準差 98,800 18,590 24,140 17,350 降伏點撓曲強度，23°C，l/8”（psi) 20,050 20,170 19,130 18,500 標準差 1,313 343 245 281 HDT，264psi，l/8”（。F) 274.2 278.3 263.1 266.5 標準差 0.6 1.9 1.0 1.6 HDT,66 psi,l/8M (°F) 302.7 306.1 294.7 300.2 標準差 0.8 0.7 0.6 1.4 凹口懸臂樑，23t(ft-Mn) 2.1 2.2 2.6 2.9 標準差 0.0 0.1 0.1 0.1 凹口 懸臂探,-30t(ft-Mn) 1.6 1.7 1.9 2.1 標準差 0.1 0.1 0.1 0.1 於最大應力的能量，23t：，7.5mph(ft-lb) 4.51 2.66 3.78 3.23 標準差 1.73 0.22 1.900.35 失效能量，23°C，7.5 mph(ft-lb) 12.05 12.04 12.13 11.49 標準差 0.54 0.59 0.90 0.53 於最大應力的能量，-30°C，7.5mph(ft-lb) 6.68 5.29 5.13 5.51 標準差 1.13 3.12 2.53 2.55 失效能量，-30°C，7.5 mph(ft-lb) 10.75 10.95 12.53 13.72 標準差 2.30 1.77 2.09 2.05 於最大應力的能量，-3(TC，5mph(ft-lb) 1.15 1.19 1.61 1.95 標準差 0.55 0.30 0.28 0.30 失效能量，-30°C，5 mph(ft-lb) 3.00 2.63 3.04 3.53 標準差 0.61 0.50 0.37 0.70 降伏點抗張強度，23°C(psi) 14,548 13,876 13,786 13,019 標準差 43.3 73.6 98.9 102.0 斷裂抗張強度，23°C(psi) 14,548 13,876 13,786 13,019 標準差 43.4 73.4 98.9 102.0 抗張破斷伸長，23°C(%) 6.73 6.71 7.46 7.32 標準差 0.10 0.09 0.05 1 0.11 (請先閱讀背面之注意事項再填寫本頁) _；_-45- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 583270 A7 B7 五、發明説明（43) 表4(續） 經濟部智慧財產局員工消費合作社印製 比較例15 實施例14 比較例16 實施例15 組成物 PP，PD403 42.00 42.00 39.00 39.00 EBR 0.00 0.00 3.00 3.00 SBS 0.00 3,00 0.00 3.00 SEBS H1043 6.00 6.00 6.00 6.00 xPS 12.00 9.00 12.00 9.00 PP-g-MA 2.00 2.00 2.00 2.00 玻璃纖維-14 0.00 0.00 0.00 0.00 滑石粉 20.00 20.00 20.00 20.00 PPE 0.46 IV 18.00 18.00 18.00 18.00 添加劑 0.25 0.25 0.25 0.25 性質 撓曲模數，23°C ,1/8”（psi) 359,800 348,200 337,300 338,200 標準差 14,850 2,787 4,600 2,071 降伏點撓曲強度，23t：，1/8”（psD 9,979 9,449 9,324 8,978 標準差 35 45 45 100 HDT,264 psi,1/8^ (°F) 189.5 187.3 188.4 181.3 標準差 4.3 2.4 0.2 1.4 HDT，66 psU/8”（°F) 273.0 266.6 267.5 263.1 標準差 5.8 2.4 2,7 1,2 凹口懸臂樑，23t (ft-Mn) 1.0 1.1 1.2 1.4 標準差 0.1 0.1 0.1 0.0 凹口懸臂樑，-30°C (ft-Mn) 0.5 0.6 0.7 0.8 標準差 0,0 0.0 0.1 0.1 於最大應力的能量，23°C，7.5mph(ft-lb) 4.38 5.65 5.49 15.48 標準差 1.98 1.74 3.70 3.12 失效能量，23°C，7·5 mph(ft-lb) 4.66 6.47 5.83 16.53 標準差 2,05 1.69 3.79 4.17 於最大應力的能量，-30t，7.5mph(ft-lb) 1.25 1.44 2.25 4.4 標準差 2.00 0.31 1.52 1.06 失效能量，-3(TC，7.5 mph(ft-lb) 1.37 1.57 2.42 4.69 標準差 0.21 0,32 1.59 1,11 於最大應力的能量，-30°C，5mph(ft-lb) 0.59 1.47 0.78 2.53 標準差 0.13 0.53 0.19 1.03 失效能量，-30°C，5 mph(ft-lb) 0.67 1.57 0.86 2.66 標準差 0.12 0.55 0.22 1,05 降伏點抗張強度,23°C (psi) 6,416 5,987 5,950 5,617 標準差 18.5 20.2 8.5 48.6 斷裂抗張強度，23t (psi) 5,764 5,298 5,460 4,926 標準差 187,5 34.6 123.8 143,6 抗張破斷伸長，23°C (%) 38.34 48.77 41.50 56.66 標準差 7.59 1.05 5.78 9.57 (請先閲讀背面之注意事項再填寫本頁) ______-46- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 583270 A7 __ B7 _ 五、發明説明（44) 實施例1 6及1 7 此類實施例將進一步的闡明與內含聚苯乙烯一接枝一 環酐共聚物的各組成物相關之優點，甚至當該類組成物不 含未氫化嵌段共聚物。各成分相同於那些於表1中敘述者 ，除了聚（芳醚）（P P E )之本性黏度在0 · 4 6 d L / g，其係於2 5 t在氯仿中測量。”添加劑”意指 1 : 1 : 3重量比例的氧化鎂、硫化鋅、及三（十二碳基 )亞磷酸鹽碳基亞磷酸鹽之摻合物。試樣製備的及測試如 以上實施例1 - 4記述者，。此類組成物及性質見如下表 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 準 標 I家 國 一國 中 I用. 適I j 一尺 錄 本 釐 公 97 2 47 5832707 B V. Description of the invention (38) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 3 Example 5 Example 6 Example 7 Composition PPE 15.00 15.00 15.00 Xps 3.75 3.75 19.43 SBS 9.25 9.25 15.00 SEBS H1043 10.00 10.00 10.00 PP , PD403 42.50 42.50 20.00 EPR 7.50 7.50 8.57 PP-g-MA 2.00 2.00 2.00 Glass fiber-14 10.00 10.00 10.00 Nature flexural modulus, 23 ° C, 1/8 "(psi) 314,800 315,600 321,300 Flexural strength at drop point, 23t, 1/8 ”(psi) 10,310 10,270 10,140 HDT, 66 psi, 1/8” (° F) 294.1 291.7 258.9 HDT, 264 psi, 1/8 ”(Τ) 224.4 228.1 218.1 Notched cantilever beam, 23t: (ft-lb / in) 3.7 3.8 4.1 Notched cantilever beam, -30 ° C (ft-lb / in) 2.2 2.3 3.1 Notched cantilever beam, 23t (ft-lb / in) 11.5 11.2 11.9 At maximum stress Energy, 23 ° C, 7.5 mph (ft-lb) 8.50 8.58 8.91 Tensile strength at break, 23 ° C (psi) 6,162 6,480 6,293 Elongation at break, 23 ° C (%) 11.47 10.53 11.40 (Please read the back first Please note this page, please fill