TW482694B

TW482694B - Product having low temperature curing type highly active oxide photocatalyst film

Info

Publication number: TW482694B
Application number: TW87106457A
Authority: TW
Inventors: Takao Kawaguchi; Takao Ishikawa; Tomoji Oishi; Noriko Shimazaki; Yuka Hirota
Original assignee: Hitachi Ltd
Priority date: 1997-05-20
Filing date: 1998-04-27
Publication date: 2002-04-11
Also published as: CN1201704A; KR19980087179A; KR100406452B1; JP3510082B2; JPH10314597A; CN1134279C; KR100375115B1

Abstract

To manufacture a product of antibacterial effect, antifouling effect and deodorizing effect for example on the surface of a plastic or a coating material by forming an oxide photocatalyst film on the surface of a part in an air flow path and adding specified ions in the oxide photocatalyst film. Ions of elements (Na, Li, K, Mg, Co, Sr, Zn, etc.) of electronegativity of less than 1.6, the ion radius of 0.12 nm or less and oxide particles mainly comprising metal elements with an electron affinity of more than 1.2 (tin oxide of antimony) are added in an oxide photocatalyst film in which TiO2 particles as an oxide photocatalyst are dispersed.

Description

482694 A7 B7 五、發明說明（1 ) 〔發明所屬技術範疇〕 (請先閱讀背面之注意事項再填寫本頁) 本發明係有關於具備氧化物光觸媒薄膜之物品，係有關於耐熱性低的有機高分子材料，特別是泛用熱塑性塑膠製部件的表面上形成有薄層狀氧化物光觸媒薄膜之物品，復有關不得用於屋外太陽光等強紫外線惟適用於紫外線燈與室內的物品全體或一部份表面上具備有氧化物光觸媒薄膜之物品。譬如有關於利用空氣洗淨機、換氣扇、扇風機、掃除機、衣物乾燥機、餐具乾燥機、餐具洗滌機、廚房渣滓處理機、暖氣機、加濕機、除濕機、空氣調和機、加熱烹調器具、電磁烹調器具、吹風機、除臭機、燻籠等電動送風機，以產生氣流的裝置。其係有關於藉生活環境中的光，以光觸媒功能，將此等電氣製品類表面上所附著浮遊於空氣中的種種污染成份與微生物分解，俾獲得防污、除臭、防菌、防霉、浸潤性增進等表面特性的技術及其物品。經濟部智慧財產笱員工消費合汴让印絮〔習知技術〕近年來，大家的目光均集中在利用以T i〇2光觸媒來產生有機物分解作用且經發現具有防污、除臭、抗菌效果的材料。此係「新陶瓷」（1 9 9 6 ) N 〇 · 2， 5 5所載利用半導體光觸媒的氧化還元反應而在瓷磚上形成 T i〇2薄膜者。一方面，就成膜而言，有氧化物薄膜噴濺在基板上的 -H·- 本紙張又度適用中國國家標準（CNSM4規格（210 X 297公釐） 482694 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（2 ) 物理方法及溶膠凝膠法等塗覆法的化學方法。前者係使用真空裝置等而可低溫成膜者。後者係以自旋塗覆、噴塗等簡單裝置塗覆於基板上，通常以數百。c溫度處理而可藉此獲得膜者。作爲抗菌防臭用材料的T i 0 2據報告，銳鈦礦型結晶有效，在功能上經發現結晶化有效（p T C ) W〇專利第94/11092號、（PTC)W〇95/ 15816號）。且據報告，Ti〇2添加v.Fe等可高性能化（W. Choi，A. Termin，M.R. Hoffmann，J.物理化學 98， 13669-13679 (1994))。就使用上述材質與手法而將氧化物光觸媒薄膜應用於各種裝置的事例而言，周知者有以下發明。就目的在於去除室內空氣中塵埃類與惡臭物質的裝置，亦即空氣淸淨機而曰，有知*開平8 — 2 6 6 8 4 1號公報、特開平8 - 2 6 6 6 0 5號公報及特開平 8—309148號公報所載，設有內含以Ti〇2爲主要成份用來作爲光觸媒的薄膜而以紫外線燈等裝置照射短波光於其上的機構的技術。復就扇風機的應用例而言，已知有特開平 7 — 3038 1 9號公報所載，在600 °C下，於金屬零件表面上燒成以T i 0 2爲主要成份的光觸媒薄膜的技術。且特開平9 一 3 8 1 8 9號用應扇風機之應用例亦周知係附設有發光二極體來照射紫外線的機構。就換氣扇適用例而言，周知者有特開平 5 - 1 5 7 3 0 5號公報所載倂用紫外線燈之構成。 (請先閱讀背面之注意事項再填寫本頁)482694 A7 B7 V. Description of the invention (1) [Technical scope of the invention] (Please read the precautions on the back before filling out this page) The present invention relates to articles with oxide photocatalyst films and organic compounds with low heat resistance Polymer materials, especially those with a thin layer of oxide photocatalyst film formed on the surface of parts made of general thermoplastic plastic, are not suitable for strong ultraviolet rays such as outdoor sunlight, but are suitable for ultraviolet lamps and indoor items or all Items with oxide photocatalyst film on part of the surface. For example, the use of air washer, ventilator, fan, sweeper, clothes dryer, dish dryer, dishwasher, kitchen waste processor, heater, humidifier, dehumidifier, air conditioner, heating cooking appliances , Electromagnetic cooking appliances, hair dryers, deodorizers, smoke cages and other electric blowers to generate air flow. It is related to the use of light in the living environment and the photocatalytic function to decompose all kinds of pollution components floating on the surface of these electrical products and airborne microorganisms to obtain anti-fouling, deodorization, anti-bacteria and anti-mold Technology for improving surface properties such as wettability and its articles. Ministry of Economic Affairs, Intellectual Property, Employees' Consumption, Printing, and Printing [Knowledge Technology] In recent years, everyone's attention has focused on the use of Tio2 photocatalyst to produce organic matter decomposition and has been found to have antifouling, deodorizing and antibacterial effects. s material. This series of "new ceramics" (199.6) No. 2, 55, which uses the redox reaction of the semiconductor photocatalyst to form a Tio2 film on the tile. On the one hand, in terms of film formation, -H ·-with an oxide film spattered on the substrate is also applicable to the Chinese national standard (CNSM4 specification (210 X 297 mm) 482694 A7 B7 staff of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives 5. Description of the invention (2) Physical method and chemical method of coating method such as sol-gel method. The former is a film that can be formed at a low temperature by using a vacuum device, etc. The latter is simple by spin coating, spray coating, etc. The device is coated on a substrate and is usually treated at a temperature of several hundred degrees C to obtain a film. T i 0 2 as an antibacterial and deodorant material has been reported to be effective in anatase type crystals and has been functionally found to crystallize Effective (p TC) WO Patent No. 94/11092, (PTC) WO95 / 15816). Furthermore, it has been reported that Ti02 can be added with v. Fe and the like for high performance (W. Choi, A. Termin, M.R. Hoffmann, J. Physico-Chem. 98, 13669-13679 (1994)). With regard to the case where the oxide photocatalyst film is applied to various devices using the above-mentioned materials and methods, the following inventions are well known. For the purpose of removing dust and odorous substances from indoor air, that is, air purifiers, it is known that * Kaihei 8 — 2 6 6 8 4 No. 1 and Japanese Patent Laid-Open No. 8-2 6 6 6 0 5 The technology disclosed in the Gazette and Japanese Patent Application Laid-Open No. 8-309148 includes a mechanism containing a thin film containing Ti02 as a main component for use as a photocatalyst, and irradiating short-wave light onto a device such as an ultraviolet lamp. As an example of the application of a fan, there is known a technique for firing a photocatalyst film mainly composed of T i 0 2 on the surface of a metal part at 600 ° C as disclosed in JP-A-7-303819. . In addition, an application example of the application fan of JP-A-Hei 9 3 8 1 8 9 is also known as a mechanism provided with a light emitting diode to irradiate ultraviolet rays. As for an application example of a ventilating fan, a well-known person has a constitution of a UV lamp for use in a gazette as disclosed in JP-A No. 5-1 5 7 3 0 5. (Please read the notes on the back before filling this page)

ϋ ϋ ι ϋ l I ·ϋ^δ,ν a n ϋ l ϋ ϋ ·ϋ I ★ 本紙張义度適用中國國家標準（CNS)A4規格（210 x 297公釐） -5- 482694 A7 B7_ 五、發明說明（3 ) 復就設置於掃除機與廚房渣滓處理機的通氣路徑中用 (請先閱讀背面之注意事項再填寫本頁) 來作爲除臭薄膜的應用例而言，曾提議者有特開平 7 — 1 0 8 1 7 5號公報所揭露使以T i〇2爲主要成份的光觸媒成爲粉末狀以塑膠纖維片包入熱封的技術。〔發明所欲解決之課題〕使用習知技術由於形成氧化物薄膜於低耐熱性基材如塑膠製部件上，故有不充份之處。在熔膠凝膠法成膜方面，固然有上述文獻所載作爲抗菌、防臭材料的抗菌瓷磚，惟爲了使氧化鈦結晶化，故須作數百°C，至少3 0 0 °C以上的熱處理。故在塑膠類，特別是廣泛應用的熱塑性塑膠類的低耐熱性基材上成膜有困難。且在屋內光度低環境下，有T i 〇2本身的有機物分解等分觸速度不充份而需特別配設其他光源的問題點。經濟部智达財查笱員工消費合作fi--n「s 前述本發明對象的裝置類固然係用在一般家庭與辦公室等屋內主要爲家庭電化製品者，惟此等製品主要使用有機高分子材料（塑膠）。使用極多玻璃部件的電視與個人電腦類的監視器之外一般家庭電化製品類零件的素材中塑膠的重量比約40〜50%,剩下的幾乎是金屬類。在容積比上，塑膠所佔接近9 0 %。塑膠因容易輕量化，式樣性極高，且價格低廉等理由而廣泛應用，其中尤其是熱塑性塑膠，由於成形作業的量產性極高，故使用極多。應用最廣的泛用塑膠構造材料固然舉例來說有聚丙烯 (PP)、丙烯酸丁苯共聚物（ABS)、苯乙烯丙烯酸 -6 - 衣紙張又度適用中國國家標準（CNS)A4規格（210 X 297公釐）經濟部智慧財產局員工消費合作社印製 482694 A7 ---BZ___ 五、發明說明（4 ) 共聚物（AS)、聚苯乙烯（PS)、尼龍（PA)、聚碳酸酯（PC)、氯乙烯（PVC)、異丁烯（PMMA )、聚乙烯（PE)、聚縮醛（P〇M)、聚乙烯對酞（ PET)、聚丁烯對酞（PBT)等，惟各個材料均不耐 3 0 0 t以上環境下的變形。譬如，ASTM D— 6 4 8 (18.6kg/crri )的熱變形溫度接近2 5 0 °C。固有將玻璃纖維等練入的聚苯撐亞硫酸、聚苯撐氧、聚醚亞氨等特殊高耐熱性樹脂，惟由於價格極高，故無法大量用於上述用途。一般而言，耐熱特性高的素材價格極高，特別是大多用於外裝部件者爲PE、 PS、 ABS、 PP、 PVC，此等材料平均佔塑膠零件類的7 5%以上。其中即使耐熱性極高的A B S其前述A S T Μ熱變形溫度在1 2 0 °C以下，在3 0 0 °C下，完全熔解成液狀，並進行氧化分解。且即使在以金屬類無機材料表面上塗覆有塗料的表面爲對象情形下，材料亦受限於具有超過3 0 0 t的耐熱性。通常，塗料使用熱硬化性高的樹脂。舉例來說有聚酯、丙稀、蜜胺、環氧、尿烷樹脂等代表例，一般在1 5 0 °C 溫度下烘烤。此等塗料暴露在超過3 〇〇 °C的環境下，常會發生光澤消失以及出現剝落等問題。如此等資料顯示，在廣泛應用的材料上，習知技術藉熔膠凝膠法來成膜具有極大的耐熱特性上的問題。另一方面，未超過3 0 0°C的溫度範圍內形成薄膜的噴濺、C V D、真空蒸鍍法等所謂物理方法必須設有真空 (請先閱讀背面之注意事項再填寫本頁) F· · 1111111 訂·！一 — I!· 參ϋ ι ι ϋ l I · ϋ ^ δ, ν an ϋ l ϋ ϋ · ϋ I Note (3) For the application example of deodorizing film, please use it in the ventilation path installed in the sweeper and kitchen dregs processor (please read the precautions on the back before filling this page). The technique disclosed in 7 — 1 0 8 1 7 5 is to make the photocatalyst with Ti 102 as a main component into a powder form and heat-seal it with a plastic fiber sheet. [Problems to be Solved by the Invention] Since the oxide film is formed on a substrate having a low heat resistance such as a plastic member using a conventional technique, it is inadequate. In terms of film formation by the melt-gel method, although there are antibacterial ceramic tiles as antibacterial and deodorant materials described in the above literature, in order to crystallize titanium oxide, heat treatment must be performed at several hundred ° C and at least 300 ° C. . Therefore, it is difficult to form a film on a low heat-resistant substrate of plastics, especially widely used thermoplastics. And in the low-light environment of the room, there is a problem that the decomposition speed of organic matter such as T i 〇2 is not sufficient, and other light sources need to be specially equipped. The Ministry of Economic Affairs Zhida Finance checks the employee's consumer cooperation fi--n "s The aforementioned devices of the present invention are of course used in households and offices and other homes mainly for household electrical products, but these products mainly use organic polymers Material (plastic). The weight ratio of plastic is about 40 ~ 50% in the materials of general household electrical products other than televisions and personal computer monitors using a lot of glass parts. The rest is almost metal. In volume In comparison, plastic accounts for nearly 90%. Plastics are widely used for reasons such as easy weight reduction, high style, and low price. Among them, thermoplastic plastics, because of the high mass productivity of molding operations, are extremely useful. The most widely used plastic construction materials include polypropylene (PP), acrylic styrene butadiene copolymer (ABS), and styrene acrylic-6. The paper is also suitable for China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 482694 A7 --- BZ___ 5. Description of the invention (4) Copolymer (AS), polystyrene (PS), nylon (PA), polycarbon Acid ester (PC), vinyl chloride (PVC), isobutylene (PMMA), polyethylene (PE), polyacetal (POM), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), etc., However, each material is not resistant to deformation under the environment of more than 300 t. For example, the heat deformation temperature of ASTM D-6 48 (18.6kg / crri) is close to 250 ° C. The inherently polymerized glass fiber Special high heat-resistant resins such as phenylene sulfite, polyphenylene oxide, polyetherimide, etc. However, due to their extremely high price, they cannot be used in a large amount for the above purposes. Generally speaking, materials with high heat resistance properties are extremely expensive, especially Most of the external components are PE, PS, ABS, PP, PVC. These materials account for more than 75% of plastic parts on average. Among them, even the extremely heat-resistant ABS has the aforementioned AST M thermal deformation temperature of 1 2 Below 0 ° C, at 300 ° C, it completely melts into a liquid state and undergoes oxidative decomposition. Even in the case where the surface of a metal-based inorganic material is coated with a coating, the material is limited to Heat resistance exceeding 300 t. Generally, coatings use resins with high thermosetting properties. For example, there are Representative examples of esters, acrylics, melamine, epoxy, urethane resins are generally baked at 150 ° C. When these coatings are exposed to temperatures exceeding 300 ° C, the gloss often disappears and Problems such as flaking appear. Such data show that, on widely used materials, the conventional technique of forming a film by the melt gel method has a problem of great heat resistance. On the other hand, the temperature does not exceed 300 ° C. The so-called physical methods, such as sputtering, CVD, and vacuum deposition methods that form thin films in the temperature range, must be provided with a vacuum (please read the precautions on the back before filling this page) F · · 1111111 Order ·! One — I! ·

經濟部智慧时產局員工消f合作让印S 482694 A7 __B7 五、發明說明（5 ) 裝置等大的裝置，故生產成本極高。且由於成膜時在高真空下形成薄膜，氧化物光觸媒的組成比歧異擴大，且光觸媒性能惡化。復在成膜時以有機材料爲基板情形下，會有道噴濺損及基板導致基板變形等問題。且在熔膠凝膠法的塗覆法等化學方法中，於使用分散氧化物微粒子的矽膠情形下，成膜於無耐熱性的基板上由於熱處理的溫度低，故無法充份燒結，以致於所形成氧化物薄膜的強度及耐水性不充份。基於以上理由，往常既有技術要在一般用於電化製品的有機高分子材料表面上不引發變形與劣化等損害而形成以T i〇2爲主要成份的光觸媒薄膜，事實上有困難。本發明第一目的在於提供一種在無耐熱性材料如塑膠與塗料的表面上形成高活性薄膜而具有抗菌、防污、除臭效果的物品。另一方面，就以T i 〇2爲主要成份的光觸媒有機物分解效果本身極高的事實而言，其見於上述光觸媒應用技術的發明中實無庸贅言。亦即，無須費心於材料的配合以改善含T i 0 2的薄膜的光活性度。因此，在譬如特開平 8 — 309148號公報及特開平8 — 266605號公報等目的在於除臭的習知利用法，或特開平 9 - 3 8 1 8 9號公報等分解香煙油垢的利用法，乃至於特開平5 - 1 5 7 3 0 5號等分解烹調油污用途方面的應用例諸情形中，由於各個光觸媒本身的活性度不充份，故倂用照射紫外線的機構與加熱裝置等，藉此提高分解反應本紙張纥度適用中國國家標準（CNS)A4規格（210 x 297公釐） .Q . (請先閱讀背面之注意事項再填寫本頁) · I n ϋ ϋ n I^OJ· ϋ n ϋ n n ·ϋ I 1 482694 A7 ____B7 _ 五、發明說明（6 ) 〇其最大原因在於，光度小情形下，T i〇2本身的有機物分解速度不充份，由於未形成有提高其效能用的措施，故倂用紫外線燈等來作爲增進光度的裝置。雖然通常係以高壓水銀燈與金屬鹵素燈來作爲紫外線燈，惟需有電源裝置與冷卻機構等機構，應用製品全體的重量與價格會提高。且燈的壽命爲2 0 0 0小時，須定期進行換裝作業等，實用性上有問題。習知技術固然已知使用添加F e、V於T i〇2中來提高分解效能的措施，惟在數百°C下進行高溫處理使其高性能化而應用於缺乏耐熱性的低融低基板材料上實有困難。本發明的第二目的在於提高光分解效率，使其較第一目的中可在低溫下形成的光觸媒薄膜的T i ◦ 2單體分解效率高，即使光度較習知所需光度小，亦可分解附著物。且習知技術在抗菌性、防臭、除臭等用途方面，由於對象物質爲有機物，且對象物爲微粒子或分子狀，因此，固然可分解所附著液狀有機物與微粒子狀有機物，惟較大的纖維類與塵埃類，即使其爲有機物，分解上亦極爲費時，乃至於在以塵土爲中心的無機物分解上亦極爲困難，其在污染防止用途上實有不周之處。此等污染物由於一般係在帶電狀態下浮遊於空氣中，故若附著於電絕緣性高的個體表面上，其靜電不易放電而會形成附著狀態。因附著無機物污染物而遮住光，即無法充份照射光於光觸面上，產生有機分解效率低下的問題。本纸張义度適用中國國家標準（CNS)A4規格（210 x 297公釐） .g« (請先閱讀背面之注意事項再填寫本頁)Staff of the Ministry of Economic Affairs ’Smart Time and Production Bureau cooperated to print S 482694 A7 __B7 V. Invention Description (5) Large devices such as devices, so the production cost is extremely high. In addition, since a thin film is formed under high vacuum during film formation, the composition ratio of the oxide photocatalyst varies widely, and the photocatalyst performance deteriorates. In the case where an organic material is used as a substrate during film formation, there are problems such as splash damage and substrate deformation caused by the substrate. In addition, in chemical methods such as the melt-gel method and the coating method, in the case of silica using dispersed oxide fine particles, the film is formed on a substrate having no heat resistance because the heat treatment temperature is low, so it cannot be sufficiently sintered, so that The strength and water resistance of the formed oxide film were insufficient. Based on the above reasons, it is actually difficult for existing technologies to form a photocatalyst film mainly composed of Tio2 on the surface of organic polymer materials generally used in electrochemical products without causing damage such as deformation and deterioration. A first object of the present invention is to provide an article having a high antibacterial, antifouling, and deodorizing effect by forming a highly active film on the surface of a non-heat-resistant material such as plastic and paint. On the other hand, as far as the fact that the photocatalyst organic matter with T i 〇2 as a main component decomposes is extremely high, it is needless to say that it is found in the invention of the photocatalyst application technology. That is, there is no need to bother with the material to improve the photoactivity of the film containing T i 0 2. Therefore, for example, conventional use methods for deodorization such as Japanese Patent Application Laid-Open No. 8-309148 and Japanese Patent Application Laid-Open No. 8-266605, or use methods for decomposing cigarette oil stains such as Japanese Patent Application No. 9-3 8 1 8 Even in application cases such as JP-A-Hei 5-1 5 7 3 0 5 for decomposing cooking oil stains, the photocatalyst itself is not sufficiently active. Therefore, it is necessary to use a mechanism and heating device that irradiate ultraviolet rays. This increase the degree of decomposition reaction of this paper is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) .Q. (Please read the precautions on the back before filling this page) · I n ϋ ϋ n I ^ OJ · ϋ n ϋ nn · ϋ I 1 482694 A7 ____B7 _ 5. Description of the invention (6) 〇 The biggest reason is that in the case of small light, the organic matter decomposition rate of T i〇2 itself is not sufficient, because it is not formed to improve its efficiency Therefore, it is necessary to use an ultraviolet lamp or the like as a device for improving luminosity. Although high-pressure mercury lamps and metal halide lamps are usually used as ultraviolet lamps, only a power supply device and a cooling mechanism are required, and the weight and price of the entire application product will increase. In addition, the life of the lamp is 2000 hours, and replacement work must be performed regularly, which has practical problems. Although conventional techniques are known to increase the decomposition efficiency by adding Fe and V to Tio2, high-temperature treatment at a temperature of several hundred ° C is used to improve the performance and it is applied to low-melting and low-heat-resisting materials. There are real difficulties with substrate materials. The second object of the present invention is to improve the photodecomposition efficiency, so that it is higher than the T i ◦ 2 monomer decomposition efficiency of the photocatalyst film that can be formed at low temperature in the first object, even if the light intensity is smaller than the conventionally required light intensity. Decompose attachments. And the conventional technology is used in antibacterial, deodorizing, deodorizing and other applications. Since the target substance is an organic substance, and the target substance is a microparticle or a molecular substance, it can decompose the attached liquid organic substance and the particulate organic substance, but the larger one Fibers and dusts are extremely time-consuming to decompose even if they are organic matter, and even it is extremely difficult to decompose inorganic matter centered on dust. They are not good in pollution prevention applications. Since these pollutants generally float in the air in a charged state, if they are attached to the surface of an individual with high electrical insulation properties, their static electricity is not easily discharged and they will form an attached state. The light is blocked by the attachment of inorganic pollutants, that is, the light cannot be fully irradiated on the light-contact surface, resulting in a problem of low organic decomposition efficiency. The meaning of this paper applies to the Chinese National Standard (CNS) A4 (210 x 297 mm) .g «(Please read the precautions on the back before filling this page)

ϋ I 1_1 ϋ 1_1 ϋ ϋ n ϋ I n 1 Mmmf am— I 經濟部智慧財產局員工消費合作社印製 482694 A7 B7___ 五、發明說明（7 ) 本發明第三目的係在此等光觸媒的氧化分解效果方面使原理上不易分解去除的大型塵埃類與無機物污染物不會藉靜電力而附著在對象材料。〔用來解決課題的裝置〕爲達成上述目的，本發明特徵在於具有驅動空氣淸淨機、換氣扇、扇風機、掃除機、衣物乾燥機、餐具乾燥機、餐具洗濯機、廚房渣滓處理機等電動送風機而產生氣流的機構，在主要用於屋內的電氣製品部件中的氣流通路及其氣流通路中的過濾機構，或面對室內照明光的外裝部件類的表面上，設有低溫硬化型高活性氧化物光觸媒薄膜。對象部件素材的融點或分解溫度在3 0 0 °C以下，特別是在泛用熱塑性塑膠製成形部件、纖維部件、發泡體部件、片狀部件上設有低溫硬化型高活性氧化物光觸媒薄膜，藉解決習知技術中污染、微生物繁殖、惡臭發生等問題〇經濟部智慧財4局3工消費合作吐.卬製本發明可藉由以T i〇2爲主體的氧化物光觸媒薄膜最適化，T i 〇 2粒子徑最適化，添加電氣陰性低而適當的離子，在以S i〇2爲接合劑情形下使其與T i〇2的混合比最適化，添加電氣親合力高的氧化物半導體，添加適當貴金屬類等配合處方，復藉由提高光觸媒反應的活性度的薄膜形成於上述電氣製品的氣流通路與外裝零件的表面上，獲得習知技術所無法達成的藉室內光來防污、除臭以及抑制微生物繁殖的效果。且可藉由膜的層疊來防止對氧化分 -10- (請先閱讀背面之注意事項再填寫本頁) 本纸張义度適用中國國家標準（CNS)A4規格（210 x 297公釐）經濟部智慧財查局員工消費合作fi印没 482694 A7 B7 五、發明說明（8 ) 解弱的有機物素質的損害。同時，本發明在形成以S i〇2與T i〇2爲主體的無機聚合物薄膜工序中，照射含破壞有機金屬化合物的金屬原子與有機基結合所需特定波長的電磁波，藉由採取促進加水分解反應的工序，在低溫下進行無機聚合物的高分子化，因此，即使在上述低耐熱性的泛用熱塑性塑膠表面上，亦可獲得在低溫下不致於發生變形、熔解、分解等的強固氧化物光觸媒薄膜的強度。以下就低溫硬化型高活性氧化物光觸媒薄膜的詳細內容加以說明。在分散有氧化物光觸媒T i 0 2微粒子的氧化物光觸媒薄膜中，藉由添加電氣陰性度小於1 · 6，離子半徑小於0 · 2 n m (納米）元素，原子價2以下的離子，改善反應效率。具體添加的元素以Na、 Li、 K、ϋ I 1_1 ϋ 1_1 ϋ ϋ n ϋ I n 1 Mmmf am— I Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 482694 A7 B7___ 5. Description of the invention (7) The third object of the present invention is the oxidative decomposition effect of these photocatalysts On the other hand, large-scale dusts and inorganic pollutants, which are difficult to decompose and remove in principle, will not adhere to the target material by electrostatic force. [Apparatus for solving the problem] In order to achieve the above object, the present invention is characterized by having electric blowers such as an air purifier, a ventilator, a fan, a sweeper, a clothes dryer, a dish dryer, a dish washer, and a kitchen waste treatment machine. The mechanism that generates airflow is provided with a low-temperature-hardening type on the surface of the airflow path mainly used in the electrical parts of the house and the filtering mechanism in the airflow path, or the exterior parts facing the indoor lighting light. Active oxide photocatalyst film. The melting point or decomposition temperature of the target component material is below 300 ° C. Especially, low-temperature hardening type highly active oxide photocatalysts are provided on the general-purpose thermoplastic plastics-shaped components, fiber components, foam components, and sheet components. The thin film solves the problems of pollution, microbial reproduction, and malodor generation in the conventional technology. The Ministry of Economic Affairs and the Intelligent Welfare Bureau, the 3rd Bureau of Industrial Cooperation and Consumer Spitting. The invention can be optimized by using the oxide photocatalyst film with T i02 as the main body. , T i 〇2 particle diameter is optimized, low electrical negative and appropriate ions are added, when S i〇2 is used as the binder, the mixing ratio with T i〇2 is optimized, and oxidation with high electrical affinity is added. Bio-semiconductor, adding appropriate noble metals, etc. in accordance with the prescription, and a thin film that enhances the activity of the photocatalyst reaction is formed on the surface of the air flow path of the electrical product and the surface of the exterior parts, and obtains indoor light that cannot be achieved by conventional technologies. Antifouling, deodorizing, and inhibiting microbial reproduction. And the film can be laminated to prevent oxidation. -10- (Please read the precautions on the back before filling this page) The meaning of this paper applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) Wisdom of the Ministry of Economic Affairs Financial Cooperation Bureau employee consumer cooperation fi stamp 482694 A7 B7 V. Description of invention (8) Eliminate the damage of weak organic matter. At the same time, in the process of forming an inorganic polymer film mainly composed of Si02 and Tio2, the present invention irradiates electromagnetic waves containing a specific wavelength required to destroy the metal atom of the organometallic compound and combine with the organic group, and promotes it by taking In the hydrolytic reaction step, the inorganic polymer is polymerized at a low temperature. Therefore, even on the surface of the above-mentioned low-heat-resistant general-purpose thermoplastic plastic, it is possible to obtain a product that does not deform, melt, or decompose at low temperatures. Strength of solid oxide photocatalyst film. The details of the low-temperature-curing type highly active oxide photocatalyst film will be described below. In the oxide photocatalyst film in which the oxide photocatalyst T i 0 2 fine particles are dispersed, by adding an element having an electrical negativeness of less than 1 · 6, an ion radius of less than 0 · 2 nm (nanometers), and an ion having an atomic value of 2 or less, the reaction is improved. effectiveness. The specific added elements are Na, Li, K,

Sr、 Mg、 Ca、 Zn特別有效，此等元素的添加量最好爲0 · 5〜20wt (重量％) °Ti〇2微粒子的大小調整爲5〜2 0 nm最爲有效。且在T i〇2微粒子分散於S i〇2中的氧化物光觸媒薄膜中，Ti〇2/Si〇2的重量比宜爲9〜5。前述氧化物薄膜的膜厚宜爲1 0 0〜5 0 0 nm。所添加成份若進一步添加前述離子，分散以至少電子親合力1 · 2以上金屬元素所構成氧化物半導體爲主體的氧化物微粒子，則更可增其效果。元素特別宜於選自S η 、Fe、 Cr。其添加量最好爲2〜50wt%。其中以 A T D (添加銻之氧化錫）爲主體的氧化物微粒子效果特本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐) 7γ\ (請先閱讀背面之注意事項再填寫本頁) 裝Sr, Mg, Ca, and Zn are particularly effective, and the addition amount of these elements is preferably 0. 5 to 20 wt.% (Weight%). The size of the Ti02 fine particles is most effectively adjusted to 5 to 20 nm. In the oxide photocatalyst thin film in which T i02 fine particles are dispersed in S i02, the weight ratio of Ti〇2 / Si〇2 is preferably 9 to 5. The film thickness of the oxide thin film is preferably 100 nm to 500 nm. If the added component is further added with the aforementioned ions, and the oxide fine particles mainly composed of an oxide semiconductor composed of a metal element having at least an electron affinity of 1.2 or more are added, the effect can be further enhanced. The element is particularly suitably selected from S η, Fe, and Cr. The added amount is preferably 2 to 50% by weight. Among them, the effect of oxide particles with ATD (antimony-added tin oxide) as the main body is specially adapted to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 7γ \ (Please read the precautions on the back before filling (This page)

