TW572960B

TW572960B - Thermoplastic elastomers having improved low temperature properties

Info

Publication number: TW572960B
Application number: TW90106985A
Authority: TW
Inventors: Maria D Ellul; Sudhin Datta; Jianya Cheng; Paul Mcdaniel; Kang-Bo Wang
Original assignee: Advanced Elastomer Systems; Exxon Chemical Patents Inc
Priority date: 2000-03-24
Filing date: 2001-04-16
Publication date: 2004-01-21
Also published as: JP2003528961A; WO2001072894A1; EP1268658A1; AU2001249416A1; KR20020089405A

Description

5?296〇 A7 B7 五、發明說明（經濟部智慧財產局員工消費合作社印？衣技術範I —般而言，本發明係針對熱塑性彈性體及其热塑性彈性體具有經改良之低溫性質。明二、寺之熱塑性彈性體係包括至少部份熟化之彈性：二物血：明性樹脂之摻合物。該彈性丑聚物美本 /、來人尤、塑對較*之…二未具有結晶性，相 ?:问：刀子1，相對較低之乙晞含量，及相對較狹有之乙缔組成分佈。發明背景熱塑性彈性體可被稱爲熱塑性硫化物，其係爲習知。並具：彈性體之多項性質，而其又可以熱塑性塑膠加工處理。一般而言，熱塑性硫化物爲聚合體摻合物，其包含細分橡膠粒子，被分散在塑膠中。此等橡膠粒子係被交聯以促進弹性。此等摻合物係以習用方式藉由動態硫化製成，其爲一種於其中使橡膠在與至少一種非硫化用聚合體之摻ς 物内熟化或硫化，而同時聚合體正在少許提高溫度下，較佳係高於非硫化用聚合體之熔融溫度下，進行混合或塑煉之方法。例如，美國專利4，130,535揭示一種熱塑性硫化物，其包含聚烯fe樹脂與完全熟化烯烴共聚物橡膠之摻合物。此烯烴共聚物橡膠可包括EPDM橡膠，其通常係藉由單體之聚合反應而形成’該單體包括兩種烯烴，通常爲乙晞與丙晞，及較少量之非共軛二烯單體，譬如5_亞乙基1原冰片烯。但是’熱塑性硫化物之特徵爲降低在較低溫度下對壓縮變形之抵抗性，此係由於熱塑性基質所致。因此，已嘗試改良 -4- 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公髮 (請先閱讀背面之注咅？事項再填寫本頁) 裝 ·11111111 0 572960 A7 經濟部智慧財產局員工消費合作社印製五、發明說明（2 在較低溫度下對壓縮變形之抵抗性。例如，已添加各種橡膠操作油，以改良此性質。而且，以及如由美國專利 5,397,832所揭tf者，某些類型之低分子量@旨增塑劑已被捧入熱塑性硫化物中。一由於熱塑性硫化物之低溫性能是很重要的，故於此項技藝中仍需要改良熱塑性硫化物之低溫性質。發明摘诚一般而言，本發明係提供一種組合物，其包含橡膠與熱塑性樹脂之掺合物，其中該橡膠係經至少部份熟化，爲乙烯、至少一種…烯烴及視情況選用之一或多種二晞單體之彈性共聚物，且其特徵爲，當藉由示差掃描卡計法度量時，具有結晶度低於10焦耳/克，以整體共聚物爲基準，乙晞含量低於90莫耳百分比，當藉由Gpc度量時，重量平均分子量大於約20,000，及乙晞組成分佈低於約4百分比。本發明亦包括一種熱塑性彈性體，藉由包括以下步驟之万法形成，（1)將橡膠與熱塑性樹脂摻合，其中該橡膠係經至少邵份熟化，爲乙烯、至少一種…晞烴及視情況選用之一或多種二烯單體之彈性共聚物，且其特徵爲，當藉由示差掃描卡計法度量時，具有結晶度低於1〇焦耳/克，以整體共聚物爲基準，乙烯含量低於9〇莫耳百分比，當藉由 GPC度量時，重量平均分子量大於約2〇，_，及乙烯組成分佈低於約4百分比；與⑺使所形成混合物中之橡膠交聯。本發明進一步包括一種形成熱塑性彈性體之方法，其包括之步驟爲⑴將彈性共聚物與熱塑性樹脂摻合，其中該彈5? 296〇A7 B7 V. Description of the invention (Institute for Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs? Clothing technology range I—In general, the present invention is directed to thermoplastic elastomers and thermoplastic elastomers with improved low temperature properties. Ming 2. The thermoplastic elastomeric system of the temple includes at least a part of the cured elasticity: two materials blood: a blend of clear resin. The elastic ugly polymer Meiben /, Laiyouyou, plastic pair is more… the second is not crystalline Phase: Q: Knife 1, relatively low content of acetamidine, and relatively narrow distribution of ethylene composition. BACKGROUND OF THE INVENTION Thermoplastic elastomers can be called thermoplastic sulfides, which are known. They have: Many properties of elastomers, which can be processed by thermoplastics. Generally speaking, thermoplastic sulfides are polymer blends that contain finely divided rubber particles and are dispersed in plastic. These rubber particles are crosslinked to Promote elasticity. These blends are made in a conventional manner by dynamic vulcanization, which is a process in which rubber is cured or vulcanized in a blend with at least one non-vulcanized polymer, and At the time, the polymer is being raised at a slightly higher temperature, preferably a method of mixing or plasticizing at a temperature higher than the melting temperature of the non-vulcanized polymer. For example, U.S. Patent No. 4,130,535 discloses a thermoplastic sulfide containing a polyolefin Blend of resin and fully cured olefin copolymer rubber. This olefin copolymer rubber may include EPDM rubber, which is usually formed by the polymerization of monomers. 'The monomer includes two olefins, usually acetylene and propylene. Pyrene, and smaller amounts of non-conjugated diene monomers, such as 5-ethylene-1 probenbornene. However, 'thermoplastic sulfides are characterized by reduced resistance to compression deformation at lower temperatures due to Due to the thermoplastic matrix. Therefore, an attempt has been made to improve the size of this paper. -4- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297) (please read the note on the back? Matters before filling this page) 0 572960 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (2 Resistance to compression deformation at lower temperatures. For example, various rubber operating oils have been added to improve this property Moreover, as well as those disclosed in US Patent No. 5,397,832, certain types of low molecular weight @ purpose plasticizers have been favored into thermoplastic sulfides. One is that the low temperature properties of thermoplastic sulfides are important, so There is still a need to improve the low temperature properties of thermoplastic sulfides in this technology. In general, the present invention provides a composition comprising a blend of rubber and a thermoplastic resin, wherein the rubber is at least partially cured. Elastic copolymers of ethylene, at least one ... olefin, and optionally one or more difluorene monomers, and having a crystallinity of less than 10 Joules / gram when measured by differential scanning cardiometry, Based on the overall copolymer, the content of acetamidine is less than 90 mol%, when measured by Gpc, the weight average molecular weight is greater than about 20,000, and the composition distribution of acetamidine is less than about 4%. The present invention also includes a thermoplastic elastomer formed by a method including the following steps: (1) blending a rubber with a thermoplastic resin, wherein the rubber is matured by at least one part, and is ethylene, at least one ... In one case, an elastic copolymer of one or more diene monomers is selected, and is characterized by having a crystallinity of less than 10 Joules / gram when measured by differential scanning card meter. Based on the overall copolymer, ethylene The content is less than 90 mole%. When measured by GPC, the weight average molecular weight is greater than about 20%, and the ethylene composition distribution is less than about 4%; it crosslinks with the rubber in the resulting mixture. The present invention further includes a method for forming a thermoplastic elastomer, which comprises the steps of: blending an elastic copolymer with a thermoplastic resin, wherein the elastomer

(請先閱讀背面之注意事項再填寫本頁) 裝訂--------- 鲁· 572960 々共聚物爲乙缔、至少-種…埽烴及視情況選用之一或多種二，單體之共聚物，且其特徵爲，當藉由示差掃描卡計法度里時’具有結晶度低於10焦耳/1，以整體共聚物爲基準，乙烯含量低於90莫耳百分比，當藉由Gpc度量時，重量平均分子量大於约2_，及乙晞組成分佈低於約4百刀比，與（2)使所形成混合物中之橡膠交聯。當與採用習用埽烴共聚物橡膠（譬如EpDM)之埶塑性於化，比較時’本發明之熱塑性彈性體係有利地顯示經改良\ 彈性，及對於在較低溫度下定型之抵抗性。此項優點之舉例爲在壓縮變形與壓縮回復性上之改良。令人驚訏的是，此結果已被達成’而不會降低熱塑性硫化物之機械性質。已發現低溫性質，尤其是低溫壓縮變形與回復性，係被乙晞含量及其分佈兩者所影嚮’達很大程度，即使是在非晶質區域中亦然。而1 ’此等結果已被達成，而不會有害地衝擊熱塑性硫化物在室溫下之硬度。之較佳具例 A. 一般描述本發明係針對熱塑性彈性體，及其製造方法。此等敎塑性彈性體包括橡膠與熱塑性塑膠之摻合物。此橡膠爲由'乙締ή希烴及視情況選用之二埽系單體之聚合反應所獲得之?早性共聚物。此彈性共聚物基本上未具有結晶性，相對較高之分子量，及相對較低之乙埽含量，以及相對較之乙烯組成分佈。 Β·熱塑性樹脂 (請先閱讀背面之注意事項再填寫本頁) 擎丨裝--------訂--------- 經濟部智慧財產局員工消費合作社印製 -6 -(Please read the precautions on the back before filling this page) Binding --------- Lu · 572960 々 copolymer is ethylene, at least-a kind ... 埽 hydrocarbons and one or more of two, single as appropriate Copolymers, and is characterized by having a crystallinity of less than 10 Joules / 1 when measured by a differential scanning card. Based on the overall copolymer, the ethylene content is less than 90 mol%. When measured by Gpc, the weight average molecular weight is greater than about 2 mm, and the acetamidine composition distribution is less than about 400 knife ratios, and (2) crosslinks the rubber in the resulting mixture. When compared with the plasticity of conventional olefin hydrocarbon copolymer rubbers (such as EpDM), the thermoplastic elastomeric system of the present invention advantageously exhibits improved elasticity and resistance to setting at lower temperatures. Examples of this advantage are improvements in compression deformation and compression recovery. Surprisingly, this result has been achieved 'without degrading the mechanical properties of the thermoplastic sulfide. It has been found that low-temperature properties, especially low-temperature compressive deformation and resilience, are greatly affected by both the content and distribution of acetylene, even in amorphous regions. These results have been achieved without adversely impacting the hardness of the thermoplastic sulfide at room temperature. Preferred examples A. General description The present invention is directed to a thermoplastic elastomer and a method for manufacturing the same. These thermoplastic elastomers include blends of rubber and thermoplastics. This rubber is an early copolymer obtained by the polymerization of 'Ethylene Hydrocarbon' and optionally selected ammonium monomer. This elastic copolymer is essentially non-crystalline, has a relatively high molecular weight, a relatively low acetamidine content, and a relatively low ethylene composition distribution. Β · Thermoplastic resin (Please read the precautions on the back before filling in this page) Engine -------- Order --------- Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs-6 -

本紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公釐 572960 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（4 本發明熱塑性彈性體之熱塑性基質，係包括至少一種熱塑性樹脂。此熱塑性樹脂爲固體，通常爲高分子量塑膠材料。此樹脂較佳爲結晶性或半結晶性聚合體樹脂，且當藉由示差掃描卡計法度量時，更佳係具有結晶度爲至少25百分比。具有高玻璃轉移溫度之聚合體，亦可接受作爲熱塑性樹脂。此樹脂較佳亦具有熔融溫度或玻璃轉移溫度在約 80 C至約350 C之範圍内，但此溶融溫度通常應低於熱塑性彈性體之分解溫度。舉例之熱塑性樹脂’包括可結晶之聚晞烴、聚酯、尼龍、聚碳酸酯、苯乙晞-丙烯腈共聚物、聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚醯胺、聚苯乙晞、聚苯乙烯衍生物、聚苯醚、聚甲醛及含氟熱塑性塑膠。較佳熱塑性樹脂爲可結晶之聚烯烴，其係經由使…烯烴聚合而形成，孽如乙晞、丙晞]丁晞、μ己晞、辛晞、2_甲基小丙晞: 3·甲基小戊晞、4-甲基-1-戊晞、5_甲基小己烯及其混合物。乙‘㈣丙晞，“晞或丙晞與另一種“希烴之共聚物亦意欲涵蓋在内，該另一種…烯烴譬如丨_ 丁烯、己烯、1_辛晞、2-甲基小丙烯、3_甲基小戊晞、"基戊烯、曱基1 己晞或其混合物。此等均聚物與共聚物可利用此項㈣已知〈任何聚合技術合成，譬如但不限於，，脑ps催化反應” ^ f ^ Ziegler-Natta ^ ^ ^ ^ ^ ^ ^ # ^ ^ ； ==但不㈣金屬垸氧垸及金屬垸離子性活化劑催化作用。阁 -種尤佳熱塑性聚缔煙係爲高結晶性同排或對排聚丙缔This paper size applies to China National Standard (CNS) A4 specifications (21 × 297 mm 572960 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy A thermoplastic resin. The thermoplastic resin is a solid, usually a high molecular weight plastic material. This resin is preferably a crystalline or semi-crystalline polymer resin, and when measured by differential scanning cardiometry, it has a better crystallinity. At least 25%. Polymers with a high glass transition temperature are also acceptable as thermoplastic resins. This resin preferably also has a melting temperature or glass transition temperature in the range of about 80 C to about 350 C, but this melting temperature is usually Should be below the decomposition temperature of thermoplastic elastomers. Examples of thermoplastic resins include crystallizable polyethylenes, polyesters, nylons, polycarbonates, styrene-acrylonitrile-acrylonitrile copolymers, polyethylene terephthalate, Polybutylene terephthalate, polyamide, polyphenylene terephthalate, polystyrene derivatives, polyphenylene ether, polyoxymethylene, and fluorine-containing thermoplastics. A good thermoplastic resin is a crystallizable polyolefin, which is formed by polymerizing olefins, such as ethyl acetate, acrylic acid, butadiene, μhexamidine, acrylamide, and 2-methylpropanepropene: 3 · methyl Pentamidine, 4-methyl-1-pentamidine, 5-methylhexahexene, and mixtures thereof. Ethyl hydrazone, a copolymer of "fluorene or propane with another" Greek hydrocarbon is also intended to be included , The other ... olefins such as butene, hexene, 1-octane, 2-methylpropene, 3-methylpentafluorene, < ylpentene, fluorenyl 1 hexane or a mixture thereof. These homopolymers and copolymers can be synthesized using this method. It is known that <any polymerization technique can be used to synthesize, such as, but not limited to, brain ps catalysis reaction. ^ F ^ Ziegler-Natta ^ ^ ^ ^ ^ ^ ^ # ^ ^; = = But it does not catalyze the action of metal, oxygen, and metal ionic activators. Ge-specially excellent thermoplastic poly-associated tobacco is highly crystalline in-line or opposite-line polypropylene.

