TW495526B - Resin film for coating a decorative metal sheet and decorative metal sheet coated with the said resin film - Google Patents

Abstract

Disclosed is to provide a resin film for coating a decorative metal sheet excellent in emboss processability, molding processability, and water resistance durability property better than that of conventional polyvinyl chloride and a decorative metal sheet coated with the said resin film. Embossing onto at least one surface of the resin film of polybutylene terephthalate having intrinsic viscosity of 1.0-2.0, the said resin film for coating decorative metal sheet was laminated onto the metal sheet to make a decorative metal sheet.

Description

495526 \i/ IX CV 明 說 明 發 五495526 \ i / IX CV

領I 術 技 的I 屬 所 明 發I 關甲覆 有二被 係苯已 明對及 發聚獏 本之薄 紋脂 花樹 凸用 凹覆 成被 形板 上屬 面金。 表飾板 於裝屬 使的金 等成飾 工而裝 加SI之 花樹膜 壓酯薄 加二脂 施丁樹 域|由酸該The collar of the technique I belongs to the Institute of Hair I. The coat of arms is covered with two layers of benzene, which has been sterilized, and the hairpins of the hairpin. Table decoration plate for decoration is made of gold and other decoration tools, plus SI's flower tree film, pressed ester thin, double fat, satin tree domain | by acid

術 技 知 習I 塑 部之係裝凸於 烯樹來 熱家内性上使凹用加丙碳以 的、或水板以成使易聚氟久 越材板耐屬時形可容或之長 優建外要金同使加可烯氟係 等以等需於惟等施需乙含等 性，器等脂，工於由聚、膜 品板機室樹的加至，、脂薄 藥屬務浴性目花，膜脂樹伸 耐金事形塑要壓著薄樹系拉 、飾' 成熱主加行脂烯酯軸 性裝器體聚為施採樹乙酸雙 計的機一覆果，予性氣烯之 設成響於被效的即塑聚丙脂 觀而音用欲蝕目來熱以性樹 外上、使，防為以的，塑酯 ，板器泛形與感久工點熱聚 性屬機廣情賦級長加觀、或。 工金子被等板高係花的脂膜著 加於電亦此屬有上壓等樹薄用 形覆、，。金具面之廉烴的使 成被器首面之板表的價烯成常 將脂電為方材屬於目且聚而經 樹、件途原金紋種，妁等被 性具構用對飾花此工等脂即 加二期對 形苯長而 成對經由 、有劑， 性含塑体 工因可氣 加，，氮 花工劑化 壓加塑氣 、成可生 性形等發。 濟易醋會生 經容二時發 在使辛燒題 雖為酸燃問 脂而甲又的 樹然二，等 稀，笨出響 乙越對滲影 氣優或上劣 聚面酯面惡 而方二表有 然等丁於會 性酸會境 工甲間環Technical skills I The Department of Plastic Department is designed to be convex on the olefin tree to heat the house internally, so as to make the concave with propylene carbon, or the water board to make the easy-fluorinated long-lasting wood board tolerable. It is recommended that the externally-maintained metal be added to the carbene fluoride system, etc., etc., etc., which is required to be equal to, but not equal to, equal to the equivalent, and other lipids. In order to protect the eyes and eyes, the thin film of the resin is stretched and pressed against the thin tree system, and it is decorated to form the main axis of the fatty resin. As a result, the presupposition of aerobic ene is to respond to the effect of the plastic polypropylene guanyin and the use of ecstasy to heat the outside of the tree, to prevent, to prevent, plastic ester, plate shape and long-lasting The thermal convergence of the work site belongs to the long-awaited, long-term view, or. Industrial gold is covered by the lipid film of the high-level flowers, and it is also covered with a thin tree. The cheap hydrocarbons on the surface of the metal fittings make the valence of the sheet on the top surface of the quilt. The grease is often used as a square material and gathers the trees and pieces of the original gold pattern. The quilts are used for decorative flowers. This kind of fat is added with two-phase para-benzene to form a pair of via and agent. Sexual plastic body can be added by gas, and nitrogen flowering agent can be used to add plastic gas to form a viable form. Jiyi vinegar will produce menstrual capacity at two o'clock, but the problem of burning burns is sour and fat, but the second one is so rare, and so thin, it will make you sound better and better. And Fang Erbiao waited for Ding Yuhuan