in this page) This paper size applies to China National Standard (CNS) A4 (210X297 mm) -41-583270 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (39) Table 3 (continued) Example 8 Example 9 Composition PPE 15.00 15.00 xPS 3.75 19.43 SBS 15.00 15.00 SEBS H1043 10.00 10.00 PP, PD403 44.25 20.00 EPR 0.00 8.57 PP-g-MA 2.00 2.00 Glass fiber-14 10.00 10.00 Properties Deflection modulus, 23t, 1/8 "(psi) 323,100 333,900 Drop point flexural strength, 23t, l / 8 ”(psi) 10,510 10,260 HDT, 66 psi, l / 8” (Τ) 291.8 25 8.8 HDT, 264 psi, l / 8 ”(° F) 228.6 218.1 Notched cantilever beam, 23 ° C (ft- lb / in) 3.8 4.5 Notched cantilever, -3 (TC (ft-lb / in) 2.3 2.9 Notched cantilever, 23 ° C (ft-lb / in) 11.7 13.0 Energy at maximum stress, 23 ° C, 7.5 mph (ft-lb) 9.05 8.64 Tensile strength at break, 23 ° C (psi) 6,431 6,213 Tensile strength at break, 23 ° C 10.38 12.42 (Please read the precautions on the back before filling this page) ______- 42- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 583270 A7 B7 V. Description of invention (40) Examples 10-15, Comparative Examples 1 1-16 Such examples and comparative examples will clarify the advantages associated with the inclusion of unhydrogenated block copolymers in the composition, and further clarify the inclusion of non-fibers in a class A composition of reinforcing materials. The ingredients are the same as those described in Table 1, except that the intrinsic viscosity of poly (arylene ether) (PPE) is 0.46 d L / g, which is measured at 25 ° C in chloroform. "Additive" means a blend of magnesium oxide, zinc sulfide, and bis (dodecyl) phosphite carbon-based phosphite in a weight ratio of 1: 1: 3. The preparation and testing of each sample are the same as those in Examples 1-4 above. The compositions and properties are shown in Table 4 below. Comparison of pairs of samples with and without unhydrogenated block copolymer SBS shows that the presence of SBS is generally related to higher notched Izod impacts at 2 3 ° C and-3 0 t Strength, higher maximum stress at-30 ° C, and higher failure energy at-30 ° C. The paired comparative examples 10 and 1 1 and examples 1 2 and 1 3 show that the presence of the ethylene-alpha olefin copolymer EBR is related to the improved notched cantilever beam at 2 3 ° C and -30 t Impact strength. (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 43- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 583270 5. Description of the invention (41) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 4 Comparative Example 11 Example 10 Comparative Example 12 Example 11 Composition PP, PD403 45.00 40.00 40.00 35.00 EBR 0.00 0.00 5.00 5.00 SBS 0.00 5.00 0.00 5.00 SEBS H1043 8.00 8.00 8.00 8.00 XPS 12.00 12.00 12.00 12.00 PP-g-MA 2.00 2.00 2.00 2.00 Fiberglass-14 15.00 15,00 15.00 15.00 Talc 0.00 0.00 0.00 0.00 PPE 0.46 IV 18.00 18.00 18.00 18.00 Additive 0.25 0.25 0.25 0.25 Properties Flexural Modulus, 23 ° C, l / 8 "(psi) 500,900 470,000 435,600 449,700 standard deviation 41,690 7,236 6,499 6,493 flexure strength at the fall point, 23 ° C, l / 8" (psD 15,410 14,670 13,930 13,930 standard deviation 607 103 141 123 HDT, 264psi, l / 8 >, (° F) 252.2 251.1 239.3 249.9 Standard deviation 4.2 2.0 3.5 0.8 HDT'66 psU / 8 "(.F) 300.0 299.4 295.7 2 95.4 Standard deviation 4.2 1.2 1.0 0.4 Notch cantilever, 23 ° C (ft-lb / in) 2.1 2.3 2.7 2.9 Standard deviation 0.1 0.1 0.1 0.1 Notch cantilever, -3 (TC (ft-lb / m) 1.2 1.4 1.4 1.8 Standard deviation 0,1 0,0 0.1 0 Energy at maximum stress, 23 ° C, 7.5mph (ft-lb) 3.03 3.30 3.08 2.96 Standard deviation 1.03 1.66 0.91 0.27 Energy at failure, 23 ° C, 7.5 mph (ft -lb) 8.77 9.66 10.29 9.96 Standard deviation 2.79 0,53 0.54 0.39 Energy at maximum stress, -30 ° C, 7.5mph (fWb) 4.49 4.65 5.69 5.40 Standard deviation 2.78 2.04 2.44 1.38 Failure energy, -30 ° C, 7.5 mph (ft-lb) 7.82 8.79 10.71 12.76 standard deviation 3.94 3.45 2.09 0.68 energy at maximum stress, -30 ° C, 5mph (ft-lb) 0.52 0.71 0.71 1.12 standard deviation 0.08 0.41 0.27 0.43 failure energy, _30 ° C, 5 mph (ft-lb) 0.57 0.85 0.83 2.14 Standard deviation 0.08 0.50 0.30 0.57 Tensile strength at falling point, 23't (psi) 10,051 9,959 9,564 9,482 Standard deviation 42.6 51.7 40.3 49.6 Tensile strength at break, 23 ° C (psi) 10,036 9,942 9,527 9,465 standard deviation 39 58 48 46 tensile elongation at break, 23 ° C (%) 9.35 9.08 10.36 9.57 standard deviation 0.16 0.14 0.25 0.13 (Please read the notes on the back before filling in this page) This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X 297 mm) -44- 583270 A7 B7 V. Description of invention (42) Table 4 (continued) ) Comparative Example 13 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 12 Comparative Example 14 Example 13 Composition PP, PD403 30.00 30.00 25.5 25.5 EBR 0.00 0.00 4.50 4.50 SBS 0.00 4.50 0.00 4.50 SEBS H1043 6.00 6.00 6.00 6.00 xPS 16.00 11.50 16.00 11.50 PP-g-MA 2.00 2.00 2.00 2.00 Glass fiber-14 30.00 30.00 30.00 30.00 Talc 0.00 0.00 0.00 0.00 PPE 0.46 IV 16.00 16.00 16.00 16.00 Additive 0.25 0.25 0.25 0.25 Properties Flexural modulus, 23 ° C, l / 8 ”(psi) 776,200 866,900 766,100 756,600 standard deviation 98,800 18,590 24,140 17,350 Falling point flexural strength, 23 ° C, l / 8” (psi) 20,050 20,170 19,130 18,500 standard deviation 1,313 343 245 281 HDT, 264psi, l / 8 ” (. F) 274.2 278.3 263.1 266.5 standard deviation 0.6 1.9 1.0 1.6 HDT, 66 psi, l / 8M (° F) 302.7 306.1 294.7 300.2 standard deviation 0.8 0.7 0.6 1.4 Notch cantilever beam, 23t (ft-Mn) 2.1 2.2 2.6 2.9 standard Difference 0.0 0.1 0.1 0.1 Notch cantilever exploration, -30t (ft-Mn) 1.6 1.7 1.9 2.1 Standard deviation 0.1 0.1 0.1 0.1 0.1 Energy at maximum stress, 23t :, 7.5mph (ft-lb) 4.51 2.66 3.78 3.23 Standard deviation 1.73 0.22 1.900.35 Failure energy, 23 ° C, 7.5 mph (ft-lb) 12.05 12.04 12.13 11.49 Standard deviation 0.54 0.59 0.90 0.53 Energy at maximum stress, -30 ° C, 7.5 mph (ft-lb) 6.68 5.29 5.13 5.51 Standard deviation 1.13 3.12 2.53 2.55 Failure energy, -30 ° C, 7.5 mph (ft-lb) 10.75 10.95 12.53 13.72 Standard deviation 2.30 1.77 2.09 2.05 Energy at maximum stress, -3 (TC, 5mph (ft-lb) 1.15 1.19 1.61 1.95 standard deviation 0.55 0.30 0.28 0.30 failure energy, -30 ° C, 5 mph (ft-lb) 3.00 2.63 3.04 3.53 standard deviation 0.61 0.50 0.37 0.70 yield point tensile strength, 23 ° C (psi) 14,548 13,876 13,786 13,019 standard Poor 43.3 73.6 98.9 102.0 Tensile strength at break, 23 ° C (psi) 14,548 13,876 13 , 786 13,019 Standard deviation 43.4 73.4 98.9 102.0 Tensile elongation at break, 23 ° C (%) 6.73 6.71 7.46 7.32 Standard deviation 0.10 0.09 0.05 1 0.11 (Please read the precautions on the back before filling this page) _; _- 45 -This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 583270 A7 B7 V. Description of the invention (43) Table 4 (continued) Comparative Example 15 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 14 Example 16 Example 15 Composition PP, PD403 42.00 42.00 39.00 39.00 EBR 0.00 0.00 3.00 3.00 SBS 0.00 3,00 0.00 3.00 SEBS H1043 6.00 6.00 6.00 6.00 xPS 12.00 9.00 12.00 9.00 PP-g-MA 2.00 2.00 2.00 2.00 Glass fiber-14 0.00 0.00 0.00 0.00 Talc powder 20.00 20.00 20.00 20.00 PPE 0.46 IV 18.00 18.00 18.00 18.00 Additive 0.25 0.25 0.25 0.25 Properties Deflection modulus, 23 ° C, 1/8 "(psi) 359,800 348,200 337,300 338,200 Standard deviation 14,850 2,787 4,600 2,071 Damp Point flexural strength, 23t :, 1/8 "(psD 9,979 9,449 9,324 8,978 standard deviation 35 45 45 100 HDT, 264 psi, 1/8 ^ (° F) 189.5 187.3 188.4 18 1.3 Standard deviation 4.3 2.4 0.2 1.4 HDT, 66 psU / 8 ”(° F) 273.0 266.6 267.5 263.1 Standard deviation 5.8 2.4 2,7 1,2 Notched cantilever beam, 23t (ft-Mn) 