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注咅？事項再填寫本頁) · I I ϋ ϋ ϋ ϋ 一-口、_ «-ϋ n ϋ n n n 572960 A7 B7 五、發明說明（5 ) 。此聚丙烯通常具有密度爲約〇·85至約〇 91克/立方公分，其中大邵份同排聚丙烯具有密度爲約〇 9〇至約〇·91克/立方公分。具有微少熔融流動速率之高與超高分子量聚丙烯，亦爲高度較佳的。根據ASTMD_1238，此等聚丙晞樹脂：‘ 徵爲熔融流動速率低於或等於1〇分克/分鐘。This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Matters before filling out this page) · II ϋ ϋ ϋ ϋ One-port, _ «-ϋ n ϋ nnn 572960 A7 B7 5. Description of the invention (5). The polypropylene usually has a density of about 0.85 to about 0.91 g / cm3, and the polypropylene in the same row has a density of about 0.90 to about 0.91 g / cm3. High and ultra-high molecular weight polypropylenes with a slight melt flow rate are also highly preferred. According to ASTM D_1238, these polypropylene resins: ′ is characterized by a melt flow rate of 10 dg / min or less.

C. EPDM 彈性共聚物係由乙晞單體、至少一種“希烴單體及視情尺夕喱布早肢I合。…晞烴可包括但不限於丙烯、丁烯-1、己烯」、4_甲基小戊烯、辛烯]、癸，其組合。較佳^希烴爲丙缔、己缔-卜辛^或其组合 -缔早體可包括但不限於5_亞乙基_2_原冰片_ ; η•己 ;5-亞甲基_2_原冰片晞"，"二缔；&甲基从己二烯一甲基辦二缔"，3_環戊二缔；M_環己二晞；二環戊二晞；5-乙晞基-2-原冰片締等，或其組合。較佳二埽單體爲5 亞乙基:-原冰片缔與5_乙埽基_2_原冰片埽。在共聚物製自乙埽烴及二埽單體之情況中，共聚物合體在使用多種㈣煙或二缔類之情況中，甚四兀聚合體。較佳彈性共聚物包括乙埽、’ 2-原冰片埽之三元聚合體。 -乙基- 此彈性共聚物含有约2〇至約9〇 ^ 單體之乙晞單位。此等共聚：自乙稀石八a 可、木籾钗佳係含有約30至约70莫耳再：：且又更佳爲約4〇至約60莫耳百分比之乙晞單位。 =至=:含有二缔單位之情況中，此二埽單位可以，相至約5莫耳百分比之量存在， I _ 8 - 本紙張尺度賴t iiii^(CNS)A4規格⑵G χ 297公i (請先閱讀背面之注意事項再填寫本頁) Μ ----訂------ 經濟部智慧財產局員工消費合作社印製 572960 、發明說明（6 刀比’又更佳爲約1至約2 5草耳百八μ 铃…八、…… ’ .5莫耳百刀比。此共聚物之其餘μ，通，係由衍生“，烴單體之單位所構成。因此，共聚物可含有約10至約5〇莫耳 c0 ^ ^ \ 今9刀比，較佳馬約30至約莫耳百7刀比，且更佳爲約4〇至約6〇莫耳百分比之衍生自〜缔烴單體之4烴單位。前述莫耳百分總莫耳數爲基準。术在本發明中所採用彈性聚合體之相對較低乙缔本量，咸認係至少部份負責本發明熱塑性硫化物之經改良;溫性f 如上述，此乙烯含量通常應低於90莫耳百分比，較佳係低於70莫耳百分比，更佳係低於6G莫耳¥分比，且又更佳係低於50莫耳百分比，以整個聚合體之莫耳百分比爲基準。令人驚訏的是，當乙烯含量降低時，即使是在非晶質區域中:於低溫性質上之改良會增加。此結果是令人驚討的 ’因為習用知識指出玻璃轉移溫度係控制聚合體之低溫性質。當然’此玻璃轉移溫度係爲結晶度之函數，其依次爲乙晞含量之函數。在乙埽含量被降至低於6〇莫耳百分比，意即’聚合體爲非晶質日寺，由於共聚物玻璃轉移溫度上之改變是可忽視的，故咸認僅藉由降低非晶質區域中之乙烯含量，意即低於60莫耳百分比，不會增進利益。再者，已發現共I物之乙烯含量不會單獨控制聚合體之低溫性質。而是，咸信聚合體之低溫性質係被乙烯含量及乙烯組成分佈兩者所影嚮，即使是在非晶質區域中亦然。因此，本發明彈性聚合體之組成分佈，以特定聚合體之分級分離試樣之最接近90百分比爲基準，應以低於4百分 "9 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） t--------tr--------- (請先閱讀背面之注意事項再填寫本頁) 572960C. EPDM elastomeric copolymer is composed of ethylammonium monomer, at least one "Hexane monomer, and the early limbs of the silk gel cloth .... The hydrocarbon may include but is not limited to propylene, butene-1, hexene" , 4-methylpentene, octene], decene, and combinations thereof. Preferably, the hydrocarbon is acetyl, hexadecyl-bucin, or a combination thereof. The associative body may include, but is not limited to, 5-ethylidene_2_orborneol_; η • hexane; 5-methylene_2 _Original Borneol ", " Di Association; & Methyl from hexadiene-methyl do Di Association ",3_Cyclopentadiene;M_Cyclohexanedifluorene;Dicyclopentadiene; 5 -Ethyl-2-propanebornyl, etc., or a combination thereof. The preferred difluorene monomer is 5 ethylidene: -orthobornyl and 5_ethyridyl_2_orthobornyl. In the case where the copolymer is made from ethane hydrocarbon and difluorene monomer, the copolymer combination is a very polymer in the case of using a plurality of fumes or dibasic compounds. Preferred elastomeric copolymers include terpolymers of acetamidine, ' 2-orthobornylamidine. -Ethyl- This elastic copolymer contains about 20 to about 90 ^ of monomer units of acetamidine. These copolymers: from acetylene, ba-co, and sylvestris, containing about 30 to about 70 moles, and further: and more preferably about 40 to about 60 moles of acetamidine units. = To =: In the case of containing two units, this two-unit unit can be present in an amount of about 5 mole percent, I _ 8-This paper size depends on iiii ^ (CNS) A4 size ⑵G χ 297 male i (Please read the notes on the back before filling out this page) Μ ---- Order ------ Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 572960, Invention Description (6 knives' and better is about 1 Up to about 25 Cao Erqiu……,.. .5 Mole hundred knife ratio. The remaining μ of this copolymer is generally composed of derivatized, hydrocarbon monomer units. Therefore, the copolymer May contain about 10 to about 50 moles C0 ^ ^ \ today 9 knife ratio, preferably about 30 to about 70 mole ratio, and more preferably about 40 to about 60 mole percentage derived from ~ 4 hydrocarbon units of associative hydrocarbon monomers. The aforementioned molar percentages are based on the total molar number. The relatively low ethylene content of the elastic polymer used in the present invention is at least partially responsible for the thermoplasticity of the present invention. Improved sulfide; temperature f as above, this ethylene content should usually be less than 90 mole%, preferably less than 70 mole%, more preferably less than 6G mole ¥ fraction ratio, and more preferably less than 50 mole percentage, based on the mole percentage of the entire polymer. Surprisingly, when the ethylene content decreases, even in the amorphous region: in Improvements in low temperature properties will increase. This result is surprising 'because conventional knowledge indicates that the glass transition temperature controls the low temperature properties of the polymer. Of course,' this glass transition temperature is a function of crystallinity, which in turn is acetamidine As a function of the content, when the content of acetamidine is reduced to less than 60 mol%, which means that the polymer is amorphous, the change in glass transition temperature of the copolymer is negligible. By reducing the ethylene content in the amorphous region, that is, less than 60 mol%, it will not increase the benefit. Furthermore, it has been found that the ethylene content of the co-I substance does not independently control the low temperature properties of the polymer. Instead, the salty The low-temperature properties of the polymers are influenced by both the ethylene content and the ethylene composition distribution, even in the amorphous region. Therefore, the composition distribution of the elastic polymer of the present invention is classified according to the specific polymer The nearest 90% from the sample is taken as the benchmark, and should be less than 4% " 9-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) t -------- tr --------- (Please read the notes on the back before filling this page) 572960

五、發明說明（7 ) 比?文變，較佳係低於3 經濟部智慧財產局員工消費合作社印又狂你低於2百分J；G，』最佳爲低於1百分比。換言之’當分析聚合體試樣様時，對於最接近90百分比之分級分離試樣而言，乙缔在名離份中之量不應變化超過4百分比，或可作爲較佳範圍。分析上而言，聚合體試樣之乙埽組成分佈，可藉決定7 文列舉之方法測定。在室溫下，使五克聚合體溶於谓毫另己垸或環己燒中。滤出不可溶部份，並藉由將整個溶㈣倒經過150網目不銹_網，使其㈣。在可溶性部份，省即上層清液中，逐滴添加2_丙醇，直到溶液變成混濁。透滴添加大約再一臺并$ 9 $ @ 毛开惑丙醇，並使溶液靜置五分鐘。使整體溶液經過15〇網目不銹鋼I網過滤，並分離殘留物及乾 Μ。若需要進-步分級转，則重複上述方法，以產生並他離份-通常達到5或6份-直到大部份聚合體被沉澱爲止:、精分析不溶性部份與殘留物之組成（乙缔與與整體試樣之組成比較。又再者’被採料本發明中之彈性共聚物，基本上應具有結晶j ’這意謂當藉由示差掃描卡計法度量時，㈣皮採用於先前技藝中之類似共聚物比較，該共聚物具有較低結晶度。-般而言，此等共聚物具有結晶度低於約 /克，較佳係低於約3焦耳/克，更佳係低於約⑽ 克，又更佳係低於约〇 $/ -、、、0 .5…、耳/克，又再更佳係低於0.2焦 /克，且最佳係低於0.1焦耳/克。 …、除了低結晶度以外，i_L ΈΓπ 古八子㈢,.^ I物應同樣地具有相對較同刀子I。咸信精由本發明熱塑性硫化物所顯示之許多有V. Description of the invention (7) Compared with the text change, the better is less than 3. The employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is crazy that you are less than 2% J; G, "The best is less than 1%. In other words, when analyzing polymer samples, for the fractionated samples that are closest to 90%, the amount of ethylene in the fraction should not change more than 4%, or it can be used as a preferred range. In terms of analysis, the ethyl acetate composition distribution of the polymer sample can be determined by the method listed in Decision 7. At room temperature, five grams of the polymer was dissolved in hexane or cyclohexane. The insoluble portion was filtered off, and the whole solution was smashed by pouring it through a 150 mesh stainless steel mesh. In the soluble part, save the supernatant, add 2-propanol dropwise until the solution becomes cloudy. Add about another one dropwise and add $ 9 $ @ 毛开乱 propanol, and let the solution stand for five minutes. The whole solution was filtered through a 150 mesh stainless steel I mesh, and the residue and dry matter were separated. If further fractionation is required, repeat the above method to generate and separate fractions-usually up to 5 or 6 fractions-until most of the polymer is precipitated :, analyze the composition of the insoluble fraction and the residue (B It is compared with the composition of the whole sample. Furthermore, 'the elastic copolymer in the present invention should basically have crystal j', which means that when measured by differential scanning cardiometry, the skin is used in Compared with similar copolymers in the prior art, the copolymers have lower crystallinity.-Generally, these copolymers have a crystallinity of less than about / gram, preferably less than about 3 joules / gram, and more preferably Below about ⑽ grams, and more preferably below about 0 $ /-,,,, 0.5 ..., ears / gram, and even more preferably below 0.2 joules / gram, and most preferably below 0.1 joules / G .... In addition to the low crystallinity, i_L ΈΓπ ancient Hachiko,. ^ I should likewise have relatively the same knife I. Many of the compounds shown by the thermoplastic sulfide of the present invention