I ϋ ϋ I^eJ· n I ·1 ϋ ϋ ϋ n I 經濟部智慧財產局員工消費合作社印製 482694 A7 B7 五、發明說明（）別大。添加此等半導體微粒子時，由於膜本身表面的電阻値降低，故含有無法氧化分解的無機污染物，污染物本身即難以靜電附著。更且，使氧化物光觸媒薄膜成爲複數疊層構造亦有效，自表面數起第1層係在s i 〇2中分散Ti 〇2微粒子，於其膜中添加上述離子，而在表面數起第二層上則分散以前述氧化物半導體爲主體的氧化物微粒子。藉此，即使在對氧化耐久性低的塑膠等的表面上，光觸媒亦具有不虞損害的效果的功能。且在同第2層上添加F e、A 1與Z r 中至少一種更具效果。添加成份若添加前述離子，添加Pt、 Rh、 Pd、 A g、C u、N i中至少一種，效果極佳。丁 i 〇2具有光觸媒功能，並具有藉有機物分解來抗菌、除臭、防污等作用。此功能起因於T i 0 2半導體照射光，特別是照射紫外線所產生的空穴-電子對。T i 0 2半導體若照射具有帶隙以上能量的光，即會產生空穴一電子對。所產生的空穴-電子對將T i 〇2上所吸著的水分解而產生Η自由基與〇Η自由基。藉由此〇Η自由基與有機物反應可分解有機物。光觸媒固化此種機構分解有機物等，惟進一步擴大反應速度者卻有以下二措施。第1係使一活性點的工作量增加，第2係使活性點的數目增加。活性點數目增加係藉由表面積擴大，亦即使T i 0 2微粒子化來達成。且爲了使活性點的工作量增加，增進T i〇2 (銳鈦礦）結晶化，防止空穴-電子對角結合。藉由滿足以上條件艮[] 本纸張Κ度適用中國國家標準（CNS)A4規格（210 X 297公餐） -12- (請先閱讀背面之注意事項再填寫本頁) * ϋ ϋ fi eamw I i·— ϋ · 1 ϋ 1 n ϋ ϋ ι 482694 A7 B7 經濟部智慧財4笱3工消費合^Tfi-卬五、發明說明（1ί)) 可擴大反應速度。惟增加T i〇2 (銳鈦礦）的結晶化與擴大表面積相反而有兩立的困難。亦即，提高結晶性會導致粒子徑增加，表面積減少。因此，在提高結晶性的方向與擴大表面積的方向之間存在有最適域。此最適領域經本發明多次實驗結果發現其爲5〜2 0 n m。在分散T i〇2微粒子情形下，改變用來作爲無機接合劑的氧化物種類，亦可在此粒子徑範圍內擴大分解速度。在藉由防止電子與空穴再結合來提高反應速度方面，可藉由提高電子與空穴的分解效率來達成。T i 〇2表面上存在有T i電子不足。此種不足成爲電子與空穴的再結合點，會阻礙反應。此時若添加離子半徑與T i相同的離子，即會侵入表面的T i不足部份，使此不足消除而減少再結合點。且由於存在有正離子，故可吸引電使其與空穴分離，促進有機物的氧化反應。經察，本發明具有此種效果的添加劑條件以電氣陰性度小於1 · 6 ,離子半徑小於 0 · 2 n m極爲有效。且經察，本發明亦可藉由添加其他氧化物半導體微粒子來使其高性能化。這可藉由自載流子濃度大的氧化物半導體將載流子注入載流子濃度小的T i 0 2中來達成。因此，載流子易於自氧化物半導體流至T i〇2有其必要性。氧化物半導體的電子親合力若在T i之下，即會形成肯脫基勢壘。因此，所添加的材料其電子親合力須在1 · 2 e v 以上。且經察，本發明若添加Fe、 Al、 Zr、 Ti〇2的 (請先閱讀背面之注意事項再填寫本頁) 7·裝I ϋ ϋ I ^ eJ · n I · 1 ϋ ϋ ϋ n I Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 482694 A7 B7 V. Description of the invention () Not great. When these semiconductor fine particles are added, since the resistance 値 on the surface of the film itself is reduced, inorganic pollutants that cannot be oxidized and decomposed are contained, and it is difficult for the pollutants themselves to adhere statically. Furthermore, it is also effective to make the oxide photocatalyst thin film into a multi-layer structure. The first layer from the surface is dispersed with Ti 〇2 fine particles in si 〇2, the above ions are added to the film, and the second is from the surface. On the layer, oxide fine particles mainly containing the aforementioned oxide semiconductor are dispersed. Thereby, the photocatalyst has the function of preventing damage even on the surface of plastics and the like having low oxidation durability. And adding at least one of F e, A 1 and Z r on the same second layer is more effective. If the aforementioned ingredients are added, at least one of Pt, Rh, Pd, Ag, Cu, and Ni is added, and the effect is excellent. Ding 〇2 has the function of photocatalyst, and has the functions of antibacterial, deodorizing, antifouling, etc. by decomposition of organic matter. This function results from the irradiation of T i 0 2 semiconductors with light, especially the hole-electron pairs generated by irradiation with ultraviolet rays. If the T i 0 2 semiconductor is irradiated with light having energy above the band gap, a hole-electron pair will be generated. The generated hole-electron pair decomposes the water absorbed on T i 〇2 to generate Η radicals and Η radicals. By this reaction of OH radicals with organics, organics can be decomposed. The photocatalyst solidifies such a mechanism to decompose organic matter, etc., but those who further increase the reaction speed have the following two measures. The first line increases the workload of one active point, and the second line increases the number of active points. The increase in the number of active points is achieved by increasing the surface area even when T i 0 2 becomes micronized. In addition, in order to increase the workload of the active point, the crystallization of Tio2 (anatase) is improved, and the hole-electron diagonal combination is prevented. By satisfying the above conditions, [] this paper is compliant with China National Standard (CNS) A4 (210 X 297 meals) -12- (Please read the precautions on the back before filling this page) I i · — ϋ · 1 ϋ 1 n ϋ ι 482694 A7 B7 Ministry of Economic Affairs, Smart Wealth, 4th, 3th, Industrial and Consumer Consumption (Tfi- 卬 5, Invention Description (1)) can increase the response speed. However, increasing the crystallization of T i02 (anatase) is opposite to expanding the surface area, which has the opposite difficulty. That is, an increase in crystallinity leads to an increase in particle diameter and a decrease in surface area. Therefore, there is an optimum region between the direction of increasing the crystallinity and the direction of increasing the surface area. This optimum field was found to be 5 to 20 nm by multiple experiments of the present invention. In the case of dispersing Tio2 fine particles, changing the type of oxide used as an inorganic bonding agent can also increase the decomposition rate within this particle diameter range. In order to improve the reaction speed by preventing recombination of electrons and holes, it can be achieved by increasing the decomposition efficiency of electrons and holes. There is a T i electron deficiency on the T i 02 surface. This deficiency becomes a recombination point for electrons and holes, which hinders the reaction. At this time, if an ion with the same ionic radius as T i is added, it will invade the insufficient portion of T i on the surface to eliminate this deficiency and reduce the recombination point. And because of the existence of positive ions, it can attract electricity to separate it from holes, and promote the oxidation reaction of organic matter. It has been found that the conditions for the additive having such an effect in the present invention are extremely effective with an electrical negativeness of less than 1 · 6 and an ion radius of less than 0 · 2 n m. Furthermore, it has been found that the present invention can also increase its performance by adding other oxide semiconductor fine particles. This can be achieved by injecting carriers into a small carrier concentration T i 0 2 from an oxide semiconductor with a high carrier concentration. Therefore, it is necessary for carriers to easily flow from the oxide semiconductor to Tio2. If the electron affinity of the oxide semiconductor is below T i, a Kennedy barrier is formed. Therefore, the electronic affinity of the added material must be above 1 · 2 e v. And it has been observed that if Fe, Al, Zr, Ti〇2 is added to the present invention (please read the precautions on the back before filling this page)

amm— n elm I · -ϋ ϋ Mmmmmr ϋ_· II ϋ 11 I 本紙張又度適用中國國家標準（CNS)A4規格（210 x 297公蓳） -13- 482694 A7 ______B7 _ 五、發明說明（11 ) 光觸媒即會消失。在以有機物爲主體的基板材料情形下，會有基板因光觸媒作用本身破壞的問題。因此，本發明固在基板與光觸媒之間形成勢壘，惟可藉由添加F e、A 1 、A r於此勢壘層中，完全抑制其本身的破壞。且由於其爲高性能的勢壘層，故膜厚可極薄。在添加A T〇等導電性微粒子並層疊情形下，可藉由提高光觸媒性能並賦與帶電防止功能，不止分解有機物，復防止空氣中浮遊的塵埃等無機物的附著，以提供更高性能的防污功能。且本發明由於上述活性高，可以較習知者更微弱的光度來分解，乃至於具有帶電防止功能，故可以習知成膜方法，在廉價而泛用性高的耐熱性不充份的素材表面上形成具有污物微粒子本身難以藉靜電附著的特性的高活性光觸媒薄膜。因此，在含有鈦與矽分子量有機金屬化合物與水的溶液無機聚合物化、高分子化之際，加入照射具有破壞該有機金屬化合物的金屬原子與有機基結合所需特定波長的電磁波的程序，即可促進該有機金屬化合物的加水分解，金屬氧化物的預聚合物形成於前述溶液中，而降低膜形成溫度。該特定波長的電磁波最好爲紫外線光。最好在將含有低分子量有機金屬化合物與水的溶液塗覆於被覆表面上之後，照射紫外線光等破壞該有機金屬化合物的金屬原子與有機基結合所需特定波長的電磁波，同時加熱乾燥，或在電磁波照射程序之後加熱乾燥。 (請先閱讀背面之注意事項再填寫本頁)amm— n elm I · -ϋ ϋ Mmmmmr ϋ_ · II ϋ 11 I This paper is again applicable to China National Standard (CNS) A4 (210 x 297 cm) -13- 482694 A7 ______B7 _ V. Description of the invention (11) The photocatalyst will disappear. In the case of a substrate material mainly composed of an organic substance, there is a problem that the substrate itself is destroyed by a photocatalyst action. Therefore, the present invention forms a potential barrier between the substrate and the photocatalyst. However, by adding Fe, A1, and Ar to this barrier layer, its own damage can be completely suppressed. And because it is a high-performance barrier layer, the film thickness can be extremely thin. When conductive fine particles such as AT0 are added and laminated, the photocatalyst performance can be improved and the charging prevention function can be provided, which not only decomposes organic substances, but also prevents the adhesion of inorganic substances such as dust floating in the air to provide higher performance antifouling. Features. In addition, the present invention has high activity and can be decomposed with a weaker luminosity than a known person, and even has a charge prevention function. Therefore, a film forming method can be known, and the surface of a material having low heat resistance and insufficient heat resistance can be widely used on the surface. A highly active photocatalyst film having a property that dirt particles are difficult to adhere by static electricity is formed. Therefore, when a solution containing titanium and silicon molecular weight organometallic compounds and water is inorganic polymerized and polymerized, a program for irradiating electromagnetic waves having a specific wavelength required to destroy the metal atoms of the organometallic compounds and organic groups is added, that is, Hydrogenation of the organometallic compound can be promoted, and a prepolymer of a metal oxide is formed in the aforementioned solution, thereby reducing the film formation temperature. The electromagnetic wave having the specific wavelength is preferably ultraviolet light. After applying a solution containing a low-molecular-weight organometallic compound and water on the coating surface, it is preferable to irradiate ultraviolet light or the like to destroy the metal atom of the organometallic compound to combine with the organic group to generate an electromagnetic wave of a specific wavelength, while heating and drying, or Heat drying after the electromagnetic wave irradiation procedure. (Please read the notes on the back before filling this page)

•ϋ ϋ 1 1. 一：OJ· n ϋ ϋ ϋ ·ϋ n I # 經濟部智慧財4局釋、工消费合泎U印.¾ 表纸張义度適用中國國家標準（CNSM4規格（21〇χ 297公t ) -14- 482694 A7 _ __ B7 五、發明說明（12) 發明之實施形式以下根據第1至2 8圖說明本發明一實施形式實例。各種模製品、塗裝鋼板類與濾淸器等的表面上所形成低溫硬化型高活性氧化物光觸媒薄膜的配合組成內容與實施例的效果彙總列示於表1至表9中。 (實施例1 ) 茲根據第1、 2與3圖說明本發明第1實施例之空氣淸淨機。第1圖係過濾型空氣淸淨機本體構成圖，第2圖係本發明斜視圖。空氣淸淨機本體1係以螺絲8將電容器電動機固定於後罩蓋1 2，將電動機驅動用電容器1 1，運轉開關9固定，風扇6以螺帽5固定於電容器電動機7，並以螺絲1 3固定後罩蓋1 2與框架4。且濾淸器3固定於面板（吸入口）2，將面板（吸入口）2向外拆下而將濾淸器3取出。開關旋鈕1 0固定於運轉開關9。藉電容式馬達7的驅動力扇葉6旋轉產生氣流。藉此氣流，自面板（吸入口）2吸入含塵埃、煙、油微粒子、微生物及其殘骸、花粉類與惡臭的室內污染空氣。所吸入的污染空氣經過濾器3過濾淨化之後，由格子板1 4的排氣口 1 5排出。過濾器3配置成具有除去各種污染物與臭味的功能的複合構造。過濾器3由外表面覆層的外過濾器 3 a與外過濾器3 a內部的內過濾器3 b構成（未圖示）。爲過濾塵埃類，各過濾器的基本構造使用聚酯、尿烷、本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） .15- (請先閱讀背面之注意事項再填寫本頁)• ϋ ϋ 1 1. One: OJ · n ϋ ϋ ϋ · ϋ n I # The Ministry of Economy ’s Smart Finance 4 Bureau release, industrial and consumer combined U-print. T) -14- 482694 A7 _ __ B7 V. Description of the invention (12) Implementation mode of the invention An example of an embodiment of the present invention is described below with reference to Figures 1 to 28. Various molded products, coated steel plates and filters The composition of the low-temperature hardening type highly active oxide photocatalyst film formed on the surface and the effects of the examples are summarized in Tables 1 to 9. (Example 1) Explanation will be given with reference to Figures 1, 2 and 3 The air purifier according to the first embodiment of the present invention. Fig. 1 is a structural diagram of a filter type air purifier body, and Fig. 2 is a perspective view of the present invention. The air purifier body 1 is fixed with a capacitor 8 to a capacitor motor by screws 8. The rear cover 1 2 fixes the motor driving capacitor 11 and the operation switch 9, the fan 6 is fixed to the capacitor motor 7 with a nut 5, and the rear cover 12 and the frame 4 are fixed with screws 13. 3Fix it to the panel (suction port) 2 and remove the panel (suction port) 2 The filter 3 is taken out. The switch knob 10 is fixed to the operation switch 9. The fan blade 6 is rotated by the driving force of the capacitive motor 7 to generate airflow. This airflow inhales dust, smoke, and oil particles from the panel (intake port) 2. , Microorganisms and their debris, pollen and malodorous indoor polluted air. The sucked polluted air is filtered and purified by the filter 3, and then discharged through the exhaust port 15 of the grid plate 14. The filter 3 is configured to remove various pollutants Composite structure with odor function. The filter 3 is composed of an outer filter 3 a coated on the outer surface and an inner filter 3 b inside the outer filter 3 a (not shown). For filtering dust, each filter The basic structure of the device uses polyester, urethane, and this paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm). 15- (Please read the precautions on the back before filling this page)

· ϋ ·ϋ I ϋ 1 a·— 一爹口，t ϋ ϋ 1_1 ϋ ϋ ϋ ϋ I 經濟部智慧財4¾員工消費合作让.叩製 482694 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（13) 纖維素、尼龍或駐極體化處理過的聚烯烴類等不織布層與海棉狀多孔質層。將此基本構造加入內過爐器中，混合混紡或封入吸附臭氣用的活性碳粒子與纖維類。且纖維本身浸透中和臭氣用的藥劑，亦有沾於其表面情形。藥劑除各種有機酸與類黃酮類的生物鹼等以外，亦可與微生物繁殖抑制用的抗菌劑類合倂使用。近年來亦使用安全性高的甲殻質、殼聚糖類與兒茶酸誘導體等。所產生的風量約2 〜3 (m3/分），具有在8坪大室內運轉3 0分鐘將7 0 〜9 5%煙草的煙除去的能力。本實施例中該外過濾器3 a由丙烯纖維不織布形成，此表面上形成後述表3所示樣本第2 1號的低溫硬化型活性氧化物光觸媒薄膜。丙烯不織布濾片電暈放電處理後，形成僅有S i 0 2的薄膜，亦即以表1的樣本第1 2號作爲基底層，在此膜形成後，形成樣本第2 1號的低溫硬化型高活性氧化物光觸媒薄膜。膜形成方法固以後述實施例9 詳細說明，惟調整預定熔膠，以各種方法塗裝於工件上之後，即在1 2 0 °C環境氣體中照射水銀燈使其硬化。以下各種實施例均以相同方法形成薄膜。塗覆方法有順應工件形狀進行噴塗、浸漬、刷毛塗覆等方法。外過濾器3 a係最先將取自面板（吸入口）2的空氣過濾的零件，其上附著大量塵埃、煙、油微粒子、微生物及其殘骸、花粉類與惡臭等各種異物。爲了有效吸入空氣 ,在面板（吸入口）2上設有多數開口部，自此開口部將室內照明與太陽光等光照射於外過濾器3 a的空氣吸入面 (請先閱讀背面之注意事項再填寫本頁) 裝訂--------- 本纸張又度適用中國國家標準（CNS)A4規格（210 X 297公餐） -16- 482694 Α7 Β7 五、發明說明（14 ) (請先閱讀背面之注意事項再填寫本頁) 上。藉由光將捕集於外過濾器3 a表面上的異物氧化分解，尤其是煙草的煙與油微粒子，由於成薄膜狀附著於過濾器表面的低溫硬化型高活性氧化物光觸媒上，故可有效分解。且空氣中浮遊的細菌類與黴菌等各種微生物會在高活性光觸媒的分解作用下死滅，或抑制其繁殖。且在玻璃質的皮膜上被覆不織布濾片的纖維表面，即可增進煙的粒子的潤濕性，復提高煙的捕集效果。且面板（吸入口）2、框架4、運轉開關9與後罩蓋 1 2等本空氣淸淨機本體1外裝零件係熱塑性塑膠A B S 的射出成形品。在此等零件的外側面上形成低溫硬化型高活性氧化物光觸媒薄膜。本實施例以剖視圖顯示於第1 9圖中，其係此等對象 A B S零件類表面上如後述表6所示樣本的丙烯不織布濾片表面的薄膜模式圖。於此情形下，塑膠被覆體1 8 9係丙烯纖維，低溫硬化型高活性氧化物光觸媒薄膜係由表面第1層1 9 2與表面第2層1 9 2構成，均成T i〇2微粒子1 8 7與鋰1 9 0分散於S i〇2膜1 8 6中狀態，而在表面第2層1 9 2中則分散有氨添加氧化錫微粒子1 9 3 經濟部智慧財4局員工消f合作.吐印賢〇形成樣本第8 6號的低溫硬化型高活性氧化物光觸媒薄膜。丙烯不織布濾片在電暈放電處理後，形成第1層，並在此層形成後，形成含有樣本第86號的ΑΤΟ的低溫硬化型高活性氧化物光觸媒第2層。照射室內照明與太陽光等光於此等外裝部件上。因此 -17- 本紙張&度適用中國國家標準（CNS)A4規格（210 x 297公釐） 482694 A7 B7_______ 五、發明說明（15 ) ，即使附著前述各種異物，亦可如過濾器情形氧化分解。第3圖係靜電集塵式空氣淸淨機之剖視圖。其整體由前罩蓋1 6與後罩蓋1 7構成。前罩蓋1 6在面板上設有吸氣口 1 9與排氣口 2 0，具有吸氣口 1 9以及可在連接吸氣口 1 9與排氣口 2 0的通風路徑中裝卸自如的前置過濾器2 1。於後方設有與集塵電極2 2對置的放電電極 2 3，復具有集塵電極2 2與除去放電電極2 3所產生臭氧用的臭氧去除過濾器2 4，並具有將前置過濾器2 1、集塵電極2 2、放電電極2 3、臭氧去除過濾器2 4安裝於框體2 5上的集塵組件。後方進一步具有位於與集塵組件接觸部位的緩衝材2 6，使集塵組件與送風機2 7連接的導管2 8，以及送風機2 7，具有緩衝材2 6安裝於導管28上，導管28進一步安裝在送風機27上，一體構成的送風組件。淨化過的空氣自排氣口 2 0排出。此前置過濾器2 1在過濾型空氣淸淨機情形下可達成與過濾器3 a相同的功能。本實施例的前置過濾器2 1係尼龍製網件，於其表面上形成有後述表3所示樣本第2 1號低溫硬化型高活性氧化物光觸媒薄膜。尼龍製網件在紫外線照射處理後，形成樣本第2 1號低溫硬化型高活性氧化物光觸媒薄膜。第 1 8圖以剖視圖顯示此種尼龍製網件表面的薄膜模式圖。於此情形下，塑膠被覆體1 8 9爲尼龍纖維，低溫硬化型高活性氧化物光觸媒薄膜1 9成T i〇2微粒子1 8 7與鋰 1 9〇分散於S i〇2膜1 8 6中狀態。 (請先閱讀背面之注意事項再填寫本頁) 裝 ϋ n ϋ ϋ 一 δ，i I n ϋ ϋ n ϋ ϋ 經濟部智慧財產局員工消費合作社印製本紙張&度適用中國國家標準（CNS)A4規格（210 X 297公f ) -18- 482694 經濟部智慧財4局員工消費合作社印製 A7 B7 五、發明說明（16) 且後罩蓋1 7爲A B S射出成形品，前罩蓋1 6係鍍亞給鋼板塑性加工製成品，外側表以聚酯系燒附塗料塗裝。與前述相同，此後罩蓋1 7與前罩蓋1 6的外側面上形成樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。 (實施例2 ) 茲以第4圖就本發明第2實施例之換氣扇加以說明。第4圖係自廚房用換氣扇構造側面所取的剖視圖。於箱型框架2 9上安裝電動機3 0，在電動機3 0上安裝葉片3 1。且在框架2 9的屋外側（排氣側）上安裝擋板 3 2，在框架2 9的屋內側（吸氣側）上安裝孔口 3 3。於孔□ 3 3的屋內側（吸氣側）上部安裝附設有螢光燈 3 4的照明器具3 5。在孔口 3 3、照明器具3 5的屋內側（吸氣側）上安裝有過濾器3 6。過濾器3 6的下部具有油囊3 7。其換氣能力一般在葉片3 1的直徑爲2 5 ( cm)情形下，約8 0 0〜1 〇〇〇 ( m 3 /時間）。第4圖的構造固實現廚房使用方式的換氣扇，惟僅在一般屋內用、化粧室用、浴室用等安裝角度與部件的位置關係方面有些許不同，基本構造均相同。濾片3 6的構造與前述空氣淸淨機的情形相同，可適應各種用途作成複合構造，賦與除臭功能與抗菌功能。於本實施例中，過濾器3 6係由丙烯纖維的不織布製成的單層濾片，於其表面上形成第3圖所示樣本第22號 (請先閱讀背面之注意事項再填寫本頁) β I MM I Μ· ΜΗΜ 訂--------- 本纸張义度適用中國國家標準（CNS)A4規格（210 x 297公f ) -19- 482694 A7 B7 五、發明說明（17) 低溫硬化型高活性氧化物光觸媒薄膜。丙烯不織布濾片在電暈放電處理後，形成僅s i〇2的薄膜，亦即以表1的樣本第1 2號爲基底層，於此膜形成後，形成樣本第2 2號的低溫硬化型高活性氧化物光觸媒薄膜。框架2 9係P S (高衝擊式苯乙烯樹脂）射出成.形品，孔口 3 3與葉片3 1係ABS射出成形品。與則述空氣淸淨機相同，在此等成形零件的表面上形成樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。且面朝屋外的部件的擋板3 2係鍍熔融亞鉛的冷延鋼板製成，其表面上電解澱積塗裝丙烯樹脂，其表面上與前述同樣，形成樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。過濾器3 6朝屋內表面以屋內照明照射，相反面則由照明器具3 5所發出的光照射。且框架2 9、孔口 3 3、葉片3 1與油囊3 7等零件亦由照明器具3 5發出的光照射面朝屋外的擋板8表面上照射太陽光。於本實施例情形下，由於係廚房用換氣扇，故與通常換氣扇相比，污染程度極大。亦即，烹調時，表面上附著大量飛散的食用油微粒子。於廚房用換氣扇情形下，一般較習知者多具備一照明具3 5。其功能經設計用來對烹調身邊照射，與換氣扇的動作同時點燈，亦可僅具有照明功能獨立點燈。本發明光觸媒的有機物分解效率由於較習知者大，故在通常污染負荷小的情形下，固不特別倂設照明器具，以室內照明即可獲得充份分解作用，惟亦有廚房等 (請先閱讀背面之注意事項再填寫本頁)· Ϋ · ϋ I ϋ 1 a · — a father's mouth, t ϋ _1 1_1 ϋ ϋ ϋ ϋ ϋ I Ministry of Economic Affairs Intellectual Property 4¾ Employee Consumption Cooperation Allowance 叩 482694 A7 B7 Description of the invention (13) Non-woven fabric layers and sponge-like porous layers such as cellulose, nylon, or electret-treated polyolefins. This basic structure is added to an internal furnace, and the activated carbon particles and fibers used for odor absorption are mixed, blended or sealed. In addition, the fiber itself is saturated with the medicament used to neutralize the odor, and it may also stick to the surface. In addition to various organic acids and flavonoid alkaloids, the agent can also be used in combination with antibacterial agents for inhibiting the growth of microorganisms. In recent years, chitin, chitosan, and catechin inducers with high safety have also been used. The generated air volume is about 2 to 3 (m3 / min), and it has the ability to remove 70 to 9 5% tobacco smoke by operating in an 8-ping room for 30 minutes. In this embodiment, the outer filter 3a is formed of a non-woven fabric made of acrylic fiber, and a low-temperature-curable active oxide photocatalyst film of sample No. 21 shown in Table 3 described later is formed on this surface. After the corona discharge treatment of the acrylic non-woven filter, a film with only S i 0 2 was formed, that is, the sample No. 12 of Table 1 was used as the base layer. After this film was formed, the low-temperature hardening of the sample No. 21 was formed. Type highly active oxide photocatalyst film. The film formation method is described in detail in Example 9 described later. However, after a predetermined melt is adjusted and applied to a workpiece by various methods, a mercury lamp is irradiated in an ambient gas at 120 ° C to harden it. In the following various examples, a thin film was formed in the same manner. Coating methods include spraying, dipping, and bristle coating in accordance with the shape of the workpiece. The outer filter 3a is the first part that filters the air taken from the panel (intake port) 2. A large amount of dust, smoke, oil particles, microorganisms and their debris, pollen, and malodor are attached to it. In order to effectively inhale air, a large number of openings are provided in the panel (intake port) 2. From this opening, indoor lighting and sunlight are irradiated to the air suction surface of the external filter 3a (please read the precautions on the back first) (Fill in this page again) Binding --------- This paper is again applicable to China National Standard (CNS) A4 (210 X 297 meals) -16- 482694 Α7 Β7 V. Description of the invention (14) ( Please read the notes on the back before filling out this page). The foreign matter trapped on the surface of the outer filter 3 a is oxidized and decomposed by light, especially the tobacco smoke and oil particles, which can adhere to the filter surface as a low-temperature hardening type highly active oxide photocatalyst in the form of a thin film. Effective decomposition. In addition, various microorganisms such as bacteria and molds floating in the air will die or inhibit their reproduction under the decomposition of highly active photocatalysts. Furthermore, coating the fiber surface of the non-woven filter on the glassy film can improve the wettability of the smoke particles and further improve the smoke collection effect. In addition, the exterior parts of the main body 1 of the air purifier 1 such as the panel (suction port) 2, the frame 4, the operation switch 9 and the rear cover 1 2 are injection molded products of thermoplastic plastic A B S. A low-temperature hardening type highly active oxide photocatalyst film is formed on the outer surfaces of these parts. This embodiment is shown in a sectional view in FIG. 19, which is a schematic diagram of the film of the surface of the acrylic non-woven filter of the sample shown in Table 6 below on the surface of these objects A B S parts. In this case, the plastic coating body 1 8 9 is a propylene fiber, and the low-temperature hardening type highly active oxide photocatalyst film is composed of the first layer 1 92 on the surface and the second layer 1 92 on the surface. 1 8 7 and lithium 1 90 are dispersed in the SiO 2 film 1 8 6 and the surface of the second layer 1 92 is dispersed with ammonia-added tin oxide particles 1 9 3 f. Collaboration. Tu Yinxian 〇 formed sample No. 86 low temperature hardening type highly active oxide photocatalyst film. After the corona discharge treatment of the acrylic non-woven filter, a first layer was formed, and after this layer was formed, a second layer of a low-temperature-curable high-reactive oxide photocatalyst containing ATO of sample No. 86 was formed. These exterior parts are irradiated with light such as indoor lighting and sunlight. Therefore -17- this paper & degree applies Chinese National Standard (CNS) A4 specification (210 x 297 mm) 482694 A7 B7_______ 5. Description of the invention (15), even if the aforementioned various foreign matter is attached, it can be oxidized and decomposed as in the case of filters . Fig. 3 is a sectional view of an electrostatic dust-collecting air purifier. The whole is composed of a front cover 16 and a rear cover 17. The front cover 16 is provided with an intake port 19 and an exhaust port 20 on the panel, has an intake port 19, and can be detachably installed in a ventilation path connecting the intake port 19 and the exhaust port 20 Pre-filter 2 1. A discharge electrode 2 3 opposite to the dust collecting electrode 2 2 is provided at the rear, and an ozone removing filter 2 4 for removing ozone generated by the dust collecting electrode 22 and the discharging electrode 2 3 is provided, and a pre-filter is provided. 2 1. Dust collection electrode 2 2. Discharge electrode 2 3. Ozone removal filter 2 4 Dust collection component installed on the frame 25. The rear side further includes a buffer material 2 6 located at a contact portion with the dust collecting component, a duct 28 connecting the dust collecting component and the blower 27, and a blower 27 having the buffer material 2 6 installed on the duct 28, and the duct 28 is further installed The blower 27 includes a blower assembly which is integrally formed. The purified air is discharged from the exhaust port 20. This pre-filter 21 can achieve the same function as the filter 3 a in the case of a filter-type air purifier. The pre-filter 21 of this embodiment is a nylon mesh member, and on its surface, a sample No. 21 of a low-temperature hardening type highly active oxide photocatalyst film shown in Table 3 described later is formed. The nylon mesh was subjected to ultraviolet irradiation to form sample No. 21, a low-temperature hardening type highly active oxide photocatalyst film. Figure 18 shows a cross-sectional view of the film on the surface of this nylon mesh. In this case, the plastic coating body 1 89 is nylon fiber, and the low-temperature hardening type highly active oxide photocatalyst film 19% is T i0 2 fine particles 1 8 7 and lithium 1 90 is dispersed in the S i0 2 film 1 8 6 Medium status. (Please read the precautions on the back before filling out this page.) Decoration n ϋ ，，, i I n ϋ ϋ n ϋ 印 Printed on paper & degree applicable to Chinese National Standards (CNS) ) A4 specification (210 X 297 male f) -18- 482694 Printed by A7 B7 of the Consumer Cooperatives of the 4th Bureau of Wisdom and Finance of the Ministry of Economic Affairs 5. Description of the invention (16) and the rear cover 1 7 is ABS injection molded product, the front cover 1 The 6 series is made of plastically processed stainless steel plate, and the outer surface is painted with polyester-based sintered coating. In the same manner as described above, a sample No. 86 of a low-temperature hardening type highly active oxide photocatalyst film is formed on the outer surfaces of the rear cover 17 and the front cover 16. (Embodiment 2) A ventilation fan according to a second embodiment of the present invention will be described with reference to FIG. Fig. 4 is a cross-sectional view taken from the side of the kitchen fan structure. A motor 30 is mounted on the box frame 29, and a blade 31 is mounted on the motor 30. A baffle 3 2 is installed on the outer side (exhaust side) of the frame 2 9, and an orifice 3 3 is installed on the inner side (intake side) of the frame 2 9. At the upper part of the inside (suction side) of the hole □ 3 3, a lighting device 3 5 with a fluorescent lamp 3 4 is installed. A filter 3 6 is installed on the inside side (intake side) of the orifice 3 3 and the lighting fixture 3 5. The lower part of the filter 36 has an oil bag 37. Its ventilation capacity is generally about 8 0 ~ 1 00 (m 3 / time) when the diameter of the blade 31 is 2 5 (cm). The structure shown in Figure 4 is used to realize the ventilation fan of the kitchen, but it is only slightly different in terms of the relationship between the installation angle and the position of the components, such as general indoor, powder room, and bathroom. The basic structure is the same. The structure of the filter 36 is the same as that of the air purifier described above, and it can be made into a composite structure suitable for various uses to impart a deodorizing function and an antibacterial function. In this embodiment, the filter 36 is a single-layer filter made of a non-woven fabric made of acrylic fiber, and a sample No. 22 shown in FIG. 3 is formed on the surface (please read the precautions on the back before filling this page) ) β I MM I Μ · ΜΗΜ Order --------- The meaning of this paper applies to China National Standard (CNS) A4 specification (210 x 297 male f) -19- 482694 A7 B7 V. Description of the invention (17) Low temperature hardening type highly active oxide photocatalyst film. After the corona discharge treatment of the acrylic non-woven filter, a thin film of only SiO2 was formed, that is, the sample No. 12 of Table 1 was used as the base layer. After the film was formed, the low-temperature hardening type of Sample No. 2 was formed. Highly active oxide photocatalyst film. The frame 2 9 series PS (high-impact styrene resin) is injection-molded. The orifice 3 3 and the blade 3 1 series are ABS injection-molded products. As in the air purifier described above, sample No. 86 of a low-temperature hardening type highly active oxide photocatalyst film was formed on the surface of these molded parts. The baffle 3 2 facing the exterior parts is made of cold-drawn steel plated with molten lead. The surface is electrolytically coated with acrylic resin. The surface is the same as the above, forming sample No. 8 and 6 low-temperature hardening type. Highly active oxide photocatalyst film. The filter 36 is irradiated with indoor lighting toward the inner surface of the room, while the opposite surface is illuminated with light emitted from the lighting fixture 35. And the parts of the frame 2 9, the orifice 3 3, the blade 3 1 and the oil bag 37 are also illuminated by the lighting device 3 5, and the projecting side faces the surface of the baffle 8 outside the room to radiate sunlight. In the case of this embodiment, since it is a kitchen ventilating fan, the degree of pollution is extremely large compared with a general ventilating fan. That is, during cooking, a large amount of scattered edible oil particles adhere to the surface. In the case of a kitchen ventilator, generally more than one person is equipped with a lighting fixture 3 5. Its function is designed to illuminate the side of the cooking and light up at the same time as the operation of the ventilation fan, or it can only have independent lighting. The organic matter decomposition efficiency of the photocatalyst of the present invention is larger than that of a known person. Therefore, in the case of a small pollution load, it is not necessary to install a lighting device, and indoor lighting can obtain a sufficient decomposition effect. (Read the notes on the back before filling out this page)