1.0 1.1 1.2 1.4 Standard deviation 0.1 0.1 0.1 0.0 Notched cantilever beam, -30 ° C (ft-Mn) 0.5 0.6 0.7 0.8 Standard deviation 0,0 0.0 0.1 0.1 Energy at maximum stress, 23 ° C, 7.5mph (ft-lb) 4.38 5.65 5.49 15.48 Standard deviation 1.98 1.74 3.70 3.12 Failure energy, 23 ° C, 7.5 mph (ft-lb) 4.66 6.47 5.83 16.53 Standard deviation 2,05 1.69 3.79 4.17 Energy at maximum stress, -30t, 7.5mph (ft-lb) 1.25 1.44 2.25 4.4 standard deviation 2.00 0.31 1.52 1.06 Energy of failure, -3 (TC, 7.5 mph (ft-lb) 1.37 1.57 2.42 4.69 standard deviation 0.21 0,32 1.59 1,11 Energy at maximum stress, -30 ° C, 5mph (ft-lb) 0.59 1.47 0.78 2.53 standard deviation 0.13 0.53 0.19 1.03 failure energy, -30 ° C, 5 mph (ft-lb) 0.67 1.57 0.86 2.66 standard deviation 0.12 0.55 0.22 1,05 yield point tensile strength, 23 ° C (psi) 6,416 5,987 5,950 5,617 standard deviation 18.5 20.2 8.5 48.6 tensile strength at break, 23t (psi) 5,764 5,298 5,460 4,926 standard deviation 187,5 34.6 12 3.8 143,6 tensile elongation at break, 23 ° C (%) 38.34 48.77 41.50 56.66 standard deviation 7.59 1.05 5.78 9.57 (Please read the precautions on the back before filling this page) ______- 46- This paper scale applies to Chinese national standards (CNS) A4 specification (210X 297 mm) 583270 A7 __ B7 _ V. Description of the invention (44) Examples 16 and 17 These examples will further clarify the copolymerization with polystyrene-grafted and cyclic anhydride. The advantages associated with each composition of the composition are even when such compositions do not contain unhydrogenated block copolymers. The ingredients are the same as those described in Table 1, except that the intrinsic viscosity of poly (aryl ether) (PPE) is 0. 4 6 d L / g, which is measured at 2 5 t in chloroform. "Additive" means a blend of magnesium oxide, zinc sulfide, and tris (dodecyl) phosphite carbon-based phosphite in a 1: 1 weight ratio. Samples were prepared and tested as described in Examples 1-4 above. Such compositions and properties are shown in the following table (please read the precautions on the back before filling out this page). The Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs print the standard standards for each country and country. It is suitable for each j. Male 97 2 47 583270

7 B 五、發明説明（45) 經濟部智慧財產局員工消費合作社印製 表5 實施例16 實施例17 組成物 PP，PD403 15.72 16.31 PP-EPR，HEC〇-30 21.70 8.85 SEBS H1043 9.98 4.99 xPS 4.14 8.34 PP-g-MA 2.00 2.00 玻璃纖維-14 31.26 39.92 PE 0.46 IV 14.96 19.36 添加劑 0.25 0.25 性質 撓曲模數，23°C ,1/8”（psi) 843,400 1,212,000 標準差 19,630 15,010 降伏點撓曲強度，23t，1/8”（psi) 20,080 23,130 標準差 118 201 HDT,264psi，l/8”（°F) 292 294.4 標準差 7.0 1.3 HDT,66psi，l/8”（。F) 313.9 315.7 標準差 0.3 0.1 凹口懸臂樑，23°C (ft-lb/m) 2.9 2.0 標準差 0.1 0.1 凹口懸臂樑，-30t (ft-Mn) 1.8 1.5 標準差 0.1 <0.05 於最大應力的能量，23°C，7.5mph(ft-lb) 4.96 7.53 標準差 2.45 1.12 於最大應力的能量，-30°C，7.5mph(ft-lb) 6.65 6.19 標準差 2.65 2,24 總能量，23°C，7.5 mph(ft-lb) 13.6 12.6 標準差 0.6 1.1 總能量,-3(TC，7.5 mph(ft-lb) 6.6 6.16 標準差 2.65 2.24 降伏點抗張強度，23t (psi) 12,781 14,830 標準差 130 150 斷裂抗張強度，23°C (pS1) 12,780 14,830 標準差 130.5 153.9 抗張破斷伸長，(%) 7.32 5.79 標準差 0.21 0.16 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -48- 583270 A7 B7 五、發明説明（46 ) 當本發明已參照較佳的具體實施例而記述，彼將可經 由那些熟悉此技藝的專業人士暸解，可作各種改變，及可 用相當者取代其元件，而未偏離本發明之範圍。此外，可 作許多改良使特別條件或材料適合於本發明教示，而未偏 離其實質的範圍。因此，宜使本發明不限於所揭示的特另 具體實施例，該具體實施例係考慮針對執行本發明的最佳 模式’而本發明將包含所有具體實施例落在附加的申請專 利範圍之中。 所有引用專利，專利申請案、及其它參考，其全文在 此加入作爲參考文獻。 