本紙張尺度刺㈣裝--------訂------ (請先閱讀背面之注意事項再填寫本頁)This paper scales -------- Order ------ (Please read the precautions on the back before filling this page)

n ϋ I 572960 A7 五、發明說明（8 ) 利機械性質，係由於使用基本上未具有結晶性之相對較高分子量共聚物所造成。顯示此等特性之彈性共聚物，並未於先前技藝中取得。明確言之，當使用聚苯乙烯標準物，藉由GPC度量時，此彈性共聚物通常應具有重量平均分子昼爲約20,000至約1，〇〇〇,〇〇〇，較佳爲約4〇,〇〇〇至約_，_ ’更佳爲約100,000至約7〇〇,〇〇〇，且最佳爲約2〇〇,〇〇〇至約 600,000。此等彈性聚合體之分子量分佈，通常應低於約7，較佳係低於約5，且更佳係低於約4。又再者’此彈性共聚物之特徵爲木尼黏度（ML 1+4@ 125。。）爲約5至約500，較佳爲約15至約2〇〇，且更佳爲約5〇至約 150。而且，當藉由十氫莕@ ι35Ό度量時，其特徵爲固有黏度約0.1至約20，較佳爲約〇·3至約10，且更佳爲約0.5至約5 〇用於實施本發明之彈性共聚物，可利用多種技術製成。例如’此等共聚物可利用ziegler_Natta或金屬烷二烯圜觸媒系統合成。亦可使用多種反應器體系，搭配此等觸媒系統。例如’進行Ziegler-Natta聚合反應，可使用VC14或V0C13作爲觸媒’及倍半氯化乙基鋁作爲助觸媒。此等觸媒系統顯示單一活性物種典型之動力學。改質劑，譬如胺或氨，可用以在聚合體鏈中引進所要含量之長鏈分枝。一般而言，此觸媒系統將產生狹窄組成分佈與狹窄分子量分佈，但其可利用反應器體系而變寬。熟諳此藝者將明暸，增加分子量之來合體’可藉由降低聚合反應期間所採用之觸媒量以及鏈轉移劑量兩者而製成。 (請先閱讀背面之注意事項再填寫本頁) 裝--------訂---------. 經濟部智慧財產局員工消費合作社印製 -11 - 經濟部智慧財產局員工消費合作社印製 ^— — — ---------B7 五、發明說明（9 ) 田私用此等釩系觸媒系統時，聚合反應較佳係在溶劑譬如己烷存在下進杆，u " 。且此聚合反應較佳係在約20°C至約65 C之脈度下，在沛留時間約6至約μ分鐘下，於壓力約7公斤/平方公分下進行。訊對燒基之濃度，係爲約ι : 4至約1 又10。被餵入反應器之每克觸媒，係產生約〇 2至約丨·5公斤 :合體。在己烷溶劑中之聚合體濃度，係爲約3至約8重量關式此聚口方法之進—步討論，可參考四氯化釩之反應···於巨分子期刊中，Datta等人，第35卷，第643〇頁（1992)。在本發明中所採用之彈性聚合體，亦可藉由前述單體， J用至屬k — *希圜觸媒系統合成。所形成之共聚物係有利地具有狹窄組成分佈與狹窄分子量分佈。缔:fe單體之金屬燒二烯圜催化作用，係爲習知且經記載。習用上，活性觸媒係以第IV-B族金屬，包括锆、給或鈦之又（裒戊一晞基）化合物形成，其已使用鋁氧燒、離子化非配仫陰離子先貝或燒基鋁化合物而被活化。關於此催化作用之進一步討論，可參考美國專利5,〇96,867，其係併於本文供參考。n ϋ I 572960 A7 V. Description of the invention (8) The mechanical properties are caused by the use of relatively high molecular weight copolymers which have substantially no crystallinity. Elastic copolymers showing these characteristics have not been obtained in prior art. Specifically, when a polystyrene standard is used, as measured by GPC, this elastic copolymer should generally have a weight average molecular weight of from about 20,000 to about 1,000,000, and preferably about 40,000. It is more preferably about 100,000 to about 700,000, and most preferably about 20,000 to about 600,000. The molecular weight distribution of these elastic polymers should generally be less than about 7, preferably less than about 5, and more preferably less than about 4. Furthermore, 'the elastic copolymer is characterized by a Muni viscosity (ML 1 + 4 @ 125 ...) of about 5 to about 500, preferably about 15 to about 200, and more preferably about 50 to About 150. Furthermore, when measured by dehydrohydrogen @ ι35Ό, it is characterized by an inherent viscosity of about 0.1 to about 20, preferably about 0.3 to about 10, and more preferably about 0.5 to about 50 for implementing the present invention. Flexible copolymers can be made using a variety of techniques. For example, these copolymers can be synthesized using a ziegler_Natta or metal alkadiene fluorene catalyst system. Various reactor systems can also be used with these catalyst systems. For example, 'for the Ziegler-Natta polymerization reaction, VC14 or V0C13 can be used as a catalyst' and ethylaluminum sesquichloride can be used as a catalyst. These catalyst systems show the kinetics typical of a single active species. Modifiers, such as amines or ammonia, can be used to introduce a desired amount of long chain branching into the polymer chain. Generally speaking, this catalyst system will produce a narrow composition distribution and a narrow molecular weight distribution, but it can be widened using the reactor system. Those skilled in the art will understand that the combination of increasing molecular weight can be made by reducing both the amount of catalyst used during the polymerization reaction and the amount of chain transfer. (Please read the precautions on the back before filling out this page) Packing -------- Order ---------. Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -11-Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives ^ — — — --------- B7 V. Description of the Invention (9) When Tian Tian used these vanadium catalyst systems, the polymerization reaction is preferably in the presence of a solvent such as hexane Down shot, u ". And, the polymerization reaction is preferably carried out at a pulse degree of about 20 ° C to about 65 ° C, a retention time of about 6 to about µ minutes, and a pressure of about 7 kg / cm 2. The concentration of the sintered base is about ι: 4 to about 1 and 10. For each gram of catalyst fed into the reactor, about 0.2 to about 5 kg are produced: combined. The concentration of the polymer in hexane solvent is about 3 to about 8 weights. This step-by-step method of this polymerization method is further discussed in the reaction of vanadium tetrachloride ... In the Journal of Macromolecules, Datta et al. Vol. 35, p. 6430 (1992). The elastic polymer used in the present invention can also be synthesized by using the aforementioned monomers, J, to the k— * Greek catalyst system. The formed copolymers advantageously have a narrow composition distribution and a narrow molecular weight distribution. The association of metal: diene fluorene catalyzed by fe monomers is well known and documented. Conventionally, active catalysts are formed from Group IV-B metals, including zirconium, zirconium, or titanium (pentamylpyridinyl) compounds, which have been aluminized, ionized non-coordinating anions, or anions. Aluminium compounds are activated. For further discussion of this catalysis, reference may be made to U.S. Patent No. 5,096,867, which is incorporated herein by reference.

除了習用金屬烷二烯圜催化作用以外，可使用離子性金屬烷二烯圜催化作用，以製備使用於本發明之彈性聚合體。此等觸媒亦爲習知且經記載。一般而言，此等催化物種係經由合併第IV-B族金屬化合物之雙（環戊二烯基）衍生物而形成，其含有至少一種配位體，其將與離子交換化合物之第一種成份結合。此第二種化合物，意即離子交換化合物係包含一種1%離子，其將不可逆地與被包含在第iv-B -12- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）' " --------^--------- (請先閱讀背面之注立思事項再填寫本頁)In addition to the conventional metal alkadiene fluorene catalysis, ionic metal alkadiene fluorene catalysis can be used to prepare the elastic polymer used in the present invention. These catalysts are also known and documented. Generally, these catalytic species are formed by combining bis (cyclopentadienyl) derivatives of Group IV-B metal compounds, which contain at least one ligand that will interact with the first of the ion-exchange compounds Ingredients combined. This second compound, which means that the ion-exchange compound contains a 1% ion, which will be irreversibly and contained in the iv-B -12- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297) Li) '" -------- ^ --------- (Please read the note on the back before filling in this page)

572960 A7 五、發明說明（1〇 ) 族金屬化合物中之至少一種配位體反應，及—種非配位降離子，其係爲龐大、易變及安定。可使用此離子性金屬燒一％圜觸媒’而無需錯氧燒活化劑，且因此較具成本有々文性。關於此催化作用之進一步討論，可參考美國專利 5，198,401、5,241，025 及 5,387,568，EP 申請案 277,003 與 277,〇〇4，及 WIPO 公告 91/09882、92/00333、93/11172 及 94/03506，其係併於本文供參考。此聚合技術亦描述於共待審國際申請案 WO 99/04553 中。正如上文所討論者，在本發明熱塑性共聚物中之彈性聚合體，通常係呈已硫化或經熟化橡膠之細分且經良好分散之粒子形式，惟共連續形態或相轉化亦爲可能。已硫化或經熟化橡膠一詞，係指已進行至少部份熟化之彈性聚合體。熟化度可以下述方式度量，測定利用煮沸之二甲苯或環己k作爲萃取劑，可自熱塑性彈性體中萃取之橡膠量。此方法係揭示於美國專利4,311，628中。利用此方法作爲基礎，本發明之經熟化橡膠具有熟化度爲其中不超過5〇百分比之橡膠爲可萃取，較佳爲不超過15百分比之橡膠爲可萃取，且更佳爲不超過5百分比之橡膠爲可萃取。在一項尤佳具體實施例中，彈性體係爲技術上完全硫化。完全硫化一詞係指一種熟化狀態，以致交聯密度爲每毫升彈性體至少 7 X 10莫耳（藉由溶脹測得）’或該彈性體低於約三百分比可被環己院在23°C下萃取。 D.熟化劑月匕夠使得被採用於本發明中之彈性共聚物熟化或交聯之 -13- 11 m (CNS)A4 (210 x 297 3 —-- -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 572960 A7572960 A7 V. Description of the Invention At least one kind of ligand reaction in the (10) group of metal compounds, and a kind of non-coordinating falling ions, which are large, variable and stable. This ionic metal can be used to burn 1% 圜 catalyst ′ without the need for oxidizing the activator, and is therefore more cost-effective. For further discussion of this catalysis, reference may be made to U.S. Patents 5,198,401, 5,241,025 and 5,387,568, EP applications 277,003 and 277,04, and WIPO bulletins 91/09882, 92/00333, 93/11172, and 94 / 03506, which is incorporated herein by reference. This polymerization technique is also described in co-pending international application WO 99/04553. As discussed above, the elastic polymers in the thermoplastic copolymers of the present invention are usually in the form of finely divided and well dispersed particles of vulcanized or cured rubber, but co-continuous morphology or phase inversion is also possible. The term vulcanized or cured rubber refers to an elastic polymer that has been at least partially cured. The degree of maturity can be measured in the following manner, and the amount of rubber that can be extracted from a thermoplastic elastomer using boiling xylene or cyclohexane as an extractant is determined. This method is disclosed in U.S. Patent 4,311,628. Using this method as a basis, the cured rubber of the present invention has a curing degree of not more than 50% of the rubber is extractable, preferably not more than 15% of the rubber is extractable, and more preferably not more than 5% Rubber is extractable. In a particularly preferred embodiment, the elastic system is technically fully vulcanized. The term fully cured refers to a state of maturation such that the crosslink density is at least 7 X 10 mols per milliliter of elastomer (measured by swelling) 'or that the elastomer is less than about three percent which can be used by the Ring House at 23 ° C extraction. D. The curing agent is enough to make the elastic copolymer used in the present invention mature or crosslink -13- 11 m (CNS) A4 (210 x 297 3 ------------- -Install -------- Order --------- (Please read the precautions on the back before filling this page) Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 572960 A7

經濟部智慧財產局員工消費合作社印製壬何熟化劑’均可用於實施本發明。此等熟化劑之一 κ 限制性實例’包括酚性樹脂、過氧化物、順丁烯二醯亞用及以矽爲基料之熟化劑。月匕夠使橡膠聚合體交聯之任何盼樹月旨，均可用於實施^ 發明。吴國專利2,972,600與3,287,440係關於此點而併於本j 装較佳酚樹脂熟化劑可被稱爲可溶祕樹脂，且係經由办土取代（紛或未經取代之紛，與趁類，較佳爲甲搭，在由性媒質中縮合，或經由雙官能性酚二醇類之縮合而製成( 燒基取代酚類之垸基取代基，典型上含有i至約靡“ 予。-羥甲基酚或酚性樹脂’於對位上被含有…”㈣ W子之Μ取代者’係爲較佳的。此等㈣熟化劑典开」上馬熱固性樹脂’且對此揭示内容之目的而言，可被稱声酚樹脂熟化劑或酚性樹脂熟化劑。此等酴性樹脂理想上係格配觸媒系統一起使用。例文』例如，非卣化酚熟化樹脂，較佳 :搭"素供體，及選用之，化氫清除劑一起使用。 &化+ b，兄中，並不需要齒素供體，但較之.#半二 ^關於熱塑性硫化物之酚樹脂熟化 ^ 一步討論’可參考美國專利伽,628，其係併於本文供參考0 、較佳酚樹脂熟化劑之實例，係根據通式⑴作定義。 I ΟΗ Ί QH oh—ch2Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, Renhe curing agent 'can be used to implement the present invention. One of these curing agents, κ Restrictive Examples ' includes phenolic resins, peroxides, maleic acid, and silicone-based curing agents. Any hope of the moon to crosslink the rubber polymer can be used to implement the invention. Wu Guo patents 2,972,600 and 3,287,440 are related to this point and the better phenol resin curing agent installed in this article can be called soluble secret resin, and is replaced by soil (unresolved or unreplaced, and similar, It is preferably methylformate, which is prepared by condensation in a sexual medium or by condensation of a bifunctional phenol diol (the fluorenyl substituent of a thiol-substituted phenol typically contains i to about 100%.- Methylolphenol or phenolic resin 'is substituted in the para position by "...", which is replaced by the "M of Wzi" is preferred. These "cure curing agents are available" and "there are thermosetting resins" and the contents of this disclosure For the purpose, it can be called phenolic resin curing agent or phenolic resin curing agent. These resins are ideally used together with a catalyst system. Example ”For example, non-fluorinated phenol curing resin, preferably: " Vegetable donor, and use it together with hydrogen scavenger. & Hua + b, brother, do n’t need the tooth donor, but compared with. # 半二 ^ about the curing of phenol resin of thermoplastic sulfide ^ For a further discussion, please refer to U.S. Patent No. 628, which is incorporated herein by reference. Examples of fat curing agents are defined according to the general formula ⑴ I ΟΗ Ί QH oh—ch2