4乃526 五、發明說明（2) 因此， 然而不添加 難，又，至 聚丙烯等聚 加工性方面 則加工部f 質化亦有添 添加可塑劑 又^勃* 徵之特性者 脂。近年來 之樹脂而成 加壓花加工 缺外觀設計 形，由於樹 的問題，適 的0 不添 可塑 於取 烯烴 良好 白化 加橡 之聚 塑性 ，惟 ，正 的雙 的情 性、 脂結 用作 加可塑 劑之樹 代聚氣 樹脂被 ’惟若 而有損 膠成分 氣乙烯 丙烯酸 係與可 予著眼 軸拉伸 形、較 及在南 晶化之 裝飾金 劑之聚氣 脂係硬質 乙烯樹脂 提出檢討 被覆於金 於外觀設 之方法被 樹脂同樣 _系樹脂 塑化聚氣 於以聚對 聚_薄膜 難獲得既 /皿多濕的 進行或加 屬板用被 乙烯樹 的，在 之樹脂 著，但 屬板上 計性。 考慮著 的軟質 、氟碳 乙烯樹 苯二甲 作為層 深又鮮 氣圍氣 水分解 覆樹脂 脂等雖 壓花加 ’雖然 是此等 並予成 因此， ’然而 樹脂。 樹脂係 脂同水 酸乙二 合材料 絶的凹 中經過 ’有被 薄膜方 予檢討著， 工上有困 有聚乙烯或 樹脂在壓花 形加工時， 為使樹脂軟 會形成與已 具有各自特 準的軟質樹 S旨為主成分 ’惟對已施 凸花紋且欠 長時期之情 膜會劣化等 面係有困難 M 的 決 解 欲明一發一 聚經薄 的水脂 用耐樹 習及該 與性覆 供工被 提加已 以形及 ，成膜 的、薄 目性脂 為工樹 題加用 問花覆 述壓被。 上之板題 決上屬課 解以金為 以等飾板 係同裝屬 月匕曰 ^11 發樹越飾 本稀優裝 乙性之 氣時膜4 乃 526 5. Description of the invention (2) Therefore, it is not difficult to add. In addition, in terms of processability such as polypropylene, the quality of the processing section is also increased. Plasticizers are also added. In recent years, the resin is made of pressed flower processing without the appearance design. Due to the problem of the tree, it is not suitable to add plasticity to take the good whitening of olefins and the plasticity of rubber. However, the positive duality and fatty texture are used as Plasticizer-based tree-generation gas-filled resins have been proposed, but only if the rubber component is damaged. Gas-acrylic acrylic resins and polyurethane-based hard vinyl resins that can be used to stretch the shape of the axis, compared with decorative gold agents crystallized in the south. Review the method of coating on the appearance of gold. Resin is the same. _Resin is used to plasticize the gas. It is difficult to obtain the film with polycondensation. The film is difficult to get both. The plate is wet or the plate is covered with vinyl. But it is on the board. Considering the soft, fluorocarbon ethylene tree xylylene as a layer deep and fresh gas surrounding water decomposition resin coating etc. Although embossed plus 'Although these are pre-formed, therefore,' but resin. Resin-based grease and ethylene glycol hydrotalcite material have been inspected by the film side, and there is polyethylene or resin in the process. In the embossing process, in order to make the resin soft and have its own characteristics, The quasi-soft tree S aims as the main component, but it is difficult to solve the problem that the embossed pattern and the long-term love film will be deteriorated. Sexual coverage for workers has been described, and film-forming, thin-meat fats have been used to explain the problems. The board problem is determined. The class is to solve the problem. Take gold as the equal decorative board. It is a combination of the moon and the moon. ^ 11 Hair tree and more decoration.

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495526 、發明說明（3) 的手段 灰1 η - 9發η明係聚對苯二甲酸丁二酯樹脂之固有黏度（I V值） I Λ之裝飾金屬板被覆用樹脂薄膜， h #經予|Ϊ苯二曱酸丁二醋樹脂薄膜之至少單面的表面 上你士卞壓花加工而成，又 μ #丨對苯二甲酸丁二酯樹脂薄膜之壓花加工面及相 對側之面上具有印刷層。 :ϋ發明亦係以上述的裝飾金屬板被覆用樹脂薄膜為 最上ϊΐ成為壓花加工面並予被覆而成的裝飾金屬板為發 明之對象。 態 形 施一 1 之 明發一 性固發薄飾 工之，脂裝 加圍形樹的 花範情此越 壓定之將優 及一膜，常 性有薄紋非 特具的花性 之由成凸計 膜用而凹設 薄使脂的觀 脂於樹艷外 樹，酯鮮得 對果二又可 ，結丁深， 等的酸既形 人討甲得情 明檢二可之 發心苯工板 之精對加屬 明經聚花金 發，的壓於。 本係度用覆板 關黏命被屬 之有現膜金 金觀工二 覆外加苯 被及花對 脂損壓聚 樹且之的 的化度越 得白程優 而分等性 上部同時 板工脂經 屬加樹水 金有烯耐 於致乙持 合不氣保 層亦聚可 膜工與下 薄加得狀 脂形可原 樹成，持 將以形保 ，予情在 果使的者 結即性再 板計， 屬設性 性容 特内 越之 優明 之發 脂本 樹明 酯說 二下 丁以 酸 曱495526, means of description of the invention (3) ash 1 η-9 hairs η inherent viscosity of polybutylene terephthalate resin (IV value) I Λ resin film for decorative metal plate coating, h # 经 予 | Benzene diacetate resin film is embossed on at least one side of the surface of the butyl succinate resin film, and the ## 丨 butyl phthalate resin film is embossed and the opposite side With printed layer. : The invention also uses the above-mentioned resin film for coating a decorative metal plate as the uppermost surface to be an embossed surface and coated with the decorative metal plate as the object of the invention. Appearance of the shape of the hair, a fixed hair thinner, fat decoration and the flower pattern of the surrounding tree will be better than a film, often with thin lines and non-specific floral nature. Convex film is thin and concave, so that the fat of the fat is observed in the tree. The ester is so fresh that it is good for the fruit, the fruit is deep, and the acid is good. The essence of the working board is inferior to Jia Mingjing's blond hair. This system uses a cover plate to close the sticky quilt. It has an existing film, gold and gold watchwork, plus a benzene cover and a flower to accumulate a tree of fat loss. The working fat belongs to the tree plus water, gold and olefin, which are resistant to causing the B to hold the gas. The protective layer is also polymerizable. The film can be formed into the original tree with a thin shape, and the shape will be preserved. The result is immediate reconsideration, which belongs to the sexual nature of Yentai's best-known hair fat tree esters.