1111111 11 . I n 訂 • 髻 (請先閲讀背面之注意事項再填寫本頁)7 B V. Description of the invention (45) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 5 Example 16 Example 17 Composition PP, PD403 15.72 16.31 PP-EPR, HEC〇-30 21.70 8.85 SEBS H1043 9.98 4.99 xPS 4.14 8.34 PP-g-MA 2.00 2.00 Fiberglass-14 31.26 39.92 PE 0.46 IV 14.96 19.36 Additive 0.25 0.25 Properties Flexural Modulus, 23 ° C, 1/8 ”(psi) 843,400 1,212,000 Standard Deviation 19,630 15,010 Drop Point Flexural Strength , 23t, 1/8 "(psi) 20,080 23,130 standard deviation 118 201 HDT, 264psi, l / 8" (° F) 292 294.4 standard deviation 7.0 1.3 HDT, 66psi, l / 8 "(.F) 313.9 315.7 standard deviation 0.3 0.1 notched cantilever beam, 23 ° C (ft-lb / m) 2.9 2.0 standard deviation 0.1 0.1 notched cantilever beam, -30t (ft-Mn) 1.8 1.5 standard deviation 0.1 < 0.05 energy at maximum stress, 23 ° C, 7.5mph (ft-lb) 4.96 7.53 standard deviation 2.45 1.12 Energy at maximum stress, -30 ° C, 7.5mph (ft-lb) 6.65 6.19 Standard deviation 2.65 2,24 Total energy, 23 ° C, 7.5 mph (ft-lb) 13.6 12.6 standard deviation 0.6 1.1 total energy, -3 (TC, 7.5 mph (ft-lb) 6.6 6.16 standard 2.65 2.24 Falling point tensile strength, 23t (psi) 12,781 14,830 standard deviation 130 150 breaking tensile strength, 23 ° C (pS1) 12,780 14,830 standard deviation 130.5 153.9 tensile elongation at break, (%) 7.32 5.79 standard deviation 0.21 0.16 (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) -48- 583270 A7 B7 V. Description of the invention (46) It will be described in the specific embodiment of the invention that it can be understood by those skilled in the art, various changes can be made, and equivalent elements can be replaced without departing from the scope of the present invention. In addition, many modifications may be made to adapt a particular condition or material to the teachings of the invention without departing from its essential scope. Therefore, the present invention should not be limited to the specific embodiments disclosed, which consider the best mode for carrying out the invention, and the invention will include all the specific embodiments within the scope of additional patent applications. . All cited patents, patent applications, and other references are incorporated herein by reference in their entirety. 1111111 11. I n Order • 髻 (Please read the notes on the back before filling this page)

經濟部智慧財產局員工消費合作社印製 -49- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -49- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

六 A8 B8 C8 D8 經濟部智慧財產局員工消費合作社印製 申請專利範圍 附件三A:第90 1 3 1 243號專利申請案修正後無劃線之 中文申請專利範圍替換本 民國92年2月24日修正 1 · 一種熱塑性組成物，該組成物中含有： 一種聚（芳醚）； 一種聚（烯基芳香族）樹脂而其含量在至少1 〇之重 量百分比，佔聚（芳醚）與聚（烯基芳香族）樹脂之總量 ， 一種聚烯烴； 一種烯基芳香族化合物與共軛雙烯之氫化嵌段共聚物 ，其中烯基芳香族含量在4 0至9 0重量百分比； 一種聚烯烴-接枝-環酐共聚物； 及一種補強塡料。 2 ·如申請專利範圍第1項之熱塑性組成物，其中聚 (芳醚）存在1 0重量百分比至5 5重量百分比，此係基 於組成物之總重。 3 .如申請專利範圍第1項之熱塑性組成物，其中聚 (烯基芳香族）樹脂至少包含2 5 %重量比的結構單位， 而該結構單位係源自如下式的烯基芳香族單體6 A8 B8 C8 D8 The scope of the patent application for printing of the patent application scope of the Intellectual Property Bureau employee ministry of the Ministry of Economic Affairs Annex 3A: No. 90 1 3 1 243 The amended Chinese application for the patent scope is not replaced. February 24, 1992 Modification 1 · A thermoplastic composition containing: a poly (aryl ether); a poly (alkenyl aromatic) resin whose content is at least 10% by weight, accounting for poly (aryl ether) and poly The total amount of (alkenyl aromatic) resin, a polyolefin; a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, wherein the alkenyl aromatic content is 40 to 90 weight percent; a polymer Olefin-grafted-cyclic anhydride copolymer; and a reinforcing material. 2. The thermoplastic composition according to item 1 of the patent application range, wherein the poly (arylene ether) is present in an amount of 10 to 55 weight percent, which is based on the total weight of the composition. 3. The thermoplastic composition according to item 1 of the application, wherein the poly (alkenyl aromatic) resin contains at least 25% by weight of a structural unit, and the structural unit is derived from an alkenyl aromatic monomer of the following formula 其中R1爲氫，Ci — C8烷基，或鹵素；Z爲乙烯基 本紙張尺度適用中國國家標準（CNS ) A4規格（2】0X297公釐） (請先閱讀背面之注意事項存填寫本寅) •裝· 訂 583270 A8 B8 C8 D8 六、申請專利範圍 、鹵素，或Ci — Cs院基；且P爲0至5。 