：η2-οη (I) (請先閱讀背面之注音？事項再填寫本頁} 裝 • I ϋ n ----^-----: Η2-οη (I) (Please read the note on the back? Matters before filling out this page} 装 • I ϋ n ---- ^ -----

-I -14- 經濟部智慧財產局員工消費合作社印製 572960 ---—B7__ 五、發明說明（12 ) 其中Q爲二價基團，選自包括-CH2 -、_CH厂〇_CH2 _ ; m爲零或1至20之正整數，及R，爲有機基團。較佳情況是，Q爲二價基團-CH2 -0-CH2 -，m爲零或1至1〇之正整數，及R，爲具有低於20個故原子之有機基團。又更佳情況是，m爲零或1至 5之正整數，及R’爲具有4與12個碳原子間之有機基團。過氧化物熟化劑通常係選自有機過氧化物。有機過氧化物之實例，包括但不限於過氧化二-第三_丁烷、過氧化二異丙苯、過氧化第三-丁基異丙苯、α，…雙（第三_丁基過氧基）二異丙基苯、2,5-二甲基2,5-二（第三-丁基過氧基）己烷、 U-二（第三-丁基過氧基）_3,3,5-三甲基環己烷、正·丁基_4,4_雙（第三·丁基過氧基）戊酸酯、過氧化二苯甲醯、過氧化月桂醯、過氧化二月桂醯、2,5_二甲基_2,5-二（第三.丁基過氧基）己烯-3，及其混合物。亦可使用二芳基過氧化物、酮過氧化物、過氧二碳酸酯、過氧酯類、二烷基過氧化物、氫過氧化物、過氧縮酮及其混合物。關於過氧化物熟化劑及其用於製備熱塑性硫化物之進一步討論，可參考美國專利 5,656,693，其係併於本文供參考。可使用之含矽熟化劑，通常包括具有至少兩個SiH基團之氫化矽化合物。於氫矽烷化觸媒存在下，此等化合物會與不飽和聚合體之碳-碳雙鍵反應。可用於實施本發明之^匕矽化合物，包括但不限於甲基氫聚矽氧烷、甲基氫二甲基· 矽氧烷共聚物、烷基甲基聚矽氧烷、雙(二甲基矽烷基二類、雙（二甲基矽烷基）苯，及其混合物。較佳氫化矽化合物可由下式作定義 ------------裝--------訂--------- (請先閱讀背面之注咅？事項再填寫本頁}-I -14- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 572960 ----- B7__ V. Description of the invention (12) where Q is a divalent group selected from the group consisting of -CH2-, _CH 厂〇_CH2 _; m is zero or a positive integer from 1 to 20, and R is an organic group. Preferably, Q is a divalent group -CH2--0-CH2-, m is a zero or a positive integer of 1 to 10, and R is an organic group having less than 20 atoms. Even more preferably, m is zero or a positive integer from 1 to 5, and R 'is an organic group having between 4 and 12 carbon atoms. The peroxide curing agent is usually selected from organic peroxides. Examples of organic peroxides include, but are not limited to, di-tertiary-butane peroxide, dicumyl peroxide, tertiary-butyl cumene peroxide, α, ... bis (tertiary-butyl peroxide) (Oxy) diisopropylbenzene, 2,5-dimethyl 2,5-bis (third-butylperoxy) hexane, U-di (third-butylperoxy) _3,3 , 5-trimethylcyclohexane, n-butyl_4,4_bis (tertiary-butylperoxy) valerate, dibenzoyl peroxide, lauryl peroxide, dilaurate Samarium, 2,5_dimethyl_2,5-bis (third.butylperoxy) hexene-3, and mixtures thereof. Diaryl peroxides, ketone peroxides, peroxydicarbonates, peroxyesters, dialkyl peroxides, hydroperoxides, peroxyketals, and mixtures thereof can also be used. For further discussion of peroxide curing agents and their use in the preparation of thermoplastic sulfides, reference may be made to U.S. Patent 5,656,693, which is incorporated herein by reference. Usable silicon-containing curing agents usually include a hydrogenated silicon compound having at least two SiH groups. In the presence of a hydrosilylation catalyst, these compounds react with carbon-carbon double bonds of unsaturated polymers. Silicon compounds useful in the practice of the present invention include, but are not limited to, methylhydropolysiloxane, methylhydrodimethyl · siloxane copolymer, alkylmethylpolysiloxane, bis (dimethyl) Silyl group II, bis (dimethylsilyl) benzene, and mixtures thereof. Preferred hydrogenated silicon compounds can be defined by the following formula: Order --------- (Please read the note on the back? Matters before filling out this page}

572960 A7 五、發明說明（13 R Si一一Si—〇 I R"572960 A7 V. Description of the invention (13 R Si—One Si—〇 I R "

I RI R

H 〇—H 〇—

•Si—〇-[fsi—O R R R"• Si—〇- [fsi—O R R R "

P 經濟部智慧財產局員工消費合作社印製各R係獨立選自含有丨至⑼個碳原子之烷基，含有4至12個石反原子之環烷基，及芳基，m爲具有數値範圍從丨至約5〇之整數’ η爲具有數値範圍從1至約5〇之整數，及p爲具有數値範圍從0至約6之整數。如上述，彈性聚合體之氫矽烷化熟化，較佳係於觸媒存在下進行。此等觸媒可包括但不限於包含第vm族過渡金屬之觸媒。此等金屬包括但不限於鈀、鍺及鉑，以及此等金屬之錯合物。較佳係爲鉑觸媒。關於使用氫矽烷化以使熱塑性硫化物熟化之進一步討論，可參考美國專利5,936,〇28 ，其係併於本文供參考。當採用含矽熟化劑時，所採用之彈性共聚物，較佳係包括5•乙締基_2•原冰片烯，作爲二烯成份。F·操作油較佳係於本發明之組合物中採用增塑劑、增量油、合成操作油或其組合。增量油可包括但不限於芳族、環烷及石蠟增量油。較佳合成操作油爲聚線性心晞烴。又更佳情況是’本發明之組合物可包含有機酯類、烷基醚類或其組合明確&之’已發現添加某些低至中等分子量之有機酯類與烷基醚酯類，至本發明之組合物中，會顯著地降低聚晞烴與橡膠成份及整體組合物之，並改良低溫性質，特別疋可挽性與強度。此等有機酯類與烷基醚酯類通常具有分 -16 —---------裝--------訂-—----- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4 x 297公釐） 572960 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（14 子量大致上低於約10,000。咸信經改自艮<作用，係藉由酯分配至組合物之聚晞烴與橡膠成份兩者 K中而達成。特別適合之酯類，包括單體物質，及寡聚合物質，复且有平均分子量低於約2_，且較佳絲於約_。重要的是，此^ 可與組合物之聚烯烴及橡膠成份兩者相刀T香相谷或落混；意即其係與其他成份混合，以形成單相。細私目3 、、工毛現取通合之酯類，係爲脂族單-或二酯類，或者，寡聚合脂族酯類或烷基醚酉旨類。已發現聚合脂族醋類與芳族自旨類，係顯著地較不有效 ’而磷酸醋大部份無效。可藉由簡易測試酯類在聚晞烴（譬如聚丙烯）中溶脹之能力，篩選酯類之適合性。對本發明之目的而言，係將聚丙晞試樣（2.0 X20 X50毫米）浸沒在各種酯增塑劑或非酯稀釋劑 (譬如礦油）中，並在125°C下溶脹至恒重（通常約24小時）。若於重量上之總體改變大於40°’。，則認爲該稀釋劑顯著地可與聚丙烯相容，因此適合製備具有加強低溫性能之組合物。已發現令人滿意地使用於本發明中之醋之實例，包括松油酸異辛酯、油酸異辛酯、松油酸正-丁酯、油酸正-丁酯、油酸丁氧基乙酯、癸二酸二辛酯、癸二酸二2_乙基己酯、壬二酸二辛酯、十二烷二酸二異辛酯、戊二酸烷基烷基醚二酯，及其寡聚物。預期可用於本發明之其他類似物，包括烷基烷基醚單-與二-己二酸酯，單-與二烷基己二酸酯、戊二酸酯、癸二酸酯、壬二酸酯，蓖麻油或松油之酯衍生物，及自其衍生之寡聚合單-與二酯或單-與二烷基醚酯 -17 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 572960 A7 B7P Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, each R is independently selected from alkyl groups containing 丨 to 碳 carbon atoms, cycloalkyl groups containing 4 to 12 stone antiatoms, and aryl groups, where m is a number having 値Integers ranging from 丨 to about 50, n is an integer having a number ranging from 1 to about 50, and p is an integer having a number ranging from 0 to about 6. As described above, the hydrosilylation and aging of the elastic polymer is preferably carried out in the presence of a catalyst. Such catalysts may include, but are not limited to, catalysts including transition metals of the vm family. These metals include, but are not limited to, palladium, germanium, and platinum, and complexes of these metals. Preferred is a platinum catalyst. For further discussion of the use of hydrosilylation to ripen thermoplastic sulfides, reference may be made to U.S. Patent 5,936,028, which is incorporated herein by reference. When a silicon-containing curing agent is used, the elastic copolymer used preferably includes 5 • ethylidene_2 • orbornene as the diene component. F. Process oil It is preferred to use a plasticizer, extender oil, synthetic process oil, or a combination thereof in the composition of the present invention. Extender oils can include, but are not limited to, aromatic, naphthenic, and paraffin extender oils. A preferred synthetic process oil is polylinear cardiocarbon. Even more preferably, 'the composition of the present invention may include organic esters, alkyl ethers, or a combination thereof' has been found to add certain low to medium molecular weight organic esters and alkyl ether esters, to In the composition of the present invention, the polyalkylene and rubber components and the overall composition are significantly reduced, and the low-temperature properties are improved, especially the resilience and strength. These organic esters and alkyl ether esters usually have -16 ----------- equipment -------- order -------- (Please read the note on the back first Please fill in this page again for this matter) This paper size applies the Chinese National Standard (CNS) A4 x 297 mm) 572960 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. The invention description (14 sub-quantity is less than approximately 10,000. The Xianxinjing was modified from the effect of <Kinxinjing>, which is achieved by the ester distribution to both K and the rubber component of the composition. Particularly suitable esters include monomers and oligomeric substances, and It has an average molecular weight of less than about 2 mm, and preferably silk is about about mm. The important thing is that it can be blended with both the polyolefin and rubber components of the composition. The ingredients are mixed to form a single phase. The finely-divided heads 3 and 3 are made of common esters, which are aliphatic mono- or diesters, or oligomeric aliphatic esters or alkyl ethers. It has been found that polymerized aliphatic vinegars and aromatic motifs are significantly less effective 'while phosphate vinegars are largely ineffective. A simple test of esters in polyfluorene The ability to swell in (such as polypropylene) to screen the suitability of esters. For the purpose of this invention, a polypropylene sample (2.0 X 20 X 50 mm) is immersed in various ester plasticizers or non-ester diluents (such as Mineral oil) and swell to constant weight (usually about 24 hours) at 125 ° C. If the overall change in weight is greater than 40 ° '., The diluent is considered to be significantly compatible with polypropylene, It is therefore suitable for the preparation of compositions having enhanced low temperature properties. Examples of vinegars that have been found to be satisfactorily used in the present invention include isooctyl oleate, isooctyl oleate, n-butyl oleate, oil N-butyl acid, butoxyethyl oleate, dioctyl sebacate, di-2-ethylhexyl sebacate, dioctyl azelate, diisooctyl dodecanedioate, pentyl Diacid alkyl alkyl ether diesters, and their oligomers. Other analogs that are expected to be useful in the present invention include alkyl alkyl ether mono- and di-adipates, and mono- and dialkyl adipates Esters, glutarates, sebacates, azelates, ester derivatives of castor oil or pine oil, and oligomerization derived therefrom -With diester or mono- with dialkyl ether ester-17-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ Package- ------ Order --------- (Please read the notes on the back before filling this page) 572960 A7 B7

