TW504720B - Independent flow-through capacitor - Google Patents

Abstract

An independent flow-through capacitor (FTC) is disclosed in the present invention. In the invented capacitor, a hollow reel is formed by two concentrically wound electrodes and two separating rubber rods. The center opening of the reel is capable of being inserted with a tube for feeding liquid material so as to deliver the fluid to the FTC. The active material of the electrode is mainly formed by the hydrated ferrite oxide Fe3O4 based nanometer-particles or powder. When fluid is injected from the feeding material tube, through the channel formed by the separation rubber rod of the reel, the fluid is restricted inside the FTC to flow outwards through the entire electrode (the longest route) of FTC. When a DC voltage not larger than 1.0 volt is added to the electrode, the ionic material is absorbed and is removed immediately by the processed liquid once it contacts the electrode. When the water solution of NaCl and CuSO4, and sea water flow through the FTC with a flow rate of 50 ml/min, the deionization rate can reach at least 19%. The capacitive deionization method of the invented FTC can be used to reduce the amount of waste liquid, and can be used to purify water and reject salt with cheap production cost and easy operation.

Description

504720 -HiltW£-d〇c/QQ9_B7 _ 五、發明說明（/ ) 發適領域 -----ILC-------^ · I I (請先閱讀背面之注意事項寫本頁) 本發明係關於一種含帶電物質之液體的電容去離子方 法（capacitive deionization ; CDI )。更定言之，本發明係 關於一種可以從無機及有機水溶液去除帶電物質之可更換 流通型電容器（flow-through capacitor FTC )。 曼明背景 線· 經濟部智慧財產局員工消費合作社印製 水係爲人類最珍貴資源的其中一種。更適切地說，水的 重要性可說是”給予我們生命”。地球面積中大約有四分之 三是水，其中98%是海水而其他2%是淡水。大部分的淡 水係在兩極的冰山，然而，可直接使用的確少於1%。隨 著都市化及工業化的人口增加’耗水量及廢水產生量也隨 之增加，許多國家因此遭遇到水荒及環境污染的問題。根 據UN預計，在西元2025年將有48國家其約佔世界人口 的32%左右的人們面臨缺乏淡水的問題。水對生活品質與 經濟繁榮而言極其重要。受污染的水可能會帶來疾病，政 府需要花費數百萬元以上之經費來淸潔受污染的地方。沒 有了淡水，日常生活及人類的活動將受到阻礙。雖然，提 供淡水資源給人民是政府的責任’然而地球上的人們也有 義務節約水用量，回收可用的資源及降低污染。 海水淡化是產生淡水最具經濟效益的方法。海水可整 年免費、無限量取得，不受到氣候的影響。然而，海水也 是所有鹽水之中總溶解固體量（TDS)最高的一種水。此 外，不論是有機或無機廢液，通常含有因爲水解、分解、 3 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） —Ε_____ 五、發明說明〇/) --------------裝---- (請先閱讀背面之注音？事項寫本頁) 凝聚'溶質的生物或化學反應所產生的帶電物質。海水及 液體中帶電物質總量係以TDS表示，單位爲ppm (每百萬 分之一）。不論是去鹽或廢水處理，其主要目的係爲了降 低TDS或去離子化，其純化的方法包括沈降、吸附、過 濾、臭氧化等。上述方法係在去離子化作用之上游或下游 處進行，以達預先處理或後處理進液液體之目的。當進料 液體的TDS降低到某一程度後可以應用於家庭或工業用 水。去離子化的方法例如是離子交換、蒸簡、逆滲透（R〇 ) 及電透析等一般技術。相較而言，CDI係爲一種相當新而 且鮮爲人知的技術。在選擇去離子化的方法時，必須考慮 材料及操作成本、濾液流量或產率；以及去鹽能力（salt rejection rate )。 --線· 用於去離子的離子交換樹脂大都是昂貴的合成樹脂， 其運作係以無害離子交換有毒離子。使用時，樹脂逐漸飽 和，因而需要再生。離子交換樹脂的再生需要使用強酸或 強鹼以及大量的沖洗水。因此，離子交換耗費非常多的水， 而再生用的化學物造成二度污染。爲了獲得淡水，蒸餾法 必須加熱鹽水或原水。蒸餾後，留下之離子形成泥漿。蒸 倉留是一種耗費能量的方法，並需要很大的空間，例如Nasser 的第4,636,283號美國專利揭露一種高度超過i〇〇m (>3〇〇 ft) 的蒸餾塔。不過，蒸餾仍是世界上海水淡化最被廣泛使用 的一種方法。就商業普及化而言，R〇是次廣受歡迎的淡 化方法。R0使用薄膜將淡水從鹽水中萃取出來，而離子 仍存在於原水中。R0需要高壓，例如800-1200 psig，以 4504720 -HiltW £ -d〇c / QQ9_B7 _ V. Description of Invention (/) Development Applicable Field ----- ILC ------- ^ · II (Please read the precautions on the back and write this page) The invention relates to a capacitive deionization method (CDI) of a liquid containing a charged substance. More specifically, the present invention relates to a replaceable flow-through capacitor (FTC) capable of removing charged substances from inorganic and organic aqueous solutions. Man Ming Background Line Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The water system is one of the most precious human resources. More appropriately, the importance of water can be said to "give us life". About three quarters of the earth's area is water, 98% of which is seawater and the other 2% is freshwater. Most of the freshwater is in icebergs at the poles, however, less than 1% is directly usable. As the population of urbanization and industrialization increases, water consumption and waste water production also increase, and many countries have suffered from water shortages and environmental pollution. According to UN estimates, people in 48 countries and about 32% of the world's population will face a shortage of fresh water by 2025 AD. Water is extremely important for quality of life and economic prosperity. Contaminated water can cause disease, and the government needs to spend more than several million yuan to clean up the polluted place. Without fresh water, daily life and human activities would be hindered. Although it is the government ’s responsibility to provide fresh water to the people ’, the people on earth also have an obligation to save water, recycle available resources and reduce pollution. Desalination is the most economical way to produce fresh water. Seawater can be obtained free and unlimited throughout the year without being affected by the climate. However, seawater is also the one with the highest total dissolved solids (TDS) among all brines. In addition, whether it is organic or inorganic waste liquid, it usually contains due to hydrolysis, decomposition, 3 paper standards applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) —E _____ V. Description of the invention 〇 /) ---- ---------- Pack ---- (Please read the note on the back? Matters to write on this page) Condensed charged substances produced by biological or chemical reactions of solutes. The total amount of charged substances in seawater and liquids is expressed in TDS, in ppm (parts per million). Whether it is desalination or wastewater treatment, its main purpose is to reduce TDS or deionization, and its purification methods include sedimentation, adsorption, filtration, ozonation, etc. The above method is performed upstream or downstream of the deionization for the purpose of pre-treating or post-treating the incoming liquid. When the TDS of the feed liquid is reduced to a certain level, it can be applied to domestic or industrial water. Deionization methods are, for example, general techniques such as ion exchange, distillation, reverse osmosis (RO), and electrodialysis. In contrast, CDI is a relatively new and little-known technology. When choosing a deionization method, material and operating costs, filtrate flow or yield, and salt rejection rate must be considered. --Wires. The ion exchange resins used for deionization are mostly expensive synthetic resins. Their operation is to exchange toxic ions with harmless ions. During use, the resin is gradually saturated and needs to be regenerated. Regeneration of ion exchange resins requires the use of strong acids or bases and large amounts of rinse water. As a result, ion exchange consumes a lot of water, and secondary chemicals cause secondary pollution. To obtain fresh water, the distillation method must heat brine or raw water. After distillation, the remaining ions form a slurry. Steam bunkering is an energy-consuming method and requires a lot of space. For example, U.S. Patent No. 4,636,283 to Nasser discloses a distillation column with a height exceeding 100 m (> 300 ft). However, distillation is still the most widely used method of water desalination in Shanghai. In terms of commercialization, Ro is the next most popular method of dilution. R0 uses a thin film to extract fresh water from the brine, while ions are still present in the raw water. R0 requires high pressure, such as 800-1200 psig, to 4