第7頁 495526 五、發明說明 (使用的金屬板） 板、i ϋ本發明之裝飾金屬板所使用的金屬板為麵k ^ 合金板、銅板、鋼合金板等，廣泛而展紹 ，即可使用。至於鋼板，以厚度0.10~12右為金屬 =車^板為宜。其中以厚度0i0~i20mm之‘二乂二= j 士卜冷軋鋼板之中雖以低碳鋼或極通鋼冷軋鋼 =用’惟亦可使用添加有Nb、Tl等之非日=氧鋼板 iif鋼、含有3〜18重量％鉻之含鉻鋼板、有各L组；λ 夷=ϊ板等。此等冷軋鋼板之表面為經予施加表面處理的 =理鋼板亦可使用。至於表面處理，# “η ς被膜生成處理或塗布處理等，其中電鍍處理例如有鍍 ^錢锌-紹合金、鍵鋅_姑_翻、鍍錫、鍵錄、鑛錄_罐、 ，鎳-鈷、鍍鎳•錫、鍍鋁等，至於化學被膜生成處理， 你J如以鉻酸鹽處理、磷酸鹽處理等公知的處理即可。至於 ，布處理則因應各種塗料性質，以烘烤、塗布的方法進 行0 等 膜 薄 脂 樹 的 用 使 ， 之由又 用。〇 覆膜宜 被薄為 板脂膜 屬接薄 金酯伸 飾二拉 裝丁較 之酸膜 明甲薄 發二伸 本苯拉 於對未 至聚以 用， 採點 1度 宜1· Ρ 為之e 圍烷hd 範乙10 之氣bel ο四u 2./ 用 0-酚利 1於中 在解浴 以溶溫 度脂恆 黏樹之 有使P 固，30 之法在 酯常， 二用後 脂薄膜，可較宜 花加工性之觀 聚對苯二曱酸丁 固有黏度係採 之混合溶液内 計，測定此黏度 111Page 7 495526 V. Description of the invention (metal plate used) Plate, i ϋ The metal plate used for the decorative metal plate of the present invention is a surface k ^ alloy plate, copper plate, steel alloy plate, etc. use. As for the steel plate, the thickness of 0.10 ~ 12 is suitable for metal = car plate. Among them, the thickness of 0i0 ~ i20mm is 'two-two-two = j cold-rolled steel sheet with mild steel or ultra-thin steel cold-rolled steel = used', but non-Japanese = oxygen steel sheet with Nb, Tl, etc. can also be used iif steel, chromium-containing steel plates containing 3 to 18% by weight chromium, each having L groups; The surface of these cold-rolled steel sheets is a surface-treated steel sheet, which can also be used. As for the surface treatment, # "η ς film formation treatment or coating treatment, etc., among which electroplating treatments include zinc zinc-shao alloy, zinc zinc_gu_turn, tin plating, key recording, mineral recording cans, nickel- Cobalt, nickel plating, tin plating, aluminum plating, etc. As for the chemical film formation treatment, you can use well-known treatments such as chromate treatment, phosphate treatment, etc. As for cloth treatment, according to various coating properties, baking, The coating method is to use 0 thin films such as thin resin, and to use them again. 0 The film should be thinned as a fat film. It is a thin gold ester extension. The two pull-ups are thinner than the acid film. This benzyl is not used for polymerization, the point of extraction should be 1 degree, 1 · P, e, alkane, hd, fan, 10, gas, bel, ο, u, 2./0-phenolic 1 in the solution in the bath to dissolve The temperature of the fat and sticky tree can make the P solid, and the method of 30 is used in the ester, and the post-use fat film can be used to calculate the inherent viscosity of polybutylene terephthalate in the mixed solution. This viscosity 111