· tmmm ·ϋ ϋ ϋ I 1··1 ϋ fl a_^i ϋ 1· 1_1 iB-i «I 1 I 參· 經濟部智慧財產局員工消費合作钍印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -20- 482694 A7 B7 五、發明說明（18 ) 污染負荷大處所不充份的情形。惟本發明若倂設有一般螢光燈與白熾燈泡的照明功能，即使在廚房與廁所等污染負荷大的場所，亦可獲得充份的效果。 (實施例3 ) . 茲以第5圖就本發明第3實施例之扇風機加以說明。第5圖係扇風機構造之外觀斜視圖。在扇風機本體基台部3 8上安裝支柱3 9，並在支柱3 9上自由滑動*** 滑管4 0上方支持有葉片4 1、護套4 2與電動機4 3等構成的頭部4 4。支柱3 9考慮其強度配置成向下直徑變大。葉片4 1藉電動機4 3的驅動力旋轉，自本體背面形成氣流。護套4 2固具有使手指不接觸旋轉葉片4 1的功能，惟爲了防止兒童等的事故，更提高其安全性，亦在護套4 2整體上被覆護網4 5 (未圖示）。支柱3 9下部安裝遙控器承座4 6，一般係將遙控器4 7收置於遙控器承座4 6內。若藉遙控器4 7的開關操作，設定動作模式，遙控器4 7的紅外線發光部4 8即發出紅外線信號，本體基台部3 8上面的紅外線接收部接收到信號，進行設定動作。於本實施例中，葉片係A S樹脂射出成形品。與前述 A B S等的成形品情形相同，在葉片4 1的表面上形成樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。護套4 2係施以聚酯系燒附塗裝的鋼線材所製成，其表面上亦形成樣本第8 6號低溫硬化型高活性氧化物光觸本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -21 - (請先閱讀背面之注意事項再填寫本頁) · ϋ _1 «_1 n 1« ·ϋ ϋ 一·口，B imw ·1 l ϋ I ϋ n .# 482694 A7 B7 五、發明說明（19) 媒薄膜。護網4 5由尼龍纖維製成，其表面上形成樣本第 8 6號低溫硬化型高活性氧化物光觸媒薄膜。 (請先閱讀背面之注意事項再填寫本頁) 且遙控器4 7的紅外線發光部4 8與本體基台部3 8 上面的紅外線接收部4 9由透明材料的A S樹脂形成。此透明零件的表面上亦形成樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。對象零件的表面上形成鈦系偶合劑的皮膜之後，形成第1層，形成此層後，形成含樣本第8 6號的A T〇的低溫硬化型高活性氧化物光觸媒薄膜第2層。葉片4 1與護套4 2等的表面固與前述空氣淸淨機與換氣扇的葉片與框架類完全一樣，附著空氣中浮遊的污物，惟根據本發明，由於形成有低溫硬化型高活性氧化物光觸媒薄膜，故具有以室內照明光的照度將所附著污染氧化分解以致難以污染的效果。且於本實施例中固利用以紅外線來作遙距操作的機構，惟由於在此紅外線信號發光部與接收部的透明部件表面上形成低溫硬化型高活性氧化物光觸媒薄膜，故信號的連絡不會因零件表面上附著污染而受阻。經濟部智慧財Ϊ局員X.消費合作社印沒本實施例固係使用推進型葉片的扇風機事例，惟於多葉片型葉片的扇風機中，亦可以完全相同的構成，獲得同樣的效果。 (實施例4 ) 茲以第6、7圖就本發明第4實施例的掃除機加以說 -22- 本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） 482694 A7 B7 五、發明說明（2Q) 明。 (請先閱讀背面之注意事項再填寫本頁) 第6圖係掃除機的外觀斜視圖，第7圖係掃除機本體的剖視圖。掃除機本體5 0由被覆下部合成樹脂成形品的下罩蓋5 1、被覆上部的上罩蓋52、罩蓋53、格子罩蓋5 4與手柄5 5等構成，後方下部的左右二側配置.一對直徑大的後方車輪5 6，以及位於前方下部的底面中央的大直徑自由車輪5 7。本體開關部5 8設在上罩蓋5 0中央部，由該本體開關部5 8中央的紅外線接收部5 9、電源開關6 0與塞繩捲軸按鈕6 1。該集塵室6 2中連接由吸塵管部6 3、延長管部6 4與吸口部6 5所構成的吸口管裝配體6 6。手柄部6 7連接於該延長管部6 4的上部，手動操作部6 8安裝於此手柄部6 7上。該手動操作部 6 8上設有紅外線信號發射部6 9，自該紅外線信號發射部6 9發出的紅外線信號以用來傳達於掃除機本體5 0的紅外線接收部5 9的無線電操作。集塵室6 2設於掃除本體5 0內部前方，電動送風機部7 0與塞繩捲軸7 1則倂設於內部後方，另，控制基板7 2設在電動送風機部7 0 與塞繩捲軸7 1的上部。經濟部智慧財i局員工消費合作社印製且，電動送風機部70後方設有自掃除機本體50的背面下端至上端沿上下方向延長的第一排氣通路7 3，該第一排氣通路7 3的下端與進一步形成於電動送風機部 70下方的第二排氣通路74連通。排氣通路7 5 (圖未顯示）由此第一排氣通路7 3與第二排氣通路7 4構成，使第二排氣通路74連通於電動送風機部7〇，並使第一 -23- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（21) 排氣通路連通於排氣通路7 6。集塵室6 2上方設有濾紙安裝部7 7、7 8，該濾紙安裝部7 7、7 8上安裝厚濾紙7 9，藉由關閉構成集塵室6 2上部的罩蓋5 3，將安裝口 8 0與濾紙7 9設於預定位置。自由車輪5 7以自由旋轉方式水平安裝在下罩蓋5 1前方底部上所形成的·凹部上。自安裝口 8 0隨氣流所吸收的垃圾、塵埃、蝨蟲、微生物收集於濾紙7 9上。將此等固體去除的氣流經由設在集塵室6 2與電動送風機7 0間的隔板8 1上並具有輔助濾片8 2的連通口 8 3導至電動送風機部7 0，將電動送風機部70冷卻，冷卻的氣流進一步經由第二排氣通路7 4、第一排氣通路 7 3，自具有排氣濾器8 4的排氣通路7 6排出。於本實施例中，掃除機本體的上罩蓋5 2、罩蓋5 3 、格子罩蓋5 4、手柄部5 5、吸水管組裝配體6 6的延長管部6 4、吸口部6 5與手柄部6 7均爲AB S樹脂射出成形品，此等成形品表面上形成有樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。在對象零件的表面上形成鈦酸酯系偶合劑製皮膜之後，形成第1層，此膜形成後，形成含樣本第8 6號A T 0的低溫硬化型高活性氧化物光觸媒第2層。掃除機與其他實施例的物品比較，由於其爲移動性高的物品，故易於傷及外裝零件的表面。亦即，·掃除機本體與吸口部由於其底面行進中會在傢倶與壁面等上面三反覆摩擦而徐徐形成刮傷，不僅失去光澤而破壞外表美觀，且 (請先閱讀背面之注意事項再填寫本頁) 裝· Tmmm · ϋ ϋ ϋ I 1 ·· 1 ϋ fl a_ ^ i ϋ 1 · 1_1 iB-i «I 1 I Participate · Consumer cooperation of employees of the Intellectual Property Office of the Ministry of Economic Affairs A4 specifications (210 X 297 mm) -20- 482694 A7 B7 V. Description of the invention (18) In the case of a space with a large pollution load. However, if the present invention is provided with a lighting function of general fluorescent lamps and incandescent bulbs, sufficient effects can be obtained even in places with heavy pollution loads such as kitchens and toilets. (Embodiment 3) A fan according to a third embodiment of the present invention will be described with reference to FIG. Figure 5 is a perspective view of the appearance of a fan structure. A support post 39 is installed on the base part 38 of the fan body, and a sliding head 40 is supported on the support post 39 by a blade 4 1, a sheath 4 2 and a motor 4 3. The pillar 39 is configured so that its diameter becomes larger downwards in consideration of its strength. The blade 41 is rotated by the driving force of the motor 4 3 to form an air flow from the back of the body. The sheath 4 2 has a function of preventing fingers from contacting the rotating blade 41. However, in order to prevent accidents of children and the like and to improve its safety, the sheath 4 2 is also covered with a protective net 4 5 as a whole (not shown). The remote control holder 4 6 is installed at the lower part of the pillar 3 9. Generally, the remote control 4 7 is housed in the remote control holder 4 6. If the operation mode of the remote control 47 is set to operate, the infrared light emitting part 48 of the remote control 47 emits an infrared signal, and the infrared receiving part on the base part 38 of the main body receives the signal and performs the setting operation. In this embodiment, the blade is an AS resin injection molded product. As in the case of the molded product such as the above-mentioned A B S, a sample No. 86 of a low-temperature hardening type highly active oxide photocatalyst film was formed on the surface of the blade 41. Sheath 4 2 is made of polyester-based fired and coated steel wire. Sample 8 is also formed on the surface. Low temperature hardening type high active oxide photo-contact. This paper applies Chinese national standards (CNS). A4 specifications (210 X 297 mm) -21-(Please read the precautions on the back before filling out this page) · ϋ _1 «_1 n 1« · ϋ ϋ one mouth, B imw · 1 l ϋ I ϋ n. # 482694 A7 B7 V. Description of the invention (19) Medium film. The protective net 4 5 is made of nylon fiber, and a sample No. 8 6 of a low-temperature hardening type highly active oxide photocatalyst film is formed on the surface. (Please read the precautions on the back before filling in this page) And the infrared light emitting part 48 of the remote control 4 7 and the infrared receiving part 49 on the main base part 3 8 are made of A S resin of transparent material. Sample No. 86 and No. 6 low-temperature hardening type highly active oxide photocatalyst film was also formed on the surface of this transparent part. A film of a titanium-based coupling agent was formed on the surface of the target part, and then a first layer was formed. After this layer was formed, a second layer of a low-temperature-curable highly active oxide photocatalyst film containing A No. 86 of the sample was formed. The surface of the blade 41 and the sheath 4 2 and the like are exactly the same as the blades and frames of the air purifier and the ventilating fan, and adhere to the floating dirt in the air. However, according to the present invention, a low-temperature hardening type highly active oxidation is formed. The photocatalyst thin film has the effect of oxidizing and decomposing the attached pollution with the illuminance of indoor illumination light, making it difficult to contaminate. Moreover, in this embodiment, a mechanism that uses infrared rays for remote operation is fixedly used. However, since a low-temperature-hardening highly active oxide photocatalyst film is formed on the surface of the transparent part of the infrared signal light emitting part and the receiving part, the signal connection is not It will be blocked by contamination on the surface of the part. Member of the Bureau of Intelligent Finance, Ministry of Economic Affairs, X. Consumption Cooperative, this example is based on the example of a fan using a propeller blade. However, it can also have the same configuration and obtain the same effect as a fan with a multi-blade blade. (Embodiment 4) The cleaning machine according to the fourth embodiment of the present invention will be described with reference to Figs. 6 and 7. -22- This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 482694 A7 B7 5. Description of Invention (2Q). (Please read the precautions on the back before filling out this page) Figure 6 is a perspective view of the appearance of the sweeper, and Figure 7 is a cross-sectional view of the sweeper body. The sweeper body 50 is composed of a lower cover 51 covering the lower synthetic resin molded product, an upper cover 52 covering the upper portion, a cover 53, a grid cover 54 and a handle 55, and the like. A pair of large-diameter rear wheels 5 6 and a large-diameter free wheel 57 located in the center of the bottom surface of the lower front portion. The main body switch portion 58 is provided at the center of the upper cover 50, and the infrared receiving portion 59 at the center of the main body switch portion 58, the power switch 60, and the cord reel button 61 are provided. The dust collecting chamber 62 is connected to a suction tube assembly 6 6 composed of a suction tube portion 6 3, an extension tube portion 64, and a suction port portion 65. A handle portion 6 7 is connected to an upper portion of the extension tube portion 64, and a manual operation portion 6 8 is mounted on the handle portion 67. The manual operation section 68 is provided with an infrared signal transmitting section 69. The infrared signal emitted from the infrared signal transmitting section 69 is used to communicate the radio operation of the infrared receiving section 59 of the cleaner body 50. The dust collecting chamber 62 is provided in the front of the cleaning body 50, and the electric blower section 70 and the cord reel 7 are installed behind the inside. In addition, the control board 7 2 is provided in the electric blower section 70 and the cord reel 7 The upper part of 1. The first exhaust passage 7 3, which is printed by the employee's consumer cooperative of the Ministry of Economic Affairs and the Consumer Cooperative, is provided behind the electric blower unit 70 and extends from the lower end to the upper end of the sweeper body 50 in the vertical direction. The lower end of 3 communicates with a second exhaust passage 74 further formed below the electric blower section 70. The exhaust passage 7 5 (not shown) is constituted by the first exhaust passage 73 and the second exhaust passage 74, and the second exhaust passage 74 is communicated with the electric blower section 70, and the first -23 is -This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 mm) 482694 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy . A filter paper mounting portion 7 7, 7 8 is provided above the dust collecting chamber 62, and a thick filter paper 7 9 is mounted on the filter paper mounting portions 7 7, 7 8. By closing the cover 5 3 constituting the upper part of the dust collecting chamber 62, The mounting port 80 and the filter paper 79 are provided at predetermined positions. The free wheel 57 is horizontally mounted on a recess formed on the front bottom of the lower cover 51 in a freely rotatable manner. Garbage, dust, lice, and microorganisms absorbed by the airflow from the installation port 80 are collected on the filter paper 79. The airflow from which these solids are removed is guided to the electric blower section 70 through a partition 8 1 provided between the dust collecting chamber 6 2 and the electric blower 70 and provided with an auxiliary filter 8 2 to the electric blower section 70. The portion 70 is cooled, and the cooled airflow is further discharged from the exhaust passage 74 having the exhaust filter 84 through the second exhaust passage 74 and the first exhaust passage 73. In this embodiment, the upper cover 5 of the main body of the sweeper 2, the cover 5 3, the grid cover 5 4, the handle portion 5 5, the extension tube portion 6 of the suction pipe assembly 6 6 and the suction portion 6 5 Both the handle portion 67 and the handle portion 67 are injection molded products of AB S resin. Samples No. 86 and No. 6 low-temperature curing type highly active oxide photocatalyst films are formed on the surfaces of these molded products. After forming a titanate-based coupling agent coating film on the surface of the target part, a first layer is formed. After this film is formed, a second layer of a low-temperature-curable highly active oxide photocatalyst containing sample No. 86 A T 0 is formed. Compared with the articles of the other embodiments, the cleaner is a highly mobile article, and therefore it is easy to damage the surface of the exterior parts. In other words, as the sweeper body and the mouthpiece part gradually rub against the upper surface of the house and the wall surface during repeated running and scratches, not only lose its luster and damage the appearance, but also (please read the precautions on the back first) (Fill in this page)

-ϋ ϋ B_i_i n 一：OJV ·ϋ n eaMm if —mmm 11 —a— I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -24- 經濟部智慧財產局員工消費合作社印製 482694 A7 ___ B7 五、發明說明（22) 幾至於一傷到便產生裂痕等破損。爲防止此種情形發生，進行習知紫外線硬化型丙烯基樹脂等的塗覆處理，固可確保表面硬度，惟根據本發明，由於構成低溫硬化型高活性氧化物光觸媒薄膜的T i〇2與用來作爲接合劑的s i〇2 的薄膜硬度較ABS硬，並具有2H〜4H鉛筆硬度·，故在用於此等外裝零件情形下，具有不易受到刮傷等傷痕的效果，同時具有固有防污效果，以及微生物繁殖抑制等效果。特別是，手柄部6 7爲手接觸的部件，細菌易於以附著的汗等身體油脂爲養份來繁殖，藉由在成形樹脂中混入習知咪唑基系、噻唑啉系等有機物系抗菌劑與銅系、亞鉛系、銀系等無機物系抗菌劑，固然可獲得抗菌效果，惟無需此種處理。且，吸口部與車輪部由於會發生滑動或旋轉運動，故在乾燥環境下使用掃除機的話，即易於帶有靜電，絨毯等的纖維與塵埃等大多會附著在上述物品類的表面上。爲防止此等情形，將習知各種界面活性劑與聚酰胺系、聚乙二醇系等親水性高分子類混合於成形樹脂中，固可防止表面電阻降低，惟本發明由於可降低低溫硬化型高活性氧化物光觸媒薄膜的電阻値，故即使是電阻値高的A B S類成形樹脂，亦可倂得防止塵埃等附著的效果。手動操作部6 8 安裝於前述手柄部6 7上，此手動操作部6 8的背面固安裝有裝載電子零件類的控制基板，惟若此手動操作部6 8 附近帶有靜電，即會誘發控制基板的錯誤動作，而本發明本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） (請先閱讀背面之注意事項再填寫本頁) · 1·— ·ϋ ·ϋ ϋ 1 ϋ ϋ 一°4曝 I I I I a·* aw 蠢 -25- 482694 A7 B7 五、發明說明（23) 的靜電防止效果不僅可防止塵埃類附著，亦可防止控制基板的錯誤動作。且設於同一手動操作部6 8上的紅外線信號接收部 6 9與掃除機本體1的紅外線接收部5 9固與前述實施例 3的扇風機情形一樣係由透明A S樹脂製成形品構成·，惟由於在表面上形成低溫硬化型高活性.氧化物光觸媒薄膜，故具有可防止因污物而對紅外信號收發所造成的阻礙。更且，本體的排氣通路7 6中所安裝的排氣濾器8 4 固可以丙烯基與P P的混紡不織布製成，惟在其表面上形成有樣本第2 1號低溫硬化型高活性氧化物光觸媒薄膜。排氣通風部7 6上設有多數開口部，排氣濾器8 4的空氣吐出面上由於自此開口部照射室內照明與太陽光等，故亦淨化濾器表面。且藉由使覆於本體上部的罩蓋5 2、罩蓋5 3、格子罩蓋5 4與手柄部5 5等的部件透明亦可令外部光線到達內部，集塵室6 2內部的濾紙7 9與輔助濾片7 9的濾片纖維表面上若形成有本發明之低溫硬化型高活性氧化物光觸媒薄膜，亦可獲得抗菌效果與除臭效果。 (實施例5 ) 茲根據第8圖就本發明第5實施例之衣物乾燥機加以說明。第8圖係衣物乾燥機之本體剖視圖。8 5係外框， 8 6係開閉蓋，8 7係旋轉圓筒，8 8係熱源，8 9係排本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） (請先閱讀背面之注意事項再填寫本頁)-ϋ ϋ B_i_i n I: OJV · ϋ n eaMm if —mmm 11 —a— I This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -24- Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printed 482694 A7 ___ B7 V. Description of the invention (22) As soon as the injury is caused, cracks and other damage will occur. In order to prevent this, a conventional UV-curing acrylic resin or the like is applied to ensure the surface hardness. However, according to the present invention, T i02 and The film hardness of SiO2, which is used as a bonding agent, is harder than ABS and has a pencil hardness of 2H to 4H. Therefore, when used in these exterior parts, it has the effect of not being easily scratched by scratches, etc. Antifouling effect, and inhibition of microbial growth. In particular, the handle portion 67 is a hand-contacted component, and bacteria are prone to multiply by adhered body fats such as sweat as nutrients. The molding resin is mixed with conventional antibacterial agents such as imidazolyl-based and thiazoline-based antibacterial agents. Although copper-based, lead-based, and silver-based antibacterial agents can obtain antibacterial effects, such treatment is not required. In addition, since the suction mouth portion and the wheel portion may slide or rotate, if the sweeper is used in a dry environment, it is liable to be charged with static electricity, and most of the fibers and dust such as fleece will adhere to the surface of the aforementioned items. In order to prevent such situations, conventional surfactants are mixed with hydrophilic polymers such as polyamides and polyethylene glycols in molding resins to prevent the reduction of surface resistance. However, the present invention can reduce low-temperature hardening. Type high active oxide photocatalyst film has a high resistance, so even if it is an ABS molding resin with a high resistance, the effect of preventing the adhesion of dust and the like can be obtained. The manual operation part 6 8 is mounted on the handle part 6 7. A control board for electronic components is fixedly mounted on the back of the manual operation part 6 8. However, if there is static electricity near the manual operation part 6 8, control will be induced. The wrong operation of the substrate, and the paper size of the present invention is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) (Please read the precautions on the back before filling this page) · 1 · — · ϋ · ϋ ϋ 1 ° ϋ 1 ° 4 exposure IIII a · * aw stupid -25- 482694 A7 B7 V. Description of the invention (23) The static electricity prevention effect can not only prevent dusts from adhering, but also prevent malfunction of the control board. In addition, the infrared signal receiving portion 69 provided on the same manual operation portion 6 8 and the infrared receiving portion 5 9 of the cleaner body 1 are made of transparent AS resin, as in the case of the fan in the foregoing embodiment. Since a low-temperature-curable, highly active, oxide photocatalyst film is formed on the surface, it has the advantage of preventing obstruction to infrared signal transmission and reception due to dirt. In addition, the exhaust filter 8 4 installed in the exhaust passage 7 6 of the main body can be made of a blended non-woven fabric of acrylic and PP, but a sample No. 21 low-temperature hardening type highly active oxide is formed on the surface. Photocatalyst film. The exhaust ventilation section 76 is provided with a large number of openings. Since the air discharge surface of the exhaust filter 84 is irradiated with indoor lighting, sunlight, etc. from this opening, the filter surface is also purified. And by making the cover 5 2, the cover 5 3, the grid cover 5 4 and the handle part 5 5 covering the upper part of the body transparent, the external light can reach the inside, and the filter paper 7 inside the dust collection chamber 6 2 9 and auxiliary filter 7 If the low-temperature-curable high-active oxide photocatalyst film of the present invention is formed on the surface of the filter fiber, the antibacterial effect and deodorizing effect can also be obtained. (Embodiment 5) A laundry dryer according to a fifth embodiment of the present invention will be described with reference to FIG. Fig. 8 is a sectional view of the body of the clothes dryer. 8 5 series frame, 8 6 series opening and closing cover, 8 7 series rotating cylinder, 8 8 series heat source, 8 9 series. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 public love) (please first (Read the notes on the back and fill out this page)