504720 A7 B7 7981twf.doc/009 五、發明說明（3 ) 強迫濾液（純水）通過薄膜的極微孔隙。高操作壓力及低 濾液流量是R0的二項缺點。R0的高操作壓力表示需要 高操作成本，而低濾液流量則會造成低產率。電透析方法 係利用DC電場及離子可穿透的薄膜進行去離子作用。每 個電透析單元裡至少含有三個部份，亦即陽極室，中間室 及陰極室。鹽水在中間室流動，離子因爲薄膜的選擇性穿 透作用及靜電引力而被吸引到陽極室或陰極室。就減少污 染的觀點，R0及電透析等薄膜技術並不捕捉或集中離子。 因此，這些技術僅能作爲液體純化之用，無法用以降低污 染。相反地，CDI係爲一種可以同時進行純化及降低污染 的技術，其進液液體的回收率高。 經濟部智慧財產局員工消費合作社印製 如同固體粒子容易以過濾介質去除，電場可以有效地 留住帶電物質。離子對於靜電引力能即時且可逆地反應， 此爲自然現象。在含有帶電物質的液體中，以兩平行導電 板之間通過電流的方式最容易產生此種靜電引力。當帶電 物質流過帶電之兩電極間時，帶電物質將迅速被吸附於電 極表面上，藉此可使TDS降低。此種去鹽方法稱爲電容 去離子（CDI)，進行CDI的裝置已知爲一種流過型電容 器（FTC)。FTC的應用已經在三十年前由J. Newman等 人公開在 J. Electrochem Soc·: Electrochemical Technology， March 1971，Ρ· 510-517，”利用多孔碳電極的去鹽方法”。 該案內容在此以參考方式倂入本案。另外，在此舉出三個 代表性CDI習知技術作參考，分別爲Andelman的美國專 利第5,779,891號，Hanank的美國專利第5,858,199號及 5 表紙張尺度適用中國國家標準（CNS)^4規格（21(^297公' 504720 7981twf.doc/〇〇9 A7 B7 經濟部智慧財產局員工消費合作社印製 … -五、發明說明（令） Farmer*的美國專利第5,9S4,937號。此三件專利案在此也 以參考方式倂入本發明。f891專利係使用石墨布作爲集電 板，及使用活性fe作爲離子吸附材料，以藉由物理壓縮形 成電極。活性材料與集電板之間沒有使用電氣結合性比物 理壓縮好的化學鍵結。黃金壓縮接點被用以結合電極線及 導線，導線再連接至DC電源。使用貴重金屬，就經濟觀 點而言，無法使FTC變成消費性產品。此外，891，專利將 鉛或其他過渡金屬摻入碳電極，以電解方法分解碳氫氯化 物（CHCs)。爲了更高的去毒效率，CHC最好以臭氧處 理’而非電解。爲了獲得最短及最直接的流徑，’891專利 在電極上開孔，並對準液體進液管的出水孔。如此設計， 不僅犧牲電極之吸附表面積，電極也要有特定的排列組 裝，使製程變複雜，而增加裝置成本及降低產品利潤。 爲了從液體中分離帶電物質，’199專利結合電場與化 合物之離心力成爲地球自轉偏向力（Coriolis force)。在設 備中加裝機械旋轉器，將造成高操作成本，且使用者操作 不易。除了碳材，’199專利也揭露混合金屬氧化物，例如 氧化鉅及氧化釕，作爲離子吸附的活性材料。然而，上述 氧化物非常昂貴，並不適用於處理大量液體。，937專利使 用昂貴的合成氣凝膠碳作爲離子吸附材料，供進行去鹽之 用。此碳材料，係由間苯二酚與甲醛聚合反應形成高分子， 接著在如900 pS1高的壓力下，於液態二氧化碳中進行超 臨界點乾燥，最後以500-120MC碳化乾燥之膠體。根據 Pekela美國專利第4,997,804號，單批次製備氣膠碳要花 6 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公釐） (請先閱讀背面之注意事項再㈣寫本頁) ii裝 -線- )U4720 7981twf.doc/〇〇9 A7 B7 五 發明說明（G ) 上二週，該案內容在此以參考方式倂入本發明。製程時間 長及使用高處理壓力與高溫度，會使FTC的材料成本變 高。此外，’937專利使用襯墊，螺栓，螺帽，端板及數對 電極以組合成一多層FTC。如此複雜的FTC結構，容易漏 液且缺乏工業用之便利性。CDI確實是一種降低液體TDS 之實用技術。然而，CDI需要更多硏究尋找經濟的材料及 FTC裝.置，以致於可以容易大量製造，並且讓使用者容易 操作該技術，成爲具有實質經濟效益之回收廢液、降低廢 水量及從海水製造淡水的裝置。 發明槪述 因此，本發明之目的係提供一種流通型電容器，可以 用於大量回收廢液，以降低廢水量。 本發明之再一目的係提供一種流通型電容器，可以有 效地淡化海水。 本發明之又 低其製造之成本 本發明之另 可以降 閱 背 Φ 之 事504720 A7 B7 7981twf.doc / 009 V. Description of the invention (3) Force the filtrate (pure water) through the extremely micropores of the membrane. High operating pressure and low filtrate flow are two disadvantages of R0. A high operating pressure of R0 means a high operating cost, while a low filtrate flow results in a low yield. Electrodialysis method uses a DC electric field and ion-permeable membrane for deionization. Each electrodialysis unit contains at least three parts, namely the anode chamber, the intermediate chamber and the cathode chamber. The brine flows in the intermediate chamber, and the ions are attracted to the anode or cathode chamber due to the selective permeation of the membrane and electrostatic attraction. From the viewpoint of reducing pollution, membrane technologies such as RO and electrodialysis do not capture or concentrate ions. Therefore, these techniques can only be used for liquid purification and cannot be used to reduce pollution. In contrast, CDI is a technology that can simultaneously purify and reduce pollution, and has a high recovery rate of the influent liquid. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Just as solid particles are easily removed by filter media, electric fields can effectively retain charged materials. Ions react instantly and reversibly to electrostatic attraction, which is a natural phenomenon. In a liquid containing a charged substance, such electrostatic attraction is most easily caused by passing a current between two parallel conductive plates. When a charged substance flows between two charged electrodes, the charged substance will be quickly adsorbed on the electrode surface, thereby reducing the TDS. This method of salt removal is called capacitive deionization (CDI), and the device that performs CDI is known as a flow-through capacitor (FTC). The application of FTC has been disclosed thirty years ago by J. Newman et al. In J. Electrochem Soc .: Electrochemical Technology, March 1971, P. 510-517, "Desalination Method Using Porous Carbon Electrode". The contents of this case are hereby incorporated by reference. In addition, three representative CDI know-how are cited here for reference, namely US Patent No. 5,779,891 by Andelman, US Patent No. 5,858,199 by Hanank, and Table 5. The paper standards are applicable to Chinese National Standard (CNS) ^ 4 specifications ( 21 (^ 297 公 '504720 7981twf.doc / 〇〇9 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ...-V. Description of Invention (Order) US Patent No. 5,9S4,937 to Farmer *. These three This patent case is also incorporated herein by reference. The f891 patent uses graphite cloth as a current collector and active fe as an ion-adsorbing material to form an electrode through physical compression. Between the active material and the current collector No chemical bonding with better electrical bonding than physical compression is used. Gold compression contacts are used to combine electrode wires and wires, which are then connected to a DC power supply. Using precious metals, from an economic point of view, FTC cannot be turned into a consumer product In addition, 891, the patent incorporates lead or other transition metals into the carbon electrode to decompose the hydrochloride (CHCs) electrolytically. For higher detoxification efficiency, CHC is best treated with ozone Management 'instead of electrolysis. In order to obtain the shortest and most direct flow path, the' 891 patent makes holes in the electrode and aligns with the water outlet of the liquid inlet pipe. This design not only sacrifice the adsorption surface area of the electrode, but also the electrode must have The specific arrangement and assembly complicates the process, increasing the cost of the device and reducing the profit of the product. In order to separate charged substances from the liquid, the '199 patent combines the centrifugal force of the electric field and the compound to become the Earth's rotation biasing force (Coriolis force). Installing a mechanical rotator will cause high operating costs and difficult operation for users. In addition to carbon materials, the '199 patent also discloses mixed metal oxides, such as oxidized giant and ruthenium oxide, as active materials for ion adsorption. However, the above oxides Very expensive and not suitable for processing large amounts of liquid. The 937 patent uses expensive synthetic aerogel carbon as an ion-adsorbing material for desalination. This carbon material is formed by the polymerization of resorcinol and formaldehyde. The molecules are then dried at a supercritical point in liquid carbon dioxide at a high pressure, such as 900 pS1, and finally at 50 pS1. 0-120MC carbonized dry colloid. According to Pekela US Patent No. 4,997,804, it takes 6 to prepare aerosol carbon in a single batch. This paper size is applicable to China National Standard (CNS) A4 (21〇X 297 mm) (Please read first Note on the reverse side of this page and reprint this page) ii installation-line-) U4720 7981twf.doc / 〇〇9 A7 B7 Five invention instructions (G) Last two weeks, the content of this case is hereby incorporated into the present invention by reference. Process The long time and high processing pressure and temperature will increase the material cost of FTC. In addition, the '937 patent uses gaskets, bolts, nuts, end plates and several pairs of electrodes to form a multilayer FTC. Such a complex FTC structure is prone to liquid leakage and lacks industrial convenience. CDI is indeed a practical technique for reducing liquid TDS. However, CDI needs more research to find economical materials and FTC equipment, so that it can be easily mass-produced, and it is easy for users to operate the technology, which has a substantial economic benefit in recycling waste liquid, reducing waste water, and reducing seawater. A device for making fresh water. DISCLOSURE OF THE INVENTION Therefore, an object of the present invention is to provide a flow-through capacitor that can be used to recover a large amount of waste liquid to reduce the amount of waste water. Another object of the present invention is to provide a flow-through capacitor which can effectively desalinate seawater. Another aspect of the invention is its low manufacturing cost.