f/Vf 495526 ί 圍 1氣 滿的 。未溼 度在多 黏度溫 ⑸有黏恆 明固有於 說得固放 0^. - > 發求 置 h可間 期 長 並 上 板 屬 金 於 覆 被 ， 形 生月 之 未 際 之 中 氣 耐 的 夠 足 得 獲 ， 乾 際困之 之之膜性 G膜製膜 2.薄成製 過成變及 超製致性 若並，化 度出高劣 黏壓提水 有擠矩耐 固機轉由 面壓之為 方擠機圍 1由壓範 另係擠之 ，融使度 ^)熔且黏。 bi熱度有50 W加黏固1 水脂高的2-^7樹成佳1 (^將變較在 性，度。係 擊形過難點 情 酸# 一，、 甲00酸、 二-3甲脂 苯20二樹 對在苯酯 聚惟對二 的，聚乙 述制的酸 上限述甲 別上二 特於笨 酉 碳 聚 予，對 未又聚 並。合 ，宜摻 度為已 厚m用 之0//使 膜20可 薄0-亦 匕曰 7 勺 月以内 樹h脂 旨 封 S其# 二J酯 酯 體 聚 絡 子 % 脂 樹 種δι己等述使 ΐ聚或醇上可 他酸4由亦 之 ' ，其甲 將脂 脂U -乙 U 樹及、一|為，肖 合M苯醇者合 k薄間 _再複 诊 二 Η脂為Γ--。的 等 丁 b樹酸的膜成 ^酯甲，薄而 ί二二ί的上 已U苯或得以 夂酸對/製種 彡曱的及脂二 旨二分，樹合 ΙΜ苯部物之層 W對如聚成膜 纟聚例共而薄 等. 旨又，的物的 ΙΜ，物代聚成 )^脂聚取共而 er樹共所的脂 om的之等代樹 on上脂酸取種。 U以樹二所各用 層上面少 單加之至 可施Η之 亦與加層 ，於花刷 膜惟壓印 薄，的、 脂膜述層 樹薄後色 之脂之著。 用樹膜、可 覆酯薄層亦 被二脂著膜 板丁樹接薄 屬酸酯合脂 金曱二層樹 飾二丁由層 裝苯酸用多 之對甲採的 明聚二，得 發的苯上而 本述對面層 又上聚的之 用的反種 使述相一f / Vf 495526 ί around 1 full of gas. Unhumidity is viscous and stable at multi-viscosity temperature. It is inherently stable and holds 0 ^.-≫ Sending h can be set for a long period and the upper plate is covered with gold, which is resistant to the formation of the moon. Sufficient to obtain, the filmy G film in the dryness of the film 2. Thin film system has been changed and super-manufactured, the degree of chemical conversion is high and the pressure is high. From the surface pressure, it is the square extruder. 1 It is squeezed by the pressure system, and the melting degree is ^). bi heat has 50 W plus cement 1 2- ^ 7 tree with high fat and water 2 becomes good 1 (^ will become more natural, and the degree is too difficult to hit. Love acid # 一 ， 甲 00 酸 ， 二 -3 甲The aliphatic benzene 20 di-tree pair is phenyl ester polybutadiene, and the acid upper limit of polyethylene is more specific than that of stupid carbon. It is not polymerized. It is advisable to mix it with thick m. Use 0 // to make the film 20 thin 0-yield within 7 spoons within a month of the resin to seal its # di-J ester ester polyplexer% lipid species διH and other descriptions to make the polymer or alcohol The acid 4 is the same as that of the other, its A will be the lipid U-B U tree and, a | is, Xiao He M benzyl alcohol and He B thin room _ and then revisited the diazepam is Γ--. The acid film is formed into esters. The thin and diethyl ether is either benzene or acetic acid / seed bismuth, and the lipid bismuth, and the layer of the benzene component is made into a polymer film. The examples of the polymerization are common and thin, etc. The purpose of the product is IM, and the product is polymerized. ^ The lipopolysaccharide is used to collect the co-er and the homogeneous tree of the om tree is used to seed the fatty acid. U is based on the two layers of the tree two. Adding only one layer to the other can be applied and adding layers. The flower brush film is only imprinted thinly, and the lipid film is a thin layer of fat. The resin film and the thin layer of ester-covered film are also connected by a double-coated film. The thin-layered polyester is made of two kinds of esters. The two-layered tree is decorated with dibutyl. The opposite type of the benzene on the surface and the coating on the surface layer makes the description one