4 .熱塑性樹脂如申請專利範圍第1項之組成物，其 中聚（烯基芳.香族）樹脂至少包含一種聚（烯基芳香族） 樹脂，而該樹脂係選自由下列所組成之類群：雜排均聚苯 乙烯、對排均聚苯乙烯、橡膠改良的聚苯乙烯、及至少包 含一項前述的聚（烯基芳香族）樹脂之混合物。 5 ·如申請專利範圍第1項之熱塑性組成物，其中聚 (烯基芳香族）樹脂存在1重量百分比至5 0重量百分比 ，此係基.於組成物之總重。 6 ·如申請專利範圍第1項之熱塑性組成物，其中該 聚烯烴包含均聚物或共聚物，該共聚物其中具有至少 8 0重量百分比之單位係源自聚合乙烯、丙烯、丁烯、或 其混合物。 7 ·如申請專利範圍第1項之熱塑性組成物，其中聚 烯烴爲丙烯聚合物；其中該丙烯聚合物爲聚丙烯之均聚物 ’或丙烯與至少一種烯烴的雜排、接枝、或嵌段共聚物， 該烯烴係選自乙烯與C 4 - C : Q α —烯烴，其限制條件爲. 該共聚物至少包含8 0之重量百分比的重覆單位係源自丙 烯。 8 ·如申請專利範圍第1項之熱塑性組成物，其中該 聚烯烴包含均聚丙燦。 9 ·如申請專利範圍第丨項之熱塑性組成物，其中聚 烯烴存在1 〇重量百分比至6 0重量百分比，此係基於組 成物之總重。 (請先閱讀背面之注意事項再填寫本頁) -裝. 訂 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家榡準（CNS ) A4規格（21〇χ297公釐） · 2 _ 583270 A8 B8 C8 D8 六、申請專利範圍 1 〇 ·如申請專利範圍第1項之熱塑性組成物，其中 氫化嵌段共聚物包含： (請先閱·#背面之注意事項再填寫本頁) (A )至少一種嵌段係源自帶有下式的烯基芳香族化 合物 r2C=CR3Among them, R1 is hydrogen, Ci—C8 alkyl, or halogen; Z is vinyl. The size of this paper is applicable to Chinese National Standard (CNS) A4 specifications (2) 0X297 mm. (Please read the notes on the back and fill in this note) • Binding · Order 583270 A8 B8 C8 D8 VI. Patent application scope, halogen, or Ci — Cs courtyard base; and P is 0 to 5. 4. A thermoplastic resin, such as the composition of the scope of application for item 1, wherein the poly (alkenyl aromatic. Aromatic) resin contains at least one poly (alkenyl aromatic) resin, and the resin is selected from the group consisting of: Miscellaneous row homopolystyrene, para-row homopolystyrene, rubber modified polystyrene, and a mixture comprising at least one of the aforementioned poly (alkenyl aromatic) resins. 5. The thermoplastic composition according to item 1 of the scope of the patent application, wherein the poly (alkenyl aromatic) resin is present in a weight range of 1 to 50 weight percent, which is based on the total weight of the composition. 6. The thermoplastic composition according to item 1 of the application, wherein the polyolefin comprises a homopolymer or a copolymer, and the copolymer has at least 80% by weight of units derived from polymerized ethylene, propylene, butene, or Its mixture. 7. The thermoplastic composition according to item 1 of the patent application, wherein the polyolefin is a propylene polymer; wherein the propylene polymer is a homopolymer of polypropylene 'or a miscellaneous row, graft, or embedding of propylene with at least one olefin Segment copolymer, the olefin is selected from ethylene and C 4-C: Q α-olefin, with the limitation that the copolymer contains at least 80% by weight of repeating units derived from propylene. 8. The thermoplastic composition according to item 1 of the patent application scope, wherein the polyolefin comprises homopolypropylene. 9 · The thermoplastic composition according to item 丨 of the patent application, wherein the polyolefin is present in the range of 10% to 60% by weight, which is based on the total weight of the composition. (Please read the precautions on the back before filling out this page)-Binding. Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, the Consumer Cooperatives. This paper is printed in accordance with China National Standards (CNS) A4 (21〇297 mm) · 2 _ 583270 A8 B8 C8 D8 6. Scope of Patent Application 1 〇 As for the thermoplastic composition of the scope of patent application item 1, the hydrogenated block copolymer contains: (Please read the note on the #back before filling this page) (A At least one block is derived from an alkenyl aromatic compound having the formula r2C = CR3 其中R2與R3各自代表氫原子、Ci — Cs烷基基團、 或C2— C8烯基基團；R4與R8各自代表氫原子、C!— C8烷基基團、氯原子，或溴原子；及R5 - R7係各自獨 立代表氫原子、Ci—Cs烷基基團，或C2 - C8烯基基團 ，或R4與R5合倂爲中央芳香環以形成萘基基團，或R5 與R6合倂爲中央芳香環以形成萘基基團；及 經濟部智慧財產局員工消費合作社印製 (B )至少一種源自共轭雙烯的嵌段，其中在嵌段（ B )中脂肪族不飽和基團之含量將經由氫化而降低。 1 1 ·如申請專利範圍第1項之熱塑性組成物，其中 氫化嵌段共聚物包含苯乙烯-（乙烯-丁烯）-苯乙烯三 嵌段共聚物。 1 2 ·如申請專利範圍第1項之熱塑性組成物，其中 氫化嵌段共聚物存在1重量百分比至2 0重量百分比，此 係基於組成物之總重。 