經濟部智慧財產局員工消費合作社印製 i員’譬如松油脂脉異癸，松油酸正-癸酿、松油， “日“故十一酿、松油酸十二醋、松油酸十三r，及松油脂肪酸血脂益酸+丄山 _曰油酸正丁西匕你1^碳衍生物。松油酸異辛酉旨與相 θ ，、馬特佳的。此等酯類可單獨使用於組合物中’或作成不同酯麵之、、曰人4 ..^ ^ 、又，此合物，或其可與習用烴油稀釋劑或操作油，例如石蠟油，合併使用。、操作油或增量油之類型，係爲通常搭配存在於組合物中 =，多=特定橡膠—起使用者，且以全部橡膠含量爲基丰，可涵蓋從零至數百Phr之範圍。但是，本發明之一項重要方面，係爲操作油不需要存在，且事實上，並可办 2組合物之酿增塑劑成份置換。換言之，依本發明二 =性體所要之性質而定’此組合物可不含操作油或可含有操作油與g旨之組合。 G·其他成份除了熱塑性樹脂、橡膠及選用之增量油等以外，本發明 ^組合物包含熟化劑，1亦可包含補強與非補強填料、抗氧化劑'安定劑、橡膠操作油、潤滑劑、結塊防止劑、抗 ^電劑m發泡劑'顏料、火培阻滞劑及橡膠換配技 ^上已知之其他加1助劑。此等添加劑可佔全部組合物之至高約50重量百分比。可使用之填料與增量劑，包括習用無機物質’譬如碳酸药、黏土、碎石、滑石、二氧化鈇、碳黑等。 H·含量此具體實施例之組合物，較佳係含有足量彈性聚合體， -18- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公f一 i ^w- ^--------tT--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 572960 五、發明說明（16 以形成物質之橡膠態組合物。熟練技師將明瞭物質之橡勝怨組合物係爲具有極限伸長率大於卿百分比，且在被拉伸至其原長之200百分比，並在其原長之百分比下保持約 10分鐘後，於約10分鐘内，快速回縮至其原長之或較低者。 ^ 因此，本發明〈組合物，在每ι〇〇重量份數合併之彈性共聚物與熱塑性樹脂中，應包含至少約％重量份數之彈性聚合體’較佳爲至少約35重量份數之彈性聚合體，又更佳爲至少約45重量份數之彈性聚合體，且又再更佳爲至少約％重量份數之彈性聚合體。更明確言之，經熟化橡膠在熱塑 f ’IU化物中之量，通g爲彈性共聚物與熱塑性樹脂合併總重量之約25至約90重量。’。，較佳爲約45至約85重量。/。，且更佳爲約60至約80重量。/〇。熱塑性樹脂在本發明熱塑性硫化物中之量，通常爲彈性共聚物與熱塑性樹脂合併總重量之約1〇至約75重量。。，較佳爲約15至約55重量％，且更佳爲約2〇至約4〇重量％。熟練技師將能夠容易地決定足夠或有效量之欲被採用之硫化劑，而無需過度計算或實驗。硫化劑之量應足以使彈性聚合體至少部份硫化。此彈性聚合體較佳係被完全硫化。在採用酚樹脂熟化劑之情況中，熟化劑之硫化用量，較佳爲每一百重量份數之彈性共聚物，約1至約20重量份數 ’更佳爲約3至約16重量份數，且又更佳爲約4至約12重量份數之紛樹脂。在採用過氧化物熟化劑之情況中，熟化劑之硫化用量，以每一百重量份數之彈性共聚物計，較佳爲 19- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）裝--------訂--------- f請先閱讀背面之注咅？事項再填寫本頁) 572960Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, for example, pine oil fat isodecyl, terpineol n-decanoate, pine oil, "Japanese" eleven brew, terpineol dodecanate, terpineol ten Three r, and pine oil fatty acid blood lipids and beneficial acids + Laoshan _ said oleic acid n-butyric acid you 1 ^ carbon derivative. Pinocinic acid isooctyl and its purpose θ, Mata. These esters can be used alone in the composition, or can be made into different esters, such as 4.. ^ ^, And this compound, or it can be used with conventional hydrocarbon oil diluents or process oils, such as paraffin oil , Combined use. The type of operating oil or extender oil is usually used in the composition. =, More = specific rubber — from the user, and based on the total rubber content, it can cover the range from zero to several hundred Phr. However, an important aspect of the present invention is that the process oil does not need to be present, and in fact, it can replace the plasticizer component of the composition. In other words, depending on the properties of the second aspect of the present invention ', the composition may contain no process oil or a combination of process oil and g. G. Other ingredients In addition to the thermoplastic resin, rubber, and optional extender oil, the composition of the present invention contains a curing agent, 1 may also contain reinforcing and non-reinforcing fillers, antioxidants' stabilizers, rubber operating oils, lubricants, Anti-caking agent, anti-electric agent, m-foaming agent, pigment, fire retarder, and other additives plus 1 known in rubber replacement technology. These additives may constitute up to about 50 weight percent of the total composition. Fillers and extenders that can be used include conventional inorganic materials such as carbonates, clays, crushed stones, talc, hafnium dioxide, carbon black, and the like. H · Content The composition of this embodiment preferably contains a sufficient amount of elastic polymer. -18- This paper size is applicable to China National Standard (CNS) A4 specifications (210 X 297 male f-i ^ w- ^- ------ tT --------- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 572960 V. Description of the invention (16 A rubbery composition. A skilled technician will understand that the material is a rubber composition that has an ultimate elongation greater than 100%, and is stretched to 200% of its original length and maintained at about 10% of its original length. Minutes later, within about 10 minutes, quickly retract to its original length or lower. ^ Therefore, the <composition of the present invention, in the elastomeric copolymer and thermoplastic resin combined per 100,000 parts by weight, should be The elastomeric polymer comprising at least about% parts by weight is preferably at least about 35 parts by weight of an elastomeric polymer, still more preferably at least about 45 parts by weight of an elastomeric polymer, and still more preferably at least about%. Parts by weight of an elastic polymer. More specifically, the cured rubber is The amount of plastic f'IU compound is from about 25 to about 90% by weight of the combined weight of the elastic copolymer and the thermoplastic resin. ', Preferably from about 45 to about 85% by weight, and more preferably about 60 to about 80% by weight. The amount of the thermoplastic resin in the thermoplastic vulcanizate of the present invention is usually about 10 to about 75% by weight of the combined weight of the elastic copolymer and the thermoplastic resin, and preferably about 15 to about 55% by weight, and more preferably from about 20 to about 40% by weight. A skilled technician will be able to easily determine a sufficient or effective amount of vulcanizing agent to be used without undue calculation or experimentation. The amount of vulcanizing agent should be sufficient The elastic polymer is at least partially vulcanized. The elastic polymer is preferably completely vulcanized. In the case of using a phenol resin curing agent, the curing amount of the curing agent is preferably an elastic copolymer per hundred parts by weight, About 1 to about 20 parts by weight 'more preferably about 3 to about 16 parts by weight, and still more preferably about 4 to about 12 parts by weight. In the case of using a peroxide curing agent, curing Vulcanization amount of the agent, elasticity per 100 parts by weight Copolymer, preferably 19- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm). Packing -------- Order --------- f Read the note on the back? Matters need to fill in this page) 572960

、發明說明（π 經濟部智慧財產局員工消費合作社印製 :一百份彈性聚合體重量份數，約1 x 10—4莫耳至約2 x ur2 旲耳，更佳爲每一百份彈性聚合體重量份數，約2 χ 1〇_4莫耳至約2 X ΚΓ3莫耳，且又更佳爲每一百份彈性聚合體重量份數，約7χ1〇_4至約L5xl(r3莫耳之過氧化物。在採用氫矽烷化作用以使彈性聚合體熟化之情況中，熟化劑之硫化用 I ’較佳爲每一個在彈性聚合體中之碳碳雙鍵，〇1至約 10莫耳當量之SiH，且較佳爲每一個碳-碳雙鍵，約〇·5至約 5莫耳當量之siH。一般而言，每100份彈性共聚物，係添加約5至約3〇〇重量份數之增量油。較佳爲每1〇〇份彈性共聚物，添加約3〇至約 250重量份數之增量油，且更佳爲每100份彈性共聚物，添加約70至約200重量份數之增量油。所添加增量油之量，係依所要之性質而定，其中上限係依特定油與摻合物成份之相容性而定；當發生增量油之過度滲出時，此極限係被超過。酯增塑劑在組合物中之量，通常爲每一百份彈性共聚物’低於約250份，且較佳爲每一百份彈性共聚物，低於約 Π5份。石反黑可以每1〇〇重量份數合併之橡膠與熱塑性材料，約4〇至約250重量份數碳黑之量添加。更佳爲每100份橡膠與聚合體摻合物總重量，添加約20至約1〇〇重量份數之碳黑。可使用之碳黑量，係至少一部份依碳黑類型及增量油使用量而足。增量油之量，係至少一部份依橡膠類型而定。高黏度橡膠係爲更高度之油可增量性。 I·加工處理技術 -20- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ^^袭--------訂--------- (請先閱讀背面之注意事項再填寫本頁} )/2960 經濟部智慧財產局員工消費合作社印製 A7 五、發明說明（18 ) 熱塑性彈性體之橡膠成八七7 > ^成彳刀’通常係以小的，意即微米級粒子，存在於連續聚烯 + 、一、布工基貝中，惟共連續形態或相轉化亦可行’依橡膠相對於塑膠 ^ ^勝< !，及熟化系統或橡膠之熟化度而定。此橡膠於期暫卜 & &人、、、上係馬至少部份交聯，且較佳爲元王或充分交聯。部份吱佘入丄 a 刀4 全父聯，可藉由添加適當橡膠热化劑至聚烯烴與橡膠、口 *❻ < 谬合物中，及使橡膠硫化至所要 <程度而達成。較佳係佶嬙你使橡膠猎由動態硫化方法交聯。當於本專利説明書中使、、動悲硫化’’一詞，係意謂被包含在熱塑性彈性組合物中之々Y <橡膠^硫化或熟化方法，其中係㈣膠在高剪切條件下，於溫度高於聚晞烴成份之熔點 'Ώ此橡膠係同時被交聯，及以微細粒子被分散在聚烯烴基質中，彳鱼1 μ、+、 # 一隹力上述，其他形態亦可存在。動態硫化係經由將熱塑性彈性晋#成丄 f版成彳刀，於兩溫下，在習用混合設備中混合而達成，号· rifL ^共辟，风成叹備譬如輥軋機、Banbury混合器、驗nder混合器、連續混合器、混合壓出機等。以動態方式 :、化、、且口，之獨特特徵，係爲儘管橡膠成份經部份或完全无、化〈事實’但組合物還是可以藉習用塑膠加工處理技術加工與再加工’譬如壓出、射出成型及壓縮成型。廢料或毛邊可以回收及再加工。 -般熟諳此藝者將明瞭熟化系統之適當量、類型，及進行橡膠石瓜化所而要之硫化條件。此橡膠可使用不同量之熟化劑、不同溫度及不同熟化時目硫化，Μ獲得所要之最適宜交聯作用。如上述，供橡膠用之任何已知熟化系統均可使用八要在^化條件下，適合所使用之特定晞烴橡膠或 -----------Φ-裝------—丨訂---------Φ (請先閱讀背面之注意事項再填寫本頁) 21 - 572960Description of the invention (π Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs: 100 parts by weight of elastic polymer, about 1 x 10-4 moles to about 2 x ur2 旲 ears, more preferably every 100 parts elasticity Parts by weight of the polymer, from about 2 x 10-4 moles to about 2 x κΓ3 moles, and more preferably parts by weight per hundred parts of elastic polymer, from about 7 x 10-4 to about L5xl (r3 moles) Ear peroxides. In the case where hydrosilation is used to ripen the elastic polymer, the curing agent I 'is preferably used for each carbon-carbon double bond in the elastic polymer, from 0 to about 10 Molar equivalent of SiH, and preferably about 0.5 to about 5 Molar equivalent of siH per carbon-carbon double bond. Generally, about 5 to about 3 are added per 100 parts of the elastic copolymer. 0 parts by weight of extender oil, preferably about 30 to about 250 parts by weight of extender oil per 100 parts of elastic copolymer, and more preferably about 70 per 100 parts of elastic copolymer Up to about 200 parts by weight. The amount of added oil depends on the desired properties, and the upper limit depends on the specific oil and blend composition. Compatibility depends; this limit is exceeded when excessive bleeding of extender oil occurs. The amount of ester plasticizer in the composition is usually less than about 250 parts per hundred parts of the elastomeric copolymer, and Preferably it is less than about Π5 per 100 parts of elastic copolymer. Stone anti-black can be added in an amount of about 40 to about 250 parts by weight of carbon black per 100 parts by weight of the rubber and thermoplastic material combined. More preferably, carbon black is added in an amount of about 20 to about 100 parts by weight per 100 parts of the total weight of the rubber and polymer blend. The amount of carbon black that can be used is at least partly based on the type and increase of carbon black The amount of oil used is sufficient. The amount of incremental oil depends at least in part on the type of rubber. High-viscosity rubber is more highly oil-increaseable. I · Processing Technology-20- This paper size applies to China National Standard (CNS) A4 Specification (210 X 297 mm) ^^ Attack -------- Order --------- (Please read the precautions on the back before filling this page}) / 2960 Printed A7 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (18) Thermoplastic elastomer rubber is 1987 > ^ 成彳刀 '通It is based on small, meaning micron-sized particles, which exist in continuous polyene +, cloth, and cloth, but co-continuous morphology or phase inversion is also possible. 'Depending on rubber relative to plastic ^ ^ 胜 !!, and curing Depending on the maturity of the system or rubber. This rubber will be at least partially cross-linked during the period & & Knife 4 full paternity, can be achieved by adding an appropriate rubber heating agent to polyolefins and rubber, ❻ * 谬 compound, and vulcanizing the rubber to the desired level. The better is that you make Rubber hunting is crosslinked by a dynamic vulcanization method. When used in this patent specification, the term `` vulcanization, vulcanization, and vulcanization '' means the 々Y < rubber ^ vulcanization or curing method included in the thermoplastic elastic composition, wherein the rubber is subjected to high shear conditions At a temperature higher than the melting point of the polyfluorinated hydrocarbon component, the rubber system is simultaneously crosslinked and dispersed in a polyolefin matrix with fine particles. The catfish 1 μ, +, and # 1 have the force described above, and other forms also Can exist. Dynamic vulcanization is achieved by mixing the thermoplastic elastomer into a trowel and mixing in conventional mixing equipment at two temperatures. No. rifL ^ co-developed, such as rolling mill, Banbury mixer, Check the nder mixer, continuous mixer, mixing extruder, etc. In a dynamic way: the unique characteristics of the chemical composition are that although the rubber component is partially or completely absent, the composition can still be processed and reprocessed by using plastic processing technology, such as extrusion. , Injection molding and compression molding. Waste or burrs can be recycled and reprocessed. -Generally, the artist will understand the proper amount and type of curing system, and the curing conditions required for rubber stone melon. This rubber can be vulcanized with different amounts of curing agents, different temperatures and different curing times, so as to obtain the most suitable crosslinking effect. As mentioned above, any known curing system for rubber can be used. Under certain conditions, it is suitable for the specific fluorene rubber or ----------- Φ-pack ---- --- 丨 Order --------- Φ (Please read the notes on the back before filling this page) 21-572960