t f 訂 經濟部智慧財產局員工消費合作社印製 目的是提供一種流通型電容器 並且降低其損耗之能源。 目的是提供一種流通型電容器 便攜帶，並且簡易操作。 利用CDI去除離子的方法係利用一種與超電容器（超 電容器可以儲存數千法拉（F)電荷）之儲能相同的機制。 CDI及超電容器均以雙層電容（DLC)爲主，如1879年 Helmholtz所述之雙層結構，作爲去離子或能量儲存之用。 根據本發明，首先合成奈米粒子，包括鐵鹽(fernte)，例如 可以方 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 7981twf.doc/009 A7 B7 經濟部智慧財產局員工消費合作社印製t f Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The purpose is to provide a circulation type capacitor and reduce its energy consumption. The purpose is to provide a portable capacitor that is portable and easy to operate. The method of removing ions using CDI uses the same mechanism as the energy storage of ultracapacitors (supercapacitors can store thousands of farads (F) of charge). CDI and supercapacitors are mainly double-layer capacitors (DLC). The double-layer structure described in 1879 by Helmholtz is used for deionization or energy storage. According to the present invention, nano particles are first synthesized, including fernte. For example, the Chinese paper standard (CNS) A4 (210 X 297 mm) can be applied to the paper size. 504720 7981twf.doc / 009 A7 B7 Wisdom of the Ministry of Economic Affairs Printed by the Property Agency Staff Consumer Cooperative

五、發明說明（k ) 水合氧化鐵Fex〇yHz，其中l.〇gx$3 〇，〇.〇<y‘4 〇及〇·〇 Szg 1.0，而且粒子的主要成分爲黑色磁鐵礦(Fe3〇4)。接 著，藉由滾筒塗佈法，粉末塗佈法或電泳沈積法，將這些 微粒固定在適當的集電板上，以形成一體之FTC電極，以 供廢液處理及去鹽之用。水合氧化鐵粉末係利用便宜的起 始材料製得，而且製造程序簡單快速。本發明的離子吸附 材料因此具經濟效益。 本發明所提供的FTC係以二片電極同心捲繞而得，兩 片電極間並用數個狹窄膠條相隔。電極捲筒之中心預留供 ***一根多孔進液管的空間。分隔膠條可以隔絕兩個電 極，使流體限制於FTC之內流動，並且使流體在電容器裡 面沿著所捲繞之電極板橫向流動。在蠕動泵浦的驅動下， 液體可在FTC中自由流動，並在離開電容器前，以水平及 向外前進方式流過全部之電極表面。離子因此具有與電極 的全部可用之表面積接觸並被吸附之最大機會。本發明之 FTC不僅使製造電極的活性材料用量達最小，而且電極及 電容器之量產容易自動化。因此，本發明使FTC成爲消費 者負擔得起的純化及去鹽消費產品。如同其他設計之FTC， 本發明之電容器亦可藉改變電極之電性而完全再生。而 且，當再生無法恢復電容器之原有的去離子能力時，電容 器可更換並丟棄或回收。本發明之離子吸附材料及更換型 FTC的集電板均可回收再用，因此有益於環保。 如同吸附碳材，離子交換樹脂及R〇薄膜通常皆爲卡 匣式之包裝，更換型FTC也可設計成卡匣型式。此FTC 請 先 閱 讀 背 意 事 項 訂 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 7981twf.doc/009 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（') 可以放置於一個容器內，容器外殼上設有流體之輸入及輸 出口，二個可連接電源的接點及一內有襯墊的頂蓋。前述 卡匣及其所有附件可用射出成型製得。將FTC置入卡匣筒 內，然後將液體進液管***FTC捲筒的中心，利用*** (snap-on)連接器連接電極導線與頂蓋上的電氣接頭，然後 用手旋緊具有螺紋的頂蓋，使卡匣密封。恢復一具CDI之 處理單元花費不到一分鐘的時間，而且不需要任何工具。 操作CDI需要如0.5伏特及100毫安培之低DC電能，如 此低的電能可以由電池、太陽能電池及燃料電池提供。與 蒸餾法、R0及電透析法比較，CDI的耗能低很多。使帶 電物質留在電極表面上，只需要很低的DC電壓，然而化 學反應或電解反應都應該避免，因爲它們對CDI能量效率 及電極壽命有不良影響。由於CDI以電能取代化學品再生 FTC的電極，因此沒有二次污染。另外，貴重金屬離子， 例如Au3+及Pd2+可以藉由CDI技術集中及濃縮，再以電鍍 或化學方法轉化成有用的形式。 由於體積小，重量輕而且可以利用電池操作，eDI成 爲一種可攜帶型的液體純化及海水淡化之去鹽技術。除了 容易將CDI納入任何已有之廢液處理系統，本發明更提供 經濟的離子吸附材料及容易使用的pTc裝置。本發明之目 I示在於幫助人們減少廢液，並自鹽水去除帶電物質而獲得 淡水。 圖式之簡單說明 (請先閱讀背面之注意事項再與寫本頁) .¾ 太 .. -_線- 9 504720 A7 B7 經濟部智慧財產局員工消費合作社印製 7981twf.doc/009 五、發明說明（2) 第1圖係爲流通式電容器（FTC)之CDI卡匣容器裡 面液體進液口及出液口的剖面視圖； 第2圖係爲電極與分隔片同心捲繞成捲筒電容器的立 體視圖； 第3圖係爲壓鑄之垂直多孔支架及水平膠條的圖案， 其中水平膠條限制液體在FTC裡面流動； 第4圖係爲CDI卡匣的上視圖，繪示出液體進液口及 出液口，電氣接頭，及FTC的組合結構； 第5A圖係說明NaCl溶液流經含有1，2及3個流通 型電容器的卡匣後，每50 ml流出液的導電度；第5B圖 顯示含有1，2及3個流通型電容器之卡匣的第一個50ml 收集液中離子之去除率。 圖式之標記說明· 102 104 106 108 110 ， 112 114 201 ， 202 203 302 304 液體進液管 出液口 頂蓋 容器主體 襯墊 螺絲洞 電極片 分隔片 水平膠條 垂直支架 10 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 五、發明說明) 411，413 電氣接頭 415 FTC組合結構 較佳實施例之詳細說明 經濟部智慧財產局員工消費合作社印製 水資源危機係爲世界上許多區域的當今或即將面臨的 議題。就水及其他液體中的污染而言，重金屬及帶電物質 乃爲主要的污染源。由於這些污染源可溶於液體中，因此 以總溶解固體量（TDS)計算並以ppm爲其單位。在許多 情況裡，當液體的TDS降低到某個ppm値時，被處理的 液體就可以使用。舉例而言，每個地方的海水TDS實質 上皆爲35,000 ppm，然而，當海水的TDS降到500 ppm 時就可用於灌溉。如果相同之海水的TDS低於200 ppm， 則可以適於飮用，而無鹹味。TDS之降低乃由於去鹽或去 離子所致，降低TDS的實施方法中，最方便者乃藉由電 容器結構之靜電電場。簡單離子與複雜之帶電物質在DC 電壓下，將立即被電極吸引。只要DC電壓存在時，帶電 物質就會停留在電極表面上。顯然地，吸附表面積越大時， 被吸附的離子數量及從進液中去除的離子數量即越多。然 而，電壓一停止施加時，被留住的大部份污染物將會釋出， 且只須要迅速將電極之極性來回顛倒數次，即可完成再 生。換言之，CDI可利用電能進行去離子及再生，相較於 取廣泛使用之離子交換技術，其再生離子交換樹脂所需要 的化學物品會造成二次污染而言，CDI是一種較爲環保的 技術。 11 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 五、發明說明（f) 經濟部智慧財產局員工消費合作社印製 本發明係應用經證實具有活性之超電容器的電極括性 材料，來製備CDI的離子吸附電極。爲了獲得電極的最大 面積，利用溶膠-凝膠（sol-gel)技術或電解技術製備鐵鹽 (ferrite)之奈米粉末，例如黑色磁鐵礦（Fe304 )及其複合 物。根據電容測量及其他測試，將合格的粉末轉化成構成 流通型電容器（FTC)捲筒的電極。連同進液管，將FTC 放入一^個幣4谷播以形成CDI處理單兀。第1圖係顯示卡 匣筒裡液體輸入及輸出的剖面視圖，其中爲了簡化說明， 省略繪示FTC。這個結構與過濾碳材、離子交換樹脂及r〇 薄膜之卡匣筒類似。液體進液管102及容器主體108可以 藉由射出成型方法，以工程塑膠，例如丙烯酸樹脂、聚碳 酸酯、聚氯乙烯（PVC) '聚乙烯（PE)或纖維強化塑膠（FRP) 製得。液體從進液管102的噴孔射出後，於經由出液口 1〇4 離開谷器BU，將流過FTC的全部電極表面。液體被引導以 水平及向外方式’流過其可接觸之電極的每^一*时表面，因 此可以增加帶電物質與FTC電極之間的接觸時間。因爲進 液流經FTC的最長路徑，因此帶電物質可以最有效地被處 理。利用壓縮襯墊110及112使容器頂蓋106緊貼附於容 器主體108，防止液體外漏。容器頂蓋1〇6可用與液體進 液管102和容器主體108相同的材料模製而得，而襯墊11〇 與112則是由氯丁二烯橡膠、丁基橡膠或矽酮橡膠做成。 在頂蓋106周圍及容器主體108邊緣上，設置鑽孔114， 以容納固定螺栓及螺帽。在另一具體實施例裡，頂蓋1〇6 與容器主體1〇8可攻牙能互相喫合之螺紋，以便用手拴緊。 12 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公釐） 504720 五、發明說明（l\ ) FTC組裝的形成及液體通道的產生，於下列各節中分別說 明。 經濟部智慧財產局員工消費合作社印製 第2圖係顯示根據本發明之一較佳具體實施例，一種 FTC組合結構，其中二個電極片201及202與二個相同之 分隔片203互交疊合並同心捲繞成一捲筒，在捲筒中心處 有一通孔。在第2圖中所示之FTC係以電極2〇1爲捲繞的 最內層，以構成中空捲筒的內壁。然而，在實際的應用時， 並不以此爲限，亦可以以分隔片203爲捲繞的最內層，以 構成中空捲筒的內壁。FTC組合結構的製造，可藉由一般 用於電容器及電池工業之捲繞機械設備，而輕易達到自動 化。所需寬度的電極片及相關配件可以連續輸入捲繞設備 中，捲繞成預定直徑的捲筒。捲筒經過切割並以膠帶固定 後，形成獨立式FTC組合結構。實際上，FTC組合結構係 爲一種超電容器之素子，只是缺少電解質及外殼。一旦電 極經過切割，集電板將外露並且產生毛邊，此可能造成短 路及其他對FTC組裝之傷害。因此，切割後需要補救程序， 例如去毛邊及鈍化絕緣。FTC組合結構的中央通孔之直徑 與進液管102之外徑吻合，且1〇2之外徑（OD)及內徑 (ID)均可隨需要而設計。另外，如第2圖所示，直徑"16” 的小孔均句分佈於進液管102的兩側上，孔與孔的間距大 約爲1/2"。依所要之FTC組裝的處理能力，進液管1〇2的 大小（，就OD，ID而言）及進液孔洞的直徑與數量皆可隨 之調整。CDI容器主體ι〇8和進液管1〇2與FTC須電氣絕 緣。電容器與容器108之間沒有電氣連通。電極201與202 13 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 981twf.doc/009 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（〇/) 係藉由各種沈積方法，將活性材料，如磁鐵礦（Fe304 ) 或其複合物塗覆於金屬箔，例如鋁箔、銅箔、鈦箔、不鏽 鋼箔或鎳箔上而成。其中活性材料的導電度不小於1〇-2 Siemen/cm，而磁通量密度不小於10 Gauss。FTC電極之 製作，也可以輕易地透過任何用以形成電極的沈積方法， 例如滾塗法、浸塗法、旋塗法、粉末塗覆法或電泳沈積法。 如果使用塗覆方法，例如滾塗法，則將上述粉末與黏結劑 在適當的溶劑內混合以形成塗覆漿液，其中黏結劑包括例 如聚二氟乙烯（PVDF)或聚四氟乙烯（PTFE)。當使用 相同的電極來製造FTC組合結構時，電極之極性係由電極 與外電源之間的連接決定。電極201或202可以藉由連接 至電源的正極而成爲陽極，而另一電極202或201則成爲 陰極。任一種連接都對FTC組合結構的去離子化功效沒有 影響。如熟習此項技藝者所知，載有離子吸附材料的基底 箔也傳導電子，因此稱爲集電板。集電板不會改善離子吸 附材料的導電度，但會影響FTC的耗電量及壽命。雖然第 2圖沒有顯示，但是電極導線可用基底箔的耳片（tab)， 或將其他金屬片以點銲或機械壓合固定於集電_反±。 板或電導線都不能與進液直接接觸，否則可能化 並因而影響CDI的效率。 應 第3圖係繪示根據本發明之一較佳具V. Description of the invention (k) FexOyHz hydrated iron oxide, of which 1.0gx $ 30.0, 0.00 < y'40 and 1.0Szg 1.0, and the main component of the particles is black magnetite (Fe3 〇4). Next, these particles are fixed on a suitable current collector plate by a roller coating method, a powder coating method, or an electrophoretic deposition method to form an integrated FTC electrode for waste liquid treatment and desalination. Hydrated iron oxide powder is made from cheap starting materials, and the manufacturing process is simple and fast. The ion-adsorbing material of the present invention is therefore economically beneficial. The FTC provided by the present invention is obtained by concentrically winding two electrodes, and the two electrodes are separated by several narrow rubber strips. The center of the electrode roll is reserved for inserting a porous inlet tube. The separator strip can isolate the two electrodes, restrict the fluid to flow within the FTC, and allow the fluid to flow laterally along the wound electrode plate inside the capacitor. Driven by the peristaltic pump, the liquid can flow freely in the FTC, and before leaving the capacitor, it flows horizontally and outwardly across all electrode surfaces. Ions therefore have the greatest chance of coming into contact with and being adsorbed on the entire available surface area of the electrode. The FTC of the present invention not only minimizes the amount of active material used to manufacture the electrodes, but also facilitates the automated production of electrodes and capacitors. Therefore, the present invention makes FTC an affordable purified and desalted consumer product for consumers. Like other designs of FTC, the capacitor of the present invention can also be completely regenerated by changing the electrical properties of the electrodes. Moreover, when regeneration cannot restore the original deionization capability of the capacitor, the capacitor can be replaced and discarded or recycled. Both the ion-adsorbing material and the collector plate of the replaceable FTC of the present invention can be recycled and reused, which is beneficial to the environment. As with the adsorption of carbon materials, ion exchange resins and Ro films are usually packaged in a cassette type, and the replacement type FTC can also be designed as a cassette type. This FTC, please read the note, the size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 504720 7981twf.doc / 009 B7 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives ') It can be placed in a container. The container housing is provided with fluid input and output ports, two contacts that can be connected to the power source, and a cushioned top cover. The aforementioned cassette and all its accessories can be made by injection molding. Put the FTC into the cartridge barrel, and then insert the liquid inlet tube into the center of the FTC roll. Use a snap-on connector to connect the electrode lead and the electrical connector on the top cover, and then screw the Top cover to seal the cassette. Recovery of a CDI processing unit takes less than a minute and requires no tools. Operating CDI requires low DC power such as 0.5 volts and 100 milliamps. Such low power can be provided by batteries, solar cells, and fuel cells. Compared with distillation, RO and electrodialysis, the energy consumption of CDI is much lower. Very low DC voltages are required to keep charged substances on the electrode surface. However, chemical reactions or electrolytic reactions should be avoided because they have a negative impact on CDI energy efficiency and electrode life. Since CDI replaces the electrodes of FTC with electrical energy, there is no secondary pollution. In addition, precious metal ions such as Au3 + and Pd2 + can be concentrated and concentrated by CDI technology, and then converted into useful forms by electroplating or chemical methods. Due to its small size, light weight, and battery operation, eDI has become a portable liquid purification and desalination technology for desalination. In addition to the ease of incorporating CDI into any existing waste liquid treatment system, the present invention provides economical ion adsorption materials and easy-to-use pTc devices. The purpose of the present invention is to help people reduce waste liquid and remove fresh water by removing charged substances from brine. A simple explanation of the drawing (please read the notes on the back before writing this page). 