本紙度適用中國國家標準（CNS ) A4規格（210X297公釐） 7TI ' 583270 A8 B8 C8 D8 六、申請專利範圍 1 3 .如申請專利範圍第1項之熱塑性組成物，其中 聚烯烴-接枝-環酐共聚物包含聚丙烯-接枝-聚（順丁 烯二酸酐）共聚物。 1 4 .如申請專利範圍第1項之熱塑性組成物，其中 聚烯烴-接枝一環酐共聚物存在0.1至10重量百分比 ，此係基於組成物之總重。. 1 5 .如申請專利範圍第1項之熱塑性組成物，其中 補強塡料係選自由下列所組成之類群：玻璃纖維、滑石粉 '石英纖維、碳纖維、鈦酸鉀纖維、碳化矽纖維、碳化硼 纖維，石膏纖維、氧化鋁纖維、鐵纖維、鎳纖維、銅纖維 、矽礦石纖維、聚（醚酮）纖維、聚醯亞胺苯并哼唑纖維 '聚（伸苯基硫化物）纖維、聚酯纖維、芳香族聚醯胺纖 維、芳香族聚醯亞胺纖維、芳香族聚醚醯亞胺纖維、丙烯 酸纖維、聚（乙烯醇）纖維、聚四氟乙烯纖維、及其中至 少包含一項前述補強塡料的組合物。 1 6 ·如申請專利範圍第1項之熱塑性組成物，其中 補強塡料包含玻璃纖維而其直徑在2至2 5微米。 1 7 ·如申請專利範圍第1項之熱塑性組成物，其中 補強塡料存在1重量百分比至5 〇重量百分比，此係基於 組成物之總重。 · 1 8 如申請專利範圍第1項之熱塑性組成物，其中 進一步的包含未氫化嵌段共聚物。 1 9 ·如申請專利範圍第1 8項之熱塑性組成物，其 中未氫化嵌段共聚物包含苯乙烯-丁二烯二嵌段共聚物或 本紙適用中國國家標準（CNS ) A4規格（210X297公釐） ΤήΖ ： "* (請先閱讀背面之注意事項再填寫本頁) •裝· 、1Τ 經濟部智慧財產局員工消費合作社印製 583270 A8 B8 C8 D8 六、申請專利範圍 本乙儲- 丁二條-苯乙烦三嵌段共聚物。 2 〇 .如申請專利範圍第1 8項之熱塑性組成物，其 中烯基芳香族化合物與共軛雙烯之未氫化嵌段共聚物存在 〇 . 5重量百分比至2 0重量百分比，此係基於組成物之 總重。 2 1 ·如申請專利範圍第1項之熱塑性組成物，其中 進一步的包含聚丙烯-聚苯乙烯接枝共聚物，而其中具有 丙烯聚合物骨幹與一或更多的苯乙烯聚合物接枝。 2 2 ·如申請專利範圍第2 1項之熱塑性組成物，其 中聚丙烯-聚苯乙烯接枝共聚物存在〇.5重量百分比至 2 0重量百分比，此係基於組成物之總重。 2 3 .如申請專利範圍第1項之熱塑性組成物，其中 進一步的包含乙烯/α-烯烴彈性體共聚物在〇.5重量 百分比至2 5重量百分比，此係基於組成物之總重。 2 4 ·如申請專利範圍第2 3項之熱塑性組成物，其 中乙烯/α -烯烴彈性體共聚物包括乙烯一丁烯橡膠、乙 烯-丙烯橡膠、或其混合物。 2 5 ·如申請專利範圍第1項之熱塑性組成物，其中 該組成物於模製之後，展現依據A S T M D 7 9 0的於 2 3 °C之下的撓曲模數大於3 0 0 . k p s i 。 2 6 ·如申請專利範圍第1項至第2 5項中任何一項 的熱塑性組成物，其係用於形成物品。 2 7 _如申請專利範圍第2 6項之熱塑性組成物，其 中該物品之形成係使用至少一種選自下列的方法：射出成 本&張尺度適用中國國家標準（0灿）六4規格（21(^297公釐） ΓΤΙ '一一 (請先閱部背面之注意事項再填寫本頁) -裝· 訂 經濟部智慧財產局員工消費合作社印製 583270 A8 B8 C8 D8 7T、申請專利乾圍 形、吹模成形、押出成形、片押出成形、膜押出成形、輪 廓押出成形、拉擠成形、壓縮模製、熱成形、壓力成形、 水壓成形，及真空成形。 (請先閲讀背面之注意事項再填寫本頁) 裝· 、1Τ 經濟部智慧財產局員工消費合作社印製 -6 - 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐）Wherein R2 and R3 each represent a hydrogen atom, a Ci-Cs alkyl group, or a C2-C8 alkenyl group; R4 and R8 each represent a hydrogen atom, a C! -C8 alkyl group, a chlorine atom, or a bromine atom; And R5-R7 each independently represent a hydrogen atom, a Ci-Cs alkyl group, or a C2-C8 alkenyl group, or R4 and R5 are combined into a central aromatic ring to form a naphthyl group, or R5 and R6 are combined倂 is a central aromatic ring to form a naphthyl group; and printed by (B) at least one block derived from a conjugated diene in a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, wherein the block (B) is unsaturated in aliphatic The group content will be reduced by hydrogenation. 1 1 · The thermoplastic composition according to item 1 of the application, wherein the hydrogenated block copolymer comprises a styrene- (ethylene-butene) -styrene triblock copolymer. 1 2 · The thermoplastic composition according to item 1 of the patent application range, wherein the hydrogenated block copolymer is present in an amount of 1% to 20% by weight, which is based on the total weight of the composition. This paper is applicable to China National Standard (CNS) A4 specifications (210X297 mm) 7TI '583270 A8 B8 C8 D8 VI. Application for patent scope 1 3. For the thermoplastic composition of the first patent scope, where polyolefin-graft- The cyclic anhydride copolymer comprises a polypropylene-graft-poly (maleic anhydride) copolymer. 14. The thermoplastic composition according to item 1 of the application, wherein the polyolefin-grafted monocyclic anhydride copolymer is present in an amount of 0.1 to 10% by weight, which is based on the total weight of the composition. 15. The thermoplastic composition according to item 1 of the scope of patent application, wherein the reinforcing material is selected from the group consisting of glass fiber, talc 'quartz fiber, carbon fiber, potassium titanate fiber, silicon carbide fiber, carbonization Boron fiber, gypsum fiber, alumina fiber, iron fiber, nickel fiber, copper fiber, silicon ore fiber, poly (ether ketone) fiber, polyimide benzohumazole fiber, poly (phenylene sulfide) fiber, Polyester fiber, aromatic polyimide fiber, aromatic polyimide fiber, aromatic polyetherimide fiber, acrylic fiber, poly (vinyl alcohol) fiber, polytetrafluoroethylene fiber, and at least one of them The aforementioned composition for reinforcing the concrete. 