· ϋ n ΛΜ9 I ί I mmmmf 一 · an —Bi n ϋ a— n —^i I 參· -26- 482694 A7 B7 五、發明說明（24 ) 氣口、 90係兩翼扇，9丄係扇框，92係產生動力的馬達，9 3係將此馬達9 2的動力傳達於該兩翼扇9 0的輪帶，94係將此馬達92的動力傳達於該兩翼扇90的環帶，9 5係第1氣密毡墊圈，係第2氣密毡墊圈， 9 7係隔板，9 8係將排自該扇框9 1的循環風導至.該熱源8 8的循環導管，9 9係紗布過濾.裝置，1 〇〇係將該扇框9 1固定於該外框8 5的F D橫樑，1 0 1係安裝有軸承1 0 2的安裝鏈，該旋轉鼓輪8 7藉軸承1 〇 2以自由旋轉方式滑動支持。該旋轉鼓輪8 7藉由馬達9 2的驅動力經輪帶9 3傳達而與兩翼扇9 〇共同旋轉。由於此種旋轉，故在攪拌衣物同時發生循環風（實線箭頭），此循環風在通過熱源8 8之際，進入旋轉圓筒8 7內，將衣物的水份蒸發乾燥。此後，循環風由兩翼扇9 〇，經循環導管98內，送至熱源88,再度加熱而重覆進行衣物的乾燥。開閉蓋8 6的內側安裝附接有螢光管1 〇 3的照明器具1 0 4。吸收衝擊的緩衝材1 〇 5沿此旋轉圓筒8 7的內周面貼附。緩衝材1 〇 5由P P發泡體製成。本實施例的旋轉圓筒8 7的內面零件係照射照明器具的光的零件，緩衝材1 0 5、紗布過濾裝置9 9、開閉蓋 86內面等零件係由ABS及PP樹脂製成，其表面上形成有樣本第8 6號低溫硬化型高活性氧化物光觸媒薄膜。在對象物品的表面上形成有機矽烷偶合劑的皮膜後，形成第1層，形成此膜後，形成含有樣本第8 6號A T 0的低溫硬化型高活性氧化物光觸媒第2層。 -27· (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 五、發明說明（25) (請先閱讀背面之注意事項再填寫本頁) 照明器具可在乾燥動作中，或與乾燥動作無關，獨立作動，隨意點燈，若照射螢光管1 0 3的光，即有將上述零件表面所附著有機物與接觸空氣中所含惡臭物質有效氧化分解而抑制微生物繁殖以及除臭的效果。爲了在乾燥動作中旋轉衣物，由於光並未充份遍.滿，故乾燥動作終了後進行一定時間的點燈以淨化旋轉圓筒 8 7內部的動作程序，將更具效果。且外框1係鍍亞鉛鋼板製成，其外面塗覆環氧樹脂粉體。於此塗覆表面上形成含樣本第8 6號ΑΤΟ的低溫硬化型高活性氧化物光觸媒薄膜。開閉蓋8 6的外表可爲P S樹脂射出成形體，於此表面上亦形成有含樣本第8 6號A Τ 0的低溫硬化型高活性氧化物光觸媒薄膜。外框8 5與開閉蓋等外裝零件外面的光觸媒薄膜效果與前述實施例1 - 4外裝零件的情形一樣，具有以室內光充份防污、抗菌等效果。 (實施例6 ) 經濟部智慧財4局員工消費合作社印製茲根據第9、 1 0、 1 1圖說明本發明第6實施例之餐具乾燥機。第9圖係餐具乾燥機外觀斜視圖，第1 0圖係排氣口 1 2 8附近的放大剖視圖，而第1 1圖則係本體剖視圖。本體1 0 6的內部以隔板1 0 9將隔板1 0 9上下分成乾燥室1 0 7與旋轉控制室1 0 8。旋轉控制室1 0 8 -28- 木紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 經濟部智慧財查笱8工消費合作达印製五、發明說明（26) 中配設有控制機1 1 8，介於吸氣口 1 1 7與加熱送m組件1 1 4之間，此吸氣口 1 1 7配設有風扇馬達1 1 0、送風扇1 1 1、外殼1 1 2與加熱機1 1 3所構成的送出乾燥空氣用的加熱送風阻件1 1 4以導管1 1 5與此乾燥室1 0 7連接的吸氣濾器1 1 6。且乾燥室1 〇 7內.部上下配置有餐具收納用上籃1 1 9與下.籃1 2 0 °可自由傾斜於扉1 2 1下部而裝載於與鉸鏈1 2 2連結的可動軌 1 2 5上的盛水皿1 2 4上配設有該下籃1 2 0 °同樣地，上籃1 1 9亦配設於可動軌1 2 3上。可動軌1 2 3、 1 2 5配置成可在自由旋轉設在乾燥室1 〇 7側壁的滾輪 (未圖示）上前後移動，藉由將扉1 2 1的手把1 2 6拉向面前，自乾燥室107將下籃120的前端部拉出，從而將上籃1 1 9拉出外部。面板1 2 7上所設排氣口 1 2 8成格子狀並具有排氣濾片1 2 9。本體1 0 6的隔板1 0 9上所設開口部1 3 0與排氣導管1 3 1與乾燥室 1 0 7連接。溫度檢測機1 3 2配置在不易受外氣溫度影響的排氣導管1 3 1內。吸氣口 1 1 7係P P射出成形品。吸氣濾片1 1 6係尼龍製網片，其表面上形成有後述表7所示樣本第9 1號低溫硬化型高活性氧化物光觸媒薄膜。尼龍製網片在紫外線照射處理後形成含樣本第9 1號銀的低溫硬化型高活性氧化物光觸媒薄膜。由於室內照明光線照射在吸氣濾片1 1 6的表面上，故所附著有機物與帶入空氣中的惡臭物質會氧化分解。排 (請先閱讀背面之注意事項再填寫本頁)· Ϋ n ΛΜ9 I ί I mmmmf a · an —Bi n ϋ a— n — ^ i I ref. -26- 482694 A7 B7 V. Description of the invention (24) Air port, 90 series two-wing fan, 9 丄 series fan frame, 92 series power generating motor, 9 3 series transmits the power of this motor 9 2 to the belts of the two wing fans 90, 94 series transmits the power of this motor 92 to the endless belts of the two wing fans 90, 9 5 series 1 airtight gasket, 2nd airtight gasket, 9 7 series partition, 9 8 series will guide the circulating air exhausted from the fan frame 9 1 to the circulation duct of the heat source 8 8, 9 9 series gauze filter The device, 100, is a FD beam that fixes the fan frame 91 to the outer frame 85, 101 is a mounting chain with a bearing 102, and the rotating drum 8 7 is supported by a bearing 102. Free rotation mode sliding support. The rotating drum 8 7 is transmitted by the driving force of the motor 92 through the belt 93, and rotates together with the two-wing fan 90. Due to this rotation, a circulating wind (solid line arrow) occurs at the same time as the clothes are stirred. When the circulating air passes through the heat source 88, it enters the rotating cylinder 88 to evaporate and dry the moisture of the clothes. After that, the circulating air is sent from the two-wing fan 90 to the heat source 88 through the circulation duct 98, and is heated again to dry the clothes repeatedly. An illuminator 104 having a fluorescent tube 103 attached thereto is installed inside the opening-closing cover 86. The shock absorbing cushioning material 105 is attached along the inner peripheral surface of the rotating cylinder 87. The buffer material 105 is made of PP foam. The inner surface parts of the rotating cylinder 8 7 in this embodiment are parts that illuminate the light of the lighting fixture. The cushioning material 105, the gauze filter device 9, and the inner surface of the opening and closing cover 86 are made of ABS and PP resin. Sample No. 86 and No. 6 low temperature hardening type highly active oxide photocatalyst film was formed on the surface. A film of an organosilane coupling agent was formed on the surface of the target article, and then a first layer was formed. After this film was formed, a second layer of a low-temperature hardening type highly active oxide photocatalyst containing sample No. 86 A T 0 was formed. -27 · (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 482694 A7 B7 V. Description of the invention (25) (Please read the back first Please note this page before filling in this page.) The lighting equipment can be operated independently during the drying action or has nothing to do with the drying action. It can be lighted at will. The odorous substances contained in the air are effectively oxidatively decomposed to inhibit the growth of microorganisms and deodorize. In order to rotate the clothes during the drying operation, since the light is not full and full, it is more effective to light the interior of the rotating cylinder 8 7 by lighting a certain time after the drying operation is finished. The outer frame 1 is made of lead-plated steel sheet, and the outer surface is coated with epoxy powder. A low-temperature hardened highly active oxide photocatalyst film containing sample No. 86 ATO was formed on the coated surface. The appearance of the opening and closing cover 86 may be a PS resin injection molded body, and a low-temperature hardening type highly active oxide photocatalyst film containing a sample No. 86 ATO is also formed on this surface. The effect of the photocatalyst film on the outer frame 85 and the exterior parts such as the opening and closing cover is the same as in the case of the exterior parts of the foregoing embodiments 1-4, and it has effects such as sufficient antifouling and antibacterial effect with indoor light. (Embodiment 6) Printed by the Consumer Cooperative of the 4th Bureau of Wisdom and Finance of the Ministry of Economy The dishwasher dryer according to the sixth embodiment of the present invention will be described with reference to FIGS. 9, 10, and 11. Fig. 9 is a perspective view of the appearance of the dish dryer, Fig. 10 is an enlarged sectional view near the exhaust port 1 2 8 and Fig. 11 is a sectional view of the main body. Inside the main body 106, a partition 1109 is divided up and down into a drying chamber 107 and a rotation control chamber 108 by a partition 1009. Rotary control room 1 0 8 -28- Wood paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 482694 A7 B7 Ministry of Economic Affairs, Smart Finance and Inspection, 8 Industrial and Consumer Cooperation Printing, V. Invention Description (26 ) Is equipped with a control machine 1 1 8 between the suction port 1 1 7 and the heating supply module 1 1 4. This suction port 1 1 7 is equipped with a fan motor 1 1 0 and a fan 1 1 1. The heating air supply resistance 1 1 4 for sending dry air composed of the casing 1 1 2 and the heater 1 1 3 is a suction filter 1 1 6 connected to this drying room 1 7 by a duct 1 1 5. In the drying room 107, upper and lower baskets 1 1 9 and lower baskets for tableware storage are arranged up and down. The basket 1 2 0 ° can be tilted freely on the lower part 1 2 1 and mounted on the movable rail 1 connected to the hinge 1 2 2 The lower basket 1 2 0 is provided on the water dish 1 2 4 on 2 5. Similarly, the upper basket 1 1 9 is also provided on the movable rail 1 2 3. The movable rails 1 2 3, 1 2 5 are arranged so as to be able to move back and forth on rollers (not shown) provided freely on the side wall of the drying chamber 107, and by pulling the hand 1 2 6 toward the front The front end of the lower basket 120 is pulled out from the drying chamber 107, so that the upper basket 1 1 9 is pulled out. The exhaust ports 1 2 8 provided on the panel 1 2 7 are in a grid shape and have exhaust filters 1 2 9. The opening portion 1 30 provided on the partition plate 1 0 9 of the main body 10 is connected to the exhaust duct 1 31 and the drying chamber 1 0 7. The temperature detector 1 3 2 is arranged in the exhaust duct 1 3 1 which is not easily affected by the outside air temperature. Suction port 1 1 7 Series P P injection molding. The suction filter 1 1 6 is a nylon mesh sheet, and a sample No. 91 shown in Table 7 described below is formed on the surface of a low-temperature hardening type highly active oxide photocatalyst film. A nylon mesh sheet was treated with ultraviolet radiation to form a low-temperature-curable highly active oxide photocatalyst film containing sample No. 91 silver. Since the indoor illumination light is irradiated on the surface of the suction filter 1 16, the attached organic substances and the malodorous substances brought into the air will be oxidized and decomposed. Row (Please read the notes on the back before filling this page)

·_1 1 1 1 «i_i n .1 · ϋ 1 i···· 1 n 1-1 I 參_ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -29 - 482694 A7 B7 五、發明說明（27 ) (請先閱讀背面之注意事項再填寫本頁) 氣口 1 2 8與排氣濾片1 2 9 —樣均形成有樣本第9 1號低溫硬化型高活性氧化物光觸媒薄膜。排氣口 1 2 8周邊所排出的濕氣易於固凝結成潮濕狀態而供黴菌與細菌類繁殖，惟使用本發明分解效率高的光觸媒，即可以室內光抑制此等微生物的繁殖。樣本第9 1號的處理最好具有·組成物中所含銀本身的抗菌作用。由於抗菌效果高，故亦宜於混合含銀的沸石與磷灰石等陶瓷粒子。經濟部智慧財產局員工消費合泎让印髮且附有螢光管1 3 3的照明器具1 3 4安裝於乾燥室 1 0 7內部。照明功能並不限於扉1 2 1開啓之際點燈而確認內部餐具乾燥程度的照明固有功能，亦可活用來作爲淨化乾燥室1 0 7內部的功能。亦即，藉由乾燥室1 0 7 內部零件的表面上形成光觸媒薄膜，獲得光照射部份的抗菌與防污效果。本實施例的上籃1 1 9與下籃1 2 0係將聚酰胺系粉體樹脂燒結塗覆於鐵製框上而構成者，此塗覆面上紫外線照射處理後形成含樣本第9 2號的銅的低溫高活性氧化物光觸媒薄膜。此上、下籃係與餐具類直接接觸的零件，固有必要使其淸潔，惟藉光觸媒效果由於可獲得表面防污與微生物繁殖抑制效果而保持淸潔。銅與銀一樣，由於其本身具有抗菌作用，故抗菌效果極佳。與實施例5的衣物乾燥機情形一樣，由於乾燥動作中，餐具會形成陰影，光線未能遍照，故使用乾燥動作終了後，點燈一定時間，將乾燥室1 〇 7內部淨化的動作程式，將更具效果。且，扉1 2 1固爲A B S樹脂成形品，惟其表面上形 -30- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 五、發明說明（28) 成有含樣本第8 6號的A T〇的低溫硬化型高活性氧化物光觸媒薄膜。 (請先閱讀背面之注意事項再填寫本頁) 此扉1 2 1表面上光觸媒薄膜的效果與前述實施例1 - 5的外裝部件情形一樣，均可以室內光充份防污、抗菌等。 . (實施例7 ) 茲根據第1 2、 1 3與1 4圖就本發明第7實施例之餐具洗濯機加以說明。第1 2圖係餐具洗濯機之外觀斜視圖，第1 3與1 4 圖則係餐具洗濯機之剖視圖。經濟部智慧財產局員工消費全泎社印裂餐具收納槽1 3 6配置在外框1 3 5的內部，設有開閉其前面開口的門1 3 7的餐具收納槽1 3 6側壁下部設有段部1 3 8，此段部· 1 3 8上裝卸自如地配置有餐具收納用下籃1 3 9。泵1 4 0配置於餐具收納槽1 3 6的底部外側。此泵1 4 0具有泵馬達1 4 1。旋轉下臂噴嘴 1 4 2配置於餐具收納用下籃1 3 9的正下方。下臂噴嘴 1 4 2上面設有複數小孔1 4 3。將送自泵1 4 0的洗淨水送至上臂噴嘴1 4 4的文丘里管1 4 5配置在餐具收納用下籃1 3 9中。此上臂噴嘴1 4 4以中央爲支點旋轉於餐具收納用上籃1 4 6正下方。上臂噴嘴1 4 4上面設有複數小孔1 4 7。餐具收納槽1 3 6外的底部或背部配置有加熱器1 4 8。配置.包覆加熱器1 4 8的加熱器罩蓋 i 4 9。給水電磁閥1 5 0配置在餐具收納槽1 3 6外側 -31 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 五、發明說明（29) (請先閱讀背面之注意事項再填寫本頁) 面上。餐具收納槽1 3 6外面上部配置有排氣導管1 5 1 ，連結於排氣口 1 5 2。門1 3 7的外側上部上設有控制面板。餐具收納槽1 3 6的底部外側上配置有排水泵 1 5 4及送風組件1 5 5。經濟部智慧財產局員工消費合作社印製進行洗淨動作時，由給水電磁閥1 5 0供給水，.驅動泵1 4 0，在朝下臂式噴嘴4 2供給加壓水同時，使加熱器1 4 8通電，令水溫上昇。在水自孔1 4 3噴出同時，若經由文丘里管1 4 5送至上壁式噴嘴4 4 ,則亦自孔 1 4 7噴出。如此，一面旋轉上下臂式噴嘴，一面遍灑溫水於餐具收納籃1 4 6內的餐具而將污漬除去。洗淨動作終了後，使排水泵1 5 4通電，將污水排出，而後則回過頭重覆上述相同動作，將內部污漬滌除。最後洗濯動作終了的話，即換過來進行烘乾動作。使送風組件1 5 5通電，令送風葉片1 5 6旋轉，經由配置於餐具收納籃1 3 6 底部的送風導管1 5 7、加熱器，朝餐具收納籃1 3 6內送風。此時，加熱器1 4 8進行通-斷控制定時通電，使冷風變成溫風。藉此溫風，將內部水滴與剩水乃至於附著於餐具上的水滴蒸發，經由排氣導管1 5 1 ,自排氣口 1 5 2排出機外。排氣口 1 5 2固爲A B S樹脂製品，惟本實施例與前述餐具烘乾機相同，由含有樣本第9 1號的銀的低溫硬化型高活性氧化物光觸媒薄膜形成。於排氣口周邊，排出的濕氣固然易於凝結而成潮濕狀態，以致黴菌與細菌會繁殖，惟使用本發明分解效率高的光觸媒，以室內光即可有效 -32- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 Α7 Β7 五、發明說明（30) 抑制微生物的繁殖。餐具收納槽1 3 6內部安裝具有螢光燈管1 5 8的照明器具1 5 9。照明功能並不限於所謂槽門1 3 7打開之際點燈以確認內部餐具的洗淨與乾燥度合適的原來照明功能，亦可在功能上活用來使餐具收納槽1 3 6淸淨。.亦即，藉由形成光觸媒薄膜於餐具收納槽.1 3 6的內部部件表面上，可獲得光照射部份的抗菌與防污效果。本實施例的餐具收納用上籃1 4 6、餐具收納用下籃 1 3 9係在鐵架上燒結聚酰胺系粉體樹脂塗覆構成者，於此塗覆面的表面上形成含樣本第9 2號的銅的低溫硬化型高活性氧化物光觸媒薄膜。此上下籃固係與餐具直接接觸的部件，必須保持淸潔，惟由於光觸媒效果，故可獲得表面防污與抑制微生物繁殖的效果，保持淸潔。再者在餐具洗淨機，雖然給水積至一定之標準時，會進行洗淨及洗濯動作，不過此時在水面部分易積存油類等之污物，在此吃水線部分會有積存污物之缺點。因在餐具收納槽1 3 6及臂式噴嘴1 4 4、 1 4 2及文丘里管1 4 5等之吃水部分形成有本發明之光觸媒，所以變的易分解且易除去污物，不會發生上述般之污物的積存。就照明器具1 5 9的光所照射的其他部件而言，有上臂式噴嘴144、下臂式噴嘴142、文丘里管145等，此等部件使用P P樹脂射出成形品與S U S可塑變形品。於此等部件表面經過電暈放電處理後，僅以S ΐί〇2的薄 (請先閱讀背面之注意事項再填寫本頁) 裝· _1 1 1 1 «i_i n .1 · ϋ 1 i ···· 1 n 1-1 I _ _ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -29-482694 A7 B7 V. Description of the invention (27) (Please read the precautions on the back before filling out this page) Port 1 2 8 and exhaust filter 1 2 9 —Sample No. 9 No. 1 low-temperature hardening type highly active oxide Photocatalyst film. The exhaust gas around the exhaust port 1 2 8 is easy to condense into a humid state for the propagation of molds and bacteria. However, the use of the photocatalyst with high decomposition efficiency of the present invention can inhibit the reproduction of these microorganisms by indoor light. It is desirable that the treatment of Sample No. 91 has the antibacterial effect of silver contained in the composition. Because of its high antibacterial effect, it is also suitable to mix silver-containing zeolites with ceramic particles such as apatite. The employees of the Intellectual Property Bureau of the Ministry of Economic Affairs have combined consumption and printing, and lighting equipment with fluorescent tubes 1 3 3 is installed inside the drying room 107. The lighting function is not limited to the lighting inherent function of confirming the dryness of the internal tableware when the lamp is turned on when it is turned on. It can also be used as a function to purify the interior of the drying room 107. That is, by forming a photocatalyst film on the surface of the internal parts of the drying chamber 107, the antibacterial and antifouling effects of the light-irradiated part are obtained. The upper basket 1 1 9 and the lower basket 1 2 0 of this embodiment are formed by sintering and coating a polyamide powder resin on an iron frame. This coated surface is treated with ultraviolet rays to form a sample 9 2 Copper Low Temperature Highly Active Oxide Photocatalyst Film. The upper and lower baskets are in direct contact with tableware, which is inherently necessary to be clean. However, the photocatalyst effect can be used to maintain cleanliness due to the effect of antifouling on the surface and the effect of inhibiting the growth of microorganisms. Copper, like silver, has an excellent antibacterial effect because of its antibacterial effect. As in the case of the clothes dryer of Example 5, since the tableware will form a shadow during the drying operation and the light cannot be illuminated, so after using the drying operation, turn on the light for a certain period of time to clean the interior of the drying room 107. Will be more effective. Moreover, 扉 1 2 1 is solid ABS resin molded product, but the shape on the surface is -30- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 482694 A7 B7 V. Description of the invention (28) A low-temperature hardening type highly active oxide photocatalyst film containing AT0 of sample No. 86 is available. (Please read the precautions on the back before filling in this page.) The effect of the photocatalyst film on the surface of 扉 1 2 1 is the same as that of the exterior components of the previous examples 1-5, and it can be fully anti-fouling, antibacterial, etc., indoor light. (Embodiment 7) A dishwasher according to a seventh embodiment of the present invention will be described with reference to FIGS. 1, 2, 3, and 14. Fig. 12 is a perspective view of the appearance of the dishwasher, and Figs. 13 and 14 are sectional views of the dishwasher. Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Products, Printed Tableware Storage Slots 1 3 6 are arranged inside the outer frame 1 3 5 and are provided with doors that open and close the front openings 1 3 7 Tableware storage slots 1 3 6 There is a section on the lower part of the side wall The section 1 3 8 has a detachable basket 1 3 9 for tableware storage. The pump 140 is disposed outside the bottom of the dish storage tank 136. This pump 1 4 0 has a pump motor 1 4 1. The rotating lower arm nozzle 1 4 2 is disposed directly below the dish storage basket 1 3 9. The lower arm nozzle 1 4 2 is provided with a plurality of small holes 1 4 3. The washing water sent from the pump 1 4 0 was sent to the upper arm nozzle 1 4 4 and the venturi tube 1 4 5 was placed in the tableware storage lower basket 1 3 9. The upper arm nozzle 1 4 4 rotates directly under the center as a fulcrum 1 4 6 for the tableware storage basket. The upper arm nozzle 1 4 4 is provided with a plurality of small holes 1 4 7. A heater 1 4 8 is arranged at the bottom or back of the dish storage tank 1 3 6. Configuration. Heater cover i 4 9 covering heater 1 4 8. The water supply solenoid valve 1 50 is arranged on the outside of the tableware storage tank 1 3 6 -31-This paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 482694 A7 B7 V. Description of the invention (29) (please first Read the notes on the back and fill out this page). An exhaust duct 1 5 1 is arranged at the upper part of the outer surface of the dish storage tank 1 3 6 and is connected to the exhaust port 1 5 2. A control panel is provided on the upper outer side of the door 1 3 7. A drain pump 1 5 4 and an air supply component 1 5 5 are arranged on the outer side of the bottom of the dish storage tank 1 3 6. When printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs for cleaning operation, water is supplied by the water supply solenoid valve 150, and the pump 1 40 is driven, and the pressurized water is supplied to the lower arm nozzle 4 2 while the heater is activated. 1 4 8 Turn on the electricity to make the water temperature rise. When water is sprayed from the hole 1 4 3, if it is sent to the upper wall nozzle 4 4 through the venturi tube 1 4 5, it is also sprayed from the hole 1 4 7. In this way, while rotating the upper and lower arm type nozzles, warm water was sprayed on the tableware in the tableware storage basket 1 4 6 to remove stains. After the washing operation is completed, the drainage pump 154 is energized to discharge the sewage, and then the same operation is repeated to remove the internal stains. At the end of the washing operation, change to the drying operation. The air supply component 15 5 is energized, the air supply blades 15 6 are rotated, and the air is supplied into the dish storage basket 1 3 6 through the air supply duct 1 5 7 and the heater arranged at the bottom of the dish storage basket 1 3 6. At this time, the heater 1 4 8 is switched on and off at regular time, so that the cold air becomes warm air. With this warm air, the internal water droplets and the remaining water or even the water droplets attached to the tableware are evaporated, and discharged out of the machine through the exhaust duct 1 5 1 and the exhaust port 1 5 2. The exhaust port 1 52 is made of A B S resin, but this embodiment is the same as the aforementioned dish dryer, and is formed of a low-temperature hardening type highly active oxide photocatalyst film containing silver of sample No. 91. Around the exhaust port, the discharged moisture is easy to condense into a humid state, so that mold and bacteria will multiply, but using the photocatalyst with high decomposition efficiency of the present invention can be effective with indoor light -32- This paper size is applicable to China Standard (CNS) A4 specification (210 X 297 mm) 482694 A7 B7 V. Description of the invention (30) Inhibit the reproduction of microorganisms. The tableware storage tank 1 3 6 is provided with a lighting device 1 5 9 having a fluorescent tube 1 5 8 therein. The lighting function is not limited to the original lighting function when the so-called tank door 1 37 is turned on to confirm the proper washing and drying of the internal tableware. It can also be used to clean the tableware storage tank 1 3 6. That is, by forming a photocatalyst film on the surface of the internal parts of the tableware storage tank, the antibacterial and antifouling effects of the light-irradiated part can be obtained. The upper basket 1 4 6 for tableware storage and the lower basket 1 3 9 for tableware storage in this embodiment are formed by sintering a polyamide powder resin coating composition on an iron frame, and a sample-containing ninth is formed on the surface of this coating surface. No. 2 copper low temperature hardening type highly active oxide photocatalyst film. The upper and lower baskets are solid parts that are in direct contact with the tableware and must be kept clean. However, due to the photocatalyst effect, the effect of anti-fouling on the surface and the inhibition of microbial proliferation can be obtained, keeping clean. Furthermore, in the tableware washing machine, although the feed water accumulates to a certain standard, washing and washing operations will be performed, but at this time, oil and other dirt are easy to accumulate on the water surface, and there will be dirt on the waterline. Disadvantages. The photocatalyst of the present invention is formed in the draft parts of the tableware storage tank 1 3 6 and the arm nozzles 1 4 4 and 1 4 2 and the venturi tube 1 4 5, so it becomes easy to decompose and it is easy to remove dirt, and it will not The accumulation of dirt as described above occurs. As for other parts illuminated by the light of the lighting device 159, there are an upper-arm nozzle 144, a lower-arm nozzle 142, and a venturi tube 145. These components use PP resin injection molded products and SUS plastic deformable products. After the surface of these parts has been treated with corona discharge, only use S ΐί〇2 thin (please read the precautions on the back before filling this page).

• I I I I ^1 ϋ ϋ 一 δ， 1· n ϋ ϋ ϋ ·_1 11 本纸張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -33- 482694 A7 B7 五、發明說明（31) (請先閱讀背面之注意事項再填寫本頁) 膜，亦即表1的樣本第1 2號爲底層來形成，此膜形成後，形成樣本第2 1號的低溫硬化型高活性氧化物光觸媒薄膜。就餐具收納槽1 3 6內部部件上形成光觸媒薄膜，附設照明器具1 5 9的餐具洗濯機特有的效果而言，具·有提高烘乾效率的效果。此效果在於，本.發明低溫硬化型高活性氧化物光觸媒薄膜基本材料T i 0 2、S i 0 2係沾水性極佳的材料，且即使附著自污漬餐具除去的油脂類等不與水調和的物質，由於藉照明器具1 5 9的光分解，故可常保高的沾水性。經濟部智慧財產局員工消費合作注印裂至於餐具洗濯動作，則在最終洗濯時將水溫提高到 6 0〜7 0 °C，固然在內部溫度提高後，藉送風動作將濕氣排出機外，惟餐具收納槽1 3 6內部殘留的水滴卻構成烘乾效率低下的原因。餐具收納槽1 3 6、上臂式噴嘴 1 4 4、下臂式噴嘴、文丘里管1 4 5等部件由於要求有極高耐水性，故多用排水性材料，通常其表面沾水性極差。沾水性差的材料表面上，水不會成膜狀擴展沾水狀態，而會呈高接觸角度的水滴狀附著。洗淨動作進行時，固然由於投入含有界面活性劑的洗濯劑，故降低洗淨水的表面張力，從而接觸角降低而成極佳沾濕狀態，惟最終洗濯時，洗濯水中幾乎不含洗濯劑成份，故水的表面張力非常高。因此在最終洗濯終了時，洗濯水成具有高接觸角的無數水滴狀附著在餐具收納槽1 3 6內部的各部件表面上。此種高接觸角水滴與薄膜狀擴展水膜情形相較，水量 -34- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 經贵部智慧时產咼員工消費合ftfi印說 A7 B7 五、發明說明（32 ) 極多，甚難烘乾。且水滴狀的水在烘乾時因係保持水滴狀縮小、烘乾，故在表面積亦縮小下，烘乾速度更慢，烘乾時間約需3倍。餐具固然以沾水性佳的玻璃、陶瓷器與木製品居多，可較快烘乾，惟若在餐具洗濯機本身沾有水滴狀態下終了，打開槽門1 3 7，在上、下餐具收納籃.拉出振動之下，水滴會掉落在餐具上，而發生烘乾餐具沾濕的不適當現象。餐具收納槽13 6、上臂式噴嘴144、下臂式噴嘴 1 4 2、文丘里管1 4 5等部件以P P模製品構成情形下，洗濯終了時的附著水滴水量約3 0 g (克），相對地，在根據本發明形成光觸媒膜情形下，附著的水量減低爲約 5 g。且由於本發明低溫硬化型高活性氧化物光觸媒薄膜具有以光活性高的照明器1 5 9的光分解所附著油脂的作用，故無油脂附著以致沾水性降低的現象。與實施例6的餐具烘乾機情形一樣，由烘乾動作中餐具擋住光線，光線未充份遍照，故使用烘乾動作終了後定時點燈來使餐具收納槽1 3 6內部淸淨的動作程序，更具效果。且槽門1 3 7固可以P P樹脂模製品製成，惟其表面經過電暈放電處理後，形成樣本第1 2號來作爲底層，此膜形成後，形成樣本第2 1號的低溫硬化型高活性氧化物光觸媒薄膜。此槽門1 3 7的表面上光觸媒薄膜的效果與前述實施例1〜6的外裝部件情形一樣，可以室內光獲得充份防污 (請先閱讀背面之注意事項再填寫本頁)• IIII ^ 1 ϋ ϋ 1 δ, 1 · n ϋ ϋ ϋ · _1 11 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) -33- 482694 A7 B7 V. Description of the invention (31 ) (Please read the precautions on the back before filling this page) The film, that is, the sample No. 12 of Table 1 is formed as the bottom layer. After this film is formed, the low-temperature hardening type high active oxide of sample No. 21 is formed. Photocatalyst film. The special effects of forming a photocatalyst film on the internal parts of the dish storage tank 1 3 6 and the dish washing machine with the lighting device 1 5 9 have the effect of improving drying efficiency. The effect is that the base material T i 0 2, S i 0 2 of the low-temperature hardening type highly active oxide photocatalyst film of the present invention is a material with excellent water absorption, and even if oils and fats removed from soiled dishes are not mixed with water, Due to the photodecomposition of the lighting device 159, it can always maintain a high degree of water absorption. The consumption cooperation of employees of the Intellectual Property Bureau of the Ministry of Economic Affairs has shown that when the tableware is washed, the water temperature is raised to 60 ~ 70 ° C during the final washing. Although the internal temperature is increased, the air is sent out to remove moisture from the machine. However, the remaining water droplets inside the tableware storage tank 1 3 6 constitute the cause of the low drying efficiency. Tableware storage tanks 1 3 6, upper arm nozzles 1 4 4, lower arm nozzles, venturi tubes 1 4 5 and other components require extremely high water resistance, so multi-purpose drainage materials are usually used, and the surface is usually poorly wetted. On the surface of a material with poor wettability, water will not expand into a film-like wetted state, but will adhere as a drop of water with a high contact angle. When the washing operation is performed, although the detergent containing a surfactant is added, the surface tension of the washing water is reduced, so that the contact angle is reduced to an excellent wet state. However, in the final washing, the washing water contains almost no detergent Ingredients, so the surface tension of water is very high. Therefore, at the end of the final washing, the washing water adheres to the surface of each component inside the tableware storage tank 1 3 6 in countless drops with a high contact angle. This kind of high contact angle water droplets is compared with the case of a thin film-like extended water film. The amount of water is -34- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 482694 ftfi prints A7 B7 V. Invention Description (32) There are too many and it is very difficult to dry. In addition, the droplet-shaped water keeps the droplet shape shrinking and drying during drying, so the surface area is also reduced, the drying speed is slower, and the drying time takes about 3 times. Of course, the tableware is mostly glass, ceramics and wooden products with good water absorption, which can be dried quickly. However, if the dishwasher itself is wet with water droplets, open the door 1 3 7 and place the upper and lower tableware storage baskets. When the vibration is pulled out, water droplets may fall on the tableware, and an inappropriate phenomenon of drying the tableware may occur. Tableware storage tank 13 6, upper arm nozzle 144, lower arm nozzle 1 4 2, Venturi tube 1 4 5 and other components are made of PP molded products, the amount of water droplets attached at the end of washing is about 30 g (g), In contrast, in the case where a photocatalyst film is formed according to the present invention, the amount of attached water is reduced to about 5 g. In addition, since the low-temperature hardening type highly active oxide photocatalyst film of the present invention has the function of decomposing the oil and fat attached by the photodegradation of the illuminator 159 with high light activity, there is no phenomenon that the oil and oil adhere to each other and the wettability is reduced. As in the case of the tableware dryer of Embodiment 6, the tableware blocks the light during the drying operation, and the light is not fully illuminated, so the timer is used to clean the interior of the tableware storage tank 1 3 6 after the drying operation is completed. Program, more effective. And the slot door 1 3 7 can be made of PP resin molding, but after the surface is treated with corona discharge, sample No. 12 is used as the bottom layer. After this film is formed, sample No. 21 is low-temperature hardening type. Active oxide photocatalyst film. The effect of the photocatalyst film on the surface of this slot door 1 3 7 is the same as that of the exterior components of the foregoing embodiments 1 to 6, and it can be fully antifouling by indoor light (please read the precautions on the back before filling this page)