太 .. -_ 线-9 504720 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 7981twf.doc / 009 V. Invention Explanation (2) Figure 1 is a cross-sectional view of the liquid inlet and outlet of the CDI cartridge container of a flow-through capacitor (FTC); Figure 2 is the electrode and separator concentrically wound into a roll capacitor Three-dimensional view; Figure 3 is a pattern of die-cast vertical porous support and horizontal rubber strips, in which horizontal rubber strips restrict the flow of liquid in the FTC; Figure 4 is a top view of the CDI cartridge, showing the liquid inlet Figure 5A shows the conductivity of the NaCl solution flowing through the cartridge containing 1, 2 and 3 flow-through capacitors per 50 ml of the effluent; Figure 5B Shows the removal rate of ions in the first 50ml collection solution of a cassette containing 1, 2 and 3 flow-through capacitors. Explanation of the marks on the drawing · 102 104 106 108 110 ， 112 114 201 ， 202 203 302 304 Liquid inlet pipe Outlet cover Container body gasket Screw hole Electrode sheet separator Horizontal rubber strip vertical bracket 10 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 504720 V. Description of the invention 411,413 Electrical connector 415 FTC combination structure Detailed description of the preferred embodiment of the structure of the preferred embodiment of the Ministry of Economic Affairs Intellectual Property Bureau Employee Consumption Cooperative Printed Water Resources Crisis Department For today's or upcoming issues in many regions of the world. In terms of pollution in water and other liquids, heavy metals and charged substances are the main sources of pollution. Because these sources of pollution are soluble in liquids, they are calculated as total dissolved solids (TDS) and are expressed in ppm. In many cases, when the TDS of a liquid is reduced to a certain ppm 値, the liquid being processed is ready for use. For example, the TDS of seawater in each location is essentially 35,000 ppm. However, when the TDS of seawater drops to 500 ppm, it can be used for irrigation. If the TDS of the same seawater is less than 200 ppm, it can be suitable for use without salty taste. The reduction of TDS is caused by desalting or deionization. In the implementation method of reducing TDS, the most convenient method is the electrostatic field of the capacitor structure. Simple ions and complex charged substances are immediately attracted to the electrode under DC voltage. As long as a DC voltage is present, charged substances will remain on the electrode surface. Obviously, the larger the adsorption surface area, the greater the number of ions being adsorbed and the number of ions removed from the feed. However, when the voltage is stopped, most of the retained pollutants will be released, and the polarity of the electrode needs to be quickly reversed several times to complete the regeneration. In other words, CDI can use electric energy for deionization and regeneration. Compared with the widely used ion exchange technology, the chemicals needed to regenerate ion exchange resins will cause secondary pollution. CDI is a more environmentally friendly technology. 11 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 504720 V. Description of the invention (f) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This invention is based on the application of proven ultracapacitors The electrode includes a material to prepare an ion-adsorbing electrode for CDI. In order to obtain the maximum area of the electrode, sol-gel technology or electrolytic technology is used to prepare ferrite nano-powder, such as black magnetite (Fe304) and its composites. According to capacitance measurement and other tests, qualified powders are converted into electrodes that form a flow-through capacitor (FTC) roll. Along with the liquid inlet pipe, the FTC is placed in a coin and 4 grains to form a CDI processing unit. Fig. 1 is a cross-sectional view showing the liquid input and output in the cartridge barrel. In order to simplify the description, the FTC is omitted. This structure is similar to the cartridge of filter carbon, ion exchange resin and r0 film. The liquid inlet pipe 102 and the container body 108 can be made by injection molding using engineering plastics such as acrylic resin, polycarbonate, polyvinyl chloride (PVC), polyethylene (PE), or fiber reinforced plastic (FRP). After the liquid is ejected from the nozzle of the liquid inlet pipe 102, it leaves the trough unit BU through the liquid outlet port 104 and flows over the entire electrode surface of the FTC. The liquid is guided horizontally and outwardly 'across the surface of each of its accessible electrodes, thereby increasing the contact time between the charged substance and the FTC electrode. Because the influent flows through the longest path of the FTC, charged substances can be processed most efficiently. The container top cover 106 is tightly attached to the container main body 108 by the compression pads 110 and 112 to prevent leakage of liquid. The container top lid 106 can be molded from the same material as the liquid inlet pipe 102 and the container body 108, and the gaskets 110 and 112 are made of chloroprene rubber, butyl rubber or silicone rubber. . Drill holes 114 are provided around the top cover 106 and on the edge of the container body 108 to accommodate fixing bolts and nuts. In another specific embodiment, the top cover 106 and the container body 108 can tap the threads that can fit each other so as to be fastened by hand. 12 This paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) 504720 V. Description of the invention (l \) The formation of FTC assembly and the generation of liquid channels are described in the following sections. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Figure 2 shows an FTC combination structure in which two electrode pads 201 and 202 and two identical separator 203 overlap each other according to a preferred embodiment of the present invention. Combined and concentrically wound into a roll with a through hole in the center of the roll. The FTC shown in Fig. 2 uses the electrode 201 as the innermost layer wound to form the inner wall of the hollow roll. However, in actual application, it is not limited to this, and the separator 203 may be used as the innermost layer of the winding to form the inner wall of the hollow roll. The manufacture of the FTC combination structure can be easily automated by winding machinery and equipment generally used in the capacitor and battery industries. The required width of the electrode sheet and related accessories can be continuously fed into the winding equipment and wound into a roll of a predetermined diameter. After the roll is cut and fixed with tape, a free-standing FTC combination structure is formed. In fact, the FTC composite structure is an element of an ultracapacitor, but it lacks an electrolyte and a case. Once the electrodes are cut, the collector plate will be exposed and burrs will occur, which may cause short circuits and other damage to the FTC assembly. Therefore, remedial procedures are required after cutting, such as deburring and passivation insulation. The diameter of the central through hole of the FTC combination structure is consistent with the outer diameter of the liquid inlet pipe 102, and the outer diameter (OD) and inner diameter (ID) of the 102 can be designed as required. In addition, as shown in Figure 2, the small holes with a diameter of "16" are distributed on both sides of the liquid inlet pipe 102, and the distance between the holes is about 1/2. According to the desired processing capacity of the FTC assembly The size of the liquid inlet tube 102 (in terms of OD and ID) and the diameter and number of liquid inlet holes can be adjusted accordingly. The main body of the CDI container, the liquid inlet tube 102, and the FTC must be electrically insulated. There is no electrical communication between the capacitor and the container 108. The electrodes 201 and 202 13 This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 504720 981twf.doc / 009 A7 B7 Employees ’Consumption of Intellectual Property, Ministry of Economic Affairs Printed by the cooperative V. Description of the invention (〇 /) The active material, such as magnetite (Fe304) or its composite, is applied to metal foils, such as aluminum foil, copper foil, titanium foil, and stainless steel foil, by various deposition methods. Or nickel foil. The conductivity of the active material is not less than 10-2 Siemen / cm, and the magnetic flux density is not less than 10 Gauss. The fabrication of FTC electrodes can also be easily passed through any deposition method used to form the electrodes. Such as roll coating, dip coating, spin coating, powder Coating method or electrophoretic deposition method. If a coating method such as a roll coating method is used, the above powder and a binder are mixed in a suitable solvent to form a coating slurry, where the binder includes, for example, polyvinylidene fluoride (PVDF) Or polytetrafluoroethylene (PTFE). When the same electrode is used to make the FTC composite structure, the polarity of the electrode is determined by the connection between the electrode and an external power source. The electrode 201 or 202 can be made by connecting to the positive electrode of the power source The anode, while the other electrode 202 or 201 becomes the cathode. Either connection has no effect on the deionization effect of the FTC composite structure. As known to those skilled in the art, the base foil carrying the ion-adsorbing material also conducts electrons, It is called a collector plate. The collector plate will not improve the conductivity of the ion-adsorbing material, but it will affect the power consumption and life of the FTC. Although not shown in Figure 2, the electrode leads can be tabs of the base foil , Or other metal pieces are fixed to the current collector by anti-spot welding or mechanical compression bonding. Neither the board nor the electrical conductors can be in direct contact with the liquid, otherwise it may be affected and the efficiency of CDI will be affected. FIG. 3 illustrates a preferred tool according to the present invention.