第9頁 五 發明說明（6) 相對於與金屬板間的接著強度祐古 、 對苯二甲酸丁二酯樹脂以外的低熔 =^要f者，設置聚 酯樹脂系或聚胺酯樹脂系等一般的桩，醋薄臈或例如聚 又至於著色層，亦可是用由以亦可。 二酯樹脂而成的薄膜，或將已添加顏J ” ？ f二甲酸： 其他聚酯樹脂薄膜之複合樹脂薄臈的者色薄膜層合炱 聚對苯二甲酸丁二醋樹脂薄膜传Μ 較易製得堅硬且平滑的表面，印刷J :生f ’f細結曰:’ 上述聚對苯二甲酸丁二醋樹脂薄的巧=力; 相對的面上，亦可使用設有藉由照相 的壓化加工之 版印刷（of fset)、網版印刷等方式之全faVUr了)、膠 部分著色印刷層之複合樹脂薄膜。 P刷層，多 壓花2 ΪΪ施加聚ί ί ?甲酸丁二酯樹脂薄膜之後述的 工之凹凸iiG产ίί，:性或耐磨性至不使壓花力口 ，均失的私度，叹置者表面保護層亦無妨。 (壓花加工方法） 方法至ίΐΛ,的/Λ苯二甲酸丁二醋樹脂薄膜之壓花加工 的模缚輥輪上並製膜^ 融脂j#r壓至已施加壓花加工 法，使薄膜吉垃ϊ ΐ Τ ί早面上有壓花花紋之薄膜的方 通過冷卻^於 =、卻的輥輪之間的方法。加熱薄膜使 進行壓花加i的=的方法、使通過旋轉篩網輥輪以真空力 間的熱針迤叙=f法、使薄膜通過穿孔機（per for a tor)之 程使用刻印輥輪並予壓縮的方法等任一方法， 495526 樹°c行 匕曰ο 隹 δ 1 二±以 丁點著 酸熔壓 甲脂予 二樹並 苯至輪 對熱輥 聚加刻 的已雕 述與用 上，使 將後時 ，之同 又上， 。板板 可屬屬 亦金金。 工於的可 加合圍亦 花層範工 j壓膜度加 $行薄溫花 h進脂之壓 7 明 說 等 方} 四G .S 作 蓆爯 見稱 XIV 無痕 擇砂 選、 可形 求0 〆g 需η • 1 之aw 品dr 製P 視e 孑e ，d 狀深 形拉 花深 壓、。 於形紋 至菱花 >|?| 、 形各 (層合方法） 對上述經施加壓花加工的聚對苯二甲酸丁 _沾& ^，採用公知的熱熔著法等層合於金屬板上。:^祕脂 $板力:熱至聚對笨二甲酸丁二醋樹脂薄膜 3 P :將 度，並將未施加聚對苯二曱酸丁二酯樹脂薄^ j上的 t =接於金属板上，以一對的層合輥輪捭$ $花加 >冗 >貝於水中並予急冷。 及持兩者，立 對與金屬板間之接著強度被高度要求 於聚，笨二曱酸丁二酯樹脂設置接著層，二如前述般 置^著層，介經接著層使金屬板及聚對1 ^金屬板上 脂薄膜層合亦有可能。 〜甲酸丁二酯 壓 定 判 之 否 與 好 良 性糙以 工粗， 加面面 花表表 壓之之之臈膜 膜、薄薄 薄脂脂 脂樹樹 樹的察 醋工觀 二加眼 丁花肉 酸壓以 甲加係 二施明 笨已發 對依本 聚係於之，。 明否斷 發與判U本好以 /1 良予 之度(5) Description of the invention on page 9 (6) For the bonding strength with metal plates, low melting point other than butyl terephthalate resin, etc., it is necessary to install polyester resin or polyurethane resin. The pile, thin vinegar, or for example, as for the coloring layer, can also be used. Film made of diester resin, or will have been added "? F dicarboxylic acid: other polyester resin film composite resin thin film color film laminated polybutylene terephthalate resin film M Easy to make a hard and smooth surface, printing J: raw f 'f thin knot said:' The above polybutylene terephthalate resin is thin and thin; the opposite side can also be used to provide photography (Composed of fset, screen printing, etc.), composite resin film with colored printing layer on the plastic part. P brush layer, multi-embossing 2 ΪΪApply poly ί? The embossing iiG of the ester resin film described later produces: properties or abrasion resistance so as not to make the embossing force, loss of privacy, and the surface protection layer of the sigher is not a problem. (Embossing processing method) Method to ίΐΛ, / Λ butyl phthalate resin film is embossed on a mold roller and embossed ^ Melt fat j # r is pressed until the embossing process has been applied to make the film 吉 吉 Τ Early face The method of embossing the thin film is performed by cooling the rollers between =, but the film is heated. The method of embossing plus i, making the hot-needle between vacuum force through the rotating screen roller and the f method, and passing the film through a perforator using a marking roller and compressing it. Method, and any other method, 495526 tree ° c line ο 1δ 1 two ± dipped in acid to melt the methyl ester to the two tree acene to the wheel-to-roller roller engraving has been carved and used to make Later, the same as above. The board can belong to Yijinjin. The workable can be added to the flower layer, the fan, the film thickness, plus the $ line, the temperature, the pressure of the fat, and the pressure of the fat. G.S is called XIV. It is said that XIV has no sand selection. It can be shaped to find 0 〆g. It needs η • 1. The aw product dr is made by P as e 孑 e. The d-shaped deep-drawn flower is deep pressed. Linghua > |? |, Shape (layering method) The polybutylene terephthalate_stained with the embossing process described above is laminated on a metal plate by a known thermal fusion method or the like. : ^ Secret fat $ plate force: heat to the polybutylene terephthalate resin film 3 P: will be the degree, and the polybutylene terephthalate resin film is not applied t = on the metal On the board Laminated rollers 捭 $ 花 加 > Redundant > Pay in water and quench. Hold the two, the bonding strength between the vertical pair and the metal plate is highly required for poly, butadiene diacetate resin settings The next layer, the second layer is placed as described above, it is also possible to laminate the metal plate and the poly film on the metal plate via the next layer. ~ Butyl formate pressure determination is good or not. The work is thick, the surface pressure of the surface and the pressure of the surface is the pressure of the sacral membrane, and the thin and thin fat tree tree. I gather here, according to this. Make it clear whether to send it out and judge it to be / 1 good