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -35- 482694 A7 ___B7 五、發明說明（33) 、抗菌等效果。 (請先閱讀背面之注意事項再填寫本頁) 本實施例固就安裝型餐具洗濯機加以說明，惟桌上型亦全然相同可獲得光觸媒薄膜的效果。於桌上型情形下，由於室內光照射在外裝部件的前面，故可有效形成光觸媒薄膜於側面與頂部的外壁面部件的表面上。 (實施例8 ) 茲以第1 5、 1 6圖就本發明實施例8的廚房渣滓處理機加以說明。第1 5圖顯示廚房渣滓處理機的外觀斜視圖式，第 1 6圖顯示本例剖視圖式。於框體1 6 0內部具有中央部份自由旋轉支持的攪拌翼1 6 1，於上部配置設有生渣滓投入口 1 6 3的處理槽 1 6 4,於其中置入培養基材1 6 5。培養基材1 6 5係以木質等微生物難以分解的纖維素爲主要成份的鋸木屑、稻殼、稻草截段等組成物，其各個顆粒具多孔性質的空隙，且粒徑複雜，於粒與粒間亦形成極大空隙。經濟部智慧財產局員工消費合作钍印裂於旋轉軸1 6 6上設有三片攪拌翼，以設於處理槽 1 6 4內的軸承1 6 7支持，另一方面突出的旋轉軸端部以驅動馬達與鏈等傳輸手段1 6 9保持適減速比予以連結。於處理槽1 6 4的上開口部1 7 0上，內蓋1 7 1可自由開關地設於上板1 7 2。復在處理槽1 6 4上部附近設置通風扇17 3、吸氣口 174與排氣口 17 5，藉通風扇173的旋轉，經排氣口 175，將處理槽164內所本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -36- 經濟部智慧財產局員工消費合泎fl印裂 482694 A7 B7 五、發明說明（34) 產生的分解氣體與水份排出機外。且吸氣口1 7 4與排氣口 1 7 5上分別配設適當網目狀的濾淸器。另設有吸氣口 17 4的開閉蓋176，配置成藉由框體1 6 0上所安裝電磁開關1 7 7的在復動作來開閉吸热口 174。更且，於上板I?2上設有運轉用操作部· 1 7 8，藉其操作，控制機1 7 9作動，使廚房渣滓處理機運轉。培養基材1 6 5經數月後其空隙部爲分解物寺塡滿而減少空隙率，由於無法處理生渣滓，故須換裝。因此，於處理槽1 6 4底部構成排出口 1 8 0與排出通道1 8 1。藉由將落入排出通路1 8 1的培養基材1 6 5掏出，即可將其取出框體1 6 0外。至於處理槽1 6 4的培養基材1 6 5上空隙部份的空氣，其濕氣與分解氣體含有大量的三甲基胺、甲基硫醇、氨、硫化氫等惡臭強度大的物質。由於此種惡臭很強，故習知廚房渣滓處理機無法設置在廚房內，且設在集合住宅的陽台亦有向周邊地帶漏出臭氣的問題。至於習知除臭機構，固有使用錳系熱分解觸媒的種種提案，惟其效果與壽命均不充份。本實施例於排氣口 1 7 5部分設有排氣濾淸器1 8 2 、1 8 3，於其間隙配置有紫外線燈1 8 4。排氣濾淸器 1 8 2以沸石爲主要成份，排氣濾淸器1 8 3以活性炭爲主要成份，二者均爲蜂窩式構造，由紫外線燈1 8 4所發出的紫外線照射到蜂窩式構造的內部深處。於此排氣濾淸本紙張义度適用中國國家標準（CNS)A4規格（210 x 297公釐） -37- (請先閱讀背面之注意事項再填寫本頁)This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) -35- 482694 A7 ___B7 V. Description of the invention (33), antibacterial and other effects. (Please read the precautions on the back before filling this page.) This example describes the installation type dishwasher. However, the effect of the photocatalyst film is the same for the table type. In the case of a desktop type, since indoor light is radiated to the front of the exterior member, a photocatalyst film can be effectively formed on the surface of the side wall and the top wall of the outer wall member. (Embodiment 8) The kitchen waste processor of Embodiment 8 of the present invention will be described with reference to Figs. Figure 15 shows a perspective view of the appearance of a kitchen dregs processor, and Figure 16 shows a sectional view of this example. Inside the frame body 1 60, there is a stirring blade 1 6 1 which is freely rotatable at the central part, and a processing tank 1 6 3 with a dross slag insertion port 1 6 3 is disposed on the upper part. A culture medium 1 6 5 is placed therein. . The culture substrate 1 6 5 is a composition consisting of sawdust, rice husks, and straw segments containing cellulose, which is difficult to be decomposed by microorganisms such as wood, as its main component. Each particle has porous voids, and the particle size is complex. There are also large voids formed between the grains. Consumption cooperation between employees of the Intellectual Property Bureau of the Ministry of Economic Affairs is printed on the rotating shaft 1 6 and is provided with three stirring wings supported by bearings 1 6 7 disposed in the processing tank 1 6 4. On the other hand, the protruding end of the rotating shaft is The driving motor and the transmission means, such as a chain, are connected at a proper reduction ratio. On the upper opening 170 of the processing tank 164, an inner cover 1 71 can be freely opened and closed on the upper plate 1 72. A ventilation fan 17 3 is installed near the upper part of the processing tank 1 6 4. The suction port 174 and the exhaust port 17 5 are adapted to the size of the paper in the processing tank 164 through the exhaust port 175 through the rotation of the ventilation fan 173. National Standard (CNS) A4 Specification (210 X 297 mm) -36- Consumption of Employees of Intellectual Property Bureau of the Ministry of Economy fl 482694 A7 B7 V. Description of Invention (34) The decomposed gas and water produced are discharged outside the machine. In addition, an appropriate mesh-shaped filter is provided on the suction port 1 74 and the exhaust port 1 7 5 respectively. An opening / closing cover 176 is also provided for the air intake port 174, and is configured to open and close the heat intake port 174 by the return operation of the electromagnetic switch 1 7 7 mounted on the frame body 160. Furthermore, an operation operation unit 1 78 is provided on the upper plate I-2, and by this operation, the control unit 17 is operated to operate the kitchen dregs processor. After several months of cultivation of the substrate 1 65, the voids are filled with the decomposition products and the void ratio is reduced. Since the dregs cannot be processed, they must be replaced. Therefore, a discharge port 1 80 and a discharge channel 181 are formed at the bottom of the processing tank 1 64. By pulling out the culture medium 165 falling into the discharge path 181, it can be taken out of the housing 160. As for the air in the void portion of the culture medium 1 65 in the treatment tank 1 64, the moisture and the decomposition gas contain a large amount of substances with strong malodorous strength such as trimethylamine, methyl mercaptan, ammonia, and hydrogen sulfide. Due to the strong stench, it is known that the kitchen dregs processor cannot be installed in the kitchen, and the balcony provided in the apartment house also has a problem of leaking odor to the surrounding area. As for the conventional deodorizing mechanism, various proposals for the use of manganese-based thermal decomposition catalysts have been made, but their effects and life have been insufficient. In this embodiment, exhaust filters 1 8 2 and 1 8 3 are provided at the exhaust port 1 7 5, and an ultraviolet lamp 1 8 4 is disposed between the exhaust filters. The exhaust filter 1 8 2 contains zeolite as the main component, and the exhaust filter 1 8 3 contains activated carbon as the main component. Both of them have a honeycomb structure, and the honeycomb type is irradiated by ultraviolet rays emitted from the ultraviolet lamp 1 8 4. Deep inside the structure. The exhaust filter here applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) -37- (Please read the precautions on the back before filling this page)

482694 A7 _ B7 五、發明說明（35) 器18 2、 18 3的蜂窩狀構造內表面上形成有如表5所示樣本第6 2號的低溫硬化型高活性氧化物光觸媒薄膜。 (請先閱讀背面之注意事項再填寫本頁) 本發明低溫硬化型高活性氧化物光觸媒薄膜分解效率極高，於如前述實施例1〜7的有機物負荷較小的用途中，以室內照明器具的亮度級數，亦即波長2 5 0〜3.5 0 (納米）紫外光爲〇 · 〇〇]_〜〇 ·.〇 ImW (毫瓦）/ c rri (公分2 )亮度級數的照度，或裝載螢光燈與白熾燈的 0 · 〇 1〜〇 · 1 m W / c m2亮度級數的照度，固可分解，惟在本發明譬如氨濃度數p p m亮度級數的高負荷情形下，有必要配置紫外線產生手段。固然可使用水銀燈與金屬鹵素燈型式的紫外線燈，惟，根據本發明，由於其分解效率較習知氧化物觸媒高，故除臭效果較大，且紫外線強度與使用習知氧化物光觸媒情形相比，亦可較小。經濟部智慧財產局員工消費合作社印製由於渣滓的分解通常在投入後的1小時至8小時之間最爲活絡，故配合此時間來將紫外線燈1 8 4點燈的話，即可保持燈的壽命長度。排氣過濾器1 8 3以活性碳爲基劑，於臭热濃度低的時候完成此活性碳的臭氣吸著，由方令隨著吸著量增加吸著效率漸漸降低，故定時照射紫外線，將所吸著的惡臭物質分解，亦可使活性碳再生。且固然框體1 6 0可由塗裝鋼板製成，外蓋1 7 1可由PP樹脂射出成形品製成，惟其表面上塗覆聚氯乙烯有機塗膜，於此塗膜表面上形成樣本第21號低溫硬化型高活性氧化物光觸媒薄膜。 -38 - 本紙張尺度適用中國國家標準（CNS)A4規格（210x297公餐）經濟部智慧財轰局員工消費合泎ft印製 482694 A7 B7___ 五、發明說明（36 ) 此種框體1 6 0與外蓋1 7 1的表面上的光觸媒薄膜與前述實施例1 - 7的外裝部件情形一樣，具有可藉室內光充份防污、抗菌等的效果。特別是，由於在廚房渣滓處理機情形下處理生渣滓，而生渣滓所流出的汁液沾污此等外裝部件的機會極多，故本發明低溫硬化型高活性氧·化物光觸媒薄膜的防污效果極大。廚房渣.滓處理機置於屋外情形下，太陽光照射在此等外部部件上。太陽光的波長 250〜350 (納米）紫外光照度爲0 · 1〜5 · 0 m W / c m2，強度較室內照明等高，可分解生渣滓的汁液等污漬。以下使用實施例9 一 1 6說明上述實施例1 一 8中，用各種熱可塑性塑膠等被覆體，形成於藉電動機所產生氣流的通道、設於此通道上的過濾器等過濾機構或室內照明等外光照射的外裝部件，以及裝置內部所設爲照明器具發出的光照射到的部件的表面上的低溫硬化型高活性氧化物光觸媒薄膜配合組成，膜硬化條件以及各配合成的特性等 (實施例9 ) 製作T 1 0 2微粒子分散於s i Ο 2膠體中的溶液。使用此種溶液形成T i〇2膜於PET薄膜上而製成第1 7圖中的P E T薄膜。其順序示明如下。首先說明S i〇‘2膠體的製作方法。將5g (克）的四乙氧基甲矽烷溶解於1 〇 0W (毫升）的水一乙醛一丙烯本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公髮） -39- (請先閱讀背面之注意事項再填寫本頁)482694 A7 _ B7 V. Description of the invention (35) The honeycomb structure of the device 18 2, 18 3 is formed on the inner surface of the honeycomb structure with the sample No. 6 2 shown in Table 5 as a low-temperature hardening type highly active oxide photocatalyst film. (Please read the precautions on the back before filling out this page) The low-temperature-curable high-active oxide photocatalyst film of the present invention has extremely high decomposition efficiency, and is used for indoor lighting appliances in applications with a small organic load as in Examples 1 to 7 The brightness level, that is, the wavelength of 2 50 ~ 3.5 0 (nm) ultraviolet light is 〇〇〇] _〜〇 · .〇ImW (milliwatt) / crri (cm 2) brightness level illuminance, or The illuminance of 0 · 〇1 ～〇 · 1 m W / c m2 brightness level with fluorescent and incandescent lamps is solidly decomposable. However, in the case of a high load such as ammonia concentration level ppm brightness level, there are It is necessary to configure ultraviolet generation means. Of course, mercury lamps and metal halide lamps can be used. However, according to the present invention, since the decomposition efficiency is higher than that of conventional oxide catalysts, the deodorizing effect is greater, and the intensity of ultraviolet rays and the situation of using conventional oxide photocatalysts are large. In comparison, it can be smaller. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The decomposition of dregs is usually the most active between 1 hour and 8 hours after the investment. Therefore, if the UV lamp is turned on for 1 to 4 hours at this time, the lamp can be maintained. Length of life. The exhaust filter 1 8 3 uses activated carbon as the base agent. The odor absorption of this activated carbon is completed when the odor heat concentration is low. The absorption efficiency gradually decreases with the increase of the absorption amount, so it is regularly irradiated with ultraviolet rays. Decomposing the sucked off odor substance can also regenerate activated carbon. Also, although the frame body 160 can be made of coated steel sheet, and the outer cover 171 can be made of a PP resin injection molded product, a polyvinyl chloride organic coating film is coated on the surface, and sample No. 21 is formed on the surface of the coating film. Low temperature hardening type highly active oxide photocatalyst film. -38-This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 meals) Printed by employees of the Smart Finance Bureau of the Ministry of Economy ft 482694 A7 B7___ 5. Description of the invention (36) Such a frame 1 6 0 Similar to the case of the photocatalyst film on the surface of the outer cover 171 and the exterior components of the foregoing embodiments 1 to 7, it has the effect of being able to sufficiently prevent dirt, antibacterial, and the like by indoor light. In particular, since the raw dross is processed in the case of a kitchen dregs processor, and the juice flowing out of the raw dross has a great chance of contaminating these external components, the antifouling of the low-temperature hardening type highly reactive oxygen species photocatalyst film The effect is great. The kitchen dregs processor is placed outside the house, and the sun shines on these external components. The wavelength of sunlight is 250 ~ 350 (nm). The ultraviolet illuminance is 0 · 1 ~ 5 · 0 m W / c m2. The intensity is higher than that of indoor lighting. It can decompose scum and other stains. In the following, Embodiments 9 to 16 will be used to describe the above-mentioned Embodiments 1 to 8. In the above-mentioned Embodiments 1 to 8, a covering body such as a plastic formed by a motor, a filtering mechanism such as a filter provided on the passage, or indoor lighting is formed. Composition of exterior components such as external light irradiation, and low-temperature-curable highly active oxide photocatalyst thin film on the surface of the components irradiated with light emitted by lighting equipment inside the device, film curing conditions, characteristics of each combination, etc. (Example 9) A solution in which T 1 0 2 fine particles were dispersed in a SiO 2 colloid was prepared. Using this solution, a Tio2 film was formed on a PET film to form a PE T film as shown in Fig. 17. The sequence is shown below. First, a method for preparing the S i0'2 colloid will be described. Dissolve 5g (g) of tetraethoxysilane in 100W (ml) of water-acetaldehyde-acrylic. The paper size is in accordance with China National Standard (CNS) A4 (210 X 297) -39- ( (Please read the notes on the back before filling out this page)

一 · I I I I IV n ϋ 一：eJ· an n an ϋ ϋ I I 482694 A7 B7 五、發明說明（37 ) 酸（3 : 2 7 : 7 0 )混合溶液中，在4 0 °C下攪拌5小時。所獲得的溶液在室溫下放置2週即製成S i〇2膠體。其次說明T i〇2微粒子分散於S i 0 2膠體中的溶液的製作方法。首先以重量比T i〇2 / S i〇2 : 9將 T i〇2添加於製成的S i〇2膠體中。且使固體成份.的濃度爲4 w t (重量）％，添加必要水量予以調整。此後， 5 m m 0的氧化鉻球，爲了將T i〇2微粒子分散於 S 1 〇2膠體中，以球磨機將其處理，製成T i 〇2微粒子分散於S i〇2膠體中的溶液。將所製成分散有T i 〇2微粒子的S i〇2膠體塗覆於 P E T薄膜1 8 5上，在1 2 0 t：下照射低壓水銀燈（強度：1 5 m W/ c rri )作5分鐘的處理，形成塗覆有 T 1〇2微粒子分散於S i〇2膜1 8 6中的T i〇2分散 S 1〇2膜1 8 8的塑膠薄膜。PET薄膜1 8 5上所製得的薄膜其膜質與強度極佳，膜厚爲3 0 0納米。I · I I I IV n ϋ I: eJ · an n an ϋ ϋ I I 482694 A7 B7 V. Description of the invention (37) In a mixed solution of acid (3: 2 7: 7 0), stir at 40 ° C for 5 hours. The obtained solution was left to stand at room temperature for 2 weeks to prepare a Sio2 colloid. Next, a method for preparing a solution in which T i02 fine particles are dispersed in a S i 02 colloid will be described. First, T i〇2 was added to the prepared S i02 colloid at a weight ratio of T i02 / S i02: 9. In addition, the concentration of the solid content was 4 w t (weight)%, and the necessary amount of water was added to adjust it. Thereafter, in order to disperse the T i02 fine particles in the S i 02 colloid, 5 mm m 0 of chromium oxide balls were processed with a ball mill to prepare a solution in which the T i 02 fine particles were dispersed in the S i 02 colloid. The prepared S i〇2 colloid with T i 〇2 fine particles dispersed was coated on a PET film 1 8 5 and irradiated with a low-pressure mercury lamp (intensity: 15 m W / c rri) at 12 0 t: 5 After a minute treatment, a plastic film coated with the T 102 dispersed S 10 02 film 1 88 in which the T 102 fine particles are dispersed in the S 102 film 1 86 is formed. The film made on PET film 185 has excellent film quality and strength, and the film thickness is 300 nm.

對此氧化締製有機物的分解活性加以評估。並進行塗覆紅紫色系有機色素於薄上照射2 5 4納米波長1 ( m W / c m2 )強度的光的活性試驗。分解速度自初期色素透過率的變化量求得。其結果顯示於第2 0圖。爲比較，圖中亦顯示塗覆有T i〇2分散S i〇2膜以外的無塗覆膜與S i〇2膜結果。無塗覆T i〇2分散 S 1〇2膜與S i〇2膜幾乎無色素量變化，有T i〇2分散S 1〇2膜情形下，具有在3 0分鐘後分解4 5 %的效果本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） .40 - (請先閱讀背面之注意事項再填寫本頁) 441、 Γ · n 1 eammw ϋ Βϋ an J ，垂 ϋ-· ^1·« ϋ* iBBBl MmM— mmm 0 482694 A7 B7_____ 五、發明說明（38 ) 可製作此種塗覆具有光觸媒功能的T i 0 2分散 s 1〇2膜的PET薄膜。本發明成膜法可在1 20 °C下製作，可使用硼矽酸耐熱玻璃基板外的塑膠材料。通常，膠體凝膠法由於需4 0 0 °C的溫度，故應用塑膠製品既困難，T i〇2結晶化復需1 〇分鐘以上的時間。另一方面.，由於本發明製作法可在低溫下成膜，故可用基材極爲豐富，可在任何表面上形成光觸媒薄膜。且可在短短數分鐘內處理，故可大幅降低成本。其次，爲了提高光觸媒的性能，進行助觸媒的添加。首先，在所製得T i 〇2微粒子分散於S i〇2膠體的溶液中添加各種硝酸鹽，於PET薄膜上成膜，進行色素的分解反應。其結果顯示於表1中。經濟部智慧財查笱員工哺費合作fi印裂 <請先閱讀背面之注意事項再填寫本頁)The decomposition activity of this oxidation-associated organic substance was evaluated. An activity test was performed in which a red-violet-based organic pigment was coated on the thin film and irradiated with light having a wavelength of 2 5 4 nm and a wavelength of 1 (m W / c m 2). The decomposition rate was determined from the amount of change in the initial pigment transmittance. The results are shown in Figure 20. For comparison, the results of the uncoated film and the Sio2 film other than the coated Tio2 dispersed Sio2 film are also shown in the figure. There is almost no change in the amount of pigment in the uncoated T i〇2 dispersed S 102 film and the S i〇2 film. In the case of T i〇2 dispersed S 1 02 film, it has a 45% decomposition after 30 minutes. Effect This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 40-(Please read the precautions on the back before filling out this page) 441, Γ · n 1 eammw ϋ Βϋ an J, vertical ϋ -· ^ 1 · «ϋ * iBBBl MmM— mmm 0 482694 A7 B7_____ V. Description of the invention (38) This kind of PET film coated with T i 0 2 dispersed s 1 02 film with photocatalyst function can be produced. The film-forming method of the present invention can be prepared at 120 ° C, and a plastic material outside a borosilicate heat-resistant glass substrate can be used. Generally, the colloidal gel method requires a temperature of 400 ° C, so it is difficult to apply plastic products. The crystallization of Tio2 takes more than 10 minutes. On the other hand, since the production method of the present invention can form a film at a low temperature, the available substrates are extremely abundant, and a photocatalyst film can be formed on any surface. And can be processed in just a few minutes, so costs can be greatly reduced. Secondly, in order to improve the performance of the photocatalyst, an auxiliary catalyst is added. First, various nitrates were added to a solution in which the obtained T i 〇2 fine particles were dispersed in a S io 2 colloid, and a film was formed on a PET film to perform a decomposition reaction of a pigment. The results are shown in Table 1. (Ministry of Economic Affairs, Smart Financial Investigation, Employees' Fiscal Cooperation & Filtration < Please read the notes on the back before filling this page)

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -41 - 482694 A7 B7 五、發明說明（39) 表 1 添加劑的添加效果樣本號碼添加物添加量 ΤιΟ 2 /SiO 2 1 0分鐘後分解率 (w t %) (重量比） (wt%) 1 NaN〇3 5 9 70 2 LiN〇3 5 9 . 100 3 M g (N 0 3) 2 5 9 50 4 Ca(N〇3)2 5 9 40 5 Sr(N〇3)2 5 9 30 6 B a(N〇3)2 5 9 20 7 Al(N〇3)3 5 9 0 8 Fe(N〇〇3 5 9 0 9 Zn(N〇3)4 5 9 35 10 Zr(N〇3)4 5 9 5 11 一一 9 25 12 一一 0(Si〇2) 0 (請先閱讀背面之注意事項再填寫本頁)This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -41-482694 A7 B7 V. Description of the invention (39) Table 1 Additive effect of additive Sample number Additive amount Ti 2 / SiO 2 1 Decomposition rate after 0 minutes (wt%) (weight ratio) (wt%) 1 NaN〇3 5 9 70 2 LiN〇3 5 9. 100 3 M g (N 0 3) 2 5 9 50 4 Ca (N〇3 ) 2 5 9 40 5 Sr (N〇3) 2 5 9 30 6 B a (N〇3) 2 5 9 20 7 Al (N〇3) 3 5 9 0 8 Fe (N〇〇3 5 9 0 9 Zn (N〇3) 4 5 9 35 10 Zr (N〇3) 4 5 9 5 11 1 9 25 12 1 0 (Si〇2) 0 (Please read the precautions on the back before filling this page)

· n ϋ I I n 1 I 一5OJ an n ϋ n 11 i··· I %- 經濟部智慧財產局員工消費合作社印製已知添加 Na、Li、K、Mg、Ca、Sr、Z n 的光觸媒有效，F e、A 1則成爲失活劑。第2 1圖顯示所繪助觸媒添加效果相對於電陰性度的結果。固然電陰性度越小效果越佳，特別是L i、N a、 M g極效，惟，經察，不只是電陰性度，離子半徑亦很重要。第2 2圖顯示電陰性度與離子半徑的一般添加效果關係。由此可知，添加電陰性度小於1 · 6，離子半徑小於本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -42 - 經濟部智慧財產局員工消費合作社印製 482694 A7 ______Β7_ 五、發明說明（4G) 〇.2納米元素的價數2以下的離子有效° (實施例1〇）製作數種分散粒子徑不同的T i〇2微粒子於S i〇2 膠體中的溶液。且以T i〇2 / S i〇2重量比9、 L. i添加量5 w t %，進行與實施例1相同·的操作，在P E T薄膜上形成T i 〇2分散S 1 〇2膜，使用有機色素檢查1 0 分鐘後的分解率。表 2 相對於T i〇2粒子徑的色素分解率樣本號碼 Li添加量 TlO 2/SlO 2 Tl〇2粒子徑 10分鐘後分解率 (wt%) (重量比） (nm) (wt%) 13 5 9 2 40 14 5 9 5 86 15 5 9 8 94 16 5 9 10 100 17 5 9 20 100 18 5 9 30 65 表2中顯示有所製作試料的各種條件與試驗結果。由此結果可知，分散的T i〇2粒子大小最有效的爲8〜1 〇納米。如此，分解速度因粒子徑而變化，且，T i〇2 / S 1〇2比變小的話，T i〇2微粒子的最適粒子徑固會變本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -43 - <請先：^讀背面之注^^^項再填寫本買> 482694 A7 B7___ 五、發明說明（41 ) 化，惟若在5〜2 〇納米範圍內，分解速度則極佳。由此可知，L i添加觸媒的T i〇2粒子徑若爲5〜2 0納米貝極佳。且，以上結果於L i以外的N a、K、M g、C a 、Sr、Z n亦相同。 (實施例1 1 ) . 表3中顯示有L i添加量、T i〇2 / S i〇2變化情形下的色素分解率與膜強度的檢查結果。且溶液的製作與成膜法如實施例1進行。由其結果可知，在分解率與強度上的有效條件係添加量爲〇 · 5〜2 0 w t %，T i〇2 / Si〇2爲9〜5。 (請先閱讀背面之注意事項再填寫本頁) · n I ·1 ·ϋ ϋ a·— t 一sOJI ϋ ϋ t i_i ϋ ϋ 經濟部智慧財產局員工消費合泎让印裂本紙張尺度適用中國國家標準（CNS)A4規格（210^ 297公釐） -44- 482694 A7B7 五、發明說明（42) 表 3 經濟部智慧財產局員工消費合作社印製 T 1〇2/S i〇2比的色素分解率樣本號碼 Li添加量 (wt%) TiO 2/S1O 2 (重量比） Ή〇2粒子徑 (nm) 10分鐘後分解度 19 0 9 25 〇 20 1 9 90 〇. 21 5 9 100* 〇 22 10 9 100 〇 23 20 9 100 〇 24 50 9 65 X 25 0 8 25 〇 26 1 8 88 〇 27 5 8 100 〇 28 10 8 100 〇 29 20 8 100 〇 30 50 8 60 X 31 0 6 25 〇 32 1 6 86 〇 33 5 6 100 〇 34 10 6 100 〇 35 20 6 100 〇 36 50 6 60 X 37 0 4 15 〇 38 1 4 15 〇 39 5 4 20 〇 40 10 4 20 〇 41 20 4 20 〇 42 50 4 15 〇 ---I---— II I------^ ·11111111 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -45- 482694 A7 ___Β7 五、發明說明（43 ) 表4中顯示有T i〇2/S i 〇2及膜厚度化情形下的色素分解率及膜質檢查結果。且溶液的製作與成膜法如實施例1進行，膜厚係使固體成份濃度變化爲〇 . 5〜8 w t %予以調節。結果可知，膜厚若爲1 0 0〜5 0 0納米，即不受 T i〇2 / S i〇2比的影響，分解率、膜質亦極佳。以上結果於L i以外的N a、K、M g、c 〇 s 、Z n亦一樣。 (請先閱讀背面之注意事項再填寫本頁}· N ϋ II n 1 I-5OJ an n ϋ n 11 i ··· I%-Printed photocatalyst known to add Na, Li, K, Mg, Ca, Sr, Z n by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Effective, F e, A 1 become inactivating agents. Figure 21 shows the results of the additive effect plotted against the electrical negativeness. Although the smaller the electrical negativeness, the better the effect, especially L i, Na, and Mg. However, it is not only the electrical negativeness, but also the ionic radius that has been observed. Figure 22 shows the relationship between the electrical negativeness and the general addition effect of the ion radius. It can be seen that the added electrical negativeness is less than 1.6, and the ionic radius is less than the paper size. The Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applicable. -42-Printed by the Consumer Property Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 482694 A7 ______ Β7_ V. Description of the invention (4G) 0.2 Ion ions with a valence of 2 or less are effective ° (Example 10) Preparation of several T i〇2 microparticles with different dispersed particle diameters in S i02 colloid solution . A T i 〇 2 dispersed S 1 〇 2 film was formed on the PET film by performing the same operations as in Example 1 with a Ti 〇 2 / S 〇 2 weight ratio of 9 and an L. i addition amount of 5 wt%. Use organic pigments to check the decomposition rate after 10 minutes. Table 2 Decomposition rate of pigment with respect to T i02 particle diameter Sample number Li addition amount TlO 2 / SlO 2 T10 2 particle diameter Decomposition rate after 10 minutes (wt%) (weight ratio) (nm) (wt%) 13 5 9 2 40 14 5 9 5 86 15 5 9 8 94 16 5 9 10 100 17 5 9 20 100 18 5 9 30 65 Table 2 shows the various conditions and test results for some samples. From this result, it can be seen that the most effective size of the dispersed T i02 particles is 8 to 10 nm. In this way, the decomposition rate changes depending on the particle diameter, and if the T i〇 2 / S 10 2 ratio becomes smaller, the optimum particle diameter and solidity of the T i〇2 fine particles will change. The paper size applies the Chinese National Standard (CNS) A4 (210 x 297 mm) -43-< Please read the note on the back ^^^^ before you fill in this purchase > 482694 A7 B7___ V. Description of the invention (41), but if it is 5 ~ 2 0 nanometers Within the range, the decomposition speed is excellent. From this, it can be seen that if the particle diameter of T i02 of the Li-added catalyst is 5 to 20 nanometers, it is excellent. The above results are also the same for Na, K, Mg, Ca, Sr, and Zn other than Li. (Example 11) Table 3 shows the results of examination of the pigment decomposition rate and film strength in the case where the amount of Li added and the change in Tio2 / Sio2 were changed. The preparation and film formation of the solution were carried out as in Example 1. From the results, it can be seen that the effective conditions for the decomposition rate and the strength are that the added amount is 0.5 to 20 w t%, and T i 2 / Si 2 is 9 to 5. (Please read the precautions on the back before filling this page) · n I · 1 · ϋ ϋ a · — t one sOJI ϋ ϋ t i_i ϋ ϋ Consumption of employees of the Intellectual Property Bureau of the Ministry of Economic Affairs to make printed paper sizes applicable to China National Standard (CNS) A4 Specification (210 ^ 297 mm) -44- 482694 A7B7 V. Description of Invention (42) Table 3 Pigments with T 1〇2 / S i〇2 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Decomposition rate sample number Li addition amount (wt%) TiO 2 / S1O 2 (weight ratio) Ή〇2 particle diameter (nm) after 10 minutes decomposition degree 19 0 9 25 〇20 1 9 90 〇. 21 5 9 100 * 〇 22 10 9 100 〇23 20 9 100 〇24 50 9 65 X 25 0 8 25 〇26 1 8 88 〇27 5 8 100 〇28 10 8 100 〇29 20 8 100 〇30 50 8 60 X 31 0 6 25 〇 32 1 6 86 〇33 5 6 100 〇34 10 6 100 〇35 20 6 100 〇36 50 6 60 X 37 0 4 15 〇38 1 4 15 〇39 5 4 20 〇40 10 4 20 〇41 20 4 20 〇 42 50 4 15 〇 --- I ---- II I ------ ^ · 11111111 (Please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 PCT) -45- 482694 A7 ___ Β7 V. invention is described in (43) The following table shows the decomposition rate of pigment and film quality checking result i〇2 at T / S i 〇2 case and a film thickness of 4. In addition, the production of the solution and the film formation method were performed as in Example 1. The film thickness was adjusted by changing the solid content concentration to 0.5 to 8 wt%. As a result, it can be seen that if the film thickness is 100 nm to 500 nm, it is not affected by the ratio T i 02 / S i 02, and the decomposition rate and film quality are also excellent. The above results are also the same for Na, K, Mg, cos, and Zn other than Li. (Please read the notes on the back before filling this page}

· ·ϋ ϋ I ϋ I ϋ «ϋ^OJ ϋ ·ϋ ϋ I ϋ ϋ ϋ I 經濟部智慧財產局員工消費合泎社印製· · Ϋ ϋ I ϋ I ϋ «ϋ ^ OJ ϋ · ϋ ϋ I ϋ ϋ ϋ I Printed by the Intellectual Property Office of the Ministry of Economic Affairs, Consumer Consumption Agency

482694 Α7R7 五、發明說明（44) 表 4 相對於T i 〇 2 / S i〇2比、膜厚的色素分解率樣本號碼 Li添加量 Ti〇2/Si〇2 膜厚 1 0分鐘後分解率膜質 (w t %) (重量比） (nm) (w t %) 43 10 9 50 80 良好 44 10 9 100 . 92 良好 45 10 9 300 100 良好 46 10 9 500 100 良好 47 10 9 600 100 不良 48 10 8 50 60 良好 49 10 8 100 74 良好 50 10 8 300 100 良好 51 10 8 500 100 良好 52 10 8 600 100 不良 53 10 6 50 20 良好 54 10 6 100 35 良好 55 10 6 300 100 良好 56 10 6 500 100 良好 57 10 6 600 100 良好 (請先閱讀背面之注意事項再填寫本頁)482694 Α7R7 V. Description of the invention (44) Table 4 Pigment decomposition rate relative to T i 〇2 / S i〇2 ratio, film thickness Sample number Li addition amount Ti〇2 / Si〇2 Decomposition rate after 10 minutes of film thickness Film quality (wt%) (weight ratio) (nm) (wt%) 43 10 9 50 80 Good 44 10 9 100. 92 Good 45 10 9 300 100 Good 46 10 9 500 100 Good 47 10 9 600 100 Bad 48 10 8 50 60 Good 49 10 8 100 74 Good 50 10 8 300 100 Good 51 10 8 500 100 Good 52 10 8 600 100 Bad 53 10 6 50 20 Good 54 10 6 100 35 Good 55 10 6 300 100 Good 56 10 6 500 100 Good 57 10 6 600 100 Good (Please read the notes on the back before filling this page)