施例，在FTCExample, in FTC

組合結構裡面形成液體通道。請同時參照第， 模製分隔片203包括水平膠條302及垂直支架3〇4。膠條 3〇2係用以隔絕兩個電極201、202，以使流體限制於FTC 14 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 請 先 閱 讀 背 項ii 寫 本 頁 訂 線 504720 A7 B7 981twf.doc/009 五、發明說明（ο) 之內流動，並且用以導引FTC裡面的液流，使流體在電容 器裡面沿著所捲繞之電極板橫向流動。而支架304係用以 支撐水平膠條302。因而，水平膠條302的厚度比支架304 厚，以使流體能在水平膠條302之間流動。例如膠條302 的厚度爲1mm，而支架304爲0.1mm厚。水平膠條302 係爲矩形帶狀，高約0.5mm到，而寬約1mm。上下 膠條位於電極之上下邊緣，中間的膠條間隔約30mm。頂 部膠條與底部膠條各略超出電極的邊緣’例如〇 · 2mm °垂 直支架304的寬度沒有限制，只要能支撐膠條302，並覆 蓋最少之電極表面即可。垂直支架304的間距至少30 mm ’ 寬度約2 mm而厚度約0·1 mm。利用分隔片203緊置於電 極201與202之間，如第2圖所示，分隔片的頂部膠條與 底部膠條皆與電極邊緣平行，用以限制液體在FTC組合結 構裡面。然而，中間膠條形成許多（0.5 —1) mm X 30 mm 經濟部智慧財產局員工消費合作社印製 的水平通道，使液體的流動實際上沒有受到限制。一旦@ 體從進液管102流出（如第1圖所示），則液體被限制在 上述的通道中呈水平及向外流動。沿著這些通道，液體流 過電極所有可接觸的表面。因爲支架304佔用相當大的胃 極表面積，因此在支架上形成數個孔洞以補償電極面積& 損失。較小的分隔片間隙雖然可產生較大的電容，但晏# 液體流動的限制則變大，適當之間隙取決於電容及阻力@ 平衡。用以隔離之膠條的高度可以從〇.3mm到1mm ’更 佳爲0.5mm到1mm。本發明之另一製造分隔膠條而不用 垂直支架的較佳具體實施例，係使用產生1mm X lmm膠 15 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 經濟部智慧財產局員工消費合作社印製 五、發明說明（v^V) 條的網印，其中膠條可用例如矽酮、橡膠或聚胺基甲酸乙 酯等彈性高分子做成，水平橫跨於電極上。分隔膠條與電 極的一體化，可以簡化FTC組合結構的製程。在本發明裡， 經模製或網印的分隔片之作用有三：1 )提供電極電氣絕 緣，以避免短路，2)限制液體於FTC組合結構裡面，及 3)定義流體在FTC組合結構裡面之流動路徑。除了彈性， 構成FTC組合結構之分隔片的高分子材料應能抵抗可能存 在於進液中的各種污染物，例如酸、鹼、鹽、有機物質及 微生物。 FTC係爲淨水及去鹽之CDI技術的核心。若CDI可變 成如常被用於廢液處理之過濾、離子交換及逆滲透等一樣 的普遍技術，則FTC之使用應該很方便。一般而言，任何 廢液處理技術之可更換元件的使用，應如同更換電燈泡或 電池那般容易。前述本發明的FTC組合結構可符合該項需 求。雖然FTC組合結構可以單獨執行廢液處理，但是最好 連同第4圖所示之容器使用。第4圖係爲第1圖之容器的 上視圖，因此以相同圖號標示同一元件。如第4圖所示， 可更換的FTC組合結構415係放入容器主體1 08內，利用 六個螺帽417及容器頂蓋1〇6密封。另一密封方法，係將 能吻合的公母螺紋設置於頂蓋106及容器108上，然後用 手旋緊。在容器頂蓋106頂上有二個電氣接頭411及413 以連接電源，例如乾電池、燃料電池或太陽能電池。以插 入式（snap-on)連接器完成FTC之電極與接頭411和413 之間的電氣連接（未示出）。廢液係經由進液管102進入 16 (請先閱讀背面之注咅？事項再填寫本頁) ,¾ . --線· 本紙張尺度適用中國國家標準（CNS)A4規袼（21〇 x 297公釐） 504720 7981twf.doc/009 A7Liquid channels are formed in the combined structure. Please refer to the same paragraph. The molded partition 203 includes a horizontal rubber strip 302 and a vertical bracket 304. The rubber strip 302 is used to isolate the two electrodes 201 and 202, so that the fluid is restricted to FTC 14 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) Please read the back item ii first Page order line 504720 A7 B7 981twf.doc / 009 V. The description of the invention (ο) flows and is used to guide the liquid flow in the FTC, so that the fluid flows laterally along the wound electrode plate in the capacitor. The bracket 304 is used to support the horizontal rubber strip 302. Therefore, the thickness of the horizontal rubber strip 302 is thicker than that of the bracket 304 so that the fluid can flow between the horizontal rubber strips 302. For example, the thickness of the rubber strip 302 is 1 mm, and the bracket 304 is 0.1 mm thick. The horizontal rubber strip 302 is a rectangular strip, with a height of about 0.5 mm and a width of about 1 mm. The upper and lower strips are located on the upper and lower edges of the electrode. The middle strips are spaced about 30mm apart. The top rubber strip and the bottom rubber strip each extend slightly beyond the edge of the electrode ', for example, the width of the vertical bracket 304 is not limited, as long as it can support the rubber strip 302 and cover the least electrode surface. The vertical brackets 304 have a pitch of at least 30 mm ', a width of about 2 mm, and a thickness of about 0.1 mm. The separator 203 is tightly placed between the electrodes 201 and 202. As shown in Fig. 2, the top and bottom rubber strips of the separator are parallel to the electrode edges to limit the liquid in the FTC assembly structure. However, the middle rubber strip forms many (0.5-1) mm X 30 mm horizontal channels printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, so that the flow of liquid is virtually unrestricted. Once the @body flows out of the inlet pipe 102 (as shown in Figure 1), the liquid is restricted to flow horizontally and outwardly in the above-mentioned channel. Along these channels, liquid flows through all accessible surfaces of the electrode. Because the stent 304 occupies a considerable surface area of the stomach, several holes are formed in the stent to compensate for electrode area & loss. Although a smaller separator gap can produce a larger capacitance, YAN # limits the flow of liquid, and the proper gap depends on the capacitance and resistance @ balance. The height of the rubber strip used for isolation may be from 0.3 mm to 1 mm ', more preferably from 0.5 mm to 1 mm. Another preferred embodiment of the present invention for manufacturing the adhesive strip without using a vertical bracket is to produce 1mm X lmm adhesive 15. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 504720 Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives. Screen printing of V.V (V ^ V) strips. The strips can be made of flexible polymers such as silicone, rubber, or polyurethane. on. The integration of the separation rubber strip and the electrode can simplify the manufacturing process of the FTC combination structure. In the present invention, the role of the molded or screen-printed separator is threefold: 1) to provide electrical insulation of the electrodes to avoid short circuits, 2) to restrict the liquid in the FTC composite structure, and 3) to define the fluid in the FTC composite structure. Flow path. In addition to elasticity, the polymer materials that make up the separator of the FTC composite structure should be able to resist various contaminants that may be present in the influent, such as acids, alkalis, salts, organic substances, and microorganisms. FTC is the core of CDI technology for water purification and desalination. The use of FTC should be convenient if CDI can be transformed into a common technology like filtration, ion exchange, and reverse osmosis, which are often used for waste liquid treatment. In general, the use of replaceable components in any waste treatment technology should be as easy as replacing a light bulb or battery. The aforementioned FTC combination structure of the present invention can meet this requirement. Although the FTC combination structure can perform waste liquid treatment alone, it is best to use it with the container shown in Figure 4. Figure 4 is a top view of the container of Figure 1, so the same components are labeled with the same drawing numbers. As shown in Fig. 4, the replaceable FTC combination structure 415 is placed in the container body 108, and sealed with six nut 417 and the container top cover 106. Another sealing method is to place the matching male and female threads on the top cover 106 and the container 108, and then tighten them by hand. There are two electrical connectors 411 and 413 on the top of the container lid 106 to connect a power source, such as a dry cell, a fuel cell or a solar cell. The electrical connection between the electrodes of the FTC and the connectors 411 and 413 (not shown) is accomplished with a snap-on connector. The waste liquid enters 16 through the liquid inlet pipe 102 (please read the note on the back? Matters before filling out this page), ¾. --Line · This paper size applies the Chinese National Standard (CNS) A4 Regulation (21〇x 297 Mm) 504720 7981twf.doc / 009 A7