五、發明說明（！9 經濟部智慧財產局員工消費合作社印製诼胗組合，及適合聚烯烴即可。 P刀瓜化與”完全硫化丨’術語，當於本專利説明書中使补丄-、破I化 < 橡膠成份已被熟化成一種狀態，其中經X聯橡PL > VI π 化狀態，而除性質，係類似該橡膠呈其習用硫、、 ’、了热塑性彈性體組成之外時之情況。熟化度可以凝膠含量，式6 卜 ^ 4反 <，以可萃取成份爲觀點作描述。或熱化度可以又聯密度爲觀點表示。所有此等描述均爲 /、技"\中所白1知，例如在美國專利5，100,947與5，157,081中 ’兩案係藉由此项指稱完全併於本文供來考。 J·用途 " 本月〈扃塑性石瓦化物可用於製造多種物件，鐾如耐候密封環、軟管、皮帶、塾片、模製品、擔板、彈性纖維及類似物件。其特別可藉由吹製、壓出、射出成型、熱成形、彈性溶接及壓縮成型技術，用於製造物件。更明確言之，本發明之物件特別可用於製造載具配件，譬如但不限於耐候密封％ ’煞車配件’包括但不限於杯狀物、聯結圓盤、隔：杯，擋板，譬如定速接頭與齒條及小齒輪接頭，管件，贫封塾片，以液壓或氣動方式操作裝置之配件，〇形環、塞、閥、閥座、闕導溝，及其他以彈性聚合體爲基料之配件，或彈性聚合體與其他材料合併，譬如金屬、塑膠組合材料’其係爲一般熟諳此藝者所已知。亦意欲涵苔在内者爲傳輸皮帶，包括V型皮帶，具有截頭稜紋之齒：皮帶’其含有織物面V，經磨碎短纖維補強之V，或具有短纖維短絨V之模製膠。此種皮帶之橫截面，及其稜疑數目二 -22 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 57296〇經濟部智慧財產局員工消費合作社印製 A7 五、發明說明（20 ) ，可隨著皮帶之最後用途、銷售類型及傳其亦可爲扁平，製自具有摩擦外側矣而改交。中可應用此等配件之意欲涵蓋之載且，織補強物。其車、機車、卡車、船及其他交通運輸工’具匕。但不限於旅行爲証實本發明之實施，已按下立抵一、又揭不又一般實驗段落中所述，製備及測試下述實例。伸是，了處似甲疋不應將此等實例視爲限制本發明之範圍。申請專利範圍將用以界定本發明。見馬根據下述-般程序，製備數種熱塑性硫化物。將敎塑性樹脂與橡膠，伴隨著適當部份之其他所要之添加劑:、、置於已加熱义壓出機中。將混合物加熱至足以使聚缔煙成份溶解之溫度，將混合物塑煉，及添加熟化劑，同時持續塑煉。在最大轉矩顯示硫化已發生後，持續混合，直到達成所要之硫化程度爲止。不同成份之添加順序可以改變。然後自混合器移除組合物，根據ASTM標準模製及測試其物理性質。明確言之，811〇代八與0硬度係依據八8彻1)_224〇-91，於23 C下’利用硬度計測定。極限抗張強度、極限伸長率及百分比模數，係根據ASTMD412-92，於23°C下，利用Instr〇n 測試機測定。重量增加係根據ASTM D-471，於125°C下24小時後測定。拉伸變形係根據ASTM D-142測定。壓縮變形與回復，係根據ASTMD-3542測定，關於此等試驗係在_29°C下操作。壓縮變形與回復，係根據ASTM D-395-B測定，關於此等試驗係在70°C與100°C下進行。壓縮變形與壓縮回復試驗 ’係在低於室溫之溫度下操作24小時，及在室溫及較高溫 -23- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）裝-------訂--------- (請先閱讀背面之注音？事項再填寫本頁) 572%〇 A7 B7 i、發明說明（21 ) 度下進行22小時。凹口 IZOD係根據ASTM D-256在-40°c下測定。壓出表面等級係利用尖筆表面光度儀測定。在製備熱塑性硫化物時，係採用五種不同彈性共聚物。此等彈性共聚物爲乙烯、丙晞及5-亞乙基-2_原冰片晞之三元聚合體，因此稱爲EPDM。經標記爲EPDMI之第一種彈性共聚物，表示習用於製造熱塑性硫化物之彈性共聚物。經標記爲EPDM II與EPDM III之彈性共聚物，表示當使用於本發明時之彈性共聚物。此等彈性共聚物之特性，係敘述於表I中。 -----------Φ f-----------訂---------Φ. (請先閱讀背面之注意事項再填寫本頁} 經濟部智慧財產局員工消費合作社印製 -24- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 B7 五、發明說明（22 ) DSC ΔΗα/g)Acid)50) ^^^(LALLS)// Mzββ >和龄^(客(1+4@ 1250) Di專呤*(wt%) 聆^:&搠^方尊呤一： (wt%) 今屮# (GPC) M 0.5 —503 81,900 288000 10086000 118,100 380000 2,916000 5.7 55·5 910 P6 53.9 102,500 265,100 780,900 155,400 35Υ800 U22000 3.5 5.00 50·7 770 P6 丨5P6 112 二 00 24 so 568,200 s,400 286,00 783,900 2.6 500 44·6 68·8 1.2 0.6 -48·3 經濟部智慧財產局員工消費合作社印剩衣 1.1 0.5 •5P3 s,200 291,700 891,500 172.100 392.100 1,154000 产3 99,100 307.900 931.900 177.300 397.300 U90000 払ο -25- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 5·Ί 50.5 87 5·1 5L7 58.6V. Description of the invention (! 9 The printed cooperative combination of employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, and suitable for polyolefins. P knife melonization and "complete vulcanization 丨" term, when used in this patent specification -, Broken I < The rubber component has been matured into a state, in which the X-linked PL PL > VI π state, and except for the properties, is similar to the rubber with its conventional sulfur, thermoplastic, and elastomer composition. In other cases, the degree of maturity can be the gel content, formula 6 ^ 4 inverse <, described from the viewpoint of extractable ingredients. Or the degree of heat can be expressed in terms of density and density. All these descriptions are / "Technology" is known, for example, in the US patents 5,100,947 and 5,157,081, the two cases are based on this allegation and are provided here for consideration. J · Uses " Stone tiles can be used to make a variety of objects, such as weather-resistant seal rings, hoses, belts, cymbals, molded products, stretchers, elastic fibers, and similar objects. They can be used in particular by blow molding, extrusion, injection molding, heat Forming, elastic welding and compression molding technology , Used to manufacture objects. To be more specific, the objects of the present invention are particularly useful for manufacturing vehicle accessories, such as, but not limited to, weather-resistant seals. 'Brake accessories' include but are not limited to cups, coupling discs, partitions: cups, Baffles, such as fixed-speed joints and rack and pinion joints, pipe fittings, lean seals, accessories for operating devices hydraulically or pneumatically, o-rings, plugs, valves, valve seats, guide channels, and others Elastic polymer is the accessory of the base material, or the combination of the elastic polymer and other materials, such as metal and plastic composite materials, which is known to those skilled in the art. It is also intended to include the moss as the transmission belt, including V Type belts with fringed ribbed teeth: belts which contain fabric surface V, V reinforced by ground short fibers, or molding glue with short fiber fluff V. The cross section of this belt and its edges Number of suspects 2-22 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- installation -------- order ----- ---- (Please read the notes on the back before filling this page) 57296〇 Member of Intellectual Property Bureau, Ministry of Economic Affairs A7 printed by the consumer cooperative V. Invention description (20), which can be changed with the final use of the belt, the type of sale, and it can also be flat, made from the outer side with friction. It is intended to cover these accessories It also contains woven reinforcements. Its vehicles, locomotives, trucks, ships, and other transportation tools are not limited to travel. In order to confirm the implementation of the present invention, the following paragraphs have been opened, unveiled, and unexplained. The following examples are prepared and tested as described in the following. It is understood that these examples should not be considered as limiting the scope of the present invention. The scope of patent application will be used to define the present invention. The procedure is to prepare several kinds of thermoplastic vulcanizates. The plastic resin and rubber are mixed with the appropriate parts of other required additives :, and placed in a heated extruder. The mixture is heated to a temperature sufficient to dissolve the poly-soot components, and the mixture is plasticized, and a curing agent is added, while the plasticization is continued. After the maximum torque indicates that vulcanization has occurred, continue mixing until the desired degree of vulcanization is achieved. The order of adding different ingredients can be changed. The composition was then removed from the mixer, and its physical properties were molded and tested according to ASTM standards. Specifically, the hardness of the 8100 and 0 and 0 hardness systems was measured using a hardness tester at 23 ° C based on the results of 1) -2240-91. The ultimate tensile strength, ultimate elongation, and percentage modulus were measured at 23 ° C according to ASTM D412-92 using an Instron tester. The weight increase was measured in accordance with ASTM D-471 after 24 hours at 125 ° C. The tensile deformation is measured according to ASTM D-142. Compression deformation and recovery are measured in accordance with ASTMD-3542, and these tests are performed at _29 ° C. Compression deformation and recovery are measured according to ASTM D-395-B, and these tests are performed at 70 ° C and 100 ° C. Compression Deformation and Compression Recovery Test 'is operated at a temperature lower than room temperature for 24 hours, and at room temperature and higher temperature-23- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm). ------- Order --------- (Please read the phonetic on the back? Matters before filling out this page) 572% 〇A7 B7 i 、 Invention description (21) 22 hours. The notch IZOD is measured at -40 ° C according to ASTM D-256. The extruded surface grade was measured using a stylus pen photometer. In preparing thermoplastic vulcanizates, five different elastic copolymers are used. These elastomeric copolymers are ternary polymers of ethylene, propane, and 5-ethylene-2_orbornazone, and are therefore called EPDM. The first elastomeric copolymer, labeled EPDMI, represents an elastomeric copolymer commonly used in the manufacture of thermoplastic vulcanizates. The elastic copolymers labeled EPDM II and EPDM III indicate the elastic copolymers when used in the present invention. The properties of these elastic copolymers are described in Table I. ----------- Φ f ----------- Order --------- Φ. (Please read the notes on the back before filling this page} Economy Printed by the Intellectual Property Cooperative of the Ministry of Intellectual Property Bureau-24- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 572960 A7 B7 V. Description of the invention (22) DSC ΔΗα / g) Acid) 50) ^^^ (LALLS) // Mzββ > and age ^ (客 (1 + 4 @ 1250) Di Zhuolin * (wt%) listen ^: & 搠 ^ 方尊尊一： (wt%) 今屮 # (GPC) M 0.5 —503 81,900 288000 10086000 118,100 380000 2,916000 5.7 55 · 5 910 P6 53.9 102,500 265,100 780,900 155,400 35Υ800 U22000 3.5 5.00 50 · 7 770 P6 丨 5P6 112 220 00 so so 568,200 s, 400 286,00 783,900 2.6 500 44 · 6 68 · 8 1.2 0.6 -48 · 3 Printed clothing for consumer cooperatives of employees of the Intellectual Property Bureau of the Ministry of Economy 1.1 0.5 • 5P3 s, 200 291,700 891,500 172.100 392.100 1,154000 Production 3 99,100 307.900 931.900 177.300 397.300 U90000 払 ο- 25- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 5 · Ί 50.5 87 5 · 1 5L7 58.6