16 · The thermoplastic composition according to item 1 of the patent application range, wherein the reinforcing material comprises glass fibers and has a diameter of 2 to 25 microns. 17 · The thermoplastic composition according to item 1 of the patent application range, wherein the reinforcing material is present in a weight percentage of 1 to 50 weight percent, which is based on the total weight of the composition. 18 The thermoplastic composition according to item 1 of the patent application scope, further comprising an unhydrogenated block copolymer. 1 9 · The thermoplastic composition according to item 18 of the scope of patent application, in which the unhydrogenated block copolymer contains a styrene-butadiene diblock copolymer or the paper is in accordance with China National Standard (CNS) A4 (210X297 mm) ) Τή ZO: " * (Please read the notes on the back before filling this page) • Installation · 1T Printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economic Affairs 583270 A8 B8 C8 D8 -Styrene block copolymer. 20. The thermoplastic composition according to item 18 of the scope of application for a patent, wherein an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene is present in an amount of 0.5 to 20% by weight, which is based on the composition The total weight of things. 2 1 The thermoplastic composition according to item 1 of the patent application scope, further comprising a polypropylene-polystyrene graft copolymer, wherein a propylene polymer backbone is grafted with one or more styrene polymers. 2 2 · The thermoplastic composition according to item 21 of the patent application scope, wherein the polypropylene-polystyrene graft copolymer is present in an amount of 0.5 to 20% by weight, which is based on the total weight of the composition. 2 3. The thermoplastic composition according to item 1 of the patent application scope, further comprising an ethylene / α-olefin elastomer copolymer in an amount of 0.5 to 25 weight percent, which is based on the total weight of the composition. 24. The thermoplastic composition according to item 23 of the patent application, wherein the ethylene /?-Olefin elastomer copolymer includes ethylene-butene rubber, ethylene-propylene rubber, or a mixture thereof. 2 5 · The thermoplastic composition according to item 1 of the scope of patent application, wherein after molding, the composition exhibits a flexural modulus under 23 ° C according to A S T M D 790 greater than 3 0. K p s i. 2 6 · The thermoplastic composition according to any one of the scope of claims 1 to 25, which is used to form articles. 2 7 _The thermoplastic composition according to item 26 of the patent application scope, wherein the article is formed by using at least one method selected from the following: Injection cost & Zhang scale is applicable to Chinese National Standard (0chan) 6 4 specifications (21 (^ 297mm) ΓΤΙ '一一 (Please read the precautions on the back of the department before filling out this page)-Binding and ordering printed by the Intellectual Property Bureau Employee Consumer Cooperative of the Ministry of Economy 583270 A8 B8 C8 D8 7T, patent application , Blow molding, extrusion molding, sheet extrusion molding, film extrusion molding, contour extrusion molding, pultrusion, compression molding, thermoforming, pressure molding, hydroforming, and vacuum forming. (Please read the precautions on the back first (Fill in this page again.) Printed at 1T Printed by the Intellectual Property Bureau Employees' Cooperatives of the Ministry of Economic Affairs -6-This paper size applies to China National Standard (CNS) Α4 specifications (210X 297 mm)