· ϋ n ·ϋ 11 I ·ϋ I 一-OJt ϋ ϋ n ϋ I ϋ ϋ I (實施例1 2 ) 表5中顯示有添加T i 〇 2以外的氧化物半導體包括 ΑΤΟ、 I Τ 〇 > Zn〇、 Fe2〇3、 Cr2〇3微粒子情形下的色素分解率檢查結果。結果顯不，添加A T〇、本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -47 482694 A7 B7 五、發明說明（45) F e 2 0 3、C r 2〇3微粒子有效，添加量在任一情形下添加均有效，尤其是1 〇〜2 〇w t %最有效。於此看一下各氧化物構成元素的電子親合力即·知道，使用具有1 · 2 e V以上電子親合力的構成元素的氧化物半導體有效。 (請先閱讀背面之注意事項再填寫本頁) 裝 ϋ ϋ n 一一aJ ϋ ϋ ϋ 1 I ϋ ϋ .參· 經濟邨智慧財產局員工消費合作fi印製 •48- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公餐） 482694 A7B7 五、發明說明（46) 表 5 經濟部智慧財產局員工消費合作社印製相對於各> 塵氧化物半導體添力 α量的色素分解率樣本號碼 Li添加量 (wt%) T102/S102 (重量比）酸化物添加量 (wt%) 10分鐘後分解率 (wt%) 58 10 9 — 65 59 10 9 ATO(l.O) 68 . 60 10 9 AT〇(5.0) 72 61 10 9 AT〇(10:0) 80 62 10 9 AT〇(20.0) 82 63 10 9 ΑΤ〇(50·0) 73 64 10 9 ITO(l.O) 55 65 10 9 IT〇(5.0) 50 66 10 9 ITO(IO.O) 42 67 10 9 ITO(20.0) 38 68 10 9 ITO(50.0) 33 69 10 9 ZnO(l.O) 62 70 10 9 Zn〇(5.0) 56 71 10 9 ZnO(lO.O) 48 72 10 9 Zn〇(20.0) 42 73 10 9 Ζη〇(50·0) 35 74 10 9 Fe2〇3(1.0) 66 75 10 9 Fe2〇3(5.0) 68 76 10 9 Fe2〇3(10.0) 70 77 10 9 Fe2〇3(20.0) 71 78 10 9 Fe2〇3(50.0) 72 79 10 9 CnCb(l.O) 65 80 10 9 Cr2〇3(5.0) 67 81 10 9 Cr2〇3(10.0) 69 82 10 9 Cr2〇3(20.0) 73 83 10 9 Cd〇3(50.0) 48 (請先閱讀背面之注意事項再填寫本頁) 裝參· 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -49- 482694 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（47) 構成元素 Ti S n In Z n F e C r 電子親合力（e V ) 1·25 1,2 0.2 - 1.2 3.1 6 3.54 在氧化物半導體的電子親合力較T i小情形下，.微粒子的粒子界面上形成肖脫基勢壘，未.出現有所添加的氧化物半導體載流子無法注入T i〇2中的效果。相對地，在氧化物半導體的電子親合力較T i小情形下，微粒子的粒子界面上未形成宵脫基勢壘，成電阻接合，則具有氧化物半導體載流子容易注入T i ◦ 2中的有效功能。特別有效的 A T 0固然其電子親合力較T i小一些，惟由於此差幾等於無，故顯見其性能提高。即，導電性氧化物A T 0載流子濃度極高，ΑΤΟ的大量載流子注入Ti〇2中，使光觸媒的活性提高。且可知，添加此種氧化物半導體時，添加 L i的效果極大。又就有效利用具有載流子的氧化物半導體的方法而言，不僅添加微粒子，亦可使其層疊化。於表6中顯示有 T 1 〇2/S i〇2膜與ΑΤΟ膜的層疊結果。由結果可知，層疊有效，且二者添加L i可進一步提高性能。復可知，多次交替層疊亦有效。 (請先閱讀背面之注意事項再填寫本頁) · n ϋ 1 iw I n ϋ 一：0, 8 I ϋ ϋ I ϋ ϋ .參- 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -50- 482694 A7 B7 五、發明說明（48 ) 表 6 A T〇層疊膜的色素分解率樣本號碼第1層 Li添加量 (wt%) 第2層 Li添加量 (wt%) 20分鐘後分解率 (wt%) 84 Ti〇2/Si〇2=9 0 ΑΤΟ 0 45 · 85 Ti〇2/Si〇2=9 5 ΑΤΟ 5 70 86 Ti〇2/Si〇2=9 10 ΑΤΟ 5 75 87 Ti〇2/Si〇2=9 20 ΑΤΟ 5 73 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合泎fi印沒 (實施例1 3 ) 製作添加粒子徑5納米T i〇2微粒子於S i〇2膠體中的溶液，分別添加相對於T i〇2爲2 w t %的A g、 Pt、 Pd' Rh、 Ni、 Cu與Ru〇2微粒子於其中。且使T i〇2/s i〇2的重量比爲9。使用所製成添加有 Ag、1111〇2微粒子的Ti〇2分散Si〇2膠體，藉相同於實施例1的操作，在P E T薄膜上形成添加有A g、 Pt、 Pd、 Rh、 Ni、 Cu與Ru〇2微粒子的 T i〇2分散S i〇2膜，並檢查有機色素的分解特性。由結果可知，如表7所示，添加A g、P t、P d、R h、 Ni、 Cu與Ru〇2微粒子，分解速度變大。· Ϋ n · ϋ 11 I · ϋ I 1 -OJt ϋ ϋ n ϋ I ϋ ϋ I (Example 1 2) Table 5 shows that oxide semiconductors other than T i 〇2 are added including ATTO, I Τ 〇 > Results of inspection of pigment decomposition rate in the case of Zn〇, Fe203, Cr203 fine particles. The results are not obvious. Adding AT〇, this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -47 482694 A7 B7 V. Description of the invention (45) F e 2 0 3, C r 2 03 The microparticles are effective, and the addition amount is effective in any case, especially 10 to 20% by weight is the most effective. Here, if we look at the electron affinity of each oxide constituent element, we know that it is effective to use an oxide semiconductor with a constituent element having an electron affinity of 1 · 2 e V or more. (Please read the precautions on the back before filling out this page) Decoration 一 n-one a ϋ ϋ ϋ I 1 I ϋ ϋ. Participate in · Economic Village Intellectual Property Bureau employee consumption cooperation fi print • 48- This paper size applies to China Standard (CNS) A4 specification (210 X 297 public meals) 482694 A7B7 V. Description of invention (46) Table 5 Pigment decomposition of the amount of α printed by each consumer ’s cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and the dust oxide semiconductor Rate sample number Li addition amount (wt%) T102 / S102 (weight ratio) Acid compound addition amount (wt%) Decomposition rate (wt%) after 10 minutes 58 10 9 — 65 59 10 9 ATO (lO) 68. 60 10 9 AT〇 (5.0) 72 61 10 9 AT〇 (10: 0) 80 62 10 9 AT〇 (20.0) 82 63 10 9 ΑΤ〇 (50 · 0) 73 64 10 9 ITO (lO) 55 65 10 9 IT 〇 (5.0) 50 66 10 9 ITO (IO.O) 42 67 10 9 ITO (20.0) 38 68 10 9 ITO (50.0) 33 69 10 9 ZnO (lO) 62 70 10 9 Zn〇 (5.0) 56 71 10 9 ZnO (lO.O) 48 72 10 9 Zn〇 (20.0) 42 73 10 9 Zη〇 (50 · 0) 35 74 10 9 Fe2〇3 (1.0) 66 75 10 9 Fe2〇3 (5.0) 68 76 10 9 Fe2〇3 (10.0) 70 77 10 9 Fe2〇3 (20.0) 71 78 10 9 Fe2〇3 (50.0) 72 79 10 9 CnCb (lO) 65 80 10 9 Cr2〇3 (5.0) 67 81 10 9 Cr2〇3 (10.0) 69 82 10 9 Cr2〇3 (20.0) 73 83 10 9 Cd〇3 (50.0) 48 (Please first Read the notes on the reverse side and fill in this page.) Loading parameters · This paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) -49- 482694 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Description of the invention (47) The electron affinity (e V) of the constituent elements Ti S n In Z n F e C r 1 · 25 1,2 0.2-1.2 3.1 6 3.54 in the case where the electron affinity of the oxide semiconductor is smaller than T i The Schottky barrier is formed at the particle interface of the microparticles, and the effect that the added oxide semiconductor carriers cannot be injected into Tio2 appears. In contrast, in the case where the electron affinity of the oxide semiconductor is smaller than T i, no thief barrier is formed at the particle interface of the fine particles, and a resistance junction is formed, and the oxide semiconductor carriers are easily injected into T i ◦ 2 Effective function. Although A T 0, which is particularly effective, has a smaller electron affinity than T i, the difference is almost equal to none, so its performance is obviously improved. That is, the carrier concentration of the conductive oxide A T 0 is extremely high, and a large number of carriers of ATO are injected into Ti0 2, which improves the photocatalytic activity. In addition, when such an oxide semiconductor is added, the effect of adding L i is great. In addition, in a method for effectively utilizing an oxide semiconductor having a carrier, not only fine particles can be added, but also lamination can be performed. Table 6 shows the results of lamination of the T 1 0 2 / S 2 film and the ATO film. From the results, it can be seen that lamination is effective, and adding Li to both can further improve performance. It can be seen that multiple alternating stacks are also effective. (Please read the precautions on the back before filling this page) · n ϋ 1 iw I n ϋ one: 0, 8 I ϋ ϋ I ϋ 参 .Refer to-This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm) -50- 482694 A7 B7 V. Description of the invention (48) Table 6 Pigment decomposition rate of AT〇 laminated film Sample No. Li addition amount in the first layer (wt%) Li addition amount in the second layer (wt%) 20 Decomposition rate after minutes (wt%) 84 Ti〇2 / Si〇2 = 9 0 ΑΤΟ 0 45 · 85 Ti〇2 / Si〇2 = 9 5 ΑΤΟ 5 70 86 Ti〇2 / Si〇2 = 9 10 ΑΤΟ 5 75 87 Ti〇2 / Si〇2 = 9 20 ΑΤΟ 5 73 (Please read the precautions on the back before filling out this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, the consumer stamp of fi (impressions of Example 1 3) A solution of 5 nanometer Ti io2 microparticles in S io2 colloid was added with Ag, Pt, Pd 'Rh, Ni, Cu, and Ru〇2 microparticles at 2 wt% relative to Ti 〇2. The weight ratio of T i〇2 / s i02 was set to 9. Using the prepared TiO2 dispersed SiO2 colloid with Ag and 1111〇2 particles added, the same operations as in Example 1 were performed to form Ag, Pt, Pd, Rh, Ni, and Cu added on the PET film. Sio2 film was dispersed with Tio2 of RuO2 fine particles, and the decomposition characteristics of organic pigments were examined. As can be seen from the results, as shown in Table 7, when Ag, Pt, Pd, Rh, Ni, Cu, and RuO2 fine particles were added, the decomposition rate was increased.

· ϋ 1_1 n ϋ »ϋ n 1 t 11 ·ϋ mMmt 1 lav ^1· I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -51 - 482694 A7B7 五、發明說明（49) 表 7 相對於貴金屬添加的色素分解率樣本號碼 Li添加量 Ti〇2/Si〇2 貴金屬添加量 20分鐘後分解率 (wt%) (重量比） (wt%) (wt%) 88 10 9 Pt(0.5) 74 · 89 10 9 Rh0.5) 72 90 10 9 Pd(0.5) 75 91 10 9 Ag(0.5) 78 92 10 9 Cu(0.5) 76 93 10 9 Ni(0.5) 68 94 10 9 Ru(0.5) 75 95 10 9 一(0.5) 65 (實施例1 4 ) 於實施例1所製成的添加L i光觸媒與無添加L i光觸媒中，使用螢光燈、太陽光、白熾燈、水銀燈，比較煙草焦油、乙醛、尿素、太腸菌的分解特性。由其結果可知，如表8所示，添加L i的光觸媒無論使用哪種燈，其煙草焦油、乙醛、尿素、大腸菌的分解特性均較無添加L i 的光觸媒的3〜5倍。由此可知，L i添加觸媒不光是以紫外線燈，以生活環境下所使用的燈亦可獲得充份的效果。且，添加Li以外的Na、 K、 Mg、 Ca、 Sr、 Z n情形下效果亦相同。 (請先閱讀背面之注意事項再填寫本頁) · 11 1 1 1· n n > 11 I IB1 l^i 1_. 4^· 經濟部智慧財產局員工消費合作社印製本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -52 - 482694 A7 _______B7__ _ 五、發明說明（50 ) 表 8 以各種燈分解有機物試驗結果 f_(—添力D 1 0 (w t % ) L i時/無添加L i時的分解率比）煙草焦油乙醛尿素大腸菌色素螢光燈 3 3 3 3 3 太陽光 5 5 5 . 5 5 5 5 5 5 5 白熾燈 3 3 3 3 3 水銀燈 4 4 4 4 4 (請先閱讀背面之注意事項再填寫本頁) (實施例1 5 ) 實施例1所製作添加L i的T i 0 2分散S i〇2膜若直接成膜於P E T薄膜上，即會由於光觸媒作用損害到基材的P E T薄膜。就此，乃在塗覆實施例9所製作添加有 L· ^的下i〇2分散s i〇2膜之際，製作在其與PET薄膜之間設有一層S i〇2膜的薄膜。且在S i〇2膜中構成有使光觸媒作用失活的成份，製作添加有A丨、F e、經濟部智慧財產局員工消費合作社印製 Z r各硝酸鹽的試料或在添加L丨的τ i〇2分散s i〇2 膜中添加有A T 0的試料，進行各種試驗。其結果顯示於表9中。 -53- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7B7 五、發明說明（51) 表 9 S i 〇 2疊層膜的色素分解試驗及耐久性試驗結果 (T i 0 2 / S i〇 2=9 ，Li ( w t % ) - 1 0 ) 樣本號碼 ΑΤΟ Si〇2 添加元素 20分鐘後分解率 10曰後的剝除塵埃附著 (wt%) (wt%) (wt%) (wt%) (膜帶試驗結果） 96 0 te j \ w Μ y \ w 65 . 有(X) 有 97 20 M j \ \\ Μ j \ \\ 82 有(X) >frni 98 0 有 Μ J V 65 無(X) 有 99 0 有 Α1(5) 65 無(〇）有 100 0 有 Fe(5) 66 無(〇）有 101 0 有 Zr(5) 65 無(〇）有 102 20 有 Al(5) 83 無(〇） >fnT- 撒 103 20 有 Fe(5) 82 無(〇） 4rrf. 挑 104 20 有 Fe(5) 82 無(〇） 4nc 無 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作江印裂結果，在添加L 1的T i〇2分散S i〇2膜與PET 薄膜間設有一層S i 0 2膜作爲防護層，即使經過長時間使用，亦可防止薄膜剝除。且可知，藉由添加A 1、F e、 Z r能使光觸媒活性完全失活，維持接合強度。復且， A 丁〇添加膜附帶有帶電防止效果，亦可抑制塵埃等附著，不僅防止有機物分解，亦可防止無機物附著，能製得具有較佳防污效果的薄膜。茲將具有前述實施例9 - 1 6所示配置的低溫硬化型高活性氧化物光觸媒薄膜與藉由實施例1 - 8所示電動機 -54- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 五、發明說明（52 ) 產生氣流的機構的各種物品使用情形下的具體效果評價結果整理如下。首先就應用於將本發明低溫硬化型高活性氧化物光觸媒薄膜設於氣流通路中的過濾機構情形的效果力口以整理。室內代表性的空氣中污染物質係煙草的煙。煙草·的煙係焦油與煤煙類浮遊微粒子，此等微粒子在濾器上蓄積成膜，濾器漸漸變成茶色而污化。茲評估煙草的煙所造成污化情形。在送風量（m 3 /分）的換氣扇吸塵側前面貼附固定對象面積1 0 cmx 1 〇 cm的聚酯纖維不織布濾片。此附有此不織布的換氣扇設置在容量45， 000 (cm3 )的容器中並加以密封。煙草的煙發生裝置倂設於此容器中。此煙草的煙發生裝置將管子安裝於著火煙草的濾片側 ,此管子與隔膜泵連接。以1 , 8 0 0 ( c m 3 /秒）的風量驅動此隔膜泵，一旦煙草側的管子端減壓，通過煙草濾片的煙即自吐出側排出，一支煙草的燃燒1 · 5分鐘。若驅動此種構成的容器中的煙草煙發生裝置與換氣扇，由於換氣扇的排氣亦排出同容器內，故充滿於容器內的煙草煙無論如何會通過不織布濾片。連續燃燃5支煙草，在換氣扇驅動1 0分鐘後開放容器而將不織布濾片取出作爲試料。此不織布濾片的纖維表面上形成有本發明低溫硬化型高活性氧化物光觸媒薄膜。其作成方法係以實施例9所說明方法作成。實施例9固以P E T膜爲對象，惟在分散 T 1〇2微粒子於S i〇2凝膠中的溶液中添加硝鋰，於此溶液中浸漬施以臭氧環境氣體表面氧化處理的不織布濾片本紙張瓦度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝· Ϋ 1_1 n ϋ »ϋ n 1 t 11 · ϋ mMmt 1 lav ^ 1 · I This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -51-482694 A7B7 V. Description of the invention (49 ) Table 7 Pigment decomposition rate with respect to noble metal addition Sample No. Li addition amount Ti〇2 / Si〇2 Noble metal addition amount 20 minutes Decomposition rate (wt%) (weight ratio) (wt%) (wt%) 88 10 9 Pt (0.5) 74 · 89 10 9 Rh0.5) 72 90 10 9 Pd (0.5) 75 91 10 9 Ag (0.5) 78 92 10 9 Cu (0.5) 76 93 10 9 Ni (0.5) 68 94 10 9 Ru (0.5) 75 95 10 9 One (0.5) 65 (Example 1 4) Among the added Li photocatalyst and non-added Li photocatalyst prepared in Example 1, fluorescent lamps, sunlight, incandescent lamps, and mercury lamps were used. To compare the decomposition characteristics of tobacco tar, acetaldehyde, urea, and enterobacteriaceae. As can be seen from the results, as shown in Table 8, the decomposition characteristics of tobacco tar, acetaldehyde, urea, and coliform were 3 to 5 times higher than those of the photocatalyst without Li, no matter which lamp was used. From this, it can be seen that the Li addition catalyst is not only an ultraviolet lamp, but also a sufficient effect can be obtained with a lamp used in a living environment. The effect is also the same when Na, K, Mg, Ca, Sr, and Z n other than Li are added. (Please read the precautions on the back before filling this page) · 11 1 1 1 · nn > 11 I IB1 l ^ i 1_. 4 ^ · Printed on paper standards of the Ministry of Economic Affairs and Intellectual Property Bureau Staff Consumption Cooperatives Applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) -52-482694 A7 _______B7__ _ V. Description of the invention (50) Table 8 Test results of decomposition of organic matter with various lamps f _ (— Tianli D 1 0 (wt%) L i / Decomposition ratio when Li is not added) Tobacco tar acetaldehyde urea coliform pigment fluorescent lamp 3 3 3 3 3 sunlight 5 5 5. 5 5 5 5 5 5 5 incandescent lamp 3 3 3 3 3 mercury lamp 4 4 4 4 4 (Please read the precautions on the back before filling in this page) (Example 1 5) If the Li-added T i 0 2 dispersed S i〇2 film produced in Example 1 is directly formed on a PET film, that is, PET film that can damage the substrate due to photocatalyst. In this regard, when the lower SiO 2 dispersed SiO 2 film prepared by adding L · ^ prepared in Example 9 was applied, a thin film with a SiO 2 film provided between it and the PET film was produced. In addition, a component that inactivates the photocatalyst function is formed in the Si 102 film. Samples added with A 丨, Fe, and the Intellectual Property Bureau of the Intellectual Property Bureau of the Ministry of Economic Affairs printed a sample of each nitrate of Zr or added with L 丨. Various samples were tested by adding AT 0 to a τ i〇2 dispersed SiO2 film. The results are shown in Table 9. -53- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 482694 A7B7 V. Description of the invention (51) Table 9 Pigment decomposition test and durability test results of S i 〇2 laminated film ( T i 0 2 / S i〇2 = 9, Li (wt%)-1 0) Sample No. ΑΤＯ Si〇2 Decomposition rate after adding element for 20 minutes, stripping dust adhesion after 10 minutes (wt%) (wt%) (wt%) (wt%) (film strip test results) 96 0 te j \ w Μ y \ w 65. Yes (X) Yes 97 20 M j \ \\ Μ j \ \\ 82 Yes (X) > frni 98 0 Yes M JV 65 No (X) Yes 99 0 Yes A1 (5) 65 No (〇) Yes 100 0 Yes Fe (5) 66 No (〇) Yes 101 0 Yes Zr (5) 65 No (〇) Yes 102 20 Yes Al (5) 83 No (〇) > fnT- Sa 103 20 Yes Fe (5) 82 No (〇) 4rrf. Pick 104 20 Yes Fe (5) 82 No (〇) 4nc No (please first (Please read the notes on the back and fill in this page again) Consumption cooperation between employees of the Intellectual Property Bureau of the Ministry of Economy As a protective layer, the film can be prevented from peeling even after a long period of use. Moreover, it can be seen that the addition of A1, Fe, and Zr can completely deactivate the photocatalyst activity and maintain the bonding strength. In addition, the A-added film has a charging prevention effect, and can also prevent the adhesion of dust and other materials. It can not only prevent the decomposition of organic substances, but also prevent the adhesion of inorganic substances, and can produce a film with better antifouling effect. The low-temperature hardening type highly active oxide photocatalyst film having the configuration shown in the foregoing Examples 9-16 and the motor -54 shown in Examples 1-8 are used in accordance with the Chinese National Standard (CNS) A4 specification ( (210 X 297 mm) 482694 A7 B7 V. Description of the invention (52) The results of the evaluation of the specific effects of various articles of the air generating mechanism are summarized as follows. First, the effect of applying the filtering mechanism of the low-temperature hardening type high-reactive oxide photocatalyst film of the present invention in the air flow path to sort out the effect will be sorted out. The representative indoor air pollutant is tobacco smoke. Tobacco · smoke-based tar and soot-type floating particles accumulate on the filter, and the filter gradually becomes brown and stains. The pollution caused by tobacco smoke is assessed. A polyester fiber non-woven filter with a fixed area of 10 cm x 10 cm is attached to the front of the dust extraction side of the ventilation fan (m 3 / min). The non-woven ventilator is placed in a container with a capacity of 45,000 (cm3) and sealed. Tobacco smoke generating devices are housed in this container. This tobacco smoke generating device installs a tube on the filter side of the burning tobacco, and this tube is connected to a diaphragm pump. The diaphragm pump is driven with an air flow of 1,800 (cm3 / sec). Once the pipe end of the tobacco side is decompressed, the smoke passing through the tobacco filter is discharged from the discharge side, and a piece of tobacco is burned for 1.5 minutes. If the tobacco smoke generating device and the ventilation fan in the container having such a structure are driven, the exhaust gas of the ventilation fan is also discharged into the same container, so the tobacco smoke filled in the container will pass through the non-woven filter in any case. Five cigarettes were continuously burned. After the fan was driven for 10 minutes, the container was opened and the non-woven filter was taken out as a sample. The fiber surface of this nonwoven fabric filter is formed with a low-temperature hardening type highly active oxide photocatalyst film according to the present invention. The preparation method is the one described in Example 9. Example 9: A PET film was used as the object, but lithium nitrate was added to a solution in which T 1 0 2 microparticles were dispersed in a S 2 0 gel, and a non-woven cloth filter treated with a surface oxidation treatment with ozone ambient gas was immersed in the solution. The wattage of this paper applies the Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page).

1 n n·- 一：口，· n 1 imam ϋ 1 I 經濟部智慧財產笱3工鸿費合作达印製 -55· 482694 A7 ____B7_ 五、發明說明（53 ) ，保持1分鐘後，將薄膜撈上來，藉吹風將不要的溶液吹散後，在1 2 0 °下照射低壓水銀燈（強度：1 5 m W/ c rri )處理5分鐘，使膜硬化而形成光觸媒薄膜於纖維表面上。此膜組成係表1中的樣本第2號。照射螢光燈的光於如此作成的試料而評估所附著.污物的分解度。使用不織布濾片的色澤變.化的色差計（日本電色工業社：Z - 1 〇〇 1 D P )來進行評估。以光照射前的污化狀態的色差爲1 0 0 %，以附著前的色差爲0 % , 針對煙草煙污化，評估其防污效果。令用來比較的僅分散 T i〇2微粒子於S i〇2中的樣本第1 1號以及不含 T i〇2微粒子僅有S i〇2的膜的樣本第1 2號同樣形成薄膜於濾片纖維表面上，予以評估。其結果顯示於第2 3與2 4圖中。第2 3圖所示係相同條件下進行煙通過濾片試驗之際對濾片污化情形歷時色差的評估結果。與無處理之丙烯基濾片比較，能了解到形成只有S 1〇2的被膜之濾片（樣本第1 2號）係幾乎相同等級之捕集率，相對於以S i 0 2作爲主體另添加鋰之被膜 (樣本第2號）變色快約5倍，即煙的捕集效果提高約5 倍。第2 4圖所示係在上述條件下對吸著煙而變成茶色的濾片照射螢光燈的光，藉光觸媒分解附著物，已變色的濾片顏色再恢復原來色調程度的色差歷時測定評估結果。圖中的累計光量表示2 5 0〜3 5 0 ( nm)波長的光照射的累計値。圖中的樣本第1 2號係不含T i 0 2僅含 S 1 0 2的情形，幾乎看不出有分解所造成的脫色效果。樣 (請先閱讀背面之注意事項再填寫本頁)1 nn ·-1: mouth, · n 1 imam ϋ 1 I Intellectual property of the Ministry of Economic Affairs 笱 3 industrial cooperation fee printing -55 · 482694 A7 ____B7_ 5. Description of the invention (53), keep the film for 1 minute Come up, blow off the unwanted solution by blowing air, and then irradiate with a low-pressure mercury lamp (intensity: 15 m W / crri) for 5 minutes at 120 ° to harden the film to form a photocatalyst film on the fiber surface. This film composition is sample No. 2 in Table 1. The sample thus prepared was irradiated with light from a fluorescent lamp to evaluate the degree of decomposition of the adhered dirt. Evaluation was performed using a color difference meter (Nippon Denshoku Kogyo Co., Ltd .: Z-1001 D P) of a non-woven filter. The color difference of the stained state before light irradiation was 100%, and the color difference of the stained state before attachment was 0%. The antifouling effect was evaluated for tobacco fouling. The sample No. 11 for comparison, in which only T i〇2 fine particles were dispersed in S i02, and the sample No. 12 with no T i02 fine particles and only S i02 was formed into a thin film. The filter fiber surface was evaluated. The results are shown in Figures 23 and 24. Figure 23 shows the evaluation results of the color difference of the filter during the smoke passing through the filter test under the same conditions. Compared with the untreated propylene-based filter, it can be understood that the filter (Sample No. 12) forming a film with only S 1 02 has almost the same level of capture rate. The lithium-added film (Sample No. 2) changed color about 5 times faster, that is, the smoke capture effect increased about 5 times. The filters shown in Figure 24 are irradiated with the light of fluorescent lamps under the conditions described above by smoking cigarettes. The photocatalyst is used to decompose the attached matter, and the color of the discolored filter is restored to its original hue. result. The cumulative light quantity in the figure represents the cumulative chirp of light irradiation at a wavelength of 250 to 350 (nm). Sample No. 12 in the figure is the case where T i 0 2 is not included and S 1 0 2 is included, and there is almost no decoloring effect caused by decomposition. (Please read the notes on the back before filling this page)

· n an mam§ i fl— ·ϋ 1- 1 ·1· I ϋ 1 1 I 經濟部智慧財查局員工消費含泎注印裂本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） .明_ 482694 A7 B7 五、發明說明（54 ) 本第1 1號與樣本第2號固含有同量T i〇2，分別具有效果，惟樣本第2號係添加L i N 0 3的本發明處方，可看得出其脫色速度大幅增進。特別是在初期可獲得無添加 L i N 0 3的2倍以上的高分解效率。實際的空氣淸淨機與換氣扇等的情形由於附著少量污物，同時照射室內光·，故初期分解速度極爲重要。由於隨著污.物附著量增多，光線會難以到達爲污物遮蔽的纖維表面的光觸媒薄膜，故分解效率會降低。因此，污物附著變厚前的分解極爲重要。實際環境下，由於附著與使用上述裝置的本試驗相同程度的污物量，故在密閉6坪大空間（約2 0 m2 )作動上述換氣扇情形下，燃燒2 0支煙草，即相當於作動後 1 2 0分鐘的污物量。且爲了檢討對於反復使用的耐久性，以反復進行在第2 4圖所示的內容之試驗之煙過濾附著及光照射來評估。累計光量照射至0 · 2 5 ( m W · h / c ηί )，分解9 Ο %的污物之後，再次地反復使煙附著之操作，而再一次地分解9 0 %之污物。雖然反復5 0次此操作，可是即使是第5 0次也維持與初期同樣之分解效率。從這個結果能了解由於反復動作也不會使觸媒的效率降低。其次就應用於在氣流通路中設有本發明低溫硬化型高活性氧化物光觸媒薄膜的過濾機構的除臭效果檢討而整理其結果。對代表性惡臭物質的氨進行評估。對與上述煙草的情形完全相同的構成進行檢討。取代煙草的煙草發生裝置，將定量氨氣注入容器內部，調整容器內部的氨氣量濃本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） _ (請先閱讀背面之注意事項再填寫本頁)· N an mam§ i fl— · ϋ 1- 1 · 1 · I ϋ 1 1 I Consumption by employees of the Bureau of Intelligent Finance and Inspection of the Ministry of Economic Affairs contains misprints. The dimensions of this paper are applicable to China National Standard (CNS) A4 (210 X 297). Mm). Ming _ 482694 A7 B7 V. Description of the invention (54) The No. 11 and No. 2 of the sample contain the same amount of T i〇2, which have effects, but the No. 2 of the sample is added with L i N 0 According to the prescription of the present invention of 3, it can be seen that the decoloring speed is greatly improved. In particular, a high decomposition efficiency of twice or more without the addition of L i N 0 3 can be obtained in the initial stage. In the case of actual air purifiers and ventilating fans, the initial decomposition speed is extremely important because a small amount of dirt adheres and the room light is irradiated at the same time. As the amount of dirt and dirt increases, it becomes difficult for light to reach the photocatalyst film on the surface of the fiber that is sheltered by the dirt, so the decomposition efficiency decreases. Therefore, it is extremely important to decompose the dirt before it becomes thick. In the actual environment, because the same amount of dirt is attached as in the test using the above device, burning 20 cigarettes in the case of operating the ventilating fan in a closed 6 ping large space (about 20 m2) is equivalent to operating Amount of dirt in 120 minutes. In addition, in order to review the durability against repeated use, the smoke filtration adhesion and light irradiation of the test shown in Fig. 24 were repeated to evaluate. The cumulative light intensity was irradiated to 0 · 2 5 (m W · h / c ηί), after decomposing 90% of the dirt, the operation of adhering the smoke was repeated again, and 90% of the dirt was decomposed again. Although this operation was repeated 50 times, the same decomposition efficiency as in the initial stage was maintained even at the 50th time. From this result, it can be understood that the efficiency of the catalyst is not reduced due to repeated actions. Next, the results of the deodorizing effect of the filter mechanism provided with the low-temperature hardening type highly active oxide photocatalyst film of the present invention in the air flow path were reviewed and collated. Evaluation of ammonia for representative malodorous substances. Review the exact same composition as in the case of tobacco. Tobacco generator that replaces tobacco, injects a certain amount of ammonia into the container and adjusts the ammonia concentration inside the container. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Fill in this page again)