WPDMI EPDMII EPDMIII EPDMIV EPDMV -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 572960 A7 B7 五、發明說明（23 ) (請先閱讀背面之注意事項再填寫本頁) 表IIA係説明被稱爲試樣1-6之熱塑性彈性體之配方。於各表内之各成份量，係爲重量份數。EPDMI係以商標名VistalonTM 7500 (Exxon 化學；Baytown，Texas)獲得。EPDM II 與 EPDM III 係按本專利説明書中所述製成。應注意的是，VistalonTM7500具有可於先前技藝中取得之其他彈性共聚物，譬如VistalonT M 8600 (Exxon)之許多特性。酚樹脂係以商標名SP-1045tm (Schenectady 國際公司；Schenectady，New York)獲得。粉末狀摻合物包含氧化鋅與氯化亞錫。酯增塑劑爲松油酸十三酯。碳黑/聚丙烯爲市購可得之濃縮物。表TO説明在個別試樣上進行之各種物理試驗之結果。表IIC説明試樣於室溫下老化約三個月後，在個別試樣上進行之各種物理試驗之結果。經濟部智慧財產局員工消費合作社印製 -26- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 B7 五、發明說明（24 ) EPDMI EPDM II EPDM 臼 t>部命參雜a尊命 it (PHR) 46P74 46Ρ74 46Ρ74 309.26 5 3.26 7 107 219·2 19k>8 3.26 7 107 219.2 19.28 100 5 3·26 7 107 219·2 1S8 s 3·26 6 130 50 5 100 1 (請先閱讀背面之注意事項再填寫本頁) 100 100 2 ΪΙΑ 3 裝-------"丨訂--------- 經濟部智慧財產局員工消費合作社印製 309.26 309.26 100s 3·26 6 130 50 10 100 10 3·26 6 130 50 5 27 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 5 6 572960 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（25 ) 挥弈_^^^^^_6 ^^l,shore D/A έο Ϊ55 SX 66A rrcv(40.909 0.911P9119912P913P9M 欹 PM外满巌>t(Mpa) 15.74 15.46 18.54 4002 4_92 503 菡诗毐^#-(％) 583 ^ 笔 §tovooo§ ^100% T ~^i^(Mpa) 8.30 8.22 8.18 2.21 2.22 2.28 % 畤*施才(2411@ 1250) 59 63 58 117 109 98 li^ACR (遂) 1895 2169 2771 782 547 1050 躑庄^卧^渰 39 53007 342 268 ‘344 %佯專耀23045 έ 亡一K)s』 S ΕΠ IZOD (J/m@ -400) 820 773 769 i ... i %蹿爺耀途，50%鉍滩@ -290i i 丨_ 43 30 21 % a 荈，50% _ 濰 @ —290.! 丨！ _! 78 85VO0 -28- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ΪΙΒ -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 572960 A7 B7 五、發明說明（26 ) 經濟部智慧財產局員工消費合作社印製涔 >!,ShoreD/A 39D 37D 38D 66A 64A 64A rrcr時 PVO一00PVO一 oi 0^^P911 0.91 欹 PM《^辭^>(Mpa) 1706 16.34 18.29 5.35 iowtooo 澈 FMt^4 (％ ) 607 616 607 355 329 299 芩100% T~^^(Mpa) 935 909 932 2·45r°42 2.47 % 時^蔬 ^ (24h@ 1250) 57 58 50 110 108 97 23042.5 41.5 39.5 11.5 9·5 ‘8.5 %觭諮飧浹NJ5%^m@70d 61 61 59 32 27 25 %^爵濰浹，25。/〇^鳓@100062 63 59 38 32 31 %礴翁濰浹，50% _ m @ -290i i i 45 33 22 %0荈，509/。鉍耀 @ -290.! ·! -! 77 84 89 1 2 3 5 6 -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) -29- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 _B7___ 五、發明說明（27 ) 表IIIA説明被稱爲試樣7-12之熱塑性彈性體之配方。所採用之成份，均與表IIA中所採用者相同。表IIIB説明在試樣7-12上進行之各種物理試驗之結果。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印制衣本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 B7 五、發明說明（28 ) 經濟部智慧財產局員工消費合作社印製 ΪΙΙΑ 挥萍__一丨_^^___10 一一 12 EPDMI , EPDM II EPDM III ϋΗ-ΖηΟM3S 蒜噃#一命 it (PHR) 309.26 309.26 309.26 309.26 309.26 309.26 10 2 1.26 50 5 6 130 10 2 r26 50 10 6 130 100 5 2 1.26 50 10 6 130 100 5 2 1·26 50 10 6 130 100 10 2 1·26 50 s 6 130 100 10 2 1.26 50 10 6 130 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） 100 100 -----------Φ-裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 572960 A7 B7 五、發明說明（29 ) β_ ϋ% ) Shore A涔沐 tCT時欹 PMA 尜硪^(Mpa) 脔诗吝洳笮(％ ) 芩30% T~^_(Mpa) % 蜱崦施才(2411@ 1250) li^ACRcII>) ^Η-^β14ϊ资你每耀浹@ 230(％ ) Βα IZODf 400J/m 躑翁S荈，50%輙飧@ ·29ο 躑薪順汸，50%鉍m®-29d 褲爺飧浹，25% _濰@ 700 輞翁滩送，25%為濰@ 1000 _IIIB 7_§_Γ 0.028 §38 §39 64 64 63 0.912 0·91Ρ912 4.9 私 4.17 28 私tosK)s 2·17 2·19 2·17 110 107 107 979 § i 336 ^ S 10 S 10 700ηθ S 私5 私2 31 30 27 28 33 32 32 -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印制农 10_y_^ 0024 0036 0035 6私 $ s 0.912 0.913 0.909 4_33 £u) 269 258 251 2.10 203 2.14 104 112 101 652 103P746 3600§UJG 1P5S9 84009 88 32 22 24 30 27 27 34 30 29 -32- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 五、發明說明（3〇 ) ，表IVA説明〒皮稱爲試樣13-18之熱塑性彈性體之配方。所如用《成& ’均與上文所採用者及在表腿中所敘述者相同。表1VB説明在試樣13·18上進行之各種物理試驗之結果。裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 33 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 B7 五、發明說明（31 ) EPDMI EPDM II EPDM III ιέκ- ΖηΟ 羚^辟鎏 M3i審琴聲爺命if 2 1·2621s 19.28 7 107 46P74 13 100 2 1.26 219.2 1S8 7 107 46P74 100 15 100 I —J 5 2 1·2621s 1S8 7 107 460.74WPDMI EPDMII EPDMIII EPDMIV EPDMV ----------- Installation -------- Order --------- (Please read the precautions on the back before filling this page) 572960 A7 B7 V. Description of the Invention (23) (Please read the notes on the back before filling this page) Table IIA describes the formulation of the thermoplastic elastomer known as sample 1-6. The amounts of the ingredients in the tables are parts by weight. EPDMI was obtained under the brand name Vistalon ™ 7500 (Exxon Chemical; Baytown, Texas). EPDM II and EPDM III are made as described in this patent specification. It should be noted that VistalonTM 7500 has many of the characteristics of other elastomeric copolymers available in prior art, such as Vistalon T M 8600 (Exxon). Phenol resin was obtained under the trade name SP-1045tm (Schenectady International; Schenectady, New York). The powder blend contains zinc oxide and stannous chloride. The ester plasticizer is tridecyl terpineate. Carbon black / polypropylene is a commercially available concentrate. Table TO shows the results of various physical tests performed on individual samples. Table IIC shows the results of various physical tests performed on individual samples after the samples were aged at room temperature for about three months. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives. 26- This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 572960 A7 B7 V. Description of the Invention (24) EPDMI EPDM II EPDM Department命参杂 a respect life (PHR) 46P74 46P74 46P74 309.26 5 3.26 7 107 219 · 2 19k > 8 3.26 7 107 219.2 19.28 100 5 3.26 7 107 219 · 2 1S8 s 3.26 6 130 50 5 100 1 ( (Please read the notes on the back before filling out this page) 100 100 2 ΪΙΑ 3 Pack ------- " 丨 Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 309.26 309.26 100s 3.26 6 130 50 10 100 10 3.26 6 130 50 5 27 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 5 6 572960 A7 B7 Employee Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printed 5. Description of the invention (25) Swing game _ ^^^^^ _ 6 ^^ l, shore D / A έο Ϊ55 SX 66A rrcv (40.909 0.911P9119912P913P9M 欹 PM outside full 巌 &t; t (Mpa) 15.74 15.46 18.54 4002 4_92 503 菡诗毐 ^ #-(%) 583 ^ pen §tovooo§ ^ 100% T ~ ^ i ^ (Mpa) 8.30 8.22 8.18 2.21 2.22 2.28% 施 * 施才 (2411 @ 1250 ) 59 63 58 117 109 98 li ^ ACR (then) 1895 2169 2771 782 547 1050 Xinzhuang ^ 卧 ^ 39 53007 342 268 '344% 佯 Specialist 23045 一一 K) s 』S ΕΠ IZOD (J / m @ -400) 820 773 769 i ... i% Ye Ye Yao Tu, 50% Bismuth beach @ -290i i 丨 _ 43 30 21% a 荈, 50% _ Wei @ —290.! 丨! _! 78 85VO0 -28- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ΪΙΒ ----------- installation -------- order-- ------- (Please read the notes on the back before filling this page) 572960 A7 B7 V. Description of Invention (26) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 经济 >!, ShoreD / A 39D 37D 38D 66A 64A 64A rrcr PVO-00PVO-oi 0 ^^ P911 0.91 欹 PM 《^ 词 ^ > (Mpa) 1706 16.34 18.29 5.35 iowtooo Che Fmt ^ 4 (%) 607 616 607 355 329 299 芩 100% T ~ ^^ (Mpa) 935 909 932 2.45r ° 42 2.47% at time ^ Vegetables ^ (24h @ 1250) 57 58 50 110 108 97 23042.5 41.5 39.5 11.5 9.5 '8.5% 觭觭 NJ5% ^ m @ 70d 61 61 59 32 27 25% / 〇 ^ 鳓 @ 100062 63 59 38 32 31% 礴 Weng Wei 浃, 50% _ m @ -290i i i 45 33 22% 0 荈, 509 /. Bi Bi Yao @ -290.! ·!-! 77 84 89 1 2 3 5 6 ----------- install -------- order --------- ( Please read the notes on the back before filling in this page) -29- This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 572960 A7 _B7___ 5. Description of the invention (27) The description in Table IIIA is called Formulations of the thermoplastic elastomers of samples 7-12. The ingredients used are the same as those used in Table IIA. Table IIIB illustrates the results of various physical tests performed on samples 7-12. (Please read the precautions on the back before filling out this page) The printed paper size of the consumer cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 572960 A7 B7 V. Description of the invention (28) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ΪΙΙΑ Sweeping __ 一丨 _ ^^ ___ 10 -11 12 EPDMI, EPDM II EPDM III ϋΗ-ZηΟM3S 噃噃 # 一命 it (PHR) 309.26 309.26 309.26 309.26 309.26 309.26 309.26 10 2 1.26 50 5 6 130 10 2 r26 50 10 6 130 100 5 2 1.26 50 10 6 130 100 5 2 1.26 50 10 6 130 100 10 2 1.26 50 s 6 130 100 10 2 1.26 50 10 6 130 This paper size applies to China National Standard (CNS) A4 specification (210 χ 297 mm) 100 100 ----------- Φ-packed -------- order ----- ---- (Please read the precautions on the back before filling out this page) 572960 A7 B7 V. Description of the invention (29) β_ ϋ%) Shore A 涔 MU tCTCTPMA 尜硪 ^ (Mpa) 脔 Poem 吝洳笮(%) 芩 30% T ~ ^ _ (Mpa)% Tick Shicai (2411 @ 1250) li ^ ACRcII >) ^ Η- ^ β14 ϊ 每 @ 230 (%) Βα IZODf 400J / m 踯翁S 荈， 50% 輙飧 @ · 29ο踯 Shun Shun, 50% Bismuth®-29d pants, 25% _ Wei @ 700 Free from Wengtan, 25% Wei @ 1000 _IIIB 7_§_Γ 0.028 §38 §39 64 64 63 0.912 0 · 91Ρ912 4.9 Private 4.17 28 Private tosK) s 2 · 17 2 · 19 2 · 17 110 107 107 979 § i 336 ^ S 10 S 10 700ηθ S Private 5 Private 2 31 30 27 28 33 32 32 -------- --- Equipment -------- Order --------- (Please read the notes on the back before filling out this page) Printed Agriculture 10_y_ ^ 0024 0036 0035 6Private $ s 0.912 0.913 0.909 4_33 £ u) 269 258 251 2.10 203 2.14 104 112 101 652 103P746 3600§UJG 1P5S9 84009 88 32 22 24 30 27 27 34 30 29 -32- This paper size applies Chinese National Standard (CNS ) A4 specification (210 X 297 mm) 572960 A7 5. Description of the invention (30), Table IVA describes the formulation of the thermoplastic elastomer known as sample 13-18. The use of "Cheng & '" is the same as that used above and described in the table legs. Table 1VB illustrates the results of various physical tests performed on samples 13.18. Packing -------- Order --------- (Please read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 33 This paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) 572960 A7 B7 V. Description of the invention (31) EPDMI EPDM II EPDM III ικκ- ZOη 羚 ^ 鎏 3 M3i piano grandfather fate if 2 12621s 19.28 7 107 46P74 13 100 2 1.26 219.2 1S8 7 107 46P74 100 15 100 I —J 5 2 1 · 2621s 1S8 7 107 460.74

_IVA 16 100 5 2 1.26 219.2 moo 7 107 46P74 -----------裝-------—訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印制衣 100 5 2 L2621s 19.200 7 107 460.74 100 5 2 1.26 219.2 19.200 7 107 4δ·74 -34- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 17 18 572960 A7 B7 五、發明說明（32 弊热一3 失麥(％) , 0.032 0 029 Shore 0涔知 38 300 ^140909 0.906 畝 PM&^^^(Mpa) 19.26 17.45 菡诗專^令(％) 591 626 芩 100% T ~葙烊(MPa) 8.41 8.21 %14*^才(24h@ 1250) 50 60 >oR (¾) 1543 2571 ,辫 56 58 体吝觸230(％) 41.5 40 sa IZOD @ -40oJ/m 6901+29 8451+12 睛諮耀浹，25%_耀 @ 70059 500 蹿翁 € 浹，25% 溆飧 @ 100060 55 14 ΐνΒ 0038 300 S09 1£0 624 oool 61 2887 282 私P5 S3I+21 5私 56 0029 38 §09 17.94 550 00.52 払00 2605 53 39 6681+47 私9 57 15 16 -----------裳------—訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 0.025 300 S06 1806 565 00.18 53 2624. 72 37.5 7451+26 500 56 P037 39 P907 20.13 601 00.15 52 2706 005 37 7611+26 55 55 -35- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 17 100 572960 A7 B7 五、發明說明（33 ) 表V説明被稱爲試樣19-24之熱塑性彈性體之配方。表V亦説明在試樣19-24上進行之各種物理試驗之結果。 -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 A7 B7 五、發明說明（34 )_IVA 16 100 5 2 1.26 219.2 moo 7 107 46P74 ----------- install --------- order --------- (Please read the precautions on the back before (Fill in this page) Printed garments by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 100 5 2 L2621s 19.200 7 107 460.74 100 5 2 1.26 219.2 19.200 7 107 4δ · 74 -34- This paper size applies the Chinese National Standard (CNS) A4 specification ( 210 X 297 mm) 17 18 572960 A7 B7 V. Description of the invention (32 disadvantages-3 loss of wheat (%), 0.032 0 029 Shore 0 unknown 38 300 ^ 140909 0.906 acres PM & ^^ (Mpa) 19.26 17.45菡 Poetry Special Order (%) 591 626 芩 100% T ~ 葙烊 (MPa) 8.41 8.21% 14 * ^ cai (24h @ 1250) 50 60 > oR (¾) 1543 2571, braid 56 58 body contact 230 (%) 41.5 40 sa IZOD @ -40oJ / m 6901 + 29 8451 + 12 Eye Consultation Yao Yao, 25% _ Yao @ 70059 500 蹿 € € 25, 25% 溆飧 @ 100060 55 14 ΐνΒ 0038 300 S09 1 £ 0 624 oool 61 2887 282 Private P5 S3I + 21 5 Private 56 0029 38 §09 17.94 550 00.52 払 00 2605 53 39 6681 + 47 Private 9 57 15 16 ----------- Shang ----- -—Order --------- (Please read the notes on the back before filling this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives 0.025 300 S06 1806 565 00.18 53 2624. 72 37.5 7451 + 26 500 56 P037 39 P907 20.13 601 00.15 52 2706 005 37 7611 + 26 55 55 -35- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 17 100 572960 A7 B7 V. Description of the invention (33) Table V shows the formulation of the thermoplastic elastomer known as sample 19-24. Table V also shows that it was performed on samples 19-24. Results of various physical tests. ----------- Installation -------- Order --------- (Please read the precautions on the back before filling this page) Economy Printed by the Consumers' Cooperative of the Ministry of Intellectual Property Bureau, the paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 572960 A7 B7 V. Description of the invention (34)