五、發明說明（\< ) 谷器108，並在液體經由出液口 1〇4離開容器前，使液體 橫向平流經過FTC組合結構415。進液管1〇2與出液口 1(^ 之間沒有直接連通。FTC組合結構415可能須定期更換， 其他兀件則可無限期使用。因爲超電容器可用無機或有機 水溶液作爲電解液，所以不論廢液是否爲無機或有機水溶 液，只要離子存在於液體中，FTC組合結構均能將帶電物 質從所有廢液中去除。本發明可根據所需的CDI生產量， 製造需要的FTC組合結構41 5大小（以直徑及高度計）。 本發明之一較佳具體實施例係使用黑色磁鐵礦粉末或其複 合物，組成大小約60 mmd) X 150 mm的FTC組合結構 415，以發展利用CDI降低TDS的商業化FTC產品。本發 明的特色之一，在於使進液流經FTC組合結構之最長的路 徑，使FTC電極的所有有效面積都能用以吸附帶電物質， 因此可以達到去離子作用的最高生產率。以下列出數組實 驗數據以供參考，然而該些數據僅用以說明，而非限制本 發明。本發明可提供一種經濟且容易使用的CDI技術作爲 淨水及去鹽之用。 經濟部智慧財產局員工消費合作社印製 實施例1 利用滾塗法，將自製之水合氧化鐵均勻漿液塗在大約 爲150 mm X 490 mm X 0·1 mm的鋁箔上’形成FTC。漿液 係以下列配方爲主： lg Fe304 及 0.03g PVDF(聚二氟乙烯）與 1.5 ml NMP (N-甲基-2-口比略酮）混合成均勻相。 17 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 7981twf.d〇c/009 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（#0 以IR光照射或其他加熱裝置，將溶劑NMP蒸發後， 電極與分隔片捲成如第2圖所示之FTC捲筒。以陽極及陰 極之基底涪的耳片作爲電氣導線，並連接至一 DC電源。 將液體進液管102***捲筒中央，再將FTC放入塑膠容器 主體108內，其中容器主體108內徑爲60 mni而高度爲150 mm。然後，利用螺栓與螺帽將頂蓋]〇6固定在容器〗〇8， 藉此密封容器108，同時將二個耳片導線延伸到容器1〇8 外，然後與DC電源連接。FTC與其容器統稱爲一個卡匣。 單一卡匣，或多個卡匣可串聯用於各種液體的去離子。 液體：NaCl水溶液，導電度爲1〇4〇 // S/cm 電壓：1.0 DC伏特 液體流速·· 50 ml/min 卡匣數：1，2及3個 每50ml流出液收集一次後，以導電度計測量。測量使 用1個’ 2個及3個卡匣所收集之第一個50 ml流出液的 導電度，各得 8$2 // S/cm，676 // S/cm 及 385 // S/cm，代 表每一組FTC組合之去離子率爲I9%，％%及63%。第 5B圖係顯示流體僅流經不同卡匣數之去離子率。然而第5A 圖顯示所收集之後半部流出液的導電度急速增加，表示 FTC的電極表面很快被覆蓋。然而，所有流出液均不曾到 達進液的濃度。當CDI爲可用於液體處理中，去除帶電物 質的唯一方法時，則FTC的大小及數目可以量身訂作，以 符合需求。液體在CDI系統流通動的方式，也可以巧妙規 劃，以達所要之目的。 18 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 請 先 閱 讀 背 意 事 項V. Description of the invention (<) The trough device 108, and before the liquid leaves the container through the liquid outlet 104, the liquid is horizontally advected through the FTC combination structure 415. There is no direct communication between the inlet pipe 102 and the outlet port 1 ^. The FTC combination structure 415 may need to be replaced regularly, and other components can be used indefinitely. Because ultracapacitors can use inorganic or organic aqueous solutions as the electrolyte, so Regardless of whether the waste liquid is an inorganic or organic aqueous solution, as long as ions are present in the liquid, the FTC combination structure can remove charged substances from all waste liquids. The present invention can manufacture the required FTC combination structure according to the required CDI production volume 41 5 size (in terms of diameter and height). A preferred embodiment of the present invention is the use of black magnetite powder or its composite to form a FTC composite structure 415 with a size of about 60 mmd) x 150 mm to develop and reduce the use of CDI. TDS's commercial FTC products. One of the features of the present invention is that the longest path of the inlet liquid flowing through the FTC combination structure, so that all the effective area of the FTC electrode can be used to adsorb charged substances, so the highest productivity of deionization can be achieved. The array experimental data is listed below for reference, however, these data are only used for illustration, but not for limiting the present invention. The invention can provide an economical and easy-to-use CDI technology for water purification and desalination. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 1 Using a roll coating method, a uniform slurry of homemade hydrated iron oxide was coated on an aluminum foil of approximately 150 mm X 490 mm X 0.1 mm to form an FTC. The slurry is mainly based on the following formula: lg Fe304 and 0.03g PVDF (polydifluoroethylene) are mixed with 1.5 ml NMP (N-methyl-2-orbitalone) to form a homogeneous phase. 17 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 504720 7981twf.d〇c / 009 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (# 0 by IR light Irradiation or other heating device, after the solvent NMP is evaporated, the electrode and the separator are rolled into a FTC roll as shown in Figure 2. The ears of the anode and cathode substrate 涪 are used as electrical wires and connected to a DC power source. Insert the liquid inlet pipe 102 into the center of the reel, and then put the FTC into the plastic container body 108, where the container body 108 has an inner diameter of 60 mm and a height of 150 mm. Then, the top cover is bolted and screwed. 〇6 It is fixed to the container, thereby sealing the container 108, and simultaneously extending the two ear lead wires outside the container 108, and then connected to the DC power supply. The FTC and its container are collectively referred to as a cassette. A single cassette, or multiple cassettes The cartridge can be used in series for deionization of various liquids. Liquid: NaCl aqueous solution, conductivity is 104 // S / cm Voltage: 1.0 DC Volt Liquid flow rate · 50 ml / min Number of cartridges: 1, 2 and After collecting 3 effluents per 50ml, the conductivity is measured Measure the conductivity of the first 50 ml effluent collected using 1 '2 and 3 cassettes, and each gets 8 $ 2 // S / cm, 676 // S / cm and 385 // S / cm, representing the deionization rate of each group of FTC combinations is I9%, %% and 63%. Figure 5B shows the deionization rate of the fluid flowing through only a different number of cassettes. However, Figure 5A shows the second half The conductivity of the effluent increases rapidly, indicating that the electrode surface of the FTC is quickly covered. However, none of the effluent has reached the concentration of the influent. When CDI is the only method that can be used in liquid processing to remove charged substances, FTC The size and number can be tailored to meet the needs. The way the liquid flows in the CDI system can also be cleverly planned to achieve the desired purpose. 18 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Please read the note first

頁 訂 504720 7981twf.doc/009 A7 B7 五、發明說明（V^ ) 實施例2 使用去離子水沖洗用過的實施例1的FTC，直到流出 液顯示低導電度（讀取數位顯示的値）。以再生的FTC 進行下列測試。 液體：CuS04水溶液，導電度爲1420/zS/cm 電壓：1.0 DC伏特 液體流速：50 ml/min 卡匣數：2個 第一個收集的50 ml流出液的導電度測量爲724 # S/cm，表示當流體在非常低電壓下，一流經FTC便有49 %的離子被移除。 請 先 閱 讀 背 意 事 項ii 本 頁 訂 經濟部智慧財產局員工消費合作社印製 實施例3 使用類似實施例2的再生方法製備海水淡化用的 FTC。從台灣西海岸某處取得太平洋的海水。爲了符合本 發明所用的導電度計的測量範圍，利用去離子水’將樣品 稀釋50倍。所用之樣品的TDS (總溶解固體量）估計爲 20,000 ppm。沒有經過任何前處理，即以下列條件進行稀 釋海水的淡化試驗。 液體：經稀釋之海水，導電度爲793// S/cm 電壓：1.0DC伏特 液體流速：50 ml/min 卡匣數：2個 19 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 504720 A7 7981twf.d〇c/〇〇9 取 ---------* ' 麵 _ 五、發明說明 第一個收集的5〇 ml流出液的導％度測量爲619以 S/Cm，總計有21%的離子被移除。本例_實施例〗的卡厘 數同爲2個，但是本實施例的去離子能力較差。這可能是 因爲海水的組成較NaC1溶液更爲複雜。 實施例4 於氧化鐵之起始材料中，放入一批次合成中所能產出 之Fe304之20重量％的活性碳，以溶膠-凝膠法進行；pe3〇4/c 複合粉末之合成。如问貫施例1的方式，配置複合粉末的 漿液，以製得FTC及其處理單元以純化水樣。 液體：NaCl水溶液，導電度爲1〇82// s/cm 電壓：1.0 DC伏特 液體流速：50 ml/min 卡匣數：1個 第一個收集的50 ml流出液的導電度測量爲 779 // S/cm，流體只流經單一電容器卡匣時，即移除28% 的離子。因爲活性碳的表面積比Fe304大，所以利用複合 物之FTC所得的去離子率比利用純金屬氧化物所得者更 高。此觀察結果與超電容器的能量儲存理論相符。 從上述的實施例可知，本發明係爲液體純化及海水淡 化的可行工具。由於材料便宜且容易製造’使用本發明的 CDI可以加入污染控制及環境保護最常用的技術行列° 雖然本發明已以一較佳實施例揭露如上’然其並非用 以限定本發明，任何熟習此技藝者，在不脫離本發明之精 20Page order 504720 7981twf.doc / 009 A7 B7 V. Description of the Invention (V ^) Example 2 Rinse the used FTC of Example 1 with deionized water until the effluent shows low conductivity (read the digital display of 値) . The following tests were performed with regenerated FTC. Liquid: CuS04 aqueous solution, conductivity is 1420 / zS / cm Voltage: 1.0 DC volts Liquid flow rate: 50 ml / min Number of cassettes: 2 The first collected 50 ml effluent has a conductivity of 724 # S / cm , Which means that when the fluid is at a very low voltage, 49% of the ions are removed by FTC. Please read the introductory note ii on this page. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Example 3 A FTC for seawater desalination was prepared using a regeneration method similar to that in Example 2. The Pacific Ocean was taken from somewhere on the west coast of Taiwan. In order to comply with the measurement range of the conductivity meter used in the present invention, the sample was diluted 50 times with deionized water '. The TDS (Total Dissolved Solids) of the sample used is estimated at 20,000 ppm. Without any pretreatment, the desalination test of dilute seawater was performed under the following conditions. Liquid: Diluted seawater, conductivity is 793 // S / cm Voltage: 1.0DC Volt Liquid flow rate: 50 ml / min Number of cassettes: 2 19 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 504720 A7 7981twf.d〇c / 〇〇9 Take --------- * 'surface_ V. Description of the invention 5 The% conductivity of the ml effluent was measured at 619 in S / Cm, and a total of 21% of the ions were removed. The caliper number of this example_embodiment is two, but the deionization ability of this example is poor. This may be because the composition of seawater is more complicated than that of NaC1 solution. Example 4 In the starting material of iron oxide, 20% by weight of activated carbon of Fe304 that can be produced in a batch of synthesis was put in a sol-gel method; synthesis of pe304 / c composite powder . In the same manner as in Example 1, the slurry of the composite powder was arranged to prepare FTC and its processing unit to purify the water sample. Liquid: NaCl aqueous solution, conductivity is 1082 // s / cm Voltage: 1.0 DC Volt Liquid flow rate: 50 ml / min Number of cassettes: 1 The first collected 50 ml effluent has a conductivity of 779 / / S / cm, 28% of the ions are removed when the fluid flows through a single capacitor cartridge. Since the surface area of activated carbon is larger than that of Fe304, the deionization rate obtained by using FTC of the composite is higher than that obtained by using pure metal oxide. This observation is consistent with the energy storage theory of ultracapacitors. As can be seen from the above examples, the present invention is a feasible tool for liquid purification and seawater desalination. Because the material is cheap and easy to manufacture, the CDI of the present invention can join the ranks of the most commonly used technologies for pollution control and environmental protection. Although the present invention has been disclosed above with a preferred embodiment, it is not intended to limit the present invention. Artists, without departing from the essence of the invention 20