一 · ϋ ϋ I _1 ·ϋ β— 1 一：口，i ϋ ·ϋ I n I I ·ϋ I #- 經濟部智慧財產局員工消費合作社印製 482694 A7 B7 五、發明說明（55) 度爲2 5 ( p p m ),驅動安裝形成有低溫硬化型高活性氧化物光觸媒薄膜的不織布的換氣扇。第2 5圖顯示與煙捕集情形一樣的玻璃質氧化物光觸媒薄膜的最初氨氣吸著結果的測定結果。相對於無處理的丙烯基纖維即使歷時i 小時亦殘留9 0 ( % )以上的氨氣，裝有以T i〇2與· S i〇2爲成份的玻璃質氧化物光觸媒.薄膜情形下，歷時1 小時後，吸著除去5 0 ( % )以下的濃度。可見具有不僅捕集煙亦捕集氨氣的效果。此氨氣吸著飽和後，容器內部所安裝的白熾燈泡即點燈，光抵達濾片表面。進行容器內氨氣濃度的歷時測定，評估氨分解效果。第2 6圖顯示此結果。不含T i〇2的樣本第1 2號濾片經察幾無濃度變化。含有T i〇2的樣本第1 1號與第2號固隨著光照射氨氣濃度降低，可知其有分解，惟樣本第2號配合本發明 L 1 N〇3分解效率大幅增進，與樣本第1 1號比較，可獲得約3倍的分解效率。雖以乙醒及甲基硫醇、硫化氫作爲別的惡臭物質來進行評估同樣的脫臭性能評價試驗，可是能得到與氨氣的情況時同樣或較其更好的分解效果，確認出能分解不只作爲對象惡臭之氨氣且也可以分解各種的惡臭。上述防污、除臭效果固揭載應用於空氣淸淨機與換氣扇例子的代表例，惟毋庸贅言，具有相同機構的各種物品的濾片亦可發揮全然相同的效果。其次評估實施例1〜8所示各種物品用於外裝部件情本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） (請先閱讀背面之注意事項再填寫本頁)· Ϋ ϋ I _1 ϋ ϋ β— 1 ：: ，, ϋ ϋ II I n II ϋ ϋ I #-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 482694 A7 B7 V. Description of the invention (55) Degree 2 5 (ppm), to drive the installation of a non-woven ventilating fan with a low-temperature hardening type highly active oxide photocatalyst film. Fig. 25 shows the measurement results of the initial ammonia gas absorption of the glassy oxide photocatalyst film as in the case of smoke capture. Compared to untreated propylene-based fibers, ammonia (90% or more) remains even after i hours. It is equipped with glass oxide photocatalysts composed of Tio2 and Sio2. In the case of thin films, After 1 hour, the concentration below 50 (%) was removed by adsorption. It can be seen that it has the effect of capturing not only smoke but also ammonia. After this ammonia gas is absorbed and saturated, the incandescent bulb installed inside the container is turned on, and the light reaches the surface of the filter. The ammonia concentration in the container was measured over time to evaluate the effect of ammonia decomposition. Figures 2 to 6 show this result. The filter No. 12 of the sample without T i02 showed almost no change in concentration. The samples No. 1 and No. 2 containing T i〇2 showed decomposition with the decrease in the concentration of ammonia gas under light irradiation, but Sample No. 2 greatly improved the decomposition efficiency with the sample L 1 N〇3 in accordance with the present invention. Comparing No. 11 with about 3 times the decomposition efficiency. Although the same deodorizing performance evaluation test was evaluated using ethoxamine, methyl mercaptan, and hydrogen sulfide as other malodorous substances, the same or better decomposition effect was obtained as in the case of ammonia, and it was confirmed It decomposes not only the target ammonia but also various malodors. The above-mentioned antifouling and deodorizing effects are representative examples of applications to air purifiers and ventilating fans, but it goes without saying that the filters of various articles with the same mechanism can also exhibit exactly the same effects. Secondly, evaluate the various items shown in Examples 1 to 8 for exterior parts. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 public love) (Please read the precautions on the back before filling this page)

· «Hu ϋ n ϋ 1_1 ϋ —ϋ 1_1 1· 11 ^1 ϋ Mmmmw I I 經濟部智慧財產局員工消費合作社印製 -58- 482694 A7 B7 涇青部費合泎吐卬Μ 五、發明說明（56) 形的具體效果而整理其結果如下。最好以用於外裝部件的射出成型形用熱可塑性A B S樹脂（高科技聚合物社：塔弗雷克斯4 5 1，白色著色品）爲試料。作成5 c m X 5 c m的板狀成形品，對其表面電暈放電處理。形成實施例 1 2的表6所示樣本第8 6號組成的低溫硬化型高活.性氧化物光觸媒薄膜。就用來比較的僅分散T i 0 2微粒子於. S i〇2中的表1中樣本第1 1號以及不含τ i〇2微粒子僅含S i〇2的膜而言，同樣於成形板表面上形成薄膜，並加以評估。對與前述不織布濾片試驗完全相同的構成加以檢討。將5 c m X 5 c m的A B S板固定於配置濾片部份的中央部，1 0支煙草燃燒後，驅動換氣扇1 2 0分鐘，白色A B S板即污染成茶色。取出此A B S板，照射與前述各種條件相同的光，藉由其前後色差測定評估其除去率。第2 7圖顯示此結果。其結果固與濾片情形幾乎相同，惟由於附著的污物本身較濾片情形少，故以一半以下的光量即可獲得相同程度的脫色效果。且樣本第8 6號係加入L i N〇3復以a T〇爲添加成份而配成者，與樣本第11號相較，可獲得更高分解效率。其次就廚房等使用油份極多的環境下使用物品因油脂而污染情形的防污效果評估而整理其結果。在實施例i 2 的表6所示樣本第8 6號組成的形成有低溫硬化型高活性氧化物光觸媒薄膜的5 c m X 5 c m玻璃板上，塗布約5 (// m )的薄層沙拉油照射紫外線燈的光線，測定油的歷 (請先閱讀背面之注意事項再填寫本頁) 裝· «Hu ϋ n ϋ 1_1 ϋ —ϋ 1_1 1 · 11 ^ 1 ϋ Mmmmw II Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-58- 482694 A7 B7 ), The results are as follows. Thermoplastic A B S resin (High-tech polymer company: Tower Frex 4 51, white colored product) for injection molding of exterior parts is preferably used as a sample. A 5 c m X 5 c m plate-shaped molded product was prepared, and the surface was subjected to corona discharge treatment. A low-temperature hardening type high-activity oxide photocatalyst film having a composition of sample No. 86 shown in Table 6 of Example 12 was formed. For comparison, the film No. 11 of Table 1 in which only T i 0 2 fine particles were dispersed in .S i〇2 and the film containing only S i〇2 without τ i〇2 fine particles were also similar to the molding. A film was formed on the surface of the board and evaluated. The exact same constitution as the aforementioned non-woven filter test was reviewed. The 5 cm x 5 cm m A B S plate was fixed to the center of the filter section. After 10 cigarettes were burned, the ventilation fan was driven for 120 minutes. The white A B S plate was contaminated with brown. This A B S plate was taken out and irradiated with light under the same conditions as described above, and its removal rate was evaluated by color difference measurement before and after. Figures 2 to 7 show this result. The result is almost the same as that of the filter, but since the attached dirt itself is less than that of the filter, the same degree of decoloring effect can be obtained with less than half the amount of light. In addition, sample No. 86 was prepared by adding L i N03 and a T〇 as an additional component. Compared with sample No. 11, a higher decomposition efficiency can be obtained. Secondly, the results of the anti-fouling evaluation of contaminated items due to oils and fats in the environment where there is a lot of oil in the kitchen and the like are collated. On a 5 cm X 5 cm glass plate formed with a low-temperature hardening type highly active oxide photocatalyst film composed of the sample No. 86 shown in Table 6 of Example i 2, a thin layer of salad of about 5 (// m) was applied. Oil is irradiated with ultraviolet light, and the calendar of oil is measured (please read the precautions on the back before filling this page)

am· bib · μ·· ο··· I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -59- 482694 A7 B7 五、發明說明（57) 時重量變化。第2 8圖顯示此結果。此結果經察，不含 T 1 〇2的樣本第1 2號幾無重量變化。含有T i〇2的樣本第1 1號與第2號固因隨著光照射油分解、揮散而重量減少，惟樣本第2號由於配有本發明L i N〇3 ,故大幅增進分解效率，與樣本第1 1號比較，可獲得約2倍的.分解效率。即使在如第2 8圖所示一般之.不能得到光量的環境，也能得到本發明之防止油的固體化效果。沙拉油等之食用油係與氧接觸就會酸化惡化，其結果是進行游離基聚合、增加粘度。特別是放置附著在換氣扇等之部分之薄層膜狀的沙拉油不管就會變成固體狀。此反應被光線照射就會加速反應，快速地變質成不易洗淨的堅固之固體狀。通常照射螢光燈及特別是紫外線燈之光線就會使因油的聚合而產生的固體化先行，加速變質成不易脫落之污垢。可是，附著於本發明之樣本第1 2號的觸媒膜上之油係不會發生此固體化，有保持低粘度液體之效果。即使在如第2 8圖般的分解卻無法達到重量減少之黑暗環境，因這種效果油不會固體化，所以即使在以肥皂及洗淨液等洗淨的情況時，也變的容易淸洗。包括以上一系列實施例情形，形成本發明低溫硬化型高活性氧化物光觸媒薄膜之際，可使用各種方法來提高與基底材質密接的性質。就使用塗料的方法而言，預先塗佈譬如各種偶合劑，而後形成光觸媒薄膜，即具有效果。舉例來說，有矽烷偶合劑與有機鈦系化合物。就矽烷偶合劑實例而言，可使用乙烯基三（Θ甲氧基本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)am · bib · μ ·· ο ··· I This paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) -59- 482694 A7 B7 5. The weight change during the description of the invention (57). Figures 2 to 8 show this result. This result was observed, and the sample No. 12 without T 1 〇2 had almost no weight change. The samples No. 1 and No. 2 containing T i〇2 have a reduced weight due to the decomposition and volatilization of the oil with light irradiation. However, the sample No. 2 is significantly improved in decomposition efficiency because it is equipped with the L i No. 3 of the invention. Compared with the sample No. 11, the decomposition efficiency of about 2 times can be obtained. Even in an environment where the amount of light cannot be obtained, as shown in Fig. 28, the solidification prevention effect of the oil of the present invention can be obtained. Food oils such as salad oils will deteriorate when contacted with oxygen. As a result, radical polymerization and viscosity increase will occur. In particular, a thin film-like salad oil placed on a part such as a ventilator becomes solid regardless of the state. This reaction is accelerated by the light, which accelerates the reaction and quickly deteriorates into a solid solid that is not easy to clean. Generally, the light emitted from fluorescent lamps and especially ultraviolet lamps causes solidification caused by the polymerization of oil in advance, and accelerates the deterioration into dirt that is not easy to fall off. However, the oil system adhered to the catalyst film No. 12 of the sample of the present invention does not solidify, and has the effect of maintaining a low-viscosity liquid. Even in a dark environment that cannot be reduced in weight as it is decomposed as shown in Figure 28, the oil does not solidify because of this effect, so it is easy to wash even when it is washed with soap or detergent. wash. Including the above series of embodiments, when forming the low-temperature hardening type highly active oxide photocatalyst film of the present invention, various methods can be used to improve the properties of close contact with the substrate material. In the method of using a coating material, it is effective to apply various coupling agents in advance, and then form a photocatalyst film. For example, there are a silane coupling agent and an organic titanium-based compound. As an example of the silane coupling agent, vinyl tris (Θ methoxy) can be used. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

· ϋ · an mmMt ·_ϋ ϋ 11 · 11 ·ϋ 1 i 1_1 11 I 經濟部*0,曰慧財查苟員二滤費合itfi印製 -60- 482694 A7 B7 五、發明說明（58 ) 乙氧基）矽烷、乙烯基三***矽烷、乙烯基三甲氧基矽院、7 —（甲基丙烯丙基）三甲氧基矽烷、/3(3, 4環氧環己基）乙基三甲氧基矽烷、r一環氧丙氧基丙基三甲氧基矽烷、r 一環氧丙氧基丙基甲基二乙氧基矽烷、N -/3 (氨乙酯）r 一氨丙基三甲氧基矽烷、η — /5 (氨乙.酯） r -氨丙基三甲基二乙氧基矽烷、r.-氨丙基三乙氧基矽烷、N-苯基一r-氨丙基三甲氧基矽烷與r-巯基丙基三曱氧基矽烷等。就有機鈦系化合物而言，可使用酞乙酯、酰化酞、鈦螯合物，特別是4 一 i 一丙氧基鈦、四（2 —乙基）酞、次一 i —丙氧基、雙（乙酰7七卜于卜）酞、酞一 i 一丙氧基辛二醇、鈦硬脂酸酯等極具效果。且，使用各種表面質地改變手段，導入氫氧基、羰基、羧基等，氧化處理對象物的表面，強固結合本發明低溫硬化型高活性氧化物光觸媒薄膜的方法有效。具體而言，有紫外線照射、電子束照射、電暈放電處理、臭氧環境氣體處理等方法。在聚酰胺樹脂與聚酯樹脂等較具親水性的樹脂情形下，無需上述前置處理固可獲得極高附著力，惟對聚烯系樹脂與高結晶性的樹脂而言，進行此種前置處理極具效果。根據前面所述，本發明混合A g與C u作爲光觸媒活性高的添加成份極具效果。這同時可獲得膜本身電絕緣性降低與帶電防止效果，更且，亦可獲得微生物繁殖抑制效果。在倂用A g與C u離子情形下，即使不接觸光，亦可本紙張瓦度適用中國國家標準（CNS)A4規格（210 X 297公爱） -61 - (請先閱讀背面之注意事項再填寫本頁) · i·— an 1 I t ·ϋ ·ϋ ϋ 482694 A7 B7 ____ 五、發明說明（59 ) 抑制微生物的繁殖。本發明對象的應用範圍並不限於以上所舉具體例說明的裝置。亦即，本發明原理在於，藉由照射紫外線等預定波長的電磁波，即可促進無機聚合物的高分子化，結果，即使是塑膠類等耐熱性低的素材表面，若形成以T i 0 2爲主要成份的光觸媒無機質薄膜，即可.活用藉由添加各種度將以此T i 0 2爲主要成份的光觸媒反應活性變增高數倍的特點，使熱可塑性泛用塑膠類、熱硬化性塑膠類或塑膠材料塗覆表面具有光觸媒功能，活用此原理，即可獲得習知技術所無法在低耐熱性低的素材表面上，以微弱光強度分解有機物的功能。且藉由添加降低膜本身表面電阻質的半導體微粒子，由於可獲得塗膜表面的帶電防止效果，故因靜電所造成的污物附著情形極少。本發明將具有上述作用的部件設置在各種裝置類的氣流部位，由於可有效分解所附著有機物，故若係具有氣流發生或過濾此氣流的構造的裝置，即易於用在任何製品。舉例來說，可應用於石油風扇加熱器、瓦斯風扇加熱器、電加熱器類與燻籠等以作爲暖房器具。同樣可應用於空氣調和機、除濕機或冷風扇。亦可應用於加熱式與超音波式加濕機。亦可適用於爐與電磁烹調機等加熱烹調器具類。亦可用於頭髮吹風機。且可用於具備冷卻扇的裝置類。亦即，個人電腦暨文字處理機等各種電腦類、陰極射線管等的電腦機器的顯示器類、或使用複印機與雷射印表機等電子攝影機構的裝置類、液晶投影機暨幻燈片投影機等 (請先閱讀背面之注意事項再填寫本頁)· Ϋ · an mmMt · _ϋ ϋ 11 · 11 · ϋ 1 i 1_1 11 I Ministry of Economic Affairs * 0, printed by Fiji Chagou 2 filter fee and printed by itfi-60- 482694 A7 B7 V. Description of the invention (58) B Oxy) silane, vinyltriethylethersilane, vinyltrimethoxysilane, 7- (methacrylpropyl) trimethoxysilane, / 3 (3, 4 epoxycyclohexyl) ethyltrimethoxysilane , R-glycidoxypropyltrimethoxysilane, r-glycidoxypropylmethyldiethoxysilane, N-/ 3 (aminoethyl) r-aminopropyltrimethoxysilane , Η — / 5 (aminoethyl.ester) r-aminopropyltrimethyldiethoxysilane, r.-aminopropyltriethoxysilane, N-phenyl-r-aminopropyltrimethoxy Silane and r-mercaptopropyltrimethoxysilane. For organic titanium compounds, ethyl phthalate, acylated phthalate, titanium chelate, especially 4-i-propoxytitanium, tetra (2-ethyl) phthalide, and sub-i-propoxy , Bis (acetyl-7-but-bu) phthalide, phthalo-i-propoxyoctanediol, titanium stearate, etc. are very effective. In addition, it is effective to use a variety of surface texture modification means to introduce a hydroxyl group, a carbonyl group, a carboxyl group, and the like to oxidize the surface of an object to be treated, and to strongly combine the low-temperature-curable highly active oxide photocatalyst film of the present invention. Specifically, there are methods such as ultraviolet irradiation, electron beam irradiation, corona discharge treatment, and ozone ambient gas treatment. In the case of relatively hydrophilic resins such as polyamide resins and polyester resins, extremely high adhesion can be obtained without the above-mentioned pretreatment. However, for polyolefin resins and highly crystalline resins, this kind of pretreatment is performed. Setting processing is very effective. According to the foregoing, the mixing of Ag and Cu in the present invention is extremely effective as an additive component having high photocatalytic activity. This can simultaneously achieve the effect of reducing the electrical insulation of the film itself and the prevention of charging, and also the effect of suppressing the growth of microorganisms. In the case of using Ag and Cu ions, the paper's wattage can be adapted to the Chinese National Standard (CNS) A4 (210 X 297 public love) even if it is not exposed to light. -61-(Please read the precautions on the back first Fill out this page again) · i · — an 1 I t · ϋ · ϋ ϋ 482694 A7 B7 ____ V. Description of the invention (59) Inhibit the reproduction of microorganisms. The application range of the object of the present invention is not limited to the devices described in the specific examples given above. That is, the principle of the present invention is that by irradiating electromagnetic waves of a predetermined wavelength such as ultraviolet rays, the polymerization of inorganic polymers can be promoted. As a result, even if the surface of a material with low heat resistance such as plastics is formed with T i 0 2 The photocatalyst inorganic thin film which is the main component can be used. By adding various degrees, the reactive activity of the photocatalyst with this T i 0 2 as the main component can be increased several times, so that the thermoplastic plastics and thermosetting plastics are widely used. The coating surface of similar or plastic materials has the function of photocatalyst. Using this principle, you can obtain the function of decomposing organics on the surface of materials with low heat resistance and low heat, which can not be degraded by conventional techniques. Moreover, by adding semiconductor fine particles that reduce the surface resistance of the film itself, since the effect of preventing the electrification of the surface of the coating film can be obtained, there is very little dirt adhesion due to static electricity. In the present invention, the components having the above-mentioned functions are provided in the air flow parts of various devices, and since the attached organic matter can be effectively decomposed, if the device has a structure that generates or filters the air flow, it is easy to use in any product. For example, it can be applied to oil fan heaters, gas fan heaters, electric heaters, fumigation cages, etc. as heating appliances. The same applies to air conditioners, dehumidifiers or cooling fans. It can also be applied to heating and ultrasonic humidifiers. It can also be applied to heating cooking appliances such as stoves and induction cookers. Can also be used for hair dryers. It can also be used in devices with cooling fans. That is, various computers such as personal computers and word processors, monitors of computer equipment such as cathode ray tubes, devices using electronic photographing mechanisms such as copiers and laser printers, liquid crystal projectors and slide projectors (Please read the notes on the back before filling out this page)

I tame Μββ I · —Bi ammmm n ϋ ϋ eMmmm I 泰紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） -62- 482694 A7 B7 五、發明說明（6Q) 裝置類上所附設的冷卻風扇部份，使用此等裝置的冷卻風扇的冷卻風通風用吸氣口暨排氣口部份以及此等吸排氣口部上安裝濾片部份，可設有與本發明相同的低溫硬化型高活性氧化物光觸媒薄膜，其效果相同。〔發明效果〕 . 以下就本發明效果加以彙整。本發明諸如空氣淸淨機、換氣扇、扇風機、掃除機、衣物乾燥機、餐具乾燥機、餐具洗濯機、蔚房渣滓處理機等內藏藉電動機產生氣流的機構，主要用於室內環境的電氣製品類的氣流通路、過濾部份、外裝部份、以照明機構照射的內藏部份，由於設有低溫硬化型高活性氧化物光觸媒薄膜，故具有以下效果。本發明具有三大效果。經濟部智慧財產局員工消費合作社印製第一，本發明藉由在習知T i 〇2等氧化物光觸媒薄膜中添加含有N a、L i等，電氣陰性度小於1 · 6，離子半徑小於0 · 2 n m的元素，原子價在2以下的離子，即可提高有機物的分解效果。甚而，倂用加於其中含有銻添加氧化錫，電氣親合力1 · 2以上的金屬氧化物半導體，或Ag、 Cu、 Ni、 Pd、 Rh、 Pt金屬微粒子，將可進一步提高分解效率。藉此即可獲得無需設有對習知氧化物光觸媒而言必要的紫外線燈等短波長光線發生機構的效果。亦即，以一般室內的光，乃至於螢光燈、白熾燈泡、水銀燈、穿起窗玻璃的太陽光等的非弱光來分解有機物 -63- (請先閱讀背面之注意事項再填寫本頁) 木紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 482694 A7 B7 五、發明說明（61) (請先閱讀背面之注意事項再填寫本頁) ，即使附著有煙草煙油與手部油脂等皮脂類的附著物所形成的污物，亦可分解而獲得防污效果。同樣，若附著分散於空氣中的有機胺與硫醇等各種惡臭肇因物質，以微弱光將其分解，由於可分解成低臭氣或無臭氣物質，故可獲得減低室內臭氣的除臭效果。且若附著飄遊於空氣中的·細菌、黴、花粉等各種微生物類，同時以微弱光來發揮有機物分解作用，由於能消滅此等微生物或抑制其繁殖，故可獲得在保持形成氧化物觸媒薄膜材料的表面淸潔同時，降低使用此等製品的室內空氣中浮遊微生物量的效果。習知濾片與網件等過濾空氣的部件大多作爲換裝部件來使用，若污物一直蓄積而塞住網目，即須取出部件洗淨，換裝新部件，而本發明由於分解所附著污物，故可獲得延長其迄於網塞住的壽命，並可減少換裝頻率的效果。I tame Μββ I · —Bi ammmm n ϋ ϋ eMmmm I Thai paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) -62- 482694 A7 B7 V. Description of Invention (6Q) The cooling fan part, the air inlet and exhaust part for the cooling air ventilation of the cooling fan using these devices, and the filter part mounted on the air exhaust part may be provided with the same The effect of the low-temperature hardening type highly active oxide photocatalyst film is the same. [Effects of the Invention]. The effects of the present invention are summarized below. Mechanisms such as air purifiers, ventilating fans, fan fans, sweepers, clothes dryers, dish dryers, dishwashers, and Weifang dregs processors are used to generate air flow by electric motors, and are mainly used for electrical products in indoor environments. Similar airflow paths, filter parts, exterior parts, and built-in parts illuminated by the lighting mechanism are provided with a low-temperature-curable, highly active oxide photocatalyst film, which has the following effects. The invention has three major effects. Printed first by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. By adding N a, Li, etc. to the conventional oxide photocatalyst film such as T i 〇2, the electrical negativeness is less than 1 · 6, and the ion radius is less than 0 · 2 nm elements, ions with an atomic value below 2 can increase the decomposition effect of organic matter. Furthermore, the use of metal oxide semiconductors containing antimony, tin oxide, and an electrical affinity of 1.2 or more, or metal particles of Ag, Cu, Ni, Pd, Rh, and Pt will further increase the decomposition efficiency. This makes it possible to obtain the effect that it is not necessary to provide a short-wavelength light generating mechanism such as an ultraviolet lamp, which is necessary for the conventional oxide photocatalyst. That is, organic matter is decomposed with non-weak light such as general indoor light, even fluorescent lamps, incandescent bulbs, mercury lamps, sunlight through window glass, etc.-(Please read the precautions on the back before filling this page ) Wood paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 482694 A7 B7 V. Description of invention (61) (Please read the precautions on the back before filling this page), even if there is tobacco smoke oil attached Dirt formed with sebum attachments such as hand grease can also be decomposed to obtain an antifouling effect. Similarly, if various odor-causing substances such as organic amines and mercaptans dispersed in the air are attached, they are decomposed with weak light, and can be decomposed into low-odor or odor-free substances, so that deodorization that reduces indoor odor can be obtained. effect. In addition, if various microorganisms such as bacteria, mold, and pollen adrift in the air are attached, and organic light is decomposed by weak light, these microorganisms can be eliminated or their reproduction can be suppressed. Therefore, it is possible to maintain the formation of oxide catalysts. The effect of reducing the amount of planktonic microorganisms in the indoor air using these products while the surface of the film material is clean. Most of the conventional air-filtering components such as filters and nets are used as replacement parts. If the dirt keeps accumulating and plugs the mesh, the parts must be taken out for cleaning and replaced with new parts. Therefore, the effect of prolonging the life of the net plugging and reducing the frequency of changing clothes can be obtained.

經濟部智慧財4局員1消費合泎fi,-pM 以下說明各用途的具體效果實例。空氣淸淨機、換氣扇、扇風機、掃除機、衣物乾燥機、餐具乾燥機、餐具洗濯機、廚房渣滓處理機的外框、框架、殻體類的外裝部件上，由於均照射室內照明與太陽光，故保持難以污染，微生物難以繁殖的淸潔狀態。且若設置成室內照明與太陽光亦照射於此等物品上所設氣流通路部件與氣流通路中的濾、片、網件等部件上，不僅同樣可獲得防污、抗菌，亦可獲得室內除臭效果。至於防污效果，空氣淸淨機、換氣扇、扇風機、掃除機固然有設置紅外線接收部於本體，設置紅外線發射部於遙控部，以進行遠距操作的情形，惟亦具有防止此紅外線 -64- 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） 482694 A7 B7 五、發明說明（62) 接收部附著污物以致於妨害信號收發的不適當現象的效果〇 (請先閱讀背面之注意事項再填寫本頁) 一般在以室內光強度無法充份分解的污染色荷大的情形，以及使用室內光無法充份接觸到的材料情形下，附設螢光燈與電燈泡等照明裝置，即具有效果。且在如此.配置亦不夠情形下，倂設水銀燈與金屬鹵.素燈等紫外線發生裝置，即可獲得極高分解效果。於此情形下，由於本發明較習知者分解效率高，故燈類的點燈時間縮短，且因燈類的輸出可低減，故可獲得節約消耗電力，延長燈類壽命，以及換裝頻度變少的效果。舉例來說，在分解廚房澄滓處理機所產生多量惡臭物質以及廚房用換氣扇附著大量食用油情形，以及必須具備餐具洗濯機、餐具乾燥機、衣物乾燥機的密閉槽與圓筒內部的淨化效果情形下，倂用前述各種波長的光發生裝置，即具有效果。第二，本發明由於添加含添加銻氧化錫，電氣親合力 1 · 2以上的金屬氧化物半導體，或Ag、Cu、Ni、經濟部智慧財產局員工消費合作钍印裂Members of the Bureau of Wisdom and Finance of the Ministry of Economic Affairs 1 Consumption combined fi, -pM The following describes examples of specific effects for each application. Air purifiers, ventilation fans, fan fans, sweepers, clothes dryers, tableware dryers, tableware washing machines, kitchen dregs processors' outer frames, frames, and housing exterior components are exposed to indoor lighting and the sun. Light, so it is difficult to contaminate, and it is difficult for microorganisms to reproduce. And if it is arranged that indoor lighting and sunlight are also irradiated on the airflow path components and filters, sheets, nets and other components in the airflow path provided on these items, not only can it be anti-fouling, antibacterial, but also indoor removal Stink effect. As for the anti-fouling effect, although air purifiers, ventilators, fans, and sweepers have infrared receivers on the body and infrared transmitters on the remote control for remote operation, they also prevent this infrared-64- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 x 297 mm) 482694 A7 B7 V. Description of the invention (62) The effect of dirt attached to the receiving part to prevent the transmission and reception of inappropriate signals. (Please read first Note on the back, please fill out this page) Generally, in the case of large pollution color charge that cannot be fully decomposed by indoor light intensity, and the use of materials that cannot be fully touched by indoor light, lighting devices such as fluorescent lamps and electric bulbs are attached. , That has effect. And in this case, the configuration is not enough, you can obtain a very high decomposition effect by setting up ultraviolet generating devices such as mercury lamps and metal halide lamps. In this case, since the present invention has higher decomposition efficiency than the conventional one, the lighting time of the lamps is shortened, and the output of the lamps can be reduced, so it can save power consumption, extend the life of the lamps, and change the frequency Less effect. For example, in the case of decomposing a large amount of odorous substances produced by a kitchen cleaning treatment machine and a large amount of edible oil adhered to a kitchen ventilating fan, and must have a cleaning effect on the closed tank of the dishwasher, dishwasher, and clothes dryer, and the purification effect inside the cylinder In this case, it is effective to use the light generating devices of the aforementioned various wavelengths. Second, due to the addition of tin oxide containing antimony, the present invention has a metal affinity semiconductor with an affinity of 1.2 or more, or Ag, Cu, Ni, and the consumer cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs.