頁 11 IX 第 495526 五、發明說明（8) mi準，評估麼花加工性之良好與否。 〇·良好 △•稍微不良，X :不良 且’上述的评估基準，係採用東京 SURFC〇M表面粗縫度計，以JIS B0 6 0 1為準粗糙度 (A 面粗趟度為4#ra以上的情形作為屢 :^ΐίΐίίί二以平均表面粗糙度與…之聚氣乙 ί:3 m ί ^表面相比稍微低劣’但對具有實用上 貝 (作xi稍微不良(△)’而未能進行壓花加工者 (加工性之評估） 將於經予賦與 之雕刻輥輪，令以 一定長度及寬度之 膜’頂接至已予加 的溫度之具有與聚 寬度之厚度0. 5〇mm 予壓著作為試片。 機，以衝擊部之外 條件试驗由此而得 般’以肉眼觀察並 〇：樹脂薄膜 平均表面粗糙度Ra=ll 凹凸的％紋 固定速度通過並已施加壓花加工的具有 聚田對苯二甲酸丁二醋樹脂薄 :苯二甲酸丁二酿樹脂薄膜； 鍍鋅鋼板上，以一對的輥輪夾持二者並 定的杜邦衝久驗 徑0· 5央吋，重量1Kg，落 3片兮衝擊加工性。評估；：C: 分成二階段予以評估。 上未發現有裂縫 五、發明說明（9) X ··樹脂薄膜令，μ亡航# 於上述評分，〇J文ί f:的裂縫 就ίο片試片予以實施及△並無使用上的問題。且此試驗係 (耐水劣化性之評估） 推測在使本發明$ #斜Y _ =壓花加工的狀態及醋=薄膜在已 的情形（例如用作一體& 的狀態下，經長期間置放 之樹脂薄膜之耐水劣化性。a間已與水接觸的情形 一定長声疋速度通過並已施加壓花加工的ιί 膜聚對苯二甲酸丁二5旨樹脂、薄 的溫】ΐίίΐΐϊ”苯二甲酸丁二醋樹脂之溶點以上 予壓著作ί% μ鍍鋅鋼板上，以一對的輥輪夾持二者並 之大小減片。將如此而得的試片裁切成60mm x 6〇mm 後，才6 /又/貝於溫度保持在3 8 ± 2 °C之離子交換水中1個月 進沾f ΐ溫乾燥’採用杜邦衝擊試驗機’以JIS K54〇〇為 5 〇、/、/ (衝擊部分外徑0 · 5英忖，重量1 K g，落下高度 施加衝擊，以肉眼觀察經施加衝擊後的樹脂薄膜， 以下述的4五個階段予以評估。 5 :，脂薄膜上未發現有裂縫 4 :樹脂薄膜之一部分上發現有微細的裂縫Page 11 IX Article 495526 V. Description of the invention (8) Mi is accurate to evaluate whether Ma Hua is good in processability. 〇Good △ • Slightly defective, X: Defective and the above-mentioned evaluation criteria are based on the Tokyo Surco surface roughness meter and JIS B0 6 0 1 as the rough roughness (the roughness of the A surface is 4 # ra The above situation is often repeated: ^ ΐίΐίίί2 The average surface roughness is slightly lower than that of the qi: 3m ί ^ The surface is slightly inferior to the surface, but it is not good for practical applications The embossing processor (evaluation of processability) will be endowed with engraving rollers, so that a film of a certain length and width is 'topped' to the added temperature and has a thickness of 0.5 mm and a poly width. mm pre-pressed work is a test piece. It is obtained by testing under conditions other than the impact part. 'Observation with the naked eye: 0: The average surface roughness of the resin film Ra = ll. Flower processing with polybutylene terephthalate resin thin film: butyl phthalate resin film; on galvanized steel, a pair of rollers are used to clamp the two and set the DuPont punching test diameter 0 · 5 inches, weight 1Kg, drop 3 pieces, impact processability. Evaluation; C: divided into two stages No cracks were found on it. V. Description of the invention (9) X ·· Resin film order, μμ 航 # Based on the above scores, the cracks of f: were implemented on the test piece and △ was not used. And this test is (evaluation of resistance to water deterioration). It is estimated that the present invention # # oblique Y _ = embossed state and vinegar = film in the existing situation (such as the state of integrated & The water resistance of the resin film that has been placed for a long period of time. In the case where it has been in contact with water, it must pass a long time and the embossing process is applied. The film polybutylene terephthalate 5 thin resin, thin temperature 】 Ϊ́ίΐΐϊ ”The butyl phthalate resin has a melting point above the pre-pressed work ％% μ galvanized steel sheet, and a pair of rollers is used to clamp the two and reduce the size. The test piece thus obtained is cut After being 60mm x 60mm, the temperature was maintained at 3 8 ± 2 ° C in ion-exchanged water for 1 month. The temperature was then dried and dried 'using a DuPont impact tester' with JIS K54〇〇 for 5 〇 、 / 、 / (The outer diameter of the impact part is 0.5 inches, the weight is 1 Kg, and the impact is applied when the height is dropped. The resin film after impact was visually observed and evaluated in the following four or five stages. 5: No cracks were found in the fat film 4: Fine cracks were found in a part of the resin film

第13頁 495526 明 說 明 發 五 縫縫 裂裂 的 細大 微較 有有 現現 發發縫 上上裂 體體的 全全著 P頁 it口咅 _ 工工有 加加上4 花花體及 壓壓全 之之上 膜臈膜 薄薄薄 匕曰匕曰匕曰 月月月 樹樹樹 ，施 分實 評以 的予 述片 上試 於片 ο I I 對 題 問 無 並 上 用 使 在 係 驗 試 此 且Page 13 495526 It shows that the size of the cracks in the five seams is larger than that in the upper part of the body with the hair cracks on the current hair. On top of the whole, the film is thin, the film is thin, the knife is thin, the moon, the moon, the tree and the tree, and the prescriptive commentary is given on the film. The test is on the film. II The question is not combined and used in the department test. This and