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 A7 B7 7981twf.doc/009 五、發明說明（巧） 神和範圍內，當可作各種之更動與潤飾，因此本發明之保 護範圍當視後附之申請專利範圍所界定者爲準。 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 504720 A7 B7 7981twf.doc / 009 V. Description of the invention (Clever) Within the scope of God and God, it can be modified and retouched. Therefore, this paper The scope of protection of the invention shall be determined by the scope of the attached patent application. Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

504720 A8 B8 C8 7981twf.doc/009 j)g 六、申請專利範圍 1. 一種獨立式流通型電容器，包括： 一第一電極，包括一第一活性材料及一第一導電箔， 其中該第一活性材料與該第一導電箔合爲一第一可撓性連 糸買長片； 一第二電極，該第二電極包括一第二活性材料及一第 二導電箔，其中該第二活性材料與該第二導電箔合爲一第 二可撓性連續長片； 一第一分隔片； 一第二分隔片， 其中該第一電極、該第一分隔片、該第二電極與該第二分 隔片係依序相疊合，且同心捲成一中空捲筒並且該第一分 隔片與該第二分隔片在該中空捲筒內的該第一及該第二電 極之間具有一間隙。 2. 如申請專利範圍第1項所述之流通型電容器，其中 該分第一分隔片與該第二分隔片，係分別由至少二長膠條 所構成。 3. 如申請專利範圍第2項所述之流通型電容器，其中 該第一分隔片與該第二分隔片，係分別更包括至少一支撐 架，該支撐架係配置於該些長膠條之間，用以支撐該些長 膠條。 4. 如申請專利範圍第3項所述之流通型電容器，其中 該些長膠條的厚度大於該支撐架之厚度。 5. 如申請專利範圍第3項所述之流通型電容器，其中 該支撐架具有複數個開孔。 22 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂· 線· 經濟部智慧財產局員工消費合作社印彻衣 504720 A8 B8 no 19 81twf. doc/ 0 0 9 gg 六、申請專利範圍 6. 如申請專利範圍第1項所述之流通型電容器，其中 該第一活性材料與該第二活性材料爲具有FexOyHz化學式 的化學組成，且 1.0‘χ€3·0，0·0<γ‘4·0，0·0‘ζ‘ 1·0。 7. 如申請專利範圍第6項所述之流通型電容器，其中 該第一活性材料與該第二活性材料爲Fe304。 8. 如申請專利範圍第1項所述之流通型電容器，其中 該第一活性材料與該第二活性材料爲一含有Fe304的複合 化合物。 9. 如申請專利範圍第8項所述之流通型電容器，其中 而該含有Fe304的複合化合物的其他組份係選自由活性 碳、石墨、氧化錫、氧化鋅及氧化鈦所組成之族群者。 10. 如申請專利範圍第1項所述之流通型電容器，其中 該第一活性材料與該第二活性材料係由導電度不小於 Siemen/cm之材質所構成。 11. 如申請專利範圍第1項所述之流通型電容器，其中 該第一活性材料與該第二活性材料係由磁通量密度不小於 10 Gauss之材質所構成。 經濟部智慧財產局員工消費合作社印製 12. 如申請專利範圍第1項所述之流通型電容器，其中 該第一導電箔與該第二導電筢係選自由銘、銅、鎳 '不鏡 鋼及鈦所組成者。 13. 如申請專利範圍第1項所述之流通型電容器，其中 該第一、第二電極係藉由滾塗法、浸塗法、旋塗法、粉末 塗覆法或電泳沈積法將該第一、第二活性材料分別塗覆於 該第一、該第二導電箔上而得。 23 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 7981twf.d〇c/〇〇9 A8 B8 C8 D8 經濟部智慧財產局員工消費合作社印谢衣 六、申請專利範圍 14·如申請專利範圍第1項所述之流通型電容器，其中 於弟 弟一'電極係將離子物質吸附於其表面上，並且利 用施加電壓於該第一、第二電極，以進行液體的去離子化 作用。 15. 如申請專利範圍第1項所述之流通型電容器，其中 該第一、第二電極係利用靜電吸引力吸附離子。 16. 如申請專利範圍第丨項所述之流通型電容器，其中 連接該第一電極於一電源的正極而連接該第二電極於該電 源的負極，使該第一電極成爲陽極而該第二電極爲陰極。 Π.如申請專利範圍第1項所述之流通型電容器，其中 連接該第二電極於一電源的正極而連接該第一電極於該電 源的負極，使該第二電極成爲陽極而該第一電極爲陰極。 18·—種獨立式流通型電容器，包括： 一容器主體，其包括一開口與一出液口； 一電容器主體，係配置於該容器主體之中，其包括： 一第一電極，包括一第一活性材料及一第一導電 箔’其中該第一活性材料與該第一導電箔合爲一第一可撓 性連續長片； 一第二電極，該 一第二導電箔，其中該第 電極包括^一^弟一^活性材料及 該第二導電箔合爲 一第二可撓性連續長片； 一第一分隔片； 一第二分隔片，其中該第一電極、該第一分隔片、 該第二電極與該第二分隔片係依序相疊合，且同心捲成一 24 (請先閱讀背面之注意事項再掏寫本頁) 訂-· 線· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 B8 7981twf.doc/009 β| 六、申請專利範圍 中空捲筒，且該第一分隔片與該第二分隔片在該中空捲筒 內的該第一及該第二電極之間具有一間隙； 一容器頂蓋，配置於該容器主體之該開口上；以及 一進液管，穿過該容器頂蓋，並且配置於該中空捲筒 之一中心開口之中。 19. 如申請專利範圍第18項所述之流通型電容器，其 中該分第一分隔片與該第二分隔片，係分別由至少二長膠 條所構成。 20. 如申請專利範圍第18項所述之流通型電容器，其 中該第一分隔片與該第二分隔片，係分別更包括至少一支 撐架，該支撐架係配置於該些長膠條之間，用以支撐該些 長膠條。 21. 如申請專利範圍第20項所述之流通型電容器，其 中該些長膠條的厚度大於該支撐架之厚度。 22. 如申請專利範圍第20項所述之流通型電容器，其 中該支撐架具有複數個開孔。 經濟部智慧財產局員工消費合作社印製 23. 如申請專利範圍第18項所述之流通型電容器，其 中該第一活性材料與該第二活性材料爲具有FexOyHz化學 式的化學組成，且 1.0SxS3.0，0.0<yS4.0，O.OSz - 1.0。 24. 如申請專利範圍第23項所述之流通型電容器，其 中該第一活性材料與該第二活性材料爲Fe3〇4。 25. 如申請專利範圍第18項所述之流通型電容器，其 中該第一活性材料與該第二活性材料爲一含有Fe304的複 合化合物。 25 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 A8 B8 7 9 8 1 twf . doc/ 0 0 9 六、申請專利範圍 26. 如申請專利範圍第25項所述之流通型電容器，其 中而該含有Fe304的複合化合物的其他組份係選自由活性 碳、石墨、氧化錫、氧化鋅及氧化鈦所組成之族群者。 27. 如申請專利範圍第18項所述之流通型電容器，其 中該第一活性材料與該第二活性材料係由導電度不小於 10·2 Siemen/cm之材質所構成。 28. 如申請專利範圍第18項所述之流通型電容器，其 中該第一活性材料與該第二活性材料係由磁通量密度不小 於10 Gauss之材質所構成。 29. 如申請專利範圍第18項所述之流通型電容器，其 中該第一導電箔與該第二導電箔係選自由鋁、銅、鎳、不 銹鋼及鈦所組成者。 30. 如申請專利範圍第18項所述之流通型電容器，其 中該第一、第二電極係藉由滾塗法、浸塗法、旋塗法、粉 末塗覆法或電泳沈積法，將該第一、第二活性材料分別塗 覆於該第一、該第二導電箔上而得。 經濟部智慧財產局員工消費合作社印製 31. 如申請專利範圍第18項所述之流通型電容器，其 中該第一、第二電極係將離子物質吸附於其表面上，並且 利用施加電壓於該第一、第二電極，以進行液體的去離子 化作用。 32. 如申請專利範圍第18項所述之流通型電容器，其 中該第一、第二電極係利用靜電吸引力吸附離子。 33. 如申請專利範圍第18項所述之流通型電容器，其 中連接該第一電極於一電源的正極而連接該第二電極於該 26 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 504720 έΐ C8 7981twf.doc/009 D8 六、申請專利範圍 電源的負極，使該第一電極成爲陽極而該第二電極爲陰 極。 34. 如申請專利範圍第18項所述之流通型電容器’其 中連接該第二電極於一電源的正極而連接該第一電極於該 電源的負極，使該第二電極成爲陽極而該第一電極爲陰 極。 35. 如申請專利範圍第18項所述之流通型電容器’其 中該頂蓋與該容器主體具有能互相契合之螺紋。 3 6.如申請專利範圍第18項所述之流通型電谷益’其 中該頂蓋與該容器主體係以螺栓與螺帽固定。 3 7.如申請專利範圍第18項所述之流通型電谷益’其 中該進液管與該容器主體之材質係選自於丙烯酸樹脂、聚 碳酸酯、聚氯乙烯(PVC)、聚乙烯(PE)或纖維強化塑膠（FRP) 組成之族群。 38.如申請專利範圍第18項所述之流通型電容器，更 包括一襯墊配置於該頂蓋與該容器主體之間’用以防止液 體外漏。 (請先閱讀背面之注意事項再填寫本頁) 訂· 線· 經濟部智慧財產局員工消費合作社印製 27 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）504720 A8 B8 C8 7981twf.doc / 009 j) g 6. Scope of patent application 1. An independent flow-through capacitor includes: a first electrode including a first active material and a first conductive foil, wherein the first The active material and the first conductive foil are combined into a first flexible flail to buy a long piece; a second electrode, the second electrode includes a second active material and a second conductive foil, wherein the second active material Combined with the second conductive foil into a second flexible continuous sheet; a first separator; a second separator, wherein the first electrode, the first separator, the second electrode and the second The separators are sequentially stacked, and are concentrically rolled into a hollow roll, and the first separator and the second separator have a gap between the first and second electrodes in the hollow roll. 2. The flow-through capacitor according to item 1 of the scope of the patent application, wherein the first and second separators are each composed of at least two long strips of rubber. 3. The flow-through capacitor according to item 2 of the scope of patent application, wherein the first separator and the second separator each further include at least one support frame, and the support frame is disposed on the long rubber strips. To support the long strips. 4. The flow-through capacitor as described in item 3 of the scope of patent application, wherein the thickness of the long strips is greater than the thickness of the support frame. 5. The flow-through capacitor according to item 3 of the patent application scope, wherein the support frame has a plurality of openings. 22 This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) Order · Thread · Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Consumption Co-operative Printing 504720 A8 B8 no 19 81twf. Doc / 0 0 9 gg 6. Application scope of patent 6. The flow-through capacitor as described in item 1 of the scope of patent application, wherein the first active material and the second active material are chemical compounds with the chemical formula FexOyHz Composition and 1.0'χ € 3 · 0,0 · 0 < γ'4 · 0,0 · 0'ζ '1 · 0. 7. The flow-through capacitor according to item 6 of the scope of patent application, wherein the first active material and the second active material are Fe304. 8. The flow-through capacitor according to item 1 of the scope of patent application, wherein the first active material and the second active material are a composite compound containing Fe304. 9. The flow-through capacitor as described in item 8 of the scope of patent application, wherein the other components of the composite compound containing Fe304 are selected from the group consisting of activated carbon, graphite, tin oxide, zinc oxide, and titanium oxide. 10. The flow-through capacitor according to item 1 of the scope of patent application, wherein the first active material and the second active material are made of a material having a conductivity of not less than Siemen / cm. 11. The flow-through capacitor according to item 1 of the scope of patent application, wherein the first active material and the second active material are made of a material having a magnetic flux density of not less than 10 Gauss. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 12. The flow-through capacitor as described in item 1 of the scope of patent application, wherein the first conductive foil and the second conductive foil are selected from the group consisting of Ming, copper, and nickel. And titanium. 