Pd、Rh、Pt金屬粒子，故膜本身的表面電阻値可壓低。就分解效果而言，可抑制與分解時間有關的大型塵埃與纖維類或無法分解的土等礦物類因靜電而附著的現象。藉此作用，可抑制難分解性污物滯積於表面以致光無法到達光觸媒薄膜表面現象。此帶電防止效果不止防止塵埃等污物附著，亦可防範因帶有靜電以致電路錯誤動作於未然。尤其，於掃除機使本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -65- 482694 A7 B7 ___ 五、發明說明（63 ) 用中，對易摩擦帶電的物品類有極大效果。茲說明各用途的具體效果實例。空氣淸淨機、換氣扇、扇風機、掃除機、衣物乾燥機、餐具乾燥機、餐具洗濯機、廚房渣滓處理機的外框、框架、殼體類外裝部件，由於特別易於附著塵土類，故極有效果。第三，在本發明具有上述效果的光觸媒薄膜形成之際由含有低分子量有機金屬化合物與水的溶液作成，爲破壞此金屬原子與有機基的結合，藉由照射須含紫外線光等特定波長的電磁波，由於促進膜化反應，故可形成較習知者更低溫薄膜。因此，相對於前述電氣製品類所用含A B S 、PS、PP、聚酯等在泛用塑膠類、鋼板類上塗覆有機塗料的表面，基底素材因熱軟化、變形、發生氣泡、割痕、脆化、強度降低、韌性降低等不適當情形不會發生，而可形成上述氧化物光觸媒薄膜。茲說明各用途具體效果實例。就通常使用於空氣淸淨機、換氣扇、扇風機、掃除機、衣物乾燥機、餐具乾燥機、餐具洗濯機、廚房渣滓處理機的外框、框架、殼體類外裝部件的合成樹脂成型體或塗覆鋼板類而言，習知以 T ^〇2爲主體的氧化物光觸媒薄膜形成溫度固可耐3 0 〇 °C以上的高溫，惟根據本發明，不會因熱損壞此等部件表面的質地，可極易形成薄膜。且上述物品類所附設氣流通路部件與氣流通路中的風扇、葉片、濾片、網件類部件同樣以耐3 0 0 °C以上熱處理的素材來構成固極爲困難，惟本發明卻易於形成上述氧 (請先閱讀背面之注意事項再填寫本頁)Pd, Rh, and Pt metal particles can reduce the surface resistance of the film itself. With regard to the decomposition effect, it is possible to suppress the phenomenon that large dusts related to decomposition time, minerals such as fibers, and soil that cannot be decomposed are adhered by static electricity. By this action, it is possible to suppress the phenomenon that hardly decomposable dirt stays on the surface so that light cannot reach the surface of the photocatalyst film. This electrification prevention effect not only prevents the attachment of dirt such as dust, but also prevents the circuit from malfunctioning due to static electricity. In particular, in the cleaning machine, the paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -65- 482694 A7 B7 ___ 5. Description of the invention (63) In use, there are items that are easily charged with friction Great effect. Examples of specific effects for each application are described below. Air purifiers, ventilators, fans, sweepers, clothes dryers, tableware dryers, tableware washing machines, kitchen dregs processors' outer frames, frames, and housing exterior components are extremely easy to adhere to dust, so they are extremely effective. Third, when the photocatalyst film having the above-mentioned effects of the present invention is formed, it is made of a solution containing a low-molecular-weight organic metal compound and water. Electromagnetic waves can form a thinner film than conventional ones because it promotes the film formation reaction. Therefore, compared with the surfaces of organic plastics and steel plates coated with ABS, PS, PP, polyester and other materials used in the aforementioned electrical products, the base material is softened, deformed, bubbled, cut, and brittle due to heat. Inappropriate situations such as reduction in strength, reduction in toughness, etc. do not occur, and the above-mentioned oxide photocatalyst film can be formed. Examples of specific effects for each use are described below. Synthetic resin moldings commonly used in the outer frames, frames, and housing exterior parts of air purifiers, ventilators, fans, sweepers, clothes dryers, dish dryers, dishwashers, kitchen dregs processors, or In the case of coated steel sheets, it is known that the formation temperature of oxide photocatalyst films with T ^ 2 as the main body can withstand high temperatures above 300 ° C. However, according to the present invention, the surface of these components will not be damaged by heat. Texture, can easily form a thin film. In addition, the airflow passage components attached to the above-mentioned items are extremely difficult to constitute with the materials such as fans, blades, filters, and net pieces in the airflow passage, which are resistant to heat treatment above 300 ° C, but the present invention is easy to form the above. Oxygen (Please read the notes on the back before filling this page)

經濟部智慧財4局員X消費合作fi卬裂本紙張&度適用中國國家標準（CNS)A4規格（210 x 297公釐） 66 經濟部智慧財產局員工消費合作钍印製 482694 A7 B7 五、發明說明（64 ) 化物光觸媒薄膜。就其他效果而言，本發明氧化物光觸媒薄膜由可形成低溫硬質膜，故可替代習知塑膠成形品上塗覆的丙烯基系樹脂等熱塗層而極具效果。因此，除了與習知熱塗層一樣可增進成形品光澤，防止表面刮傷外，復可獲得微生.物繁殖抑制效果、防污效果與帶電防止效果。且在用於不織布、織布、海棉等製成的濾片類情形下，纖維表面上所形成的氧化物光觸媒薄膜，其表面吸著性與浸潤性極佳。因此，可增進臭氣的捕集與煙粒子的捕集效率。固然即使形成僅含s i 〇2的薄膜亦同理可增進捕集效率，惟臭氣與煙粒子附著而被覆於纖維表面上的話，即會減少捕集效率，由於本發明此玻璃質膜本身具有光觸媒作用，故纖維表面可常保持潔淨，由於高吸著性的質地表面持續露出，故效果持續保持。更且，在餐具洗濯機情形下，可利用光觸媒防污效果，低減內部所附著水滴的接觸角度。藉此由於可低減殘水總量，故具有提高餐具乾燥效率的效果。利用此效果可在水滴附著而難以處理方面作各種應用。圖式之簡單說明第1圖係本發明實施形式之過濾型空氣淸淨機本體之構成圖。第2圖係本發明實施形式之過濾型空氣淸淨機本體之斜視圖。 (請先閱讀背面之注意事項再填寫本頁)Member of the Bureau of Intellectual Property 4 of the Ministry of Economic Affairs X Consumer Cooperation Fission Paper & Degree Applies to Chinese National Standard (CNS) A4 Specification (210 x 297 mm) 66 Employees of Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperation Printing 482694 A7 B7 V. Description of the Invention (64) A photocatalyst film. In terms of other effects, the oxide photocatalyst film of the present invention can form a low-temperature hard film, so it can be very effective in replacing a thermal coating such as an acrylic-based resin applied on a conventional plastic molded article. Therefore, in addition to improving the gloss of the molded product and preventing scratches on the surface, as in the conventional thermal coating, microbiological growth inhibition effects, antifouling effects, and antistatic effects can be obtained. In the case of filters made of non-woven fabrics, woven fabrics, sponges, etc., the oxide photocatalyst film formed on the fiber surface has excellent surface absorption and wettability. Therefore, the efficiency of trapping odor and trapping smoke particles can be improved. Although even the formation of a film containing only si 〇2 can also improve the collection efficiency, but if the odor and the smoke particles adhere to the fiber surface, it will reduce the collection efficiency. Because the vitreous membrane of the present invention has The photocatalyst function keeps the fiber surface clean, and the high-absorption texture surface is continuously exposed, so the effect is maintained. Moreover, in the case of a dishwashing machine, the photocatalyst antifouling effect can be used to reduce the contact angle of the water droplets attached inside. As a result, the total amount of residual water can be reduced, which has the effect of improving the drying efficiency of tableware. This effect can be used for various applications in which water droplets are attached and difficult to handle. Brief Description of the Drawings Fig. 1 is a structural diagram of a filter type air purifier body according to an embodiment of the present invention. Fig. 2 is a perspective view of a main body of a filtering type air purifier according to an embodiment of the present invention. (Please read the notes on the back before filling this page)

本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） · 67 482694 A7 _ B7 五、發明說明（65) 第3圖係本發明實施形式之靜電集塵式空氣淸淨機本體之剖視圖。第4圖係本發明實施形式之廚房用通風扇本體之剖視圖。第5圖係本發明實施形式之電風扇本體之剖視圖。· 第6圖係本發明實施形式之掃除機之斜視圖。第7圖係本發明實施形式之掃除機本體之剖視圖。第8圖係本發明實施形式之衣物烘乾機本體之剖視圖〇第9圖係本發明實施形式之餐具烘乾機本體之斜視圖〇第1 0圖係本發明實施形式之餐具烘乾機本體之剖視圖。第1 1圖係本發明實施形式之餐具烘乾機之排氣口部份放大剖視圖。第1 2圖係本發明實施形式之餐具洗濯機本體之斜視圖。 H 1 3圖係本發明實施形式之餐具洗濯機本體之剖視圖。胃1 4 B係本發明實施形式之餐具洗濯機本體之剖視圖。胃1 5圖係本發明實施形式之廚房渣滓處理機本體之斜視圖。胃1 6圖係本發明實施形式之廚房渣滓處理機本體之 -68- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） 482694 A7 B7 經濟部智慧財4笱3工璁費合泎?£印製五、發明說明（66) 剖視圖。第1 7圖係PET薄膜上所形成T i〇2分散S i〇2 膜之剖視圖。第1 8圖係被覆體上所形成低溫硬化型高活性光觸媒薄膜之剖視圖。第1 9圖係被覆體上層疊二層所形成低溫硬化型高活性氧化物光觸媒薄膜之剖視圖。第2 0圖係顯示有機色素分解試驗結果之圖表。第21圖係顯示電陰性度與分解率關係之圖表。第2 2圖係顯示電陰性度與離子半徑關係之圖表。第2 3圖係顯示低溫硬化型高活性氧化物光觸媒薄膜之煙捕集效果之圖表。第2 4圖係顯示煙附著薄膜之光分解效果之圖表。第2 5圖係顯示低溫硬化型高活性氧化物光觸媒薄膜之氨捕集效果圖表。第2 6圖係顯示氨氣的光分解效果的圖表。第2 7圖係顯不煙附著A B S板之光分解效果之圖表〇第2 8圖係顯示沙拉油光分解效果之圖表。符號說明 1 空氣淸淨機本體 2 板（吸入口） 3、3 6 過濾器 (請先閱讀背面之注意事項再填寫本頁)This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) · 67 482694 A7 _ B7 V. Description of the invention (65) Figure 3 shows the body of the electrostatic precipitator air purifier according to the implementation form of the present invention Cutaway view. Fig. 4 is a sectional view of a kitchen fan main body according to an embodiment of the present invention. Fig. 5 is a sectional view of an electric fan body according to an embodiment of the present invention. Figure 6 is a perspective view of a sweeper according to an embodiment of the present invention. Fig. 7 is a sectional view of the main body of the sweeper according to the embodiment of the present invention. Fig. 8 is a sectional view of a clothes dryer body according to an embodiment of the present invention. Fig. 9 is a perspective view of a dish dryer body according to an embodiment of the present invention. Fig. 10 is a dish dryer body according to an embodiment of the present invention. Cutaway view. Fig. 11 is an enlarged sectional view of an exhaust port portion of a dishwasher according to an embodiment of the present invention. Fig. 12 is a perspective view of a dishwasher body according to an embodiment of the present invention. H 1 3 is a cross-sectional view of a dishwasher body according to an embodiment of the present invention. Stomach 14 B is a cross-sectional view of a dishwasher body according to an embodiment of the present invention. Stomach 15 is a perspective view of a kitchen waste treatment machine body according to an embodiment of the present invention. The stomach 16 figure is -68- of the kitchen waste treatment machine body of the implementation form of the present invention (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210x 297 mm) 482694 A7 B7 Ministry of Economic Affairs Wisdom Wealth 4 笱 3 Working Expenses? £ 5. Description of Invention (66) Sectional view. Fig. 17 is a cross-sectional view of a Tio2 dispersed Sio2 film formed on a PET film. Fig. 18 is a cross-sectional view of a low-temperature-curable, highly active photocatalyst film formed on a coating body. Fig. 19 is a cross-sectional view of a low-temperature-curing highly active oxide photocatalyst film formed by laminating two layers on a coating body. Figure 20 is a graph showing the results of an organic pigment decomposition test. Figure 21 is a graph showing the relationship between electrical negativeness and decomposition rate. Figure 22 is a graph showing the relationship between electrical negativeness and ion radius. Fig. 23 is a graph showing the smoke trapping effect of the low-temperature hardening type highly active oxide photocatalyst film. Figure 24 is a graph showing the photodecomposition effect of the smoke-adhered film. Fig. 25 is a graph showing the ammonia trapping effect of a low-temperature hardening type highly active oxide photocatalyst film. Fig. 26 is a graph showing the photodecomposition effect of ammonia gas. Fig. 27 is a graph showing the photodecomposition effect of non-smoke attached A B S plate. 〇 Fig. 28 is a graph showing the photodecomposition effect of salad oil. Explanation of symbols 1 Air purifier body 2 Plate (suction port) 3, 3 6 Filter (Please read the precautions on the back before filling this page)

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本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -69- 482694 A7 B7 五、發明說明（67 ) 14 格子板 15、 2〇、89、 128、 152、 175 排氣口 19、 117、 174 吸氣口 21 前置過濾器 24 臭氧去除過濾器 · 30,43 電動機 . 31.41 葉片 3 3 孔口 34、 133、 158 螢光管 3 8 電風扇本體基台部 3 9 支柱 4 0 滑動管 4 2 保護部 4 5 網件 5 0 掃除機本體 6 2 集塵室 7 〇電動送風機部 7 3 第 — 排氣通風路 7 4 第二排氣通風路 7 5 排氣通風路 7 6 排氣通風部 7 9 濾紙 8 2 輔助過濾器 8 4、 129、182 排氣過濾器 (請先閱讀背面之注意事項再填寫本頁)This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -69- 482694 A7 B7 V. Description of the invention (67) 14 Grid plate 15, 20, 89, 128, 152, 175 Exhaust port 19, 117, 174 Suction port 21 Pre-filter 24 Ozone removal filter · 30, 43 Motor. 31.41 Blade 3 3 Orifice 34, 133, 158 Fluorescent tube 3 8 Fan body abutment part 3 9 Pillar 4 0 Sliding pipe 4 2 Protective part 4 5 Net piece 5 0 Sweeper body 6 2 Dust collecting chamber 7 〇 Electric blower part 7 3 First-exhaust ventilation path 7 4 second exhaust ventilation path 7 5 exhaust ventilation path 7 6 Exhaust ventilation section 7 9 Filter paper 8 2 Auxiliary filter 8 4, 129, 182 Exhaust filter (Please read the precautions on the back before filling this page)

· ϋ n ϋ ϋ I ί ϋ-^-rejI n ϋ ϋ I I I I I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -70- 482694 A7 _B7 五、發明說明（68 ) 8 5 外框 9 8 循環導管 10 6 本體 10 7 乾燥室 116 吸氣過濾器 13 1. 15 1 排氣導管 134 照明器具 13 5 外框 136 餐具收貯槽 155 送風組件 15 6 送風扇 159 照明器具 16 0 框體 16 1 攪拌翼 16 3 生渣滓投入口 16 4 處理槽 17 3 通風扇 18 4 紫外線燈經濟邹智慧財4局員Η消費合作fi.印製 (請先閱讀背面之注意事項再填寫本頁) 18 5 P E T薄膜 18 6 S 1〇2膜 18 7 T 1〇2微粒子 188 Τι〇2分散Si〇2膜 189 塑膠被覆體 1 9 〇 Li 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） _ 71 _ 482694 A7 B7 .、發明說明（69) 19 1 高活性光觸媒膜 1 9 2 帶電防止底層 19 3 氨添加氧化錫 19 4 高活性光觸媒膜 (請先閱讀背面之注意事項再填寫本頁)· Ϋ n ϋ ϋ I ί ^-^-rejI n ϋ ϋ IIIII This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -70- 482694 A7 _B7 V. Description of the invention (68) 8 5 Outer frame 9 8 Circulation duct 10 6 Main body 10 7 Drying room 116 Suction filter 13 1. 15 1 Exhaust duct 134 Lighting fixture 13 5 Outer frame 136 Tableware storage tank 155 Air supply assembly 15 6 Air supply fan 159 Lighting appliance 16 0 Frame Body 16 1 Stirring wing 16 3 Slag feed port 16 4 Processing tank 17 3 Ventilation fan 18 4 Ultraviolet lamp economy Zou Zhicai 4 Bureau members Η Consumer cooperation fi. Printed (please read the precautions on the back before filling this page) 18 5 PET film 18 6 S 1〇2 film 18 7 T 1〇2 fine particles 188 Tι2 dispersed Si〇2 film 189 plastic coating 1 9 〇 Li This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 (Mm) _ 71 _ 482694 A7 B7., Description of the invention (69) 19 1 Highly active photocatalyst film 1 9 2 Anti-charge bottom layer 19 3 Ammonia added tin oxide 19 4 Highly active photocatalyst film (Please read the precautions on the back before filling (This page)

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經齋邨皆¾)¾¾¾員Χ-消費令泎f£.--pM 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -72-All members in Jingzhai Village ¾) ¾¾¾ X-Consumption Order 泎 f £ .-- pM This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -72-

Claims

482694 本告公 >0 8 8、、 Λ B CD ft T 土印申請專利範圍 1 · 一種具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其特徵爲：在接觸室內光源或室外太陽光的物件表面上，形成散佈有T i 〇2微粒子的塗膜，於該塗膜中摻雜元素的電陰性度小於1 · 6、離子半徑小於〇 . 2納米，至少係N a、 L i 、K、Mg、Ca與S r的一種，且添加元素的原子價2以下的離子，其添加量爲0.5〜2Owt%。 2 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中形成前述低溫硬化型高活性氧化物光觸媒薄膜的物品其材料熔點或分解溫度具有 3 0 0 °C以下的耐熱特性。 3 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中形成前述低溫硬化型高活性氧化物光觸媒薄膜的物品其表面材料係由有機高分子或充塡無機絲與無機纖維的有機高分子所組成。 4 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中形成前述低溫硬化型高活性氧化物光觸媒薄膜的物品其部件材料係由有機高分子或充填無機絲與無機纖維的有機局分子所組成。 5 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中前述T i〇2微粒子的大小爲5〜2 0納米。 6 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中前述T i〇2微粒子散布在 -、紙戌义度巧同中國國家蠓準（CNS ) A4規格（210X 2Q7公螫〜 '.ά-τ 先¾¾ 背 6 二注4^項再靖：.^本頁) 、v't482694 This document > 0 8 8, Λ B CD ft T Soilmark Application Patent Scope 1 · An article with a low temperature hardening type highly active oxide photocatalyst film, which is characterized by: On the surface of the object, a coating film dispersed with T i 〇2 fine particles is formed, and the electronegativity of the doping element in the coating film is less than 1.6, and the ion radius is less than 0.2 nm, at least Na, Li, K One of Mg, Mg, Ca, and S r, and an ion with an atomic valence of 2 or less for the added element, and the added amount is 0.5 to 2 wt%. 2 · For items with low temperature hardening type highly active oxide photocatalyst film as described in item 1 of the scope of patent application, wherein the material forming the aforementioned low temperature hardening type highly active oxide photocatalyst film has a material melting point or decomposition temperature below 300 ° C Heat resistance. 3 · If the article with a low-temperature-curable high-active-oxide photocatalyst film is the first item in the scope of the patent application, the surface material of the article forming the aforementioned low-temperature-curable high-active-oxide photocatalyst film is made of organic polymers or filled inorganic wires Composed of organic polymers with inorganic fibers. 4 · If the article with a low-temperature-curable high-active-oxide photocatalyst film is the first item in the scope of the application for a patent, wherein the component material of the article forming the aforementioned low-temperature-curable high-active-oxide photocatalyst film is composed of organic polymers or filled inorganic wires It consists of organic molecules of inorganic fibers. 5. The item having a low-temperature-curable, highly active oxide photocatalyst film as described in item 1 of the scope of the patent application, wherein the size of the aforementioned Tio2 particles is 5 to 20 nm. 6 · If the item with low temperature hardening type highly active oxide photocatalyst film in item 1 of the patent application scope, wherein the aforementioned Tio2 fine particles are dispersed in-, the paper is of the same meaning as China National Standard (CNS) A4 ( 210X 2Q7 public 螫 ~ '.ά-τ first ¾¾ back 6 two notes 4 ^ item and then Jing:. ^ This page), v't

-73- .¾ it vi :’p 482694 B8 C8 D8 V、申請專利範圍 Si〇2中，Ti〇2/Si〇2的重量比爲9〜5。 7 .如申請專利範圍第6項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中前述低溫硬化型高活性氧化物光觸媒薄膜之膜厚爲1 0 〇〜5 0 0納米。 8 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中添加調配於前述氧化物光觸媒薄膜中的電陰性度小於1 · 6、離子半徑小於0 · 2 納米、原子價2以下的離子所構成的元素，散布有以至少電子親合力1 · 2以上金屬元素所構成的氧化物半導體爲主體的氧化物微粒子。 9 ·如申請專利範圍第8項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中以前述氧化物半導體爲主體的氧化物微粒子爲A T 0 (銻摻雜氧化錫）。 1 0 ·如申請專利範圍第8項或9項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中以前述氧化物半導體爲主體的氧化物微粒子其添加量爲2〜5 Ow t %。 1 1 ·如申請專利範圍第6項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中前述氧化物光觸媒薄膜係複數層疊構造，在表面算起第1層上形成有T i 〇2微粒子散布於S i〇2中，添加電陰性度小於1 · 6、離子半徑小於0 · 2納米的元素的原子價2以下離子的氧化物光觸媒薄膜，並在表面算起第2層上形成有散佈氧化物微粒子的氧化物薄膜，此氧化物微粒子以至少電子親合力1 . 2 以上金屬元素所構成的氧化物半導體爲主體。方、纸張义度適用中國國家樣準（CNS ) A4規格（210>〇W公等-73- .¾ it vi: ’p 482694 B8 C8 D8 V, in the scope of patent application Si〇2, the weight ratio of Ti〇2 / Si〇2 is 9 ~ 5. 7. The article having a low-temperature hardening type highly active oxide photocatalyst film according to item 6 of the patent application scope, wherein the film thickness of the low-temperature-hardening type highly active oxide photocatalyst film is 100 nm to 500 nm. 8 · If the item with a low temperature hardening type highly active oxide photocatalyst film in item 1 of the patent application scope is added, the electronegativity of the oxide photocatalyst film added to the aforementioned oxide photocatalyst film is less than 1 · 6, the ion radius is less than 0 · 2 nm, An element composed of ions having an atomic value of 2 or less is interspersed with oxide fine particles mainly composed of an oxide semiconductor composed of a metal element having at least an electron affinity of 1.2 or more. 9 · For the article with a low-temperature hardening type highly active oxide photocatalyst film according to item 8 of the patent application scope, wherein the oxide fine particles mainly comprising the aforementioned oxide semiconductor are A T 0 (antimony-doped tin oxide). 10 · If the item with low temperature hardening type highly active oxide photocatalyst film of item 8 or 9 of the scope of patent application, the addition amount of the oxide fine particles mainly composed of the aforementioned oxide semiconductor is 2 to 5 Owt%. 1 1 · If the article has a low-temperature hardening type highly active oxide photocatalyst film according to item 6 of the patent application scope, wherein the aforementioned oxide photocatalyst film has a plurality of laminated structures, and T i 〇2 fine particles are formed on the surface of the first layer. An oxide photocatalyst thin film dispersed in Si 02 with an electronegative degree of less than 1 · 6 and an element with an ion radius of less than 0 · 2 nm with an atomic valence of 2 or less, and a dispersion is formed on the surface of the second layer An oxide thin film of oxide fine particles. The oxide fine particles mainly include an oxide semiconductor composed of a metal element having at least an electron affinity of 1.2 or more. Squareness and paper sense are applicable to China National Standard (CNS) A4 specifications (210 > 〇W etc.

-74 482694 Λ\\ j .» η I it ri B8 C8 D8 申請專利範圍 1 2 ·如申請專利範圍第9戌、1 1項中任一項之具備低溫硬化型尚活性氧化物光觸媒薄膜之物品，其中於散布有以電子親合力1·2以上金屬兀素所構成氧化物半導體爲主體的氧化物微粒子的前述氧化物薄膜中，氧化物微粒子由S η、F e與C r的至少其中一種的氧化物所構成。 1 3 ·如申請專利範圍第1 1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中以前述氧化物半導體爲主體的氧化物微粒子爲A T〇（銻摻雜氧化錫）。 1 4 ·如申請專利範圍第1 1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中於前述表面算起第2 層上形成有以S i 〇2爲主體的薄膜，此S i 〇2添加選自 Al、 Zr與Fe的至少其中一種。 1 5 ·如申請專利範圍第1 4項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中於前述表面算起第1 層與表面算起第2層的至少其中一層薄膜中添加AT〇。 1 6 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中在添加調配於前述氧化物光觸媒薄膜中的電陰性度小於1 . 6、離子半徑小於〇 · 2納米、原子價2以下離子所構成的元素外，復添加 Pt、 Rh、 Pd、 Ag、 Cu與Ni中至少一元素。 1 7 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中形成前述低溫硬化型高活性氧化物光觸媒薄膜之方法包括以下步驟：以含有低分子量有機金屬化合物與水的溶液所形成者方、纸張度適同中國國家愫準（〔NS丨A4規格（210X. 公蝥-74 482694 Λ \\ j. »Η I it ri B8 C8 D8 Application for patent scope 1 2 · If the patent scope of any one of the patent application items 9 戌 and 11 is equipped with a low temperature hardening type active oxide photocatalyst film, In the oxide thin film in which the oxide fine particles mainly composed of an oxide semiconductor composed of a metal element having an electron affinity of 1.2 or more are used, the oxide fine particles are composed of at least one of S η, F e and C r. Of oxides. 1 3 · As for the article with a low-temperature hardening type highly active oxide photocatalyst film according to item 11 of the scope of patent application, the oxide fine particles mainly composed of the aforementioned oxide semiconductor are A T0 (antimony-doped tin oxide). 1 4 · If the article with a low-temperature hardening type highly active oxide photocatalyst film according to item 11 of the scope of the patent application, wherein a film consisting mainly of S i 〇2 is formed on the second layer from the aforementioned surface, this S i 〇2 At least one selected from Al, Zr, and Fe is added. 15 · If the article with a low-temperature-curable high-active oxide photocatalyst film in item 14 of the scope of patent application, AT is added to at least one of the first layer and the second layer from the surface. . 16 · If the item with a low temperature hardening type highly active oxide photocatalyst film as described in item 1 of the patent application scope, wherein the electronegativity is less than 1.6 when added to the aforementioned oxide photocatalyst film, and the ion radius is less than 0.2 In addition to the element composed of ions having a nanometer and an atomic valence of 2 or less, at least one element of Pt, Rh, Pd, Ag, Cu, and Ni is further added. 1 7 · If the article with a low-temperature-curable high-active-oxide photocatalyst film is the first item in the scope of patent application, the method for forming the low-temperature-curable high-active-oxide photocatalyst film includes the following steps: The formula of the water solution and the degree of paper are suitable for the Chinese national standard ([NS 丨 A4 Specification (210X.

-75- 482694 wuri.-*' B8 C8 DS 六、申請專利範圍供具有破壞該有機金屬化合物金屬原子與有機基的結合所需特定波長成份的電磁波照射，促進該有機金屬化合物的加水分解，於前述溶液中形成金屬氧化物之預聚物；以及將該預聚物溶液塗佈於前述物品表面上，並將其烘乾〇 1 8 .如申請專利範圍第1項之低溫硬化型高活性氧化物光觸媒薄膜之物品，其中形成前述低溫硬化型氧化物光觸媒薄膜之方法包括以下步驟= 以含有低分子量的有機金屬化合物與水的溶液來形成，在含有該低分子量有機金屬化合物與水的溶液塗佈於目標部件表面上之後，於含有該低分子量有機金屬化合物與水的溶液處於濕潤狀態期間，照射具有破壞該有機金屬化合物金屬原子與有機基結合所需特定波長成份的電磁波，促進該有機金屬化合物的加水分解，於前述溶液中形成金屬氧化物的預聚物；以及將該預聚物溶液烘乾。 1 9 ·如申請專利範圍第1 7項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中具有破壞前述有機金屬化合物金屬原子與有機基結合所需特定波長成份的電磁波爲紫外線。 2 0 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中氧化物光觸媒爲T i〇2 、S rT i 〇3、 BaT i 〇3、W〇3 與 S i C 中任一種或複數倂用者。方、纸張心度適同中國國家標準（cns ) A4規格（21〇乂：^公缝、，而之注.έ事項再填4本頁) 泰- ------1T------續--- -76- 482694 丨六、申請專利範圍 2 1 ·如申請專利範.圍第1項之具備低溫硬化型高活 I » 性氧化物光觸媒薄膜之物品，其中導電性微粒子散布於塗 I I 膜中，該塗膜表面電阻値在109Ω/□以下，且有防止帶 I i電功能。 ! * 22 ·如申請專利範圍第1項之具備低溫硬化型高活 I | 性氧化物光觸媒薄膜之物品，其中在光照射於前述低溫硬 I化型高活性氧化物光觸媒薄膜表面的位置上具有螢光燈管或白熾燈泡。 2 3 ·如申請專利範圍第1項之具備低溫硬化型高活性氧化物光觸媒薄膜之物品，其中在光照射於前述低溫硬化型局活性氧化物光觸媒薄膜表面的位置上具有紫外線燈 7ί;}- •二 4^^^11:^¾ 十、纸張β、度適用申國阈家榡箪（「NS ) A4規格（210 X Y公帑 -77--75- 482694 wuri .- * 'B8 C8 DS 6. The scope of the patent application is for electromagnetic wave irradiation with specific wavelength components required to destroy the combination of the metal atom of the organometallic compound and the organic group to promote the hydrolytic decomposition of the organometallic compound. A prepolymer that forms a metal oxide in the aforementioned solution; and the prepolymer solution is coated on the surface of the aforementioned article, and is dried 0 1. The low-temperature hardening type highly active oxidation as described in the first patent application range An article of a photocatalyst film, in which the method for forming the aforementioned low-temperature-curable oxide photocatalyst film includes the following steps: = forming a solution containing a low molecular weight organometallic compound and water, and coating the solution containing the low molecular weight organometallic compound and water After being placed on the surface of the target part, while the solution containing the low molecular weight organometallic compound and water is in a wet state, an electromagnetic wave having a specific wavelength component required to destroy the metal atom of the organometallic compound and the organic group is irradiated to promote the organometal Hydrolysis of the compound to form gold in the aforementioned solution An oxide-based prepolymer; and drying the prepolymer solution. 19 · If the item with a low-temperature hardening type highly active oxide photocatalyst film according to item 17 of the scope of patent application, the electromagnetic wave having a specific wavelength component required to destroy the aforementioned metal atom of the organic metal compound and the organic group is ultraviolet rays. 2 0 · Items with low temperature hardening type highly active oxide photocatalyst film as in item 1 of the scope of patent application, wherein the oxide photocatalyst is T i〇2, S rT i 〇3, BaT i 〇3, W〇3 and S i C Any or plural users. The squareness of the paper and the paper conform to the Chinese National Standard (cns) A4 specification (21〇乂: ^ quilt, and note. Please fill in 4 pages again) Thai------- 1T ----- -Continued --- -76- 482694 丨 VI. Patent application scope 2 1 · If the scope of the patent application is applied. The item with low temperature hardening type high activity I »sexual oxide photocatalyst film in the first item, in which conductive particles are dispersed In the coating II film, the surface resistance of the coating film 値 is below 109Ω / □, and it has the function of preventing the electrical charging. * 22 · If the item with a low temperature hardening type high activity I | photo-active oxide photocatalyst film as described in item 1 of the scope of the patent application has light irradiated on the surface of the aforementioned low temperature hard type I highly active oxide photocatalyst film, Fluorescent tubes or incandescent bulbs. 2 3 · If the article with a low-temperature hardening type highly active oxide photocatalyst film according to item 1 of the scope of the patent application has an ultraviolet lamp 7 at a position where the light is irradiated on the surface of the aforementioned low-temperature-hardening local active oxide photocatalyst film;}- • 2 4 ^^^ 11: ^ ¾ X. Paper β and degree are applicable to the Shen Guo threshold furniture ("NS) A4 specification (210 XY male -77-