以下以實施例進一步詳細說明本發 採用機擠壓表1所示的具有固有黏度之聚 此Ϊ J 一 2樹脂並製作0·10mm膜後之未拉伸薄膜。於制― ί ίϊτ脂Λ膜r之際，加熱熔融樹脂薄膜，將已加 2::公對部分薄膜而f，於與已施加壓花加工i: 接t f 上，利用照相凹版印刷進行全面著色印刷。又， 擠壓機’將具有表1所示的固有黏度之聚對苯二 製^ S旨^脂與上述的聚對苯二甲酸丁二酯樹脂同法製膜， 膜出單面上已施加壓花加工的0.10mm膜後之未拉伸薄 虹°利用肉眼觀察由此而得的樹脂薄膜之壓花加工性之 好與否，予評估。評估結果示於表2。 八其次以下述要領將上述已施加壓花加工的樹脂薄膜層 5於金屬板上。 、 於厚度0· 50mm之低碳鋁脫氧冷軋鋼板上施加〇· 0〇2min &之鍍鋅。加熱此鍍鋅鋼板至2 4 0 °C，將聚對笨二曱酸In the following, the present invention is further explained in detail by using an example. The un-stretched film obtained by extruding the polymer having intrinsic viscosity shown in Table 1 using a machine as shown in Table 1 and producing a 0 · 10 mm film is described below. In the production of ί ίϊτ lipid Λ film r, heat the molten resin film, add 2 :: male to part of the film and f, and apply embossing to i: then tf, and use photogravure printing for full coloring. print. In addition, the extruder was used to produce a film made of poly (p-terephthalate) having the inherent viscosity shown in Table 1 in the same manner as the above-mentioned polybutylene terephthalate resin, and pressure was applied to one side of the film. The unstretched thin rainbow after the flower-processed 0.10 mm film was observed with the naked eye to see if the embossing processability of the resulting resin film was good or not, and evaluated. The evaluation results are shown in Table 2. Eighth, the above-mentioned embossed resin film layer 5 was applied to a metal plate in the following manner. 2. Apply a zinc plating of 0.002min & to a low-carbon aluminum deoxidized cold-rolled steel sheet having a thickness of 0.50mm. Heating this galvanized steel to 240 ° C

第14頁 495526 五、發明說明（11) 丁二酯樹脂 以一對層合 予急冷。對 脂系之接著 已加熱接著 合。如此而 鋼板。又加 二曱酸乙二 面上，以一 於水中並予 鍍鋅鋼板。 對依上 之鍍鋅鋼板 用杜邦衝擊 膜之加工性 又，已 6 0mm大小之 浸潰1個月相 JIS K5400 J 明之實施例 果示於表2。 薄膜之未施加壓花加工的面頂接於其單面上， ^輪夾持兩者並予壓著後，立即浸^於水中並 2 ΐ已施加印刷的薄膜之情形，將聚胺醋樹 m 3施力:印刷的面上並予乾燥後頂接至 ^之塗布面之鍍鋅鋼板上，與上 甲酸丁二酷樹脂「專膜：鑛： 鋅鋼板至28〇°c，將聚對苯 S曰樹脂薄膜之未施加壓花加工的 對的層合輥輪夾持兩者並予壓 ς 急冷。如此而得被覆有聚對C酸； 述而得的被覆有聚對苯二甲醅 及被覆有聚對笨二甲酸乙二I:t樹脂薄膜 試驗機以JIS K540 0為準的之鍍鋅鋼板，採 。評估結果示於表2。 、 11平估樹脂薄 被覆各自的樹脂薄膜之鍍鋅Page 14 495526 V. Description of the invention (11) The succinate resin is quenched in a pair of layers. For fat-based bonding, it has been heated and bonded. So the steel plate. Add diethylene glycol diacetate to one in water and pre-galvanize the steel sheet. The workability of the DuPont impact film for the above galvanized steel sheet is shown in Table 2 as shown in Table 2 below. The non-embossed side of the film is abutted on one side of the film. After the two are clamped and pressed, they are immersed in water immediately and the printed film is applied. M 3 force: printed surface and dried on top of the galvanized steel plate coated with ^, with butyl formic acid resin "special film: ore: zinc steel plate to 28 ° C, Benzene refers to the pair of lamination rollers of the resin film without embossing, which are clamped by both and quenched. In this way, it is coated with polypara-C acid; And galvanized steel sheet coated with polyethylene terephthalate I: t resin film testing machine based on JIS K540 0. The evaluation results are shown in Table 2. and 11 Galvanized

試片，於溫度保持在3 8 ± 2。反裁切出60mm X I丄在室溫乾燥後，採用杜邦 =父換水中 b準的條件，評估樹脂薄膜擎试驗機，以 及比較例之樹脂薄膜表示於/ 5性。將本發 、卜表1，其評估結 495526 五、發明說明（12) 表1 試料編號 樹脂薄膜 薄膜種類 IV值 印刷層 1比較例 ΡΒΊΤ 0.8 無 2實施例 PBT* 1.0 無 3實施例 PBT* 1.2 無 4實施例 PBT* 1.4 有 5實施例 ΡΒΊΤ 2.0 無 6比較例 PET# 0.6 無 7比較例 PET# 1.1 無 表2 5式料編號 特性評估的結果 製膜性 壓花加工性 加工性 财水劣化性 綜合評估 1比較例 〇 Δ X 1 X 2實施例 〇 〇 Δ 4 〇 3實施例 〇 〇 〇 5 〇 4實施例 〇 〇 〇 5 〇 5實施例 〇 〇 〇 5 〇 6比較例 〇 Δ 〇 2 X 7比較例 〇 Δ Δ 3 Δ 註：ΡΒΊΤ :聚對苯二曱酸丁二酯 PET# :聚對苯二甲酸乙二酯 im 第16頁 反 '發明說明（13) 上的ΐ = ΐ果雖然示於表2，然而以被覆由固有黏度1 · 〇以 已# ^ ί本一甲酸丁二酯樹脂而成的薄膜之鍍鋅鋼板，與 相比，Ϊ聚Ϊ笨二甲酸乙二酯樹脂而成的薄膜之鍍鋅鋼^ 上沾二在壓花性、加工性及耐水劣化性方面顯示出同等以 層ΐ H Ϊ tt覆有已印刷的薄膜之鍍鋅鋼板’除印刷 =吳麗的色凋外，又可得已施加壓花加工的透明薄膜 厚度而引起的立體感，在外觀設計上 、<The test piece was kept at 3 8 ± 2 at the temperature. After cutting out 60mm X I 丄 at room temperature, the resin film tester was evaluated under the conditions of DuPont = father changing water b, and the resin film of the comparative example was shown as / 5. This article and Table 1 are evaluated 495526. V. Description of the invention (12) Table 1 Sample No. Resin film Type IV Value Printed layer 1 Comparative example PBYT 0.8 None 2 Examples PBT * 1.0 None 3 Examples PBT * 1.2 None 4 examples PBT * 1.4 Yes 5 examples PBQT 2.0 none 6 comparative examples PET # 0.6 none 7 comparative examples PET # 1.1 none Table 2 5 results of evaluation of formula number characteristics film forming embossing processability processability property deterioration Comprehensive Evaluation 1 Comparative Example ΔΔ X 1 X 2 Example 〇ΔΔ 〇3 Example 005005 04 Example 005005 005 Example 005005 〇6 Comparative Example 〇Δ 〇2 X 7 Comparative Example 〇Δ Δ 3 Δ Note: PBYT: Polybutylene terephthalate PET #: Polyethylene terephthalate im 第 on the 16th description of the invention (13) = fruit Although shown in Table 2, the galvanized steel sheet coated with a thin film made of a butyric acid resin with an inherent viscosity of 1 · 〇〇 已 has been compared with that of a polyethylene resin The thin film made of galvanized steel ^ has embossability, processability and poor water resistance. In terms of properties, it shows that the galvanized steel sheet covered with the printed film is equivalent to the layer ΐ H Ϊ tt. In addition to printing = Wu Li's color, the three-dimensional effect caused by the thickness of the transparent film that has been embossed can be obtained. In terms of design, <

效 功 之 明發I 酯 二 丁 酸 甲 二 苯 對 聚 係 明 發 本 工 加 花 壓 予 經 面 表 之 面 單 少 至 度 黏 有 固 之 脂 樹 板薄，花對及水 屬脂化壓聚性耐 金樹白之的工要 飾酯分度越加需 裝二部程優之等 之丁工等性膜室 層酸加相時薄浴 刷甲有脂經脂形 印二致樹水樹成 有笨不烯耐在體 具對亦乙持，一 上聚工氣保性於 面該加聚可特用 之覆形與下越適 側被成得狀優可 對已使可原之， 相及即，持脂越 面，，性保樹優 工膜板計在酯面 為σ薄屬設者二方。 ν)“脂金觀再丁性等 (IU樹飾外，酸化材 W用裝及性甲劣建 U覆之損工二水之 被膜而加苯耐性 又Efficacy of Mingfa I ester dimethyl dibutyrate p-polybenzyl series Mingfa. This work adds flower pressure to the surface of the menstrual surface. The surface of the tree is thin and sticky. Polyester-resistant gold-tree-white resins need to be decorated with more and more ester divisions. Two Cheng Chengzhi grades of Dinggong isotropic membranes are added during acid addition. Thin bath brushes are made of fat. The stupid is resistant to the body and the body. One of the polymers can maintain the gas in the face. The special shape of the addition and polymerization can be formed on the appropriate side and the shape of the lower side can be made intolerable. , The more fat-holding surface, the better the properties of the tree membrane in the ester surface is σ thin and belongs to the two parties. ν) "Zi Jinguan and other properties (except for IU tree decoration, acidified materials, W materials, and inferior nails, U cover, damaged water and two water coatings, and benzene resistance)

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Claims (1)

495526 六 教明申請第88 1 20564號申請專利範圍修k本（tDri 1. (A ) 1 · 一種裝飾金屬板被覆用樹脂薄膜，其中所用的聚斜 苯二甲酸丁二酯樹脂之固有黏度（IV值）為丨· 〇一2· 〇。 2 ·如申請專利範圍第1 酉旨樹脂薄膜之至少單面的 膜，其中前述聚對苯二甲酸丁衣部金屬板被覆用樹脂薄 表面上係經予壓花加工而成。 3·如申請專利範圍第2項 膜，其中前述聚對苯二甲萨衣飾至屬板被覆用樹脂薄 及相對側之面上具有印刷層。-酯樹脂薄膜之壓花加工面 4·如申請專利範圍第1項至 板被覆用樹脂薄膜，係於前述m—項之裝飾金屬 膜之最上表面使成壓花加工面並:甲酸丁二酯樹脂薄 金屬板。 並予被覆金屬板而形成裝飾 91005-901108.ptd 第19頁495526 Six teaching application No. 88 1 20564 Application patent revision (tDri 1. (A) 1 · A resin film for decorative metal plate coating, in which the intrinsic viscosity of polybutylene terephthalate resin ( (IV value) is 丨 · 〇 2 · 〇. 2 · As in the scope of patent application No. 1 of the purpose of the resin film on at least one side of the film, wherein the aforementioned polybutylene terephthalate coating metal sheet coating resin thin surface It is made by embossing. 3. If the film in the second item of the patent application scope, wherein the aforementioned poly-terephthalate is decorated with a resin layer for covering the metal plate and a printing layer is provided on the opposite side. -Ester resin film The embossed surface 4 · If the patent application scope item 1 to the resin film for panel coating is the uppermost surface of the decorative metal film of the aforementioned item m-to make an embossed surface and a thin metal plate of butadiene formate resin And covered with metal sheet to form decoration 91005-901108.ptd page 19