13. The flow-through capacitor according to item 1 of the scope of patent application, wherein the first and second electrodes are formed by a roll coating method, a dip coating method, a spin coating method, a powder coating method, or an electrophoretic deposition method. A first and a second active material are respectively coated on the first and the second conductive foils. 23 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 504720 7981twf.d〇c / 〇〇9 A8 B8 C8 D8 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 14. The flow-through capacitor as described in item 1 of the scope of patent application, wherein the younger brother Yu's electrode system adsorbs ionic substances on its surface, and applies a voltage to the first and second electrodes to remove the liquid. Ionization. 15. The flow-through capacitor according to item 1 of the scope of the patent application, wherein the first and second electrodes use electrostatic attraction to adsorb ions. 16. The flow-through capacitor according to item 丨 of the patent application scope, wherein the first electrode is connected to the positive electrode of a power supply and the second electrode is connected to the negative electrode of the power supply, so that the first electrode becomes the anode and the second electrode The electrode is the cathode. Π. The flow-through capacitor according to item 1 of the scope of patent application, wherein the second electrode is connected to the positive electrode of a power supply and the first electrode is connected to the negative electrode of the power supply, so that the second electrode becomes the anode and the first The electrode is the cathode. 18 · —A self-contained flow-through capacitor, comprising: a container body including an opening and a liquid outlet; a capacitor body disposed in the container body and including: a first electrode including a first electrode An active material and a first conductive foil, wherein the first active material and the first conductive foil are combined into a first flexible continuous sheet; a second electrode, the second conductive foil, and the first electrode The first conductive material and the second conductive foil are combined into a second flexible continuous sheet; a first separator; a second separator, wherein the first electrode and the first separator The second electrode and the second separator are sequentially stacked and are concentrically rolled into a 24 (please read the precautions on the back before writing this page) Order-· Line · This paper size applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) 504720 B8 7981twf.doc / 009 β | 6. The patent application is for a hollow roll, and the first separator and the second separator are in the first part of the hollow roll. There is a gap between the second electrode and the second electrode; Container lid disposed on the opening of the container body; and a liquid inlet pipe, through which the vessel head, and disposed in the central opening in one of the hollow roll. 19. The flow-through capacitor according to item 18 of the scope of patent application, wherein the first separator and the second separator are each composed of at least two long strips. 20. The flow-through capacitor according to item 18 of the scope of patent application, wherein the first separator and the second separator each further include at least one support frame, and the support frame is disposed on the long rubber strips. To support the long strips. 21. The flow-through capacitor according to item 20 of the scope of patent application, wherein the thickness of the long strips is greater than the thickness of the support frame. 22. The flow-through capacitor according to item 20 of the patent application scope, wherein the support frame has a plurality of openings. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 23. The flow-through capacitor as described in item 18 of the scope of patent application, wherein the first active material and the second active material have a chemical composition of the FexOyHz chemical formula, and 1.0SxS3. 0, 0.0 < yS4.0, O.OSz-1.0. 24. The flow-through capacitor according to item 23 of the scope of patent application, wherein the first active material and the second active material are Fe304. 25. The flow-through capacitor according to item 18 of the scope of the patent application, wherein the first active material and the second active material are a composite compound containing Fe304. 25 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 504720 A8 B8 7 9 8 1 twf .doc / 0 0 9 VI. Scope of patent application 26. As described in item 25 of the scope of patent application A flow-through capacitor, in which the other components of the Fe304-containing composite compound are selected from the group consisting of activated carbon, graphite, tin oxide, zinc oxide, and titanium oxide. 27. The flow-through capacitor according to item 18 of the scope of patent application, wherein the first active material and the second active material are made of a material having a conductivity of not less than 10 · 2 Siemen / cm. 28. The flow-through capacitor according to item 18 of the scope of the patent application, wherein the first active material and the second active material are made of a material having a magnetic flux density of not less than 10 Gauss. 29. The flow-through capacitor according to item 18 of the scope of the patent application, wherein the first conductive foil and the second conductive foil are selected from the group consisting of aluminum, copper, nickel, stainless steel, and titanium. 30. The flow-through capacitor as described in item 18 of the scope of patent application, wherein the first and second electrodes are formed by a roll coating method, a dip coating method, a spin coating method, a powder coating method, or an electrophoretic deposition method. The first and second active materials are respectively coated on the first and the second conductive foils. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 31. The flow-through capacitor as described in item 18 of the scope of patent application, wherein the first and second electrodes adsorb ionic substances on the surface and apply voltage to the The first and second electrodes perform deionization of the liquid. 32. The flow-through capacitor according to item 18 of the scope of the patent application, wherein the first and second electrodes use electrostatic attraction to adsorb ions. 33. The flow-through capacitor as described in item 18 of the scope of the patent application, wherein the first electrode is connected to the positive electrode of a power source and the second electrode is connected to the 26 paper. The Chinese paper standard (CNS) A4 specification (210 X 297 mm) 504720 ΐ C8 7981twf.doc / 009 D8 6. The negative electrode of the patent application power supply, so that the first electrode becomes the anode and the second electrode becomes the cathode. 34. The flow-through capacitor according to item 18 of the scope of the patent application, wherein the second electrode is connected to the positive pole of a power source and the first electrode is connected to the negative pole of the power source, so that the second electrode becomes the anode and the first The electrode is the cathode. 35. The flow-through capacitor according to item 18 of the scope of the patent application, wherein the top cover and the container body have threads that can fit each other. 3 6. The circulation type electric valley benefit described in item 18 of the scope of patent application, wherein the top cover and the main system of the container are fixed with bolts and nuts. 3 7. The flow-through electric valley benefit described in item 18 of the scope of the patent application, wherein the material of the liquid inlet pipe and the container body is selected from acrylic resin, polycarbonate, polyvinyl chloride (PVC), and polyethylene (PE) or fiber reinforced plastic (FRP). 38. The flow-through capacitor according to item 18 of the scope of patent application, further comprising a gasket disposed between the top cover and the container body 'to prevent leakage of liquid. (Please read the precautions on the back before filling out this page) Order · Thread · Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 27 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)