Shore A涔知 rrb14 欹PM《尜漭綷营0 犛！1 #洳爷(％) 芩100% T ~ 燕^官0 %14^疏穿 li^ACR(E>) ^K-^a♦渰体A青濰230(％ ) 礴諮0薛，50% _^@·29ο 5 5 5 3.26 3.26 3.26 7 7 7 219.2 21S 219.2 130 115 105 .! 15 25 63 2 2 0.912 Ρ912 0.909 6500§ 3iH ito名 356 o WJ4 s 126 119 192 225 250 203 232 288 17.5 15 14 77 700^ 經濟部智慧財產局員工消費合作社印製與薛_^^_21 22 23 24 WPDMI 一〇〇一〇〇一〇〇 EPDM II EPDM III ϋΗ- ^v -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁) 100 100 ! — — 115 10 10 10 3_26 3.26 3.26 6 6 6 50 50 50 130 115 - 115 — 15 — 64 δ 64 P911 0·91 0.907 626 568 734 312 280 305 318 315 350 12 私 § 一2 285 200 281 319 256 239 15 13 12 s 81 85 -37- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 572960 經濟部智慧財產局員工消費合作社印制衣 A7 B7 五、發明說明（35 ) 雖然本發明之最良好模式與較佳具體實施例，已根據專利法提出，但本發明之範圍並不限於此，而是由隨文所P付之申請專利範圍所界定。因此，本發明之範圍係包括可落在申請專利範圍之範疇内之所有修正與變異。 -38- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） —----------裝------—訂--------- (請先閱讀背面之注意事項再填寫本頁)Shore A knows rrb14 欹 PM 《尜漭綷营 0 牦! 1 # 洳爷 (%) 芩 100% T ~ Yan ^ official 0% 14 ^ Sacrifice li ^ ACR (E >) ^ K- ^ a ♦ Carcass A Qingwei 230 (%) 礴 Cousin 0 Xue, 50% _ ^ @ · 29ο 5 5 5 3.26 3.26 3.26 7 7 7 219.2 21S 219.2 130 115 105.! 15 25 63 2 2 0.912 P912 0.909 6500§ 3iH ito name 356 o WJ4 s 126 119 192 225 250 203 232 288 17.5 15 14 77 700 ^ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and Xue _ ^^ _ 21 22 23 24 WPDMI 1001002010 EPDM II EPDM III ϋΗ- ^ v ---------- -Install -------- Order --------- (Please read the precautions on the back before filling this page) 100 100! — — 115 10 10 10 3_26 3.26 3.26 6 6 6 50 50 50 130 115-115 — 15 — 64 δ 64 P911 0 · 91 0.907 626 568 734 312 280 305 318 315 350 12 Private § 1 2 285 200 281 319 256 239 15 13 12 s 81 85 -37- This paper is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) 572960 Printed Clothing A7 B7 for Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention (35) Although the best mode and preferred embodiment of the present invention have been Filed under patent law, but the scope of the invention It is not limited to this, but is defined by the scope of patent application paid with the document. Therefore, the scope of the present invention includes all modifications and variations that may fall within the scope of the patent application. -38- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). -(Please read the notes on the back before filling this page)

Claims

572960 一^)572960 a ^)

、矣第0細0985號專利申請案二一中iii青專利範圍替換本吹年4月) 、申請專利範園 1· 一種用於形成熱塑性彈性體之組合物，其包含： 25至90重f百分率之橡膠與1〇至75重量百分率之熱塑性樹脂（以橡膠與熱塑性樹脂之總重量計）之摻合物，其中該橡膠係經部份或完全熟化，為乙烯、一或多種 α-烯烴及一或多種二烯單體之彈性共聚物，且其特徵為，當藉由不差掃描卡計法度量時，具有結晶度低於川焦耳/克，以整體共聚物為基準，乙烯含量低於90 莫耳百分比，當藉由GPC度量時，重量平均分子量大於 20,00Q ’及乙烯組成分佈低於4百分比。 2. 根據申請專利範圍第丨項之組合物，其中該組合物進一步包含增量油，選自石油操作油類、合成油類、增塑劑、有機酯類、烷基醚酯類，或其兩種或多種之組合。 3. 根據申請專利範圍第丨項之組合物，其中該彈性共聚物為乙烯、丙烯及5-亞乙基-2-原冰片烯之三元聚合體。 4. 根據申叫專利範圍第1項之組合物，其中該彈性共聚物 I特徵為，具有結晶度低3焦耳/克，以整體共聚物為基準，乙烯含量低於70莫耳百分比，重量平均分子量大於40,000，及乙烯組成分佈低於3百分比。 5·根據申請專利範圍第i項之組合物，其中該彈性共聚物之特徵為，具有結晶度低於0.2焦耳/克，以整體共聚物為基準，乙烯含量低於60莫耳百分比，重量平均分子f大於100,000 ’及乙烯組成分作低於2百分比。 6·根據申請專利範圍第1項之組合物，其中該彈性共聚物申清專利範圍之特徵為，具有結晶度低於01焦耳/克，以整體共聚物為基準’乙婦含量低於50莫耳百分比，重量平均分子量大於250,000，及乙稀·組成分柿低於1百分比。 7. 根據申请專利範圍第1項之組合物，其中該彈性共聚物具有木尼黏度（ML 1+4 @ 125°C )為5至5〇〇。 8. 根據申請專利範圍第7項之組合物，其中該彈性聚合體具有木尼黏度（ML 1+4 @ 125°C )為15至200。 9. 根據申凊專利範圍第1項之組合物，其中該掺合物包含一種:以上之橡膠。 1〇· 一種形成熱塑性彈性體之方法，其包括以下步騾： (a) 使25至90重量百分率之橡膠與1〇至75重量百分率之熱塑性樹脂（以橡膠與熱塑性樹脂之總重量計）掺合，其中該橡膠係經部份或完全熟化，為乙烯、一或多種α-烯烴及一或多種二烯單體之彈性共聚物，且其特徵為，當藉由示差掃描卡計法度量時，具有結晶度低於10焦耳/克，以整體共聚物為基準，乙烯含量低於90莫耳百分比，當藉由Gpc度量時，重量平均分子量大於20,000，及乙烯組成分佈低於4百分比；與 (b) 使所形成混合物中之橡膠動態硫化。 11.根據申請專利範圍第1〇項之方法，其中該摻合彈性共聚物與熱塑性樹脂之步驟，進一步包括摻合增量油與彈性共聚物及熱塑性樹脂’其中增量油係選自石油操作油類、合成油類、增塑劑、有機酯類、烷基醚酯類， -2- 572960 A BCD 々、申請專利範圍或其兩種或多種之組合。 12. 根據申請專利範圍i 10項之方法，其中該彈性共聚物之特徵為，具有結晶度低於3焦耳/克，及以整體共聚物為基準，乙烯含量低於70莫耳百分比，重量平均分子量大於40,000，且乙烯組成分佈低於3百分比。 13. 根據申請專利範圍第10項之方法，其中該彈性共聚物之特徵為，具有結晶度低於0.2焦耳/克，及以整體共聚物為基準，乙烯含量低於60莫耳百分比，重量平均分子量大於1〇〇,〇〇〇，且乙烯組成分佈低於2百分比。 14. 根據申請專利範圍第10項之方法，其中該彈性共聚物之特徵為，當藉由示差掃描卡計法度量時，具有結晶度低於0.1焦耳/克，以整體共聚物為基準，乙烯含量低於50莫耳百分比，重量平均分子量大於250,000，及乙烯組成分佈低於1百分比。 -3- 本紙張尺度適用中國國家標準(CNS) A4規格(210 x 297公釐）矣 Patent No. 0 Xi 0985 patent application No. 21 iii cyan patent scope replacement April this year), patent application Fanyuan 1. A composition for forming a thermoplastic elastomer, comprising: 25 to 90 weight f Percent blend of rubber and 10 to 75 weight percent thermoplastic resin (based on the total weight of rubber and thermoplastic resin), where the rubber is partially or fully cured and is ethylene, one or more alpha-olefins, and An elastic copolymer of one or more diene monomers, which is characterized by having a crystallinity of less than Chuan Joules / gram when measured by a non-defective scanning card meter method. Based on the overall copolymer, the ethylene content is less than 90 mol%. When measured by GPC, the weight average molecular weight is greater than 20,000Q 'and the ethylene composition distribution is less than 4%. 2. The composition according to item 丨 of the patent application scope, wherein the composition further comprises an extender oil selected from petroleum processing oils, synthetic oils, plasticizers, organic esters, alkyl ether esters, or A combination of two or more. 3. The composition according to item 丨 of the patent application scope, wherein the elastic copolymer is a terpolymer of ethylene, propylene, and 5-ethylidene-2-orbornene. 4. The composition according to claim 1 of the patent scope, wherein the elastic copolymer I is characterized by having a low crystallinity of 3 joules / gram, based on the overall copolymer, the ethylene content is less than 70 mol%, and the weight average The molecular weight is more than 40,000, and the ethylene composition distribution is less than 3%. 5. The composition according to item i of the patent application range, wherein the elastic copolymer is characterized by having a crystallinity of less than 0.2 J / g, based on the overall copolymer, an ethylene content of less than 60 mol%, and a weight average The molecular f is greater than 100,000 'and the ethylene composition is divided below 2 percent. 6. The composition according to item 1 of the scope of the patent application, wherein the patent scope of the elastic copolymer is characterized by having a crystallinity of less than 01 joules per gram, based on the overall copolymer, and the content of the second woman is lower than 50 Mo. Ear percentage, weight average molecular weight is greater than 250,000, and the percentage of ethylene and composition persimmon is less than 1 percentage. 7. The composition according to item 1 of the patent application scope, wherein the elastic copolymer has a Muni viscosity (ML 1 + 4 @ 125 ° C) of 5 to 5000. 8. The composition according to item 7 of the scope of patent application, wherein the elastic polymer has a Muni viscosity (ML 1 + 4 @ 125 ° C) of 15 to 200. 9. The composition according to item 1 of the patent application range, wherein the blend comprises one or more rubbers. 10. A method of forming a thermoplastic elastomer, comprising the following steps: (a) Blending 25 to 90 weight percent rubber with 10 to 75 weight percent thermoplastic resin (based on the total weight of rubber and thermoplastic resin) The rubber is partially or completely cured and is an elastic copolymer of ethylene, one or more α-olefins and one or more diene monomers, and is characterized in that when measured by differential scanning card method With a crystallinity of less than 10 Joules / gram, based on the overall copolymer, the ethylene content is less than 90 mol%, when measured by Gpc, the weight average molecular weight is greater than 20,000, and the ethylene composition distribution is less than 4%; and (b) Dynamic vulcanization of the rubber in the resulting mixture. 11. The method according to item 10 of the scope of patent application, wherein the step of blending the elastic copolymer and the thermoplastic resin further comprises blending an extender oil with an elastic copolymer and a thermoplastic resin, wherein the extender oil is selected from petroleum operations Oils, synthetic oils, plasticizers, organic esters, alkyl ether esters, -2-572960 A BCD 々, patent application scope or a combination of two or more of them. 12. The method according to item 10 of the scope of patent application, wherein the elastic copolymer is characterized by having a crystallinity of less than 3 Joules / gram, and based on the overall copolymer, with an ethylene content of less than 70 mol% and a weight average The molecular weight is greater than 40,000 and the ethylene composition distribution is less than 3%. 13. The method according to item 10 of the scope of patent application, wherein the elastic copolymer is characterized by having a crystallinity of less than 0.2 J / g, and based on the overall copolymer, with an ethylene content of less than 60 mol% and a weight average The molecular weight is greater than 100,000, and the ethylene composition distribution is less than 2%. 14. The method according to item 10 of the scope of patent application, wherein the elastic copolymer is characterized by having a crystallinity of less than 0.1 Joules / gram when measured by differential scanning calorimetry. Based on the overall copolymer, ethylene The content is less than 50 mol%, the weight average molecular weight is more than 250,000, and the ethylene composition distribution is less than 1%. -3- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm)